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EXPERIENCE OF DEVELOPMENT, IMPLEMENTATION AND MODERNIZATION OF HOT WATER SUPPLY BOILERS WITH DUAL-SCREENS AND THE SLOT BOTTOM BURNERS 双屏槽底燃烧器热水锅炉研制、实施及现代化的经验
Pub Date : 2019-09-20 DOI: 10.33070/ETARS.3.2019.02
E. M. Lavrentsov, I. Sigal, A. Smikhula, E. P. Dombrowska, O. S. Kernazhytska, O. Marasin
The increases service life of gas hot water supply boilers with uniform heat supply along of the depth (width) of the combustion chamber for more than 40 years, by using of slot bottom burners was shown. While reducing nitrogen oxide emissions by using of dual-screens its can significantly increase the heat stress of the furnace, the volume of the furnace chamber and the temperature of the flue gases had left unchanged. The boilers with a capacity of 1–10 MW, with the above technical design solutions of the Gas Institute of the NAS of Ukraine, with a total heat capacity of more than 60 GW, continue to be operated and produce in Ukraine and the CIS countries. Installed boilers relatively nitrogen oxide emissions comply with new EU directive (EU) 2015/2193. The using of gas slot bottom burners can reduce nitrogen oxide emissions by approximately 15 % compared to the basic factory vortex types GMG or GMGB installed on many boilers was shown. A project for the reconstruction of boilers TVG-8 (TVG-8M) and KVG-7.56 with an increase in convective surface area by replacing the factory pipe 28x3 mm with 32x3 mm had developed. Using the improved slot bottom burners in particular equipped with calibrated nozzles for precise dosing of natural gas into the air was envisaged. As a result of a research test of the reconstructed boilers for 3-5 years these technical solutions could increase the energy efficiency of existing TVG and KVG boilers up to the current European level —94–95 at rated heat output was shown. Ref.18, Fig.4, Tab. 5.
采用槽底燃烧器,使沿燃烧室深度(宽度)均匀供热的燃气热水锅炉使用寿命延长了40多年。采用双筛网减少氮氧化物排放,可显著增加炉膛热应力,但炉膛容积和烟气温度不变。采用上述乌克兰国家燃气研究所技术设计方案,总热容量超过60gw的1 - 10mw锅炉继续在乌克兰和独联体国家运行和生产。安装的锅炉相对氮氧化物排放符合欧盟新指令(EU) 2015/2193。与安装在许多锅炉上的基本工厂涡旋型GMG或GMGB相比,使用燃气槽底燃烧器可以减少约15%的氮氧化物排放。开展了对锅炉TVG-8 (TVG-8M)和KVG-7.56进行改造,将工厂28x3 mm管改为32x3 mm管,增加对流表面积的项目。设想使用改进的槽底燃烧器,特别是配备校准喷嘴的燃烧器,以精确地向空气中添加天然气。通过对改造后的锅炉进行3-5年的研究测试,这些技术解决方案可以将现有的TVG和KVG锅炉的能源效率提高到目前的欧洲标准-94-95。参考文献18,图4,表5。
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引用次数: 2
EXPERIENCE OF THE DEVELOPMENT OF BURNERS, CHAMBERS, AND TECHNOLOGIES FOR REDUCING EMISSIONS OF NITROGEN OXIDES BY BOILERS DURING THE COMBUSTION OF NATURAL GAS 开发燃烧器、燃烧室和减少天然气燃烧过程中锅炉氮氧化物排放的技术的经验
Pub Date : 2019-09-20 DOI: 10.33070/ETARS.3.2019.07
I. Sigal, A. Smikhula, O. Sigal
In the article discusses the features of constructive solutions accepted in the burner devices and chambers of boiler units, which were used both when converting solid fuel boilers to natural gas, and creating new designs of gas boiler units. The works to reduce nitrogen oxide emissions at the Gas Institute of the National Academy of Sciences of Ukraine began in the 1960s and by 1971 significant results had been achieved was shown. The main methods and technical solutions that are used to reduce emissions of nitrogen oxides during the combustion of natural gas in boilers of various capacities, including 300 MW power units, are considered. The principal design of a two-stage burner, which are operated in an amount of more than 2000 units in Ukraine and the CIS countries is presented. The installed two-stage burner devices for combustion of natural gas require immediate reconstruction with bringing their indicators to the calculated ones at the first stage. The modernization of the exist ing two-stage burners is possible to achieve the readings of the EU emissions directive 2010/75/EU was shown. The most promising technologies for further reducing the level of nitrogen oxide emissions less than 100 mg/Nm3 (3% O2, dry gases) when burning natural gas were shown. Bibl. 38, Fig.4, Tab. 1.
本文讨论了固体燃料锅炉改气和燃气锅炉机组新设计中所采用的锅炉燃烧器装置和燃烧室建设性解决方案的特点。乌克兰国家科学院天然气研究所减少氮氧化物排放的工作始于1960年代,到1971年已取得显著成果。考虑了包括300mw机组在内的不同容量的锅炉在天然气燃烧过程中减少氮氧化物排放的主要方法和技术解决方案。介绍了一种两级燃烧器的主要设计,该燃烧器在乌克兰和独联体国家的运行量超过2000台。已安装的天然气两级燃烧装置需要立即改造,使其指标达到第一级计算值。现有两级燃烧器的现代化有可能达到欧盟排放指令2010/75/EU的读数。展示了在燃烧天然气时进一步降低氮氧化物排放水平(低于100 mg/Nm3 (3% O2,干气体))的最有前途的技术。圣经38,图4,表1。
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引用次数: 3
PLASMA-CHEMICAL PROCESS CONTROL OF WATER PURIFICATION FROM PERSISTENT ORGANIC POLLUTION 等离子体化学过程控制对持久性有机污染的水净化
Pub Date : 2019-09-20 DOI: 10.33070/ETARS.3.2019.06
S. V. Petrov, S. Bondarenko, A. Pastushenko, K. Vovnenko
The urgency of work is connected with the need to find alternative methods of water purification from persistent organic pollutants, which will satisfy the level of quality of treated water and will meet modern environmental requirements and sanitary norms of sewage quality and electrical energy. The efficiency of the method of electrodischarge water purification from persistent organic pollutants has been experimentally determined. The SCADA-system, which provides data processing and management of water treatment processes from persistent organic pollutants, is developed. Digitizing oscillograms using the Origin Pro environment. The values of power, energy consumption for water purification from phenol are determined. Determine the efficiency of the plant to clean water from persistent organic pollutants. To visualize and control the process of water purification, a technological scheme was built in the environment of Trace Mode 6. Bibl. 13, Fig. 10. Tab. 3.
这项工作的紧迫性与需要找到从持久性有机污染物中净化水的替代方法有关,这些方法将满足处理过的水的质量水平,并将满足现代环境要求和污水质量和电能的卫生标准。实验验证了电放法净化持久性有机污染物的效率。开发了scada系统,为持久性有机污染物的水处理过程提供数据处理和管理。使用Origin Pro环境数字化示波器。确定了用苯酚净化水的功率、能耗值。确定工厂清除持久性有机污染物的效率。为了可视化和控制水的净化过程,在Trace Mode 6环境下建立了一个技术方案。圣经13,图10选项卡。3。
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引用次数: 0
DEVELOPMENT OF THERMAL TECHNOLOGY FOR DISPERSED MATERIALS PROCESSING 分散材料加工热技术的发展
Pub Date : 2019-09-20 DOI: 10.33070/ETARS.3.2019.05
K. Kostohryz, Yu.I. Hvastuhin, V. Orlyk, V. Sobchenko, O. Maksymuk
The article contains information on the work of the department of thermal heterogeneous processes of the Institute of Gas of the NAS of Ukraine over the past ten years, devoted to the development of scientific and technological foundations for the thermal treatment of dispersed materials. The problem of the efficient use of natural resources in connection with the reduction of fossil energy resources while increasing their demand to meet the growing needs of production is discussed. The results of mathematical modeling of the heat treatment of dispersed materials are presented — a detailed study of the co-combustion of wood particles with natural gas is carried out taking into account the main stages of the process, a methodology for the qualitative and quantitative analysis of the process of dioxin formation during high-temperature processing of chlorine-containing waste is described. The possibilities of using carbonate sorbents for trapping sulfur compounds are evaluated. A detailed mathematical description of the endothermic process of calcining limestone particles during its passage through the high-temperature zone of the heated inert particles of the fluidized bed is carried out. The technology of three-stage processing of material in fluidized-bed apparatuses and the design of a reverting furnace combined with a recuperator, which is an element of energy conservation, have been developed. Created and implemented technologies in production of heat-insulating materials from hydrosilicates, perlite, mineral wool products. Schemes, dependencies of technological parameters, technical characteristics and general view of the implemented developments are given. Ref. 27, Fig. 10, Tab. 2.
这篇文章包含了乌克兰国家科学院天然气研究所热异构过程部门在过去十年中的工作信息,致力于发展分散材料热处理的科学和技术基础。讨论了在减少矿物能源的同时增加对矿物能源的需求以满足日益增长的生产需要的情况下有效利用自然资源的问题。本文介绍了分散材料热处理数学模型的结果,详细研究了木材颗粒与天然气的共燃烧过程,考虑了该过程的主要阶段,描述了一种定性和定量分析含氯废物高温处理过程中二恶英形成过程的方法。评价了利用碳酸盐吸附剂捕获含硫化合物的可能性。对石灰石煅烧颗粒通过流化床加热惰性颗粒的高温区时的吸热过程进行了详细的数学描述。在流化床装置中发展了物料的三级处理技术,并设计了一种节能的还原炉与回热器相结合的装置。创建并实施了从氢硅酸盐,珍珠岩,矿棉产品中生产隔热材料的技术。给出了方案、技术参数的依赖关系、技术特性和实施发展的总体看法。参考文献27,图10,表2。
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引用次数: 0
TECHNOLOGICAL ASPECTS OF ENERGY USE OF SOLID HOUSEHOLD WASTE 固体家庭废物能源利用的技术方面
Pub Date : 2019-09-20 DOI: 10.33070/ETARS.3.2019.03
I. Karp, K. Pyanykh
Technological aspects of energy use of solid waste and their constituents and possibility of applying certain technologies in Ukraine are analyzed. Global trends in waste management technologies are identified. When organizing waste sorting, half of their energy potential can be used, which is estimated to be 1.5 billion m3 of natural gas equivalent in Ukraine. Share of food waste is close to 40 %. It is advisable to recycle them in biogas and biomethane mixtures with agricultural waste and energy plants. Biomethane production can be increased in several times. Electricity and heat production from biogas require government assistance in form of special tariffs. Biomethane is being used alongside natural gas in compressed and liquefied state as a motor fuel. Biogas complexes are used as balancing power of grids. The most common technology for utilizing the energy potential of municipal solid waste is incineration. Emissions systems for waste incineration plants have reached a level of perfection that allows them to be placed close to residential areas. Ref. 15, Fig. 6, Tab. 2.
分析了固体废物及其成分的能源利用的技术方面以及在乌克兰应用某些技术的可能性。确定了废物管理技术的全球趋势。在组织废物分类时,可以利用其一半的能源潜力,估计乌克兰的能源潜力为15亿立方米天然气当量。食物浪费的比例接近40%。建议将它们与农业废物和能源工厂混合在沼气和生物甲烷中回收利用。生物甲烷的产量可以增加几倍。利用沼气发电和供热需要政府以特殊关税的形式提供援助。生物甲烷与压缩液化的天然气一起被用作汽车燃料。沼气复合体被用作电网的平衡电源。利用城市固体废物能源潜力的最常用技术是焚烧。垃圾焚烧厂的排放系统已经达到了一个完美的水平,可以让它们靠近居民区。参考文献15,图6,表2。
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引用次数: 1
THE POTENTIALS OF THE CHEMICAL ELEMENTS OF GASEOUS MIXTURE IN THE THERMODYNAMICAL CONTEXT 气体混合物中化学元素的热力学势
Pub Date : 2019-09-20 DOI: 10.33070/ETARS.3.2019.04
V. Bezuglyi
It was found out that the partial atomic function of Gibbs of mixture may be considered in the chemical thermodynamics context as transfer characteristic of the chemical element of mixture. This characteristic was named in our previous works as «the potential of the mixture chemical element». It was shown that chemical elements potentials play a role of so-called «undefined Lagrange multipliers» in the system of equations for calculation of states equilibrium properties of gaseous mixture by certain values of temperature, pressure and chemical elements composition. Ref. 9.
在化学热力学的背景下,发现混合物的吉布斯部分原子函数可以看作是混合物中化学元素的传递特性。这个特性在我们之前的作品中被命名为“混合化学元素的潜力”。研究表明,化学元素势在用一定的温度、压力和化学元素组成计算气体混合物的状态、平衡性质的方程组中起着所谓的“未定义拉格朗日乘子”的作用。Ref。9。
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引用次数: 1
ELECTRO-CHEMICAL PRODUCTION OF TUNGSTEN OXIDE FROM PSEUDO-ALLOY CARBIDE TYPE WC-Co 用WC-Co型伪硬质合金电解生产氧化钨
Pub Date : 2019-06-20 DOI: 10.33070/ETARS.2.2019.06
G. Tulsky, L. Lyashok, M. P. Osmanova, A. Soboļeva
Widespread use of specialized tools, the component part of which is tungsten, leads to the accumulation of its secondary raw materials (worked tools, cutters, drills, etc.). That is why there is a need to create technologies for recycling of the demanded metals, in particular tungsten. The purpose of this work is to study the anode behavior of carbide pseudoalloy type WC-Co in solutions of nitric acid with the addition of fluoride acid to obtain, as a target product, higher tungsten oxide in one stage. The corrosion behavior of carbide type pseudoalloy in acid solutions has been studied, and it has been found that the highest oxidation rate occurs in a concentrated solution of nitric acid. In order to accelerate the process and to increase the yield on the substance, adding to the fluoride acid working electrolyte has been proposed. As a result of the researches, it has been found that the behavior of the dissolution of pseudoalloys of the carbide type is characterized by the properties of the main component — tungsten. An electrolyte for obtaining higher tungsten oxide in one stage has been proposed. Bibl. 10, Fig. 1, Tab. 1.
以钨为主要组成部分的专用刀具的广泛使用,导致其二次原料(刀具、刀具、钻头等)的积累。这就是为什么有必要创造回收所需金属,特别是钨的技术。本工作的目的是研究碳化合金型WC-Co在硝酸溶液中的阳极行为,并在硝酸溶液中加入氟化酸,以一步获得更高的氧化钨作为目标产物。研究了碳化物型假合金在酸性溶液中的腐蚀行为,发现在浓硝酸溶液中氧化速率最高。为了加快反应速度,提高该物质的收率,建议在氟酸工作电解质中加入。研究结果表明,碳化物型假合金的溶解行为以其主要成分钨的性质为特征。提出了一种一段制得高氧化钨的电解液。圣经10,图1,表1。
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引用次数: 0
THE COMPLEX APPROACH TO THE MODERNIZATION OF BOILERS, HEAT NETWORKS AND CONNECTED BUILDINGS 锅炉、热网和互联建筑现代化的复杂方法
Pub Date : 2019-06-20 DOI: 10.33070/ETARS.2.2019.03
Y. Nikitin, O. Dutka
The mathematical model that allows for a comparative analysis of the technical and economic characteristics of the three scenarios of the thermal modernization district heating system: the replacement of boilers, heat networks and pumps, the replacement of these elements in combination with thermal modernization of buildings, as well as a scenario that includes the implementation of all previous measures and the installation of Individual Heat Points in buildings (complex modernization). The advantages of the complex modernization on the horizon of planning for 50 years have been shown. Calculated analysis of the influence of various factors on the preference for this scenario has been carried out. The developed model can be used for the preparation of feasibility studies of projects energy efficient modernization of district heating systems and buildings. Bibl. 5, Fig. 8, Tab. 2.
该数学模型允许对热现代化区域供热系统的三种方案的技术和经济特征进行比较分析:锅炉,热网和泵的更换,与建筑物热现代化相结合的这些元素的更换,以及包括实施所有先前措施和在建筑物中安装单个热点的方案(复杂现代化)。在规划50年的地平线上,复杂现代化的优势已经显现出来。计算分析了各种因素对该方案偏好的影响。所开发的模型可用于编制区域供热系统和建筑物的节能现代化项目的可行性研究。圣经5,图8,表2。
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引用次数: 1
UTILIZATION OF SEWAGE SLUDGE 污水污泥的利用
Pub Date : 2019-06-20 DOI: 10.33070/ETARS.2.2019.05
I. Karp, K. Pyanykh, K. Pianykh
Sewage sludge utilization technologies must meet two requirements: the use of energy potential and ensuring that the products of their processing are not negatively affected by the environment. New technologies for the disposal of sediments that meet these requirements are being developed: pyrolysis, hydro pyrolysis, combined processes of fermentation and gasification, polygeneration, steam conversion, gasification of mixtures with other fuels, thermocatalytic reforming, three-stage gasification. Most of these technologies have not yet been commercialized. The energy potential of «fresh» sediments in Ukraine is estimated at 446 thousand tons of conditional fuel. Its use for the electricity production and thermal energy and secondary liquid and solid fuels is appropriate as being consistent with the global trend of decentralized energy development. The economically efficient, acceptable for Ukrainian conditions is the technology used to dispose of sediment, is their joint combustion with other solid fuels and waste in boilers of power stations and in cement kilns. For objects of decentralized energy, it should be preferred to the processes of gasification or pyrolysis of sewage sludge. Composting technology is acceptable to dispose of accumulated precipitates. Bibl. 27, Fig. 5, Tab. 3.
污水污泥利用技术必须满足两个要求:利用能源潜力和确保其处理的产品不受环境的负面影响。满足这些要求的沉积物处理新技术正在开发:热解、加氢热解、发酵和气化联合工艺、多联产、蒸汽转化、与其他燃料混合气化、热催化重整、三级气化。这些技术大多尚未商业化。乌克兰“新鲜”沉积物的能源潜力估计为44.6万吨有条件燃料。它用于发电和热能以及二次液体和固体燃料是适当的,因为它符合分散能源发展的全球趋势。在乌克兰的条件下,经济有效和可接受的是处理沉淀物的技术,是它们与其他固体燃料和废物在发电站的锅炉和水泥窑中联合燃烧。对于能源分散的对象,应优先采用污泥的气化或热解工艺。堆肥技术可用于处理积累的沉淀物。圣经27,图5,表3。
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引用次数: 1
DEEP OXIDATION OF METHANE OVER MULTICOMPONENT CoO BASED CATALYSTS ON CERAMIC MONOLITHS 陶瓷单体上多组分CoO基催化剂上甲烷的深度氧化
Pub Date : 2019-06-20 DOI: 10.33070/ETARS.2.2019.04
G. Kosmambetova, A. Trypolskyi, S. Soloviev, A. Kapran, P. Strizhak
Multicomponent CoO-CeO2(SrO)-Pd(Pt) catalysts on ceramic monoliths of a honeycomb structure (synthetic cordierite) were shown to be efficient for the deep oxidation of methane. Based on the results of the studying the effect of Al2O3 as a second carrier-substrate, the content of CoO, modifying/promoting additives of strontium and cerium oxides, palladium, platinum on catalyst activities, it was found that a 4,9%CoO-4,9%CeO2-0,1%Pd/cordierite specimen is optimal for use in catalytic heat generators. The catalyst of this composition, with increased mechanical strength, thermal resistance and resistance to carbonization, provides CO free oxidation of methane in the stoichiometric mixture with oxygen. Bibl. 33, Fig. 4.
在蜂窝结构的陶瓷块(合成堇青石)上制备了多组分CoO-CeO2(SrO)-Pd(Pt)催化剂,用于甲烷的深度氧化。通过对Al2O3作为第二载体-底物、CoO含量、锶、铈氧化物、钯、铂等改性/促进助剂对催化剂活性的影响的研究,发现4,9%CoO-4,9% ceo2 -0,1% pd /cordierite试样最适合用于催化制热装置。该组成的催化剂具有更高的机械强度、耐热性和抗碳化性,可使化学计量混合物中的甲烷与氧气无CO氧化。圣经33,图4。
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引用次数: 0
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