A. Arjunan, K. Balasundaram, Purushottam Kumar, Jaeseok Lee, Sang Yoon, S. Kim, Sushant Gupta, R. Singh
Poor adhesion and delamination of diamond-like carbon(DLC) films due to high residual stresses has been a long standing challenge for thick (>1 μm) DLC films. In this study, delamination-free and low stress DLC films were deposited using multi-cycle pulsed laser deposition (MCPLD) from a graphite target. Residual stress values of a micron thick film prepared by MCPLD was 2 GPa, as compared to 9 GPa in films deposited by conventional or single cycle pulsed laser deposition (SCPLD). Adhesion failure was completely absent in the DLC films prepared by the MCPLD process owing to such low residual stress.
{"title":"Fabrication of Delamination Free, Low Stress Diamond Like Carbon (DLC) Films Using Pulsed Laser Deposition (PLD)","authors":"A. Arjunan, K. Balasundaram, Purushottam Kumar, Jaeseok Lee, Sang Yoon, S. Kim, Sushant Gupta, R. Singh","doi":"10.1149/2.010201ESL","DOIUrl":"https://doi.org/10.1149/2.010201ESL","url":null,"abstract":"Poor adhesion and delamination of diamond-like carbon(DLC) films due to high residual stresses has been a long standing challenge for thick (>1 μm) DLC films. In this study, delamination-free and low stress DLC films were deposited using multi-cycle pulsed laser deposition (MCPLD) from a graphite target. Residual stress values of a micron thick film prepared by MCPLD was 2 GPa, as compared to 9 GPa in films deposited by conventional or single cycle pulsed laser deposition (SCPLD). Adhesion failure was completely absent in the DLC films prepared by the MCPLD process owing to such low residual stress.","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"48 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73426888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Mun, Myung-Jin Lee, Joung-Won Park, Dukjin Oh, Doo-yeon Lee, S. Doo
An organic redox flow battery adopting tris(2,2'-bipyridine)nickel(II)tetrafluoroborate (Ni(Bpy)3(BF4)2) and tris(2,2'-bipyridine)iron(II)tetrafluoroborate (Fe(BPy)3(BF4)2)) in propylenecarbonate electrolyte is investigated. With cyclic voltammetry, the redox current of one-electron related Fe(II)/Fe(III) and two-electron related Ni(II)/Ni(0) appears at 0.65 V and −1.66 V (vs. Ag/Ag+), respectively and their cycleabilities are highly stable during 100 cycles. Their charge-discharge characteristics on the carbon-felt electrodes are evaluated with 0.4 M Fe(Bpy)3(BF4)2 and 0.2 M Ni(Bpy)3(BF4)2 which are adopted as catholyte and anolyte. Comparing with the aqueous system, the higher cell voltage of 2.2 V was achieved and initial coulombic and energy efficiencies were reached with 90.4 and 81.8%.
研究了在碳酸丙酯电解质中采用三(2,2′-联吡啶)镍(II)四氟硼酸盐(Ni(Bpy)3(BF4)2)和三(2,2′-联吡啶)铁(II)四氟硼酸盐(Fe(Bpy)3(BF4)2))的有机氧化还原液流电池。通过循环伏安法，单电子相关的Fe(II)/Fe(III)和双电子相关的Ni(II)/Ni(0)的氧化还原电流分别为0.65 V和- 1.66 V(相对于Ag/Ag+)，它们的循环能力在100次循环中高度稳定。分别以0.4 M Fe(Bpy)3(BF4)2和0.2 M Ni(Bpy)3(BF4)2作为阴极电解质和阳极电解质，对其在碳毡电极上的充放电特性进行了评价。与水体系相比，电池电压为2.2 V，库仑效率和能量效率分别为90.4和81.8%。
{"title":"Non-Aqueous Redox Flow Batteries with Nickel and Iron Tris(2,2′-bipyridine) Complex Electrolyte","authors":"J. Mun, Myung-Jin Lee, Joung-Won Park, Dukjin Oh, Doo-yeon Lee, S. Doo","doi":"10.1149/2.033206ESL","DOIUrl":"https://doi.org/10.1149/2.033206ESL","url":null,"abstract":"An organic redox flow battery adopting tris(2,2'-bipyridine)nickel(II)tetrafluoroborate (Ni(Bpy)3(BF4)2) and tris(2,2'-bipyridine)iron(II)tetrafluoroborate (Fe(BPy)3(BF4)2)) in propylenecarbonate electrolyte is investigated. With cyclic voltammetry, the redox current of one-electron related Fe(II)/Fe(III) and two-electron related Ni(II)/Ni(0) appears at 0.65 V and −1.66 V (vs. Ag/Ag+), respectively and their cycleabilities are highly stable during 100 cycles. Their charge-discharge characteristics on the carbon-felt electrodes are evaluated with 0.4 M Fe(Bpy)3(BF4)2 and 0.2 M Ni(Bpy)3(BF4)2 which are adopted as catholyte and anolyte. Comparing with the aqueous system, the higher cell voltage of 2.2 V was achieved and initial coulombic and energy efficiencies were reached with 90.4 and 81.8%.","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"21 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81695465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Solution Processed p-Doped Hole Transport Layer for Polymer Light-Emitting Diodes","authors":"K. Yook, Jun Yeob Lee","doi":"10.1149/2.004203ESL","DOIUrl":"https://doi.org/10.1149/2.004203ESL","url":null,"abstract":"","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"41 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83290550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"NaCrO2 is a Fundamentally Safe Positive Electrode Material for Sodium-Ion Batteries with Liquid Electrolytes","authors":"X. Xia, J. Dahn","doi":"10.1149/2.002201ESL","DOIUrl":"https://doi.org/10.1149/2.002201ESL","url":null,"abstract":"","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81598831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Junying Hu, Daobing Huang, Guoan Zhang, G. Song, Xingpeng Guo
Summary Thesynthesizedenvironment-friendlytetraphenylporphyrin(TPP)proved to be an efficient inhibitor for pure Mg. TPP may chelate withMgandformaTPP-Mgcompound,precipitatingonMgsurface.ThismeansthatTPPanditsderivativemayactaseffectiveinhibitorsforMgalloys; chelating reaction could be a mechanism responsible for Mgcorrosion inhibition. Following this, more highly efficient inhibitorsmay be identified for Mg alloys. Acknowledgments The authors thank the support of the Center of Forecasting andAnalysis,HuazhongUniversityofScienceandTechnology,inmolec-ular simulation. References 1. E. Ghali, “Magneisum and Magnesium alloys,” Uhlig’s Corrosion Handbook : 793(2000).2. G. Song and D. StJohn, Mater. Corros. , 56 ,15 (2005).3. G.-L. Song and Z. Xu, Electrochim. Acta. , 55 , 4148 (2010).4. L.J.Li,Z.M.Yao,J.L.Lei,H.Xu,S.T.Zhang,andF.S.Pan, Acta.Physico-Chimica.Sinica. , 25 , 1332 (2009).5. J. L. Lei, L. J. Li, H. S. Yu, M. L. Chen, S. T. Zhang, and F. S. Pan, Chem Res &Appl , 20 , 461 (2008).6. E. Slavcheva and G. Schmitt,
{"title":"A Study on Tetraphenylporphyrin as a Corrosion Inhibitor for Pure Magnesium","authors":"Junying Hu, Daobing Huang, Guoan Zhang, G. Song, Xingpeng Guo","doi":"10.1149/2.021206ESL","DOIUrl":"https://doi.org/10.1149/2.021206ESL","url":null,"abstract":"Summary Thesynthesizedenvironment-friendlytetraphenylporphyrin(TPP)proved to be an efficient inhibitor for pure Mg. TPP may chelate withMgandformaTPP-Mgcompound,precipitatingonMgsurface.ThismeansthatTPPanditsderivativemayactaseffectiveinhibitorsforMgalloys; chelating reaction could be a mechanism responsible for Mgcorrosion inhibition. Following this, more highly efficient inhibitorsmay be identified for Mg alloys. Acknowledgments The authors thank the support of the Center of Forecasting andAnalysis,HuazhongUniversityofScienceandTechnology,inmolec-ular simulation. References 1. E. Ghali, “Magneisum and Magnesium alloys,” Uhlig’s Corrosion Handbook : 793(2000).2. G. Song and D. StJohn, Mater. Corros. , 56 ,15 (2005).3. G.-L. Song and Z. Xu, Electrochim. Acta. , 55 , 4148 (2010).4. L.J.Li,Z.M.Yao,J.L.Lei,H.Xu,S.T.Zhang,andF.S.Pan, Acta.Physico-Chimica.Sinica. , 25 , 1332 (2009).5. J. L. Lei, L. J. Li, H. S. Yu, M. L. Chen, S. T. Zhang, and F. S. Pan, Chem Res &Appl , 20 , 461 (2008).6. E. Slavcheva and G. Schmitt,","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90778716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Early Failure Induced by Phase Transformation in Microjoints for Chip-Level Integration","authors":"Ren-Shin Cheng, H. Chang, Tao-Chih Chang, J. Chou","doi":"10.1149/2.023203ESL","DOIUrl":"https://doi.org/10.1149/2.023203ESL","url":null,"abstract":"","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89245818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
P. Shrestha, Adaku Ochia, K. Cheung, J. Campbell, H. Baumgart, G. Harris
{"title":"High-Speed Endurance and Switching Measurements for Memristive Switches","authors":"P. Shrestha, Adaku Ochia, K. Cheung, J. Campbell, H. Baumgart, G. Harris","doi":"10.1149/2.002206ESL","DOIUrl":"https://doi.org/10.1149/2.002206ESL","url":null,"abstract":"","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"11 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86851399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kuan‐Chang Chang, T. Tsai, T. Chang, Yong-En Syu, Siang-Lan Chuang, Chenghua Li, D. Gan, S. Sze
2011, Volume 15, Issue 3, Pages H65-H68. Electrochem. Solid-State Lett. Chuang, Cheng-Hua Li, Der-Shin Gan and Simon M. Sze Kuan-Chang Chang, Tsung-Ming Tsai, Ting-Chang Chang, Yong-En Syu, Siang-Lan The Effect of Silicon Oxide Based RRAM with Tin Doping service Email alerting click here in the box at the top right corner of the article or Receive free email alerts when new articles cite this article sign up
{"title":"The Effect of Silicon Oxide Based RRAM with Tin Doping","authors":"Kuan‐Chang Chang, T. Tsai, T. Chang, Yong-En Syu, Siang-Lan Chuang, Chenghua Li, D. Gan, S. Sze","doi":"10.1149/2.013203ESL","DOIUrl":"https://doi.org/10.1149/2.013203ESL","url":null,"abstract":"2011, Volume 15, Issue 3, Pages H65-H68. Electrochem. Solid-State Lett. Chuang, Cheng-Hua Li, Der-Shin Gan and Simon M. Sze Kuan-Chang Chang, Tsung-Ming Tsai, Ting-Chang Chang, Yong-En Syu, Siang-Lan The Effect of Silicon Oxide Based RRAM with Tin Doping service Email alerting click here in the box at the top right corner of the article or Receive free email alerts when new articles cite this article sign up","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76188343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. Lin, Y. J. Chen, C. C. Chang, X. F. Li, S. Hsu, C. Y. Liu
{"title":"Pattern-Coverage Effect on Light Extraction Efficiency of GaN LED on Patterned-Sapphire Substrate","authors":"H. Lin, Y. J. Chen, C. C. Chang, X. F. Li, S. Hsu, C. Y. Liu","doi":"10.1149/2.018203ESL","DOIUrl":"https://doi.org/10.1149/2.018203ESL","url":null,"abstract":"","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"80 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86235762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Structural and Ionic Conductivity Studies of Doped Ceria Electrolyte","authors":"S. Ramesh, K. Raju","doi":"10.1149/2.019203ESL","DOIUrl":"https://doi.org/10.1149/2.019203ESL","url":null,"abstract":"","PeriodicalId":11627,"journal":{"name":"Electrochemical and Solid State Letters","volume":"46 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91347912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：