首页 > 最新文献

Fire and Materials最新文献

英文 中文
Progress to Develop Globally Harmonized International Testing Standards for Large Outdoor Fires, Including Wildland-Urban Interface Fires 制定大型室外火灾全球统一国际测试标准的进展,包括荒地-城市界面火灾
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-12-08 DOI: 10.1002/fam.3258
Samuel L. Manzello

The wildland-urban interface (WUI) fire problem continues to perplex governments around the world. The WUI fire situation is not becoming better across the earth and globally harmonized test standards are required to help lessen the destruction in the event of WUI fire disasters. In this brief overview, a review of activities undertaken in ISO TC92/WG14, the Large Outdoor Fires and the Built Environment Working Group, under ISO TC92, is provided. Specifically, the genesis of how this working group came to be formed is provided as well as an overview of current documents that have been published by ISO TC92 and developed by ISO TC92/WG14. The review closes with recently added new work items in ISO TC92/WG14 and some possible future challenges.

荒地-城市界面(WUI)火灾问题一直困扰着世界各国政府。在全球范围内,WUI火灾的情况并没有好转,需要全球统一的测试标准来帮助减少WUI火灾时的破坏。在这个简短的概述中,提供了ISO TC92/WG14,即ISO TC92下的大型室外火灾和建筑环境工作组所开展的活动的回顾。具体来说,提供了该工作组如何形成的起源,以及ISO TC92发布和ISO TC92/WG14开发的当前文件的概述。审查结束于ISO TC92/WG14中最近增加的新工作项目和一些可能的未来挑战。
{"title":"Progress to Develop Globally Harmonized International Testing Standards for Large Outdoor Fires, Including Wildland-Urban Interface Fires","authors":"Samuel L. Manzello","doi":"10.1002/fam.3258","DOIUrl":"https://doi.org/10.1002/fam.3258","url":null,"abstract":"<p>The wildland-urban interface (WUI) fire problem continues to perplex governments around the world. The WUI fire situation is not becoming better across the earth and globally harmonized test standards are required to help lessen the destruction in the event of WUI fire disasters. In this brief overview, a review of activities undertaken in ISO TC92/WG14, the Large Outdoor Fires and the Built Environment Working Group, under ISO TC92, is provided. Specifically, the genesis of how this working group came to be formed is provided as well as an overview of current documents that have been published by ISO TC92 and developed by ISO TC92/WG14. The review closes with recently added new work items in ISO TC92/WG14 and some possible future challenges.</p>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 5","pages":"512-516"},"PeriodicalIF":2.4,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/fam.3258","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144751273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal Analysis and Fire Property Quantification of Crumb Rubber and Plastic Eco-Aggregates for Sustainable Construction 用于可持续建筑的橡胶和塑料生态集料的热分析和防火性能量化
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-28 DOI: 10.1002/fam.3259
Yohannes Werkina Shewalul, Natalia Flores Quiroz, Richard Walls

With a drive for sustainable construction, various products are being introduced to promote recycling, but often their properties relation to behaviour in fire are not known. In this paper, the fire performance of crumb rubber and a plastic eco-aggregate, called RESIN8, were assessed. Various tests, including cone calorimeter, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC), were conducted. These are supplemented by numerical calculations and the Coats–Redfern kinetic model to quantify the thermal and fire properties of these materials. Cone calorimeter tests were conducted at 35 and 50 kW m−2, while the critical heat flux (CHF) values were determined using a range of irradiance levels. Time to ignition (TTI), heat release rate (HRR), peak heat release rate (pHRR), and thermal fire hazard parameters were quantified. Both materials were classified under the high thermal fire hazard class. The peak thermal decomposition rates occurred at 365°C (single peak) for CR and at 435°C and 550°C (two peaks) for RESIN8. The calculated activation energy values were 66.7 kJ mol−1 for crumb rubber and 55.1 and 43.9 kJ mol−1 for RESIN8 in the first and second stages, respectively. These eco-aggregates could pose a significant thermal fire hazard, in the recycling facility during and after the recycling process, as well as when stored in bulk and when incorporated in large quantities in construction systems. Further investigation is crucial for understanding the effect of incorporating these eco-aggregates within masonry and concrete systems from a fire safety perspective.

在可持续建筑的推动下,各种产品被引入以促进回收利用,但它们的特性与火灾行为的关系往往是未知的。本文对橡胶屑和塑料生态骨料RESIN8的防火性能进行了评价。进行了各种测试,包括锥量热计、热重分析(TGA)和差示扫描量热法(DSC)。这些都辅以数值计算和Coats-Redfern动力学模型来量化这些材料的热性能和防火性能。锥形量热计在35和50 kW m - 2下进行了测试,而临界热流密度(CHF)值是使用一系列辐照水平确定的。对着火时间(TTI)、热释放率(HRR)、峰值热释放率(pHRR)和热火灾危险参数进行了量化。这两种材料都属于高热火灾危险类。CR的热分解速率峰值出现在365°C(单峰),RESIN8的热分解速率峰值出现在435°C和550°C(双峰)。在第一阶段和第二阶段,橡胶屑的活化能分别为66.7 kJ mol−1,树脂8的活化能分别为55.1 kJ mol−1和43.9 kJ mol−1。这些生态聚集体在回收过程中和之后的回收设施中,以及在散装储存和在建筑系统中大量使用时,可能造成严重的热火灾危险。从消防安全的角度来看,进一步的调查对于理解将这些生态骨料纳入砖石和混凝土系统的影响至关重要。
{"title":"Thermal Analysis and Fire Property Quantification of Crumb Rubber and Plastic Eco-Aggregates for Sustainable Construction","authors":"Yohannes Werkina Shewalul,&nbsp;Natalia Flores Quiroz,&nbsp;Richard Walls","doi":"10.1002/fam.3259","DOIUrl":"https://doi.org/10.1002/fam.3259","url":null,"abstract":"<p>With a drive for sustainable construction, various products are being introduced to promote recycling, but often their properties relation to behaviour in fire are not known. In this paper, the fire performance of crumb rubber and a plastic eco-aggregate, called RESIN8, were assessed. Various tests, including cone calorimeter, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC), were conducted. These are supplemented by numerical calculations and the Coats–Redfern kinetic model to quantify the thermal and fire properties of these materials. Cone calorimeter tests were conducted at 35 and 50 kW m<sup>−2</sup>, while the critical heat flux (CHF) values were determined using a range of irradiance levels. Time to ignition (TTI), heat release rate (HRR), peak heat release rate (pHRR), and thermal fire hazard parameters were quantified. Both materials were classified under the high thermal fire hazard class. The peak thermal decomposition rates occurred at 365°C (single peak) for CR and at 435°C and 550°C (two peaks) for RESIN8. The calculated activation energy values were 66.7 kJ mol<sup>−1</sup> for crumb rubber and 55.1 and 43.9 kJ mol<sup>−1</sup> for RESIN8 in the first and second stages, respectively. These eco-aggregates could pose a significant thermal fire hazard, in the recycling facility during and after the recycling process, as well as when stored in bulk and when incorporated in large quantities in construction systems. Further investigation is crucial for understanding the effect of incorporating these eco-aggregates within masonry and concrete systems from a fire safety perspective.</p>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 2","pages":"184-195"},"PeriodicalIF":2.0,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/fam.3259","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wildfire and Its Impact on the Ecosystem in Guizhou Province 贵州省野火及其对生态系统的影响
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-27 DOI: 10.1002/fam.3257
Hua Liu, Xuefei Zhou

In February 2024, a total of 221 recorded excess wildfires occurred throughout Guizhou Province. The atypical weather conditions attributed to climate change, seasonal drought during the non-monsoon period, and human activities associated with the Spring Festival are identified as the primary factors contributing to this period of extensive wildfires. To facilitate a comprehensive assessment of the local ecosystem, analyses were conducted on precipitation, temperature, air quality index records, and water quality monitoring of downstream lakes and rivers. The early onset of the rainy season in April exacerbated soil erosion in Guizhou Province, where 81% of the terrain is mountainous. The repercussions of the excess wildfires on the downstream surface water ecosystem may persist for several months. The findings revealed significant differences in biomass accumulation and response times between rivers and lakes. A more thorough understanding of the impacts of wildfires on water and soil is essential for the formulation of effective recovery policies aimed at safeguarding downstream water resources.

2024年2月,贵州省共发生有记录的过火221次。气候变化导致的非典型天气条件、非季风期的季节性干旱以及春节相关的人类活动是造成这一时期大面积野火的主要因素。为了全面评估本地生态系统,我们分析了降水、温度、空气质量指数记录,以及下游湖泊和河流的水质监测。4月雨季的提前到来加剧了贵州省81%的山地地形的水土流失。过量的野火对下游地表水生态系统的影响可能持续数月。研究结果表明,河流和湖泊之间的生物量积累和响应时间存在显著差异。更深入地了解野火对水土的影响,对于制定有效的恢复政策以保护下游水资源至关重要。
{"title":"Wildfire and Its Impact on the Ecosystem in Guizhou Province","authors":"Hua Liu,&nbsp;Xuefei Zhou","doi":"10.1002/fam.3257","DOIUrl":"https://doi.org/10.1002/fam.3257","url":null,"abstract":"<div>\u0000 \u0000 <p>In February 2024, a total of 221 recorded excess wildfires occurred throughout Guizhou Province. The atypical weather conditions attributed to climate change, seasonal drought during the non-monsoon period, and human activities associated with the Spring Festival are identified as the primary factors contributing to this period of extensive wildfires. To facilitate a comprehensive assessment of the local ecosystem, analyses were conducted on precipitation, temperature, air quality index records, and water quality monitoring of downstream lakes and rivers. The early onset of the rainy season in April exacerbated soil erosion in Guizhou Province, where 81% of the terrain is mountainous. The repercussions of the excess wildfires on the downstream surface water ecosystem may persist for several months. The findings revealed significant differences in biomass accumulation and response times between rivers and lakes. A more thorough understanding of the impacts of wildfires on water and soil is essential for the formulation of effective recovery policies aimed at safeguarding downstream water resources.</p>\u0000 </div>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 5","pages":"550-558"},"PeriodicalIF":2.4,"publicationDate":"2024-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144751391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical simulation study on shaft plug-holing height during natural smoke evacuation in deep buried tunnels 深埋隧道自然排烟井筒塞孔高度的数值模拟研究
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-23 DOI: 10.1002/fam.3254
Liu Bin, Mao Jun, Jiang Xiangyang, Xi Yanhong

In this paper, we investigate the plug-holing phenomenon under the influence of natural smoke venting in deeply buried tunnel shafts using a fire dynamics simulator based on a large eddy simulation model. Additionally, we discuss the effects of heat release rate and shaft height. The results indicate that the temperature distribution of the smoke upstream of the fire remains consistent when the height of the shaft does not exceed 20 m. Once the shaft height reaches 50 m, the temperature of the smoke upstream of the fire decreases with the increase in shaft height. Simultaneously, the smoke downstream of the fire can be completely discharged through the shaft. As the shaft height increases in the deeply buried tunnel, the degree of plug-holing increases, leading to reduced smoke evacuation efficiency. This phenomenon is caused by the horizontal inertia force and vertical thermal buoyancy of the smoke below the shaft. The critical plugging phenomenon occurs when Ri = 2.72, as determined through force analysis of the smoke. Subsequently, we analyze the mechanism by which shaft height and heat release rate influence plug hole height and establish a quantitative expression equation for plug-holing height.

本文利用基于大涡模拟模型的火灾动力学模拟器,研究了深埋隧道竖井自然排烟影响下的塞孔现象。此外,我们还讨论了放热速率和竖井高度的影响。结果表明:当竖井高度不超过20 m时,火灾上游烟气温度分布基本一致;当竖井高度达到50m时,火灾上游烟气温度随竖井高度的增加而降低。同时,火灾下游的烟气可以通过竖井完全排出。在深埋隧道中,随着竖井高度的增加,堵孔程度增大,导致排烟效率降低。这种现象是由于竖井下方的烟在水平方向上的惯性力和垂直方向上的热浮力共同作用造成的。通过对烟气的受力分析确定,当Ri = 2.72时出现临界堵塞现象。在此基础上,分析了井筒高度和放热速率对塞孔高度的影响机理,建立了塞孔高度的定量表达式方程。
{"title":"Numerical simulation study on shaft plug-holing height during natural smoke evacuation in deep buried tunnels","authors":"Liu Bin,&nbsp;Mao Jun,&nbsp;Jiang Xiangyang,&nbsp;Xi Yanhong","doi":"10.1002/fam.3254","DOIUrl":"https://doi.org/10.1002/fam.3254","url":null,"abstract":"<p>In this paper, we investigate the plug-holing phenomenon under the influence of natural smoke venting in deeply buried tunnel shafts using a fire dynamics simulator based on a large eddy simulation model. Additionally, we discuss the effects of heat release rate and shaft height. The results indicate that the temperature distribution of the smoke upstream of the fire remains consistent when the height of the shaft does not exceed 20 m. Once the shaft height reaches 50 m, the temperature of the smoke upstream of the fire decreases with the increase in shaft height. Simultaneously, the smoke downstream of the fire can be completely discharged through the shaft. As the shaft height increases in the deeply buried tunnel, the degree of plug-holing increases, leading to reduced smoke evacuation efficiency. This phenomenon is caused by the horizontal inertia force and vertical thermal buoyancy of the smoke below the shaft. The critical plugging phenomenon occurs when <i>Ri</i> = 2.72, as determined through force analysis of the smoke. Subsequently, we analyze the mechanism by which shaft height and heat release rate influence plug hole height and establish a quantitative expression equation for plug-holing height.</p>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 2","pages":"162-172"},"PeriodicalIF":2.0,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143447150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wildland Urban Interface Codes in the USA: Comparison Between the Codes From the International Code Council and the State of California 美国的荒地城市接口代码:国际代码委员会和加利福尼亚州代码的比较
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-21 DOI: 10.1002/fam.3255
Marcelo M. Hirschler

Two organizations in the United States have developed codes to protect against the hazards associated with wildfires: the International Code Council (ICC; a private not-for-profit organization) and the state of California. Both codes contain strict requirements that, when put into effect, do significantly improve fire safety. The ICC code (IWUIC) has been adopted (either as issued or with amendments) by several states in the USA while the California code (CA Chapter 7A) applies only in that state. There are many similarities between both sets of codes but there are also some clear differences. The most important difference is that CA Chapter 7A allows wood that has not been treated with fire retardants (untreated wood) to be used on decks and walls, while the IWUIC requires the use of materials with improved fire performance for those applications. On the other hand, there are also requirements in CA Chapter 7A that are more conducive to fire safety than the equivalent ones in the IWUIC. One example is the fact that CA Chapter 7A does not permit the use of coated wood materials, in view of the act that all wildland applications involve exterior use and that coatings on wood materials have been shown to be susceptible to suffer fire performance degradation when exposed to weather; IWUIC is silent on that issue, meaning that the use of coated wood materials is not prohibited. The two codes (in the USA only) will be compared and contrasted in this work with respect to delivering improved fire safety.

美国有两个组织制定了防止与野火有关的危害的守则:国际守则理事会;一个私人非营利组织)和加利福尼亚州。这两个守则都有严格的规定,一旦实施,就会大大改善消防安全。国际商会法典(IWUIC)已被美国几个州采用(无论是发布还是修订),而加州法典(CA第7A章)仅适用于该州。两套代码之间有许多相似之处,但也有一些明显的差异。最重要的区别是CA第7A章允许未经阻燃剂处理的木材(未经处理的木材)用于甲板和墙壁,而IWUIC要求使用具有改进防火性能的材料用于这些应用。另一方面,CA Chapter 7A中的要求也比IWUIC中的同等要求更有利于消防安全。一个例子是CA第7A章不允许使用涂层木材材料,因为所有的荒地应用都涉及外部使用,并且木材材料上的涂层在暴露于天气时容易遭受防火性能下降;IWUIC在这个问题上保持沉默,这意味着不禁止使用涂层木质材料。这两个规范(仅在美国)将在提供改进的消防安全方面进行比较和对比。
{"title":"Wildland Urban Interface Codes in the USA: Comparison Between the Codes From the International Code Council and the State of California","authors":"Marcelo M. Hirschler","doi":"10.1002/fam.3255","DOIUrl":"https://doi.org/10.1002/fam.3255","url":null,"abstract":"<div>\u0000 \u0000 <p>Two organizations in the United States have developed codes to protect against the hazards associated with wildfires: the International Code Council (ICC; a private not-for-profit organization) and the state of California. Both codes contain strict requirements that, when put into effect, do significantly improve fire safety. The ICC code (IWUIC) has been adopted (either as issued or with amendments) by several states in the USA while the California code (CA Chapter 7A) applies only in that state. There are many similarities between both sets of codes but there are also some clear differences. The most important difference is that CA Chapter 7A allows wood that has not been treated with fire retardants (untreated wood) to be used on decks and walls, while the IWUIC requires the use of materials with improved fire performance for those applications. On the other hand, there are also requirements in CA Chapter 7A that are more conducive to fire safety than the equivalent ones in the IWUIC. One example is the fact that CA Chapter 7A does not permit the use of coated wood materials, in view of the act that all wildland applications involve exterior use and that coatings on wood materials have been shown to be susceptible to suffer fire performance degradation when exposed to weather; IWUIC is silent on that issue, meaning that the use of coated wood materials is not prohibited. The two codes (in the USA only) will be compared and contrasted in this work with respect to delivering improved fire safety.</p>\u0000 </div>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 5","pages":"824-834"},"PeriodicalIF":2.4,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144751280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flame-Retarded Poly (Lactic Acid) Containing Phosphating Chitosan 含磷化壳聚糖的阻燃聚乳酸
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-19 DOI: 10.1002/fam.3256
Baochai Li, Huijuan Sun, Li Zhang, Xiaoya Zhao, Aznizam Abu Bakar, Zurina Mohamad

Poly (lactic acid) (PLA) is a promising thermoplastic aliphatic polyester to replace petroleum-based polymers in many fields. However, its flammability has limited its application in areas where fire safety is crucial. Chitosan (CS) is a type of natural alkaline polysaccharide with abundant content and good biocompatibility. In this study, a bio-based flame-retardant phosphating chitosan (PCS) was prepared and the effects of PCS on the flammability, mechanical and thermal properties of PLA were evaluated. The limiting oxygen index (LOI) of PLA/PCS blend containing 9 wt% PCS reached 28.9% which was relatively higher than LOI of pure PLA of 20% and passed UL-94 V-0 rating. PCS accelerated the carbonization of PLA matrix, and increased the char residue at 800°C. The combustion process was further investigated by cone calorimeter test, and the peak heat release rate and total heat release were significantly decreased. X-ray photoelectron spectrometer and thermogravimetric-infrared analysis were used to analyze the composition of char residue and pyrolysis products, which further confirmed that the flame-retardant mechanism of PCS was the combination of condensed phase and gas phase. However, the mechanical properties of PLA/PCS blend inevitably decreased with increasing of PCS content.

聚乳酸(PLA)是一种很有前途的热塑性脂肪族聚酯,可以在许多领域取代石油基聚合物。然而,它的可燃性限制了它在消防安全至关重要的领域的应用。壳聚糖(CS)是一种含量丰富、生物相容性好的天然碱性多糖。本研究制备了一种生物基阻燃磷化壳聚糖(PCS),并研究了PCS对聚乳酸(PLA)的可燃性、力学性能和热性能的影响。含9wt % PCS的PLA/PCS共混物的极限氧指数(LOI)达到28.9%,相对高于纯PLA的20%,达到UL-94 V-0等级。在800℃时,聚乳酸加速了聚乳酸基体的碳化,增加了焦渣。通过锥形量热仪对燃烧过程进行了进一步研究,发现峰值放热率和总放热率均显著降低。利用x射线光电子能谱仪和热重-红外分析对炭渣和热解产物的组成进行了分析,进一步证实了PCS的阻燃机理为缩合相和气相结合。但随着PCS含量的增加,PLA/PCS共混物的力学性能不可避免地下降。
{"title":"Flame-Retarded Poly (Lactic Acid) Containing Phosphating Chitosan","authors":"Baochai Li,&nbsp;Huijuan Sun,&nbsp;Li Zhang,&nbsp;Xiaoya Zhao,&nbsp;Aznizam Abu Bakar,&nbsp;Zurina Mohamad","doi":"10.1002/fam.3256","DOIUrl":"https://doi.org/10.1002/fam.3256","url":null,"abstract":"<div>\u0000 \u0000 <p>Poly (lactic acid) (PLA) is a promising thermoplastic aliphatic polyester to replace petroleum-based polymers in many fields. However, its flammability has limited its application in areas where fire safety is crucial. Chitosan (CS) is a type of natural alkaline polysaccharide with abundant content and good biocompatibility. In this study, a bio-based flame-retardant phosphating chitosan (PCS) was prepared and the effects of PCS on the flammability, mechanical and thermal properties of PLA were evaluated. The limiting oxygen index (LOI) of PLA/PCS blend containing 9 wt% PCS reached 28.9% which was relatively higher than LOI of pure PLA of 20% and passed UL-94 V-0 rating. PCS accelerated the carbonization of PLA matrix, and increased the char residue at 800°C. The combustion process was further investigated by cone calorimeter test, and the peak heat release rate and total heat release were significantly decreased. X-ray photoelectron spectrometer and thermogravimetric-infrared analysis were used to analyze the composition of char residue and pyrolysis products, which further confirmed that the flame-retardant mechanism of PCS was the combination of condensed phase and gas phase. However, the mechanical properties of PLA/PCS blend inevitably decreased with increasing of PCS content.</p>\u0000 </div>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 2","pages":"173-183"},"PeriodicalIF":2.0,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143447074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comprehensive laboratory study on smoke gases during the thermal oxidative decomposition of forest and vegetation fuels 森林和植被燃料热氧化分解过程中烟雾气体的综合实验室研究
IF 2.4 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-14 DOI: 10.1002/fam.3253
Kira Piechnik, Lukas Heydick, Anja Hofmann, Andrea Klippel

This study investigates the composition of smoke gases in forest and vegetation samples to draw conclusions about the actual smoke gas composition during wildfires. The focus is particularly on regions with extensive pine forests, like in Eastern Germany. The relevance of smoke gases is well illustrated by the example of wildfires in Québec, influencing air quality in New York, in 2023. By employing a modified DIN tube furnace, a bench-scale test set-up, the research emphasizes the examination of smoke composition from tree species and ground cover, prioritizing gases while disregarding particles. Key smoke gases are identified as CO, CO2, SO2, HCN, C3H4O (acrolein) and CH2O (formaldehyde) and their concentrations are compared with Acute Exposure Guideline Levels (AEGL) limits. Acknowledging the limitations of AEGL usage and the problem with direct quantitative comparison of toxicant concentrations (cf. ISO 29903-1:2020), the study highlights variations in smoke composition across different samples. The results of the studies reveal a significant disparity in CO concentration between dry and fresh pine needles. Frequently, the AEGLs of key gases are exceeded significantly. The elemental analysis of the barks indicates distinct differences in composition, reflecting in the concentrations of smoke gases. The ratio of 1 mole of substance turnover to the identified key components will be used to determine input parameters for the subsequent numerical simulation.

本研究通过对森林和植被样品中烟雾气体的组成进行调查,得出火灾中实际烟雾气体组成的结论。重点特别放在拥有大片松林的地区,如东德。2023年发生在quemail的野火影响了纽约的空气质量,很好地说明了烟雾的相关性。通过使用一个改进的DIN管炉,一个实验规模的测试装置,研究强调检查来自树木和地面覆盖的烟雾成分,优先考虑气体,而忽略颗粒。确定了主要烟雾气体为CO、CO2、SO2、HCN、c3h40(丙烯醛)和CH2O(甲醛),并将其浓度与急性暴露指南水平(AEGL)限值进行了比较。承认AEGL使用的局限性和直接定量比较有毒物质浓度的问题(参见ISO 29903-1:2020),该研究强调了不同样品中烟雾成分的变化。研究结果表明,干松针和新鲜松针的CO浓度存在显著差异。关键气体的egls经常被显著超过。树皮的元素分析表明,在组成上有明显的差异,反映在烟雾气体的浓度上。1mol物质周转量与确定的关键组分的比值将用于确定后续数值模拟的输入参数。
{"title":"Comprehensive laboratory study on smoke gases during the thermal oxidative decomposition of forest and vegetation fuels","authors":"Kira Piechnik,&nbsp;Lukas Heydick,&nbsp;Anja Hofmann,&nbsp;Andrea Klippel","doi":"10.1002/fam.3253","DOIUrl":"https://doi.org/10.1002/fam.3253","url":null,"abstract":"<p>This study investigates the composition of smoke gases in forest and vegetation samples to draw conclusions about the actual smoke gas composition during wildfires. The focus is particularly on regions with extensive pine forests, like in Eastern Germany. The relevance of smoke gases is well illustrated by the example of wildfires in Québec, influencing air quality in New York, in 2023. By employing a modified DIN tube furnace, a bench-scale test set-up, the research emphasizes the examination of smoke composition from tree species and ground cover, prioritizing gases while disregarding particles. Key smoke gases are identified as CO, CO<sub>2</sub>, SO<sub>2</sub>, HCN, C<sub>3</sub>H<sub>4</sub>O (acrolein) and CH<sub>2</sub>O (formaldehyde) and their concentrations are compared with Acute Exposure Guideline Levels (AEGL) limits. Acknowledging the limitations of AEGL usage and the problem with direct quantitative comparison of toxicant concentrations (cf. ISO 29903-1:2020), the study highlights variations in smoke composition across different samples. The results of the studies reveal a significant disparity in CO concentration between dry and fresh pine needles. Frequently, the AEGLs of key gases are exceeded significantly. The elemental analysis of the barks indicates distinct differences in composition, reflecting in the concentrations of smoke gases. The ratio of 1 mole of substance turnover to the identified key components will be used to determine input parameters for the subsequent numerical simulation.</p>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 5","pages":"599-610"},"PeriodicalIF":2.4,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/fam.3253","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144751641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review of the NRC Canada studies on fire resistance of floor assemblies: Results, design guidelines and research gaps 加拿大NRC对楼板构件耐火性能的研究综述:结果、设计指南和研究差距
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-13 DOI: 10.1002/fam.3244
Linbo Zhang, Mohamed A. Sultan

The National Research Council Canada conducted two major fire resistance studies on floor assemblies over the past two decades. Despite the publication of the experimental results, there is a lack of suggested guidelines for design practitioners and gaps for future research. Thus, this paper comprehensively reviews the fire resistance results of 85 full-scale floor tests, suggests design guidelines, and identifies research gaps. These efforts aim to enhance the understanding and support the potential improvement of the fire performance of floor assemblies. The review of the results covers the impact of various design parameters on the fire resistance of floor assemblies, such as framing type and spacing, insulation type, subfloor configuration, resilient channel spacing, number of gypsum board layers, and screw spacing from the board edge. Although the interaction of these factors is complex, some of them play significant roles in determining the overall fire resistance of floor assemblies. For instance, rock and cellulose insulation outperformed glass fibre, a wider resilient channel spacing lowered fire resistance, whilst an increased distance of screws from the board edge improved the fire resistance. More importantly, detailed explanations are provided for the influences these parameters exert on fire resistance. Following this detailed examination of the results, design guidelines are provided for practitioners' consideration. A comparison is made between the experimental results and predictions from the component additive methods in the Canadian and Euro Codes, demonstrating that both methods yield conservative results. Finally, this paper concludes by identifying research gaps and providing recommendations for future investigations, including the necessity of experimental studies on floor assemblies with new design configurations and the promising role of machine learning in fire resistance evaluation.

加拿大国家研究委员会在过去二十年中对地板组件进行了两次主要的防火研究。尽管发表了实验结果,但缺乏设计从业者的建议指南和未来研究的空白。因此,本文全面回顾了85个全尺寸地板测试的耐火结果,提出了设计指南,并确定了研究空白。这些努力的目的是加强理解和支持地板组件的防火性能的潜在改进。对结果的审查涵盖了各种设计参数对地板组件的防火性的影响,例如框架类型和间距,绝缘类型,底层配置,弹性通道间距,石膏板层数以及与板边缘的螺钉间距。虽然这些因素的相互作用是复杂的,但其中一些因素在决定楼板组件的整体防火性能方面起着重要作用。例如,岩石和纤维素绝缘材料的性能优于玻璃纤维,更宽的弹性通道间距降低了防火性能,而螺丝与板边缘的距离增加了防火性能。更重要的是,详细说明了这些参数对耐火性能的影响。在对结果进行详细检查之后,提供了供从业者考虑的设计指南。将试验结果与加拿大和欧洲规范中构件加和法的预测结果进行了比较,表明两种方法的计算结果都较为保守。最后,本文通过确定研究差距并为未来的调查提供建议,包括对具有新设计配置的地板组件进行实验研究的必要性以及机器学习在防火评估中的有希望的作用。
{"title":"Review of the NRC Canada studies on fire resistance of floor assemblies: Results, design guidelines and research gaps","authors":"Linbo Zhang,&nbsp;Mohamed A. Sultan","doi":"10.1002/fam.3244","DOIUrl":"https://doi.org/10.1002/fam.3244","url":null,"abstract":"<p>The National Research Council Canada conducted two major fire resistance studies on floor assemblies over the past two decades. Despite the publication of the experimental results, there is a lack of suggested guidelines for design practitioners and gaps for future research. Thus, this paper comprehensively reviews the fire resistance results of 85 full-scale floor tests, suggests design guidelines, and identifies research gaps. These efforts aim to enhance the understanding and support the potential improvement of the fire performance of floor assemblies. The review of the results covers the impact of various design parameters on the fire resistance of floor assemblies, such as framing type and spacing, insulation type, subfloor configuration, resilient channel spacing, number of gypsum board layers, and screw spacing from the board edge. Although the interaction of these factors is complex, some of them play significant roles in determining the overall fire resistance of floor assemblies. For instance, rock and cellulose insulation outperformed glass fibre, a wider resilient channel spacing lowered fire resistance, whilst an increased distance of screws from the board edge improved the fire resistance. More importantly, detailed explanations are provided for the influences these parameters exert on fire resistance. Following this detailed examination of the results, design guidelines are provided for practitioners' consideration. A comparison is made between the experimental results and predictions from the component additive methods in the Canadian and Euro Codes, demonstrating that both methods yield conservative results. Finally, this paper concludes by identifying research gaps and providing recommendations for future investigations, including the necessity of experimental studies on floor assemblies with new design configurations and the promising role of machine learning in fire resistance evaluation.</p>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 1","pages":"40-58"},"PeriodicalIF":2.0,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143114783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fire parameters of recycled plastic pellets 再生塑料颗粒的燃烧参数
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-06 DOI: 10.1002/fam.3248
Courtney Devine, Natalia Flores-Quiroz, Richard Walls, Carlo Kuhn

During the recycling process, waste plastic undergoes various processes that change its geometry. The thermal properties and fire behaviour of plastic in different geometries has not been widely studied. This paper aims to determine critical thermal properties of plastic pellets made of recycled plastic. For this paper, cone calorimeter tests of various volumes of recycled plastic pellets of low- and high-density polyethylene and polypropylene were conducted. During these tests, the heat release rate (HRR), mass loss rate and time-to-ignition were measured, thereafter the heat of combustion (HOC) was calculated. A calibration of suitable time-to-ignition equations is carried out. The average HRR is between 353 and 581 kW/m2 with an external heat flux of 50 kW/m2. The measured time-to-ignition values ranged between 27 s at 50 kW/m2 and just more than 90 s at 25 kW/m2. Values obtained analytically from the thermally thin time-to-ignition equations for these materials describe ignition well, which appears to be due to the particulate nature of the samples. The HOC (40–41 MJ/kg) shows good agreement with the HOC for virgin plastic found in literature. These properties can be used as a basis for material characterisation, and further testing will be done before using this as simulation inputs to determine how bulk stored plastic pellets will behave in the event of a fire.

在回收过程中,废塑料经历了改变其几何形状的各种过程。不同几何形状的塑料的热性能和防火性能尚未得到广泛的研究。本文旨在确定由再生塑料制成的塑料颗粒的临界热性能。本文对不同体积的低、高密度聚乙烯和聚丙烯再生塑料球团进行了锥形量热试验。在这些试验中,测量了热释放率(HRR)、质量损失率和点火时间,然后计算了燃烧热(HOC)。对合适的点火时间方程进行了标定。平均HRR在353 ~ 581 kW/m2之间,外热通量为50 kW/m2。测量到的点火时间值在50kw /m2时为27s,在25kw /m2时为90s以上。从这些材料的热薄点火时间方程中解析得到的值很好地描述了点火,这似乎是由于样品的颗粒性质。HOC (40-41 MJ/kg)与文献中发现的原生塑料的HOC一致。这些特性可以作为材料特性的基础,在将其用作模拟输入之前,将进行进一步的测试,以确定散装储存的塑料颗粒在发生火灾时的表现。
{"title":"Fire parameters of recycled plastic pellets","authors":"Courtney Devine,&nbsp;Natalia Flores-Quiroz,&nbsp;Richard Walls,&nbsp;Carlo Kuhn","doi":"10.1002/fam.3248","DOIUrl":"https://doi.org/10.1002/fam.3248","url":null,"abstract":"<p>During the recycling process, waste plastic undergoes various processes that change its geometry. The thermal properties and fire behaviour of plastic in different geometries has not been widely studied. This paper aims to determine critical thermal properties of plastic pellets made of recycled plastic. For this paper, cone calorimeter tests of various volumes of recycled plastic pellets of low- and high-density polyethylene and polypropylene were conducted. During these tests, the heat release rate (HRR), mass loss rate and time-to-ignition were measured, thereafter the heat of combustion (HOC) was calculated. A calibration of suitable time-to-ignition equations is carried out. The average HRR is between 353 and 581 kW/m<sup>2</sup> with an external heat flux of 50 kW/m<sup>2</sup>. The measured time-to-ignition values ranged between 27 s at 50 kW/m<sup>2</sup> and just more than 90 s at 25 kW/m<sup>2</sup>. Values obtained analytically from the thermally thin time-to-ignition equations for these materials describe ignition well, which appears to be due to the particulate nature of the samples. The HOC (40–41 MJ/kg) shows good agreement with the HOC for virgin plastic found in literature. These properties can be used as a basis for material characterisation, and further testing will be done before using this as simulation inputs to determine how bulk stored plastic pellets will behave in the event of a fire.</p>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 2","pages":"127-137"},"PeriodicalIF":2.0,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/fam.3248","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kinetic analysis on low-temperature oxidation of wood pellets by isothermal microcalorimetry 用等温微量热法分析木质颗粒低温氧化动力学
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1002/fam.3252
Can Yao, Changdong Sheng

Low-temperature chemical oxidation is the major driver of self-heating during storage of wood pellets and its kinetics is essential to describe the heat evolution. In the present work, isothermal microcalorimetry was used to characterize heat generation behavior of three types of wood pellets (pine, fir, and redwood pellets) at 30–70°C. The obtained data were employed to derive the kinetics of low-temperature oxidation by the peak power, iso-conversional method, and non-steady analysis. The consistency and applicability of the kinetics derived by the three methods were evaluated. Kinetic parameters determined by the peak power method were observed to match those from the iso-conversional method at lower conversions of the oxidation for heat generation. The kinetics derived by the iso-conversional method indicated the oxidation reactivity generally decreasing and activation energy increasing with the conversion because of O2 consumption and reaction mechanism changing. With the impact of O2 consumption considered separately, the kinetics from the non-steady analysis is capable of describing the evolution of heat power with the conversion and also consistent with that from the peak power method in describing intrinsic reactivity of pellet materials. The kinetics from the peak power and iso-conversional methods lump the impact of O2 concentration with the reaction reactivity, suggesting their applications requiring additional models for connecting with O2 consumption.

低温化学氧化是木屑颗粒储存过程中自热的主要驱动因素,其动力学对描述热演化至关重要。在本研究中,采用等温微热法对三种木屑颗粒(松木、冷杉和红木颗粒)在30-70℃下的产热行为进行了表征。采用峰值功率法、等转换法和非稳态分析等方法推导了低温氧化动力学。评价了三种方法得到的动力学结果的一致性和适用性。用峰值功率法测定的动力学参数在较低的氧化产热转化率下与等转换法测定的动力学参数相匹配。等转化动力学结果表明,随着氧化反应的进行,氧化反应活性普遍降低,活化能随着反应机理的改变而升高。在单独考虑氧气消耗影响的情况下,非稳态分析的动力学能够描述热功率随转化的演变,并且与峰值功率法描述球团材料的固有反应性的结果一致。从峰值功率和等转换方法得到的动力学将O2浓度的影响与反应活性混为一谈,这表明它们的应用需要额外的模型来连接O2消耗。
{"title":"Kinetic analysis on low-temperature oxidation of wood pellets by isothermal microcalorimetry","authors":"Can Yao,&nbsp;Changdong Sheng","doi":"10.1002/fam.3252","DOIUrl":"https://doi.org/10.1002/fam.3252","url":null,"abstract":"<p>Low-temperature chemical oxidation is the major driver of self-heating during storage of wood pellets and its kinetics is essential to describe the heat evolution. In the present work, isothermal microcalorimetry was used to characterize heat generation behavior of three types of wood pellets (pine, fir, and redwood pellets) at 30–70°C. The obtained data were employed to derive the kinetics of low-temperature oxidation by the peak power, iso-conversional method, and non-steady analysis. The consistency and applicability of the kinetics derived by the three methods were evaluated. Kinetic parameters determined by the peak power method were observed to match those from the iso-conversional method at lower conversions of the oxidation for heat generation. The kinetics derived by the iso-conversional method indicated the oxidation reactivity generally decreasing and activation energy increasing with the conversion because of O<sub>2</sub> consumption and reaction mechanism changing. With the impact of O<sub>2</sub> consumption considered separately, the kinetics from the non-steady analysis is capable of describing the evolution of heat power with the conversion and also consistent with that from the peak power method in describing intrinsic reactivity of pellet materials. The kinetics from the peak power and iso-conversional methods lump the impact of O<sub>2</sub> concentration with the reaction reactivity, suggesting their applications requiring additional models for connecting with O<sub>2</sub> consumption.</p>","PeriodicalId":12186,"journal":{"name":"Fire and Materials","volume":"49 1","pages":"116-124"},"PeriodicalIF":2.0,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143112000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Fire and Materials
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1