首页 > 最新文献

Emerging Materials Research最新文献

英文 中文
Research on the influence of clay shock on inert slurry in shield tunneling construction 盾构施工中粘土冲击对惰性浆体影响的研究
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00173
Y. Wan, He Sun, Zhiduo Zhu, Wangwen Huo, Chen Zhang
Shield-out synchronous grouting is a new technology used to temporarily fill shield-out spaces between strata and the shield when creating subterraneous tunnels. The grouting materials are called ‘clay shock,’ which are soft, plastic, sticky, and easily dispersed via a pressurized jet. This study analyzes the mixing process of clay shock and backfill grouting material (inert slurry), and investigates the influence of clay shock on the inert slurry through laboratory testing. The findings show that the fluidity and bleeding rate of the inert slurry continuously decreases with the clay shock volume. The unconfined compressive strength (UCS) and flexural strength of the inert slurry increase initially before decreasing with the clay shock volume ratio. The X-ray diffraction (XRD) and scanning electron microscopy (SEM) results reveal that the alkalinity of the clay shock initiates an alkali excitation reaction, which generates more gelling products and increases the strength of the inert slurry. Excessive clay shock causes the inert slurry to retain a loose and porous structure, which then decreases its strength. To ensure the effect of the inert slurry on settlement control, the grouting volume of the clay shock should not exceed 1/4 of the inert slurry volume.
盾构同步注浆是在建造地下隧道时,用于临时填充地层与盾构之间的盾构间隙的一种新技术。灌浆材料被称为“粘土冲击”,它柔软、可塑、粘稠,很容易通过加压射流分散。本研究分析了粘土冲击与回填灌浆材料(惰性浆液)的混合过程,并通过实验室试验研究了粘土冲击对惰性浆液的影响。研究结果表明,随着粘土冲击体积的增加,惰性浆液的流动性和泌水率不断降低。惰性浆液的无侧限抗压强度(UCS)和抗弯强度随粘土冲击体积比的增大先增大后减小。X射线衍射(XRD)和扫描电子显微镜(SEM)结果表明,粘土冲击的碱度引发了碱激发反应,产生了更多的胶凝产物,提高了惰性浆料的强度。过度的粘土冲击会使惰性浆液保持松散多孔的结构,从而降低其强度。为保证惰性浆液对沉降控制的作用,粘土冲击的灌浆量不应超过惰性浆液量的1/4。
{"title":"Research on the influence of clay shock on inert slurry in shield tunneling construction","authors":"Y. Wan, He Sun, Zhiduo Zhu, Wangwen Huo, Chen Zhang","doi":"10.1680/jemmr.22.00173","DOIUrl":"https://doi.org/10.1680/jemmr.22.00173","url":null,"abstract":"Shield-out synchronous grouting is a new technology used to temporarily fill shield-out spaces between strata and the shield when creating subterraneous tunnels. The grouting materials are called ‘clay shock,’ which are soft, plastic, sticky, and easily dispersed via a pressurized jet. This study analyzes the mixing process of clay shock and backfill grouting material (inert slurry), and investigates the influence of clay shock on the inert slurry through laboratory testing. The findings show that the fluidity and bleeding rate of the inert slurry continuously decreases with the clay shock volume. The unconfined compressive strength (UCS) and flexural strength of the inert slurry increase initially before decreasing with the clay shock volume ratio. The X-ray diffraction (XRD) and scanning electron microscopy (SEM) results reveal that the alkalinity of the clay shock initiates an alkali excitation reaction, which generates more gelling products and increases the strength of the inert slurry. Excessive clay shock causes the inert slurry to retain a loose and porous structure, which then decreases its strength. To ensure the effect of the inert slurry on settlement control, the grouting volume of the clay shock should not exceed 1/4 of the inert slurry volume.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44277413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Impact of truncation on absorption spectra in graphene-based random photonic crystal 截断对石墨烯基随机光子晶体吸收光谱的影响
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00087
Pulimi Mahesh, C. Nayak, Damodar Panigrahy
The present study investigates the influence of randomness on getting multi-mode broadband and narrowband absorption of graphene-embedded photonic structures. In the first proposed photonic configuration, with the change in randomness parameter, it is possible to get single, multi-mode broadband absorption up to 0.8. This value was further enhanced up to 0.99 by varying the Fermi-level to −0.9 eV. The position of absorption peaks can be tuned by varying thickness of the silicon carbide layer. Further, an investigation is carried out on the influence of adding a defective periodic PC to the first photonic configuration, which provided a multi-mode narrowband absorption with a value up to 0.99 and the strength and location of absorption peaks can be altered to the desired value by changing the graphene’s Fermi level and thickness of the silicon carbide layer. Finally, the authors also survey the influence of magnetic field B on the absorption behaviour of LCP and RCP waves. The results indicate that the FWHM of absorption peaks expanded with applying a positive magnetic field for LCP waves, whereas it shrinks for RCP waves. It has applications in the design of tunable broadband, narrowband absorbers, and sensors.
本文研究了随机性对石墨烯嵌入光子结构多模宽带和窄带吸收的影响。在第一种提出的光子结构中,随着随机参数的变化,有可能获得高达0.8的单模、多模宽带吸收。当费米能级为- 0.9 eV时,该值进一步提高到0.99。吸收峰的位置可以通过改变碳化硅层的厚度来调节。此外,研究了在第一光子结构中加入缺陷周期PC的影响,该结构提供了一个多模窄带吸收,其值高达0.99,并且可以通过改变石墨烯的费米能级和碳化硅层的厚度来改变吸收峰的强度和位置。最后,研究了B磁场对LCP波和RCP波吸收特性的影响。结果表明,对LCP波施加正磁场时,吸收峰的频宽增大,对RCP波施加正磁场时,吸收峰的频宽减小。它在可调谐宽带、窄带吸收器和传感器的设计中都有应用。
{"title":"Impact of truncation on absorption spectra in graphene-based random photonic crystal","authors":"Pulimi Mahesh, C. Nayak, Damodar Panigrahy","doi":"10.1680/jemmr.22.00087","DOIUrl":"https://doi.org/10.1680/jemmr.22.00087","url":null,"abstract":"The present study investigates the influence of randomness on getting multi-mode broadband and narrowband absorption of graphene-embedded photonic structures. In the first proposed photonic configuration, with the change in randomness parameter, it is possible to get single, multi-mode broadband absorption up to 0.8. This value was further enhanced up to 0.99 by varying the Fermi-level to −0.9 eV. The position of absorption peaks can be tuned by varying thickness of the silicon carbide layer. Further, an investigation is carried out on the influence of adding a defective periodic PC to the first photonic configuration, which provided a multi-mode narrowband absorption with a value up to 0.99 and the strength and location of absorption peaks can be altered to the desired value by changing the graphene’s Fermi level and thickness of the silicon carbide layer. Finally, the authors also survey the influence of magnetic field B on the absorption behaviour of LCP and RCP waves. The results indicate that the FWHM of absorption peaks expanded with applying a positive magnetic field for LCP waves, whereas it shrinks for RCP waves. It has applications in the design of tunable broadband, narrowband absorbers, and sensors.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48310367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Flake shaped ZnFe2O4 nanoparticles: synthesis, characterization and visible light induced photocatalytic study 片状纳米ZnFe2O4:合成、表征及可见光诱导光催化研究
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00184
J. P. Dhal, Amit Sahoo, A. Acharya
Flake shaped ZnFe2O4 nanoparticles have successfully been prepared by co-precipitation method. The phase and crystallinity of the synthesised ZnFe2O4 nanoparticles were studied by XRD. The SEM result reveals that the flake shaped entities are formed by the combination of rod-shaped nanomaterial. The band gap of the synthesised ZnFe2O4 nanoparticles is found to be ∼ 2.14 eV by UV-Vis DRS measurements indicating thereby that this material absorbs visible light (λmax = 579.37 nm). The ferrite nanoparticles were successfully employed as a photocatalytic materials for the degradation of the dye Malachite green (MG) in aqueous medium with ∼ 99% efficiency under visible light irradiation.
采用共沉淀法成功制备了片状ZnFe2O4纳米颗粒。采用XRD对合成的纳米ZnFe2O4的物相和结晶度进行了研究。SEM结果表明,片状实体是由棒状纳米材料结合形成的。通过UV-Vis DRS测量发现,合成的ZnFe2O4纳米粒子的带隙为~ 2.14 eV,表明该材料吸收可见光(λmax = 579.37 nm)。在可见光照射下,铁酸盐纳米颗粒作为光催化材料在水介质中降解孔雀石绿(MG)染料,效率为99%。
{"title":"Flake shaped ZnFe2O4 nanoparticles: synthesis, characterization and visible light induced photocatalytic study","authors":"J. P. Dhal, Amit Sahoo, A. Acharya","doi":"10.1680/jemmr.22.00184","DOIUrl":"https://doi.org/10.1680/jemmr.22.00184","url":null,"abstract":"Flake shaped ZnFe2O4 nanoparticles have successfully been prepared by co-precipitation method. The phase and crystallinity of the synthesised ZnFe2O4 nanoparticles were studied by XRD. The SEM result reveals that the flake shaped entities are formed by the combination of rod-shaped nanomaterial. The band gap of the synthesised ZnFe2O4 nanoparticles is found to be ∼ 2.14 eV by UV-Vis DRS measurements indicating thereby that this material absorbs visible light (λmax = 579.37 nm). The ferrite nanoparticles were successfully employed as a photocatalytic materials for the degradation of the dye Malachite green (MG) in aqueous medium with ∼ 99% efficiency under visible light irradiation.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48601545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Effect of longitudinal magnetic field on arc motion and joint structure of hollow stud 纵向磁场对空心螺柱电弧运动及接头结构的影响
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00221
Deku Zhang, Mengyu Duan, Xinkai Zhu, Hongyu Zhang, Chonglin Wu, Kehong Wang
Given the non-uniform melting of the end face of the joint and the local non-fusion of the joint in large-diameter hollow stud welding, to research the law of arc motion, the joint forming quality, the weld microstructure and mechanical properties, in the process of hollow stud welding propelled by the longitudinal magnetic field in this paper. The results reveal that under the influence of the longitudinal magnetic field, the arc on the end of stud is affected by Lorentz force and spirals downward. In the welding process, with the increase of magnetic field intensity, the arc uniformly burns the stud end face, preventing local non-fusion and resulting in a well-shaped joint. Under the action of magnetic field stirring, the eutectoid ferrite is broken, the content of eutectoid ferrite and bainite is diminished, the nucleation barrier is reduced and the grain is refined. Under the action of the longitudinal magnetic field, the shear strength of the hollow stud welded joint is raised to 312 MPa, surpassing the strength of a joint welded without a magnetic field.
针对大直径空心螺柱焊中接头端面熔化不均匀和接头局部不熔合的问题,研究了纵向磁场推动空心螺柱焊过程中电弧运动规律、接头成形质量、焊缝显微组织和力学性能。结果表明:在纵向磁场的作用下,螺柱末端的圆弧受到洛伦兹力的影响,呈螺旋向下运动;在焊接过程中,随着磁场强度的增加,电弧均匀地烧伤螺柱端面,防止了局部不熔合,形成了形状良好的接头。在磁场搅拌作用下,共晶铁氧体破碎,共晶铁氧体和贝氏体含量减少,形核屏障减少,晶粒细化。在纵向磁场作用下,空心螺柱焊接接头的抗剪强度提高到312 MPa,超过了无磁场焊接接头的抗剪强度。
{"title":"Effect of longitudinal magnetic field on arc motion and joint structure of hollow stud","authors":"Deku Zhang, Mengyu Duan, Xinkai Zhu, Hongyu Zhang, Chonglin Wu, Kehong Wang","doi":"10.1680/jemmr.22.00221","DOIUrl":"https://doi.org/10.1680/jemmr.22.00221","url":null,"abstract":"Given the non-uniform melting of the end face of the joint and the local non-fusion of the joint in large-diameter hollow stud welding, to research the law of arc motion, the joint forming quality, the weld microstructure and mechanical properties, in the process of hollow stud welding propelled by the longitudinal magnetic field in this paper. The results reveal that under the influence of the longitudinal magnetic field, the arc on the end of stud is affected by Lorentz force and spirals downward. In the welding process, with the increase of magnetic field intensity, the arc uniformly burns the stud end face, preventing local non-fusion and resulting in a well-shaped joint. Under the action of magnetic field stirring, the eutectoid ferrite is broken, the content of eutectoid ferrite and bainite is diminished, the nucleation barrier is reduced and the grain is refined. Under the action of the longitudinal magnetic field, the shear strength of the hollow stud welded joint is raised to 312 MPa, surpassing the strength of a joint welded without a magnetic field.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44034322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Modified ZnO mediated dye detoxification by a heterogeneous Fenton process 改性ZnO介导的染料非均相Fenton脱毒
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00151
A. Alsukaibi, Mohd A. Khan, Ahmed M. Al-Otaibi, A. Alshamari, Eida Mohammad Alshammari, L. Mechi, F. Alimi, S. Khan
The continuous and unchecked discharge of effluents by the dyeing industry in water bodies, have lead to the rising importance of water treatment. This study focusses on the successful abatement of Auramine O (AM) dye in the aqueous system by a heterogeneous Fenton process using ultrasonication. Zinc oxide (ZnO) nanoparticles (NPs) were obtained by a straightforward precipitation method and then modified by glycine (M-ZnO). The NPs size sharply decreased upon modification with glycine. Light absorbing capacity and band gap were determined by Ultra Violet (UV) visible spectrophotometry. X-ray diffraction (XRD) was used to determine the basic crystal properties, such as crystallinity. Changes in crystal size and morphology were determined by scanning electron microscopy (SEM), while high-resolution transmission electron microscopy (HRTEM) provide more information on the shape and size of NPs. It was observed that the size of NPs sharply decreased from 24.6 nm (pure ZnO) to 17.3 nm upon modification of ZnO with glycine. A bandgap of 3.4 eV was determined for M-ZnO using UV-visible spectrophotometer. Fourier transform infrared (FTIR) spectroscopy was used to find different functional groups along with the presence of ZnO, which further confirmed the modification of ZnO with glycine. Thermal gravimetric analysis revealed the excellent thermal stability of M-ZnO compared with ZnO. The catalytic activity for AM abatement was determined using a Fenton process at pH 6. Detoxification assays showed pure H2O2 or pure ZnO exhibited 38% and 37% AM dye degradation respectively. However, M-ZnO showed 97% of AM dye degradation in 240 min. A plausible mechanism has been proposed for AM abatement using ZnO.
印染工业不断向水体排放废水,使水处理的重要性日益提高。本文研究了超声波非均相Fenton法对水溶液中金胺O (AM)染料的去除效果。采用直接沉淀法制备氧化锌纳米粒子(NPs),然后用甘氨酸(M-ZnO)修饰。甘氨酸修饰后,NPs的大小急剧下降。用紫外可见分光光度法测定了材料的吸光能力和带隙。用x射线衍射(XRD)测定了晶体的结晶度等基本性质。通过扫描电子显微镜(SEM)确定了晶体尺寸和形态的变化,而高分辨率透射电子显微镜(HRTEM)提供了更多关于NPs形状和尺寸的信息。结果表明,甘氨酸修饰ZnO后,NPs的尺寸从24.6 nm(纯ZnO)急剧减小到17.3 nm。用紫外可见分光光度计测定了M-ZnO的带隙为3.4 eV。利用傅里叶变换红外光谱(FTIR)发现ZnO存在时不同的官能团,进一步证实了甘氨酸对ZnO的修饰。热重分析表明,M-ZnO具有较好的热稳定性。在pH为6的条件下,采用Fenton法测定了其对AM的催化活性。解毒实验表明,纯H2O2和纯ZnO对AM染料的降解率分别为38%和37%。而M-ZnO在240 min内对AM染料的降解率为97%。提出了氧化锌对AM的抑制机理。
{"title":"Modified ZnO mediated dye detoxification by a heterogeneous Fenton process","authors":"A. Alsukaibi, Mohd A. Khan, Ahmed M. Al-Otaibi, A. Alshamari, Eida Mohammad Alshammari, L. Mechi, F. Alimi, S. Khan","doi":"10.1680/jemmr.22.00151","DOIUrl":"https://doi.org/10.1680/jemmr.22.00151","url":null,"abstract":"The continuous and unchecked discharge of effluents by the dyeing industry in water bodies, have lead to the rising importance of water treatment. This study focusses on the successful abatement of Auramine O (AM) dye in the aqueous system by a heterogeneous Fenton process using ultrasonication. Zinc oxide (ZnO) nanoparticles (NPs) were obtained by a straightforward precipitation method and then modified by glycine (M-ZnO). The NPs size sharply decreased upon modification with glycine. Light absorbing capacity and band gap were determined by Ultra Violet (UV) visible spectrophotometry. X-ray diffraction (XRD) was used to determine the basic crystal properties, such as crystallinity. Changes in crystal size and morphology were determined by scanning electron microscopy (SEM), while high-resolution transmission electron microscopy (HRTEM) provide more information on the shape and size of NPs. It was observed that the size of NPs sharply decreased from 24.6 nm (pure ZnO) to 17.3 nm upon modification of ZnO with glycine. A bandgap of 3.4 eV was determined for M-ZnO using UV-visible spectrophotometer. Fourier transform infrared (FTIR) spectroscopy was used to find different functional groups along with the presence of ZnO, which further confirmed the modification of ZnO with glycine. Thermal gravimetric analysis revealed the excellent thermal stability of M-ZnO compared with ZnO. The catalytic activity for AM abatement was determined using a Fenton process at pH 6. Detoxification assays showed pure H2O2 or pure ZnO exhibited 38% and 37% AM dye degradation respectively. However, M-ZnO showed 97% of AM dye degradation in 240 min. A plausible mechanism has been proposed for AM abatement using ZnO.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49010211","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Effects of modified argon glow plasma source on PET polymeric surface properties 改性氩辉光等离子体源对PET聚合物表面性能的影响
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00199
H. Al-Yousef, M. Atta, E. Abdeltwab, A. Atta, M. Abdel-Hamid
A home-made plasma source with a Langmuir electrical probe was built for this work in order to create a plasma beam that could be utilized successfully in a range of uses. By modifying the operational parameters, including the discharging voltage, cathode-anode spacing, as well as argon (Ar) pressure, a steady discharging media was achieved. Additionally, a locally design electrical probe is introduced into the discharging plasma to monitor the current-voltage (I-V) characteristics curve in order to assign plasma properties. The probe is moved to any intended destination in the plasma volume and has the following dimensions: 1 mm in length, 0.5 mm in diameter. The gas pressure as well as probe-cathode separation are modified to record the plasma characteristics including electron density and electron temperature. As the pressure rises from 0.15 up to 0.3 Torr, it was found that the electron temperature Te varies 4.66*104 to 2.91*104 eV. By subjecting PET polymeric film to Ar plasma beams, its surface wettability is altered. By increasing the plasma period from 0 to 8 minutes, the overall surfaces free energy is raised from 32.2 to 67.7 mJ/m2. Additionally, the developed plasma source is highly efficient and tailored to satisfy the needs of applications like polymeric-surface modifications.
为了这项工作,我们制作了一个带有朗缪尔电探针的自制等离子体源,以产生一种可以在各种用途中成功利用的等离子体束。通过修改操作参数,包括放电电压、阴极-阳极间距以及氩气(Ar)压力,实现了稳定的放电介质。此外,在放电等离子体中引入了局部设计的电探针,以监测电流-电压(I-V)特性曲线,从而分配等离子体特性。探针被移动到等离子体体积中的任何预期目的地,并具有以下尺寸:1 长度为mm,0.5 直径为mm。对气体压力和探针阴极分离进行了修改,以记录等离子体特性,包括电子密度和电子温度。当压力从0.15托升至0.3托时,发现电子温度Te变化为4.66*104至2.91*104 通过使PET聚合物膜经受Ar等离子体束,其表面润湿性发生改变。通过将等离子体周期从0分钟增加到8分钟,整个表面自由能从32.2分钟提高到67.7分钟 mJ/m2。此外,所开发的等离子体源是高效的,并可满足聚合物表面改性等应用的需求。
{"title":"Effects of modified argon glow plasma source on PET polymeric surface properties","authors":"H. Al-Yousef, M. Atta, E. Abdeltwab, A. Atta, M. Abdel-Hamid","doi":"10.1680/jemmr.22.00199","DOIUrl":"https://doi.org/10.1680/jemmr.22.00199","url":null,"abstract":"A home-made plasma source with a Langmuir electrical probe was built for this work in order to create a plasma beam that could be utilized successfully in a range of uses. By modifying the operational parameters, including the discharging voltage, cathode-anode spacing, as well as argon (Ar) pressure, a steady discharging media was achieved. Additionally, a locally design electrical probe is introduced into the discharging plasma to monitor the current-voltage (I-V) characteristics curve in order to assign plasma properties. The probe is moved to any intended destination in the plasma volume and has the following dimensions: 1 mm in length, 0.5 mm in diameter. The gas pressure as well as probe-cathode separation are modified to record the plasma characteristics including electron density and electron temperature. As the pressure rises from 0.15 up to 0.3 Torr, it was found that the electron temperature Te varies 4.66*104 to 2.91*104 eV. By subjecting PET polymeric film to Ar plasma beams, its surface wettability is altered. By increasing the plasma period from 0 to 8 minutes, the overall surfaces free energy is raised from 32.2 to 67.7 mJ/m2. Additionally, the developed plasma source is highly efficient and tailored to satisfy the needs of applications like polymeric-surface modifications.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48847846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Image-driven deep learning enabled automatic microstructural recognition 图像驱动的深度学习实现了自动微结构识别
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.1680/jemmr.22.00010
Rishabh Nigam, Vedasri Bai Khavala, Khushbu Dash, Nachiketa Mishra
Deep learning (DL) method consisting of Convolutional Neural Network (CNN) was employed to automate the task of microstructural recognition and classification to identify dendritic characteristics in metallic microstructures. The dendrites are an important feature which decide the mechanical properties of an alloy, further the dendritic arm spacing is critical in ascertaining the values of strength and ductility. The current work has been divided into two tasks i.e., classification of microstructures into dendritic and non-dendritic (Task 1) and further classifying the dendritic microstructures into longitudinal and cross-sectional view (Task 2). The data set comprising of micrographs from experimental and online sources covering a broad range of alloy compositions, micrograph magnifications and orientations. The tasks were achieved by employing a 4 layered CNN to yield an accuracy of 97.17±0.64% for Task 1 and 87.86±1.07% for Task 2 independently. The employment of deep learning model for classification of microstructures circumvents the feature extraction step while ensuring high accuracy. This work reduces dependency on skilled and experienced researchers and expedites the material development cycle.
采用卷积神经网络(CNN)组成的深度学习(DL)方法,实现了微结构识别与分类的自动化,以识别金属微结构中的枝晶特征。枝晶是决定合金力学性能的重要特征,枝晶臂间距是确定合金强度和塑性的关键因素。目前的工作分为两个任务,即将微观结构分为枝晶和非枝晶(任务1),并进一步将枝晶微观结构分为纵向和横向视图(任务2)。数据集包括来自实验和在线来源的显微照片,涵盖了广泛的合金成分,显微照片放大和方向。通过采用4层CNN来完成任务,任务1的准确率为97.17±0.64%,任务2的准确率为87.86±1.07%。采用深度学习模型对微结构进行分类,在保证高精度的同时避免了特征提取步骤。这项工作减少了对熟练和经验丰富的研究人员的依赖,并加快了材料开发周期。
{"title":"Image-driven deep learning enabled automatic microstructural recognition","authors":"Rishabh Nigam, Vedasri Bai Khavala, Khushbu Dash, Nachiketa Mishra","doi":"10.1680/jemmr.22.00010","DOIUrl":"https://doi.org/10.1680/jemmr.22.00010","url":null,"abstract":"Deep learning (DL) method consisting of Convolutional Neural Network (CNN) was employed to automate the task of microstructural recognition and classification to identify dendritic characteristics in metallic microstructures. The dendrites are an important feature which decide the mechanical properties of an alloy, further the dendritic arm spacing is critical in ascertaining the values of strength and ductility. The current work has been divided into two tasks i.e., classification of microstructures into dendritic and non-dendritic (Task 1) and further classifying the dendritic microstructures into longitudinal and cross-sectional view (Task 2). The data set comprising of micrographs from experimental and online sources covering a broad range of alloy compositions, micrograph magnifications and orientations. The tasks were achieved by employing a 4 layered CNN to yield an accuracy of 97.17±0.64% for Task 1 and 87.86±1.07% for Task 2 independently. The employment of deep learning model for classification of microstructures circumvents the feature extraction step while ensuring high accuracy. This work reduces dependency on skilled and experienced researchers and expedites the material development cycle.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44786148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Reaction mechanisms of pristine and Cu-doped ZnO clusters with ethanol using Evans–Polanyi principle 利用Evans–Polanyi原理研究原始和Cu掺杂ZnO团簇与乙醇的反应机理
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.1680/jemmr.22.00149
M. A. Abdulsattar, H. Abduljalil, H. Abed
The interaction and adsorption of pristine and Cu-doped ZnO nanoparticles of ethanol (C2H6O) and several other gases are calculated. These gases include carbon dioxide (CO2), carbon monoxide (CO), ammonia (NH3), ozone (O3), nitrogen dioxide (NO2), and sulfur dioxide (SO2). Most of these gases are air pollutants. ZnO wurtzoid clusters are used to represent ZnO nanoparticles. Gibbs free energy and enthalpy of reactions are evaluated. Evans–Polanyi principle is used to evaluate the activation energy that gives the best fit to the Arrhenius equation of the reaction. The results of solving the reaction rate equations are used to compare with experimental findings. The reaction of gases with the air before reaching the sensor surface is included. A comparison of calculated response time (10.5 s), recovery time (470 s), and reaction rate with available experimental results is performed (9 and 420 s respectively) for 50 ppm of ethanol at room temperature. From results above, Evans–Polanyi principle combined with Arrhenius equation can give acceptable results. The response time is inversely proportional to gas concentration, while recovery time is linearly proportional to the gas concentration. A correlation factor can relate reaction rate with the response.
计算了乙醇(C2H6O)和其他几种气体的原始和Cu掺杂的ZnO纳米颗粒的相互作用和吸附。这些气体包括二氧化碳(CO2)、一氧化碳(CO)、氨(NH3)、臭氧(O3)、二氧化氮(NO2)和二氧化硫(SO2)。这些气体大多是空气污染物。ZnO纤锌团簇用于表示ZnO纳米颗粒。评价了反应的吉布斯自由能和焓。Evans–Polanyi原理用于评估活化能,该活化能最适合反应的Arrhenius方程。将反应速率方程的求解结果与实验结果进行了比较。包括气体在到达传感器表面之前与空气的反应。计算响应时间的比较(10.5 s) ,恢复时间(470 s) ,并进行具有可用实验结果的反应速率(9和420 分别为s) ppm的乙醇。从以上结果来看,Evans–Polanyi原理与Arrhenius方程相结合可以给出可接受的结果。响应时间与气体浓度成反比,而恢复时间与气体密度成线性比例。相关因子可以将反应速率与响应相关联。
{"title":"Reaction mechanisms of pristine and Cu-doped ZnO clusters with ethanol using Evans–Polanyi principle","authors":"M. A. Abdulsattar, H. Abduljalil, H. Abed","doi":"10.1680/jemmr.22.00149","DOIUrl":"https://doi.org/10.1680/jemmr.22.00149","url":null,"abstract":"The interaction and adsorption of pristine and Cu-doped ZnO nanoparticles of ethanol (C2H6O) and several other gases are calculated. These gases include carbon dioxide (CO2), carbon monoxide (CO), ammonia (NH3), ozone (O3), nitrogen dioxide (NO2), and sulfur dioxide (SO2). Most of these gases are air pollutants. ZnO wurtzoid clusters are used to represent ZnO nanoparticles. Gibbs free energy and enthalpy of reactions are evaluated. Evans–Polanyi principle is used to evaluate the activation energy that gives the best fit to the Arrhenius equation of the reaction. The results of solving the reaction rate equations are used to compare with experimental findings. The reaction of gases with the air before reaching the sensor surface is included. A comparison of calculated response time (10.5 s), recovery time (470 s), and reaction rate with available experimental results is performed (9 and 420 s respectively) for 50 ppm of ethanol at room temperature. From results above, Evans–Polanyi principle combined with Arrhenius equation can give acceptable results. The response time is inversely proportional to gas concentration, while recovery time is linearly proportional to the gas concentration. A correlation factor can relate reaction rate with the response.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42707360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Microstructure and mechanical properties of SS316L prepared by selective laser melting 选择性激光熔融制备SS316L的组织与力学性能
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.1680/jemmr.22.00139
Di Chen, Q. Pan, Ziqi Liu, Qile Shi, Lin Zhang, Jingguang Peng, Ying Li
In this work, 316L stainless steel samples were prepared by selective laser melting (SLM) and the effects of the bulk laser energy density on the resulting density and mechanical properties were evaluated. The results show that the density and mechanical properties of SLM 316L stainless steel first improved then deteriorated with increasing bulk laser energy density. When the bulk laser energy density was 70.2 J·mm−3, the obtained tensile strength and yield strength vertical to the building direction were 720 and 546 MPa, respectively, which surpass the design requirements for forged 316L stainless steel. The influence of the microstructure on the mechanical properties of SLM 316L stainless steel is also discussed. The purpose of this research was to provide experimental data and a theoretical basis for high-performance 316L stainless steel fabricated by SLM.
在本工作中,通过选择性激光熔化(SLM)制备了316L不锈钢样品,并评估了体激光能量密度对所得密度和力学性能的影响。结果表明,随着体激光能量密度的增加,SLM36L不锈钢的密度和力学性能先提高后下降。当体激光能量密度为70.2 J·mm−3时,获得的垂直于建筑方向的抗拉强度和屈服强度分别为720和546 MPa,超过了锻造316L不锈钢的设计要求。还讨论了显微组织对SLM36L不锈钢力学性能的影响。本研究的目的是为SLM制备高性能316L不锈钢提供实验数据和理论依据。
{"title":"Microstructure and mechanical properties of SS316L prepared by selective laser melting","authors":"Di Chen, Q. Pan, Ziqi Liu, Qile Shi, Lin Zhang, Jingguang Peng, Ying Li","doi":"10.1680/jemmr.22.00139","DOIUrl":"https://doi.org/10.1680/jemmr.22.00139","url":null,"abstract":"In this work, 316L stainless steel samples were prepared by selective laser melting (SLM) and the effects of the bulk laser energy density on the resulting density and mechanical properties were evaluated. The results show that the density and mechanical properties of SLM 316L stainless steel first improved then deteriorated with increasing bulk laser energy density. When the bulk laser energy density was 70.2 J·mm−3, the obtained tensile strength and yield strength vertical to the building direction were 720 and 546 MPa, respectively, which surpass the design requirements for forged 316L stainless steel. The influence of the microstructure on the mechanical properties of SLM 316L stainless steel is also discussed. The purpose of this research was to provide experimental data and a theoretical basis for high-performance 316L stainless steel fabricated by SLM.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":" ","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42548608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Research on microstructure and mechanical properties of RSW joints of 7075T-6 alloy containing Sc 含Sc 7075T-6合金RSW接头组织与力学性能研究
IF 2.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.1680/jemmr.21.00142
Chao-pin Ma, Jun Shen, Hao Li, C. Zeng, Fuxing Xie
Nowadays, Resistance spot welding is a common welding method used in automobiles and other industries, and 7000 series Al alloy has become a very common industrial material because of its high strength and easy machinability. Scandium (Sc) is often used for alloy strengthening, however, there are few studies on resistance spot welding joint of Al alloy containing Sc. Here, 7075-T6 alloys containinga small amount of Sc were obtained to investigate the joint of resistance spot weldability. The simulation shows that the effective contact area between the Al sheet surface is about 19.5%, which is an important factor in nucleation. It has been found that the average grain size of the nugget decreased from 51.51 ± 5.74 μm to 8.15 ± 1.09 μm when Sc was added from 0 to 0.4 wt%, which is mainly due to the Al3Sc particles acting as the heterogeneous nucleus in the melt. The test results show that the tensile shear strength of welded joints with 0.4 wt% Sc addition is 29.2% higher than that of the joints without Sc because of grain refine strengthening.
目前,电阻点焊是汽车等行业常用的焊接方法,而7000系铝合金因其强度高、易切削加工,已成为一种非常常用的工业材料。钪(Sc)是一种常用的合金强化材料,但对含Sc的铝合金电阻点焊接头的研究较少。本文选取含少量Sc的7075-T6合金,研究其电阻点焊接头的可焊性。模拟结果表明,铝片表面之间的有效接触面积约为19.5%,这是影响成核的重要因素。当Sc的添加量为0 ~ 0.4 wt%时,熔核的平均晶粒尺寸由51.51±5.74 μm减小到8.15±1.09 μm,这主要是由于Al3Sc颗粒在熔体中起非均相核的作用。试验结果表明,Sc添加量为0.4 wt%时,由于晶粒细化强化,焊接接头的抗拉剪切强度比未添加Sc的焊接接头高29.2%。
{"title":"Research on microstructure and mechanical properties of RSW joints of 7075T-6 alloy containing Sc","authors":"Chao-pin Ma, Jun Shen, Hao Li, C. Zeng, Fuxing Xie","doi":"10.1680/jemmr.21.00142","DOIUrl":"https://doi.org/10.1680/jemmr.21.00142","url":null,"abstract":"Nowadays, Resistance spot welding is a common welding method used in automobiles and other industries, and 7000 series Al alloy has become a very common industrial material because of its high strength and easy machinability. Scandium (Sc) is often used for alloy strengthening, however, there are few studies on resistance spot welding joint of Al alloy containing Sc. Here, 7075-T6 alloys containinga small amount of Sc were obtained to investigate the joint of resistance spot weldability. The simulation shows that the effective contact area between the Al sheet surface is about 19.5%, which is an important factor in nucleation. It has been found that the average grain size of the nugget decreased from 51.51 ± 5.74 μm to 8.15 ± 1.09 μm when Sc was added from 0 to 0.4 wt%, which is mainly due to the Al3Sc particles acting as the heterogeneous nucleus in the melt. The test results show that the tensile shear strength of welded joints with 0.4 wt% Sc addition is 29.2% higher than that of the joints without Sc because of grain refine strengthening.","PeriodicalId":11537,"journal":{"name":"Emerging Materials Research","volume":"1 1","pages":""},"PeriodicalIF":2.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67477657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
Emerging Materials Research
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1