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Effect of clay concentration on the mechanical properties and rheological behavior of ceramic slip 粘土浓度对陶瓷滑移体力学性能和流变特性的影响
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2022-01-01 DOI: 10.14382/epitoanyag-jsbcm.2022.19
Sahra Mahi, Labri Hammadi, N. Boudjenane
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引用次数: 0
Compressive strength and Scheffe’s optimization of mechanical properties of recycled ceramics tile aggregate concrete 再生瓷砖骨料混凝土抗压强度及Scheffe力学性能优化
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/epitoanyag-jsbcm.2021.14
E. Ambrose, F. Okafor, M. Onyia
Ceramic industry generates a large amount of wastes which are presently not reused in any significant quantity. Reusing these wastes in concrete could solve the ceramic industry waste management problem and also lead to a more sustainable concrete industry. While the use of ceramic wastes as coarse aggregate has been extensively investigated, not much findings are available on its use as fine aggregate and there are presently no models for predicting the properties of ceramic wastes aggregate concretes. This study investigates effect of crushed recycled-ceramic tiles (CRT) fine aggregate content on compressive strength of concrete. Scheffe’s second degree polynomial models were also formulated for compressive strength, slump height and cost of CRT concrete. Results show that incorporation of CRT as fine aggregate improves the compressive strength of concrete and this increase is directly proportional to its content. Authors therefore recommend up to 100% replacement of conventional fine aggregate with CRT in concrete production. The formulated models could predict compressive strength, slump and cost of CRT concrete if the mix ratio is known and vice versa. Analysis of variance and normal probability plots of model residuals were used to test adequacy of the models, and the models were found to be adequate at 95% confidence level. With the model equations, sample optimization was carried out to obtain the most economical mix for certain predefined criteria and the results were promising. Several similar optimizations can be carried out using the formulated model equations for any desired criteria of the modeled responses.
陶瓷工业产生了大量的废物,而这些废物目前没有得到大量的再利用。在混凝土中再利用这些废物可以解决陶瓷工业废物管理问题,也可以促进混凝土工业的可持续发展。陶瓷废料作为粗骨料的研究已经广泛开展,但陶瓷废料作为细骨料的研究还不多,目前还没有预测陶瓷废料骨料混凝土性能的模型。研究了再生瓷砖细骨料掺量对混凝土抗压强度的影响。建立了CRT混凝土抗压强度、坍落度高度和成本的Scheffe二阶多项式模型。结果表明,CRT细骨料的掺入提高了混凝土的抗压强度,其提高程度与其掺入量成正比。因此,作者建议在混凝土生产中使用CRT代替100%的传统细骨料。所建立的模型可以预测CRT混凝土的抗压强度、坍落度和成本,如果配合比已知,反之亦然。采用方差分析和模型残差的正态概率图来检验模型的充分性,发现模型在95%置信水平下是充足的。根据模型方程进行了样品优化,在一定的预定条件下获得了最经济的组合,结果令人满意。对于模型响应的任何期望标准,可以使用公式模型方程进行几个类似的优化。
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引用次数: 6
Shear behaviour of silicate-based structural adhesives for timber 木材用硅酸盐基结构胶粘剂的剪切性能
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/EPITOANYAG-JSBCM.2021.12
Dániel Csanády, Olivér Fenyvesi
In timber structures, many joints are constructed with polymer adhesives and industrial timber by-products also contain polymer resins in huge amount. Majority of these adhesives are artificial polymers with big environmental footprints and lots of them have a negative effect on human health. Some natural or silicate-based adhesives are available in the construction industry, but their heat or water resistance are poor. Some of these types of adhesives have evolved but compounds contain some artificial polymer, and the heat resistance is worse than silicate-based in general. In this article, water-resistance and heat resistance have been investigated in the case of silicate-based binders. In order to be a benchmark, a PVA based industrial timber adhesive (as reference) was also tested. The shear strength of the bonded joints was tested and compared under wet and hot conditions. Reference silicate-based binder was modified with other silicate, acids or alkalines. The effect of modifiers on the solubility of binders was also investigated. As a result it was stated, that reference binder has a higher strength under normal conditions, but the modified silicate binders have better performance under wet and hot conditions. The modifiers can increase the shear strength, ductility, and water-resistance without decreasing the heat resistance and also makes the material quality more uniform. The silicate binders make a rough bond surface, which can pass the forces effectively between the components of specimens.
在木结构中,许多接缝都使用高分子胶粘剂,工业木材副产品中也含有大量的高分子树脂。这些粘合剂大多是人造聚合物,对环境的影响很大,其中许多对人体健康有负面影响。一些天然或硅酸盐基胶粘剂可用于建筑行业,但其耐热性或耐水性较差。这些类型的粘合剂中的一些已经发展,但化合物含有一些人造聚合物,并且耐热性一般比硅酸盐基差。本文研究了硅酸盐基粘结剂的耐水性和耐热性。为了作为基准,还测试了PVA基工业木材胶粘剂(作为参考)。对粘接接头进行了湿、热两种工况下的抗剪强度测试和比较。用其它硅酸盐、酸或碱对基准硅酸盐基粘结剂进行改性。研究了改性剂对粘合剂溶解度的影响。结果表明,标准粘结剂在正常条件下具有较高的强度,而改性硅酸盐粘结剂在湿热条件下具有较好的性能。改性剂可以在不降低材料耐热性的情况下提高材料的抗剪强度、延展性和耐水性,并使材料质量更加均匀。硅酸盐粘结剂形成了粗糙的粘结面,可以有效地传递试样组分之间的力。
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引用次数: 0
Sintering of Silica-Alumina Granular Materials and its Catalytic Properties 二氧化硅-氧化铝颗粒材料的烧结及其催化性能
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/epitoanyag-jsbcm.2021.19
A. S. Apkarian, L. Gömze, J. F. Ibrahim, S. Kulkov
In this work was developed a filtering material, where a granular glass-ceramic with a catalytically active layer applied as a carrier. The main component of the pellet batch is alkaline glass which made it possible to intensify the processes of melting and foaming of the molten glass. It has been defined physical and technical characteristic of granules and obtained that its density smaller 300 kg/m3 and strength under compression layers between 0.8-2.6 MPa. Taking into account the physical and technical characteristics of GCM granules, studies were carried out to determine the possibility of using them as filtering media with a catalytically active layer. This makes it possible not only to dispose of cullet, but also to create a highly efficient material from it, allowing water to be purified up to standards.
在这项工作中,开发了一种过滤材料,其中带有催化活性层的颗粒状玻璃陶瓷用作载体。球团的主要成分是碱性玻璃,这使得熔融玻璃的熔化和发泡过程得以加强。确定了颗粒的物理技术特性,得到了颗粒的密度小于300 kg/m3,压缩层强度在0.8 ~ 2.6 MPa之间。考虑到GCM颗粒的物理和技术特性,进行了研究,以确定将其用作具有催化活性层的过滤介质的可能性。这不仅可以处理鱼片,还可以从中制造出一种高效的材料,使水达到标准的净化。
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引用次数: 1
Durability against carbonation of concrete formulated with partial replacement of cement with marble powder 用大理石粉部分替代水泥配制的混凝土的耐碳化性
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/EPITOANYAG-JSBCM.2021.4
A. Merah, Benharzallah Krobba
The first objective of this study is the use of marble waste powder as a partial replacement for cement (CEM I 42.5) in concrete. Furthermore, the phenomenon of carbonation significantly influences the durability of reinforced concrete structures, in this context, the second objective of this work is the study of the effect of accelerated carbonation on the durability of concretes formulated with cement. Containing marble powder with different percentages. To achieve this objective, four concrete mixes containing 0%, 10%, 15% and 30% marble powder as a cement replacement by weight were prepared. These concrete mixes were subjected to accelerated carbonation to study their durability against this phenomenon. The series of tests is carried out to study the effect of replacing 10%, 20% and 30% of the cement with marble powder on the depth of carbonation and the compressive strength and compare it with traditional concrete. The result of the present study indicates that the depth of carbonation increases with the increase in the rate of replacement of the cement with marble powder (10% to 30%) and that the resistance to compression decreases slightly with the increase in the replacement. the compressive strength of the concrete remains within the acceptable range recommended by the regulations used in Algeria.
本研究的第一个目标是使用大理石废粉作为混凝土中水泥(CEM I 42.5)的部分替代品。此外,碳化现象显著影响钢筋混凝土结构的耐久性,在这种情况下,本工作的第二个目标是研究加速碳化对水泥配制的混凝土耐久性的影响。含不同百分比的大理石粉。为了实现这一目标,配制了四种混凝土混合物,分别含有0%、10%、15%和30%的大理石粉作为水泥的重量替代品。这些混凝土混合物经受加速碳化,以研究它们对这种现象的耐久性。通过系列试验研究了大理岩粉替代10%、20%、30%水泥对混凝土碳化深度和抗压强度的影响,并与传统混凝土进行了对比。本研究结果表明,随着大理岩粉水泥替代率(10% ~ 30%)的增加,碳化深度增加,抗压性能随替代率的增加略有下降。混凝土的抗压强度保持在阿尔及利亚使用的法规推荐的可接受范围内。
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引用次数: 0
Kinetics and products composition of catalytic hydration of ethylene oxide in the presence of layered double hydroxides 层状双氢氧化物存在下环氧乙烷催化水化的动力学和产物组成
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/EPITOANYAG-JSBCM.2021.2
E. Butenko, E. Kapustina, A. Kapustin
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引用次数: 1
Laboratory study of the effect of saturation degree on quality of fair-faced concrete surfaces 饱和度对清水混凝土表面质量影响的室内研究
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/epitoanyag-jsbcm.2021.17
K. Ajtayné Károlyfi, F. Papp
The concrete composition is one of the most significant factor influencing the quality of the fairfaced concrete surfaces. Practical experiences showed, that in case of architectural concrete slightly oversaturated concrete mixtures result in higher quality surfaces. In this work the surface quality of fair-faced concrete samples was examined depending on the saturation degree of the cement paste and the dimensions of the mould. The main evaluation aspects were the surface void ratio, the discoloration, the honeycomb and bleeding. The surface void ratio was obtained by using digital image processing techniques, while the other surface irregularities were examined using manual methods. The concrete samples were classified according to the Austrian and German guidelines. The effect of saturation degree on the mechanical properties of the concrete was also studied. Results show that the increase in saturation degree of cement paste improves significantly the surface quality, while the dimensions of the mould have a reduced, but also a positive effect. In the meantime, there is a decrease in the mechanical properties of the concrete.
混凝土成分是影响清水混凝土表面质量的重要因素之一。实践表明,在建筑混凝土微过饱和情况下,混凝土混合料的表面质量较高。在这项工作中,根据水泥膏体的饱和度和模具的尺寸,检查了清水混凝土样品的表面质量。主要评价方面为表面空隙率、变色、蜂窝状和出血。表面空隙率采用数字图像处理技术,其他表面不规则性采用人工方法检测。根据奥地利和德国的指导方针对混凝土样品进行分类。研究了饱和程度对混凝土力学性能的影响。结果表明,水泥浆体饱和度的增加明显改善了表面质量,而模具尺寸减小,但也有积极的影响。同时,混凝土的力学性能有所下降。
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引用次数: 2
In-situ carbonization of natural zeolite-alumina composite materials incorporated sawdust 天然沸石-氧化铝复合材料的原位碳化研究
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/epitoanyag-jsbcm.2021.20
J. F. Ibrahim, A. S. Apkarian, M. Tihtih, S. Kulkov, L. Gömze
This research study investigates the potential use of traditional raw materials to synthesize new ceramic composite materials that can be used in different industrial applications. The composite materials were developed through mechanical activation, carbonization, and reactive sintering techniques. Natural zeolite from Tokaj region, alumina from Motim, and sawdust were used as starting raw materials. Stoichiometric amounts of the raw materials were mixed and milled in planetary ball milling followed by uniaxially pressing to produce cylindrical ceramic discs. The produced green ceramics were then sintered in an electric laboratory kiln under an oxygen-free environment at 1200 °C. In-situ carbonization of the sawdust was confirmed via X-ray diffraction. The thermal properties were also investigated by derivatography. The produced ceramic specimens were tested on microstructural characteristics, porosity, density, and water absorption.
本研究探讨了传统原料合成新型陶瓷复合材料的潜在用途,可用于不同的工业应用。复合材料是通过机械活化、炭化和反应烧结技术制备的。以托卡伊地区的天然沸石、Motim地区的氧化铝和锯末为起始原料。将化学计量量的原料混合,在行星球磨中研磨,然后进行单轴压榨,生产圆柱形陶瓷圆盘。然后在实验室电窑中,在1200°C无氧环境下进行绿色陶瓷烧结。通过x射线衍射证实了木屑的原位碳化。用衍生法研究了其热性能。对制备的陶瓷试样进行了显微结构特征、孔隙率、密度和吸水性测试。
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引用次数: 0
Effect of different supplementary cementitious materials and superplasticizers on rheological behavior of eco-friendly mortars 不同补充胶凝材料和高效减水剂对环保砂浆流变特性的影响
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/epitoanyag-jsbcm.2021.18
S. Safiddine, H. Soualhi, B. Benabed, A. Belaidi, E. Kadri
The drive towards using eco-friendly binders with increasing proportion of supplementary cementitious materials (SCMs) will lead to the development of more complex mixtures. However, the availability of fly ash (FA) would not cover future needs due to restrictions on the combustion of coal in power plants. Accordingly, the addition of limestone filler (LF) has an inherent advantage throughout the world of its availability in large deposits. The first main aim of this study was to determine the effect of high-volume LF used as Portland cement replacement with up to 60% on the rheological properties of cement mortar compared to the FA and the slag (BFS). Unlike FA and BFS, an increase in LF replacement reduced the rheological properties of the mortar. The relationship obtained between relative solid concentration and rheological properties of mortar with different SCMs was reasonable. The second aim of this study was to determine the rheological behavior of the mortar with different superplasticizer (SP) admixtures. Three SP types were utilized, ether-polycarboxylic modified (SP1), phosphonate modified (SP2) and new generation of polycarboxylate (SP3), with various dosages. The results show that, SP2 reduced the rheological properties better than SP1 and SP3 with dosages of less than 1%.
随着补充胶凝材料(SCMs)比例的增加,使用环保粘合剂的动力将导致更复杂混合物的发展。然而,由于电厂对燃煤的限制,粉煤灰的可用性将无法满足未来的需求。因此,石灰石填料(LF)的添加在世界范围内具有其在大型矿床中的可用性的固有优势。本研究的第一个主要目的是确定与FA和矿渣(BFS)相比,作为波特兰水泥替代品的高容量LF对水泥砂浆流变特性的影响,其含量高达60%。与FA和BFS不同,LF替换量的增加降低了砂浆的流变性能。得到了不同粒径砂浆的相对固体浓度与砂浆流变性能之间的合理关系。本研究的第二个目的是确定砂浆与不同的高效减水剂(SP)外加剂的流变行为。采用三种不同剂量的聚羧酸酯,分别为醚聚羧酸酯改性(SP1)、膦酸酯改性(SP2)和新一代聚羧酸酯(SP3)。结果表明,当SP2用量小于1%时,SP2对材料流变学性能的降低效果优于SP1和SP3。
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引用次数: 0
Effects of poly-sal polymer and barite addition on rheological properties of algerian bentonite 聚硅聚合物和重晶石的加入对阿尔及利亚膨润土流变性能的影响
IF 0.7 Q4 MATERIALS SCIENCE, COMPOSITES Pub Date : 2021-01-01 DOI: 10.14382/EPITOANYAG-JSBCM.2021.1
Ilyes Bachir Belmehdi, A. Mellak, L. Hammadi
In this paper, we investigate the effect of Poly-Sal polymer and barite on the rheological properties of bentonite of Maghnia (western Algeria). The modified Cross model is used to fit the stationary flow curves of bentonite at different concentrations of Poly-Sal add in base bentonite (4%) and the generalized model of Kelvin-Voigt is successfully applied to fit the creep and recovery data and to analyze the viscoelastic properties of the mixture Bentonite-Barite. Finally, the thixotropic behavior studied of the mixture Bentonite-Barite at constant temperature is analyzed by using a structural kinetic model (SKM) in order to account for the time dependent effect. It is demonstrated that the increase in quantity of barite in base bentonite induces a restructuring and reorganization of the particles of the bentonite at the microstructural level.
本文研究了聚铝聚合物和重晶石对阿尔及利亚西部Maghnia膨润土流变性能的影响。采用改进的Cross模型拟合了膨润土中不同浓度聚盐(4%)的稳态流动曲线,并成功地应用Kelvin-Voigt广义模型拟合了蠕变和恢复数据,分析了膨润土-重晶石混合物的粘弹性特性。最后,利用结构动力学模型(SKM)分析了膨润土-重晶石混合物在恒温下的触变行为,以考虑时间依赖效应。结果表明,重晶石在碱性膨润土中含量的增加引起了膨润土颗粒在微观结构水平上的重构和重组。
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引用次数: 2
期刊
Epitoanyag - Journal of Silicate Based and Composite Materials
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