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Laboratory-Scale Assessment of Carbon-Epoxy Structural U-Channels Exposed to Flange Heating 暴露在法兰加热下的碳-环氧结构u型通道的实验室规模评估
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-09 DOI: 10.1002/fam.3262
Tim J. Aspinall, Emmajane L. Erskine, Kevin A. Denham, Derek C. Taylor, Rory M. Hadden

This study investigates the combined thermal and mechanical response of pre-loaded woven carbon-epoxy U-channels subjected to radiant heating conditions similar to those experienced by aircraft structures in the event of a fire. A custom-built laboratory scale test rig was used to combine the mechanical loads and thermal boundary conditions. The main experimental aim was to measure failure times, failure modes, displacement and temperature distribution of the U-channels. The results show that the U-channels undergo multiple phases of decomposition when exposed to heat. These phases include physico-chemical changes such as bubble formation, visible charring, and epoxy resin pyrolysis. Additionally, the U-channels experience mechanical degradation through thermal-induced delamination and torsional deformation, causing the flange furthest from the heat source to buckle. The rate of decomposition and loss of load-bearing capacity are directly proportional to heat flux, with higher heat fluxes accelerating these processes. Analysis of displacement data reveals that higher heat fluxes correlate with lower displacement variability over time for U-channels under identical thermal conditions. Temperature measurements indicate that higher heat fluxes result in higher temperatures but lower temperature gradients, directly influencing failure times and modes. Consequently, higher temperatures lead to shorter failure times, while lower temperatures extend failure times. The findings from this study will provide valuable knowledge to inform optimised approaches, especially in the domain of aircraft structural fire safety.

本研究研究了预加载的编织碳环氧树脂u型通道在类似于飞机结构在火灾中所经历的辐射加热条件下的热学和力学综合响应。采用定制的实验室规模试验装置,对机械载荷和热边界条件进行了综合试验。实验的主要目的是测量u型通道的失效次数、失效模式、位移和温度分布。结果表明,u型通道受热后发生多相分解。这些阶段包括物理化学变化,如气泡形成、可见炭化和环氧树脂热解。此外,u型通道会因热引起的分层和扭转变形而发生机械退化,导致离热源最远的法兰发生屈曲。分解和承载能力丧失的速度与热流成正比,较高的热流加速了这些过程。对位移数据的分析表明,在相同的热条件下,较高的热通量与较低的位移随时间变化相关。温度测量表明,较高的热流导致较高的温度,但较低的温度梯度,直接影响故障时间和模式。因此,较高的温度会缩短失效时间,而较低的温度会延长失效时间。这项研究的结果将为优化方法提供有价值的知识,特别是在飞机结构消防安全领域。
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引用次数: 0
New Laboratory Results on Ignition and Propagation in Live Vegetation Paving the Road to a Semi-Empirical Model 活体植被点火和繁殖的新实验结果为建立半经验模型铺平了道路
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-09 DOI: 10.1002/fam.3273
Bruno Guillaume, Anne Ganteaume, Malek Majeri, Jacky Fayad, Mohamad El Houssami, Yannick Pizzo, Bernard Porterie

Wildfires arriving at a brush-cleared vegetation near vulnerable assets in the Wildland-Urban Interface (WUI), experience significantly reduced fire propagation, intensity, and associated risks. However, assessing the effectiveness of fuel reduction on fire behavior remains challenging due to limited understanding of ignition and propagation mechanisms in live vegetation. To fill this gap, a simplified approach was designed, focusing more on the combination of physical modeling with new empirical data rather than providing new insight in the physical process modeling. Burning experiments were conducted on cypress trees at two scales of live vegetation, the “laboratory scale” and the “real scale,” to gather data on fire behavior in cypress canopies with varying fuel moisture content (FMC) and bulk density (BD), using two ignition methods. A semi-empirical model, based on the physical model Fire Dynamic Simulator was developed, using the “laboratory scale” data as inputs, while the data recorded at “real scale” were used to validate the model. Laboratory-scale experiments showed consistent results when ignition was initiated by flame contact. In contrast, indirect radiant heat ignition was highly variable due to the influence of gaps between leaves. At the real scale, BD had a significant impact on fire behavior. The model evaluation showed it could simulate fire auto-propagation in live vegetation much more precisely compared to current physical models, leveraging the precise fire behavior data obtained at the laboratory scale.

野火到达荒地-城市界面(WUI)脆弱资产附近的灌木丛清除植被时,火灾的传播、强度和相关风险显著降低。然而,由于对活植被的点火和传播机制的了解有限,评估燃料减少对火灾行为的有效性仍然具有挑战性。为了填补这一空白,设计了一种简化的方法,更多地关注物理建模与新的经验数据的结合,而不是在物理过程建模中提供新的见解。在“实验室尺度”和“实际尺度”两种活植被尺度上对柏树进行了燃烧实验,以收集不同燃料含水率(FMC)和体积密度(BD)的柏树冠层在两种点火方法下的燃烧行为数据。在火灾动态模拟器物理模型的基础上,以“实验室规模”数据为输入,以“实际规模”数据为输入,建立了半经验模型。实验室规模的实验表明,当点火是由火焰接触引起的一致的结果。相反,间接辐射热点燃由于叶片间隙的影响而变化很大。在真实尺度下,BD对火灾行为有显著影响。模型评估表明,与目前的物理模型相比,利用在实验室尺度上获得的精确火灾行为数据,该模型可以更精确地模拟活植被中的火灾自动传播。
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引用次数: 0
Hot-Particle Ignition of Typical Fuels in the Wildland-Urban Interface and Subsequent Fire Behaviors 典型燃料在荒地-城市界面中的热粒子点火及随后的燃烧行为
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-09 DOI: 10.1002/fam.3276
Kaifeng Wang, Supan Wang, Xinyan Huang

The hot-particle ignition is a common cause of wildland and building fires. This study investigates the ignition of three typical fuels (straw, pine needles, and cotton) in the wildland-urban interface (WUI) by a hot metal particle of different temperatures and void ratios. In the absence of wind, the ignition of cotton is the easiest, where a flame occurs directly without clear smoldering. As the particle becomes hollow, the required minimum particle temperature for igniting cotton becomes smaller, because of a longer contact time between particle and fuel surface. Once ignited, the flaming of cotton is the weakest, with a mass loss of less than 25% because of an intensive charring. The burning of straw and pine needles is intense, with a large flame height and very little residue. Materials with finer and thinner structure like cotton are easy to initiate a flame by a hot particle while hard to sustain smoldering ignition. The hollow-structure or large-porosity materials like straw are prone to smoldering ignition under a weaker spot heating source. The fast-cooling void particles cannot induce a smoldering ignition of all three WUI fuels, because smoldering ignition requires a longer effective heating duration. This study helps understand the ignition propensity of WUI fuels by a hot particle and the subsequent flame-spread and burning process, which supports the fire protection design for WUI communities.

热粒子点火是引起荒地和建筑物火灾的常见原因。本文研究了不同温度和空隙比的热金属颗粒在荒地-城市界面(WUI)中点燃三种典型燃料(稻草、松针和棉花)的情况。在没有风的情况下,点燃棉花是最容易的,火焰直接发生,没有明显的阴燃。随着颗粒变得空心,点燃棉花所需的最低颗粒温度变得更小,因为颗粒与燃料表面之间的接触时间更长。一旦点燃,棉花的火焰是最弱的,由于强烈的炭化,质量损失不到25%。秸秆和松针燃烧强烈,火焰高度大,残留物很少。像棉花这样结构更细、更薄的材料很容易被热颗粒点燃火焰,而很难持续阴燃。空心结构或大孔隙率的材料如稻草,在较弱的点热源下容易阴燃着火。快速冷却的空隙颗粒不能诱导所有三种WUI燃料的阴燃点火,因为阴燃点火需要更长的有效加热持续时间。本研究有助于了解WUI燃料被热颗粒点燃的倾向以及随后的火焰蔓延和燃烧过程,为WUI社区的防火设计提供支持。
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引用次数: 0
A Comparative Study of Ignitibility and Combustibility Properties of Four Algerian Plants: Application to Wildland Fuels Classification 阿尔及利亚四种植物的可燃性和可燃性比较研究:在野外燃料分类中的应用
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-08 DOI: 10.1002/fam.3274
F. Z. Krim, N. Zekri, H. Boutchiche, O. Mosbah, S. Sahraoui

To seek a fire-resistant fuel, the reaction to fire of Algerian Phoenix dactylifera leaves known for their thermal resistance was compared to that of three highly flammable Algerian fuel particles: Eucalyptus globulus leaves and Pinus halepensis and Pinus canariensis needles. By using a small-scale cone calorimeter, their thermal properties were investigated under a low irradiance of � � � � � � 3.5� � � � kW� � /� � � � m� � 2, while their ignition and combustion properties were examined with irradiances of � � � � � � 17.5 and � � � � � � 50� � � � kW� � /� � � � m� � 2. Eucalyptus globulus leaves were found the most ignitable fuels with the largest released heat, while Phoenix dactylifera leaves were found by far the least ignitable fuels with the smallest released heat, particularly under large heat flux intensities. Based on a theoretical analysis of thermal and ignition properties, a new flammability/spreading index combining the ignitability and combustibility metrics was proposed to rank these fuels. This index was compared with the fire retardancy index used for polymer composites and adapted to these plants because it uses a cone calorimeter. A similar ranking order was obtained between the two indices for the considered fuels, where Eucalyptus globulus leaves were found by far the most fire-spreading fuels particularly at large fire intensity. On the other hand, Phoenix dactylifera leaves appeared by far the least fire-spreading fuels particularly at large fire intensity. The possible use of <

为了寻找一种耐火燃料,我们将以耐热性而闻名的阿尔及利亚凤凰dactylifera叶片与三种高度易燃的阿尔及利亚燃料颗粒(尤加利桉叶、halepensis松和canariensis松针)的燃烧反应进行了比较。通过使用小型锥形热量计,在3.5 kW / m2的低辐照度下研究了它们的热性能;在17.5和50 kW /的辐照度下测试了它们的点火和燃烧性能m2。尤加利(Eucalyptus globulus)的叶子被发现是最易燃的燃料,释放的热量最大,而凤凰(Phoenix dactylifera)的叶子被发现是迄今为止最不易燃的燃料,释放的热量最小,特别是在大热通量强度下。在对燃料的热、燃特性进行理论分析的基础上,提出了一种结合可燃性和可燃性指标的可燃性/蔓延指数。该指数与用于聚合物复合材料的阻燃指数进行了比较,并适用于这些植物,因为它使用了锥形量热计。在考虑的燃料的两个指数之间获得了类似的排名顺序,其中尤加利球状树叶被发现是迄今为止最具火势蔓延的燃料,特别是在大火灾强度下。另一方面,在大火强度较大的情况下,凤尾草的叶子是迄今为止火势蔓延最小的燃料。本文讨论了凤凰树作为极端阻燃剂在荒地燃料管理中的应用,以及在荒地-城市交界面的应用,但这些结果还有待于大规模的证实。
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引用次数: 0
Characterisation of Hedge Burning in the Context of Wildland Urban Interface (WUI) Fire Prevention 林地城市界面(WUI)防火背景下的树篱燃烧特征
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-08 DOI: 10.1002/fam.3266
Virginie Tihay-Felicelli, Karina Meerpoel-Pietri, Paul-Antoine Santoni, Yolanda Perez-Ramirez, Anthony Graziani, Frédéric Morandini, Camille Luciani, William Mell, Alexander Maranghides

With global warming, the wildfire season tends to get longer, causing fatalities and devastating damage to human property. Although many countries have implemented fire risk prevention measures, particularly in Wildland Urban Interfaces (WUI), this finding shows that there are weaknesses in the prevention measures. This is mainly due to a lack of knowledge about WUI fire exposure conditions. This paper presents field-scale experiments to characterise the burning of rockrose-reconstructed hedges (6 × 1 × 1 m) close to a building in order to provide experimental data on heat release rate (HRR), flame front geometry, and heat fluxes to the building. The mean horizontal flame extent was 4.4 (±0.7) m with values up to 5.5 m. These values are generally higher than the minimum distance to be maintained between vegetation and buildings in most countries. The fire intensity ranged from 283 to 3479 kW/m, resulting in maximum values at 3 m from the hedge of up to 45.4 kW/m2 for the total heat flux and 38.1 kW/m2 for the radiant heat flux. However, the flame duration is short, averaging 112.8 (±27.1) s. This type of exposure is far from those used to test the fire resistance worldwide. Therefore, the data obtained in this study are crucial for improving fire risk prevention methods worldwide, whether for fuel management in defensible zones or for testing building materials to make buildings more resistant to wildfires.

随着全球变暖,野火季节往往变得更长,造成人员死亡和对人类财产的毁灭性破坏。尽管许多国家已经实施了火灾风险预防措施,特别是在荒地城市界面(WUI),但这一发现表明预防措施存在弱点。这主要是由于缺乏对WUI火灾暴露条件的了解。本文提出了一种野外尺度的实验,以表征岩石玫瑰重建的树篱(6 × 1 × 1 m)在建筑物附近燃烧的特征,以提供热释放率(HRR)、火焰前缘几何形状和建筑物热流的实验数据。平均水平火焰范围为4.4(±0.7)m,最高可达5.5 m。在大多数国家,这些值通常高于植被与建筑物之间保持的最小距离。火灾强度范围为283至3479 kW/m,导致距离树篱3 m处的总热流密度最大值可达45.4 kW/m2,辐射热通量最大值可达38.1 kW/m2。然而,火焰持续时间很短,平均112.8(±27.1)秒。这种类型的暴露与世界范围内用于测试耐火性的方法相差甚远。因此,本研究获得的数据对于改善世界范围内的火灾风险预防方法至关重要,无论是用于防御区的燃料管理还是用于测试建筑材料以使建筑物更耐野火。
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引用次数: 0
Comprehensive Experimental Studies on Smoldering Characteristics of Forest Soil from pinus sylvestris Vegetation 森林土壤阴燃特性的综合实验研究
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-08 DOI: 10.1002/fam.3275
Lukas Heydick, Kira Piechnik, Andrea Klippel

Smoldering combustion, often linked with forest fires in coniferous forests, pose significant health and environmental risks, particularly in densely populated countries like Germany, where these fires commonly occur in wildland–urban interface (WUI) areas. This study investigates the combustion characteristics of Pinus sylvestris soil, focusing on the underlying processes and thermal behavior. The aim is to provide a comprehensive analysis of smoldering combustion in pine forest soil, with a specific focus on fire-exposed soil horizons. The research integrates soil characterization, elemental analysis, heat of combustion determination, and thermogravimetric analysis (TGA) of pine soil fractions ranging from < 0.063 to > 4 mm, conducted under both air and nitrogen atmospheres. The derivative thermogravimetry (DTG) curves reveal that the fastest mass loss occurs during pyrolysis, with peak temperatures between 240°C and 280°C. Activation energies (E a ) were calculated using the Kissinger–Akahira–Sunose (KAS) and Flynn–Wall–Ozawa (FWO) methods. The highest activation energies were observed between conversion rates of 0.2 and 0.4. Activation energies at peak temperatures for all fractions were determined using the Kissinger method. Residue analysis reveals significant variations in organic content, ranging from 22.6% to 92.7%. The findings demonstrate that German-typical pine soil is prone to smoldering combustion, highlighting processes determined as preheating, drying, pyrolysis, and oxidation. As part of the German Pilot of the EUs TREEADS project, this study provides essential data for numerical simulations, emphasizing the need to consider both physical and chemical properties of soil fractions to mitigate the impact of smoldering fires in pine forest ecosystems.

阴燃通常与针叶林的森林火灾有关,造成重大的健康和环境风险,特别是在德国等人口稠密的国家,这些火灾通常发生在荒地-城市界面地区。本文研究了松林土壤的燃烧特性,重点研究了燃烧过程和热行为。目的是提供一个全面的分析阴燃在松林土壤,特别侧重于火暴露的土壤水平。该研究整合了土壤特征、元素分析、燃烧热测定和热重分析(TGA),在空气和氮气氛下进行了范围为0.063至4毫米的松土组分。导数热重(DTG)曲线显示,热解过程中质量损失最快,峰值温度在240 ~ 280℃之间。采用Kissinger-Akahira-Sunose (KAS)和Flynn-Wall-Ozawa (FWO)方法计算活化能(ea)。转化率为0.2 ~ 0.4时,活化能最高。用Kissinger法测定了各组分在峰值温度下的活化能。残留分析显示有机含量差异显著,从22.6%到92.7%不等。研究结果表明,德国典型的松土容易阴燃,突出的过程确定为预热,干燥,热解和氧化。作为欧盟TREEADS项目德国试点项目的一部分,本研究为数值模拟提供了必要的数据,强调需要考虑土壤组分的物理和化学性质,以减轻阴燃火灾对松林生态系统的影响。
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引用次数: 0
Experimental and Analytical Study on Heat Transfer of Concrete With Different Degrees of Saturation Under Elevated Temperatures 高温下不同饱和度混凝土传热特性的实验与分析研究
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-06 DOI: 10.1002/fam.3270
Jun Deng, Jiajie Cui, Ridho Surahman, Min Tu, Yi Wang

In hygrothermal conditions, structural safety is a major concern because of the occurrence of explosive spalling when concrete structures are exposed to fire. To evaluate the fire damage of concrete accurately, the effect of moisture content and water-to-cement ratio on the thermal conductivity of concrete under elevated temperatures was studied experimentally and analytically in this paper. The experimental results showed that the temperature fields had a significant change among the cases with different water-to-cement ratios while the changes between dried and saturated cases were marginal. The temperature changes of dried samples were slightly swifter than those of saturated one. It indicates that compared with mixture proportions, concrete saturation degree has an insignificant influence on concrete heat transfer in the procedure of fire exposure. Based on the test and analytical results, an analytical model for heat transfer analysis of fire-damaged concrete under hot and humid environments was proposed and showed good agreement with the test results.

在湿热条件下,由于混凝土结构暴露在火灾中会发生爆炸性剥落,因此结构安全是一个主要问题。为了准确评价混凝土的火灾损伤,本文通过实验和分析研究了高温下含水率和水灰比对混凝土导热系数的影响。实验结果表明,不同水灰比情况下的温度场变化显著,而干燥和饱和情况下的温度场变化不大。干燥样品的温度变化略快于饱和样品。结果表明,与混凝土配合比相比,混凝土饱和度对混凝土在火灾暴露过程中的传热影响不显著。在试验和分析结果的基础上,建立了湿热环境下火灾损伤混凝土的传热分析模型,与试验结果吻合较好。
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引用次数: 0
Experimental Studies of the Effects of Recoating on Fire Protection Properties of Old and New Layers of Intumescent Coatings for Steel Elements 重涂对钢构件新、旧膨胀涂层防火性能影响的实验研究
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-01-05 DOI: 10.1002/fam.3271
L. L. Wang, X. Zhu, T. J. Liu

This paper presents the results of experimental studies investigating the effects of recoating on fire protection properties of composite layers of intumescent coatings for steel elements. Intumescent coatings, both with and without topcoats, were applied to steel plates. The samples were subjected to different cycles of hydrothermal aging before recoating. The composite layers of the existing and new coatings were then tested under fire. Comparisons of the morphological structures of the carbonaceous char revealed that the existing coating had little effect on the expansion properties of the new coating. However, the new coating reduced the expansion ratio of the existing coating. The thermal resistance of the existing coating decreased with the increasing thickness of the new coating. For specimens with a new coating 1.0 mm thick, the thermal resistance of the existing coating, after even moderate environmental exposure, was < 20% of the total and can be ignored. Contributions from the existing coating may be considered when specifying the thickness of the new coating if the new coating thickness is small and the existing coating is subjected to moderate environmental aging. Recoating with a different type of intumescent coating from the existing one appeared to provide better fire protection performance than using the same type.

本文介绍了再涂对钢构件膨胀涂层复合层防火性能影响的实验研究结果。膨胀涂层,包括面漆和无面漆,被应用于钢板。在涂层前对样品进行了不同循环的水热老化。然后在火下测试了现有涂层和新涂层的复合层。对炭质炭的形态结构进行比较,发现原有涂层对新涂层的膨胀性能影响不大。然而,新涂层降低了现有涂层的膨胀率。现有涂层的热阻随着新涂层厚度的增加而降低。对于新涂层厚度为1.0 mm的试件,即使在中等环境暴露后,现有涂层的热阻也占总热阻的20%,可以忽略不计。如果新涂层厚度小且现有涂层经受适度的环境老化,则在指定新涂层厚度时可考虑现有涂层的贡献。用一种不同类型的膨胀涂层重新涂覆现有涂层似乎比使用相同类型的涂层提供更好的防火性能。
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引用次数: 0
Postfire Estimation of Heating Temperatures Experienced by Fire Retardant Coatings Using Smartphone Videos and Machine Learning 使用智能手机视频和机器学习对防火涂料的加热温度进行火灾后估计
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-30 DOI: 10.1002/fam.3268
Zhichao Zhu, Weiran Song, Xin Yue, Yihan Lyu, Ji Wang

Accurate estimation of heating temperatures experienced by fire retardant coatings (FRCs) is crucial in identifying the ignition source during fire investigations. While traditional methods, such as spectroscopy, effectively capture the compositional changes in FRC at various heating temperatures, they are typically bulky, costly, and unsuitable for rapid field analysis. This study proposes the use of smartphone and machine learning to predict the heating temperatures of FRC. A smartphone is employed to capture short videos of FRC samples illuminated by its color-changing screen. Video frames are then decomposed into color images and converted into spectral data for further processing. Linear and nonlinear regression models are applied to identify key variables and enhance predictive accuracy. The performance of smartphone-based temperature estimation is compared to that of hyperspectral imaging and laser-induced breakdown spectroscopy. In the test phase, the coefficient of determination for smartphone-based estimation ranges from 0.946 to 0.962, often surpassing that of benchmark methods. These results indicate that smartphones can provide a low-cost, effective means for estimating heating temperatures of FRC in fire investigations.

在火灾调查过程中,准确估算阻燃涂层(FRC)所经历的加热温度对于确定点火源至关重要。虽然光谱分析等传统方法能有效捕捉 FRC 在不同加热温度下的成分变化,但它们通常体积庞大、成本高昂,而且不适合现场快速分析。本研究建议使用智能手机和机器学习来预测热轧卷的加热温度。使用智能手机捕捉 FRC 样品在变色屏幕照射下的短视频。然后将视频帧分解为彩色图像,并转换为光谱数据,以便进一步处理。应用线性和非线性回归模型来确定关键变量并提高预测准确性。将基于智能手机的温度估算性能与高光谱成像和激光诱导击穿光谱法进行了比较。在测试阶段,基于智能手机的温度估算的判定系数从 0.946 到 0.962 不等,往往超过基准方法。这些结果表明,在火灾调查中,智能手机可以提供一种低成本、有效的方法来估算 FRC 的加热温度。
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引用次数: 0
Evolution of Multifunctional Cotton Fabric as the Flame Retardant/Crease Proof/Microbial Resistant Blended With Green Synthesised TiO2 Nanoparticles Coatings 绿色合成纳米TiO2复合涂层阻燃/防皱/抗微生物多功能棉织物的研究进展
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-27 DOI: 10.1002/fam.3272
Karan Kapoor, Sachin Kumar Godara, Veer Singh, Anupreet Kaur

In this work, green synthesised TiO2 nanoparticles' coating was used to improve the fire safety and antibacterial property of 100% cotton fabric. In the first stage, Aloe vera extract was prepared, and subsequently used in the synthesis of TiO2 nanoparticles. The average size of these as-synthesised TiO2 nanoparticles was confirmed to be 16 nm using DLS (dynamic light scattering). Further, XRD (X-ray diffraction) patterns confirmed the successful synthesis of nanoparticles. The vibrational photon of TiO2 was represented by peaks in the FTIR (Fourier transform infrared spectroscopy) spectrum between 450 and 800 cm−1. Subsequently, in an attempt to establish the flame retardant/crease proof/microbial resistant properties of the as-synthesised TiO2 nanoparticles, the TiO2 NPs coated cotton fabric was used for the investigations. Based on the investigations, the bending length (measure of fabric stiffness) value of the coated fabric (%) increased from 2.4 cm (uncoated fabric) to 3.71 cm (at 20% TiO2 coating). Also, the crease recovery angle value increased from 71.8 (uncoated fabric) to 98.6 (20% TiO2 coating), respectively. A vertical flammability test revealed that the burning time decreased from 13.31 s (0%) to 10.84 s (20%), confirming a fire-retardant trait of green synthesised TiO2 nanoparticle coated fabric. Additionally, the disc diffusion method confirmed that the treated coated fabrics exhibit antibacterial properties against both gram-positive and gram-negative bacterial cultures: Escherichia coli and Staphylococcus aureus. This study provides an environmentally benign route for producing versatile cotton fabric blended with bioinspired TiO2 NPs possessing improved flame resistance as well as antibacterial attributes.

本研究采用绿色合成TiO2纳米粒子涂层来提高100%纯棉织物的防火安全性和抗菌性能。首先制备芦荟提取物,然后将其用于TiO2纳米颗粒的合成。利用DLS(动态光散射)证实了这些合成的TiO2纳米颗粒的平均尺寸为16 nm。此外,XRD (x射线衍射)图证实了纳米颗粒的成功合成。TiO2的振动光子在450 ~ 800 cm−1的FTIR(傅里叶变换红外光谱)光谱中表现为峰值。随后,为了确定合成的TiO2纳米颗粒的阻燃/防皱/耐微生物性能,使用TiO2 NPs涂层棉织物进行了研究。结果表明,涂层织物的弯曲长度(织物刚度的度量)值(%)从2.4 cm(未涂层织物)增加到3.71 cm (20% TiO2涂层)。同时,折痕恢复角值从71.8(未涂层)增加到98.6 (20% TiO2涂层)。垂直可燃性测试表明,燃烧时间从13.31 s(0%)减少到10.84 s(20%),证实了绿色合成TiO2纳米颗粒涂层织物的阻燃特性。此外,圆盘扩散法证实,处理后的涂层织物对革兰氏阳性和革兰氏阴性细菌培养物:大肠杆菌和金黄色葡萄球菌都具有抗菌性能。该研究提供了一种环保的途径,用于生产具有提高阻燃性和抗菌特性的生物启发TiO2 NPs混纺的多功能棉织物。
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Fire and Materials
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