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Determination of Shale Types and their Volumes and Petrophysical Exponents for more Accurate Water Saturation Estimation for Raha Formation, Gulf of Suez, Egypt 确定页岩类型及其体积和岩石物理指数,以便更准确地估算埃及苏伊士湾拉哈地层的含水饱和度
Q1 Earth and Planetary Sciences Pub Date : 2024-04-07 DOI: 10.62593/2090-2468.1002
T. Shazly, Ahmed Z. Nouh, M. Z. El-sawy, M. El-Bay
This study depends on the analysis of well logging data for the Raha Formation, utilizing eight wells scattered in the Ras Budran Oil Field. It is situated in the northern region of the Gulf of Suez ' s Belayim Offshore Oil Field and is 4 km away from the Sinai coast. Water saturation is one of the steps through which the characterization of the reservoir and prediction of future accumulation are determined. Many parameters, such as types of shale, volumes of each type, and petrophysical exponents, are necessary to detect the accurate estimation of water saturation. First, Dia-Porosity crossplots are used to estimate three types of shale and their volumes (dispersed, laminated, and structural). From these plots, it was found that the dispersed shale exhibits the highest percentage in the middle of the study area, while the laminated shale volume increases toward the north directions, but the structural shales give the maximum value in the north-west trend. The presence of scattered shale in a formation is known to have a negative impact on the permeability of the rock, unlike the laminated shale, which decreases the total average of effective porosity. Comparable to laminated shale, structural shale has nearly identical characteristics. Second, the petrophysical exponents (cementation factor ( m ), saturation exponent ( n ), and tortuosity factor ( a ) were ascertained using Pickett ' s plot. It gave the values of m ranging from 1.8 to 2.3 and values of a varying from 0.72 to 1 in the studied wells, where these petrophysical exponents play a vital role for calculating the water saturation (Sw) in both clean and shaly rocks. This study aimed to determine the different types of shale and calculate the petrophysical exponents, which are important for a good estimation of the water saturation in rocks (clean and/or shaly) and for determining hydrocarbon saturation (Sh)
本研究利用分布在拉斯布德兰油田的八口油井,对拉哈地层的测井数据进行分析。该油田位于苏伊士湾贝拉伊姆海上油田北部地区,距离西奈海岸 4 公里。含水饱和度是确定储层特征和预测未来储量的步骤之一。许多参数,如页岩类型、每种类型的体积和岩石物理指数,都是准确估算含水饱和度的必要条件。首先,使用 Dia-Porosity 交叉图估算三种页岩类型及其体积(分散页岩、层状页岩和结构页岩)。从这些图中可以发现,分散页岩在研究区域的中部所占比例最高,层状页岩的体积向北增加,而结构页岩则在西北方向给出了最大值。众所周知,地层中分散页岩的存在会对岩石的渗透性产生负面影响,而层状页岩则不同,它会降低有效孔隙度的总平均值。与层状页岩相比,结构页岩具有几乎相同的特征。其次,利用皮克特曲线图确定了岩石物理指数(胶结系数(m)、饱和指数(n)和曲折系数(a))。在所研究的油井中,m 的值从 1.8 到 2.3 不等,a 的值从 0.72 到 1 不等,这些岩石物理指数对计算清洁岩石和页岩的含水饱和度(Sw)起着至关重要的作用。这项研究旨在确定不同类型的页岩并计算岩石物理指数,这对正确估算岩石(清洁和/或有页岩)中的含水饱和度以及确定碳氢化合物饱和度(Sh)非常重要。
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引用次数: 0
Different Baffle Gaps With Numerical Analysis of Multidesigned Shell-Tube-Heat Exchanger 不同挡板间隙与多列管壳式换热器的数值分析
Q1 Earth and Planetary Sciences Pub Date : 2024-04-07 DOI: 10.62593/2090-2468.1008
Mehmet Akif Kartal
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引用次数: 0
Heterogeneous nanocomposite catalysts supported on activated Egyptian clay for biofuel production from castor oil 以活性埃及粘土为支撑的异质纳米复合催化剂用于利用蓖麻油生产生物燃料
Q1 Earth and Planetary Sciences Pub Date : 2024-04-07 DOI: 10.62593/2090-2468.1012
N. Negm, M. A. Betiha, Nariman M.H. El-Wakeel, E. A. Mohammed
Egyptian clay named diatomite was obtained and acid-activated to prepare two heterogeneous catalysts to catalyze the conversion reaction of castor oil into biodiesel. The prepared catalysts were diatomite e copper and diatomite e copper/ aluminum-layered double hydroxide composites. The catalysts were characterized using FT-IR, radiography diffraction, and N 2 -adsorption/desorption measurements and used in the conversion reaction of castor oil into biodiesel under different conditions to determine their optimum performance for yielding the maximum yield. The diatomite e copper composite showed acceptable catalyzing performance, while the more alkaline diatomite e copper/aluminum-layered double hydroxide composite exhibited excellent catalyzing performance during the transesteri fi cation conversion of castor oil. Speci fi cations of the yielded biodiesels including viscosity at 40 (cid:1) C, density at 15 (cid:1) C, pour point, cloud point, cetane number, fl ash point, and sulfur content were in good agreement with the standard ASTM speci fi cations. The conversion mechanism has been discussed.
研究人员获得了名为硅藻土的埃及粘土,并通过酸活化制备了两种异相催化剂,用于催化蓖麻油转化为生物柴油的反应。制备的催化剂是硅藻土铜和硅藻土铜/铝层双氢氧化物复合材料。利用傅立叶变换红外光谱、射线衍射和 N 2 吸附/解吸测量对催化剂进行了表征,并在不同条件下将其用于蓖麻油转化为生物柴油的反应,以确定其最佳性能,从而获得最大产率。硅藻土-铜复合材料的催化性能尚可,而碱性较强的硅藻土-铜/铝层双氢氧化物复合材料在蓖麻油的阳离子转化过程中表现出优异的催化性能。生成的生物柴油的规格(包括 40 (cid:1) C 时的粘度、15 (cid:1) C 时的密度、倾点、浊点、十六烷值、灰分和硫含量)与标准 ASTM 规格非常一致。对其转换机制进行了讨论。
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引用次数: 0
Monitoring organic pollutants from aliphatic hydrocarbons in Soil Samples within the shoreline in Gulf of Suez, Egypt 监测埃及苏伊士湾海岸线土壤样本中脂肪族碳氢化合物的有机污染物
Q1 Earth and Planetary Sciences Pub Date : 2024-04-07 DOI: 10.62593/2090-2468.1005
Ahmed M. Rashad, M. B. Masod, Eman S. Abdullah, Sayed K. Attia
The principal goal of this research is to evaluate the current extent of anthropogenic contamination as a combination of both time and location in the shoreline in Suez Gulf. This oil re fi nery contamination was mostly the result of improper hydrocarbon disposal, which led to water leaks caused by equipment damage, vandalism, and accidents, which will ultimately pollute groundwater or release waste into the Gulf of Suez. Seven composite sediment samples were taken from a test plot. Total petroleum hydrocarbons were found in concentrations of 21.96, 23.58, 37.56, 54.48, 57.36, 33.96, and 23.04 g/kg, respectively. Hydrocarbons distribution were examined on a Hewlett-Packard (HP-7890 plus) gas chromatograph with a fl ame ionization detector. The resolved n-alkanes (R c ) were found to be 0.088, 0.087, 0.193, 0.091, 0.099, 0.123, and 0.177 m g/g. The results showed that the hydrocarbons are originated from terrestrial inputs. Several ratios of hydrocarbons indicated the predominance of petrogenic hydrocarbons. This was supported by high normalized aliphatic hydrocarbons concentrations; signi fi cant contributions of unresolved complex mixture; low n-alkane carbon preference index and even-to-odd carbon number predominance. Therefore, the chronic oil pollution in the area may be due to the large quantities of re fi ned products and the limited capabilities of water treatment units located in the studied areas.
这项研究的主要目的是评估苏伊士湾海岸线目前人为污染的程度,并将其与时间和地点相结合。这些油井污染主要是由于碳氢化合物处理不当,导致设备损坏、人为破坏和事故造成的水泄漏,最终污染地下水或将废物排放到苏伊士湾。从一个试验小区采集了 7 个复合沉积物样本。发现总石油碳氢化合物的浓度分别为 21.96、23.58、37.56、54.48、57.36、33.96 和 23.04 克/千克。碳氢化合物的分布情况由带有火焰离子化检测器的惠普(HP-7890 plus)气相色谱仪进行检测。正构烷烃的解析度(R c)分别为 0.088、0.087、0.193、0.091、0.099、0.123 和 0.177 m g/g。结果表明,碳氢化合物来自陆地输入。碳氢化合物的几种比率表明石油碳氢化合物占主导地位。高归一化脂肪族碳氢化合物浓度、未解决的复杂混合物的显著贡献、低正烷烃碳偏好指数和偶数至偶数碳数占优势都证明了这一点。因此,该地区的长期石油污染可能是由于大量的再生成物和所研究地区的水处理装置能力有限造成的。
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引用次数: 0
Modified polystyrene-chitosan composite as an electrolyte membrane: structure-property relationship 作为电解质膜的改性聚苯乙烯-壳聚糖复合材料:结构-性能关系
Q1 Earth and Planetary Sciences Pub Date : 2024-04-07 DOI: 10.62593/2090-2468.1013
Kholoud A. Afifi, M. A. Saied, N. A. Khaleq, Alaa Fahmy
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引用次数: 0
Petrophysical and Gas Chromatographic Analysis Integration for Hydrocarbon Identifications in Cretaceous Reservoirs, Azhar Field, Beni Suef Basin, Egypt 埃及贝尼苏埃夫盆地阿扎尔油田白垩系储层碳氢化合物鉴定的岩石物理和气相色谱综合分析
Q1 Earth and Planetary Sciences Pub Date : 2024-04-07 DOI: 10.62593/2090-2468.1018
Sherif Farouk, S. Saada, Mohamed S. Fagelnour, Mohamed Arafat
The petrophysical assessment of the Cretaceous succession from late Albian to Cenomanian (Upper Kharita, Bahariya formations, and Abu Roash ‘ G ’ Member) con fi rmed by gas chromatographic analysis utilizing well-log data and core data from the Azhar A-2 and Azhar E ¡ 1X wells located within the Beni Suef Basin, Western Desert of Egypt, was the aim of this work. The oil net pay zone of the Upper Bahariya Formation in the Azhar A-2 well is more effective and has a lower thickness than that of the Upper Bahariya Formation in the Azhar E ¡ 1X well. The gas chromatographic value analysis of the two wells (Azhar A-2 and Azhar E ¡ 1X) gives a good signature about the type of hydrocarbon content. The Abu Roash ‘ G ’ Member is characterized by the presence of oil in its lowermost part, and the C 1 /C 2 ratio also con fi rmed the presence of oil, which ranges from 3 to 7, where 40 greater than wetness ratio greater than 17.5, character ratio greater than or equal to 0.5 with balance ratio less than 17.5. In the upper part of A/R, ‘ G ’ Member is characterized by the presence of oil/heavy oil because the wetness ratio is greater than 40 and the character ratio is greater than or equal to 0.5 with the balance ratio less than 17.5 and the C 1 /C 2 ratio also con fi rmed the presence of oil/heavy oil that ranged from 2 to 5. The Upper Bahariya Formation is characterized by the presence of oil/heavy oil, where the wetness ratio is greater than 40, character ratio is greater than or equal to 0.5 with the balance ratio less than 17.5, and the C 1 /C 2 ratio also con fi rmed the presence of oil and heavy oil, which ranges from 2 to 7.7. The statistical analysis of the Upper Kharita Formation conventional core data indicated that the Upper Kharita Formation is characterized by fair-to-good porosity, fair permeability, and its gas chromatographic value analysis shows the presence of oil/heavy oil, where the wetness ratio greater than 40, character ratio greater than or equal to 0.5 with balance ratio less than 17.5, and C 1 /C 2 ratio also con fi rmed the presence of oil/heavy oil, which ranged from 1.5 to 7.
这项工作的目的是利用位于埃及西部沙漠贝尼苏伊夫盆地的 Azhar A-2 井和 Azhar E ¡ 1X 井的井记录数据和岩心数据,通过气相色谱分析,对白垩系晚期至新生代演替(上 Kharita 层、Bahariya 层和 Abu Roash ' G ' 成员)进行岩石物理评估。与 Azhar E ¡ 1X 井的上巴哈里亚地层相比,Azhar A-2 井的上巴哈里亚地层的石油净付层效果更好,厚度更小。两口井(Azhar A-2 井和 Azhar E¡ 1X 井)的气相色谱值分析很好地显示了碳氢化合物的类型。Abu Roash'G'成员的特征是其最下部存在石油,C 1 /C 2 比率也确定了石油的存在,其范围在 3 到 7 之间,其中 40 大于湿度比大于 17.5,特征比大于或等于 0.5,平衡比小于 17.5。在 A/R 的上部,"G "成员的特征是存在石油/重油,因为润湿比大于 40,特征比大于或等于 0.5,平衡比小于 17.5,C 1 /C 2 比值也表明存在石油/重油,其范围为 2 至 5。上巴哈利亚地层(Upper Bahariya Formation)的特点是存在石油/重油,其中润湿比大于 40,特征比大于或等于 0.5,平衡比小于 17.5,C 1 /C 2 比率也确定了石油和重油的存在,范围在 2 至 7.7 之间。对上哈里塔地层常规岩心数据的统计分析表明,上哈里塔地层的特点是孔隙度一般至良好,渗透率一般,其气相色谱值分析表明存在石油/重油,其中湿度比大于 40,特征比大于或等于 0.5,平衡比小于 17.5,C 1 /C 2 比值也表明存在石油/重油,其范围在 1.5 至 7 之间。
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引用次数: 0
Carrier Line Technique for Downhole Chemical Injection in Oil and Gas Industry; Case Study: El Hamra Oil Company 油气行业井下化学品注入的载体线技术;案例研究:哈姆拉石油公司
Q1 Earth and Planetary Sciences Pub Date : 2023-12-01 DOI: 10.1016/j.ejpe.2023.10.001
Ahmed Abdel Salam , Alaa Elshabasy , Mohammed Elzawawy

In oil production companies, corrosion is a common issue with various adverse economic and environmental consequences. Active well production fluid always comprises inherently corrosive and highly corrosive substances. There are a variety of treatment techniques to prohibit corrosion, such as chemical treatment, cathodic protection, and paint-based corrosion inhibitors. El Hamra Oil Company produces crude oil from three main locations. The research group noticed several downhole localized corrosion problems in the artificial lift system. This paper presents a case study to quantify the extra operation cost of periodically replacing the entire tubing string, renting the pulling unit, and production deferring. The research quantifies the economic impacts after corrosion inhibitor is injected downhole using the carrier line technique (CLT). The results show that the company saved more than 672 K $ during three years of using downhole chemical treatment; dramatically decreasing the regular corrosion incidents in three active wells. The actual profits are expected to increase exponentially for the following years, meanwhile reducing the environmental impacts to meet Egypt’s strategy towards sustainable goals in 2030.

在石油生产企业中,腐蚀是一个常见问题,会带来各种不利的经济和环境后果。活跃的油井生产流体总是包含固有的腐蚀性和高腐蚀性物质。有多种处理技术可以防止腐蚀,如化学处理、阴极保护和涂料缓蚀剂。El Hamra 石油公司从三个主要地点生产原油。研究小组注意到人工举升系统中存在若干井下局部腐蚀问题。本文通过一个案例研究,量化了定期更换整个油管串、租用拉拔装置和推迟生产所产生的额外运营成本。研究量化了使用载流线技术(CLT)向井下注入缓蚀剂后的经济影响。结果表明,在使用井下化学处理的三年中,该公司节省了超过 672 K 美元;大大减少了三口活跃井的定期腐蚀事故。预计未来几年的实际利润将成倍增长,同时减少对环境的影响,以实现埃及 2030 年的可持续发展战略目标。
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引用次数: 0
Environmentally friendly radiation EDTA modified hydrogel based on gelatin for adsorptive removal of cationic and anionic dye from synthetic wastewater 基于明胶的环境友好型辐射EDTA改性水凝胶吸附去除合成废水中的阳离子和阴离子染料
Q1 Earth and Planetary Sciences Pub Date : 2023-11-21 DOI: 10.1016/j.ejpe.2023.10.002
Asmaa E. Elsayed , Sayed K. Attia , Ghada A. Mahmoud , Yasser M. Mostafa , Afaf R.Taman , Doaa I. Osman

Colored wastewater discharge from several industries, including paper, cosmetics, leather, dying, and textile industries, is a significant environmental management issue, especially in developing countries. Copolymerization of acrylic acid (AAc) as well as gelatin (Gltn) was performed in different compositions and crosslinked utilizing gamma irradiation to form Gltn/AAc hydrogel. EDTA has modified the hydrogel to improve adsorption properties. The effect of irradiation dose, the composition of Gltn-AAc, EDTA content, and AAc content on gel percentage was studied. The swelling behavior were studied as a time function. The prepared hydrogels’ surface morphologies and structure were confirmed with FTIR, SEM, as well as XRD. Modified hydrogel used in batch adsorption was studied to remove anionic and cationic dyes, namely methyl orange (MO) and methylene blue (MB), from simulated wastewater. The parameters of adsorption, like pH, time, and initial metals concentration, were studied. The removal of MB dye by modified Gltn/AAc/EDTA hydrogel was found to be greater than that of MO dye.

造纸、化妆品、皮革、染色和纺织等行业的有色废水排放是一个重要的环境管理问题,特别是在发展中国家。将丙烯酸(AAc)和明胶(Gltn)以不同的组分进行共聚,并利用伽马辐射交联形成Gltn/AAc水凝胶。EDTA对水凝胶进行了改性,提高了其吸附性能。研究了辐照剂量、gln -AAc组成、EDTA含量和AAc含量对凝胶率的影响。研究了膨胀行为随时间的变化规律。用红外光谱(FTIR)、扫描电镜(SEM)和x射线衍射(XRD)对制备的水凝胶的表面形貌和结构进行了表征。研究了用改性水凝胶间歇吸附法去除模拟废水中的阴离子和阳离子染料甲基橙(MO)和亚甲基蓝(MB)。研究了pH、时间、初始金属浓度等吸附参数。改性Gltn/AAc/EDTA水凝胶对MB染料的去除率大于对MO染料的去除率。
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引用次数: 0
Using the Fenton reactions to eliminate Total Organic Carbon (TOC) from industrial effluents 利用Fenton反应去除工业废水中的总有机碳(TOC)
Q1 Earth and Planetary Sciences Pub Date : 2023-11-21 DOI: 10.1016/j.ejpe.2023.10.003
Amany M. Naguib , Soha A. Abdel-Gawad , Ahmed S. Mahmoud

Industrial effluents are produced in large quantities in underdeveloped nations, where they cannot be handled using conventional treatment techniques. In this study, hydroxyl radicals (HO) were successfully generated for the treatment of industrial wastewater represented in TOC removals by combining a ferrous catalyst with hydrogen peroxide in the Fenton reaction. The effects of operating conditions of pH, ferrous dose, H2O2 dose, time, and initial TOC concentration were studied for the Fenton process and different operating parameters were studied for the coagulation process to optimize and control the removal efficiency. The results showed that Fenton oxidation processes are able to reduce about 86 % for initial TOC level of 2000 and 95 % for initial TOC level of 400 after using 0.15 g/L ferrous dose, 10 mL/L of 30 % H2O2 for 30 min at acidic pH 4. Finally, this study recommends removing organic materials from industrial effluent using the Fenton oxidation method.

工业废水在不发达国家大量产生,无法用传统的处理技术处理。在本研究中,在Fenton反应中,通过亚铁催化剂与过氧化氢结合,成功地产生了羟基自由基(HO•),用于处理以TOC去除为代表的工业废水。研究了pH、亚铁剂量、H2O2剂量、时间和初始TOC浓度对Fenton工艺的影响,并研究了不同操作参数对混凝工艺的影响,以优化和控制混凝工艺的去除率。结果表明,在酸性pH为4的条件下,当亚铁浓度为0.15 g/L, H2O2浓度为30 %,H2O2浓度为10 mL/L,氧化时间为30 min时,Fenton氧化工艺对初始TOC水平为2000时可降低约86 %,对初始TOC水平为400时可降低约95 %。最后,本研究建议采用Fenton氧化法去除工业废水中的有机物质。
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引用次数: 0
Monitoring, modeling, and optimization of parameters affecting the recovery efficiency of acid gases from a sweetening unit 影响脱硫装置酸性气体回收效率的参数监测、建模和优化
Q1 Earth and Planetary Sciences Pub Date : 2023-11-11 DOI: 10.1016/j.ejpe.2023.11.001
Walaa Mahmoud Shehata, Ehab Ibrahim Abd-elhamid, Fatma Khalifa Gad

Amine processes are the advanced technology available today for the removal of carbon dioxide (CO2) and hydrogen sulfide (H2S) acid gases. Methyldiethanolamine (MDEA) is a well-known tertiary amine used selectively for the removal of carbon dioxide from natural gas. There are many parameters that can affect the efficiency of separating these acid gases from natural gas. In this paper, we have studied, modeled, and optimized different operating parameters of sour gas feed and MDEA solution which affect the CO2 recovery efficiency from an existing sweetening unit. These operating parameters are the sour gas feed temperature and pressure, volume ratio (%) of carbon dioxide in the feed gas, amine inlet temperature, and amine circulation rate. Actual data were collected from an industrial CO2 sweetening unit over one year. These data were used to study the effect of the studied operating parameters on the recovery efficiency of CO2 from the sweetening unit. All studied operating parameters were found to have an impact on the recovery efficiency of the removed gases. A response surface methodology approach was used in Design-Expert software version 13 to model the relationship between considered operating parameters and CO2 recovery efficiency. In addition, Design Expert numerical optimization has been used to maximize CO2 recovery efficiency. The results showed that the optimal range of sour gas feed temperature is 34.71 to 45.56 °C, sour gas feed pressure is 8.32 to 10.04 barg, the volume ratio (%) of carbon dioxide in the sour gas feed is 8.51 to 10.15, the temperature of the amine is 38.03 to 43.96 °C, and the amine circulation rate is 788.39 to 1122.35 m3/h. The presented work can be considered as a guideline for increasing the recovery efficiency of CO2 for both new and existing sweetening units.

胺法是目前用于去除二氧化碳(CO2)和硫化氢(H2S)酸性气体的先进技术。甲基二乙醇胺(MDEA)是一种众所周知的叔胺,用于选择性地从天然气中去除二氧化碳。有许多参数会影响从天然气中分离这些酸性气体的效率。本文对某现有脱硫装置含酸气进料和MDEA溶液的不同操作参数对CO2回收效率的影响进行了研究、建模和优化。这些操作参数是酸气进料温度和压力、进料气中二氧化碳的体积比(%)、胺入口温度和胺循环速率。实际数据从一个工业二氧化碳脱硫装置收集了一年多的时间。利用这些数据研究了所研究的操作参数对脱硫装置CO2回收率的影响。所有研究的操作参数都对脱气的回收效率有影响。Design-Expert软件版本13采用响应面方法对考虑的操作参数与CO2采收率之间的关系进行建模。此外,Design Expert数值优化已被用于最大限度地提高二氧化碳回收效率。结果表明,酸气进料温度为34.71 ~ 45.56℃,酸气进料压力为8.32 ~ 10.04 bar,二氧化碳体积比为8.51 ~ 10.15,胺料温度为38.03 ~ 43.96℃,胺料循环速率为788.39 ~ 1122.35 m3/h。本文的工作可作为提高现有和新建脱硫装置CO2回收率的指导方针。
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引用次数: 0
期刊
Egyptian Journal of Petroleum
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