Pub Date : 2017-02-21DOI: 10.1002/9780471264194.FOS11600
T. Ho, M. Fieser, L. Fieser
{"title":"Copper(II) Trifluoroacetate","authors":"T. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11600","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11600","url":null,"abstract":"","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84509102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-02-21DOI: 10.1002/9780471264194.FOS11638.PUB2
T. Ho, M. Fieser, L. Fieser
{"title":"Iron(II) Triflate","authors":"T. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11638.PUB2","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11638.PUB2","url":null,"abstract":"","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86026946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-02-21DOI: 10.1002/9780471264194.FOS11138
T. Ho, M. Fieser, L. Fieser
{"title":"Vanadium(IV) chloride","authors":"T. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11138","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11138","url":null,"abstract":"","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75385382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-02-21DOI: 10.1002/9780471264194.FOS11737
T.-L. Ho, M. Fieser, L. Fieser
{"title":"Gallium(III) Triflate","authors":"T.-L. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11737","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11737","url":null,"abstract":"","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74044924","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-02-21DOI: 10.1002/9780471264194.FOS09648.PUB6
T. Ho
This article has no abstract. Keywords: preparation; hexamethyl-trans-σ-trishomobenzene (2); preparation; olefins from vinyl halides and alkyllithiums; beckmann fragmentation of ketoximes; aryl- and vinyl-substituted acetylenes; dehydrobromination of α-bromo ketones; ketone synthesis; extrusion of mercury from bis(propenyl)mercury; allylation of amines; alkenes from vinyl iodides and grignard reagents; conjugated enynes; arylalkynes; unsymmetrical biaryls and diarylmethanes; vinyl nitriles; cyclization via π-allylpalladium complexes; steroid side chain; cyclization to medium-sized lactones; chiral methyl chiral lactic acid (5); isomerization of 1,3-diene epoxides; alkylation of vinyl lactones; reductive acylation of alkoxy-substituted allylic acetates; methylenecyclopentanes; stereospecific synthesis of alkenes; cross-coupling of aryl halides and 1-alkenylboranes; iboga alkaloids; isomerization and elimination of allylic acetates; supported reagent; coupling of allyl bromides and allylstannanes; decarboxylation of β-acetoxy carboxylic acids; cleavage of endoperoxides; alkylation of dihydropyranyl acetates; alkylation and amination of allylic phosphates; 1,4-Dienes; α-Allylated ketones; alkylation of allyl nitroalkanes; allylation of nucleophiles; alkylation of vinyl epoxides; vinylsilanes; nucleophilic substitution reactions with α-acetoxy-β,γ-unsaturated nitriles; macrocyclization; macroheterocyclization; β-Keto esters; double silylation; allylic sulfones; 2,3-Disubstituted bicyclo[2.2.1]heptanes; desulfonylation; homoallylic alcohols; sequential π-allylpalladium alkylation; biaryls; 1,3-Dienes; heterosubstituted 1,3-dienes; 1,3-Diynes; allenynes; coupling of vinyl triflates with organotins; acylation of organozinc reagents; β-Carboline synthesis; allylation of potassium enoxyborates; allylic amination; macrocyclization by allylation–alkylation; steroidal 6β-hydroxy-2,4-diene-1-ones; trans- cis-Cinnamic acids; RX RCHO; coupling of vinyl triflates with alkenes; α-Diketones; carbonylation of 1-iodo-1,4- and -1,5-dienes; conjugate reduction; denitro-sulfonylation; allylic sulfones; coupling of 1-alkenylboranes with 1-bromoalkenes or -alkynes; cross-coupling of organoalanes with allylic acetals or ortho esters; carbonylation; 1,4-diazepines; decarbonylative cross coupling of acyl halides; decarbonylation of acyl cyanides; allylation of lithium 1-cyclopentenolates; asymmetric allylation; bisethynylation of vic-dichloroethylenes; pyrrolidines; piperidines; unsymmetrical biaryls; primary allylic amines; coupling of aryl triflates with organostannanes; coupling of vinylboranes and vinyl halides; intramolecular heck reactions; hydroxylamination; denitration of allylic nitro groups; coupling of RCOCl with Bu4Pb; intramolecular arylation; cyclizative heck coupling; [3 + 2]Annelation; Pd-catalyzed intramolecular ene reactions; allylidenation of aldehydes; 3-Aza-
{"title":"Tetrakis(triphenylphosphine)palladium(0)","authors":"T. Ho","doi":"10.1002/9780471264194.FOS09648.PUB6","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS09648.PUB6","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000preparation; \u0000hexamethyl-trans-σ-trishomobenzene (2); \u0000preparation; \u0000olefins from vinyl halides and alkyllithiums; \u0000beckmann fragmentation of ketoximes; \u0000aryl- and vinyl-substituted acetylenes; \u0000dehydrobromination of α-bromo ketones; \u0000ketone synthesis; \u0000extrusion of mercury from bis(propenyl)mercury; \u0000allylation of amines; \u0000alkenes from vinyl iodides and grignard reagents; \u0000conjugated enynes; \u0000arylalkynes; \u0000unsymmetrical biaryls and diarylmethanes; \u0000vinyl nitriles; \u0000cyclization via π-allylpalladium complexes; \u0000steroid side chain; \u0000cyclization to medium-sized lactones; \u0000chiral methyl chiral lactic acid (5); \u0000isomerization of 1,3-diene epoxides; \u0000alkylation of vinyl lactones; \u0000reductive acylation of alkoxy-substituted allylic acetates; \u0000methylenecyclopentanes; \u0000stereospecific synthesis of alkenes; \u0000cross-coupling of aryl halides and 1-alkenylboranes; \u0000iboga alkaloids; \u0000isomerization and elimination of allylic acetates; \u0000supported reagent; \u0000coupling of allyl bromides and allylstannanes; \u0000decarboxylation of β-acetoxy carboxylic acids; \u0000cleavage of endoperoxides; \u0000alkylation of dihydropyranyl acetates; \u0000alkylation and amination of allylic phosphates; \u00001,4-Dienes; \u0000α-Allylated ketones; \u0000alkylation of allyl nitroalkanes; \u0000allylation of nucleophiles; \u0000alkylation of vinyl epoxides; \u0000vinylsilanes; \u0000nucleophilic substitution reactions with α-acetoxy-β,γ-unsaturated nitriles; \u0000macrocyclization; \u0000macroheterocyclization; \u0000β-Keto esters; \u0000double silylation; \u0000allylic sulfones; \u00002,3-Disubstituted bicyclo[2.2.1]heptanes; \u0000desulfonylation; homoallylic alcohols; \u0000sequential π-allylpalladium alkylation; \u0000biaryls; \u00001,3-Dienes; \u0000heterosubstituted 1,3-dienes; \u00001,3-Diynes; \u0000allenynes; \u0000coupling of vinyl triflates with organotins; \u0000acylation of organozinc reagents; \u0000β-Carboline synthesis; \u0000allylation of potassium enoxyborates; \u0000allylic amination; \u0000macrocyclization by allylation–alkylation; \u0000steroidal 6β-hydroxy-2,4-diene-1-ones; \u0000trans- cis-Cinnamic acids; \u0000RX RCHO; \u0000coupling of vinyl triflates with alkenes; \u0000α-Diketones; \u0000carbonylation of 1-iodo-1,4- and -1,5-dienes; \u0000conjugate reduction; \u0000denitro-sulfonylation; allylic sulfones; \u0000coupling of 1-alkenylboranes with 1-bromoalkenes or -alkynes; \u0000cross-coupling of organoalanes with allylic acetals or ortho esters; \u0000carbonylation; 1,4-diazepines; \u0000decarbonylative cross coupling of acyl halides; \u0000decarbonylation of acyl cyanides; \u0000allylation of lithium 1-cyclopentenolates; \u0000asymmetric allylation; \u0000bisethynylation of vic-dichloroethylenes; \u0000pyrrolidines; piperidines; \u0000unsymmetrical biaryls; \u0000primary allylic amines; \u0000coupling of aryl triflates with organostannanes; \u0000coupling of vinylboranes and vinyl halides; \u0000intramolecular heck reactions; \u0000hydroxylamination; \u0000denitration of allylic nitro groups; \u0000coupling of RCOCl with Bu4Pb; \u0000intramolecular arylation; \u0000cyclizative heck coupling; \u0000[3 + 2]Annelation; \u0000Pd-catalyzed intramolecular ene reactions; \u0000allylidenation of aldehydes; \u00003-Aza-","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84539775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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