首页 > 最新文献

Fire最新文献

英文 中文
Upgrading Carthamus by HTC: Improvement of Combustion Properties 用 HTC 对胡麻进行升级:改善燃烧特性
Pub Date : 2024-03-22 DOI: 10.3390/fire7040106
José Manuel Díaz-Rasero, B. Ledesma, María Alonso, Silvia Román
This study investigated the fuel potential and combustion behavior of hydrochars derived from a unique precursor: Carthamus pomace. Initially, the hydrothermal carbonization process of this novel feedstock was examined across various temperature ranges (180–240 °C) and durations (15–180 min). The impact of these processing conditions was analyzed in terms of degradation mechanisms and their correlation with the resulting properties of the hydrochars (HCs) produced. Then, the combustion performance of these materials was studied by means of thermogravimetry, and the differences in reactivity and activation energy were analyzed and associated with preparation processes. Finally, the most promising HTC parameters were identified and a thermoeconomic study on the use of selected HCs on a thermal plant devoted to the production of electricity was evaluated including energy savings associated with the implementation of heat exchangers using the heat of the flue gases to partially supply the energy needs associated with HTC.
本研究调查了一种独特前体产生的水合碳的燃料潜力和燃烧行为:肉豆蔻渣。首先,研究了这种新型原料在不同温度范围(180-240 °C)和持续时间(15-180 分钟)内的水热碳化过程。分析了这些加工条件对降解机制的影响,以及它们与所产生的水合碳(HCs)特性之间的相关性。然后,通过热重分析法研究了这些材料的燃烧性能,分析了反应活性和活化能的差异,并将其与制备过程联系起来。最后,确定了最有前途的氢化炭参数,并对在一家专门生产电力的热电厂使用选定的碳氢化合物进行了热经济研究评估,包括使用热交换器利用烟气热量部分满足氢化炭相关能源需求所带来的节能效果。
{"title":"Upgrading Carthamus by HTC: Improvement of Combustion Properties","authors":"José Manuel Díaz-Rasero, B. Ledesma, María Alonso, Silvia Román","doi":"10.3390/fire7040106","DOIUrl":"https://doi.org/10.3390/fire7040106","url":null,"abstract":"This study investigated the fuel potential and combustion behavior of hydrochars derived from a unique precursor: Carthamus pomace. Initially, the hydrothermal carbonization process of this novel feedstock was examined across various temperature ranges (180–240 °C) and durations (15–180 min). The impact of these processing conditions was analyzed in terms of degradation mechanisms and their correlation with the resulting properties of the hydrochars (HCs) produced. Then, the combustion performance of these materials was studied by means of thermogravimetry, and the differences in reactivity and activation energy were analyzed and associated with preparation processes. Finally, the most promising HTC parameters were identified and a thermoeconomic study on the use of selected HCs on a thermal plant devoted to the production of electricity was evaluated including energy savings associated with the implementation of heat exchangers using the heat of the flue gases to partially supply the energy needs associated with HTC.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"111 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140386973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance Evaluation of Cable Shaft Fireproof Sealing System in High-Rise Buildings: A Comparative Test Method 高层建筑电缆井防火密封系统的性能评估:比较试验方法
Pub Date : 2024-03-21 DOI: 10.3390/fire7030102
Bizhen Zhang, Shengwen Shu, Zhicong Zheng, Bo Qu, Xin Li, Xingyao Xiang, Shuai Xia
The effectiveness of fireproof sealing systems in preventing the spread of fire in high-rise building cable shafts relies on the properties of various sealing materials and the construction process. Therefore, a comprehensive evaluation is necessary. The authors of this paper propose a comparative test method based on an entity test platform for a performance evaluation of cable shaft fireproof sealing systems in high-rise buildings. The test platform measures changes in temperature, humidity, and smoke mass during fire tests to compare the performance of four sets of fireproof sealing systems in terms of thermal insulation, smoke sealing capacity, and overall integrity. In addition, a fire dynamics simulation (FDS) of fireproof sealing systems was carried out on the entity test platform, and the sealing failure process in the case of cracking in the fireproof sealing system was revealed. The simulation results for the temperature trends in the lower space align with the fire test results. Furthermore, as the gap size increases, the diffusion of smoke and flame accelerates. Consequently, the performance of cable shaft fireproof sealing systems depends not only on the sealing material but also on the construction process.
防火密封系统防止火灾在高层建筑电缆井蔓延的效果取决于各种密封材料的特性和施工工艺。因此,有必要进行综合评估。本文作者提出了一种基于实体测试平台的比较测试方法,用于高层建筑电缆井防火密封系统的性能评估。该测试平台可测量火灾测试过程中温度、湿度和烟气质量的变化,从而比较四套防火密封系统在隔热、烟气密封能力和整体完整性方面的性能。此外,还在实体试验平台上对防火密封系统进行了火灾动力学模拟(FDS),揭示了防火密封系统开裂时的密封失效过程。下部空间温度趋势的模拟结果与防火测试结果一致。此外,随着间隙的增大,烟雾和火焰的扩散速度也会加快。因此,电缆井防火密封系统的性能不仅取决于密封材料,还取决于施工工艺。
{"title":"Performance Evaluation of Cable Shaft Fireproof Sealing System in High-Rise Buildings: A Comparative Test Method","authors":"Bizhen Zhang, Shengwen Shu, Zhicong Zheng, Bo Qu, Xin Li, Xingyao Xiang, Shuai Xia","doi":"10.3390/fire7030102","DOIUrl":"https://doi.org/10.3390/fire7030102","url":null,"abstract":"The effectiveness of fireproof sealing systems in preventing the spread of fire in high-rise building cable shafts relies on the properties of various sealing materials and the construction process. Therefore, a comprehensive evaluation is necessary. The authors of this paper propose a comparative test method based on an entity test platform for a performance evaluation of cable shaft fireproof sealing systems in high-rise buildings. The test platform measures changes in temperature, humidity, and smoke mass during fire tests to compare the performance of four sets of fireproof sealing systems in terms of thermal insulation, smoke sealing capacity, and overall integrity. In addition, a fire dynamics simulation (FDS) of fireproof sealing systems was carried out on the entity test platform, and the sealing failure process in the case of cracking in the fireproof sealing system was revealed. The simulation results for the temperature trends in the lower space align with the fire test results. Furthermore, as the gap size increases, the diffusion of smoke and flame accelerates. Consequently, the performance of cable shaft fireproof sealing systems depends not only on the sealing material but also on the construction process.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"136 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140222981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Different Time Step Sizes on Pedestrian Evacuation Time under Emergencies Such as Fires Using an Extended Cellular Automata Model 使用扩展蜂窝自动机模型计算不同时间步长对火灾等紧急情况下行人疏散时间的影响
Pub Date : 2024-03-21 DOI: 10.3390/fire7030100
Hongpeng Qiu, Xuanwen Liang, Qian Chen, Eric W.M. Lee
The cellular automata (CA) model has been a meaningful way to study pedestrian evacuation during emergencies, such as fires, for many years. Although the time step used in the CA model is one of the most essential elements, there is a lack of research on its impact on evacuation time. In this paper, we set different time step sizes in an extended cellular automaton model and discuss the effect of time step size on the overall evacuation time under different emergency types and levels. For a fixed step time mode, the larger the time step, the longer the evacuation time. In each time step size, the evacuation time gradually increases with the increase of emergency level, and there is a sharp increase when the time for pedestrians to move one step is exactly an integer multiple of the time step. When there is no friction between pedestrians, the evacuation time at each time step first decreases slightly with the increase of emergency level and then remains unchanged; the larger the time step, when the evacuation time remains unchanged, the lower the emergency level and the greater the evacuation time. For the variable time step model, when the friction between pedestrians approaches infinity, the total evacuation time does not change with the emergency level; when the friction between pedestrians is reduced, the total evacuation time slightly decreases with the increase of the emergency level. The less friction there is, the more significant the reduction. The results of previous actual experiments are also reflected in the simulation at a lower emergency level. The result shows that the time step size significantly impacts the evacuation simulation results of the CA model, and researchers should choose carefully to obtain more realistic simulation results.
多年来,细胞自动机(CA)模型一直是研究火灾等紧急情况下行人疏散的有效方法。虽然 CA 模型中使用的时间步长是最基本的要素之一,但目前还缺乏关于时间步长对疏散时间影响的研究。本文在扩展的蜂窝自动机模型中设置了不同的时间步长,并讨论了在不同紧急情况类型和级别下,时间步长对整体疏散时间的影响。在固定步长时间模式下,时间步长越大,疏散时间越长。在每种时间步长下,疏散时间随着紧急情况级别的增加而逐渐增加,当行人移动一步的时间正好是时间步长的整数倍时,疏散时间会急剧增加。当行人之间没有摩擦时,每个时间步长的疏散时间先是随着紧急程度的增加而略有减少,然后保持不变;当疏散时间保持不变时,时间步长越大,紧急程度越低,疏散时间越长。对于可变时间步长模型,当行人之间的摩擦力接近无穷大时,总疏散时间不随紧急程度的变化而变化;当行人之间的摩擦力减小时,总疏散时间随紧急程度的增加而略有减少。摩擦力越小,缩短的时间越明显。之前的实际实验结果也反映在较低紧急程度下的模拟中。结果表明,时间步长对 CA 模型的疏散模拟结果有很大影响,研究人员应谨慎选择,以获得更真实的模拟结果。
{"title":"Effect of Different Time Step Sizes on Pedestrian Evacuation Time under Emergencies Such as Fires Using an Extended Cellular Automata Model","authors":"Hongpeng Qiu, Xuanwen Liang, Qian Chen, Eric W.M. Lee","doi":"10.3390/fire7030100","DOIUrl":"https://doi.org/10.3390/fire7030100","url":null,"abstract":"The cellular automata (CA) model has been a meaningful way to study pedestrian evacuation during emergencies, such as fires, for many years. Although the time step used in the CA model is one of the most essential elements, there is a lack of research on its impact on evacuation time. In this paper, we set different time step sizes in an extended cellular automaton model and discuss the effect of time step size on the overall evacuation time under different emergency types and levels. For a fixed step time mode, the larger the time step, the longer the evacuation time. In each time step size, the evacuation time gradually increases with the increase of emergency level, and there is a sharp increase when the time for pedestrians to move one step is exactly an integer multiple of the time step. When there is no friction between pedestrians, the evacuation time at each time step first decreases slightly with the increase of emergency level and then remains unchanged; the larger the time step, when the evacuation time remains unchanged, the lower the emergency level and the greater the evacuation time. For the variable time step model, when the friction between pedestrians approaches infinity, the total evacuation time does not change with the emergency level; when the friction between pedestrians is reduced, the total evacuation time slightly decreases with the increase of the emergency level. The less friction there is, the more significant the reduction. The results of previous actual experiments are also reflected in the simulation at a lower emergency level. The result shows that the time step size significantly impacts the evacuation simulation results of the CA model, and researchers should choose carefully to obtain more realistic simulation results.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"175 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140222626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An Experimental Analysis of a Nuclear-Grade Cable Based on Fire Combustion Characteristics and Pyrolysis Behavior 基于火灾燃烧特性和热解行为的核级电缆实验分析
Pub Date : 2024-03-21 DOI: 10.3390/fire7030101
Qiang Shi, Jiaxu Zuo, Wei Song, Fang Jing
Nuclear power fire protection is an important part of nuclear safety, and strengthening fire protection technology research is essential for improving nuclear safety and fire protection. The operating platform inside a containment structure is one important element in fire risk evaluation in nuclear power plants. In this paper, a combustible nuclear-grade cable in a fire scenario was firstly selected as the research object, and then the nuclear-grade cable was separately subjected to a combustion test as well as a thermogravimetric test in order to obtain the relevant thermal parameters, which provide more accurate data support for the establishment of a cable fire development and spread model. The nuclear-grade cable material data obtained from the test were compared with a civil PVC cable in order to conduct a specific analysis of the fire risk of nuclear-grade cables. This study shows that the effects of different heating rates and heating atmospheres on the thermal decomposition behavior of cable materials are meaningful and helpful in understanding whether the materials will undergo combustion processes at high temperatures and whether fire spread will occur.
核电消防是核安全的重要组成部分,加强消防技术研究对于提高核安全和消防水平至关重要。安全壳结构内的操作平台是核电站火灾风险评估的重要内容之一。本文首先选取了火灾场景下的可燃核级电缆作为研究对象,然后分别对核级电缆进行了燃烧试验和热重试验,以获得相关的热参数,为建立电缆火灾发展和蔓延模型提供更准确的数据支持。试验获得的核级电缆材料数据与民用聚氯乙烯电缆进行了对比,以便对核级电缆的火灾风险进行具体分析。该研究表明,不同加热速率和加热气氛对电缆材料热分解行为的影响是有意义的,有助于了解材料在高温下是否会发生燃烧过程以及是否会发生火势蔓延。
{"title":"An Experimental Analysis of a Nuclear-Grade Cable Based on Fire Combustion Characteristics and Pyrolysis Behavior","authors":"Qiang Shi, Jiaxu Zuo, Wei Song, Fang Jing","doi":"10.3390/fire7030101","DOIUrl":"https://doi.org/10.3390/fire7030101","url":null,"abstract":"Nuclear power fire protection is an important part of nuclear safety, and strengthening fire protection technology research is essential for improving nuclear safety and fire protection. The operating platform inside a containment structure is one important element in fire risk evaluation in nuclear power plants. In this paper, a combustible nuclear-grade cable in a fire scenario was firstly selected as the research object, and then the nuclear-grade cable was separately subjected to a combustion test as well as a thermogravimetric test in order to obtain the relevant thermal parameters, which provide more accurate data support for the establishment of a cable fire development and spread model. The nuclear-grade cable material data obtained from the test were compared with a civil PVC cable in order to conduct a specific analysis of the fire risk of nuclear-grade cables. This study shows that the effects of different heating rates and heating atmospheres on the thermal decomposition behavior of cable materials are meaningful and helpful in understanding whether the materials will undergo combustion processes at high temperatures and whether fire spread will occur.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"84 s371","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140223459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mitigating Coal Spontaneous Combustion Risk within Goaf of Gob-Side Entry Retaining by Roof Cutting: Investigation of Air Leakage Characteristics and Effective Plugging Techniques 通过顶板截割降低煤层中的煤炭自燃风险:漏风特性和有效堵漏技术研究
Pub Date : 2024-03-20 DOI: 10.3390/fire7030098
Zhipeng Zhang, Xiaokun Chen, Zhijin Yu, Hao Sun, Dewei Huang, Jiangle Wu, Hao Zhang
Relative to conventional coal pillar retention mining technology (the 121 mining method), gob-side entry retaining by cutting roof (the 110 mining method), a non-pillar mining technique, efficiently addresses issues like poor coal resource recovery and significant rock burst damage. Nonetheless, the open-type goaf created by 110 mining techniques suffers from complex and significant air leaks, increasing the likelihood of coal spontaneous combustion (CSC) within the gob area. To address the CSC problem caused by complex air leakage within the goaf of gob-side entry retaining by roof cutting, this study takes the 17202 working face of Dongrong Second Coal Mine as the object of study. Field tests and simulation calculations are conducted to research the features of air leakage and the distribution of the oxidation zone within the goaf. Subsequently, plugging technology with varying plugging lengths is proposed and implemented. The tests and simulations reveal that the airflow migration within the goaf follows an L-shaped pattern, while air leakage primarily originates from gaps found in the gob-side entry retaining wall. The amount of air leaking into the gob-side entry retaining section is 171.59 m3/min, which represents 7.3% of the overall airflow. The maximum oxidation zone within the goaf ranges from 58.7 m to 151.8 m. After the air leakage is blocked, the airflow migration route within the goaf is transformed into a U-shaped distribution, and the maximum oxidation zone range changes from 42.8 m to 80.7 m. Engineering practice demonstrates that after air leakage plugging, the total air leakage volume within the gob-side entry retaining section significantly reduces to 20.59 m3/min, representing only 0.78% of the total airflow volume. This research provides reference on how to prevent the occurrence of CSC in similar mine goafs.
相对于传统的煤柱截留开采技术(121 采矿方法),非煤柱开采技术(110 采矿方法)中的切顶式巷道侧进风截留技术可有效解决煤炭资源回收率低和岩爆破坏严重等问题。然而,110 采矿技术所产生的露天煤层存在复杂而严重的漏风问题,增加了煤层区域内煤炭自燃(CSC)的可能性。针对顶板截割保留巷道内复杂漏风引起的煤自燃问题,本研究以东荣二矿 17202 工作面为研究对象。通过现场试验和模拟计算,研究了巷道内的漏风特征和氧化区分布。随后,提出并实施了不同堵塞长度的堵塞技术。试验和模拟结果表明,气流在沟谷内的迁移呈 L 形,而漏气主要来自沟谷侧入口挡墙的缝隙。泄漏到鹅槽侧入口挡墙部分的空气量为 171.59 立方米/分钟,占总气流的 7.3%。工程实践证明,在堵塞漏风口后,山坡入口挡墙段内的总漏风量明显降低至 20.59 立方米/分钟,仅占总风量的 0.78%。这项研究为如何防止类似矿井巷道发生 CSC 提供了参考。
{"title":"Mitigating Coal Spontaneous Combustion Risk within Goaf of Gob-Side Entry Retaining by Roof Cutting: Investigation of Air Leakage Characteristics and Effective Plugging Techniques","authors":"Zhipeng Zhang, Xiaokun Chen, Zhijin Yu, Hao Sun, Dewei Huang, Jiangle Wu, Hao Zhang","doi":"10.3390/fire7030098","DOIUrl":"https://doi.org/10.3390/fire7030098","url":null,"abstract":"Relative to conventional coal pillar retention mining technology (the 121 mining method), gob-side entry retaining by cutting roof (the 110 mining method), a non-pillar mining technique, efficiently addresses issues like poor coal resource recovery and significant rock burst damage. Nonetheless, the open-type goaf created by 110 mining techniques suffers from complex and significant air leaks, increasing the likelihood of coal spontaneous combustion (CSC) within the gob area. To address the CSC problem caused by complex air leakage within the goaf of gob-side entry retaining by roof cutting, this study takes the 17202 working face of Dongrong Second Coal Mine as the object of study. Field tests and simulation calculations are conducted to research the features of air leakage and the distribution of the oxidation zone within the goaf. Subsequently, plugging technology with varying plugging lengths is proposed and implemented. The tests and simulations reveal that the airflow migration within the goaf follows an L-shaped pattern, while air leakage primarily originates from gaps found in the gob-side entry retaining wall. The amount of air leaking into the gob-side entry retaining section is 171.59 m3/min, which represents 7.3% of the overall airflow. The maximum oxidation zone within the goaf ranges from 58.7 m to 151.8 m. After the air leakage is blocked, the airflow migration route within the goaf is transformed into a U-shaped distribution, and the maximum oxidation zone range changes from 42.8 m to 80.7 m. Engineering practice demonstrates that after air leakage plugging, the total air leakage volume within the gob-side entry retaining section significantly reduces to 20.59 m3/min, representing only 0.78% of the total airflow volume. This research provides reference on how to prevent the occurrence of CSC in similar mine goafs.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"29 13","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140226408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elucidating the Mechanisms of Reactions in Energetic Materials: A Critical Methodology Review 阐明高能材料的反应机制:重要方法论综述
Pub Date : 2024-03-20 DOI: 10.3390/fire7030099
Kinga Łysień, Tomasz Jarosz, Karolina Głosz, A. Stolarczyk
Identification of the mechanism of changes taking place in energetic materials (EMs) is one of the most important issues in the rational design and use of EMs. Due to the extremely rapid nature of these changes, reliable monitoring and real-time analysis are extremely difficult. Hence, analysis of the mechanism of such processes often has to rely on adaptation of classical methods or on comparison of the initial and final states of the EM. In this critical review, we focus on current approaches to the methodology of investigating the mechanisms of processes taking place in EMs, showcasing viable experimental strategies, points of uncertainty, and adaptations of classical instrumental methods.
确定高能材料(EMs)的变化机制是合理设计和使用 EMs 的最重要问题之一。由于这些变化极为迅速,可靠的监测和实时分析极为困难。因此,对此类过程的机理分析往往必须依赖于对经典方法的调整,或对电磁的初始状态和最终状态进行比较。在这篇评论性文章中,我们将重点介绍目前研究电磁过程机制的方法,展示可行的实验策略、不确定因素以及对经典仪器方法的调整。
{"title":"Elucidating the Mechanisms of Reactions in Energetic Materials: A Critical Methodology Review","authors":"Kinga Łysień, Tomasz Jarosz, Karolina Głosz, A. Stolarczyk","doi":"10.3390/fire7030099","DOIUrl":"https://doi.org/10.3390/fire7030099","url":null,"abstract":"Identification of the mechanism of changes taking place in energetic materials (EMs) is one of the most important issues in the rational design and use of EMs. Due to the extremely rapid nature of these changes, reliable monitoring and real-time analysis are extremely difficult. Hence, analysis of the mechanism of such processes often has to rely on adaptation of classical methods or on comparison of the initial and final states of the EM. In this critical review, we focus on current approaches to the methodology of investigating the mechanisms of processes taking place in EMs, showcasing viable experimental strategies, points of uncertainty, and adaptations of classical instrumental methods.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"14 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140226431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and Characterization of Microencapsulated Ammonium Polyphosphate with Polyurethane Shell and Its Flame Retardance in Polypropylene 聚氨酯外壳微胶囊聚磷酸铵的制备和特性及其在聚丙烯中的阻燃性能
Pub Date : 2024-03-19 DOI: 10.3390/fire7030097
Thuy Tien Nguyen Thanh, Ziya Yusifov, Bence Tóth, K. Bocz, Péter Márton, Zoltán Hórvölgyi, György Marosi, B. Szolnoki
Polypropylene (PP) shows no charring ability in burning due to the lack of hydroxyl functional groups; thus, the flame retardant system needs an additional amount of carbonizing agent. An ammonium polyphosphate (APP)-based all-in-one intumescent flame-retardant system was prepared by the in situ polymerization of polymeric methylene diphenyl diisocyanate (pMDI) with a glycerol-based and a glycerol–sorbitol-based polyol of high OH value. The microencapsulated APP with a polyurethane shell (MCAPP) of different polyols was characterized. The MCAPP with speculated improved flame retardant performance was selected for further evaluation in the PP matrix at different loadings by means of standard flammability tests.
由于缺乏羟基官能团,聚丙烯(PP)在燃烧时没有炭化能力;因此,阻燃体系需要额外添加一定量的碳化剂。通过聚合亚甲基二苯基二异氰酸酯(pMDI)与高羟基值的甘油基和甘油-山梨醇基多元醇的原位聚合,制备了一种基于聚磷酸铵(APP)的多合一膨胀型阻燃体系。对带有不同多元醇的聚氨酯外壳的微胶囊 APP(MCAPP)进行了表征。通过标准的可燃性测试,选择了具有更好阻燃性能的 MCAPP,以进一步评估其在 PP 基质中的不同负载量。
{"title":"Preparation and Characterization of Microencapsulated Ammonium Polyphosphate with Polyurethane Shell and Its Flame Retardance in Polypropylene","authors":"Thuy Tien Nguyen Thanh, Ziya Yusifov, Bence Tóth, K. Bocz, Péter Márton, Zoltán Hórvölgyi, György Marosi, B. Szolnoki","doi":"10.3390/fire7030097","DOIUrl":"https://doi.org/10.3390/fire7030097","url":null,"abstract":"Polypropylene (PP) shows no charring ability in burning due to the lack of hydroxyl functional groups; thus, the flame retardant system needs an additional amount of carbonizing agent. An ammonium polyphosphate (APP)-based all-in-one intumescent flame-retardant system was prepared by the in situ polymerization of polymeric methylene diphenyl diisocyanate (pMDI) with a glycerol-based and a glycerol–sorbitol-based polyol of high OH value. The microencapsulated APP with a polyurethane shell (MCAPP) of different polyols was characterized. The MCAPP with speculated improved flame retardant performance was selected for further evaluation in the PP matrix at different loadings by means of standard flammability tests.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"64 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140230114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of Fires on Desert Plant Communities at the Chernye Zemli (SW Russia) 火灾对切尔诺耶泽姆利(俄罗斯西南部)沙漠植物群落的影响
Pub Date : 2024-03-17 DOI: 10.3390/fire7030096
G. Klink, S. Lednev, I. Semenkov, M. Konyushkova, A. Karpachevskiy, M. M. Chemidov, Svetlana S. Ulanova, Natal’ya L. Fedorova, A. Sharapova, Sergey A. Bogun, Tatyana V. Koroleva
Understanding the rate and direction of pyrogenic succession in arid ecosystems, which depends on many factors, including the intensity of grazing and the frequency of pyrogenic expo-sure, will allow for more accurate predictions of the consequences of fire onplant communities, and will assist with better fire management. We studied the vegetation on 55 sites in and near the “Chernye Zemli” Natural Biosphere Reserve that burned at different times or were not affected by fires over the past 35 years and characterized the changes in vegetation cover associated with the impact of wildfire and grazing. The descriptions were grouped into chronological stages according to the time elapsed since the last fire, or into groups according to the frequency of fires. In pairwise comparison of the projective cover of plant species between chronological stages, it correlated most strongly between successive initial stages (for stages 1 and 2, p = 0.003, r = 0.73; for stages 2 and 3, p < 0.001, r = 0.78). Species with an initially higher projective cover were more likely to grow on plots in the first year after the fire: p < 0.03. Plots with rare and frequent fires had similar projective cover of individual species (r = 0.64, p < 0.001). We conclude that in the course of pyrogenic succession, communities are gradually replaced over at least ten years. At the same time, the composition of a plant community at the initial point of succession depends on the prevalence of species in the community before the fire. No fundamental effect of the frequency of fires on the composition of plant communities has been revealed.
干旱生态系统的火原生演替速度和方向取决于多种因素,包括放牧强度和火原生演替频率,了解这些因素将有助于更准确地预测火灾对植物群落造成的后果,并有助于更好地进行火灾管理。我们对 "切尔诺耶泽姆利 "自然生物圈保护区内和附近的 55 个地点的植被进行了研究,这些地点在过去 35 年中在不同时间发生过火灾或未受火灾影响,并描述了与野火和放牧影响相关的植被变化。根据上一次火灾发生后的时间,或根据火灾发生的频率,将描述分为不同的时间阶段。在对不同年代阶段的植物物种投影覆盖率进行配对比较时,连续初始阶段之间的相关性最强(第 1 和第 2 阶段,p = 0.003,r = 0.73;第 2 和第 3 阶段,p < 0.001,r = 0.78)。火灾后第一年,最初投影覆盖率较高的物种更有可能在地块上生长:p < 0.03。罕见火灾地块和频繁火灾地块的物种投影覆盖率相似(r = 0.64,p < 0.001)。我们的结论是,在火成演替过程中,群落会在至少 10 年内逐渐被取代。同时,演替初期的植物群落组成取决于火灾前群落中物种的普遍性。目前尚未发现火灾频率对植物群落组成的根本影响。
{"title":"Influence of Fires on Desert Plant Communities at the Chernye Zemli (SW Russia)","authors":"G. Klink, S. Lednev, I. Semenkov, M. Konyushkova, A. Karpachevskiy, M. M. Chemidov, Svetlana S. Ulanova, Natal’ya L. Fedorova, A. Sharapova, Sergey A. Bogun, Tatyana V. Koroleva","doi":"10.3390/fire7030096","DOIUrl":"https://doi.org/10.3390/fire7030096","url":null,"abstract":"Understanding the rate and direction of pyrogenic succession in arid ecosystems, which depends on many factors, including the intensity of grazing and the frequency of pyrogenic expo-sure, will allow for more accurate predictions of the consequences of fire onplant communities, and will assist with better fire management. We studied the vegetation on 55 sites in and near the “Chernye Zemli” Natural Biosphere Reserve that burned at different times or were not affected by fires over the past 35 years and characterized the changes in vegetation cover associated with the impact of wildfire and grazing. The descriptions were grouped into chronological stages according to the time elapsed since the last fire, or into groups according to the frequency of fires. In pairwise comparison of the projective cover of plant species between chronological stages, it correlated most strongly between successive initial stages (for stages 1 and 2, p = 0.003, r = 0.73; for stages 2 and 3, p < 0.001, r = 0.78). Species with an initially higher projective cover were more likely to grow on plots in the first year after the fire: p < 0.03. Plots with rare and frequent fires had similar projective cover of individual species (r = 0.64, p < 0.001). We conclude that in the course of pyrogenic succession, communities are gradually replaced over at least ten years. At the same time, the composition of a plant community at the initial point of succession depends on the prevalence of species in the community before the fire. No fundamental effect of the frequency of fires on the composition of plant communities has been revealed.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"71 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140235000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on the Inhibitory Effect of Hydrated Phase Change Materials on Spontaneous Combustion in Coal 水合相变材料对煤炭自燃的抑制作用研究
Pub Date : 2024-03-17 DOI: 10.3390/fire7030095
Fanghua Wu, Shiliang Shi, Shuzhen Shao, Yi Lu, Wangxin Gu, Youliang Wang, Xindi Yuan
In order to study the effect of hydrated phase change materials on the suppression of spontaneous combustion in coal, a thermogravimetric experiment and a reaction activation energy analysis experiment were conducted to explore the changes in the combustion characteristic parameters, characteristic temperature, and activating energy of gas coal, long-flame coal, meagre coal, and lean coal before and after adding hydrated phase change materials. The research results indicated that hydrated phase change materials increased the characteristic temperature point of the coal samples and had effective inhibitory effects on different stages of the oxidation process. However, the effect was best at low temperatures, as hydrated phase change materials undergo phase change and absorb heat when heated at low temperatures, isolating coal from contact with oxygen. The activating energy increased by 1.138–23.048 KJ·mol−1 and the mass loss was reduced by 1.6%–9.3% after inhibition of the coal samples, indicating that the oxidation rate of the various coal samples was slowed down and, thus, spontaneous combustion can be suppressed through the use of hydrated phase change materials. At the same time, this material reduced the combustibility indices of meagre coal and lean coal, as well as the comprehensive combustion indices of long-flame coal and gas coal.
为了研究水合相变材料对煤炭自燃的抑制作用,进行了热重实验和反应活化能分析实验,探讨了添加水合相变材料前后气煤、长焰煤、贫煤和瘦煤的燃烧特征参数、特征温度和活化能的变化。研究结果表明,水合相变材料提高了煤样的特征温度点,对氧化过程的不同阶段都有有效的抑制作用。不过,在低温下效果最好,因为水合相变材料在低温加热时会发生相变并吸收热量,从而隔离煤炭与氧气的接触。对煤样进行抑制后,活化能增加了 1.138-23.048 KJ-mol-1,质量损失减少了 1.6%-9.3%,这表明各种煤样的氧化速度都减慢了,因此,通过使用水合相变材料可以抑制自燃。同时,该材料还降低了贫煤和瘦煤的燃烧指数,以及长焰煤和气煤的综合燃烧指数。
{"title":"Research on the Inhibitory Effect of Hydrated Phase Change Materials on Spontaneous Combustion in Coal","authors":"Fanghua Wu, Shiliang Shi, Shuzhen Shao, Yi Lu, Wangxin Gu, Youliang Wang, Xindi Yuan","doi":"10.3390/fire7030095","DOIUrl":"https://doi.org/10.3390/fire7030095","url":null,"abstract":"In order to study the effect of hydrated phase change materials on the suppression of spontaneous combustion in coal, a thermogravimetric experiment and a reaction activation energy analysis experiment were conducted to explore the changes in the combustion characteristic parameters, characteristic temperature, and activating energy of gas coal, long-flame coal, meagre coal, and lean coal before and after adding hydrated phase change materials. The research results indicated that hydrated phase change materials increased the characteristic temperature point of the coal samples and had effective inhibitory effects on different stages of the oxidation process. However, the effect was best at low temperatures, as hydrated phase change materials undergo phase change and absorb heat when heated at low temperatures, isolating coal from contact with oxygen. The activating energy increased by 1.138–23.048 KJ·mol−1 and the mass loss was reduced by 1.6%–9.3% after inhibition of the coal samples, indicating that the oxidation rate of the various coal samples was slowed down and, thus, spontaneous combustion can be suppressed through the use of hydrated phase change materials. At the same time, this material reduced the combustibility indices of meagre coal and lean coal, as well as the comprehensive combustion indices of long-flame coal and gas coal.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"13 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140235237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Decolonising Fire Science by Reexamining Fire Management across Contested Landscapes: A Workshop Approach 通过重新审视有争议地貌的火灾管理,实现火灾科学的非殖民化:研讨会方法
Pub Date : 2024-03-16 DOI: 10.3390/fire7030094
Abigail R. Croker, Adriana E. S. Ford, Y. Kountouris, Jay Mistry, Amos Chege Muthiuru, Cathy Smith, Elijah Praise, David O. Chiawo, Veronica Muniu
In many landscapes worldwide, fire regimes and human–fire interactions were reorganised by colonialism and continue to be shaped by neo-colonial processes. The introduction of fire suppression policies and state-centric property-rights systems across conservation areas and the intentional erasure of Indigenous governance systems and knowledge have served to decouple Indigenous fire-dependent communities from culturally mediated fire regimes and fire-adapted landscapes. This has driven a decline in anthropogenic fires while simultaneously increasing wildfire risk where Indigenous people have been excluded, resulting in widespread social–ecological vulnerabilities. Much contemporary fire research also bears colonial legacies in its epistemological traditions, in the global geographical distribution of research institutions, and the accessibility of research outputs. We report on a two-day workshop titled ‘Fire Management Across Contested Landscapes’ convened concurrently in Nairobi, Kenya, and London, UK. The workshop formed part of a series of workshops on ‘Decolonising Fire Science’ held by the Leverhulme Centre for Wildfires, Environment and Society, UK. The workshop in Nairobi invited diverse Kenyan stakeholders to engage in participatory activities that facilitate knowledge sharing, aiming to establish an inclusive working fire network. Activities included rich pictures, world café discussions, participatory art, and the co-development of a declaration to guide fire management in Kenya. Meanwhile, in London, Leverhulme Wildfires researchers explored participatory research methodologies including rich pictures and participatory video, and developed a declaration to guide more equitable research. There were opportunities throughout the workshop for participants in Nairobi and London to engage in dialogue with one another, sharing their experiences and understandings of complex fire challenges in Kenya and globally.
在世界各地的许多地貌中,火灾制度和人类与火灾的互动是由殖民主义重组的,并继续由新殖民主义进程塑造。在整个保护区推行的灭火政策和以国家为中心的产权制度,以及对土著治理体系和知识的有意抹杀,使得依赖火灾的土著社区与以文化为媒介的火灾机制和适应火灾的景观脱钩。这导致了人为火灾的减少,同时也增加了土著居民被排斥在外的野火风险,造成了广泛的社会生态脆弱性。许多当代火灾研究在认识论传统、研究机构的全球地理分布以及研究成果的可获取性方面也带有殖民主义色彩。我们报告了在肯尼亚内罗毕和英国伦敦同时召开的为期两天的题为 "跨越有争议地貌的火灾管理 "研讨会的情况。该研讨会是英国勒弗胡尔姆野火、环境与社会研究中心举办的 "火灾科学非殖民化 "系列研讨会的一部分。在内罗毕举办的研讨会邀请肯尼亚各利益相关方参与促进知识共享的活动,旨在建立一个包容性的消防工作网络。活动包括丰富的图片、世界咖啡馆讨论、参与式艺术,以及共同制定指导肯尼亚火灾管理的宣言。同时,在伦敦,Leverhulme 野火研究人员探索了参与式研究方法,包括丰富图片和参与式视频,并制定了一份宣言,以指导更公平的研究。在整个研讨会期间,内罗毕和伦敦的与会者都有机会相互对话,分享他们的经验以及对肯尼亚和全球复杂火灾挑战的理解。
{"title":"Decolonising Fire Science by Reexamining Fire Management across Contested Landscapes: A Workshop Approach","authors":"Abigail R. Croker, Adriana E. S. Ford, Y. Kountouris, Jay Mistry, Amos Chege Muthiuru, Cathy Smith, Elijah Praise, David O. Chiawo, Veronica Muniu","doi":"10.3390/fire7030094","DOIUrl":"https://doi.org/10.3390/fire7030094","url":null,"abstract":"In many landscapes worldwide, fire regimes and human–fire interactions were reorganised by colonialism and continue to be shaped by neo-colonial processes. The introduction of fire suppression policies and state-centric property-rights systems across conservation areas and the intentional erasure of Indigenous governance systems and knowledge have served to decouple Indigenous fire-dependent communities from culturally mediated fire regimes and fire-adapted landscapes. This has driven a decline in anthropogenic fires while simultaneously increasing wildfire risk where Indigenous people have been excluded, resulting in widespread social–ecological vulnerabilities. Much contemporary fire research also bears colonial legacies in its epistemological traditions, in the global geographical distribution of research institutions, and the accessibility of research outputs. We report on a two-day workshop titled ‘Fire Management Across Contested Landscapes’ convened concurrently in Nairobi, Kenya, and London, UK. The workshop formed part of a series of workshops on ‘Decolonising Fire Science’ held by the Leverhulme Centre for Wildfires, Environment and Society, UK. The workshop in Nairobi invited diverse Kenyan stakeholders to engage in participatory activities that facilitate knowledge sharing, aiming to establish an inclusive working fire network. Activities included rich pictures, world café discussions, participatory art, and the co-development of a declaration to guide fire management in Kenya. Meanwhile, in London, Leverhulme Wildfires researchers explored participatory research methodologies including rich pictures and participatory video, and developed a declaration to guide more equitable research. There were opportunities throughout the workshop for participants in Nairobi and London to engage in dialogue with one another, sharing their experiences and understandings of complex fire challenges in Kenya and globally.","PeriodicalId":12279,"journal":{"name":"Fire","volume":"41 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140235963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Fire
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1