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Correction: Recent Advances in Thermal Interface Materials 修正:热界面材料的最新进展
Pub Date : 2020-11-19 DOI: 10.30919/esmm5f940
Yongcun Zhou, Siqi Wu, Pengli Zhu, Feixiang Wu, Feng Liu, Vignesh Murugadoss, W. Winchester, Amit Nautiyal, Zhe Wang, Zhanhu Guo
Yongcun Zhou,1,2,* Siqi Wu,1 Pengli Zhu,3 Feixiang Wu4 and Feng Liu1,5 Vignesh Murugadoss,6,7 Williams Winchester,8 Amit Nautiyal,8 Zhe Wang8,* and Zhanhu Guo7,* 1School of Material Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, China 2Yangtze River Delta Research Institute of NPU, Taicang 215400, China Shenzhen Institute of Advanced Electronic Materials, Shenzhen Fundamental Research Institutions, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China 4School of Metallurgy and Environment, Central South University, Changsha 410083, China Analytical & Testing Center, Northwestern Polytechnical University, Xi’an 710072, China Electro-Materials Research Laboratory, Centre for Nanoscience and Technology, Pondicherry University, Puducherry 605014, India Integrated Composites Laboratory (ICL), Department of Chemical and Biomolecular Engineering, University of Tennessee, Knoxville, TN 37996, USA Chemistry Department, Xavier University of Louisiana, New Orleans 70125, USA *E-mail: yczhou@nwpu.edu.cn; zwang@xula.edu; zguo10@utk.edu, nanomaterials2000@gmail.com
周永存,1,2,*吴思琪,1朱鹏力,3吴飞翔4,刘峰1,2,5 Vignesh Murugadoss,6,7 Williams Winchester,8 Amit nautial,8王哲8,*,郭展虎7,* 1西北工业大学材料科学与工程学院,西安710072 2西北工业大学长三角研究所,太仓215400,中国深圳先进电子材料研究所,深圳基础研究院,深圳先进技术研究院,4中南大学冶金与环境学院,长沙410083;西北工业大学分析测试中心,西安710072;本地治里大学纳米科学与技术中心,中国电材料研究实验室,普杜切里605014;田纳西大学化学与生物分子工程系,印度集成复合材料实验室,田纳西州诺克斯维尔37996;路易斯安那泽维尔大学化学系,新奥尔良70125 *E-mail: yczhou@nwpu.edu.cn;zwang@xula.edu;zguo10@utk.edu, nanomaterials2000@gmail.com
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引用次数: 2
Nanocrystalline Copper Selenide formation by Direct Reaction between Cu-ions and Selenosulfate 铜离子与硫酸亚硒酸盐直接反应生成纳米晶硒化铜
Pub Date : 2020-10-17 DOI: 10.30919/esmm5f905
H. Pathan, Balasaheb M. Palve, esh R. Jadkar, O. Joo
Copper selenide (Cu 3 Se 2 ) nanocrystals were successfully synthesized on glass substrate by the chemical bath deposition technique. The room temperature formation of Cu 3 Se 2 from the reaction between Cu-ions and selenosulfate in aqueous solution was investigated. The resulting precipitate from the reaction of Cu-ions and selenosulfate was initially light green (mainly a mixture of amorphous Cu 2 SO 3 .CuSO 3 and Cu(OH) 2 ) and turned to greenish brown and finally brownish (mainly Cu 3 Se 2 ). Cu 3 Se 2 was formed via the hydroxide cluster mechanism and reaction between Cu(OH) 2 and the slowly generated Se 2-ions. The Cu 3 Se 2 exhibited a disordered phase and small nanocrystals in the range of 2 to 5 nm. The formation mechanism of different phases of copper selenide by chemical bath deposition technique were explained in details.
采用化学浴沉积技术在玻璃衬底上成功地合成了硒化铜纳米晶体。研究了Cu离子与硫酸亚硒酸盐在水溶液中的室温反应生成cu3se2的过程。铜离子与硫酸亚硒酸盐反应产生的沉淀最初为浅绿色(主要是无定形的cu2so3、cuso3和Cu(OH) 2的混合物),然后变为绿棕色,最后变为褐色(主要是cu3se2)。Cu(OH) 2与缓慢生成的Se - 2离子反应形成cu3se2。Cu - 3se - 2在2 ~ 5nm范围内表现为无序相和小的纳米晶体。详细阐述了化学浴沉积法不同相硒化铜的形成机理。
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引用次数: 5
Integrating Artificial Intelligence, Theory, Modeling and Experiments – Perspectives, Challenges, and Opportunities in Materials and Manufacturing 整合人工智能,理论,建模和实验-材料和制造的前景,挑战和机遇
Pub Date : 2020-09-21 DOI: 10.30919/esmm5f915
Guang Lin, Na Lu
Artificial intelligence (AI)/machine learning (ML) are an active research field, which has shown a great success in various commercial applications. It will play an important role and have a great impact on many fields of science and engineering, in particular materials and manufacturing. In the past decades, AI and ML have become a crucial complement to theoretical, computational modeling, and experimental aspects in Engineering and Science. AI and ML models have great potentials particularly in the research areas where the mechanism is still not completely well-understood, or the computational models are too expensive to run to obtain accurate solutions at desired spatiotemporal resolutions. In this work, we introduce some recent work and promising research directions to integrate AI and ML in Engineering and Science. We attempt to provide a broader perspective, open challenges and unique opportunities on integrating AI, theory, modeling and experiments in the fields of materials and manufacturing. First, experiments or computational models can be employed to generate data to train the AI/ML models. The trained AI/ML models can be viewed as a fast surrogate model of the corresponding time-consuming experiments or computational models. A convolutional encoder-decoder networks with quantified uncertainty (ConvPDE-UQ) was developed to predict the solutions of partial differential equations on varied domains, which was much faster than the traditional finite element solver. A deep neural networks named Peri-Net was designed for analysis of crack patterns, which is much faster than the peridynamics solver. A deep neural process with a quantified uncertainty capability named Peri-Net-Pro was developed for analysis of crack patterns. Second, theory and physics laws can be integrated with AI/ML models. The application of AI/ML models in science and engineering domains is facing some grand challenges due to the large data requirements and lack of generalizability. Recently various novel AI/ML models have been proposed to integrate both scientific knowledge and data together Third, AI/ML models also can be employed to automatically discover theory, in particular, the physical laws. Various AI/ML models have been developed to automatically discover ordinary differential equations and partial differential equations. Uncertainty quantifications for the discovery of physical laws using AI/ML models have also been investigated. Fourth, in many applications in materials and manufacturing, it is expensive or time-consuming to collect experimental or simulation data. To resolve such challenges, active learning models can be employed to design optimal experiments and computational model simulations to greatly enhance the predictive capability of the AI/ML models with reduced experimental or simulation data size. An adaptive design criterion combining the D-optimality and the maximin space-filling criterion has been designed and demonstrated its capability. Fifth,
人工智能(AI)/机器学习(ML)是一个活跃的研究领域,在各种商业应用中取得了巨大的成功。它将在许多科学和工程领域,特别是材料和制造领域发挥重要作用和产生重大影响。在过去的几十年里,人工智能和机器学习已经成为工程和科学理论、计算建模和实验方面的重要补充。AI和ML模型具有巨大的潜力,特别是在机制尚未完全理解的研究领域,或者计算模型过于昂贵而无法在所需的时空分辨率下获得准确的解决方案。在这项工作中,我们介绍了一些最近的工作和有前途的研究方向,以整合人工智能和机器学习在工程和科学。我们试图在材料和制造领域整合人工智能,理论,建模和实验方面提供更广阔的视角,开放的挑战和独特的机会。首先,可以使用实验或计算模型生成数据来训练AI/ML模型。经过训练的AI/ML模型可以看作是相应耗时实验或计算模型的快速代理模型。提出了一种具有量化不确定性的卷积编码器-解码器网络(ConvPDE-UQ),用于预测不同域上偏微分方程的解,其速度比传统的有限元求解器快得多。设计了一种深度神经网络perii - net,用于裂纹模式分析,其速度远远快于周期动力学求解器。开发了一种具有量化不确定性的深度神经过程——perinet - pro,用于裂纹模式分析。第二,理论和物理定律可以与AI/ML模型相结合。人工智能/机器学习模型在科学和工程领域的应用面临着大量数据需求和缺乏通用性的巨大挑战。最近提出了各种新颖的AI/ML模型,将科学知识和数据结合在一起。第三,AI/ML模型还可以用于自动发现理论,特别是物理定律。各种AI/ML模型已经被开发出来,可以自动发现常微分方程和偏微分方程。还研究了使用AI/ML模型发现物理定律的不确定性量化。第四,在材料和制造的许多应用中,收集实验或模拟数据是昂贵或耗时的。为了解决这些挑战,可以使用主动学习模型来设计最优实验和计算模型仿真,从而在减少实验或仿真数据量的情况下大大增强AI/ML模型的预测能力。设计了一种结合d -最优性和最大空间填充准则的自适应设计准则,并对其性能进行了验证。第五,在材料和制造领域,有各种各样的多保真度计算模型和实验仪器。如何整合所有模型和实验仪器的数据是一个巨大的挑战。近年来,先进的多保真度模型被开发出来,用于整合由多保真度计算模型或实验产生的多分辨率数据,用于训练和预测。先进的优化算法[14-15]已被开发用于调整深度神经网络的超参数。ES材料与制造
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引用次数: 1
Polypyrrole Functionalized Graphene Oxide Accelerated Zinc Phosphate Coating under Low-Temperature 聚吡咯功能化氧化石墨烯低温加速磷酸锌涂层研究
Pub Date : 2020-09-05 DOI: 10.30919/esmm5f927
Qingsong Zhu, Jingguang Liu, Xin Wang, Yuxiang Huang, Yingtao Ren, Chenzhong Mu, Xianhu Liu, Feng Wei, Chuntai Liu
Zinc phosphate coating, as an effective and fast anticorrosion technique for the metals, have been developed rapidly in recent years. However, it is still a challenge to synthesize a low energy, environmentally friendly and efficient accelerator through a facile method. Herein, as a new accelerator, polypyrrole (PPy) functionalized graphene oxide (GO-PPy) nanocomposites were prepared by in-situ process to grow PPy film on GO surface, Incorporation of GO-PPy into phosphate baths accelerated the phosphating process of phosphate coating and promoted the nucleation and growth of phosphate crystals, achieving stronger corrosion resistance, which were confirmed by electrochemical measures and morphologies characteristic of the phosphate coating. Additionally, when the concentration of GO-PPy in the phosphate baths reached up 1.2 g/L, the phosphate coating possessed the most compact and uniform phosphate crystals and the best corrosion protection performance. Finally, the special mechanism of the phosphate process was discussed. This work introduces a new, low-energy, facile, environmentally friendly and alternative accelerator for the preparation of phosphate coatings.
磷酸锌涂层作为一种高效、快速的金属防腐技术,近年来得到了迅速发展。然而,如何通过简单的方法合成低能量、环保、高效的加速器仍然是一个挑战。本文采用原位法制备了聚吡咯(PPy)功能化氧化石墨烯(GO-PPy)纳米复合材料作为新型促进剂,在氧化石墨烯表面生长PPy薄膜,将GO-PPy加入到磷酸盐液中,加速了磷酸盐涂层的磷化过程,促进了磷酸盐晶体的成核和生长,获得了更强的耐腐蚀性,这一点通过电化学测量和磷酸盐涂层的形貌特征得到了证实。另外,当磷酸液中GO-PPy的浓度达到1.2 g/L时,所制备的磷酸盐涂层具有最致密均匀的磷酸盐晶体和最佳的防腐性能。最后讨论了磷化过程的特殊机理。本文介绍了一种新型、低能耗、简便、环保、可替代的制备磷酸盐涂料的加速剂。
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引用次数: 37
Polydimethylsiloxane Resin Nanocomposite Coating with Alternating Multilayer Structure for Corrosion Protection Performance 多层交变结构聚二甲基硅氧烷树脂纳米复合涂层的防腐性能研究
Pub Date : 2020-09-05 DOI: 10.30919/esmm5f912
Jianping Liu, Jiaoxia Zhang, Jijun Tang, Liuyue Pu, Yanli Xue, Mei-juan Lu, Lei Xu, Zhanhu Guo
Polydimethylsiloxane (PDMS) composite coatings filled with nanoparticles have been used extensively as anticorrosion materials. The alternating multilayer polydimethylsiloxane resin nanocomposite coating was first fabricated based on stepwise coating method via adding graphene and α-alumina. Their mechanical and anticorrosion properties were discussed. The binary fillers greatly improved the adhesion up to level 1, at the same time, the coating remained extreme flexibility. When the graphene was 0.3 wt%, the alternating multilayer coating exhibited the best corrosion resistance with the 4.82 V of corrosion potential (Ecorr), which was increased by near 40 times compared with pure PDMS coating. Meanwhile, the impedance value of composite coating reached 10 Ω•cm. The corrosion current density (Icorr) of the coating was smaller than that of bare tinplate. The long-term soaking results prove that the alternating multilayer composite coating still possess the outstanding corrosion resistance for tinplate after 30-day immersion.
填充纳米粒子的聚二甲基硅氧烷(PDMS)复合涂层作为防腐材料得到了广泛的应用。以α-氧化铝和石墨烯为原料,采用分步包覆法制备了多层聚二甲基硅氧烷树脂纳米复合涂层。对其力学性能和防腐性能进行了讨论。二元填料大大提高了涂层的附着力,达到1级,同时涂层保持了极高的柔韧性。当石墨烯含量为0.3 wt%时,交变多层涂层的耐蚀性能最佳,腐蚀电位(Ecorr)为4.82 V,比纯PDMS涂层提高了近40倍。同时,复合涂层的阻抗值达到10 Ω•cm。涂层的腐蚀电流密度(Icorr)小于裸马口铁。长期浸渍试验结果表明,交替多层复合涂层在浸渍30天后仍具有优异的耐马口铁腐蚀性能。
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引用次数: 51
Effect of Different Sintering Additives on the Microstructure, Phase Compositions and Mechanical Properties of Si3N4/SiC Ceramics 不同烧结添加剂对Si3N4/SiC陶瓷显微组织、相组成及力学性能的影响
Pub Date : 2020-08-12 DOI: 10.21203/rs.3.rs-53947/v1
H. Yan, Qing-gang Li, Zhi Wang, Hao Wu, Yuying Wu, Xin Cheng
Y2O3 and CeO2 were chosen as additives to investigate the effect of different additives on the microstructure, composition of phases and mechanical properties of Si3N4/SiC ceramics using pressureless sintering. Si3N4/SiC ceramic without additives had a high density, while after adding Y2O3 and CeO2, the density and flexural strength of Si3N4/SiC ceramics were significantly decreased due to the increase of porosity. The main phase compositions of samples were β-Si3N4 and SiC. Moreover, the liquid phases Y-Si-O-N and Ce-Si-O-N were observed after adding Y2O3 and CeO2 respectively. It also indicated that for Si3N4/SiC composite ceramics, the high aspect ratio β-Si3N4 overlapped with each other and closely bonded with glass phase could improve flexure strength effectively. Besides, the SiC crystal grains mainly existed in grain boundary, which could inhibit the secondary recrystallization to avoid that the decrease of flexural strength caused by the overgrowth of β-Si3N4 grains.
选择Y2O3和CeO2作为添加剂,研究了不同添加剂对无压烧结Si3N4/SiC陶瓷显微组织、相组成和力学性能的影响。未添加添加剂的Si3N4/SiC陶瓷具有较高的密度,而添加Y2O3和CeO2后,由于孔隙率的增加,Si3N4/SiC陶瓷的密度和抗弯强度明显降低。样品的主要相组成为β-Si3N4和SiC。添加Y2O3和CeO2后,分别观察到液相Y-Si-O-N和Ce-Si-O-N。对于Si3N4/SiC复合陶瓷而言,高纵横比β-Si3N4相互重叠并与玻璃相紧密结合可有效提高其抗弯强度。此外,SiC晶粒主要存在于晶界,可以抑制二次再结晶,避免β-Si3N4晶粒过度生长导致抗弯强度下降。
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引用次数: 7
Real-Time Precise Damage Characterization in Self-Sensing Materials via Neural Network-Aided Electrical Impedance Tomography: A Computational Study 基于神经网络辅助电阻抗断层成像的自感知材料的实时精确损伤表征:一项计算研究
Pub Date : 2020-05-05 DOI: 10.25394/PGS.12245678.V1
Lin, Guang, Zhao, Lang, Tallman, Tyler
Many cases have evinced the importance of having structural health monitoring (SHM) strategies that can allow the detection of the structural health of infrastructures or buildings, in order to prevent the potential economic or human losses. Nanocomposite material like the Carbon nanofiller-modified composites have great potential for SHM because these materials are piezoresistive. So, it is possible to determine the damage status of the material by studying the conductivity change distribution, and this is essential for detecting the damage on the position that can-not be observed by eye, for example, the inner layer in the aerofoil. By now, many researchers have studied how damage influences the conductivity of nanocomposite material and the electrical impedance tomography (EIT) method has been applied widely to detect the damage-induced conductivity changes. However, only knowing how to calculate the conductivity change from damage is not enough to SHM, it is more valuable to SHM to know how to determine the mechanical damage that results in the observed conductivity changes. In this article, we apply the machine learning methods to determine the damage status, more specifically, the number, radius and the center position of broken holes on the material specimens by studying the conductivity change data generated by the EIT method. Our results demonstrate that the machine learning methods can accurately and efficiently detect the damage on material specimens by analysing the conductivity change data, this conclusion is important to the field of the SHM and will speed up the damage detection process for industries like the aviation industry and mechanical engineering.
许多案例证明了结构健康监测(SHM)战略的重要性,这种战略可以检测基础设施或建筑物的结构健康状况,以防止潜在的经济或人员损失。纳米复合材料,如碳纳米填料改性复合材料,由于其压阻性,在SHM中具有很大的潜力。因此,通过研究材料的电导率变化分布来确定材料的损伤状态是可能的,这对于检测肉眼无法观察到的位置,例如翼型内层的损伤是必不可少的。目前,许多研究者对损伤对纳米复合材料电导率的影响进行了研究,电阻抗层析成像(EIT)方法已广泛应用于检测损伤引起的电导率变化。然而,对于SHM来说,仅仅知道如何计算损伤后的电导率变化是不够的,知道如何确定导致观察到的电导率变化的机械损伤对SHM来说更有价值。在本文中,我们通过研究EIT方法生成的电导率变化数据,应用机器学习方法来确定材料试样上的损伤状态,即破碎孔的数量、半径和中心位置。我们的研究结果表明,机器学习方法可以通过分析电导率变化数据来准确有效地检测材料样品的损伤,这一结论对SHM领域具有重要意义,并将加快航空工业和机械工程等行业的损伤检测过程。
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引用次数: 5
The Doping of Alkali Metal for Halide Perovskites 卤化钙钛矿中碱金属的掺杂
Pub Date : 2020-03-28 DOI: 10.30919/esmm5f705
Jintian Jiang, Jing Xu, Huddoy Walter, A. Kazi, Daoyuan Wang, G. Wangila, M. Mortazavi, Chao Yan, Qinglong Jiang, Pine Bluff Arkansas Usa Physics
DOI: 10.30919/esmm5f705 Doping, introducing impurities in the materials, plays a critical role for junction formation in semiconductor. It directs the flow of charge carriers and improves their transport properties in the thin-film electronic devices including halide perovskite materials based optical-electric devices. Dopants can strongly modify electronic, optical and other properties of materials. Due to the relative smaller size,alkali metals play an important role for halide perovskite materials. In this review, recent research work on the doping of halide perovskite materials byalkali metals, especially the electrochemical doping, have been studied from the view of chemistry and physics.
掺杂,在材料中引入杂质,在半导体结形成中起着至关重要的作用。它在包括卤化物钙钛矿材料的光电器件在内的薄膜电子器件中指导载流子的流动并改善其输运特性。掺杂剂可以强烈地改变材料的电子、光学和其他性质。由于相对较小的尺寸,碱金属在卤化钙钛矿材料中起着重要的作用。本文从化学和物理的角度综述了近年来碱金属掺杂卤化钙钛矿材料的研究进展,特别是电化学掺杂。
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引用次数: 11
COVID-19: From Crude Oil to Medical Mask COVID-19:从原油到医用口罩
Pub Date : 2020-03-22 DOI: 10.30919/esmm5f766
Qinglong Jiang, Lun-Shan Lu
On March 17, 2020, cases of COVID-19, a disease caused by coronavirus, were reported to be increased over 1700 in a single day in USA, with 100 reported deaths among total cases about 6500 in all 50 States (Fig. 1a). At the same time, this COVID-19 has spread to almost all the countries on this planet with over 200,000 cases. In about three months over 8,000 reported cases of death (Fig. 1b). Unfortunately, we still cannot see the end of this dark road, at least in the next couple of months. We have managed to survive after other outbreaks: MERS-CoV, SARS, Ebola,and of course the flu. Fortunately, we have doctors, vaccinologists, chemists, nurses and many others fighting for us. Among them, there are American, Chinese, Indian, European, Japanese, Iranian, Korean...... There is no country boundary for the virus and there is no boundary for the scientists. Stay together, we will win; fight with each other, we will all lose. Materials and manufacturing, not only play an important role in industry and research, but also play a critical role in this battle against the virus. Fig. 2 shows a typical structure for
据报道,2020年3月17日,美国一天内COVID-19病例增加了1700多例,在所有50个州的6500例病例中,有100例报告死亡(图1a)。与此同时,新冠肺炎已经蔓延到世界上几乎所有国家,病例超过20万。在大约三个月内,报告的死亡病例超过8,000例(图1b)。不幸的是,至少在接下来的几个月里,我们仍然看不到这条黑暗道路的尽头。在其他疫情爆发后,我们成功地生存了下来:中东呼吸综合征冠状病毒、SARS、埃博拉病毒,当然还有流感。幸运的是,我们有医生、疫苗专家、化学家、护士和其他许多人为我们而战。其中,有美国、中国、印度、欧洲、日本、伊朗、韩国......病毒没有国界,科学家也没有国界。团结在一起,我们会赢;互相争斗,我们都会输。材料和制造业不仅在工业和科研中发挥着重要作用,而且在这场抗击病毒的斗争中发挥着关键作用。图2显示了典型的结构
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引用次数: 17
Recent Advances in Thermal Interface Materials 热界面材料的最新进展
Pub Date : 2020-03-08 DOI: 10.30919/esmm5f717
Jing Cao, Tzee Luai Meng, Xikui Zhang, N. Gong, Rahul Karyappa, Chee Kiang Ivan Tan, A. Suwardi, Qiang Zhu, Hongfei Liu
DOI: 10.30919/esmm5f717 In recent years, miniaturization and integration have become the development trends of electronic devices. With the power of electronic devices continuing to increase, the amount of heat generated is sharply increasing. Thermal interface material (TIM) can effectively improve heat transfer between two solid interfaces, and it plays an important role in the performance, service life and stability of electronic devices. In this case, higher requirements are put forward for thermal management, so much attention is also attached to the innovation and optimization of TIM. In this paper, recent research development of TIM is reviewed. Rheology-based modeling and design are discussed for the widely used polymeric TIMs. It is discussed for the effects of thermal conductive fillers on the properties of composites. Many studies have shown that some polymers filled with high thermal conductivity and low loss ceramics are well suitable for electronic packaging for device encapsulation. Until now, extensive attentions have been paid to the preparation of polymeric composites with high thermal conductivity for the application in electronic packaging. Finally, the problems are also discussed and the research directions of TIM in the future are prospected.
近年来,小型化和集成化已成为电子器件的发展趋势。随着电子设备功率的不断增加,产生的热量也急剧增加。热界面材料(TIM)可以有效改善两个固体界面之间的传热,对电子器件的性能、使用寿命和稳定性起着重要作用。在这种情况下,对热管理提出了更高的要求,因此TIM的创新和优化也受到了人们的重视。本文综述了近年来TIM的研究进展。讨论了广泛应用的聚合物TIMs基于流变学的建模和设计。讨论了导热填料对复合材料性能的影响。许多研究表明,一些填充有高导热性和低损耗陶瓷的聚合物非常适合用于电子封装器件封装。目前,制备高导热聚合物复合材料在电子封装领域的应用受到了广泛的关注。最后,对存在的问题进行了讨论,并对TIM未来的研究方向进行了展望。
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引用次数: 56
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ES Materials & Manufacturing
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