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Preparation and electromagnetic microwave adsorption performances of porous nanocomposite self-assembled by CoFe2 O4 nanoparticles and diatomite 二氧化钛与硅藻土自组装多孔复合材料的制备及其电磁微波吸附性能
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.20
Haodong Huang, M. He, O. Kotova, Y. Golubev, F. Dong, L. Gömze, E. Kurovics, Rui Lv, Shiyong Sun
The efficient nanocomposite of CoFe2O4 diatomite for electromagnetic microwave adsorption was assembled by CoFe2O4 nanoparticles (NPs) and diatomite via a simple citric acid-nitrate sol-gel auto-combustion method. The electronic microscopy results show that the magnetic CoFe2O4 NPs are uniformly dispersed in the surface and porous structure of diatomite to form stable CoFe2O4/diatomite nanocomposite. The magnetic and dielectric properties with various mass ratios of CoFe2O4 to diatomite was investigated. It was showed that nanocomposite of CoFe2O4/ diatomite has strong superparamagnetic and electromagnetic microwave absorbing properties with optimized conditions of coercive force of 837.07 Oe, the saturation magnetization of 96.5 emu/g, and the remanence ratio (Mr/Ms) of 0.52, respectively. The maximum reflection loss is -12dB, and <-10dB frequency ranges from 10Hz to 12Hz when the ratio of CoFe2O4 to Diatomite is 1:10. The results indicate that CoFe2O4/diatomite composites can be used as the highly efficient microwave absorption materials, which expanded the application field of diatomite-based functional nanomaterials.
采用简单的柠檬酸-硝酸盐溶胶-凝胶自燃烧法,将CoFe2O4纳米颗粒与硅藻土组装成用于电磁微波吸附的CoFe2O4纳米复合材料。电镜结果表明,磁性CoFe2O4纳米粒子均匀分散在硅藻土表面和多孔结构中,形成稳定的CoFe2O4/硅藻土纳米复合材料。研究了硅藻土与CoFe2O4质量比不同时的磁性和介电性能。结果表明,CoFe2O4/硅藻土纳米复合材料具有较强的超顺磁性和电磁微波吸收性能,其最佳矫顽力为837.07 Oe,饱和磁化强度为96.5 emu/g,剩磁比(Mr/Ms)为0.52。当CoFe2O4与硅藻土的比例为1:10时,最大反射损耗为-12dB, <-10dB的频率范围为10Hz ~ 12Hz。结果表明,CoFe2O4/硅藻土复合材料可作为高效微波吸收材料,拓展了硅藻土基功能纳米材料的应用领域。
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引用次数: 0
Insights into the applicability of the X-Ray phase quantification supported by SEM for the rock-forming silicates minerals in the basaltic lava flows 玄武岩熔岩流中形成岩石的硅酸盐矿物在扫描电镜支持下的x射线相定量的适用性
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.29
I. Gembitskaya, E. Kotova, I. Abdrakhmanov, E. Kurovics, L. Gömze
The authors present their results obtained from the study of the magmatic rock-forming mineral phase-relations. In the study a number of standard and modern instruments were used for sample analyses. These include the X-Ray Diffraction, Scanning Electron Microscopy, X-Ray microprobe analysis and laser-granulometry analytic method. A combination of these instruments is considered very robust in the study of magmatic mineral-phases. The dataset obtained through the use of X-Ray Diffraction in combination with a corrected calibration on the mono-mineral fractions plays a critical role in comparing series of volcanic basalts. This approach was chosen for comparison studies of the volcanics due to its optical precision in determining modes and petrographic characteristics of the basaltic rocks. This study has used basaltic rocks from the modern volcanic eruptions of the Tolbachik region in the Russian Federation. Studies of other additional basaltic rocks were conducted from 10 samples which represents the Etna eruption which occurred in 2001. This enabled us to constrain the diversity in the nature of basaltic rocks of these two events.
本文介绍了岩浆岩造岩矿物相关系的研究结果。在这项研究中,许多标准和现代仪器被用于样品分析。这些方法包括x射线衍射、扫描电子显微镜、x射线微探针分析和激光粒度分析法。这些仪器的组合在岩浆矿物相的研究中被认为是非常可靠的。通过x射线衍射结合单矿物组分的校正校准获得的数据集在比较一系列火山玄武岩中起着关键作用。由于该方法在确定玄武岩的模态和岩石学特征方面具有光学精度,因此选择该方法进行火山岩对比研究。这项研究使用了来自俄罗斯联邦托尔巴切克地区现代火山喷发的玄武岩。对另外10个代表2001年埃特纳火山喷发的样本进行了其他玄武岩的研究。这使我们能够限制这两个事件中玄武岩性质的多样性。
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引用次数: 2
Analcime-bearing rocks as advanced sorbents 含钙岩石作为高级吸附剂
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.26
D. Shushkov, O. Kotova, J. F. Ibrahim, M. Harja, L. Gömze, T. Shchemelinina, G. V. Ignatiev
The rational use of water and soil resources and their effective purification are actual scientific problems for modern society. Inexpensive and effective natural sorbents, zeolites, are widely used to solve environmental problems and improve the safety of the use of water and soil resources. This article presents results of our study of the sorption properties of analcime-bearing rocks in the north-east of the European part of Russia. Experiments and analytical studies were carried out using modern analytical equipment. The high sorption activity of these rocks with respect to radioactive elements (uranium, radium, thorium) was established. The simulated biogeosorbents based on analcime-bearing rocks and target microorganisms exhibited high sorption and destructive properties to oil products and phenols, ensured preservation and increased the growth of Chlorella vulgaris microalgae cells under stress conditions: with increased salinity and exposure to organic pollutants.
水土资源的合理利用及其有效净化是现代社会面临的现实科学问题。廉价有效的天然吸附剂沸石被广泛用于解决环境问题,提高水土资源的使用安全性。本文介绍了我们对俄罗斯欧洲部分东北部含铝岩石的吸附特性的研究结果。实验和分析研究使用现代分析设备进行。这些岩石对放射性元素(铀、镭、钍)具有较高的吸附活性。基于含钙岩石和目标微生物的模拟生物地吸附剂对油品和酚类具有较高的吸附和破坏性能,在盐度增加和有机污染物暴露的胁迫条件下,保证了普通小球藻微藻细胞的保存并促进了其生长。
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引用次数: 1
Rheology and strength of concrete made with recycled concrete aggregates as replacement of natural aggregates 用再生混凝土骨料代替天然骨料制成的混凝土流变学和强度
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.8
Z. Tahar, B. Benabed, E. Kadri, Tien-Tung Ngo, A. Bouvet
This paper presents the results of an experimental study carried out to evaluate the influence of the nature and the content of the recycled fine and coarse aggregates from concrete construction and demolition wastes on the rheological and strength properties of concrete. For this purpose, concretes mixtures were made with different percentages (15, 30, 50, 70 and 100%) of recycled sand and recycled gravel. Three different cement / admixture ratios were used. At fresh state, tests applied include slump, yield stress, plastic viscosity, air content and fresh density. Moreover, in order to follow the evolution of these properties over time, the tests were carried out at different times: directly after mixing, 30 minutes, 60 minutes and 90 minutes after completion of the mixing). At hardened state, compressive strength was determined at age of 7 and 28 days. The results show that, the properties of the concretes made with recycled aggregates depend up on the cement / admixture ratio and the substitution level of recycled aggregates. This means that there is indeed an influence of the recycled aggregates on the compatibility (physicochemical equilibrium) of the cement / admixture ratio. This influence is more noticeable on the sand than on the gravel. The results also show that, increasing the percentage of substitution of recycled aggregates in concrete mixture increases the yield stress and the plastic viscosity of fresh concrete. However, a decrease in the compressive strength was found with increasing the content of recycled aggregate.
本文介绍了一项试验研究的结果,以评估从混凝土建筑和拆除废物中回收的细骨料和粗骨料的性质和含量对混凝土流变学和强度性能的影响。为此,混凝土混合物采用不同比例(15%、30%、50%、70%和100%)的再生砂和再生砾石。使用了三种不同的水泥/外加剂比例。在新鲜状态下,应用的测试包括坍落度、屈服应力、塑性粘度、空气含量和新鲜密度。此外,为了跟踪这些性能随时间的变化,在不同的时间进行了测试:混合后直接,混合完成后30分钟,60分钟和90分钟)。在硬化状态下,分别在7天和28天测定抗压强度。结果表明,再生骨料混凝土的性能取决于水泥/外加剂比和再生骨料的替代水平。这意味着再生骨料确实对水泥/外加剂比的相容性(物理化学平衡)有影响。这种影响在沙子上比在砾石上更明显。结果还表明,增加再生骨料在混凝土混合料中的替代率,会增加新拌混凝土的屈服应力和塑性粘度。但随着再生骨料掺量的增加,抗压强度有所下降。
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引用次数: 3
Effects of tunnel-fire on load bearing capacity of tunnel-lining and surrounding rock mass. Part 2 (Sectional Calculation) 隧道火灾对隧道衬砌及围岩承载能力的影响。第二部分(分段计算)
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.16
Dániel Csanády, Olivér Fenyvesi, T. Megyeri
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引用次数: 0
Polynomial relationship of compaction properties of silicate-based RHA modified expansive soil for pavement subgrade purposes 道路路基用硅酸盐基RHA改性膨胀土压实特性的多项式关系
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.36
K. Onyelowe, M. Onyia, E. Onukwugha, Oscar C. Nnadi, I. Onuoha, Fazal E. Jalal
The effect of varying proportions of rice husk ash (RHA) on the compaction behaviour of modified soil has been investigated under laboratory conditions. Problematic soils exhibit undesirable characteristics that make them unsuitable for use as foundation materials due to their swell shrink properties. Clay dominant in montmorillonite and illite belongs to such group of soil due to the net negative cations at the surface when exposed to moisture. For this reason, such soils are modified in a stabilization process to improve their mechanical properties. In this research series of preliminary studies were carried out and it was discovered that the studied soil has 73.2% passing number 200 sieve, has liquid limit of 48% and plasticity index of 19%. This helped to classify the soil as A-7-6 soil according to AASHTO classification method. The soil was also classified as poorly graded soil and highly plastic. The dominant mineral is montmorillonite observed by scanning electron microscopy (SEM) method and due to its high affinity with moisture due to cation exchange, the soil swells and shrinks. The soil was treated with 2% to 30% by weight of solid with RHA and the results were observed. The results showed a steady decrease in the maximum dry density (MDD) of the RHA modified soil. The MDD did not reduce beyond the minimum value for clay soil, which is 1.20 g/cm3. The decrease recorded in MDD was due to smaller specific gravity compared to the soil. Conversely, the optimum moisture content increased due to moulding moisture demand of the isomorphic net negative cation exchange. Though the cementing property of the RHA was due to the silicate-based aluminosilicates that provided bonding of the treated material, the blend will need a filler material to achieve a more appropriate densification. Finally, mathematical relationships of a polynomial form were proposed that summarized the total compaction behaviour of the RHA modified soil.
在实验室条件下,研究了不同比例稻壳灰(RHA)对改性土压实性能的影响。有问题的土壤表现出不受欢迎的特性,由于它们的膨胀收缩特性,使它们不适合用作基础材料。以蒙脱土和伊利石为主的粘土,由于其在受潮时表面的净负离子,就属于这类土壤。由于这个原因,这种土壤在稳定过程中进行了改性,以改善其力学性能。本研究进行了一系列的初步研究,发现所研究的土壤200筛合格率为73.2%,液限为48%,塑性指数为19%。这有助于根据AASHTO分类方法将土壤分类为A-7-6土壤。土壤也被归类为差级土壤和高塑性土壤。通过扫描电镜(SEM)观察到,主要矿物是蒙脱土,由于阳离子交换,其与水分的亲和力高,土壤膨胀和收缩。在土壤中添加2% ~ 30%的RHA,观察结果。结果表明,RHA改良土壤的最大干密度(MDD)呈稳定下降趋势。粘土的MDD没有超过最小值1.20 g/cm3。MDD记录的减少是由于与土壤相比比重较小。相反,由于同构净负离子交换的成型水分需求,最佳水分含量增加。虽然RHA的胶结性能是由于硅酸盐基硅铝酸盐提供了处理材料的粘合,但共混物需要填充材料来实现更合适的致密化。最后,提出了一个多项式形式的数学关系,总结了RHA改性土的总压实行为。
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引用次数: 5
Effect of Bauxite Grain Size Distribution on Beneficiation and Improvement of Materials 铝土矿粒度分布对物料选矿及改进的影响
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.23
O. Kotova, I. Razmyslov, E. Kurovics, A. Lvovsky, L. Gömze
The rational use of the constituent aluminum-containing ores in the industry to create new functional materials is one of the promising trends of mineral processing and engineering. Chemical analysis was carried out by X-ray fluorescence method using Horiba MESA 500. Shimadsu XRD-6000 device was used for X-ray diffraction analysis. The particle size distribution was determined by LS 13 320 XR laser particle size analyzer (Beckman Coulter). We compared results of X-ray phase and granulometric analyses. It was shown that the technology of deep fractionation of particles of high-iron bauxites and kaolinite clays improved the quality of raw materials and efficiency of use of minerals in enrichment processes and various industries, when creating functional materials.
在工业上合理利用含铝矿石成分,制造新型功能材料,是选矿与工程的发展趋势之一。化学分析采用x射线荧光法,仪器为Horiba MESA 500。x射线衍射分析采用Shimadsu XRD-6000装置。采用LS 13320 XR激光粒度分析仪(Beckman Coulter)测定其粒度分布。我们比较了x射线相分析和颗粒分析的结果。结果表明,高铁铝土矿和高岭石粘土颗粒深度分选技术在制造功能材料时,提高了原料质量和选矿过程中矿物的利用效率。
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引用次数: 0
Thermal and mechanical properties of fabricated plaster of Paris filled with groundnut seed coat and waste newspaper materials for structural application 以花生种皮和废报纸材料填充结构用巴黎石膏的热力学性能
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.12
U. Robert, S. Etuk, Asuquo Iboh Ubong, G. Umoren, O. Agbasi, Z. Abdulrazzaq
This work sought to assess the suitability of using boards produced with plaster of Paris (P.O.P) and various weight proportions of groundnut seed coat (GSC) as well as P.O.P and similar proportions of waste newspaper paste (WNP) as ceiling in building design. The results obtained from the investigation of thermal and mechanical properties of the fabricated boards revealed that with the use of GSC as filler, the samples were of higher mean values of specific heat capacity, thermal conductivity, thermal absorptivity, but lower mean values of bulk density, thermal diffusivity, percentage water absorption, flaking concentration and flexural strength when compared to the samples with similar proportions of WNP as filler content. Also, the sample with 13.8% content of GSC and the one containing 22.5% of WNP were found to exhibit an impressive performance. Generally, it was observed that the samples filled with either GSC or WNP were lighter than pure P.O.P samples and the recorded values for all the measured properties favoured them for use as ceiling material in buildings. It is noteworthy that the proportion of the filler can be adjusted for optimum performance of such environmentally-friendly and cost-effective ceilings. Utilizing groundnut seed coat and waste newspapers as filler materials in fabrication of P.O.P ceiling can help to reduce environment pollution level, ensure better thermal insulation of buildings and solve the lingering problem of high cost of using P.O.P or other conventional materials as ceiling in buildings by the end-users.
这项工作旨在评估在建筑设计中使用巴黎石膏(P.O.P)和不同重量比例的花生种皮(GSC)以及P.O.P和类似比例的废报纸糊(WNP)制成的板作为天花板的适用性。热力学性能研究结果表明,与WNP含量相同的材料相比,GSC作为填料的材料具有更高的比热容、导热系数、吸热系数平均值,而体积密度、热扩散系数、吸水率、剥落浓度和抗弯强度的平均值较低。此外,GSC含量为13.8%的样品和WNP含量为22.5%的样品表现出令人印象深刻的性能。一般来说,可以观察到,填充GSC或WNP的样品比纯P.O.P样品轻,所有测量特性的记录值都有利于它们用作建筑物的天花板材料。值得注意的是,填料的比例可以调整,以获得这种环保和经济高效的天花板的最佳性能。利用花生种皮和废报纸作为填充材料制作P.O.P吊顶,可以降低环境污染程度,保证建筑物的保温效果,解决最终用户使用P.O.P或其他传统材料作为建筑物吊顶成本高的问题。
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引用次数: 6
Strength and consistency behaviour of replacement of cement with silicate-based geopolymer cement modified soft soil treated with crushed waste glasses for pavement underlain 路面下垫层用碎玻璃处理的硅酸盐基地聚合物水泥改性软土替代水泥的强度和稠度特性
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.31
D. B. Van, K. Onyelowe, O. Onyia, M. Xuan, Lam Dao Phuc, Chidozie Ikpa, S. Yubonchit, A. Eberemu, K. Osinubi, A. B. Salahudeen, A. Amadi, M. Maduabuchi, Jesuborn Obimba-Wogu, I. Onuoha, Z. Saing
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引用次数: 1
Evaluation of index and compaction properties of lateritic soils treated with quarry dust based geopolymer cement for subgrade purpose 路基用采石场粉尘基地聚合物水泥处理红土的指标及压实特性评价
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2020-01-01 DOI: 10.14382/epitoanyag-jsbcm.2020.2
K. Onyelowe, D. B. Van, Lam Dao-Phuc, F. A. D. Onyelowe, Chidozie Ikpa, C. Ezugwu, A. B. Salahudeen, M. Maduabuchi, Jesuborn Obimba Wogu, K. Ibe, Light Ihenna
The effect of quarry dust based geopolymer cement on the index and compaction characteristics of soft problematic soils has been studied in the laboratory. The particular interest was on the geopolymer cement treatment of test problematic soils subgrade as hydraulically bound materials. In pavement foundation constructions, particular emphasis is always placed on how moisture suction and capillary actions affect the performance of the subgrade layer. Lateritic soils, which form the compacted foundation of pavements have the tendency to behave like plastics or liquids when in contact with moisture. These factors affect substantially the behavior and overtime performance, which is the durability of pavement subgrades. The primary aim of this research work was to adapt geopolymer cement synthesized from valorized solid waste materials (quarry dust and metallurgical slag). Laboratory experiments were used in this study. The test soils were observed to belong to A-2-6, A-2-7 and A-7 soils according to AASHTO classification, which are highly plastic and expansive. They are also of high clay content, a property which makes them unsuitable as moisture bound materials in foundations. The quarry dust based geopolymer cement was utilized at the rate of 10 to 150% by weight of dry soil in an increment of 10%. The test soils treatment protocol shows that the additive consistently improved the plasticity index and maximum dry density of the treated soils obtained at optimum moisture condition. The results have shown that the environmentally friendly cement derived from the valorization of solid waste has improved the properties of the compacted earth utilized under moisture bound environment. So, it stands as a good replacement for ordinary cement.
在室内研究了采石场粉尘基地聚合物水泥对软质问题土的指标和压实特性的影响。特别感兴趣的是地聚合物水泥处理试验问题土壤路基作为水力结合材料。在路面基础施工中,特别强调的是吸湿作用和毛细作用如何影响路基层的性能。红土是夯实路面的基础,当与水分接触时,红土的行为倾向于像塑料或液体。这些因素在很大程度上影响着路面路基的行为和耐久性。本研究工作的主要目的是利用固体废物(采石场粉尘和冶金渣)合成地聚合物水泥。本研究采用实验室实验。试验土按AASHTO分类属于A-2-6、A-2-7和A-7土,属于高塑性、高膨胀土。它们的粘土含量也很高,这一特性使它们不适合作为地基中的防潮材料。采石场粉尘基地聚合物水泥的利用率为干土重量的10 ~ 150%,增量为10%。试验土处理方案表明,在最佳水分条件下,添加剂对处理土的塑性指数和最大干密度均有显著提高。研究结果表明,固体废物再生的环保型水泥改善了湿约束环境下使用的压实土的性能。因此,它是普通水泥的良好替代品。
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引用次数: 18
期刊
Epitoanyag - Journal of Silicate Based and Composite Materials
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