Fieser and Fieser's Reagents for Organic Synthesis最新文献

{"title":"1,1,3,3‐Tetrakis(trifluoromethanesulfonyl)propane","authors":"T. Ho","doi":"10.1002/9780471264194.FOS11926.PUB2","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11926.PUB2","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000tetrabutylammonium fluoride, TBAF; \u0000tetrabutylammonium difluorotriphenylsilicate; \u0000tetracarbonylhydridorhenium; \u0000titanocene bis(triethyl phosphite); \u0000trimethylsilyl trifluoromethanesulfonate","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87049314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rhodium(II) carboxylates","authors":"T. Ho, M. Fieser, L. Fieser, R. Danheiser, W. Roush, Janice Y. Smith","doi":"10.1002/9780471264194.fos08768.pub2","DOIUrl":"https://doi.org/10.1002/9780471264194.fos08768.pub2","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000cyclopropanation with alkyl diazoacetates; \u0000cyclopropenation; \u0000thiophenium ylides; \u0000cyclopropanation; \u0000β-lactams; \u0000β-keto esters from α-diazo-β-hydroxy esters; \u0000buchner reaction; \u0000cyclopropanation of ; \u00002-carbapenems; \u0000alkylation of β-lactams; \u0000intramolecular cycloaddition of a diazo ketone to a cyclopropene; \u0000cyclopentanones; \u0000cis-α,β-unsaturated esters; \u0000unsaturated ethers; \u0000δ-lactones; \u0000chiral cyclopentanones; \u0000intramolecular buchner reaction; \u0000hydroformylation; \u0000benzyl ketones; \u0000cyclization-cycloaddition of an α-diazoacetophenone; \u0000chiral 3,3-disubstituted cyclopentanones; \u0000intramolecular C—H insertion; \u0000oxepanes and oxocanes; \u0000cyclopropanation of furanyl diazo ketones; \u0000β-lactams; \u0000α-silyl esters or ketones; \u0000diazo ketone cyclization to hydroazulenones; \u0000cyclization/cycloaddition route to oxapolycycles; \u00002,5-disubstituted 3(2H)-furanones; \u0000furans; \u0000carbenoid–monothiophthalimide coupling; \u0000rearrangement of N-nitrosoamides; \u0000tropones; \u0000reaction of α-diazo ketones with alkynes; \u0000synthesis of (+)-griseofulvin (3); \u0000reaction of cyclic diazo-1,3-dicarbonyls with aryl heterocycles; \u0000tricyclic dihydropyrrolizines; \u0000reaction with cyclopropenes; \u0000α-alkoxy esters; \u0000insertion into SiH bonds; \u0000heterocyclization; \u0000silylformylation; \u0000carbenoid insertions; \u0000cyclopropanation; \u0000heterocycles; \u0000conjugated ketenes; \u0000hydroformylation; \u0000carbenoid insertions; \u0000rearrangements; \u0000four-membered rings; \u0000diheterobicycloalkanes; \u0000[3 + 2]cycloadditions; \u0000wolff rearrangement; \u0000three-membered rings; \u0000five-membered rings; \u0000C-H insertion; \u0000rearrangement; \u00001-acetoxyazulenes; \u0000coupling; \u0000transylidation; \u0000bond insertion; \u0000bicyclization; \u0000benzyl alcohols; \u0000N-sulfonylcarboxamides; \u0000isomerization; \u0000arylation; \u0000CH Bond Insertion; \u0000NH Bond Insertion; \u0000NO Bond Insertion; \u0000cyclization; \u0000rhenium(VII) oxide; \u0000Rh/alumina catalyst hydrogenation; \u0000rhodium - iron; \u0000rhodium(I) hexafluoroantimonate; \u0000ruthenium(III) chloride hydrate","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78980544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Palladium/Inorganic Supports","authors":"T. Ho","doi":"10.1002/9780471264194.FOS11879.PUB3","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11879.PUB3","url":null,"abstract":"","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89641751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Palladium(II) acetate","authors":"T. Ho, M. Fieser, R. Danheiser, W. Roush, L. Fieser","doi":"10.1002/9780471264194.FOS07552.PUB6","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS07552.PUB6","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000oxidative dimerization of β-substituted α-olefins; \u0000benzylic oxidation of toluenes; \u0000π-allylpalladium complexes; \u0000cyclopropanation; \u0000substitution of vinylic hydrogens; \u0000oxidation of ethylene; \u0000cyclopropanation; \u0000examples; \u0000ArI  Ar–Ar; \u0000acetoxylation of arenes; \u0000arylation of allylic alcohols with aryl halides; \u0000α,β-enones; \u00001,4-dienes; \u0000(E)- and (Z)-alkenes; \u0000arylation of allylic alcohols; \u0000arylation of olefins; \u0000terminal 1,3-dienes; \u00002,2,7,7,12,13,17,18-octamethylisobacteriochlorin; \u0000α,β-enones; \u0000benzohydrofuranes; \u0000transannular reactions of grayanotoxin-II; \u0000cyclopentenes; \u00003-methyl-2-cyclopentenones; \u0000polycyclic indoles; \u0000β-lactams; \u0000intramolecular cyclization via π-allylpalladium complexes; \u0000β-aryl-α,β-unsaturated carbonyl compounds; \u0000arenecarboxylic acids; \u00002,2′-bipyrroles; \u0000bridged and spirocyclic bicycloalkenones; \u0000ketones from halohydrins; \u0000arylation of quinones; \u0000cyclopropanation; \u00001,4-diacetoxylation of1,3-dienes; \u00001,4-acetoxytrifluoroacetoxylation of 1,3-dienes; \u0000vinylation of alkyl or aryl halides; \u0000β-aryl aldehydes; \u0000hydrogenolysis of allylic acetates; \u0000enones; \u0000ortho-alkylation of acetanilides; \u0000arylation of cycloalkenes; \u0000allylic acetoxylation; \u0000oxidative coupling of alkenylstannanes; \u0000lactonization of dienes by 1,4-functionation; \u00001,3,5-trienes; \u0000cyclization of o-iodophenyl allyl ethers to benzofurans; \u0000coupling of CH2CHSi(CH3)3 with vinyl iodides; \u0000vinylation of cycloalkenes; \u0000arylannelation of 1,3-dienes; \u0000coupling of ArI and unsaturated epoxides; \u0000bicyclic acetals; \u00001,4-additions to1,3-dienes; \u0000didehydroamino acids; \u0000cyclopentenones from carbohydrates; \u00003-arylcycloalkenes; \u0000coupling of vinyl halides with allylic alcohols; \u0000cyclization of 4,6- and 5,7-dieneamides; \u0000oxaspirocyclic addition to 1,3-dienes; \u0000RCH2CHO  RCHCHOCH3  RCHCHCHO; \u0000heck cyclization; \u0000heck-type coupling of allylic alcohols and enol triflates; \u0000coupling of vinyl halides with allyl alcohols; \u0000arylation of allylic alcohols; \u0000hydroacetoxylation of 2-alkynoates; \u0000three-component coupling of alkenes; \u0000heck reaction; \u0000suzuki, stille, and related couplings; \u0000reductive acylation and transesterification; \u00002-benzenesulfenyl-1,3-dienes; \u0000allylic oxidation; \u00001,4-difunctionalization of 1,3-dienes; \u0000cycloisomerization of enynes; \u0000heck reaction; \u0000arylation with onium salts; \u0000suzuki couplings; \u0000carboxylation; \u0000addition to multiple bonds; \u0000oxidation; \u0000heck reaction and other couplings; \u0000addition to multiple bonds; \u0000dehydrogenation of carbonyl compounds; \u0000indoles; \u0000cyclopropanation; \u0000enol ethers; \u0000coupling reactions; \u0000reactions of alkynes; \u0000carbonyl compounds; \u0000miscellaneous reactions; \u0000hydroarylation; \u0000carboxylation; \u0000rearrangement-coupling; \u0000conjugate addition; \u0000coupling reactions; \u0000redox reactions; \u0000vinyl glycosides; \u0000cyclizations; \u0000additions; \u0000allylic displacements; \u0000cyclopropanation; \u0000coupling reactions; \u0000addition reactions; \u0000cyclization reactions; \u0000cyclopentadienone acetals; \u0000oxidation; \u0000ketone synthesis; \u0000racemization; \u0000transan","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74101192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rhodium-carbene complexes","authors":"T. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11904.PUB2","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11904.PUB2","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000rhenium(VII) oxide; \u0000Rh/alumina catalyst hydrogenation; \u0000rhodium - iron; \u0000rhodium(I) hexafluoroantimonate; \u0000ruthenium(III) chloride hydrate","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76682662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tungsten Carbene and Carbyne Complexes","authors":"T. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11101.PUB2","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11101.PUB2","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000aminocarbene diels–alder reactions; \u0000intramolecular bis-alkyne annelations; \u0000cycloheptadienones; \u0000cyclopentannulation; \u0000alkyne metathesis; \u0000cycloadditions; \u00001-hydroxytetralins; \u0000dihydropyran formation; \u0000alkyne metathesis","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80982213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Iron(III) Chloride","authors":"T. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11421.PUB4","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11421.PUB4","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000reduction; \u0000substitutions; \u0000homoallylic ethers; \u0000Michael reaction; \u0000condensations; \u0000deacetalization; \u0000arylation; \u0000friedel—crafts reactions; \u0000cyclization reactions; \u0000addition and cycloaddition; \u0000substitution; \u0000substitution; \u0000addition; \u0000condensation; \u0000redox reactions; \u0000friedel–crafts reactions; \u0000other annulations; \u0000organoindium reagents; \u0000N-Functionalization; \u0000indium(III) bromide; \u0000skeletal reorganization; \u0000iodosuccinimide, NIS","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90721658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"2,8,9‐Trialkyl‐1‐phospha‐2,5,8,9‐tetraazabicyclo[3.3.3]undecanes","authors":"T. Ho","doi":"10.1002/9780471264194.FOS10048.PUB4","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS10048.PUB4","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000trans-stilbene epoxides; \u0000condensation reactions; \u0000alcohol–ester interchange; \u0000silylcyanations; \u0000coupling reactions; \u0000diaryl ethers; \u0000isomerization; \u0000condensation","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80746388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molybdenum(V) chloride","authors":"T. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11872","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11872","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000pinacolatoboron B-Benzylation; \u0000MMPP; \u0000manganese(III) acetate; \u0000manganation; \u0000molybdenum-carbyne complexes","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87694077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Palladium(II) chloride","authors":"T. Ho, M. Fieser, L. Fieser, Rick Danheiser, William R. Roush, Janice Smith","doi":"10.1002/9780471264194.FOS07690.PUB6","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS07690.PUB6","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000π-allylpalladium complexes; \u0000phenolic coupling; \u0000asymmetric allylic alkylations; \u0000π-allylpalladium chloride dimers; \u0000reactions of allene catalyzed by palladium or rhodium compounds; \u0000aryl isocyanates; \u0000dehydrogenation; \u0000π-allylpalladium chloride dimers; \u0000alkylation of π-allylpalladium complexes; \u0000π-allylpalladium chloride dimers of α,β-unsaturated ketones; \u0000hydrolysis of nitriles to amides; \u0000pyridine- and quinolinecarboxylic acids; \u0000carbodiimides; \u0000polymer-supported reagent; \u0000π-allylpalladium dimers; \u0000oxidation of primary amines; \u0000polymer-supported reagent; \u00001,3-dienes; \u0000α,β-unsaturated ketosteroids; \u0000γ,δ-unsaturated sulfones; \u0000phenylation of enones; \u0000polymer-bound reagent; \u00001,5-dienes from π-allylpalladium chloride dimers; \u0000thallation–carbonylation; \u0000acetoxylation of β,γ-unsaturated esters; \u0000cyclization–insertion; \u0000wacker oxidation; \u0000carbonylation of (π-allyl)palladium dimers; \u0000coupling of π-(allylic)palladium complexes with an alkenylzirconium(IV) complex;1,4-dienes; \u0000(Z)-Δ3-alkenyl sulfones; \u0000α,β-unsaturated carbonyl compounds; \u0000allyl–allyl coupling; \u0000cyclization of hydroxyalkenes to furanes and pyranes; \u0000conjugate addition of 2-bromoarylmercury compounds; \u0000pyranosides cyclohexanones; \u00002,5-disubstituted tetrahydrofurans; \u0000reduction; \u0000acetals; \u0000o-Hydroxybenzophenones; \u0000cross-couplings; \u0000coupling reactions; \u0000arylation of salicylaldehydes; \u0000deallylation; \u0000halosilanes; \u0000hydrogenation; \u0000coupling reactions; \u0000oxidation; \u0000aziridines; \u0000coupling reactions; \u0000hydroarylation; \u0000coupling reactions; \u0000oxidation of alkenes; \u0000o-hydroxybenzyl ethers; \u0000benzhydryl ethers; \u0000alkylation; \u0000coupling reactions; \u0000cyclopentenones; \u0000reduction; \u0000addition; \u0000substitution; \u0000coupling reactions; \u0000oxidation; \u0000palladacycles; \u0000cross-coupling reactions; \u0000Suzuki coupling; \u0000palladium(II) acetate – silver salts; \u0000palladium – aminocarbene complexes","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88606189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}