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Development in Mechanical and Fatigue Properties of AA6061/AL2O3 Nanocomposites Under Stirring Temperature (ST) 搅拌温度下AA6061/AL2O3纳米复合材料力学与疲劳性能的研究进展
Pub Date : 2021-08-26 DOI: 10.15587/1729-4061.2021.238588
Raad Mohammed Abed, A. Khenyab, H. J. Alalkawi
Aluminum is expected to remain the core material for many critical applications such as aircraft and automobiles. This is due to the high resistance to different environmental conditions, desired and manageable mechanical properties, as well as high fatigue resistance. Aluminum nanocomposites such as AA6061/Al2O3 can be made in many ways using a liquid metallurgy method. The main challenges for this method in the production of nanocomposites are the difficulties of achieving a uniform distribution of reinforcing materials and possible chemical reactions between the reinforcing material and the matrix. For structural applications exclusive to aerospace sectors. The growing cost-effective nanocomposites mass production technology with essential operational and geometric flexibility is a big challenge all the time. Each method of preparing AA6061/Al2O3 nanocomposites can provide different mechanical properties. In the present study, nine nanocomposites were prepared at three stirring temperatures (800, 850, and 900 °C) with the level of Al2O3 addition of 0, 5, 7, and 9 wt %. The results of tensile, hardness and fatigue tests revealed that the composite including 9 wt % Al2O3 with 850 °C stirring temperatures has the best properties. It was also revealed that the 850 °C stirring temperature (ST) with 9 wt % Al2O3 composite provide an increase in tensile strength, VHN and reduction in ductility by 20 %, 16 % and 36.8 % respectively, compared to zero-nano. Also, the fatigue life at the 90 MPa stress level increased by 17.4 % in comparison with 9 wt % nanocomposite at 800 °C (ST). Uniform distributions were observed for all nine microstructure compositions.
预计铝仍将是许多关键应用的核心材料,如飞机和汽车。这是由于高耐不同的环境条件,理想的和可控的机械性能,以及高抗疲劳性。铝纳米复合材料如AA6061/Al2O3可以通过多种方法使用液体冶金方法制备。这种方法在生产纳米复合材料时面临的主要挑战是难以实现增强材料的均匀分布以及增强材料与基体之间可能发生的化学反应。专用于航空航天领域的结构应用。随着纳米复合材料的大规模生产技术的不断发展,其成本效益和几何灵活性一直是一个巨大的挑战。制备AA6061/Al2O3纳米复合材料的不同方法可以提供不同的力学性能。在本研究中,在三种搅拌温度(800、850和900℃)下制备了9种纳米复合材料,Al2O3的添加量分别为0、5、7和9 wt %。拉伸、硬度和疲劳试验结果表明,添加9wt % Al2O3的复合材料在850℃搅拌温度下具有最佳性能。与零纳米相比,850°C搅拌温度(ST)和9wt % Al2O3复合材料的抗拉强度、VHN和塑性分别提高了20%、16%和36.8%。在800℃(ST)温度下,与9wt %纳米复合材料相比,90mpa应力水平下的疲劳寿命提高了17.4%。9种显微组织组成均呈均匀分布。
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引用次数: 3
Improvement of the Extruder Body Design in Order To Increase Reliability and Quality of Extrusion 改进挤出机本体设计,提高挤出的可靠性和质量
Pub Date : 2021-07-27 DOI: 10.15587/2706-5448.2021.237539
I. Kazak
The article highlights one of the ways to improve the design of the extruder body in order to increase the reliability and, at the same time, the quality of extrusion. The object of research is a single-worm extruder. One of the most problematic areas of the extruder is the body. The main disadvantage of the extruder is the wear of the body surfaces due to corrosion or abrasion and requires regular replacement. This is due to the abrasive properties of the polymers and, accordingly, due to the friction of the polymer material against the body and the worm, especially due to contamination in the recycled material. In various sources, the replacement of the extruder worm with a more advanced design is widely covered. And scientists do not pay enough attention to improving the body of the extruder, which indicates the relevance of this study. That is why the problem of increasing the reliability of the extruder body is completely unsolved and urgent. In the course of the study, we used an analysis of the structural features of the extruder body, a literature-patent review of existing methods for improving the body of a single-worm extruder to increase the reliability and, at the same time, the quality of extrusion. As a result of the literature and patent review, the option of improving the extruder body based on the prototype of the split body, which additionally contains an inner surface of steel ribbed plates, was selected. It was found that the ribbing of the plates on the inner surface of the body increases the wear resistance of the body and promotes more intensive advancement of the polymer used material to the extruder head. This is due to the fact that the proposed improved body of the extruder has a number of features: steel ribbed plates rigidly fixed inside it are installed with overlap of the parting line of the extruder body. This makes it possible to increase the wear resistance and, accordingly, the reliability of the extruder body and, additionally, the extrusion quality. Compared with the known one-piece structures of the extruder body, the design of the body is detachable with steel rigidly mounted ribbed plates on the inner surface, which will simplify maintenance during repairs and, at the same time, improve the quality of extrusion.
本文重点介绍了改进挤出机本体设计的方法之一,以提高挤出机的可靠性,同时提高挤出质量。研究对象为单蜗杆挤出机。挤出机最容易出问题的地方之一就是机身。挤出机的主要缺点是机体表面因腐蚀或磨损而磨损,需要定期更换。这是由于聚合物的磨蚀性能,因此,由于聚合物材料与机体和蠕虫的摩擦,特别是由于回收材料中的污染。在各种来源中,用更先进的设计替代挤出机蜗杆被广泛报道。而科学家对改进挤出机本体的重视程度不够,这说明了本研究的相关性。这就是为什么提高挤出机本体可靠性的问题是完全没有解决的和紧迫的。在研究过程中,我们对挤出机本体的结构特征进行了分析,对现有的改进单蜗杆挤出机本体的方法进行了文献专利审查,以提高可靠性,同时提高挤出质量。根据文献和专利审查的结果,选择了在分体原型的基础上改进挤出机体的选项,该分体另外包含钢肋板的内表面。研究发现,在挤出机机体内表面的板肋增加了机体的耐磨性,并促进了所用聚合物材料更密集地向挤出机头推进。这是由于所提出的改进挤出机本体具有以下几个特点:内部刚性固定的钢肋板安装在挤出机本体分型线的重叠处。这使得它有可能增加耐磨性,因此,挤出机本体的可靠性,另外,挤出质量。与目前已知的挤出机机身一体式结构相比,该机身采用可拆卸的设计,内表面采用钢刚性安装的肋板,简化了维修时的维护,同时提高了挤出质量。
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引用次数: 0
Estimation of the Error of the Simplified Algorithm of Processing of Functions of Deflations of Deformed Frames of Bodies of Rolling Stock 机车车体变形车架收缩函数处理简化算法的误差估计
Pub Date : 2021-07-27 DOI: 10.15587/2706-5448.2021.237296
Y. Horobets
The study is aimed at assessing the size of the error that arises when processing the results of examining the geometric characteristics of the bearing structures of rolling stock units using an algorithm without using trigonometric functions. The object of the research is a method of simplified alignment of the deflection function of body frame beams to the horizontal plane. One of the biggest problem areas is the lack of understanding by some customers of the work of the possibility of using this algorithm due to the lack of information about the errors that arise in the simplified calculation. The study was carried out by comparing the results of processing the initial data by two methods, obtained during the work on the inspection of the state of the supporting structures of the unit of the shunting diesel locomotive TGM6. One method, the algorithm of which is the subject of this study, assumes that no complex calculations are used during data processing. The second method involves the use of an algorithm for aligning the deflection functions of the body frame beams of a rolling stock unit of railways in the horizontal plane, taking into account all trigonometry tools, which will exclude the accompanying calculation errors of the simplified method. After processing the initial data, two sets of results were obtained – with the desired calculation error and without. Comparison of these datasets yielded an error value for frame tilt of 5.7. For clarity, the size of the error was compared with the expanded uncertainty values of the main sources of uncertainty in the methodology for examining the bearing structures of rolling stock. On the basis of the analysis of two methods of leveling the inclination to the horizontal plane of the deformed rolling stock body frame, the expediency of such an approach has been proved. The results obtained make it possible to reasonably use the Simplified approach to processing the data obtained during the survey of the geometric characteristics of the rolling stock. If necessary, the developed mathematical model can be used to improve the accuracy of calculating the uncertainty of measurements of geometric characteristics, as well as for use in the study of modification of existing or development of new measurement techniques.
该研究旨在评估在使用不使用三角函数的算法处理检查机车车辆单元轴承结构几何特征的结果时产生的误差大小。本文的研究对象是框架梁挠度函数在水平面上的简化对齐方法。最大的问题之一是,由于缺乏关于简化计算中出现的错误的信息,一些客户对使用该算法的可能性缺乏理解。对TGM6调车内燃机车机组支承结构状态检测工作中所获得的两种初始数据处理结果进行了对比研究。一种方法,其算法是本研究的主题,假设在数据处理过程中不使用复杂的计算。第二种方法涉及使用一种算法来对准铁路机车车辆单元的车身框架梁的挠度函数在水平面上,考虑到所有的三角工具,这将排除伴随的简化方法的计算误差。在对初始数据进行处理后,得到了两组结果——具有期望的计算误差和没有计算误差。这些数据集的比较得出帧倾斜的误差值为5.7。为了清楚起见,将误差的大小与检查机车车辆轴承结构的方法中主要不确定源的扩展不确定值进行了比较。通过对变形车体框架的两种倾斜度调平方法的分析,证明了这种方法的方便性。所得结果为合理地利用简化方法对机车车辆几何特性调查数据进行处理提供了可能。如有必要,所建立的数学模型可用于提高几何特性测量不确定度计算的准确性,也可用于研究现有测量技术的改进或开发新的测量技术。
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引用次数: 0
Synthesis of New Immobilized N-Chloro-Sulfonamides and Release of Active Chlorine From Them 新型固定化n -氯磺酰胺的合成及活性氯的释放
Pub Date : 2021-07-23 DOI: 10.21303/2461-4262.2021.001929
B. Murashevych, V. Toropin, D. Stepanskyi, H. Maslak, K. Burmistrov, V. Kotok, V. Kovalenko
A method has been developed for the synthesis of granular polymeric materials with immobilized N-chloro-sulfonamide groups. Commercially available resin polymers widely applied for the preparation of ion exchangers have been used as polymer carriers. The elaborated technological conditions make it possible to modify these resins with a high conversion degree, without deteriorating the strength characteristics, and with the possibility of regulating the concentration of active chlorine over a wide range (up to 11 % w/w). The structure of the synthesized polymers was confirmed by IR spectroscopy data. To determine the concentration of functional groups, a special method of iodometric titration has been developed. The processes of emission of active chlorine from synthesized polymers into aqueous solutions have been studied. It has been shown that this process significantly depends on the composition of the solution: no release of active chlorine into distilled water is observed, and when using tap water, its concentration is reached 5–8 mg/dm3 and remains up to 30 days when the granules are in water. The processes of activation of active chlorine emission by compounds of amine nature have been studied, the corresponding kinetic curves of the dependence between change in the concentration of active chlorine in solution and the used activator are presented. It has been found that the nature of the used activator strongly affects, among other things, the stability of the obtained chlorine-active solutions. Taurine and sulfamic acid are found to be the optimal activators for obtaining stable solutions of active chlorine of high concentration. The composition of the N-chloro-taurin solution obtained in this way has been additionally analyzed by UV spectroscopy. Thus, the synthesized polymers make it possible to quickly in situ obtain high-purity solutions of active chlorine without the use of special electrochemical equipment. The polymers themselves are compact, stable, and can be repeatedly regenerated
提出了一种合成固定n -氯磺胺基颗粒状高分子材料的方法。广泛用于离子交换剂制备的市售树脂聚合物已被用作聚合物载体。详细阐述的技术条件使改性这些树脂具有高转化率,而不恶化的强度特性,并有可能调节活性氯的浓度在一个大范围内(高达11% w/w)。红外光谱数据证实了合成聚合物的结构。为了测定官能团的浓度,发展了一种特殊的碘量滴定法。研究了合成的聚合物向水溶液中释放活性氯的过程。研究表明,这一过程在很大程度上取决于溶液的组成:没有观察到活性氯释放到蒸馏水中,当使用自来水时,其浓度达到5-8 mg/dm3,当颗粒在水中时,其浓度可保持长达30天。研究了胺类化合物活化活性氯释放的过程,给出了溶液中活性氯浓度变化与所用活化剂关系的动力学曲线。人们发现,所使用的活化剂的性质,除其他外,强烈影响所获得的氯活性溶液的稳定性。牛磺酸和氨基甲酸是获得稳定的高浓度活性氯溶液的最佳活化剂。用紫外光谱法分析了用这种方法得到的n -氯牛磺酸溶液的组成。因此,合成的聚合物可以在不使用特殊电化学设备的情况下快速就地获得高纯度的活性氯溶液。聚合物本身致密、稳定,并且可以反复再生
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引用次数: 5
Improving Pastille Manufacturing Technology Using the Developed Multicomponent Fruit and Berry Paste 利用研制的多组分果莓糊改进制粒工艺
Pub Date : 2021-06-30 DOI: 10.15587/1729-4061.2021.231730
K. Kasabova, A. Zagorulko, Andreii Zahorulko, N. Shmatchenko, Olga Simakova, I. Goriainova, O. Volodko, D. Mironov
A method for manufacturing multicomponent fruit and berry paste based on apples, cranberries, hawthorn with a high content of pectin substances has been improved. A special feature of the technique is the concentration in a rotary film apparatus until a dry matter content of 28... 30 % under a mild mode during 25...50 s provided that the puree is preheated to 50 °C. The limiting shear stress for each type of raw material and the effective viscosity index for the samples of the formulations of the studied pastes have been established. It was found that the best properties are demonstrated by composition with the following formulation ratio of components: apple – 50 %; cranberries – 40 %; hawthorn – 10 %. That makes it possible to obtain pastes with the best chemical composition (the higher content of pectin substances, organic acids, ascorbic acid, etc.). The rational amount of adding 75 % of fruit and berry paste to replace apple puree has been determined and substantiated. That makes it possible to manufacture pastille with a high degree of structure formation, which is confirmed by the viscosity index of 616 Pa∙s, compared with control – 354 Pa∙s. A decrease in the mass fraction of dry substances by 5.0 %, an increase in acidity and reducing substances are ensured, which meets the requirements set by regulatory documents. This amount of paste provides for excellent organoleptic properties, i.e. it gives the products an even red color, pleasant taste, and smell. The developed technology expands the range of "healthy food" by partially replacing raw materials with a low content of physiologically functional components with a multicomponent composition, as well as provides for an increase in the pastille nutritional value. The use of sparing modes of concentration makes it possible to intensify the process of manufacturing a multicomponent paste, which indicates energy and resource-saving technology.
改进了一种以苹果、蔓越莓、山楂为原料,高含量果胶物质的多组分水果浆果酱的生产方法。该技术的一个特点是在旋转膜装置中浓缩,直到干物质含量为28…在温和模式下30%在25…如果果泥预热到50°C,则为50 s。建立了各种原料的极限剪切应力和膏体配方样品的有效粘度指数。结果表明:苹果- 50%为最佳配比;蔓越莓- 40%;山楂- 10%。这使得获得具有最佳化学成分(果胶物质、有机酸、抗坏血酸等含量较高)的浆料成为可能。确定并证实了以75%的果莓酱代替苹果泥的合理用量。这使得生产具有高度结构形成度的颗粒成为可能,这一点通过粘度指数616 Pa∙s得到证实,而对照组为354 Pa∙s。干燥物质的质量分数降低5.0%,酸度和还原性物质的增加得到保证,符合法规文件的要求。这种数量的糊状物提供了优异的感官特性,即它使产品具有均匀的红色,令人愉悦的味道和气味。开发的技术扩大了“健康食品”的范围,用多组分组成部分替代低含量生理功能成分的原料,并增加了颗粒的营养价值。节约浓缩方式的使用使多组分浆料的制造过程得以加强,这是一种节能和资源节约技术。
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引用次数: 10
Studying the Influence of Mungbean Use on the Structure-Forming Indicators of Meat-Plant Systems Based on Veal, Pork, Chicken Meat 研究绿豆用量对以小牛肉、猪肉、鸡肉为原料的肉类-植物系统结构形成指标的影响
Pub Date : 2021-06-30 DOI: 10.15587/1729-4061.2021.234987
Y. Biletska, T. Ryzhkova, V. Novikova, R. Plotnikova, I. Hnoievyі, I. Yatsenko, Katerina Silchenko, T. Danilova, R. Severin, Lyudmila Karpenko
This paper reports a study into the use of germinated mungbean as a promising raw material influencing the structure-forming indicators of meat systems during the production of meat-vegetable sausages. The content of iodine in the germinated mungbean and its anatomical parts has been examined using solutions of potassium iodide. A change in the phytic acid content and size of phytin globoloids has been established in mungbean malt depending on germination conditions. The influence of flour from germinated mungbean on the moisture-binding, moisture-retaining, fat-retaining abilities, as well as on the pH of meat systems based on veal meat, pork, chicken has been investigated.The reported set of studies is important as the defined patterns could make it possible to devise technologies for meat-vegetable sausages, to expand the range of enriched meat products.The result of this study has established that the degree of biotransformation of iodine into beans is influenced by the protein content in the native beans. Almost 90...95 % of iodine is accumulated in the cotyledons of beans in the protein fraction, 5...10 % ‒ in sprouts and roots. The rational range of potassium iodide concentrations in the germination solution is 76.5 g per 1,000 cm3, over 48 hours. Prolonging the germination time leads to microbiological damage to the bean mass.The germination process affects the reduction of phytic acid content, which is confirmed by a decrease in the diameter of phytin globoloids.It is rational to use in meat systems based on pork meat and veal meat 10 % of the developed flour by reducing meat raw materials. With this ratio of formulation ingredients, the maximum increase in the moisture-binding, moisture-retaining, and fat-retaining capacities of these meat systems is achieved. In the meat systems based on chicken meat, it is possible to increase a replacement part of up to 15 %.The reported set of studies is useful and important because it could form the basis for devising the technologies of meat-vegetable sausages to meet the needs of different segments of consumers
本文报道了利用发芽绿豆作为一种有前途的原料,在肉-蔬菜香肠生产过程中影响肉类体系结构形成指标的研究。用碘化钾溶液测定了发芽绿豆及其解剖部位的碘含量。绿豆麦芽中植酸含量和植素球状体大小的变化取决于发芽条件。研究了发芽绿豆粉对小牛肉、猪肉、鸡肉等肉质体系的保湿、保湿、保脂性能及pH值的影响。报道的这组研究很重要,因为确定的模式可以使设计肉-蔬菜香肠的技术成为可能,以扩大强化肉制品的范围。本研究的结果表明,碘在豆类中的生物转化程度受原生豆类中蛋白质含量的影响。近90…在大豆的蛋白质部分中,95%的碘积累在子叶中。10% -在芽和根中。48小时内,萌发液中碘化钾的合理浓度范围为76.5 g / 1,000 cm3。延长发芽时间会对豆块造成微生物损害。发芽过程影响植酸含量的降低,这一点可以通过植酸球状体直径的减小来证实。通过减少肉类原料,在以猪肉和小牛肉为基础的肉类体系中使用10%的发达面粉是合理的。有了这个配方成分的比例,最大限度地增加了这些肉类系统的防潮、保湿和保脂能力。在以鸡肉为基础的肉类系统中,可以增加高达15%的替换部分。报告的一系列研究是有用和重要的,因为它可以形成设计肉-蔬菜香肠技术的基础,以满足不同消费者群体的需求
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引用次数: 1
Comparing the Effect of Nanoclays on the Water-Resistance of Intumescent Fire-Retardant Coatings 纳米粘土对膨胀型防火涂料耐水性影响的比较
Pub Date : 2021-06-18 DOI: 10.15587/1729-4061.2021.232822
L. Vakhitova, Kostyantyn Kalafat, V. Plavan, V. Bessarabov, Nadezhda Тaran, G. Zagoriy
This paper reports a study into the effect of nanoclays on the water-resistance of the intumescent system ammonium polyphosphate/melamine/pentaerythritol/titanium dioxide/polymer (ethylene vinyl acetate (EVA) or styrene acrylate (SA). It has been established that adding nanoclay to a coating based on ethylene vinyl acetate increases the fire resistance limit of a metal plate by 30 %, and to a coating based on styrene acrylate – by 50 %. At the same time, coatings that include the EVA polymer are characterized by greater fire-retardant efficiency and less water resistance than coatings containing the SA polymer. It has been shown that intumescent coatings, regardless of the nature of the polymer, under the conditions of 80 % humidity over 800 days their reduce fire-protective properties by an average of 10 %. The loss of coating fire resistance occurs due to the leaching of pentaerythritol, ammonium polyphosphate, and polymer degradation by hydrolysis. The admixtures of nanoclays with a high degree of exfoliation to the studied system create a barrier effect and maximize the chemical formulation of the intumescent coating. The fireproof properties of coatings with organically-modified montmorillonite admixtures are maintained or reduced to 5 % under the conditions of 80 % humidity over 800 days. It has been determined that the direct effect of water on the coating over a period of more than 2 days leads to a significant decrease in the swelling coefficient of intumescent coatings, regardless of the content of a nanoclay admixture in their composition. At the same time, the half-decay period of coatings without nanoclay, calculated on the basis of solubility constant in water, is 0.5 days. For coatings, which include the admixtures of organically-modified nanoclays, the half-decay period increases to 2 days. The results reported in this paper could be recommended for designing water-proof fire-resistant reactive-type nano-coatings with prolonged service life.
研究了纳米粘土对聚磷酸铵/三聚氰胺/季戊四醇/二氧化钛/聚合物(醋酸乙烯酯(EVA)或丙烯酸苯乙烯(SA))膨胀体系耐水性能的影响。研究表明,在醋酸乙烯基涂层中添加纳米粘土可使金属板的耐火极限提高30%,在丙烯酸苯乙烯基涂层中添加纳米粘土可使金属板的耐火极限提高50%。同时,与含有SA聚合物的涂料相比,含有EVA聚合物的涂料具有更高的阻燃效率和更低的耐水性。研究表明,无论聚合物的性质如何,在湿度为80%的条件下,超过800天,膨胀涂层的防火性能平均降低10%。由于季戊四醇、聚磷酸铵的浸出和聚合物的水解降解,涂层的耐火性能下降。将高度剥落的纳米粘土掺合到所研究的体系中,可以产生屏障效应,最大限度地提高膨胀涂层的化学成分。采用有机改性蒙脱土外加剂的涂料在湿度为80%的条件下,800天以上的防火性能保持或降低到5%。已经确定,在超过2天的时间里,水对涂层的直接影响导致膨胀涂层的膨胀系数显著降低,而不管其组成中纳米粘土混合物的含量如何。同时,根据纳米粘土在水中的溶解度常数计算,无纳米粘土涂层的半衰退期为0.5 d。对于含有有机改性纳米粘土外加剂的涂料,半衰退期增加到2天。本文的研究结果可为设计具有较长使用寿命的防水防火反应型纳米涂料提供参考。
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引用次数: 4
Laser Beam Melting of H13 Tool Steel: From the Evolution of Microstructure to Process Simulation 激光熔化H13工具钢:从组织演变到过程模拟
Pub Date : 2021-06-04 DOI: 10.2139/ssrn.3860221
L. Wu, F. Xia, W. Gridin, S. Leuders, F. Brenne, T. Niendorf
H13, a multifunctional chromium-molybdenum carbon steel, is widely used in hot work applications. Based on previous experimental evidence, H13 can be processed by additive manufacturing at elevated temperatures by applying appropriate laser parameters. The current investigation focuses on the evaluation of the microstructure in different heat treatment conditions, in particular evaluation of phases and defects from macro- to microscale, and on the corresponding mechanical properties. Furthermore, the mutual relations of composition, process conditions and resulting microstructures are studied. The experimentally confirmed parameters seem to be promising for both manufacturing of high-demanding components and for implementation within a mechanism-based simulation model for prediction of laser parameters for new alloys and other laser beam melting systems.
H13是一种多功能铬钼碳钢,广泛应用于热加工领域。根据以往的实验证据,通过适当的激光参数,可以在高温下对H13进行增材制造。目前的研究重点是评价不同热处理条件下的微观组织,特别是从宏观到微观的相和缺陷的评价,以及相应的力学性能。进一步研究了成分、工艺条件和微观组织之间的相互关系。实验证实的参数似乎对高要求部件的制造和基于机制的模拟模型的实施有希望,用于预测新合金和其他激光束熔化系统的激光参数。
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引用次数: 2
Fabrication and Testing of Carbon Foams by Kraft Lignin 硫酸盐木质素制备泡沫碳材料及其性能研究
Pub Date : 2021-03-15 DOI: 10.2139/ssrn.3805250
Q. Yan, R. Arango, Jinghao Li, Z. Cai
Carbon foams have been prepared using Kraft lignin as the solely resource. No catalysts, foaming/blowing agents, surfactants, and/or crosslinking agents are used for the foam preparation. The process includes pressing carbon foam precursors into molds followed by formation of lignin foam through heating and carbonization/graphitization of the lignin derived foams. The resultant lignin carbon foam (LCF) has an open-cell structure with densities ranging from about 0.18 g/cm3 to 0.68 g/cm3. The compressive strengths of LCFs increase with increasing of bulk density, from 7.03 ± 1.25 MPa of LCF1 to 30.16 ± 2.41 MPa of LCF7, and thermal conductivity is strongly influenced by the bulk density with increase from 0.21±0.02 W/(m·K) to 0.75±0.01 W/(m·K). The bulk electrical conductivities of LCF samples increase with increasing of bulk densities from 701 S/m to 2031 S/m. The LCF samples were evaluated for resistance to fire and native subterranean termites. LCF samples exhibit excellent fire resistance, no damage occurred when the LCF sample was exposed to an oxyacetylenic flame in air over 1050 °C for more than 3 minutes. Termite testing showed no degradation to the LCF samples after the evaluation.
以硫酸盐木质素为唯一原料制备了泡沫炭。制备泡沫时不使用催化剂、发泡/发泡剂、表面活性剂和/或交联剂。该工艺包括将碳泡沫前体压入模具,然后通过加热和木质素衍生泡沫的碳化/石墨化形成木质素泡沫。所得木质素碳泡沫(LCF)具有开孔结构,密度范围约为0.18 g/cm3至0.68 g/cm3。LCF1的抗压强度为7.03±1.25 MPa, LCF7的抗压强度为30.16±2.41 MPa; LCF7的导热系数受容重的影响较大,容重从0.21±0.02 W/(m·K)增加到0.75±0.01 W/(m·K)。随着体积密度的增加,LCF样品的体积电导率从701 S/m增加到2031 S/m。对LCF样品进行了耐火性和地底白蚁性评价。LCF样品具有优异的耐火性,在1050°C以上的空气中暴露于氧乙炔火焰中3分钟以上无损伤。白蚁测试表明,评价后的LCF样品没有降解。
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引用次数: 0
Study of LMD of Inconel 718 on Inclined Planes: Influence of Inclination on Width and Height of Deposited Material 斜面上Inconel 718的LMD研究:倾角对沉积材料宽度和高度的影响
Pub Date : 2021-02-15 DOI: 10.2139/ssrn.3785875
M. Bold, J. Zielinski, S. Ziegler, J. Schleifenbaum
Laser Metal Deposition (LMD) as a repair technology has been established in recent times. A commonly used material for repairs of turbines are nickel-base alloys, such as Inconel 718 (IN718), which presents good mechanical properties at temperatures up to 650 °C and good corrosive resistance. Inclined or curved surfaces pose a challenge in repairing parts with LMD due to the dependence of height and width of deposited tracks on the local inclination angle. An extensive preparation on path planning is needed to prevent bond defects and to achieve good mechanical properties. The aim of this study is to gain a better understanding of the influence of the local angle between laser beam and component surface on the track geometry. In a first step, single tracks are deposited at various inclinations and process strategies. The track geometries are then evaluated by optical profilometry and metallographic analyses. In a second step, single layers consisting of overlapping tracks are deposited onto different inclined plates, and the welding strategy is varied as follows: a) horizontal overlapping tracks starting from the top going down, b) horizontal overlapping tracks starting from the bottom going up, c) overlapping tracks going up and down. The single layers are analysed metallographically to determine the influence of inclination angle and deposition strategy on the layer height. Furthermore, the influence of inclination on dilution of the base material and on defects such as pores and bonding defects is investigated. By studying the basis of LMD on inclined surfaces, the results presented in this paper help to improve and accelerate path planning for repairs by LMD on freeform surfaces and to design tool paths for the deposition of layers with uniform thickness.
激光金属沉积(LMD)是近年来建立起来的一种修复技术。用于涡轮机维修的常用材料是镍基合金,例如Inconel 718 (IN718),它在高达650°C的温度下具有良好的机械性能和良好的耐腐蚀性。由于沉积轨迹的高度和宽度与局部倾斜角的关系,倾斜或弯曲的表面对LMD修复零件构成了挑战。为了防止粘结缺陷和获得良好的力学性能,需要进行大量的路径规划准备。本研究的目的是为了更好地了解激光束与部件表面之间的局部夹角对轨道几何形状的影响。在第一步,单轨道沉积在不同的倾斜度和工艺策略。然后通过光学轮廓术和金相分析来评估轨道的几何形状。第二步,将由重叠轨迹组成的单层沉积在不同的倾斜板上,焊接策略如下:a)从顶部开始向下的水平重叠轨迹,b)从底部开始向上的水平重叠轨迹,c)上下重叠轨迹。对单层进行了金相分析,确定了倾角和沉积方式对层高的影响。此外,还研究了倾角对基材稀释度和气孔、粘结缺陷等缺陷的影响。通过研究倾斜曲面上LMD的基础,本文的研究结果有助于改进和加快自由曲面上LMD修复的路径规划,以及设计均匀厚度层沉积的刀具路径。
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引用次数: 1
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EngRN: Engineering Design Process (Topic)
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