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Hydrothermally grown CdS-embedded graphene oxide nanocomposites with enhanced optical properties 水热生长的CdS嵌入氧化石墨烯纳米复合材料具有增强的光学性能
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-09-01 DOI: 10.1680/jemmr.22.00019
J. B. Kaundal, R. Tiwari, Y. Goswami
Nanocomposites based on graphene oxide have shown significant potential in various applications, including solar devices. In this work, hydrothermally synthesised cadmium sulfide-embedded graphene oxide (GO-CdS) nanocomposites have been reported. The resulting powder is black and was filtered and washed with distilled water. The samples were then characterised by X-ray diffraction, FTIR, optical transmission, and photoluminescence studies. The samples demonstrated a polycrystalline phase with a rutile structure and high luminescence peaks. As the amount of cadmium sulfide (CdS) in the graphene oxide increases, the size of the nanocomposites also increases. FTIR analysis confirmed the formation of GO-CdS nanocomposites. Furthermore, the samples exhibited excellent photoluminescence, which makes these composites highly suitable for optoelectronic applications.
基于氧化石墨烯的纳米复合材料在包括太阳能器件在内的各种应用中显示出巨大的潜力。在这项工作中,已经报道了水热合成的硫化镉嵌入氧化石墨烯(GO-CdS)纳米复合材料。得到的粉末是黑色的,用蒸馏水过滤和洗涤。然后通过x射线衍射、红外光谱、光学透射和光致发光研究对样品进行表征。样品表现为具有金红石结构的多晶相,发光峰高。随着氧化石墨烯中硫化镉(cd)含量的增加,纳米复合材料的尺寸也会增加。FTIR分析证实了氧化石墨烯- cds纳米复合材料的形成。此外,样品表现出优异的光致发光,这使得这些复合材料非常适合光电应用。
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引用次数: 1
Simulation study of defect density on the performance of quantum dot solar cell with PTAA HTL layer using SCAPS-1D 缺陷密度对PTAA HTL层量子点太阳能电池性能的SCAPS-1D模拟研究
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-09-01 DOI: 10.1680/jemmr.22.00130
Ahmad Umar, Vaishali Yadav, V. Srivastava, Sadanand, P. Lohia, D. K. Dwivedi, A. Ibrahim, S. Akbar, H. Qasem, S. Baskoutas
In recent years, the quantum dot solar cell has attracted attention due to its versatile electrical and optical properties as a material. The quantum dot solar cell can be tuned in terms of bandgap and size. In the present work effect of defect density on the performance of the solar cell is studied with the help of Solar Cell Capacitance Simulator in one dimension (SCAPS-1D). The defect density Poly[bis(4-phenyl) (2,4,6-trimethyl phenyl)amine] (PTAA)/ PbS- tetra-butyl ammonium iodide(PbS-TBAI) and PbS- tetra-butyl ammonium iodide(PbS-TBAI/ Titanium dioxide(TiO2) is varied from 1x1010 cm−2 to 1x1017 cm−2 and variation of electron mobility of TiO2, temperature and work function is done. This simulation-based quantum dot absorber-based solar cells may, in the future, prove to be extremely effective quantum dot solar cell.
近年来,量子点太阳能电池因其作为一种材料具有多功能的电学和光学特性而备受关注。量子点太阳能电池可以根据带隙和尺寸进行调整。本文利用一维太阳能电池电容模拟器(SCAPS-1D)研究了缺陷密度对太阳能电池性能的影响。缺陷密度聚[双(4-苯基)(2,4,6-三甲基苯基)胺](PTAA)/PbS-四丁基碘化铵(PbS-TBAI)和PbS-四丁基碘化铵(PbS TBAI/二氧化钛(TiO2)为1x1010 cm−2至1x1017 cm−2和TiO2的电子迁移率、温度和功函数的变化。这种基于模拟的量子点吸收体太阳能电池在未来可能会被证明是非常有效的量子点太阳能电池。
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引用次数: 1
Iron materials facilitated methane production from anaerobic wastewater treatment 铁材料促进厌氧废水的甲烷生成
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-09-01 DOI: 10.1680/jemmr.23.00034
Y. Wang, Jichun He, B. Xu, Nahid A Osman, Hassan Algadi, H. Abo-Dief, Na Lu, P. Wasnik, D. Sridhar, Abdullah K. Alanazi, Qinglong Jiang, B. Qiu, Zhanhu Guo
Various iron materials have been used to improve methane production rate in the anaerobic sludge. The effect of iron materials including zerovalent iron (ZVI), magnetite (Fe3O4) and iron (III) oxide (Fe2O3) on the methane production rate was compared. It was found that all the iron materials can improve the methane production rate, and ZVI, Fe3O4 and Fe2O3 increased by 19.8%, 13.7% and 17.9% in which the ZVI performed better on improving the methane production. Then the long-term effects of ZVI on the methane production rate by anaerobic organisms was further studied. ZVI increased the methane production rate by 7.2%, the improvement was unstable and decreased due to the corrosion and loss of the ZVI in the anaerobic wastewater treatment system. The improved performance was recovered after the ZVI was re-added into the anaerobic sludge, the methane production rate increased by 6.1%. The added ZVI obviously enriched exoelectrogenic archaea Methanobacterium due to its ability of direct interspecific electron transfer, and its relative abundance was up to 61.99%. The enhanced direct interspecific electron transfer was disclosed as the main mechanism involved in enhanced methanogenesis in the anaerobic sludge.
为了提高厌氧污泥的甲烷产率,采用了多种铁材料。比较了零价铁(ZVI)、磁铁矿(Fe3O4)和氧化铁(Fe2O3)等铁材料对甲烷产率的影响。结果表明,所有铁材料均能提高甲烷产率,其中ZVI、Fe3O4和Fe2O3分别提高了19.8%、13.7%和17.9%,其中ZVI对甲烷产率的提高效果更好。然后进一步研究了ZVI对厌氧生物产甲烷速率的长期影响。ZVI使产甲烷率提高了7.2%,但由于ZVI在厌氧废水处理系统中的腐蚀和损失,提高效果不稳定,降低了产甲烷率。在厌氧污泥中重新添加ZVI后,其性能得到恢复,产甲烷率提高了6.1%。添加ZVI后,由于其具有直接种间电子转移的能力,明显富集了产电古甲烷菌,其相对丰度高达61.99%。结果表明,增强的种间直接电子转移是促进厌氧污泥产甲烷的主要机制。
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引用次数: 1
CMT-based wire arc additive manufacturing of Inconel 625 alloy 铬镍铁合金625的CMT基电弧增材制造
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-09-01 DOI: 10.1680/jemmr.23.00053
J. Junwen, A. Zavdoveev, D. Vedel, T. Baudin, S. Motrunich, I. Klochkov, S. Friederichs, N. Strelenko, M. Skoryk
Cold metal transfer (CMT) technology is considered in an application for wire arc additive manufacturing WAAM of refractory high corrosion resistant Inconel 625 alloy. Based on the fabricated wall it has been shown the suitability of CMT WAAM for the sound formation of weld and homogenous distribution of mechanical properties has been shown. Microscopy analysis has revealed that the microstructure of the deposited alloy along the height of the wall element is relatively uniform. The minor differences in the microstructure are observed in the bottom part, caused by welding specifically. It should be noted that there is a slight decrease in strength indicators from the bottom to the top of the welded product, but they do not exceed 5%, which is considered entirely satisfactory. This phenomenon is caused by structural transformations that take place in slightly different cooling conditions, namely in the lower layers, the substrate on which the surfacing was carried out plays a more significant role in heat flow. This leads to more intensive cooling of the lower layers and as a result slightly higher values of strength.
将冷金属转移(CMT)技术应用于难熔高耐蚀Inconel 625合金的线弧增材制造WAAM。基于预制壁,已经表明CMT WAAM适用于焊缝的良好形成和机械性能的均匀分布。显微镜分析表明,沉积合金的微观结构沿着壁元件的高度是相对均匀的。在底部观察到微观结构的微小差异,这是由焊接引起的。应该注意的是,从焊接产品的底部到顶部,强度指标略有下降,但不超过5%,这被认为是完全令人满意的。这种现象是由在稍微不同的冷却条件下发生的结构转变引起的,即在较低的层中,进行堆焊的基底在热流中起着更重要的作用。这导致较低层的更密集的冷却,并且因此强度值略高。
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引用次数: 1
Effect of Magnetite on physical, tribological and magnetic characteristics of Kenaf fiber 磁铁矿对红麻纤维物理、摩擦学和磁性质的影响
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00162
S. Pujari, S. Santosh Kumar, N. Naveen, C. Devi, Sivarao
The demand for organic fibres with remarkable mechanical, magnetic, and physical properties is rising. As a result, the current study investigated the impact of magnetite reinforcement on Kenaf fiber. The test samples were prepared by the hand-layup process with the addition of magnetite in the range of 10–40 wt%. Test results showed that samples with 30% magnetite content exhibit the best mechanical, physical, and tribological characteristics. It shows water absorption of 0 g, average wear of 112 microns, and an average frictional force of 1.1 N. Magnetic absorption in samples with 30 and 40 weight percent magnetite is -0.000378 to 0.00038623  emu/g and -0.000260218 to 0.000257814 emu/g, respectively.
对具有显著机械、磁性和物理性能的有机纤维的需求正在上升。因此,本研究探讨了磁铁矿增强对红麻纤维的影响。测试样品采用手工铺层工艺制备,添加10-40 wt%的磁铁矿。测试结果表明,磁铁矿含量为30%的样品具有最佳的机械、物理和摩擦学特性。吸水率为0 g,平均磨损度为112微米,平均摩擦力为1.1 N。磁铁矿含量为30%和40%的样品的磁吸收率分别为-0.000378 ~ 0.00038623 emu/g和-0.000260218 ~ 0.000257814 emu/g。
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引用次数: 1
Editorial: Materials for a more sustainable usage 社论:更可持续使用的材料
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-06-01 DOI: 10.1680/jemmr.2023.12.2.101
F. Heim
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引用次数: 0
Effect of Magnetic field on dielectric properties in PLT/BNCFO composites 磁场对PLT/BNCFO复合材料介电性能的影响
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00183
I. Sharma, Shruti Mahajan, V. Arora, Mehak Arora, Nitin Mahajan, Kanika Aggarwal, Anupinder Singh
The main goal of this study is to analyze the magnetic, dielectric, and magneto-dielectric characteristics of Pb1− x La x Ti1− x O 3 - (Ba1–3 x Nd2 x )4Co2Fe36O60 (where x = 0.25) composite material at various temperatures T1-T3 (i.e 1100°C ,1200°C, 1300°C respectively). The X-ray diffraction investigation has been introduced in order to pinpoint the creation of the U-type hexaferrite phase. SEM micrographs reveal that sample sintered at T2 reached the maximum value of grain size and the largest experimental density value of 6.14 g/cm3 due to the composite material's intensified grain growth. The magnetic investigations further indicate that the sample T2 achieved the highest remnant magnetization, measuring 1.550 emu/g, revealing the accuracy of the sintering temperature. The magneto-dielectric investigations demonstrate the presence of multiferroicity in all samples, and came to the conclusion that sample T2 exhibits the highest magneto-dielectric response of 41.99 at 1.2 Tesla and a magneto-dielectric coefficient (γ) of around 0.7609 g2/emu2. Numerous metrics, including nyquist plots, impedance, electrical modulus, dielectric constant, and conductivity, were carefully examined in order to determine the electrical properties of the proposed sample. It was found that sample T2 produced the enhanced results and had the right temperature for the substance to develop.
本研究的主要目的是分析Pb1−x La x Ti1−x O 3 - (Ba1-3 x Nd2 x)4Co2Fe36O60 (x = 0.25)复合材料在T1-T3(分别为1100℃、1200℃、1300℃)不同温度下的磁性、介电和磁介电特性。为了查明u型六铁素体相的形成,引入了x射线衍射研究。SEM显微图显示,T2烧结试样的晶粒尺寸最大值和实验密度最大值为6.14 g/cm3,这是由于复合材料晶粒生长加剧所致。磁性研究进一步表明,T2样品的残余磁化强度最高,为1.550 emu/g,表明烧结温度的准确性。磁介电特性研究表明,所有样品均存在多铁性,并得出结论,样品T2在1.2特斯拉时的磁介电响应最高,为41.99,磁介电系数(γ)约为0.7609 g2/emu2。许多指标,包括奈奎斯特图,阻抗,电模量,介电常数和电导率,仔细检查,以确定所提出的样品的电学性质。发现样品T2产生了增强的结果,并且具有合适的温度来形成物质。
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引用次数: 1
Investigation of failure mechanism of dissimilar resistance spot welding of steels 钢异种电阻点焊失效机理的研究
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00224
M. Prabhakaran, D. Jeyasimman, M. Varatharajulu
Austenitic and Duplex Stainless steel was majorly preferred for the heat exchangers and the chemical containers. This research work proposed to investigate the failure mechanism of dissimilar welded joints of AISI 347 and DSS 2205. The welded specimens were investigated under tensile shear test, cross tension test, coach peel test, and micro-hardness test. The specimen absorbed a maximum tensile shear load of 18 kN during the tensile shear test and the failure mode was button pull out with brittle fracture. The test sample absorbed a load of 15.1 kN during the cross tension test and the failure mode was button pull out with brittle fracture. During coach peel test, the sample absorbed a maximum load of 4 kN and ductile fracture was witnessed at the vicinity of the nugget. The failure mode in coach peel test was button pull out type. The microhardness test recorded a maximum hardness of 312.8 HV which is 78.74% and 7.1% higher than the base metal hardness values of AISI 347 and AISI 2205 respectively. The specimen failed under pull out failure mode in all the tests and hence the weld zone was intact in all the specimen arrangement and loading conditions.
奥氏体和双相不锈钢主要用于热交换器和化学容器。本研究旨在探讨AISI 347与DSS 2205异种焊接接头的失效机理。对焊接试样进行了拉伸剪切试验、交叉拉伸试验、教练剥离试验和显微硬度试验。试件在拉伸剪切试验过程中最大受拉剪切载荷为18 kN,破坏模式为扣拔脆性断裂。试件在交叉拉伸试验中承受了15.1 kN的载荷,破坏模式为拉扣脆性断裂。在剥离试验中,试样最大承受荷载为4kn,在熔核附近出现韧性断裂。车厢剥离试验的失效模式为扣拔式。显微硬度测试的最大硬度为312.8 HV,分别比AISI 347和AISI 2205基体硬度值高78.74%和7.1%。在所有试验中,试样均在拉出破坏模式下破坏,因此在所有试样布置和加载条件下,焊缝区都是完整的。
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引用次数: 1
Photocatalytic performance of Nd-TiO2 coatings: effect of voltage and frequency Nd-TiO2涂层的光催化性能:电压和频率的影响
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00063
Yuanji Shi, Y.Q. Dai, Junwan Li, Cheng Cheng, Jingxiao Li
The Nd-TiO2 micro-arc oxidation (MAO) coatings were formed in phosphate-based electrolyte with the addition of Nd2O3 using suitable voltage and frequency. SEM results revealed that the coatings were varied with different voltage and frequency. And composition analysis showed the Nd-TiO2 coatings are mainly composed of anatase and rutile phase. Meanwhile, the anatase content increased and then decreased. In addition, XPS results indicated that the Ti2p spin-orbit components of Nd-TiO2 coatings are shifted towards higher binding energy, suggesting that some of the Nd3+ ions are combined with TiO2 lattice and led dislocation. Furthermore, the photocatalytic experiment results showed that the photocatalytic activity of Nd-TiO2 coatings can be greatly enhanced with moderate amount of Nd3+. However, excessive amount of Nd3+ is not of an effective impact on the improvement of photocatalytic activity.
采用适当的电压和频率,在磷酸盐电解质中添加Nd2O3,制备了Nd-TiO2微弧氧化(MAO)涂层。扫描电镜结果表明,涂层随电压和频率的变化而变化。成分分析表明,Nd-TiO2涂层主要由锐钛矿相和金红石相组成。同时,锐钛矿含量先增加后减少。此外,XPS结果表明,Nd-TiO2涂层的Ti2p自旋轨道成分向更高的结合能移动,表明部分Nd3+离子与TiO2晶格和led位错结合。此外,光催化实验结果表明,适量的Nd3+可以大大提高Nd-TiO2涂层的光催化活性。然而,过量的Nd3+对光催化活性的提高没有有效影响。
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引用次数: 1
Characteristics of Abelmoschus Esculentus (Indian okra) fiber varieties 印度秋葵纤维品种的特性研究
IF 2.2 4区 材料科学 Q2 Physics and Astronomy Pub Date : 2023-06-01 DOI: 10.1680/jemmr.22.00230
Prafull P. Kolte, V. Shivankar
Okra fiber is the natural cellulosic bast fiber extracted from the bark of the Abelmoschus esculentus plant stem. India is the largest producer of okra for the cultivation of “okra fruit.” After harvesting the okra plant in the field, the okra fruit is collected as a vegetable, and the okra plant is thrown out as agricultural waste. In India, an estimated 4.5 million tons of green okra plants were discarded annually as agricultural waste. The okra plant has the potential to produce 150–160 kg of okra fibers per hectare and about 13.4 million kg of okra fibers annually. The okra plant is cultivated in two seasons: summer and winter. The summer variety (SV) and winter variety (WV) were extracted from okra plants cultivated in the summer and winter seasons, respectively. In this study, characteristics of the summer and winter varieties of okra fibers (morphological, thermal, and structural) are investigated by optical and electron microscopy (SEM), thermogravimetric analysis (TGA, DTG, DSC), X-ray diffraction analysis (XRD), and Fourier transform infrared spectrometry (FTIR). This study analyzed the characteristics of both varieties of okra fiber, compared them, and proved their potential for commercial applications like banana, jute, flax, hemp, and kenaf bast fibers.
秋葵纤维是从秋葵茎的树皮中提取的天然纤维素韧皮纤维。印度是种植“秋葵果”的最大秋葵生产国。在田里收割秋葵植物后,秋葵果被作为蔬菜收集起来,秋葵植物被当作农业废弃物扔掉。在印度,估计每年有450万吨绿色秋葵植物作为农业废物被丢弃。秋葵植物有潜力生产150–160株 每公顷约1340万公斤的秋葵纤维。秋葵有两个季节:夏天和冬天。夏品种(SV)和冬品种(WV)分别从夏冬季栽培的秋葵植物中提取。本研究采用光学和电子显微镜(SEM)、热重分析(TGA、DTG、DSC)、X射线衍射分析(XRD)和傅里叶变换红外光谱(FTIR)研究了夏、冬两季秋葵纤维的形态、热性能和结构特征。本研究分析了两种秋葵纤维的特性,并对其进行了比较,证明了其在香蕉、黄麻、亚麻、大麻和红麻韧皮纤维等方面的商业应用潜力。
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引用次数: 4
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Emerging Materials Research
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