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The Effect of Methyl Hydroxyethyl Cellulose on the Cement Matrix Properties 甲基羟乙基纤维素对水泥基体性能的影响
Pub Date : 2020-06-30 DOI: 10.15587/1729-4061.2020.205347
Y. Kovalenko, V. Tokarchuk, V. Poliuha
The effect of a methyl hydroxyethyl cellulose additive on the technical and physical-mechanical properties of the cement matrix has been investigated. The study involved cellulose ether of low (11,000–16,000 MPa∙s), medium (17,000–23,000 MPa∙s), and high (20,000–30,000 MPa) viscosity. The additives were introduced into cement in the amount of 0.25, 0.5, and 0.75 % by weight. It has been established that the introduction of cellulose ether in cement leads to an increase in the normal density of the slurry and extends the duration of the mortar setting. The normal density of cement slurry increases with the introduction of cellulose ethers of low viscosity (LV) and medium viscosity (MV) by 5.4‒16.8 %; when introducing the ether of high viscosity (HV), by 21.3–41.4 %. This confirms the high water-retaining capacity of methyl hydroxyethyl cellulose, which increases with increasing viscosity of the additives. The setting duration of cement slurry increases, depending on the concentration and viscosity of the additives, by 2‒4 times, compared with an additive-free material. There is also a significant reduction in the strength of the cement matrix in the early periods of hardening (1–7 days) depending on the concentration of the additives, by 2.2–4.2 times. The strength of the samples is least affected by the cellulose ether of low viscosity, largest – by that of high viscosity. The reduction of strength is observed at the age of 28 days, although not very much pronounced. Compared to the additive-free cement, the strength amount to: for the ester of low viscosity at concentrations: 0.25 % by weight – 14.3 %, 0.50 % by weight – 23.9 %, 0.75 % by weight – 40.5 %; for the ether of medium viscosity, respectively, 23.8, 26.2, and 33.3 %; for the ether of high viscosity, 28.6; 45.2, and 61.0 %. The corrosion resistance of the cement matrix with methyl hydroxyethyl cellulose additives is increased at a concentration of up to 0.25 % by weight and then gradually decreases. The above results make it possible to recommend using, in the production of dry construction mixtures, the cellulose ethers of low and medium viscosity, which would ensure the required time to maintain the solution mobility and the sufficient strength of the resulting material
研究了甲基羟乙基纤维素添加剂对水泥基体技术性能和物理力学性能的影响。研究涉及低粘度(11,000-16,000 MPa∙s)、中粘度(17,000-23,000 MPa∙s)和高粘度(20,000-30,000 MPa)的纤维素醚。在水泥中分别添加重量为0.25、0.5和0.75%的添加剂。已经确定,在水泥中引入纤维素醚会导致浆料的正常密度增加,并延长砂浆凝结的时间。低粘度(LV)和中粘度(MV)纤维素醚的加入使水泥浆的正常密度提高了5.4 ~ 16.8%;当引入高粘度醚(HV)时,降低21.3 - 41.4%。这证实了甲基羟乙基纤维素的高保水能力,随着添加剂粘度的增加而增加。与不含添加剂的材料相比,水泥浆的凝结时间增加了2-4倍,这取决于添加剂的浓度和粘度。水泥基质的强度在硬化初期(1-7天)也有显著的降低,这取决于添加剂的浓度,降低了2.2-4.2倍。样品的强度受低粘度纤维素醚的影响最小,受高粘度纤维素醚的影响最大。在28天龄时观察到强度的降低,尽管不是很明显。与无添加剂水泥相比,低粘度酯的强度为:0.25%重量比- 14.3%,0.50%重量比- 23.9%,0.75%重量比- 40.5%;对于中等粘度的醚,分别为23.8%、26.2%、33.3%;高粘度醚为28.6;45.2%和61.0%。添加甲基羟乙基纤维素添加剂后,水泥基体的耐腐蚀性能在浓度达到0.25%(重量比)时有所提高,随后逐渐降低。上述结果使我们有可能推荐在生产干性建筑混合物时使用低粘度和中粘度的纤维素醚,这将确保所需的时间来保持溶液的流动性和所得到的材料的足够强度
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引用次数: 4
Improvement of a Scraper Heat Exchanger for Pre-Heating Plant-Based Raw Materials Before Concentration 植物原料浓缩前预热刮板换热器的改进
Pub Date : 2020-06-30 DOI: 10.15587/1729-4061.2020.202501
K. Kasabova, S. Sabadash, V. Mohutova, Vadym Volokh, A. Poliakov, T. Lazarieva, O. Blahyi, Oleg Radchuk, Vladyslav Lavruk
When heating liquid and paste-type products, enterprises in the food industry commonly use scraper heat exchangers, which, given their high heat treatment intensity, make it possible to retain the original properties of the treated raw materials. Most heat exchangers demonstrate an unstable stabilizing effect: the vapor pressure ‒ the temperature that leads to damage to raw materials, under conditions of significant energy- and metal capacity. It is possible to eliminate these drawbacks by using a temperature-stable flexible film resistive electric heater of the radiating type as a heater in an improved scraper heat exchanger. We have proposed applying a hinged blade with a cutting edge (with a reflective heating surface) as a stirring element of the heat exchanger to obtain the uniform distribution of a product layer thickness at the working surface and to additionally heat by the blade's reflective surface. The heat exchanger can be supplemented with a cooling shell with ring channels to pass the refrigerant, which is placed on the outer surface of the non-thermally insulated flexible electric heater. Such a solution provides the possibility of cooling to −15 °C and it simultaneously serves the additional air thermal insulation in the absence of the carrier in it. We have determined the uniformity of heat flow distribution over the heating surface of the model design of the improved unit (60.3...60.5 °C) and at the reflective surface of the hinged blade with a cutting edge (60.0...60.3 °C). The total thickness of a liquid layer has been established depending on the shaft rotation frequency of the proposed hinged blade with a cutting edge: at 50 min –1 – 1–2.65 mm, at 350 min –1 –1.5 mm, compared with a standard hinge blade (a layer thickness is from 5.0 mm to 1.5 mm), in terms of product consumption W=50 l/h. The improved scraper heat exchanger is characterized by a 1.48-time decrease in the specific energy consumption (170.4 kJ/kg), used to heat a product volume unit, compared to the heater with a steam shell – 252.6 kJ/kg. The research result is the confirmed efficiency of using the improved scraper heat exchanger, as well as its proposed structural scheme
在加热液体和糊状产品时,食品行业的企业通常使用刮板换热器,由于其热处理强度高,因此可以保留被处理原料的原始性能。大多数热交换器表现出一种不稳定的稳定效果:蒸汽压-在能量显著的条件下导致原材料损坏的温度-和金属容量。通过在改进的刮刀热交换器中使用温度稳定的柔性薄膜电阻式辐射型电加热器作为加热器,可以消除这些缺点。我们建议采用带切削刃(带反射加热面)的铰链叶片作为热交换器的搅拌元件,以获得产品层厚度在工作表面的均匀分布,并通过叶片的反射面进行额外加热。换热器可增设带环形通道的冷却壳,使制冷剂通过,该冷却壳置于非绝热柔性电加热器的外表面。这种解决方案提供了冷却到- 15°C的可能性,同时在没有载体的情况下提供额外的空气隔热。我们已经确定了改进单元模型设计的受热面(60.3…60.5°C)和带切削刃的铰链叶片反射面(60.0…60.3°C)的热流分布均匀性。液体层的总厚度已经确定,这取决于所提出的带有切削刃的铰链叶片的轴旋转频率:与标准铰链叶片(层厚度从5.0 mm到1.5 mm)相比,在50分钟- 1 - 1-2.65 mm时,在350分钟- 1 - 1.5 mm时,产品消耗W=50升/小时。改进后的刮刀换热器的特点是加热一个产品体积单位的比能耗(170.4 kJ/kg)比带蒸汽壳的加热器(252.6 kJ/kg)降低1.48倍。研究结果证实了改进型刮刀换热器的使用效率,并提出了改进型刮刀换热器的结构方案
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引用次数: 13
Substantiation of Technologies and Technical Means for Disposal of Mining and Metallurgical Waste in Mines 矿山矿冶废弃物处理技术与技术手段的论证
Pub Date : 2020-06-30 DOI: 10.15587/2706-5448.2020.200897
V. Lyashenko, O. Khomenko, Fedor Topolnij, O. Helevera
The object of research is environmental and resource-saving technologies in underground mining of mineral deposits with the laying of the developed space. One of the most problematic places is the delivery of hardening filling mixtures to the place of their installation and the lack of components for their preparation. This increases the importance of managing the state of ore-bearing massifs and the preservation of the earth’s surface.

The paper presents the main scientific and practical results of the substantiation of technologies and technical means for the disposal of mining and metallurgical production wastes into underground mined spaces (man-made voids) as components of hardening filling mixtures. Methods of theoretical generalizations are described using mathematical statistics, physical and mathematical modeling, with calculations and feasibility studies, laboratory and field experimental studies, industrial tests in operating enterprises. It is established that the use of vibration, mechanical and electroactivation of the components of the hardening filling mixture in mining enterprises leads to an increase in the activity of substandard materials by up to 10–40 % for each device. In particular, the enrichment of substandard inert materials at the vibrating screen GV-1.2/3.2 (Ukraine) increases the activity by 15–20 %. It is proved that the activation of binders (blast furnace granulated slag) in the DU-65 disintegrator (Disintegrator, Estonia) increases the activity of the binder by 20–25 %, with the output of the active class of fractions of 0.074 mm in size – by 55 % versus 40 % in ball mills. Vibration transport unit are recommended, which increase the activity of the solid components of the hardening filling mixture by 10–15 %, and electrodialysis apparatus for activating mixing water increase its activity by 30–40 %. It is shown that the use of vibration gravity transport systems ensures the filling of the filling mixture at a distance exceeding the height of the vertical stand by 15–20 times. A set of technical means is proposed for activating the components of hardening filling mixtures (binder, inert aggregate and electrochemically purified mine mixing water) during the manufacture and transportation of them to the installation site. This complex was introduced at such mining enterprises as:

– State Enterprise «Eastern Mining and Processing Plant» and Balaklava Mining Administration (Ukraine);

– Joint-stock company «Tselinnyi Mining and Chemical Combine» (Republic of Kazakhstan);

– Public Joint-Stock Company «Priargunsky Industrial Mining and Chemical Association» and Closed Joint-Stock Company «Uralzoloto» (Russian Federation) in other developed mining countries.
研究的对象是矿床地下开采环境与资源节约型技术与发达空间的铺设。最成问题的地方之一是将硬化填充混合物运送到安装地点,以及缺乏准备部件。这就增加了管理含矿体状态和保护地球表面的重要性。本文介绍了矿冶生产废弃物作为硬化充填混合物组分进入地下采空区(人工空洞)处理的技术和技术手段的主要科学和实践成果。运用数理统计、物理和数学建模、计算和可行性研究、实验室和现场实验研究、经营企业的工业试验来描述理论概括的方法。研究证实,在矿山企业中,对硬化充填料的各组分进行振动、机械和电活化,每台设备可使不合格物料的活度提高10 - 40%。特别是在GV-1.2/3.2(乌克兰)振动筛处富集不合格惰性物质,使活度提高15 - 20%。经证明,在DU-65型粉碎机(爱沙尼亚粉碎机)中活化粘结剂(高炉粒状矿渣)可使粘结剂的活性提高20 - 25%,其中0.074 mm级的活性组分的产量为55%,而在球磨机中则为40%。建议采用振动输送装置,使硬化填料的固体组分活性提高10 - 15%,电渗析装置活化混合水,使其活性提高30 - 40%。结果表明,采用振动重力输送系统可保证充填料在超过立式支架高度15-20倍的距离上进行充填。提出了一套在硬化充填料(粘结剂、惰性骨料和电化学净化的矿用混合水)的制造和输送至安装现场过程中使其组分活化的技术手段。在其他发达矿业国家的国有企业“东部采矿和加工厂”和巴拉克拉瓦矿业管理局(乌克兰)、股份公司“策林尼采矿和化学联合公司”(哈萨克斯坦共和国)、公共股份公司“普里亚尔贡斯基工业采矿和化学协会”和封闭股份公司“乌拉尔佐洛托”(俄罗斯联邦)等矿业企业都采用了这种综合设施。
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引用次数: 8
Reverse Blending as a Strategy for Purely Customizing Fertilizers While Considerably Reducing the Diversity to Be Produced: A Case Study 反向混合作为一种策略,以纯定制肥料,同时大大减少多样性生产:一个案例研究
Pub Date : 2020-06-26 DOI: 10.2139/ssrn.3636066
L. Benhamou, P. Féniès, F. Fontane, V. Giard
Reasoned fertilization is a major concern for sustainable agriculture and requires a major increase in the number of fertilizer formulas that cannot be achieved cost-effectively with current production models. We propose therefore a new approach, called reverse blending, based on a delayed differentiation performed nearby end-users, consisting in defining the composition of inputs that do not pre-exist, whose number must be as small as possible and whose blends will meet the exact requirements of a very wide variety of customized fertilizers. This approach is demonstrated through a case study that has identified the optimal composition of 8 inputs, whose blends enable the production of 700 fertilizers that are customized for some Moroccan provinces.
合理施肥是可持续农业的一个主要问题,需要大量增加肥料配方的数量,而目前的生产模式无法实现成本效益。因此,我们提出了一种新的方法,称为反向混合,基于在终端用户附近进行的延迟区分,包括定义不存在的输入成分,其数量必须尽可能少,其混合物将满足各种定制肥料的确切要求。通过一个案例研究证明了这种方法,该案例研究确定了8种投入物的最佳组成,这些投入物的混合物可以生产700种肥料,这些肥料是为摩洛哥一些省份定制的。
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引用次数: 1
Effect of Slime and Dust Emission on Micro-Cutting When Processing Carbon-Carbon Composites 碳-碳复合材料加工过程中煤泥和粉尘排放对微切削的影响
Pub Date : 2020-06-19 DOI: 10.15587/1729-4061.2020.203279
A. Salenko, O. Chencheva, V. Glukhova, V. Shchetynin, Mohamed R. F. Budar, S. Klimenko, E. Lashko
Results of theoretical and experimental studies aimed at establishing features of micro-cutting with abrasive grains characterized by active emission of slime and dust particles were presented. The slime particles are just partially withdrawn from the interaction zone and partially change surfaces of the tool and the workpiece of a carbon composite material, in particular, of carbon-carbon and carbon-polymer groups. The above materials possessing a complex of unique physical and mechanical properties are used in high-tech production though composites remain difficult to process materials. The problems manifest themselves to their utmost in making various apertures, shoulders, cutting of holes, processing edges. The study has shown that the phenomenon of dust and slime emission in abrasive processing of carbon-based non-dense composites and plastics results from sliding fracture and cyclic weakening of the surface non-dense layer which exhibits quasi-brittle properties under the action of fast-moving micro-indenters. Conditionality of the average slime particle sizes by normal stresses in the cutting zone and the magnitude of protrusion of diamond grains above the cutting surface of the tool was revealed. Since it was found that the particles formed during cutting are only partially withdrawn outside the cutting zone and the degree of removal decreases with an increase in the processing time, a conclusion on the cause of change in the state of the tool surface was drawn. The remaining slime and dirt change topography of the surface which results in the cutting zone temperature rise to critical values. It was shown that the use of tools with cyclic advance makes it possible to partially improve the condition of material processing which is relevant for the implementation of the processes of ring diamond drilling, processing with diamond saw blades. It was proved that the intermittent application of areas of the diamond-bearing layer reduces the phenomenon of dirt particle sticking to the surface of the working tool. Thus, the tool stays free of dirt for longer and the machining process is more efficient
本文介绍了以泥粒和粉尘颗粒主动发射为特征的磨粒微切削的理论和实验研究结果。黏液颗粒只是部分地从相互作用区撤出,部分地改变了碳复合材料,特别是碳-碳和碳-聚合物基团的工具和工件的表面。上述材料具有独特的物理和机械性能,虽然复合材料仍然是难以加工的材料,但它们用于高科技生产。这些问题在制作各种孔径、肩部、切割孔、加工边缘时表现得淋漓尽致。研究表明,碳基非致密复合材料和塑料磨料加工中粉尘和黏液的排放是由于表面非致密层在快速移动的微压头作用下呈现准脆性的滑动断裂和循环弱化所致。揭示了切削区法向应力和刀具切削表面上方金刚石颗粒突出程度对平均黏液粒径的制约作用。由于发现切削过程中形成的颗粒仅部分退出切削区,且去除程度随加工时间的增加而减小,由此得出了刀具表面状态变化原因的结论。残余的泥和污垢改变了表面的地形,导致切割区温度上升到临界值。结果表明,使用循环推进刀具可以部分改善材料的加工条件,这与金刚石锯片环形钻削加工工艺的实施有关。试验证明,含金刚石层区域的间歇施用减少了刀具表面粘污现象。因此,刀具保持无污垢更长时间,加工过程更有效
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引用次数: 8
Determining the Features of Loading the Improved Bearing Structure of a Platform Wagon for the Transportation of Military Equipment 军事装备运输平台车改进型轴承结构载荷特性的确定
Pub Date : 2020-06-19 DOI: 10.15587/1729-4061.2020.203245
A. Lovska, O. Fomin, Anna Chechet, O. Soloviova
The paper reports the improvement in the bearing structure of a platform wagon that transports military equipment and is involved in artillery fire. A special feature of the platform wagon is the presence of rotary sectors made from a composite material with viscous or elastic-viscous links, which makes it possible to absorb the kinetic energy that is transmitted to the frame when firing from the wagon, as well as enables the loading/unloading of military equipment from its side. We have investigated the dynamic loading of the bearing structure of a platform wagon for military equipment transportation and combat operations. A mathematical model has been constructed, which takes into consideration the movement of the bearing structure of a platform wagon when firing from it. It has been considered that the platform wagon is loaded with two anti-aircraft guns. The mathematical model was solved in the Mathcad programming environment. The study was conducted in a flat coordinate system. We have determined the accelerations that act on the bearing structure of a platform wagon. The maximum acceleration rate, in this case, is about 3.6 m/s 2 at bouncing oscillations and 4.0 m/s 2 at galloping oscillations. In other words, considering the proposed technical solutions, the dynamic loading of the bearing structure of a platform wagon in the vertical plane at firing decreases by almost 30 %. The magnitude of the acceleration is almost independent of the firing angle in this case. The derived acceleration values have been taken into consideration in determining the strength indicators for the bearing structure of a platform wagon. Calculation was carried out by the method of finite elements in the CosmosWorks programming environment. The maximum equivalent stresses in the bearing structure of a platform wagon amounted to about 285 MPa; they are concentrated in the region where the bearing structure rests on the trolley. Consequently, the durability of the bearing structure of a platform wagon is ensured. Modal analysis of the bearing structure of a platform wagon has been conducted. The values of the natural oscillation frequencies are within allowable limits. Our research would contribute to designing innovative structures for platform wagons
本文报道了一种用于运输军事装备和参与火炮射击的平台车的轴承结构的改进。平台车的一个特殊功能是由具有粘性或弹性粘性链接的复合材料制成的旋转部分的存在,这使得从马车发射时吸收传递到框架的动能成为可能,并且能够从其侧面装载/卸载军事装备。对军用装备运输和作战用平台式货车承载结构的动载荷进行了研究。建立了考虑平台车射击时轴承结构运动的数学模型。有人认为,平台车装载了两门高射炮。在Mathcad编程环境下求解数学模型。这项研究是在平面坐标系下进行的。我们已经确定了作用在平台式货车的轴承结构上的加速度。在这种情况下,最大加速度在弹跳振荡时约为3.6 m/s 2,在飞奔振荡时约为4.0 m/s 2。换句话说,考虑到所提出的技术解决方案,平台车在垂直平面上的轴承结构在射击时的动载荷降低了近30%。在这种情况下,加速度的大小几乎与发射角度无关。在确定平台式货车承载结构的强度指标时,考虑了推导出的加速度值。在CosmosWorks编程环境下,采用有限元法进行计算。平台式货车承载结构的最大等效应力约为285 MPa;它们集中在承载结构支承在小车上的区域。从而保证了平台车承载结构的耐久性。对平台式货车的轴承结构进行了模态分析。固有振荡频率值在允许范围内。我们的研究将有助于设计出新颖的平台式货车结构
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引用次数: 2
Electric Current Dependence on Superplastic Tensile Flow in Tetragonal Zirconia Polycrystal Under a DC Field 直流电场下四方氧化锆多晶超塑性拉伸流动的电流依赖性
Pub Date : 2020-06-18 DOI: 10.2139/ssrn.3622581
Y. Sasaki, K. Morita, Takahisa Yamamoto, K. Soga, H. Masuda, H. Yoshida
Electric DC current dependence on the superplastic flow in densified, fine-grained tetragonal ZrO2 polycrystal was systematically investigated. An optimal current density for large tensile ductility existed; the maximum elongation of 135% was achieved under the current density of 250 mA∙mm-2 at a furnace temperature of 1000 oC and an initial strain rate of 1×10-3 s-1. Application of DC current decreased the flow stress, while that simultaneously accelerated the grain growth in tetragonal ZrO2 polycrystal. The reduced flow stress and improved ductility can be explained not only by Joule heating but also by enhanced atomic diffusion or accelerated grain boundary sliding.
系统地研究了直流电流对致密细晶方形ZrO2多晶超塑性流动的影响。存在大拉伸延展性的最佳电流密度;当电流密度为250 mA∙mm-2,炉温为1000℃,初始应变速率为1×10-3 s-1时,拉伸伸长率达到135%。直流电流的施加降低了流动应力,同时加速了方形ZrO2多晶的晶粒生长。流动应力的降低和延展性的提高不仅可以用焦耳加热来解释,还可以用原子扩散的增强或晶界滑动的加速来解释。
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引用次数: 0
Feedstocks for AD AD原料
Pub Date : 2020-06-15 DOI: 10.48216/9788269203325ch5
J. Lamb
Biomass is a generic word used to characterise all matter created naturally. Therefore, it contains all sorts of materials and substances extracted from living organisms. Forest and farm biomass, commercial and urban residues and waste are the sources of biomass used as a bioenergy feedstock. Biomass resources suitable as biogas feedstocks, usually referred to as anaerobic digestion feedstocks, are represented by a wide variety of renewable organic materials available, ranging from simple compounds to complex high-solid substrates. They usually have a high content of sugar, starch, proteins or fats, and their ability to be easily decomposed through anaerobic digestion is a common feature. This chapter gives an overview of biomass sources for anaerobic digestion as well as their important characteristics.
生物质是一个通用的词,用来描述所有自然产生的物质。因此,它包含了从生物体中提取的各种物质和物质。森林和农场生物量、商业和城市残留物和废物是用作生物能源原料的生物量的来源。适合作为沼气原料的生物质资源,通常被称为厌氧消化原料,以各种各样的可再生有机材料为代表,从简单的化合物到复杂的高固体底物。它们通常含有高含量的糖、淀粉、蛋白质或脂肪,并且它们易于通过厌氧消化分解的能力是它们的一个共同特征。本章概述了厌氧消化的生物质来源及其重要特征。
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引用次数: 0
Design of Solute Clustering During Thermomechanical Processing of AA6016 Al-Mg-Si Alloy AA6016 Al-Mg-Si合金热处理过程中溶质团簇的设计
Pub Date : 2020-06-10 DOI: 10.2139/ssrn.3614851
Su-Qin Zhu, H. Shih, Xiangyuan Cui, Chung-Yi Yu, S. Ringer
Solute clustering is a technologically important microstructural process in Al alloys. Exerting control over this process in order to enhance the alloy properties and reduce the energy costs of production is a major scientific and technological focus, with automotive sheet applications serving as a key driver. In this work, we detail changes in the state of clustering arising from the insertion of a thermomechanical pre-ageing process, via a coiling step, immediately after solution treatment. This pre-ageing step effectively mitigates the negative effects of the natural ageing on the mechanical properties that would otherwise occur after solution treatment and ahead of the final paint-bake step. Our work sought to raise the strength of AA6016, which nominally contains little or no Cu, to levels equivalent to the higher Cu-bearing 6xxx grade alloys, whilst preserving excellent ductility. This novel combination of process design and alloy selection has been studied in detail using a combination of atom probe tomography (APT) and first principles density functional theory (DFT) simulations. The thermomechanical process described here invokes a strong cluster strengthening phenomenon. We report on the details of the single-species Si-Si and Mg-Mg clusters and those of the Mg-Si co-clusters and relate the APT observations to our DFT calculations. Mg-Si co-clusters ≥ 20 solute atoms are found to be responsible for the excellent properties in the material exposed to the pre-ageing and paint-baking process. Our results revealed that vacancies can effectively stabilise single-species Si clusters enabling them to attract further solute and serving as a pathway to formation of the larger Mg-Si co-clusters that are so beneficial to alloy properties.
溶质聚类是铝合金中技术上重要的显微组织过程。为了提高合金性能和降低生产的能源成本,对这一过程进行控制是一个主要的科学和技术重点,汽车板材的应用是一个关键的驱动力。在这项工作中,我们详细介绍了在固溶处理后立即通过卷取步骤插入热机械预老化过程引起的聚类状态的变化。这个预老化步骤有效地减轻了自然老化对机械性能的负面影响,否则会在固溶处理之后和最后的烤漆步骤之前发生。我们的工作旨在将名义上只含少量或不含Cu的AA6016的强度提高到与含Cu较高的6xxx级合金相当的水平,同时保持良好的延展性。利用原子探针层析成像(APT)和第一性原理密度泛函理论(DFT)模拟的结合,详细研究了这种工艺设计和合金选择的新组合。这里描述的热机械过程引起了强的团簇强化现象。我们报告了单种Si-Si和Mg-Mg簇以及Mg-Si共簇的细节,并将APT观察结果与我们的DFT计算联系起来。Mg-Si共团簇≥20个溶质原子被发现对暴露在预老化和油漆烘烤过程中的材料的优异性能负责。我们的研究结果表明,空位可以有效地稳定单种Si团簇,使它们能够吸引更多的溶质,并作为形成更大的Mg-Si共团簇的途径,这对合金性能非常有益。
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引用次数: 0
High-Entropy Oxides Based on Valence Combinations: Design and Practice 基于价态组合的高熵氧化物:设计与实践
Pub Date : 2020-06-06 DOI: 10.2139/ssrn.3656143
Lei Tang, Zemin Li, Kepi Chen, Cuiwei Li, Xiaowen Zhang, L. An
High-entropy oxides (HEOs) are a new class of materials that are promising for a wide range of applications. Designing HEOs needs to consider both geometric compatibility and electrical equilibrium. However, there is currently no available method to systematically consider these two factors when selecting constituent materials for making HEOs. Here we propose a two-step strategy, where a HEO system to be explored is first partitioned into multiple subsystems based on the valence combinations of substituted cations; the geometric compatibility is then considered in selecting suitable substituted cations. We demonstrate this strategy by using A(5B0.2)O3 perovskite as a model system. We show that the system can be partitioned into 12 subsystems. Ten of the subsystems have formed a single-phase cubic perovskite, while two have partially ordering structure. The formation of single phases is correlated to Goldschmidt's tolerance factor, while the formation of the ordering structure is mainly correlated to cation-valence difference. We anticipate that this strategy is applicable to exploring HEOs in other systems.
高熵氧化物(HEOs)是一类具有广泛应用前景的新型材料。设计heo需要同时考虑几何兼容性和电平衡。然而,在选择制造heo的组成材料时,目前还没有一种方法可以系统地考虑这两个因素。在这里,我们提出了一个两步走的策略,首先根据取代阳离子的价组合将待探索的HEO系统划分为多个子系统;然后在选择合适的取代阳离子时考虑几何相容性。我们通过使用A(5B0.2)O3钙钛矿作为模型系统来证明这一策略。我们证明了该系统可以划分为12个子系统。十个子系统形成了单相立方钙钛矿,两个子系统具有部分有序结构。单相的形成与Goldschmidt容差因子有关,而有序结构的形成主要与阳离子价差有关。我们预计该策略适用于探索其他系统中的heo。
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引用次数: 41
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EngRN: Engineering Design Process (Topic)
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