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Grafting of PHGH on lignin improves the antibacterial activity and the usage as an additive of starch film 在木质素上接枝 PHGH 可提高抗菌活性并用作淀粉膜添加剂
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101300
Yali Gao , Xinlu Liu , Shuzhen Ni , Xiaoqian Chen , Yingjuan Fu , Menghua Qin

The insufficient bacteriostatic capacity of lignin greatly limits its application performance in the packaging and medical fields. Herein, a lignin with significantly enhanced antibacterial activity was prepared, in which PHGH (polyhexamethylene guanidine hydrochloride) was chosen to be grafted onto lignin, initiated by the glyoxal induced cross-linking. The grafting of PHGH on the lignin (PHGH-m-lignin) was confirmed by the FTIR, 1H- and 31P NMR spectra. The diameter size and zeta potential of PHGH-m-LNP were evaluated. Compared with that (199.96 nm) of pristine LNP, the diameter size of PHGH-m-LNP decreased to 71.44 nm, and the zeta potential increased to − 25.6 mV from − 30.1 mV. The results of antibacterial activity showed that the PHGH-m-LNP exhibited an excellent antibacterial activity (>99.99 %) towards E.coli. AFM images disclosed the physically antibacterial mechanism of PHGH-m-LNP. For the application, different concentrations of PHGH-m-lignin nanofiller (PHGH-m-LNP) were used to fabricate starch films via casting method. The PHGH-m-LNP could confer the starch film an exceptional antimicrobial activity (antibacterial activities = 98.84 %) at the addition level of 1 % (wt). In addition, the hydrophobicity and UV shielding capacity of starch film were enhanced, with the decreased maximum thermal degradation rate. Therefore, a new way to improve the antibacterial activity of lignin is provided, which is greatly significant for boosting the high-value application potential of lignin in the packaging and medical fields.

木质素的抑菌能力不足极大地限制了其在包装和医疗领域的应用。本文制备了一种抗菌活性明显增强的木质素,通过乙二醛诱导交联,将 PHGH(聚六亚甲基胍盐酸盐)接枝到木质素上。傅立叶变换红外光谱、1H- 和 31P NMR 光谱证实了 PHGH 与木质素(PHGH-m-木质素)的接枝。对 PHGH-m-LNP 的直径大小和 ZETA 电位进行了评估。与原始 LNP 的直径尺寸(199.96 nm)相比,PHGH-m-LNP 的直径尺寸减小到 71.44 nm,zeta 电位从 - 30.1 mV 上升到 - 25.6 mV。抗菌活性结果表明,PHGH-m-LNP 对大肠杆菌具有极佳的抗菌活性(99.99%)。原子力显微镜图像揭示了 PHGH-m-LNP 的物理抗菌机制。在应用中,使用不同浓度的PGH-m-木质素纳米填料(PGH-m-LNP)通过浇铸法制成淀粉膜。当 PHGH-m-LNP 的添加量为 1 %(重量比)时,淀粉膜具有优异的抗菌活性(抗菌活性 = 98.84 %)。此外,淀粉膜的疏水性和紫外线屏蔽能力也得到了增强,最大热降解率降低。因此,这提供了一种提高木质素抗菌活性的新方法,对于提升木质素在包装和医疗领域的高价值应用潜力意义重大。
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引用次数: 0
Innovative use of chitosan/ZnO NPs bio-nanocomposites for sustainable antimicrobial food packaging of poultry meat 壳聚糖/氧化锌氮氧化物生物纳米复合材料在禽肉可持续抗菌食品包装中的创新应用
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101298
Shivitraloshini Sasidharan , Lai-Hock Tey , Sinouvassane Djearamane , Nor Khaizura Mahmud Ab Rashid , Rajeshwari PA , V. Rajendran , Asad Syed , Ling Shing Wong , Vimaleswaran Karani Santhanakrishnan , Vijanth Sagayan Asirvadam , Anto Cordelia Tanislaus Antony Dhanapal

A novel nanocomposite was developed by integrating zinc oxide nanoparticles (ZnO NPs) into chitosan (CS) matrix and investigated for its impact on the quality and shelf life of refrigerated poultry meat over 11 days. Physicochemical properties including weight, pH, titratable acidity, color, thiobarbituric acid reactive substances assay, microbiological growth studies encompassed total psychotropic and mesophilic aerobic microorganisms, Enterobacteriaceae analyses, and zinc migration levels were conducted to determine the optimal nanocomposite concentration. Results revealed that bio-nanocomposite exhibited superior characteristics compared to chemogenic nanocomposite, chitosan, polyvinyl alcohol, and unwrapped meats. Bio-nanocomposite with reduced unsaturated lipid content extends poultry shelf life to 7 days in packaging, outperforming chemogenic-nanocomposites (5 days) and chitosan (4 days). This study proves that CS/ZnO NP nanocomposite is a promising active packaging material for meat, extending their shelf life without deteriorating its physicochemical characteristics and supporting sustainability, though further research on its toxicological properties is warranted.

通过在壳聚糖(CS)基质中添加氧化锌纳米颗粒(ZnO NPs),开发了一种新型纳米复合材料,并研究了它对冷藏禽肉 11 天内的质量和货架期的影响。物理化学特性包括重量、pH 值、可滴定酸度、色度、硫代巴比妥酸活性物质测定、微生物生长研究(包括总精神性和中嗜氧性微生物)、肠杆菌分析和锌迁移水平,以确定最佳纳米复合材料浓度。结果显示,与化学纳米复合材料、壳聚糖、聚乙烯醇和无包装肉类相比,生物纳米复合材料表现出更优越的特性。降低了不饱和脂质含量的生物纳米复合材料将家禽在包装中的保质期延长至 7 天,优于化学纳米复合材料(5 天)和壳聚糖(4 天)。这项研究证明,CS/ZnO NP 纳米复合材料是一种很有前途的肉类活性包装材料,它能延长肉类的货架期,而不会降低其理化特性,并支持可持续发展,不过还需要对其毒理学特性进行进一步研究。
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引用次数: 0
Maize bran arabinoxylans mediated green synthesis of silver nanoparticles and their incorporation in gelatin-based packaging film 玉米麸阿拉伯木聚糖介导的银纳米粒子绿色合成及其在明胶基包装膜中的应用
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101301
Muhammad Ahtisham Raza, Awais Ahmad, Farhan Saeed, Muzzamal Hussain, Muhammad Afzaal, Amara Rasheed

Current research was aimed to extract arabinoxylans (AXs) from maize bran and synthesis of silver nanoparticles (AgNPs) through maize bran arabinoxylans (MBAXs), their characterization, and in-vitro efficacy against S. aureus, E.coli, and K. pneumoniae. Then, AgNPs were loaded in gelatin-based biofilm in different concentrations (0 %, 0.5 %, 1 %, and 1.5 %). The results showed that MBAXs contained arabinose (25.83 %), and xylose (32.12 %) in higher proportions. XRD spectra of MBAXs were amorphous, however, AgNPs capped with MBAXs showed crystalline spectra. SEM micrographs showed the spherical and irregular structure of AgNPs. Further, AgNPs showed an inhibition zone in the range of 7.38–13.78 mm, 11.45–19.14 mm, and 7.00–14.66 mm against E. coli, S. aureus, and K. pneumoniae respectively. FTIR spectra of biofilm showed stretchings at 3270, 2935, 1625, 1542, and 1030 cm−1 which showed the presence of –OH, -CH, and N-H groups of gelatin. An increase in AgNPs concentration, imparted minor changes in SEM micrographs on the film surface. Further, gelatin biofilm showed that the addition of AgNPs didn’t affect the thickness of biofilms but affected the mechanical properties after exceeding 0.5 %. The antimicrobial activity of the biofilm assessed on different foodborne pathogens showed a definite inhibition zone, which showed that packaging films loaded with AgNPs are effective in enhancing the shelf life of food commodities from microbial spoilage. Conclusively, current research showed that MBAXs are suitable for synthesizing AgNPs with definite antimicrobial activity and their incorporation in gelatin biofilm in a concentration-dependent manner could be a sustainable way to the development of sustainable packaging.

目前的研究旨在从玉米麸皮中提取阿拉伯木聚糖(AXs),并通过玉米麸皮阿拉伯木聚糖(MBAXs)合成银纳米粒子(AgNPs),对其进行表征,并对金黄色葡萄球菌、大肠杆菌和肺炎双球菌进行体外药效试验。然后,将不同浓度(0%、0.5%、1% 和 1.5%)的 AgNPs 添加到明胶基生物膜中。结果表明,MBAXs 中阿拉伯糖(25.83%)和木糖(32.12%)的比例较高。MBAXs 的 XRD 图谱为无定形,而添加了 MBAXs 的 AgNPs 则显示出结晶图谱。扫描电镜显微照片显示了 AgNPs 的球形和不规则结构。此外,AgNPs 对大肠杆菌、金黄色葡萄球菌和肺炎双球菌的抑制面积分别为 7.38-13.78 毫米、11.45-19.14 毫米和 7.00-14.66 毫米。生物膜的傅立叶变换红外光谱在 3270、2935、1625、1542 和 1030 cm-1 处显示出伸展,表明明胶中存在 -OH、-CH 和 N-H 基团。随着 AgNPs 浓度的增加,薄膜表面的扫描电镜显微照片也发生了细微变化。此外,明胶生物膜显示,添加 AgNPs 不会影响生物膜的厚度,但超过 0.5 % 后会影响机械性能。对不同食源性病原体的生物膜抗菌活性评估显示,生物膜具有明确的抑制区,这表明添加了 AgNPs 的包装膜能有效延长食品的保质期,防止微生物腐败。总之,目前的研究表明,MBAXs 适合合成具有明确抗菌活性的 AgNPs,以浓度依赖的方式将其加入明胶生物膜中,可以成为开发可持续包装的一种可持续方法。
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引用次数: 0
Antioxidant release, morphology and packaging properties of gallic acid incorporated biodegradable PBAT blended PBS active packaging 含有没食子酸的生物可降解 PBAT 混合 PBS 活性包装的抗氧化剂释放、形态和包装特性
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101304
Pitchaya Pothinuch , Juthathip Promsorn , Shyam S. Sablani , Nathdanai Harnkarnsujarit

Enhancing biodegradable packaging with antioxidative functions effectively improved shelf-life extension capability to reduce food loss and waste. Gallic acid (GA) as antioxidant was compounded with biodegradable polymer blends namely poly(butylene adipate-co-terephthalate) and poly(butylene succinate) (PBAT/PBS) (70/30 and 30/70) at up to 15 % to enhance antioxidant activity. GA addition formed aggregated clumps giving an irregular rough surface, preventing recrystallization and affecting the degree of crystallinity (up to 2-fold) and changes in morphology of each crystalline polymorph, while also modifying mechanical relaxation of the amorphous matrices. Increasing GA content reduced mechanical strength (up to 85 %, and 68 % for 70PBAT/30PBS and 30PBAT/70PBS) and increased permeability (up to 2.4 and 11.8 folds for water vapor and oxygen permeation, respectively) because of a less homogeneous structure. Release of antioxidant capacity was monitored by DPPH radical scavenging activity in aqueous simulants (water, 10 % ethanol, 50 % ethanol and acetic acid) and was mainly dependent on simulant types and GA loading. Radical scavenging activity corresponded with the release of phenolic compounds from the sheets. The 30PBAT/70PBS blend containing GA at 15 % showed the highest antioxidant capacity. Results showed that active biodegradable packaging could be used to prolong the oxidative degradation of foods.

增强可生物降解包装的抗氧化功能可有效延长保质期,减少食品损耗和浪费。作为抗氧化剂的没食子酸(GA)与可生物降解聚合物混合物(即聚(己二酸丁二醇酯-对苯二甲酸丁二醇酯)和聚(丁二酸丁二醇酯)(PBAT/PBS)(70/30 和 30/70)的混合比例高达 15%,以增强抗氧化活性。GA 的添加会形成聚集的团块,使表面变得不规则粗糙,阻止再结晶,影响结晶度(最高达 2 倍)和每种结晶多晶体的形态变化,同时也会改变无定形基质的机械松弛性。GA 含量的增加会降低机械强度(70PBAT/30PBS 和 30PBAT/70PBS 的机械强度分别为 85% 和 68%),并由于结构不均匀而增加渗透性(水蒸气和氧气渗透分别增加 2.4 倍和 11.8 倍)。在水性模拟液(水、10%乙醇、50%乙醇和乙酸)中,通过 DPPH 自由基清除活性监测抗氧化能力的释放情况,这主要取决于模拟液类型和 GA 含量。自由基清除活性与薄片中酚类化合物的释放量相对应。含 15% GA 的 30PBAT/70PBS 混合物显示出最高的抗氧化能力。结果表明,活性生物降解包装可用于延长食品的氧化降解时间。
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引用次数: 0
Innovative edible film for fresh fruit packaging: Formulation and characterization 用于新鲜水果包装的创新型可食用薄膜:配方和表征
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101309
Dandan Niu , Jing Zhang , Chunru Zhou , Linyun Mou , Nokuthula Peace Mchunu , Meng Zhang , Zhengxiang Wang

Edible packaging films are gaining attention as an innovative and sustainable solution for food preservation, providing a protective barrier against physical damage, microbial contamination, and environmental factors. This study aimed to develop an advanced edible packaging film by incorporating galactooligosaccharides (GOS) to strengthen intermolecular interactions and improve film integrity. The composite film, consisting of chitosan (CS), zein, and GOS, was carefully optimized and thoroughly characterized for its physicochemical properties. The impact of GOS incorporation on the film's mechanical strength, barrier properties, and performance in food preservation was systematically investigated. The resulting CS-Zein-GOS film, fabricated with a 1 % (w/v) concentration using the solvent casting technique, exhibited enhanced light-blocking capabilities, improved hydrophobicity, and significantly improved barrier properties against water vapor and oxygen permeability compared to the CS counterpart. Moreover, the composite film displayed thermal stability up to 303.91 °C and superior flexibility, as indicated by elongation at break and tensile strength values. Application tests showed that the CS-Zein-GOS coating effectively extended the shelf life of strawberries and cherries at room temperature by up to three days. Analytical techniques revealed the interaction between the components and confirmed the potential of this novel water-soluble, edible film in food packaging applications, particularly for fresh produce, to extend shelf life and reduce plastic waste. These findings highlight the promising prospects of edible packaging films in addressing sustainability challenges in the food industry.

可食用包装膜作为一种创新的、可持续的食品保鲜解决方案,为食品提供了一道抵御物理损伤、微生物污染和环境因素的保护屏障,因而受到越来越多的关注。本研究旨在通过加入半乳寡糖(GOS)来加强分子间的相互作用,提高薄膜的完整性,从而开发出一种先进的可食用包装膜。研究人员对由壳聚糖(CS)、玉米蛋白和 GOS 组成的复合薄膜进行了仔细的优化,并对其理化性质进行了全面的表征。系统地研究了 GOS 的加入对薄膜的机械强度、阻隔性能和食品保鲜性能的影响。采用溶剂浇铸技术制成的 CS-Zein-GOS 薄膜浓度为 1%(w/v),与 CS 薄膜相比,具有更强的遮光能力、更高的疏水性以及显著改善的水蒸气阻隔性和氧气渗透性。此外,从断裂伸长率和拉伸强度值来看,复合薄膜具有高达 303.91 °C 的热稳定性和优异的柔韧性。应用测试表明,CS-玉米蛋白-GOS 涂层有效地延长了草莓和樱桃在室温下长达三天的保质期。分析技术揭示了各成分之间的相互作用,并证实了这种新型水溶性可食用薄膜在食品包装应用中的潜力,特别是在新鲜农产品方面,可延长保质期并减少塑料垃圾。这些发现凸显了可食用包装薄膜在应对食品工业可持续发展挑战方面的广阔前景。
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引用次数: 0
Development and application of intelligent packaging films based on carboxymethyl starch/PVA with Cu-LTE nanocrystal as functional compatibilizer 以羧甲基淀粉/PVA 为基础、以 Cu-LTE 纳米晶为功能相容剂的智能包装膜的开发与应用
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101306
Nannan Li , Hai Qin , Qun Tang , Daijiang Peng , Xiaoyan Luo , Heping Li , Zhiming Zou

In the realm of food safety, innovative intelligent packaging material that can provide the capacity for timely and effectively monitoring the food freshness are essential. In this work, ammonia-sensitive Cu-based metal organic framework (Cu-LTE) nanocrystal was manufactured and characterized, and then explored as a functional compatibilizer of carboxymethyl starch/polyvinyl alcohol (CMS/PVA) blend to develop novel intelligent packaging film materials. The results demonstrated that the introduction of Cu-LTE nanocrystal into CMS/PVA blend brought about significant promotions regarding to the compatibility, mechanical strength (48.1 MPa), UV-protection (with UV transmittance of only 1.6 %), and moisture/oxygen barrier effectiveness, while preserving long-term colour stability of the blend film. Moreover, the developed CMS/PVA/Cu-LTE blend film featured remarkable antibacterial capacity (over 99.0 %) toward both E. coli and S. aureus bacteria, as well as outstanding colour change ability under ammonia environment. The developed CMS/PVA/Cu-LTE blend film also presented visually identifiable colour change during the monitoring of shrimp deterioration. These findings indicated that the developed CMS/PVA/Cu-LTE blend film should hold tremendous potential as an intelligent active packaging material.

在食品安全领域,能够及时有效地监测食品新鲜度的创新型智能包装材料至关重要。本研究制备并表征了对氨敏感的铜基金属有机框架(Cu-LTE)纳米晶体,并将其作为羧甲基淀粉/聚乙烯醇(CMS/PVA)共混物的功能性相容剂,用于开发新型智能包装膜材料。结果表明,在 CMS/PVA 共混物中引入 Cu-LTE 纳米晶后,共混膜的相容性、机械强度(48.1 兆帕)、紫外线防护性能(紫外线透过率仅为 1.6%)和湿气/氧气阻隔效果都得到了显著提升,同时还保持了长期的颜色稳定性。此外,所开发的 CMS/PVA/Cu-LTE 共混薄膜对大肠杆菌和金黄色葡萄球菌都具有显著的抗菌能力(超过 99.0%),并且在氨环境下具有出色的变色能力。所开发的 CMS/PVA/Cu-LTE 混合薄膜在监测虾的变质过程中还能呈现出肉眼可识别的颜色变化。这些研究结果表明,所开发的 CMS/PVA/Cu-LTE 混合薄膜作为一种智能活性包装材料具有巨大的潜力。
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引用次数: 0
The challenges of food preservation materials and technologies for a more sustainable world 食品保鲜材料和技术对实现更可持续世界的挑战
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101273
Carlos Alberto Fuenmayor , Fabio Licciardello

In a global scenario so severely affected by food insecurity, all food science and technology stakeholders are called to face the most pivotal of the sustainability challenges: ensuring the availability of safe and adaptable foods in all territories; foods that meet our needs as consumers with least possible negative impact. This was the guiding subject of the presentations and discussions that animated the tenth edition of the Shelf Life International Meeting (SLIM 2022), held in Bogotá from November 28th to December 1st 2022. The congress, organized for the first time in Latin America, was the main international rendezvous entirely dedicated to the latest developments and future prospects in the field of shelf life and food packaging. The Colombian capital hosted over 140 researchers and experts from academic institutions and companies around the world, including Colombia, Italy, Spain, Peru, Chile, Mexico, Ecuador, and the United States, who presented 91 scientific contributions. It was an opportunity for an exchange of scientific and technological knowledge on crucial aspects for achieving more sustainable food chains and, consequently, a more sustainable world. A future is possible where food packaging systems and other preservation technologies not only ensure the integrity of our food supply but also minimize environmental impact and promote the well-being of consumers worldwide. We hereby discuss the main outcomes of the meeting, attempting to catalogue and contextualize the selection of works that are part of the Food Packaging and Shelf Life special issue dedicated to SLIM 2022.

在全球粮食不安全问题如此严重的情况下,所有食品科学与技术相关方都需要面对可持续发展方面最关键的挑战:确保所有地区都能获得安全、适应性强的食品;这些食品既能满足我们作为消费者的需求,又能尽可能减少负面影响。这是 2022 年 11 月 28 日至 12 月 1 日在波哥大举行的第十届国际保质期会议(SLIM 2022)上发言和讨论的主题。该会议首次在拉丁美洲举办,是专门讨论保质期和食品包装领域最新发展和未来前景的主要国际会议。来自哥伦比亚、意大利、西班牙、秘鲁、智利、墨西哥、厄瓜多尔和美国等世界各地学术机构和公司的 140 多名研究人员和专家在哥伦比亚首都参加了会议,并提交了 91 篇科学论文。这是一次就实现更可持续的食物链,进而实现更可持续的世界的关键方面交流科技知识的机会。在未来,食品包装系统和其他保存技术不仅能确保食品供应的完整性,还能最大限度地减少对环境的影响,促进全球消费者的福祉。我们在此讨论会议的主要成果,并尝试对《食品包装和保质期》特刊中的部分作品进行编目和背景介绍,该特刊是专门为 2022 年 SLIM 会议出版的。
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引用次数: 0
Improving the antioxidant ability of gelatin-chitosan film by incorporating an oil-in-water (O/W) Pickering emulsion emulsified by betanin-loaded quaternary ammonium-functionalized mesoporous silica nanoparticles 通过加入由倍他宁负载季铵官能化介孔二氧化硅纳米粒子乳化的水包油(O/W)皮克林乳液,提高明胶-壳聚糖薄膜的抗氧化能力
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101303
Jiahao Xu , Zhengang Zhao

Active food packaging films with biological activities are a promising food technology, and antioxidant ability is one of the most important biological activities. In this study, an antioxidant active packaging film was prepared by directly blending gelatin, chitosan and a novel O/W Pickering emulsion and then drying. The emulsion was prepared from two antioxidant compounds, Mesona Chinensis essential oils (MCB-EO) and betanin-loaded quaternary ammonium-functionalized mesoporous silica nanoparticles (betanin-QAMSNPs), which provide this emulsion with high antioxidant activity. After adding the emulsion, the water content (26.63 %), water solubility (28.3 %), and water contact angle (86.2°) of the film are lower than those of the gelatin-chitosan film. The thickness and water vapour permeabilities of the betanin-Pickering emulsion film are 275.25 µm and 4.802 × 10−10 g·s−1·m−1·Pa−1, respectively, which are higher than those of gelatin-chitosan films. Adding betanin-Pickering emulsions can decrease the roughness of the surface, which is observed by atomic force microscopy (AFM) and scanning electron microscopy (SEM). The DPPH and ABTs+ free radical scavenging capacities of the betanin-Pickering emulsion films are 21.77 % and 91.87 %, respectively, which are higher than those of the gelatin-chitosan films (4.64 % and 61.15 %), indicating that adding the betanin-Pickering emulsion can enhance the antioxidant ability of the gelatin-chitosan films. The betanin-Pickering emulsion films can inhibit the oxidation of soybean oil. In conclusion, in this study, a novel food packaging film was successfully prepared and has potential application as an antioxidant food packaging material.

具有生物活性的活性食品包装膜是一种前景广阔的食品技术,而抗氧化能力是最重要的生物活性之一。本研究通过直接混合明胶、壳聚糖和一种新型 O/W Pickering 乳液,然后进行干燥,制备了一种抗氧化活性包装膜。该乳液由两种抗氧化化合物制备而成,一种是中药精油(MCB-EO),另一种是贝特宁负载季铵官能化介孔二氧化硅纳米颗粒(贝特宁-QAMSNPs),这两种化合物使该乳液具有很高的抗氧化活性。加入该乳液后,薄膜的含水量(26.63%)、水溶性(28.3%)和水接触角(86.2°)均低于明胶-壳聚糖薄膜。betanin-Pickering 乳液薄膜的厚度和水蒸气渗透率分别为 275.25 µm 和 4.802 × 10-10 g-s-1-m-1-Pa-1,均高于明胶-壳聚糖薄膜。原子力显微镜(AFM)和扫描电子显微镜(SEM)可以观察到,加入甜菜宁-Pickering 乳液可以降低表面的粗糙度。甜菜素-Pickering 乳液的 DPPH 和 ABTs+ 自由基清除能力分别为 21.77 % 和 91.87 %,高于明胶-壳聚糖薄膜的 4.64 % 和 61.15 %,表明添加甜菜素-Pickering 乳液可以增强明胶-壳聚糖薄膜的抗氧化能力。白桦脂-Pickering 乳液薄膜可以抑制大豆油的氧化。总之,本研究成功制备了一种新型食品包装薄膜,具有作为抗氧化食品包装材料的潜在应用价值。
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引用次数: 0
Active packaging coatings based on pectin modified with phenolic acids and its application in seabass fillet preservation 基于酚酸改性果胶的活性包装涂层及其在鲈鱼片保鲜中的应用
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101302
Pengkai Wang , Peng Fei

In this study, three variants of phenolic acids, namely p-hydroxybenzoic acid (PHBA), p-hydroxyphenylacetic acid (PHAA), and p-hydroxyphenylpropionic acid (PHPA), were integrated into pectin through an enzymatic approach to enhance the preservation efficacy of seabass fillets. Structural elucidation revealed that, under lipase catalysis, each phenolic acid variant was successfully grafted onto pectin via esterification, with the corresponding phenolic acid content being 0.719, 0.699, and 0.731 mmol/g in the p-hydroxyphenylacetic acid-modified pectin (Hb-Pe), p-hydroxyphenylacetic acid-modified pectin (Ha-Pe), and p-hydroxyphenylpropionic acid-modified pectin (Hp-Pe), respectively. Regarding antioxidative activity, the modified pectins showcased a more pronounced inhibition of β-carotene bleaching than their original forms, though there was no noticeable variance in 2,2-diphenyl-1-picrylhydrazyl (DPPH) scavenging. Additionally, the enhanced pectin displayed increased antibacterial activity against Escherichia coli and Staphylococcus aureus, with the Hp-Pe type presenting the most potent inhibitory effect. Moreover, the application of modified pectin as a coating markedly extended the storage duration of seabass fillets, with the Hp-Pe variant being particularly effective.

本研究通过酶解方法将三种酚酸变体(即-羟基苯甲酸(PHBA)、-羟基苯乙酸(PHAA)和-羟基苯丙酸(PHPA))整合到果胶中,以提高鲈鱼片的保鲜效果。结构分析表明,在脂肪酶催化下,每种酚酸变体都能通过酯化作用成功接枝到果胶上,相应的酚酸含量分别为 0.719、0.在-羟基苯乙酸改性果胶(Hb-Pe)、-羟基苯乙酸改性果胶(Ha-Pe)和-羟基苯丙酸改性果胶(Hp-Pe)中,相应的酚酸含量分别为 0.719、0.699 和 0.731 mmol/g。在抗氧化活性方面,虽然 2,2-二苯基-1-苦基肼(DPPH)清除率没有明显差异,但改性果胶对 β-胡萝卜素漂白的抑制作用比原形果胶更明显。此外,增强型果胶对和的抗菌活性也有所提高,其中 Hp-Pe 型的抑制作用最强。此外,使用改性果胶作为涂层可明显延长鲈鱼片的贮藏时间,其中 Hp-Pe 变体的效果尤为显著。
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引用次数: 0
Multifunctional food packaging based on wampee seed starch and red pear peel extracts for simultaneous freshness preservation and visual freshness detection 基于万皮籽淀粉和红梨果皮提取物的多功能食品包装,可同时保鲜和进行视觉新鲜度检测
IF 8 1区 农林科学 Q1 Engineering Pub Date : 2024-06-01 DOI: 10.1016/j.fpsl.2024.101293
Haitao Jiang , Jian Liu , Jiankang Cao , Mohammad Rizwan Khan , Naushad Ahmad , Weibo Jiang

In the present work, the starch was prepared from wampee fruit seeds and wampee seed starch (WSS) was prepared utilized as biopolymers for packaging films for the first time. The red pear peel anthocyanin extracts (RPPAEs) were incorporated as active compounds and indicators into WSS films to develop novel active and intelligent packaging. The WSS have excellent film-forming capacities. The RPPAEs had great compatibility with WSS matrix without influencing their chemical structures. The introduced RPPAEs enhanced the optical performance of WSS films, allowing the improved ultraviolet barrier capacities. The RPPAEs might have some plasticizing effects, which contributed to the reduced tensile strength as well as enhanced elongation at break. Meanwhile, RPPAEs imparted excellent antioxidant capacities and sensitive pH-color responsiveness on WSS films. The WSS-based films had great biodegradability. The active and intelligent WSS/RPPAEs composite films presenting multifunctionality showed promise for the preservation of apple fruits and visible monitoring of shrimp freshness.

在本研究中,我们首次从芒果种子中制备了淀粉,并将芒果种子淀粉(WSS)用作包装薄膜的生物聚合物。将红梨果皮花青素提取物(RPPAEs)作为活性化合物和指示剂添加到 WSS 薄膜中,以开发新型活性智能包装。WSS 具有出色的成膜能力。RPPAEs 与 WSS 基质有很好的相容性,不会影响其化学结构。引入的 RPPAEs 增强了 WSS 薄膜的光学性能,从而提高了紫外线阻隔能力。RPPAEs 可能具有一定的塑化作用,这有助于降低拉伸强度和提高断裂伸长率。同时,RPPAEs 还赋予了 WSS 薄膜出色的抗氧化能力和敏感的 pH 颜色反应能力。基于 WSS 的薄膜具有很好的生物降解性。活性智能 WSS/RPPAEs 复合薄膜具有多功能性,有望用于苹果水果的保鲜和虾类新鲜度的可视监测。
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引用次数: 0
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Food Packaging and Shelf Life
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