Pub Date : 2017-02-21DOI: 10.1002/9780471264194.FOS07552.PUB6
T. Ho, M. Fieser, R. Danheiser, W. Roush, L. Fieser
This article has no abstract. Keywords: oxidative dimerization of β-substituted α-olefins; benzylic oxidation of toluenes; π-allylpalladium complexes; cyclopropanation; substitution of vinylic hydrogens; oxidation of ethylene; cyclopropanation; examples; ArI Ar–Ar; acetoxylation of arenes; arylation of allylic alcohols with aryl halides; α,β-enones; 1,4-dienes; (E)- and (Z)-alkenes; arylation of allylic alcohols; arylation of olefins; terminal 1,3-dienes; 2,2,7,7,12,13,17,18-octamethylisobacteriochlorin; α,β-enones; benzohydrofuranes; transannular reactions of grayanotoxin-II; cyclopentenes; 3-methyl-2-cyclopentenones; polycyclic indoles; β-lactams; intramolecular cyclization via π-allylpalladium complexes; β-aryl-α,β-unsaturated carbonyl compounds; arenecarboxylic acids; 2,2′-bipyrroles; bridged and spirocyclic bicycloalkenones; ketones from halohydrins; arylation of quinones; cyclopropanation; 1,4-diacetoxylation of1,3-dienes; 1,4-acetoxytrifluoroacetoxylation of 1,3-dienes; vinylation of alkyl or aryl halides; β-aryl aldehydes; hydrogenolysis of allylic acetates; enones; ortho-alkylation of acetanilides; arylation of cycloalkenes; allylic acetoxylation; oxidative coupling of alkenylstannanes; lactonization of dienes by 1,4-functionation; 1,3,5-trienes; cyclization of o-iodophenyl allyl ethers to benzofurans; coupling of CH2CHSi(CH3)3 with vinyl iodides; vinylation of cycloalkenes; arylannelation of 1,3-dienes; coupling of ArI and unsaturated epoxides; bicyclic acetals; 1,4-additions to1,3-dienes; didehydroamino acids; cyclopentenones from carbohydrates; 3-arylcycloalkenes; coupling of vinyl halides with allylic alcohols; cyclization of 4,6- and 5,7-dieneamides; oxaspirocyclic addition to 1,3-dienes; RCH2CHO RCHCHOCH3 RCHCHCHO; heck cyclization; heck-type coupling of allylic alcohols and enol triflates; coupling of vinyl halides with allyl alcohols; arylation of allylic alcohols; hydroacetoxylation of 2-alkynoates; three-component coupling of alkenes; heck reaction; suzuki, stille, and related couplings; reductive acylation and transesterification; 2-benzenesulfenyl-1,3-dienes; allylic oxidation; 1,4-difunctionalization of 1,3-dienes; cycloisomerization of enynes; heck reaction; arylation with onium salts; suzuki couplings; carboxylation; addition to multiple bonds; oxidation; heck reaction and other couplings; addition to multiple bonds; dehydrogenation of carbonyl compounds; indoles; cyclopropanation; enol ethers; coupling reactions; reactions of alkynes; carbonyl compounds; miscellaneous reactions; hydroarylation; carboxylation; rearrangement-coupling; conjugate addition; coupling reactions; redox reactions; vinyl glycosides; cyclizations; additions; allylic displacements; cyclopropanation; coupling reactions; addition reactions; cyclization reactions; cyclopentadienone acetals; oxidation; ketone synthesis; racemization; transan
{"title":"Palladium(II) acetate","authors":"T. Ho, M. Fieser, R. Danheiser, W. Roush, L. Fieser","doi":"10.1002/9780471264194.FOS07552.PUB6","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS07552.PUB6","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000oxidative dimerization of β-substituted α-olefins; \u0000benzylic oxidation of toluenes; \u0000π-allylpalladium complexes; \u0000cyclopropanation; \u0000substitution of vinylic hydrogens; \u0000oxidation of ethylene; \u0000cyclopropanation; \u0000examples; \u0000ArI Ar–Ar; \u0000acetoxylation of arenes; \u0000arylation of allylic alcohols with aryl halides; \u0000α,β-enones; \u00001,4-dienes; \u0000(E)- and (Z)-alkenes; \u0000arylation of allylic alcohols; \u0000arylation of olefins; \u0000terminal 1,3-dienes; \u00002,2,7,7,12,13,17,18-octamethylisobacteriochlorin; \u0000α,β-enones; \u0000benzohydrofuranes; \u0000transannular reactions of grayanotoxin-II; \u0000cyclopentenes; \u00003-methyl-2-cyclopentenones; \u0000polycyclic indoles; \u0000β-lactams; \u0000intramolecular cyclization via π-allylpalladium complexes; \u0000β-aryl-α,β-unsaturated carbonyl compounds; \u0000arenecarboxylic acids; \u00002,2′-bipyrroles; \u0000bridged and spirocyclic bicycloalkenones; \u0000ketones from halohydrins; \u0000arylation of quinones; \u0000cyclopropanation; \u00001,4-diacetoxylation of1,3-dienes; \u00001,4-acetoxytrifluoroacetoxylation of 1,3-dienes; \u0000vinylation of alkyl or aryl halides; \u0000β-aryl aldehydes; \u0000hydrogenolysis of allylic acetates; \u0000enones; \u0000ortho-alkylation of acetanilides; \u0000arylation of cycloalkenes; \u0000allylic acetoxylation; \u0000oxidative coupling of alkenylstannanes; \u0000lactonization of dienes by 1,4-functionation; \u00001,3,5-trienes; \u0000cyclization of o-iodophenyl allyl ethers to benzofurans; \u0000coupling of CH2CHSi(CH3)3 with vinyl iodides; \u0000vinylation of cycloalkenes; \u0000arylannelation of 1,3-dienes; \u0000coupling of ArI and unsaturated epoxides; \u0000bicyclic acetals; \u00001,4-additions to1,3-dienes; \u0000didehydroamino acids; \u0000cyclopentenones from carbohydrates; \u00003-arylcycloalkenes; \u0000coupling of vinyl halides with allylic alcohols; \u0000cyclization of 4,6- and 5,7-dieneamides; \u0000oxaspirocyclic addition to 1,3-dienes; \u0000RCH2CHO RCHCHOCH3 RCHCHCHO; \u0000heck cyclization; \u0000heck-type coupling of allylic alcohols and enol triflates; \u0000coupling of vinyl halides with allyl alcohols; \u0000arylation of allylic alcohols; \u0000hydroacetoxylation of 2-alkynoates; \u0000three-component coupling of alkenes; \u0000heck reaction; \u0000suzuki, stille, and related couplings; \u0000reductive acylation and transesterification; \u00002-benzenesulfenyl-1,3-dienes; \u0000allylic oxidation; \u00001,4-difunctionalization of 1,3-dienes; \u0000cycloisomerization of enynes; \u0000heck reaction; \u0000arylation with onium salts; \u0000suzuki couplings; \u0000carboxylation; \u0000addition to multiple bonds; \u0000oxidation; \u0000heck reaction and other couplings; \u0000addition to multiple bonds; \u0000dehydrogenation of carbonyl compounds; \u0000indoles; \u0000cyclopropanation; \u0000enol ethers; \u0000coupling reactions; \u0000reactions of alkynes; \u0000carbonyl compounds; \u0000miscellaneous reactions; \u0000hydroarylation; \u0000carboxylation; \u0000rearrangement-coupling; \u0000conjugate addition; \u0000coupling reactions; \u0000redox reactions; \u0000vinyl glycosides; \u0000cyclizations; \u0000additions; \u0000allylic displacements; \u0000cyclopropanation; \u0000coupling reactions; \u0000addition reactions; \u0000cyclization reactions; \u0000cyclopentadienone acetals; \u0000oxidation; \u0000ketone synthesis; \u0000racemization; \u0000transan","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":"15 1","pages":"000-000"},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74101192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Molybdenum(V) chloride","authors":"T. Ho, M. Fieser, L. Fieser","doi":"10.1002/9780471264194.FOS11872","DOIUrl":"https://doi.org/10.1002/9780471264194.FOS11872","url":null,"abstract":"This article has no abstract. \u0000 \u0000Keywords: \u0000 \u0000pinacolatoboron B-Benzylation; \u0000MMPP; \u0000manganese(III) acetate; \u0000manganation; \u0000molybdenum-carbyne complexes","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":"9 1","pages":"1-3"},"PeriodicalIF":0.0,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87694077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}