Pub Date : 2024-02-01DOI: 10.2138/gselements.20.1.31
S. Tachibana, Nami Sakai
The C-type asteroid Ryugu samples returned by the Hayabusa2 spacecraft are the chemically most pristine material in the Solar System, as they have not been exposed to terrestrial environments. The organic matter in Ryugu records the molecular evolution from the Sun’s parent molecular cloud chemistry to asteroidal aqueous alteration. In this article, we review the results of Ryugu sample analysis and discuss the evolution of organic matter in the early Solar System by comparing these results with recent radio and infrared observations of protostars and protoplanetary disks.
{"title":"Asteroidal Organics from the Sample Return Mission Hayabusa2 and their Implication for Understanding our Origins","authors":"S. Tachibana, Nami Sakai","doi":"10.2138/gselements.20.1.31","DOIUrl":"https://doi.org/10.2138/gselements.20.1.31","url":null,"abstract":"The C-type asteroid Ryugu samples returned by the Hayabusa2 spacecraft are the chemically most pristine material in the Solar System, as they have not been exposed to terrestrial environments. The organic matter in Ryugu records the molecular evolution from the Sun’s parent molecular cloud chemistry to asteroidal aqueous alteration. In this article, we review the results of Ryugu sample analysis and discuss the evolution of organic matter in the early Solar System by comparing these results with recent radio and infrared observations of protostars and protoplanetary disks.","PeriodicalId":11643,"journal":{"name":"Elements","volume":null,"pages":null},"PeriodicalIF":4.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139831798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-01DOI: 10.2138/gselements.20.1.60
{"title":"International Association of Geoanalysts","authors":"","doi":"10.2138/gselements.20.1.60","DOIUrl":"https://doi.org/10.2138/gselements.20.1.60","url":null,"abstract":"","PeriodicalId":11643,"journal":{"name":"Elements","volume":null,"pages":null},"PeriodicalIF":4.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139876127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-01DOI: 10.2138/gselements.20.1.57
{"title":"International Association of GeoChemistry","authors":"","doi":"10.2138/gselements.20.1.57","DOIUrl":"https://doi.org/10.2138/gselements.20.1.57","url":null,"abstract":"","PeriodicalId":11643,"journal":{"name":"Elements","volume":null,"pages":null},"PeriodicalIF":4.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139892216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-01DOI: 10.2138/gselements.20.1.61
{"title":"Mineralogical Society of Poland","authors":"","doi":"10.2138/gselements.20.1.61","DOIUrl":"https://doi.org/10.2138/gselements.20.1.61","url":null,"abstract":"","PeriodicalId":11643,"journal":{"name":"Elements","volume":null,"pages":null},"PeriodicalIF":4.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139889262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-01DOI: 10.2138/gselements.20.1.63
{"title":"Japan Association of Mineralogical Sciences","authors":"","doi":"10.2138/gselements.20.1.63","DOIUrl":"https://doi.org/10.2138/gselements.20.1.63","url":null,"abstract":"","PeriodicalId":11643,"journal":{"name":"Elements","volume":null,"pages":null},"PeriodicalIF":4.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139875226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-01DOI: 10.2138/gselements.20.1.38
Yoko Kebukawa, Mehmet Yesiltas, T. Glotch
Advances in analytical techniques are essential for understanding the nature, formation, and evolutionary history of extraterrestrial organic matter. In this chapter, we briefly review analytical techniques used to detect and characterize organic matter in extraterrestrial materials. Mass spectrometry is often coupled with gas chromatography or liquid chromatography for elemental and isotopic analysis, and for identifying specific organic compounds. Spectroscopy involves interaction of molecules with electromagnetic radiation at various wavelengths. Almost every wavelength—from X-rays to radio waves—can be used for spectroscopic measurements. The most major microscopic and nanoscopic techniques are scanning and/or transmission electron microscopy. Spectroscopy and mass spectrometry can also be coupled with microscopic analysis for detailed compositional investigations.
分析技术的进步对于了解地外有机物的性质、形成和演化历史至关重要。在本章中,我们将简要回顾用于检测和描述地外物质中有机物特征的分析技术。质谱法通常与气相色谱法或液相色谱法结合使用,用于元素和同位素分析,以及识别特定的有机化合物。光谱学涉及分子与不同波长电磁辐射的相互作用。从 X 射线到无线电波,几乎所有波长都可用于光谱测量。最主要的显微和纳米技术是扫描和/或透射电子显微镜。光谱分析和质谱分析也可与显微分析相结合,进行详细的成分研究。
{"title":"Analytical Techniques for Identification and Characterization of Extraterrestrial Organic Matter","authors":"Yoko Kebukawa, Mehmet Yesiltas, T. Glotch","doi":"10.2138/gselements.20.1.38","DOIUrl":"https://doi.org/10.2138/gselements.20.1.38","url":null,"abstract":"Advances in analytical techniques are essential for understanding the nature, formation, and evolutionary history of extraterrestrial organic matter. In this chapter, we briefly review analytical techniques used to detect and characterize organic matter in extraterrestrial materials. Mass spectrometry is often coupled with gas chromatography or liquid chromatography for elemental and isotopic analysis, and for identifying specific organic compounds. Spectroscopy involves interaction of molecules with electromagnetic radiation at various wavelengths. Almost every wavelength—from X-rays to radio waves—can be used for spectroscopic measurements. The most major microscopic and nanoscopic techniques are scanning and/or transmission electron microscopy. Spectroscopy and mass spectrometry can also be coupled with microscopic analysis for detailed compositional investigations.","PeriodicalId":11643,"journal":{"name":"Elements","volume":null,"pages":null},"PeriodicalIF":4.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139825968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-01DOI: 10.2138/gselements.20.1.19
Zita Martins, M. Pasek
The inner Solar System—including the planet Earth—was heavily bombarded by comets, asteroids, and their fragments (i.e., meteorites, micrometeorites, and interplanetary dust particles) from 4.56 to about 3.5 billion years ago. This bombardment resulted in a rich assortment of organics delivered to the Earth, as comets and many asteroids contain carbonaceous material. These organic compounds were likely further processed on the early Earth (e.g., by impact-shock reactions), providing a feedstock of prebiotic molecules to the crust and oceans. In this chapter, we review the mechanisms of organic matter delivery to the primitive Earth, further reactions and processing, and the importance of exogenous material in the evolution of our planet and life.
{"title":"Delivery of Organic Matter to the Early Earth","authors":"Zita Martins, M. Pasek","doi":"10.2138/gselements.20.1.19","DOIUrl":"https://doi.org/10.2138/gselements.20.1.19","url":null,"abstract":"The inner Solar System—including the planet Earth—was heavily bombarded by comets, asteroids, and their fragments (i.e., meteorites, micrometeorites, and interplanetary dust particles) from 4.56 to about 3.5 billion years ago. This bombardment resulted in a rich assortment of organics delivered to the Earth, as comets and many asteroids contain carbonaceous material. These organic compounds were likely further processed on the early Earth (e.g., by impact-shock reactions), providing a feedstock of prebiotic molecules to the crust and oceans. In this chapter, we review the mechanisms of organic matter delivery to the primitive Earth, further reactions and processing, and the importance of exogenous material in the evolution of our planet and life.","PeriodicalId":11643,"journal":{"name":"Elements","volume":null,"pages":null},"PeriodicalIF":4.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139827558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Organic compounds are a major component of dust in molecular clouds, alongside silicates and water ice, due to the high abundances of elements that make up these compounds in the Galaxy. The initial molecular inventory of the Solar System, inherited from the molecular cloud, was modified and new complex molecules were formed in the protoplanetary disk and planetesimals. Because astronomical observations mainly target gas, while cosmochemical evidence deals with solid phases, it is crucial to link discrepant knowledge on organic species through state-of-the-art modeling. This chapter reviews the latest understanding of surface reactions on inter-stellar dusts, gas–dust reactions in the protoplanetary disk, and alteration processes on planetesimals in the early Solar System.
{"title":"Formation and Evolution Mechanisms for Organic Matter in Space","authors":"Hideko Nomura, Queenie Hoi Shan Chan, Hikaru Yabuta","doi":"10.2138/gselements.20.1.13","DOIUrl":"https://doi.org/10.2138/gselements.20.1.13","url":null,"abstract":"Organic compounds are a major component of dust in molecular clouds, alongside silicates and water ice, due to the high abundances of elements that make up these compounds in the Galaxy. The initial molecular inventory of the Solar System, inherited from the molecular cloud, was modified and new complex molecules were formed in the protoplanetary disk and planetesimals. Because astronomical observations mainly target gas, while cosmochemical evidence deals with solid phases, it is crucial to link discrepant knowledge on organic species through state-of-the-art modeling. This chapter reviews the latest understanding of surface reactions on inter-stellar dusts, gas–dust reactions in the protoplanetary disk, and alteration processes on planetesimals in the early Solar System.","PeriodicalId":11643,"journal":{"name":"Elements","volume":null,"pages":null},"PeriodicalIF":4.5,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139888834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}