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A STATE OF ART AND PROSPECTS OF USED PNEUMATIC TIRES MANAGEMENT (REVIEW) 废旧充气轮胎管理现状与展望(综述)
Pub Date : 2021-09-20 DOI: 10.33070/etars.3.2021.06
I. Mikulionok
The basic data on the volume of production of pneumatic tires in the world and in Ukraine are presented. The need to improve the ways of handling pneumatic tires that have lost their con-sumer properties (worn out tires as a result of their intended use and tires rejected as a result of passing quality control during their manufacture) is shown as one of the most dangerous for the environment and promising in terms of using their properties. A detailed classification of methods for handling worn out and defective tires is proposed and a critical analysis of each of them is given. Particular attention is paid to the methods of utilization of tires, in particular, recycling, which makes it possible to efficiently use the secondary raw materials obtained from tires directly for their intended purpose. The features of physical, physicochemical and chemical processing methods, in particular combustion, gasification, pyrolysis of tires and their frag-ments, as well as the prospects for their decomposition under the influence of environmental factors, in particular microorganisms, are also considered. The main ways of solving the prob-lem of tires that have lost their consumer properties in Ukraine are proposed. Bibl. 88, Fig. 2.
介绍了世界和乌克兰充气轮胎产量的基本数据。由于充气轮胎已经失去了其消费特性(由于其预期用途而磨损的轮胎和由于在制造过程中通过质量控制而被拒绝的轮胎),因此需要改进处理充气轮胎的方法,这是对环境最危险的轮胎之一,并且在使用其特性方面很有希望。提出了处理磨损和缺陷轮胎的方法的详细分类,并对每一种方法进行了批判性的分析。特别注意轮胎的利用方法,特别是回收,这使得有可能有效地利用从轮胎中直接获得的二次原材料用于其预定目的。还讨论了轮胎及其碎片的物理、物理化学和化学处理方法的特点,特别是燃烧、气化、热解的特点,以及在环境因素,特别是微生物的影响下轮胎及其碎片分解的前景。提出了解决乌克兰轮胎失去消费属性问题的主要途径。圣经第八十八章,图二。
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引用次数: 2
ACETOLYSIS OF TECHNICAL OILS AS A BASIS FOR THEIR COMPLEX PROCESSING INTO ALTERNATIVE ONESBIOPRODUCTS OF THE FUEL AND LUBRICANTS INDUSTRY: AN INNOVATIVE METHOD AND TECHNOLOGY 技术油的丙酮解作为其复杂加工成替代燃料和润滑油工业生物产品的基础:一种创新的方法和技术
Pub Date : 2021-09-20 DOI: 10.33070/etars.3.2021.04
V. Kyrychenko, V. Kyrychenko, V. Nezdorovin
The material of the article reflects the results of the next stage of the systematic study of a very important problem in finding effective methods for processing chemical (T) oils into alternative functionally high quality and high biodegradability bioproducts of the fuel and lubricants (PM) materials. The main object of experimental research is the method of acetolysis of oils as one of the practically unexplored methods in comparison with well-developed methods of alcoholysis and esterolysis of T-oils. Based on the considered mechanism of catalytic and reversible reaction of acetolysis of oils as specific preacylation of their triacetylglycerol molecules, chemical-technological bases of processes of acetolysis of oils of two types are developed, namely: basic – rapeseed (g) and composition on its basis with 20 %, castor oil the so-called "ripritsol-20" (years). The optimal technological parameters for achieving high efficiency of acetolysis processes to obtain high-quality intermediates - mixtures of the corresponding FFAs of the general formulas RрC(O)–OH or RррC(O)–OH have been established. The necessity of combining the process of acetolysis of oils (p) or (pp) as the basis of the first stage of processing technology with the next stage, namely the conversion of VJ acids into more active in the reactions of the next stage derivatives - acid chlorides, and by a known, simple and fast method almost quantitative yield of intermediate products - mixtures of HlAn-VZhK (r) or (rr). The conceptual idea of the complex technology indicates the directions of rational processing of mixtures of VZ acids and their anhydrides (mixtures of HlAn-VZhK) into biocomponents of a wide range of purposes. In the second stage of the complex process, it is proposed to process Hlan-IJK mixtures into main bioproducts - biofuels or basic bio-oils by the well-known technologically and perfect Schotten-Bauman method, which is based on the acylation reaction of alcohols of the appropriate structure with chlorides of a certain type. or HlAn-VZhK (pp). Emphasis is placed on the rather favorable course of the acylation reaction of alcohols by the chosen method, in particular on its irreversibility, high speed under standard conditions, under such conditions high technical and economic efficiency of the second stage technology of the complex process is provided. It is shown that the technological operations of the complex process can be modified, directing them to the production of certain bioproducts, such as biofuels or biooils on the basis of adapted selection of the necessary combinations of raw materials. Thus, new biofuels of ester structure are proposed to be obtained by acylation of methanol or ethanol with mixtures of VOR acid chlorides derived from ripol. While new basic biooils of diester structure are recommended to be obtained by acylation of glycolysis of industrial production (in particular ethylene glycol) with a mixture of HlAn-VZhK, derived from the composi
本文的材料反映了一个非常重要的问题的系统研究的下一阶段的结果,即寻找有效的方法将化学(T)油加工成可替代的功能性高质量和高生物降解性的燃料和润滑油(PM)材料的生物产品。实验研究的主要对象是油的醇解法,与成熟的醇解法和酯解法相比,醇解法是尚未开发的方法之一。在考虑了油的催化和可逆反应机理为其三乙酰甘油分子的特异性预酰化的基础上,开发了两类油的醇解工艺的化学工艺基础,即:碱性菜籽油(g)和在其基础上与20%的蓖麻油组成所谓的“ripritsol-20”(年)。确定了实现高效乙酰水解工艺的最佳工艺参数,以获得高质量的中间体——由通式r平易c (O) - oh或r平易c (O) - oh的相应游离脂肪酸组成的混合物。有必要将油(p)或(pp)的乙酰解过程作为第一阶段加工技术的基础与下一阶段加工技术相结合,即将VJ酸转化为更活跃的下一阶段衍生物-酸性氯化物的反应,并通过一种已知的,简单和快速的方法几乎定量地产生中间产物- HlAn-VZhK (r)或(rr)的混合物。该复合技术的概念思想为合理处理VZ酸及其酸酐混合物(HlAn-VZhK混合物)成为广泛用途的生物组分指明了方向。在复杂工艺的第二阶段,建议采用众所周知的技术和完善的Schotten-Bauman方法将Hlan-IJK混合物加工成主要生物产品-生物燃料或基础生物油,该方法是基于适当结构的醇与某种类型的氯化物的酰化反应。或lan - vzhk (pp)。重点介绍了所选方法对醇类酰化反应的有利过程,特别是其不可逆性,在标准条件下反应速度快,在此条件下复杂工艺的第二阶段工艺具有较高的技术和经济效率。它表明,可以修改复杂过程的技术操作,将其导向某些生物产品的生产,如生物燃料或生物油,其基础是对原材料的必要组合进行适应性选择。因此,新的酯结构生物燃料被提议通过甲醇或乙醇与由ripol衍生的VOR酸氯化物混合物的酰化来获得。而新的二酯结构的碱性生物油则被推荐通过工业生产的糖酵解(特别是乙二醇)与由复合油ripritsol-20衍生的HlAn-VZhK混合物的酰化得到。所提供的表计算的物料平衡的每一个阶段的复杂过程,其技术和经济效率和环境安全的特点。确定了研究过程中获得的产品实验样品的主要功能特性和一些操作指标:生物燃料和基础生物油,以及以最好的矿物和生物产品为基础的复合产品,特别是生物柴油和汽车微型生物油。对其特性的分析表明,它们在质量的功能指标上并不逊于pm材料分支中最好的传统材料。圣经12,表5。
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引用次数: 1
INCREASING THE EFFICIENCY OF THE SYSTEMS OF COMPRESSOR-PUMPING AND REFRIGERATION UNITS SUPPLYING LIQUID CO2 AND NH3 TO THE UNIT FOR CARBAMIDE SYNTHESIS 提高压缩机泵送系统和制冷装置的效率,为尿素合成装置提供液态co2和nh3
Pub Date : 2021-09-20 DOI: 10.33070/etars.3.2021.02
G. K. Lavrenchenko, B. Hrudka
Carbon dioxide is used in large volumes to produce urea, a highly efficient nitrogen fertilizer. It is compressed in a multistage compressor to a pressure of 15 MPa and fed to the urea synthesis unit. The specific energy consumption for the compression of carbon dioxide by a compressor reaches 0.16 kWh/kg. It may be more profitable to use in the system of compressor-pumping and refrigeration units. They can be used to liquefy carbon dioxide and compress it to pressure 15 MPa before feeding it to the synthesis of urea. In the simplest scheme, an ammonia compression refrigeration machine (ACRM) is included in the system to improve efficiency. The specific energy consumption in such a system for the liquefaction and compression of CO2 is 0.118 kWh/kg. In case of replacement of the ACRM with an absorption refrigeration machine, unit costs can be reduced to 0.09 kWh/kg. These two systems can be used to increase urea production or to ensure stable operation of the units during the summer period of their operation. The analysis showed that further improvement of the technological scheme of the entire system will completely abandon the use of the compressor method of compression of CO2 to pressure 15 MPa before its supply to the urea synthesis unit. To do this, you need to include an additional absorption lithium bromide refrigeration machine in the system. In this scheme, the compressor-pumping unit will provide the simultaneous supply of liquid carbon dioxide and ammonia for the synthesis of urea with a pressure of 15 MPa. To increase the daily production of urea from 1400 to 2000 tons, it is necessary to increase the feed liquid CO2 in the amount of 62 t/hour and liquid NH3 — 47.5 t/hour. Bibl. 14, Fig. 3.
二氧化碳被大量用于生产尿素,这是一种高效的氮肥。在多级压缩机中压缩至15mpa压力,送入尿素合成装置。压缩机压缩二氧化碳的比能耗为0.16 kWh/kg。在压缩机泵送和制冷机组的系统中使用可能更有利可图。它们可以用来液化二氧化碳并将其压缩到15 MPa的压力,然后再将其用于尿素的合成。在最简单的方案中,系统中加入氨压缩制冷机(ACRM)以提高效率。该系统用于液化和压缩CO2的比能耗为0.118 kWh/kg。若将ACRM更换为吸收式制冷机,单位成本可降至0.09 kWh/kg。这两种系统可用于提高尿素产量或确保装置在夏季运行期间的稳定运行。分析表明,进一步改进整个系统的工艺方案,将彻底放弃采用将CO2压缩至15 MPa压力后再供给尿素合成装置的压缩机方法。要做到这一点,你需要在系统中包括一个额外的吸收式溴化锂制冷机。在本方案中,压缩机-抽油机将同时为尿素合成提供压力为15 MPa的液态二氧化碳和氨。尿素日产量由1400吨提高到2000吨,需增加进料液CO2 62 t/h,液NH3 - 47.5 t/h。圣经14,图3
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引用次数: 1
INVESTIGATION OF THE PROCESSES OF THERMAL DESTRUCTION OF CELLULOSE-CONTAINING (PAPER) WASTE 含纤维素(纸)废料热破坏工艺的研究
Pub Date : 2021-09-20 DOI: 10.33070/etars.3.2021.05
O. Sezonenko, O. Vasechko, V. Aleksyeyenko, A. V. Snihur
Materials of practical research work on thermal destruction of paper waste were presented. The main task was The comprehensive study of the aspects of carbon formation on the basis of analytical studies was considered, as well as using a specially built laboratory installation — a waste graphitizer. Research has been carried out on the effectivity of application of pyrolysis gases of the process as fuel to maintain the temperatures of the thermal destruction reaction. Practical examples have proved the possibility and expediency of using the solid residue of the reaction as a component in various fields of production. Bibl. 10, Fig. 1, Tab. 3.
介绍了废纸热破坏的实际研究工作资料。主要任务是在分析研究的基础上对碳形成的各个方面进行综合研究,并使用专门建造的实验室装置-废石墨化剂。对该工艺热解气体作为燃料维持热破坏反应温度的有效性进行了研究。实例证明了将该反应的固体残渣作为一种组分应用于各个生产领域的可能性和方便性。圣经10,图1,表3。
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引用次数: 0
TECHNOLOGICAL COMPLEX FOR PROCESSING OF SOLID HOUSEHOLD AND TREATMENT FACILITIES WASTE WITH BIOGAS OBTAINING 固体生活垃圾及处理设施垃圾沼气处理技术综合体
Pub Date : 2021-06-20 DOI: 10.33070/etars.2.2021.06
O. Seryogin, O. Vasylenko, F. Riedel, H. Aigner
A concept has been developed for processing of biologically active sludge from municipal wastewater treatment plants in combination with the organic fraction of municipal solid waste using the BioTech Process. The complex, which makes it possible to implement the proposed concept, does not require additional land plots, and classified secondary raw materials, biogas and high-quality biofertilizers suitable for use in the agricultural industry are the products of its activity. The proposed concept will allow solving several problems at once due to the construction of a waste recycling plant on the territory of the filtration zone of the existing water treatment facilities. The new processing plant will be used not only for processing and sorting of solid waste, but also for treating sludge from wastewater treatment plants, together with organic waste obtained from solid waste in the BioTech Process to obtain biogas and biofertilizers, the so-called compost. The new recycling plant will be environmentally friendly and, among other benefits, will be able to process of municipal solid waste with preliminary sorting and separation of recyclable materials. Bibl. 9, Fig. 1.
已经开发了一种概念,将城市污水处理厂的生物活性污泥与城市固体废物的有机部分结合使用生物技术工艺进行处理。该综合体使实施提议的概念成为可能,不需要额外的土地地块,其活动的产物是分类的二级原料、沼气和适合农业工业使用的高质量生物肥料。拟议的概念将能够同时解决由于在现有水处理设施的过滤区建设废物回收厂而产生的几个问题。新的处理厂不仅将用于处理和分类固体废物,还将用于处理废水处理厂的污泥,以及生物技术过程中从固体废物中获得的有机废物,以获得沼气和生物肥料,即所谓的堆肥。新的回收厂将对环境友好,除其他好处外,将能够处理城市固体废物,对可回收材料进行初步分类和分离。圣经第九章,图一
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引用次数: 1
DEVELOPMENT OF CONCEPTUAL TECHNICAL SOLUTIONS AND METHODS OF THEIR IMPLEMENTATION DURING THE DESIGN OF A DUST COAL STEAM GENERATOR OF SUPER-SUPER CRITICAL PARAMETERS OF STEAM 28 MPA / 600 °C/600 °C FOR 300 MW ENERGY UNIT. PART 3. 在300mw发电机组超超临界参数28mpa /600℃/600℃的尘煤蒸汽发生器设计过程中,提出了概念性技术方案及其实施方法。第3部分。
Pub Date : 2021-06-20 DOI: 10.33070/etars.2.2021.01
B. Rokhman, N. Dunayevska, V. Vifatnyuk
In the third part of this article, an attempt is made to expand the range of regulation of the steam generator load from 40% to 100% by injecting recirculating flue gases taken after the water economizer into the middle radiation part of the furnace. For this, verification thermal calculations of the boiler were carried out when burning ДГ-100 coal in a wide range of variation of the recirculation coefficient Krec = 10−20% at loads of 40% and 50% of the nominal. It is shown that: a) at a load of 50%, recirculation of flue gases Krec = 13 % leads to a drop in the steam temperature along the primary path, due to which the maximum wall temperatures of all-welded screens decrease, which makes it possible to reduce the cost of boiler manufacture by reducing the use of expensive austenitic steels by 116.3 t; b) to ensure a live steam temperature of 600 °С at a load of 40%, it is necessary that Krec = 12%. This leads to a rise in the cost of the boiler in comparison with the load of 50% due to the use of steel grade 10X16N16V2MBR in the manufacture of ceiling screens. Bibl. 3, Fig. 17, Tab. 4.
在本文的第三部分,尝试将省水器后的循环烟气注入炉膛的中辐射部分,将蒸汽发生器负荷调节范围从40%扩大到100%。为此,在40%和50%的标称负荷下,在循环系数Krec = 10−20%的大范围变化范围内,锅炉在燃烧ДГ-100煤时进行了验证热计算。结果表明:a)在负荷为50%时,烟气再循环率为Krec = 13%,导致主路径蒸汽温度下降,从而使全焊筛的最大壁温降低,从而可以通过减少使用昂贵的奥氏体钢来降低锅炉制造成本116.3 t;b)为保证在40%负荷下的活汽温为600°С,必须使Krec = 12%。由于在制造吊顶屏风时使用了10X16N16V2MBR钢级,这导致锅炉的成本与负荷相比增加了50%。圣经3,图17,表4。
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引用次数: 0
THE CURRENT STATE OF THE ISSUE OF PERSISTENT ORGANIC POLLUTANTS IN UKRAINE AND APPROACHES FOR ITS RESOLUTION 乌克兰持久性有机污染物问题的现状及其解决办法
Pub Date : 2021-06-20 DOI: 10.33070/etars.2.2021.07
V. Chetverykov, I. Holoubek, K. Pianykh
Persistent organic pollutants (POPs) relate to a group of toxicants, which is separated due to an extremely hazardous impact on human health and is regulated by a special international agreement — the Stockholm Convention on POPs. Each Party of the Convention should develop and consistently renew the National Implementation Plan to implement requirements under this Convention. Ukraine developed the National Implementation Plan in 2007, and the experts started works on its renewal in 2020. The article contains results of expert analysis of changes in volumes and forms of accumulation of waste, consisting of containing or contaminated with POPs, in particular, unusable and prohibited plant protection chemicals (PPC). There are outcomes of expert analysis of changes in use of electrical equipment that contained synthetic dielectric liquids based on polychlorinated biphenyls (PCBs). Based on analysis, activities are proposed to the National Implementation Plan for development of effective infrastructure for thermal destruction of POP-containing waste. In addition to storage sites of POPs-containing waste, so-called “nintentional production” is an essential source of POPs entering environment. For categories of sources that under the Stockholm Convention can potentially polluted environment with POPs volumes of annual emission into the air, water, and soil for six basic pollutants have been calculated. Modern extensive monitoring system for POPs should be established to clear up a real state with environmental pollution by POPs in the country. Results of such monitoring together with strong regulatory support may motivate enterprises to an introduction of “best available techniques”. Bibl. 7, Tab. 3.
持久性有机污染物(POPs)是指一组有毒物质,由于对人类健康产生极其危险的影响而被分离出来,并受到一项特别国际协定——《关于持久性有机污染物的斯德哥尔摩公约》的管制。《公约》每一缔约方应制定并不断更新《国家执行计划》,以执行本《公约》的要求。乌克兰于2007年制定了国家实施计划,专家们于2020年开始了更新计划的工作。该条款载有专家对含有持久性有机污染物或受其污染的废物,特别是不可使用和禁用的植物保护化学品(PPC)的废物堆积量和形式变化的分析结果。专家分析了含有基于多氯联苯(pcb)的合成介电液体的电气设备使用变化的结果。根据分析,向国家执行计划提出了发展有效的基础设施以热销毁含持久性有机污染物废物的活动。除了储存含持久性有机污染物废物的场所外,所谓的“无意生产”也是持久性有机污染物进入环境的一个重要来源。对于根据《斯德哥尔摩公约》可能以持久性有机污染物污染环境的各种来源,已经计算了六种基本污染物每年向空气、水和土壤排放的量。应建立现代广泛的持久性有机污染物监测体系,梳理我国持久性有机污染物污染环境的真实状况。这种监测的结果加上强有力的管理支持可能促使企业采用“现有的最佳技术”。圣经7,表3。
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引用次数: 1
GEOINFORMATION ASPECTS OF DISTRICT HEATING MODERNIZATION 区域供热现代化的地理信息方面
Pub Date : 2021-06-20 DOI: 10.33070/etars.2.2021.04
Y. Nikitin, I.S. Komkov
The article considers the tools and methods of analysis cities district heating modernization, using modern geographic information systems. The characteristics of district heating and the issues that arise given the need for their modernization are listed. Geographic information systems briefly divided into types in terms of their application to the tasks. The most promising areas of further research in the direction of integration of geographic information systems in the field of district heating are identified. Bibl. 11, Fig. 4, Table 1.
本文探讨了利用现代地理信息系统分析城市区域供热现代化的工具和方法。列出了区域供热的特点以及由于其现代化需要而产生的问题。地理信息系统按其在任务中的应用简要地分为几种类型。确定了区域供热领域地理信息系统集成方向上最有前途的进一步研究领域。圣经11,图4,表1。
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引用次数: 1
CRYOGENIC ACCUMULATION OF ELECTRICITY GENERATED USING RENEWABLE ENERGY SOURCES 利用可再生能源产生的电力的低温积累
Pub Date : 2021-06-20 DOI: 10.33070/etars.2.2021.02
V. Braverman, B. Ilienko
Possibilities and prospects of accumulation of the electric power generated on objects of renewable energy sources - solar and wind power plants, with use of cryogenic liquids are considered. A comparison of the three most common ways of accumulating electricity: using lithium-ion batteries, hydrogen, liquid air. According to the proposed technology, the efficiency of recovery of electricity from liquid air is from 54 to 70%. The developed technology is based on cryogenic and thermal accumulation and has a high accumulation coefficient. It is shown that energy storage in cryogenic storage devices is the cheapest today. The proposed technology can also be used to generate electricity from liquefied natural gas using standard equipment developed by industry. The technological scheme of the cryoaccumulating station is offered. Bibl. 10, Fig. 1, Table 1.
考虑了利用低温液体积累可再生能源-太阳能和风力发电厂产生的电力的可能性和前景。三种最常见的蓄电方式的比较:使用锂离子电池,氢气,液态空气。根据所提出的技术,从液态空气中回收电的效率为54% ~ 70%。该技术以低温和热富集为基础,具有较高的富集系数。研究表明,低温储存装置中的能量储存是目前最便宜的。该技术还可用于利用工业开发的标准设备从液化天然气中发电。提出了低温蓄冷站的工艺方案。圣经10,图1,表1。
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引用次数: 2
A STATE OF ART AND PROSPECTS OF PLASTIC SOLID WASTE MANAGEMENT 塑料固体废物管理的现状与展望
Pub Date : 2021-06-20 DOI: 10.33070/etars.2.2021.05
I. Mikulionok
Basic data on the volume and structure of solid waste in the world and Ukraine are presented. The need to improve the ways of handling plastic solid waste as one of the most dangerous for the environment and promising from the point of view of using their properties is shown. A detailed classification of methods for handling plastic solid waste is proposed and a critical analysis of each of them is given. Particular attention is paid to the methods of disposal of plastic solid waste, in particular, recycling, which makes it possible to effectively use secondary plastic raw materials directly for their intended purpose. The features of physical, chemical, biological and combined processing methods are also considered, in particular combustion, gasification, pyrolysis, plasma decomposition of plastic solid waste, as well as their decomposition under the influence of sunlight and microorganisms. The main ways of solving the problem of plastic solid waste in Ukraine are proposed. Bibl. 83, Fig. 3, Tab. 3.
介绍了世界和乌克兰固体废物的体积和结构的基本数据。塑料固体废物是对环境最危险的废物之一,从利用其特性的角度来看,有必要改进处理塑料固体废物的方法。提出了塑料固体废物处理方法的详细分类,并对每一种方法进行了批判性分析。特别注意塑料固体废物的处理方法,特别是回收利用,这使得有可能有效地将二次塑料原料直接用于其预定用途。还考虑了物理、化学、生物和组合处理方法的特点,特别是塑料固体废物的燃烧、气化、热解、等离子体分解,以及它们在阳光和微生物影响下的分解。提出了解决乌克兰固体塑料垃圾问题的主要途径。圣经83,图3,表3。
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引用次数: 2
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