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Analysis of Burning Rate Variation of Tungsten Delay Composition Close to Zero Oxygen Balance 接近零氧平衡时钨延迟成分燃烧速率变化分析
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-02-05 DOI: 10.1002/fam.3279
Yuan-Gen Lu, Bo Hao, Geng Chen, Cai-Xian Xu, Li Zhang

Tungsten delay compositions are widely utilized in ammunition, small detonators, and other devices. In this study, we first explored the changes in the burning rate of micron-sized tungsten delay compositions (W/BaCrO4/KClO4) when achieving zero oxygen balance under different material tube walls. Subsequently, SiO2, CuO, BN, and shellac were added to the tungsten delay composition to investigate the burning rate variations of different samples in aluminum tubes. The experimental results reveal that the combustion rate of the tungsten delay composition decreases with an increase in the thermal conductivity of the tube wall. The content of BN exhibits a linear relationship with the combustion rate of the tungsten delay composition, the combustion rate of the tungsten delay composition decreases with the increase of the mass percentage of BN. A small amount of SiO2, CuO, and shellac accelerates the combustion rate of the tungsten delay composition, but the combustion rate decreases as the content of these additives increases. The conclusion of this study can provide a wider range of delay times for delay devices with significant spatial limitations.

钨延迟药广泛应用于弹药、小型雷管和其他装置中。在本研究中,我们首先探索了在不同材料管壁下达到零氧平衡时微米级钨延迟成分(W/BaCrO4/KClO4)燃烧速率的变化。随后,在钨延迟剂中加入SiO2、CuO、BN和紫胶,研究不同样品在铝管中的燃烧速率变化。实验结果表明,钨延燃剂的燃烧速率随管壁热导率的增大而减小。BN的含量与延迟剂的燃烧速率呈线性关系,随着BN质量百分比的增加,延迟剂的燃烧速率降低。少量的SiO2、CuO和紫胶可以加速钨延迟剂的燃烧速度,但随着添加量的增加,燃烧速度降低。本研究的结论可以为具有明显空间限制的延迟器件提供更广泛的延迟时间范围。
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引用次数: 0
Effect of Ammonium Polyphosphate/Silicate Content on the Postfire Mechanics of Epoxy Glass-Fiber Composites Using Facile Chocolate Bar-Inspired Structures 聚磷酸铵/硅酸盐含量对巧克力棒结构环氧玻璃纤维复合材料火后力学的影响
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-02-03 DOI: 10.1002/fam.3280
Sruthi Sunder, Maria Jauregui Rozo, Sneha Inasu, Dietmar Meinel, Bernhard Schartel, Holger Ruckdäschel

This study investigates the postfire mechanical properties of epoxy glass-fiber reinforced composites (EP GFRCs) using increasing concentrations of ammonium polyphosphate (APP) and inorganic silicate (InSi) to modify the char and fire residue. A facile chocolate bar-inspired structure was introduced for fire exposure and subsequent flexural testing of the GFRCs. The resin matrix used here was a diglycidyl ether of bisphenol-A (DGEBA) resin, cured with dicyandiamide (DICY), and accelerated by Urone. The microstructures of the degraded composites after three-point bending tests, were evaluated using scanning electron microscopy (SEM) and x-ray computed tomography (XCT) imaging. A previous study showed that increasing the APP and InSi content significantly enhanced flame retardancy, via improved char formation under fire conditions. However, flexural properties and fire resistance were adversely affected after fire exposure, highlighting a trade-off effect. Fiber breakage and delamination of the composites increased upon failure with increasing APP + InSi content in the composite due to unconsolidated char. The experimental values for the postfire flexural mechanics were in good agreement with the two-layer model proposed in literature. This paper presents a preliminary basis for postfire mechanical testing of epoxy composites for use in fire-safe structures, using a combination of standardized testing norms.

本研究通过增加聚磷酸铵(APP)和无机硅酸盐(InSi)的浓度来改性环氧玻璃纤维增强复合材料(EP GFRCs)的炭和火渣,研究了环氧玻璃纤维增强复合材料(EP GFRCs)的火灾后力学性能。一个简单的巧克力棒式结构被引入,用于GFRCs的火灾暴露和随后的弯曲测试。本研究使用的树脂基体为双酚a二缩水甘油酯(DGEBA)树脂,用双氰胺(DICY)固化,并用脲酮加速。通过扫描电子显微镜(SEM)和x射线计算机断层扫描(XCT)成像,对三点弯曲后降解复合材料的微观结构进行了评估。先前的一项研究表明,增加APP和InSi含量可以通过改善着火条件下的成焦而显著提高阻燃性。然而,火灾暴露后,弯曲性能和耐火性受到不利影响,突出了权衡效应。随着复合材料中APP + InSi含量的增加,复合材料的纤维断裂和分层现象随着破坏而增加。火灾后弯曲力学的实验值与文献中提出的两层模型吻合较好。本文提出了防火结构用环氧复合材料火灾后力学性能测试的初步依据,并结合了标准化测试规范。
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引用次数: 0
Fire Hazard of Fiber Dust Layers With Different Widths and Inclination Angles Exposed to Simulated Hotspots 不同宽度和倾角纤维粉尘层暴露于模拟热点的火灾危险性
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-20 DOI: 10.1002/fam.3277
Jinglin Zhang, Zhenguo Du, Qi Yuan, Chang Li, Shixun Ding, Gang Li, Chunmiao Yuan

Fiber dust's flocculent structure often leads to underestimation of its potential for fire and explosion. In order to compare the fire hazards of fiber dust layers with different widths and inclination angles exposed to simulated hotspots with traditional powdered dust layers. The current research systematically studied the flame spread characteristics of flax, paper scraps, and wood dust with widths of 20, 30, 40, 50, and 60 mm at inclination angles of 0°, −10°, −20°, −30° and −40°. Studies have found that at different widths and inclination angles, flax dust has a higher flame spread velocity than wood powder, and even metal powder. Under the coupling effect of the width and inclination angle of the countercurrent flame, the inclination angle has a significant impact on the flame spread velocity of the countercurrent flame. Flax fiber dust has a significantly higher fire hazard than conventional dust. These findings should be taken into account in the industrial processes of handling flax fiber dust.

纤维粉尘的絮状结构往往导致其火灾和爆炸的可能性被低估。为了比较不同宽度和倾角的纤维粉尘层与传统粉末粉尘层暴露在模拟热点下的火灾危险性。本研究系统地研究了宽度为20、30、40、50和60 mm的亚麻、纸屑和木屑在倾角为0°、−10°、−20°、−30°和−40°时的火焰蔓延特性。研究发现,在不同宽度和倾斜角下,亚麻粉的火焰传播速度高于木粉,甚至高于金属粉。在逆流火焰宽度和倾斜角的耦合作用下,倾斜角对逆流火焰的火焰传播速度有显著影响。亚麻纤维粉尘的火灾危险性明显高于常规粉尘。这些发现应在处理亚麻纤维粉尘的工业过程中加以考虑。
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引用次数: 0
How to Approach the Definition of WUI in Northern Europe 北欧地区如何界定无水上网
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-16 DOI: 10.1002/fam.3264
Javier Elio Medina, Frida Vermina Plathner, Elsa Pastor, Nieves Fernandez-Anez

This article aims to delineate the wildland–urban interface in the sparsely populated, limited-resourced Scandinavian peninsula (excluding Finland). Common WUI mapping assumptions and how different thresholds capture the reality of building ignition from wildfire in this region are evaluated. We show that dedicated fuel maps capture areas at risk slightly better than vegetation maps, although the choice of map per se is less important than the selected limit for possible ember transport. The commonly used 6.17 buildings/km2 threshold for building density fails to capture most wildfire incidents that have led to building ignition.

本文旨在描绘人口稀少、资源有限的斯堪的纳维亚半岛(芬兰除外)的荒地-城市界面。评估了常见的WUI映射假设以及不同阈值如何捕获该地区野火引起的建筑物着火的现实。我们表明,专用燃料图比植被图更好地捕获有风险的区域,尽管地图本身的选择不如可能的余烬运输的选择限制重要。通常使用的建筑密度阈值为6.17个建筑/平方公里,这一阈值无法捕获大多数导致建筑物着火的野火事件。
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引用次数: 0
Laboratory-Scale Assessment of Carbon-Epoxy Structural U-Channels Exposed to Flange Heating 暴露在法兰加热下的碳-环氧结构u型通道的实验室规模评估
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-09 DOI: 10.1002/fam.3262
Tim J. Aspinall, Emmajane L. Erskine, Kevin A. Denham, Derek C. Taylor, Rory M. Hadden

This study investigates the combined thermal and mechanical response of pre-loaded woven carbon-epoxy U-channels subjected to radiant heating conditions similar to those experienced by aircraft structures in the event of a fire. A custom-built laboratory scale test rig was used to combine the mechanical loads and thermal boundary conditions. The main experimental aim was to measure failure times, failure modes, displacement and temperature distribution of the U-channels. The results show that the U-channels undergo multiple phases of decomposition when exposed to heat. These phases include physico-chemical changes such as bubble formation, visible charring, and epoxy resin pyrolysis. Additionally, the U-channels experience mechanical degradation through thermal-induced delamination and torsional deformation, causing the flange furthest from the heat source to buckle. The rate of decomposition and loss of load-bearing capacity are directly proportional to heat flux, with higher heat fluxes accelerating these processes. Analysis of displacement data reveals that higher heat fluxes correlate with lower displacement variability over time for U-channels under identical thermal conditions. Temperature measurements indicate that higher heat fluxes result in higher temperatures but lower temperature gradients, directly influencing failure times and modes. Consequently, higher temperatures lead to shorter failure times, while lower temperatures extend failure times. The findings from this study will provide valuable knowledge to inform optimised approaches, especially in the domain of aircraft structural fire safety.

本研究研究了预加载的编织碳环氧树脂u型通道在类似于飞机结构在火灾中所经历的辐射加热条件下的热学和力学综合响应。采用定制的实验室规模试验装置,对机械载荷和热边界条件进行了综合试验。实验的主要目的是测量u型通道的失效次数、失效模式、位移和温度分布。结果表明,u型通道受热后发生多相分解。这些阶段包括物理化学变化,如气泡形成、可见炭化和环氧树脂热解。此外,u型通道会因热引起的分层和扭转变形而发生机械退化,导致离热源最远的法兰发生屈曲。分解和承载能力丧失的速度与热流成正比,较高的热流加速了这些过程。对位移数据的分析表明,在相同的热条件下,较高的热通量与较低的位移随时间变化相关。温度测量表明,较高的热流导致较高的温度,但较低的温度梯度,直接影响故障时间和模式。因此,较高的温度会缩短失效时间,而较低的温度会延长失效时间。这项研究的结果将为优化方法提供有价值的知识,特别是在飞机结构消防安全领域。
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引用次数: 0
New Laboratory Results on Ignition and Propagation in Live Vegetation Paving the Road to a Semi-Empirical Model 活体植被点火和繁殖的新实验结果为建立半经验模型铺平了道路
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-09 DOI: 10.1002/fam.3273
Bruno Guillaume, Anne Ganteaume, Malek Majeri, Jacky Fayad, Mohamad El Houssami, Yannick Pizzo, Bernard Porterie

Wildfires arriving at a brush-cleared vegetation near vulnerable assets in the Wildland-Urban Interface (WUI), experience significantly reduced fire propagation, intensity, and associated risks. However, assessing the effectiveness of fuel reduction on fire behavior remains challenging due to limited understanding of ignition and propagation mechanisms in live vegetation. To fill this gap, a simplified approach was designed, focusing more on the combination of physical modeling with new empirical data rather than providing new insight in the physical process modeling. Burning experiments were conducted on cypress trees at two scales of live vegetation, the “laboratory scale” and the “real scale,” to gather data on fire behavior in cypress canopies with varying fuel moisture content (FMC) and bulk density (BD), using two ignition methods. A semi-empirical model, based on the physical model Fire Dynamic Simulator was developed, using the “laboratory scale” data as inputs, while the data recorded at “real scale” were used to validate the model. Laboratory-scale experiments showed consistent results when ignition was initiated by flame contact. In contrast, indirect radiant heat ignition was highly variable due to the influence of gaps between leaves. At the real scale, BD had a significant impact on fire behavior. The model evaluation showed it could simulate fire auto-propagation in live vegetation much more precisely compared to current physical models, leveraging the precise fire behavior data obtained at the laboratory scale.

野火到达荒地-城市界面(WUI)脆弱资产附近的灌木丛清除植被时,火灾的传播、强度和相关风险显著降低。然而,由于对活植被的点火和传播机制的了解有限,评估燃料减少对火灾行为的有效性仍然具有挑战性。为了填补这一空白,设计了一种简化的方法,更多地关注物理建模与新的经验数据的结合,而不是在物理过程建模中提供新的见解。在“实验室尺度”和“实际尺度”两种活植被尺度上对柏树进行了燃烧实验,以收集不同燃料含水率(FMC)和体积密度(BD)的柏树冠层在两种点火方法下的燃烧行为数据。在火灾动态模拟器物理模型的基础上,以“实验室规模”数据为输入,以“实际规模”数据为输入,建立了半经验模型。实验室规模的实验表明,当点火是由火焰接触引起的一致的结果。相反,间接辐射热点燃由于叶片间隙的影响而变化很大。在真实尺度下,BD对火灾行为有显著影响。模型评估表明,与目前的物理模型相比,利用在实验室尺度上获得的精确火灾行为数据,该模型可以更精确地模拟活植被中的火灾自动传播。
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引用次数: 0
Hot-Particle Ignition of Typical Fuels in the Wildland-Urban Interface and Subsequent Fire Behaviors 典型燃料在荒地-城市界面中的热粒子点火及随后的燃烧行为
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-09 DOI: 10.1002/fam.3276
Kaifeng Wang, Supan Wang, Xinyan Huang

The hot-particle ignition is a common cause of wildland and building fires. This study investigates the ignition of three typical fuels (straw, pine needles, and cotton) in the wildland-urban interface (WUI) by a hot metal particle of different temperatures and void ratios. In the absence of wind, the ignition of cotton is the easiest, where a flame occurs directly without clear smoldering. As the particle becomes hollow, the required minimum particle temperature for igniting cotton becomes smaller, because of a longer contact time between particle and fuel surface. Once ignited, the flaming of cotton is the weakest, with a mass loss of less than 25% because of an intensive charring. The burning of straw and pine needles is intense, with a large flame height and very little residue. Materials with finer and thinner structure like cotton are easy to initiate a flame by a hot particle while hard to sustain smoldering ignition. The hollow-structure or large-porosity materials like straw are prone to smoldering ignition under a weaker spot heating source. The fast-cooling void particles cannot induce a smoldering ignition of all three WUI fuels, because smoldering ignition requires a longer effective heating duration. This study helps understand the ignition propensity of WUI fuels by a hot particle and the subsequent flame-spread and burning process, which supports the fire protection design for WUI communities.

热粒子点火是引起荒地和建筑物火灾的常见原因。本文研究了不同温度和空隙比的热金属颗粒在荒地-城市界面(WUI)中点燃三种典型燃料(稻草、松针和棉花)的情况。在没有风的情况下,点燃棉花是最容易的,火焰直接发生,没有明显的阴燃。随着颗粒变得空心,点燃棉花所需的最低颗粒温度变得更小,因为颗粒与燃料表面之间的接触时间更长。一旦点燃,棉花的火焰是最弱的,由于强烈的炭化,质量损失不到25%。秸秆和松针燃烧强烈,火焰高度大,残留物很少。像棉花这样结构更细、更薄的材料很容易被热颗粒点燃火焰,而很难持续阴燃。空心结构或大孔隙率的材料如稻草,在较弱的点热源下容易阴燃着火。快速冷却的空隙颗粒不能诱导所有三种WUI燃料的阴燃点火,因为阴燃点火需要更长的有效加热持续时间。本研究有助于了解WUI燃料被热颗粒点燃的倾向以及随后的火焰蔓延和燃烧过程,为WUI社区的防火设计提供支持。
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引用次数: 0
A Comparative Study of Ignitibility and Combustibility Properties of Four Algerian Plants: Application to Wildland Fuels Classification 阿尔及利亚四种植物的可燃性和可燃性比较研究:在野外燃料分类中的应用
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-08 DOI: 10.1002/fam.3274
F. Z. Krim, N. Zekri, H. Boutchiche, O. Mosbah, S. Sahraoui

To seek a fire-resistant fuel, the reaction to fire of Algerian Phoenix dactylifera leaves known for their thermal resistance was compared to that of three highly flammable Algerian fuel particles: Eucalyptus globulus leaves and Pinus halepensis and Pinus canariensis needles. By using a small-scale cone calorimeter, their thermal properties were investigated under a low irradiance of � � � � � � 3.5� � � � kW� � /� � � � m� � 2, while their ignition and combustion properties were examined with irradiances of � � � � � � 17.5 and � � � � � � 50� � � � kW� � /� � � � m� � 2. Eucalyptus globulus leaves were found the most ignitable fuels with the largest released heat, while Phoenix dactylifera leaves were found by far the least ignitable fuels with the smallest released heat, particularly under large heat flux intensities. Based on a theoretical analysis of thermal and ignition properties, a new flammability/spreading index combining the ignitability and combustibility metrics was proposed to rank these fuels. This index was compared with the fire retardancy index used for polymer composites and adapted to these plants because it uses a cone calorimeter. A similar ranking order was obtained between the two indices for the considered fuels, where Eucalyptus globulus leaves were found by far the most fire-spreading fuels particularly at large fire intensity. On the other hand, Phoenix dactylifera leaves appeared by far the least fire-spreading fuels particularly at large fire intensity. The possible use of <

为了寻找一种耐火燃料,我们将以耐热性而闻名的阿尔及利亚凤凰dactylifera叶片与三种高度易燃的阿尔及利亚燃料颗粒(尤加利桉叶、halepensis松和canariensis松针)的燃烧反应进行了比较。通过使用小型锥形热量计,在3.5 kW / m2的低辐照度下研究了它们的热性能;在17.5和50 kW /的辐照度下测试了它们的点火和燃烧性能m2。尤加利(Eucalyptus globulus)的叶子被发现是最易燃的燃料,释放的热量最大,而凤凰(Phoenix dactylifera)的叶子被发现是迄今为止最不易燃的燃料,释放的热量最小,特别是在大热通量强度下。在对燃料的热、燃特性进行理论分析的基础上,提出了一种结合可燃性和可燃性指标的可燃性/蔓延指数。该指数与用于聚合物复合材料的阻燃指数进行了比较,并适用于这些植物,因为它使用了锥形量热计。在考虑的燃料的两个指数之间获得了类似的排名顺序,其中尤加利球状树叶被发现是迄今为止最具火势蔓延的燃料,特别是在大火灾强度下。另一方面,在大火强度较大的情况下,凤尾草的叶子是迄今为止火势蔓延最小的燃料。本文讨论了凤凰树作为极端阻燃剂在荒地燃料管理中的应用,以及在荒地-城市交界面的应用,但这些结果还有待于大规模的证实。
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引用次数: 0
Characterisation of Hedge Burning in the Context of Wildland Urban Interface (WUI) Fire Prevention 林地城市界面(WUI)防火背景下的树篱燃烧特征
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-08 DOI: 10.1002/fam.3266
Virginie Tihay-Felicelli, Karina Meerpoel-Pietri, Paul-Antoine Santoni, Yolanda Perez-Ramirez, Anthony Graziani, Frédéric Morandini, Camille Luciani, William Mell, Alexander Maranghides

With global warming, the wildfire season tends to get longer, causing fatalities and devastating damage to human property. Although many countries have implemented fire risk prevention measures, particularly in Wildland Urban Interfaces (WUI), this finding shows that there are weaknesses in the prevention measures. This is mainly due to a lack of knowledge about WUI fire exposure conditions. This paper presents field-scale experiments to characterise the burning of rockrose-reconstructed hedges (6 × 1 × 1 m) close to a building in order to provide experimental data on heat release rate (HRR), flame front geometry, and heat fluxes to the building. The mean horizontal flame extent was 4.4 (±0.7) m with values up to 5.5 m. These values are generally higher than the minimum distance to be maintained between vegetation and buildings in most countries. The fire intensity ranged from 283 to 3479 kW/m, resulting in maximum values at 3 m from the hedge of up to 45.4 kW/m2 for the total heat flux and 38.1 kW/m2 for the radiant heat flux. However, the flame duration is short, averaging 112.8 (±27.1) s. This type of exposure is far from those used to test the fire resistance worldwide. Therefore, the data obtained in this study are crucial for improving fire risk prevention methods worldwide, whether for fuel management in defensible zones or for testing building materials to make buildings more resistant to wildfires.

随着全球变暖,野火季节往往变得更长,造成人员死亡和对人类财产的毁灭性破坏。尽管许多国家已经实施了火灾风险预防措施,特别是在荒地城市界面(WUI),但这一发现表明预防措施存在弱点。这主要是由于缺乏对WUI火灾暴露条件的了解。本文提出了一种野外尺度的实验,以表征岩石玫瑰重建的树篱(6 × 1 × 1 m)在建筑物附近燃烧的特征,以提供热释放率(HRR)、火焰前缘几何形状和建筑物热流的实验数据。平均水平火焰范围为4.4(±0.7)m,最高可达5.5 m。在大多数国家,这些值通常高于植被与建筑物之间保持的最小距离。火灾强度范围为283至3479 kW/m,导致距离树篱3 m处的总热流密度最大值可达45.4 kW/m2,辐射热通量最大值可达38.1 kW/m2。然而,火焰持续时间很短,平均112.8(±27.1)秒。这种类型的暴露与世界范围内用于测试耐火性的方法相差甚远。因此,本研究获得的数据对于改善世界范围内的火灾风险预防方法至关重要,无论是用于防御区的燃料管理还是用于测试建筑材料以使建筑物更耐野火。
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引用次数: 0
Comprehensive Experimental Studies on Smoldering Characteristics of Forest Soil from pinus sylvestris Vegetation 森林土壤阴燃特性的综合实验研究
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-08 DOI: 10.1002/fam.3275
Lukas Heydick, Kira Piechnik, Andrea Klippel

Smoldering combustion, often linked with forest fires in coniferous forests, pose significant health and environmental risks, particularly in densely populated countries like Germany, where these fires commonly occur in wildland–urban interface (WUI) areas. This study investigates the combustion characteristics of Pinus sylvestris soil, focusing on the underlying processes and thermal behavior. The aim is to provide a comprehensive analysis of smoldering combustion in pine forest soil, with a specific focus on fire-exposed soil horizons. The research integrates soil characterization, elemental analysis, heat of combustion determination, and thermogravimetric analysis (TGA) of pine soil fractions ranging from < 0.063 to > 4 mm, conducted under both air and nitrogen atmospheres. The derivative thermogravimetry (DTG) curves reveal that the fastest mass loss occurs during pyrolysis, with peak temperatures between 240°C and 280°C. Activation energies (E a ) were calculated using the Kissinger–Akahira–Sunose (KAS) and Flynn–Wall–Ozawa (FWO) methods. The highest activation energies were observed between conversion rates of 0.2 and 0.4. Activation energies at peak temperatures for all fractions were determined using the Kissinger method. Residue analysis reveals significant variations in organic content, ranging from 22.6% to 92.7%. The findings demonstrate that German-typical pine soil is prone to smoldering combustion, highlighting processes determined as preheating, drying, pyrolysis, and oxidation. As part of the German Pilot of the EUs TREEADS project, this study provides essential data for numerical simulations, emphasizing the need to consider both physical and chemical properties of soil fractions to mitigate the impact of smoldering fires in pine forest ecosystems.

阴燃通常与针叶林的森林火灾有关,造成重大的健康和环境风险,特别是在德国等人口稠密的国家,这些火灾通常发生在荒地-城市界面地区。本文研究了松林土壤的燃烧特性,重点研究了燃烧过程和热行为。目的是提供一个全面的分析阴燃在松林土壤,特别侧重于火暴露的土壤水平。该研究整合了土壤特征、元素分析、燃烧热测定和热重分析(TGA),在空气和氮气氛下进行了范围为0.063至4毫米的松土组分。导数热重(DTG)曲线显示,热解过程中质量损失最快,峰值温度在240 ~ 280℃之间。采用Kissinger-Akahira-Sunose (KAS)和Flynn-Wall-Ozawa (FWO)方法计算活化能(ea)。转化率为0.2 ~ 0.4时,活化能最高。用Kissinger法测定了各组分在峰值温度下的活化能。残留分析显示有机含量差异显著,从22.6%到92.7%不等。研究结果表明,德国典型的松土容易阴燃,突出的过程确定为预热,干燥,热解和氧化。作为欧盟TREEADS项目德国试点项目的一部分,本研究为数值模拟提供了必要的数据,强调需要考虑土壤组分的物理和化学性质,以减轻阴燃火灾对松林生态系统的影响。
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Fire and Materials
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