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Adoption Dynamics of Organic Pesticides Among Cocoa Producers In Two Ecological Zones Of Ghana 加纳两个生态区可可生产者采用有机农药的动态
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-17 DOI: 10.1002/gch2.202500045
Michael Asigbaase, Simon Abugre, Mary Banowiiri, Josephine Akutteh

The use of organic pesticides to reduce insect and disease infestations and boost agricultural productivity can minimize the health and environmental costs of synthetic pesticides. However, adoption remains slow, and barriers and drivers influencing their uptake among cocoa farmers across different ecological zones are unclear. Grounded in the Diffusion of Innovations Theory, this study investigated perceptions, drivers, barriers, and strategies to enhance organic pesticide adoption among cocoa farmers in two ecological zones. A mixed-methods approach is employed, collecting data from 450 farmers in eight cocoa-growing communities through questionnaire-led interviews. Data are analyzed using linear mixed-effects regression, probit regression, ANOVA, Chi-Square, and thematic analysis. Findings revealed that adopters have a 7%-32% more favorable perception of the environmental and health benefits of organic pesticides, influencing their adoption. Farm characteristics, farming experience, incomes, land tenure, and ecological zone significantly influenced adoption. Non-adopters cited barriers such as high transportation costs, offensive odors, and limited information access. Suggested strategies to enhance adoption included capacity building, financial incentives, improved product availability, institutional support, and awareness campaigns. These findings highlight the need for targeted interventions to address demographic and socio-economic barriers and promote organic pesticide use. Future research should explore longitudinal impacts on productivity and soil health.

使用有机农药减少病虫害和提高农业生产力可以最大限度地减少合成农药的健康和环境成本。然而,采用的速度仍然缓慢,影响不同生态区可可种植者采用它们的障碍和驱动因素尚不清楚。本研究以创新扩散理论为基础,调查了两个生态区可可农户对有机农药使用的认知、驱动因素、障碍和策略。采用混合方法,通过问卷调查的方式,从8个可可种植社区的450名农民那里收集数据。数据分析采用线性混合效应回归、概率回归、方差分析、卡方分析和专题分析。调查结果显示,采用者对有机农药的环境和健康益处的好感度高出7%-32%,这影响了他们的采用度。农场特征、耕作经验、收入、土地权属和生态区对采用率有显著影响。不采用的人列举了诸如高运输成本、难闻的气味和有限的信息获取等障碍。提高采用率的建议策略包括能力建设、财政激励、改进产品可用性、机构支持和宣传活动。这些发现突出表明,需要采取有针对性的干预措施,解决人口和社会经济障碍,促进有机农药的使用。未来的研究应探索对生产力和土壤健康的纵向影响。
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引用次数: 0
The Piggy Solution: Harnessing Food Waste for Sustainable Hog Farming 猪猪解决方案:利用食物浪费实现可持续养猪业
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-16 DOI: 10.1002/gch2.202500073
Matthew C. Ogwu, Catherine E. Hills, Silvana Pietrosemoli

The increasing global population and concomitant rise in food demand lead to significant challenges in sustainable agricultural practices and food waste management. This review explores a promising solution to these challenges by examining the potential of utilizing food waste in hog farming as a sustainable feed resource. The paper highlights the environmental, economic, and social benefits of diverting food waste from landfills and repurposing it for livestock nutrition. Nutritional adequacy, safety, and regulatory frameworks surrounding the use of food waste in hog diets, as well as technological advancements and logistical considerations necessary for the widespread adoption of this practice, are discussed along with pilot projects that have successfully implemented food waste feeding programs, assessing their outcomes in terms of feed efficiency, animal health, and environmental impact. Using food waste as animal feed provides a cost-effective alternative to traditional feedstuffs. It also contributes to the global goal of reducing the food, land, and greenhouse gas (GHG) mitigation gaps by 12%, 27%, and 15%, respectively, by 2050. This practice will significantly lower the carbon footprint of hog farming by redirecting 45% of GHG emissions from conventional feed production to promote a circular economy within the agricultural sector. However, successfully implementing food waste feeding programs requires stringent monitoring and adherence to safety standards to prevent contamination and ensure animal welfare.

全球人口的不断增长以及随之而来的粮食需求的上升,给可持续农业实践和粮食浪费管理带来了重大挑战。这篇综述探讨了一个有希望的解决方案,通过研究在养猪业中利用食物垃圾作为可持续饲料资源的潜力来应对这些挑战。这篇论文强调了从垃圾填埋场转移食物垃圾并将其重新用于牲畜营养的环境、经济和社会效益。围绕在猪粮中使用食物垃圾的营养充足性、安全性和监管框架,以及广泛采用这种做法所必需的技术进步和后勤考虑,与成功实施食物垃圾喂养计划的试点项目一起讨论,评估其在饲料效率、动物健康和环境影响方面的结果。使用食物垃圾作为动物饲料提供了一种具有成本效益的传统饲料替代品。它还有助于实现到2050年将粮食、土地和温室气体减排差距分别缩小12%、27%和15%的全球目标。这种做法将显著降低生猪养殖的碳足迹,将传统饲料生产中45%的温室气体排放重新定向,以促进农业部门的循环经济。然而,成功实施食物垃圾喂养计划需要严格的监控和遵守安全标准,以防止污染和确保动物福利。
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引用次数: 0
Smart and Sustainable Regeneration of Fouled Desalination Membranes Using Artificial Intelligence 利用人工智能技术实现海水淡化污染膜的智能可持续再生
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-14 DOI: 10.1002/gch2.202500235
Muhammad Mubashir, Mustakeem Mustakeem, Ammar Alnumani, Abdulrahman Abutaleb, Ali Hamoud Naji Sumayli, Tausif Ahmad, Muhammad Rizwan Azhar

During the desalination process, scaling, fouling, and degradation are associated issues that lead to a drop in the separation performance of membranes. Membrane regeneration emerges as a critical technology in which upcycling and downcycling can offer a promising avenue for promoting sustainable membrane lifecycle management. Multiple research papers and reviews have critically analyzed the regeneration of membranes, which explains the end-of-cycle assessment and cost analysis of membrane recycling. However, challenges associated with the conventional and innovative regeneration processes are not yet analyzed. The potential impact of artificial intelligence (AI) on membrane regeneration is not explained in the literature. This review paper aims to explore the synergistic relationship between AI and membrane regeneration, elucidating the principles, challenges, opportunities, and emerging trends in this rapidly evolving field. By examining the role of AI techniques in enhancing the understanding, monitoring, and control of regeneration membrane processes, as well as their applications in optimizing regeneration strategies and addressing end-of-life considerations, this paper seeks to provide insights into the transformative potential of AI in reshaping the landscape of membrane regeneration.

在脱盐过程中,结垢、结垢和降解是导致膜分离性能下降的相关问题。膜再生是一项关键技术,其中升级回收和降级回收可以为促进可持续的膜生命周期管理提供有前途的途径。许多研究论文和评论批判性地分析了膜的再生,这解释了膜回收的周期结束评估和成本分析。然而,与传统和创新再生工艺相关的挑战尚未得到分析。人工智能(AI)对膜再生的潜在影响在文献中没有解释。本文旨在探讨人工智能与膜再生之间的协同关系,阐明这一快速发展领域的原理、挑战、机遇和新趋势。通过研究人工智能技术在加强对再生膜过程的理解、监测和控制方面的作用,以及它们在优化再生策略和解决寿命终止问题方面的应用,本文试图提供人工智能在重塑膜再生景观方面的变革潜力的见解。
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引用次数: 0
Performance Optimization of Solar Water Heating Systems Using Molten Salt Thermal Energy Storage Across Varying Tilt Angles 不同倾角下熔盐储能太阳能热水系统性能优化研究
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-02 DOI: 10.1002/gch2.202500074
Natrayan Lakshmaiya, Gobikrishnan Udhayakumar, Prem Kumar Reddy M, Karthick M, Ramya Maranan, Prabhu Paramasivam, Asefash Getachew Girma

This study proposes a novel approach to enhance the performance of solar water heating systems by integrating molten salt thermal energy storage (MSTES) and evaluating its effectiveness under varying tilt angles (15°, 30°, 45°, and 60°). While prior research has extensively explored solar collectors and conventional storage media, there have been limited studies that experimentally assessed the combined effect of MSTES and tilt angle optimization on thermal performance. To address this gap, a parabolic trough collector system is employed using a eutectic mixture of sodium nitrate and potassium nitrate, known for its high thermal stability and energy retention. Key performance metrics, including collector efficiency, heat transfer coefficient, and storage efficiency, are analyzed under different tilt configurations. Results revealed that a 60° tilt angle offered the best performance, achieving a collector efficiency of 75%, a heat transfer coefficient exceeding 880 W m2 K, and a storage efficiency of 61% during peak solar radiation. These findings highlight the effectiveness of MSTES in maximizing solar energy absorption and storage, thereby contributing to the development of high-efficiency solar thermal systems that are adaptable to diverse climatic conditions and energy demands.

本研究提出了一种通过集成熔盐储能(MSTES)来提高太阳能热水系统性能的新方法,并评估了其在不同倾斜角度(15°,30°,45°和60°)下的有效性。虽然之前的研究广泛地探索了太阳能集热器和传统的存储介质,但实验评估MSTES和倾角优化对热性能的综合影响的研究有限。为了解决这个问题,采用了一个抛物线槽集热器系统,使用硝酸钠和硝酸钾的共晶混合物,以其高热稳定性和能量保留性而闻名。关键性能指标,包括集热器效率,传热系数和存储效率,在不同的倾斜配置进行了分析。结果表明,当倾角为60°时,集热器效率可达75%,传热系数超过880 W m−2 K,在太阳辐射峰值时存储效率可达61%。这些发现突出了MSTES在最大限度地吸收和储存太阳能方面的有效性,从而有助于开发适应各种气候条件和能源需求的高效太阳能热系统。
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引用次数: 0
Computational Perspectives on Amoxicillin and Staphylococcus Aureus in Mirror Life 阿莫西林和金黄色葡萄球菌在镜像生命中的计算前景
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-02 DOI: 10.1002/gch2.202500051
Lorenzo Pedroni, Chiara Dall'Asta, Gianni Galaverna, Luca Dellafiora

The concept of mirror life is first introduced by Louis Pasteur, referring to biological systems composed of enantiomeric biomolecules. Although nowadays technologies are making a mirror life theoretically achievable, its potential risks remain uncertain. Here, an integrated multi-tier computational pipeline is employed to address the potential environmental threat posed by the hypothetical mirror-image of Staphylococcus aureus, a bacterium relevant to environmental and food safety. The findings suggest that amoxicillin, and perhaps other conventional antibiotics, should not be effective against their mirror targets. On the other hand, the enantiomeric amoxicillin may be a successful counteracting measure, although the risks for the biosphere remain unknown. Overall, this study highlights the need for further dedicated investigations in this field, while emphasizing in silico methods, in particular molecular modeling, as a versatile and effective first-line approach for analysis, free from biohazards and technical limitations of reagents supply.

镜像生命的概念最早是由巴斯德提出的,指的是由对映体生物分子组成的生物系统。虽然现在的技术使镜像生命在理论上可以实现,但其潜在的风险仍然不确定。本文采用一体化的多层计算管道来解决与环境和食品安全相关的细菌金黄色葡萄球菌(Staphylococcus aureus)的假想镜像所带来的潜在环境威胁。研究结果表明,阿莫西林,也许还有其他传统抗生素,对它们的镜像目标不应该有效。另一方面,对映体阿莫西林可能是一种成功的对抗措施,尽管其对生物圈的风险尚不清楚。总的来说,这项研究强调了在这一领域进一步专门研究的必要性,同时强调了硅方法,特别是分子建模,作为一种通用和有效的一线分析方法,没有生物危害和试剂供应的技术限制。
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引用次数: 0
Removal of Phenol by Ozonation in Strongly Alkaline Conditions using a Jet Loop Reactor Operated in Continuous Phase 连续相喷射循环反应器在强碱性条件下臭氧氧化去除苯酚的研究
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-02 DOI: 10.1002/gch2.202500085
Melahat Semin Barlak, Ibrahim Cengiz, Nejdet Degermenci, Ergun Yildiz

In this study, phenol removal by ozonation under strong alkaline conditions in a continuously operated jet loop reactor (JLR) is investigated. The effects of inlet ozone gas concentration, hydraulic retention time (HRT), and influent phenol concentration on phenol, chemical oxygen demand (COD), and total organic carbon (TOC) removal in the JLR effluent are evaluated. When the inlet ozone gas concentration is 17.5 gO3 m−3, the steady-state phenol, COD, and TOC removal efficiencies are determined as 97.8%, 61.1%, and 32.2%, respectively. When the inlet ozone concentration increases from 17.5 to 56.5 gO3 m−3, phenol is not detected in the JLR effluent. The system operates at different HRTs, and the highest removal efficiency at steady-state is obtained at 8 h HRT. While phenol is completely removed at this HRT, COD and TOC removals are 76.8% and 48.2%, respectively. An increase in phenol concentration in the JLR influent leads to a reduction in the phenol, COD, and TOC removal efficiencies in the steady-state effluent.

研究了连续运行射流循环反应器(JLR)在强碱性条件下臭氧氧化对苯酚的去除效果。考察了进口臭氧气体浓度、水力停留时间(HRT)和进水苯酚浓度对捷豹路虎出水苯酚、化学需氧量(COD)和总有机碳(TOC)去除率的影响。当进口臭氧气体浓度为17.5 gO3 m−3时,稳态苯酚、COD和TOC去除率分别为97.8%、61.1%和32.2%。当进口臭氧浓度从17.5 gO3 m−3增加到56.5 gO3 m−3时,JLR出水中未检测到苯酚。系统在不同的HRT下运行,在HRT为8 h时获得了最高的稳态去除效率。在此HRT下,苯酚完全去除,COD和TOC去除率分别为76.8%和48.2%。JLR进水中苯酚浓度的增加导致稳态出水中苯酚、COD和TOC去除效率的降低。
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引用次数: 0
Global Challenges: Bridging Business, Law, Science, Design, and Engineering for Sustainability 全球挑战:为可持续发展架起商业、法律、科学、设计和工程的桥梁
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-06-30 DOI: 10.1002/gch2.202500273
Rui Torres de Oliveira, Agnes Toth-Peter, Leonie Barner

The 21st century faces a planetary crisis, where biodiversity loss, climate change, resource depletion (caused by human activities), technological disruptions, and economic inequality intersect to challenge sustainable development.[1, 2] These interconnected issues have brought sustainability to the forefront as a critical concept.[3] What began as a focus on environmental issues has evolved into a rich, multidimensional concept, and sustainability now integrates economic and social considerations alongside ecological concerns, giving rise to a broad and dynamic range of sustainability discourses. Sustainability has become a central ambition across policy, business, and academia, with a substantial and enduring influence that continues to shape national and international agendas and drive action across sectors.[4]

Sustainability and sustainable development emphasise that human development and economic growth should occur without threatening people, animals, ecosystems, or the Earth's stability.[5] However, current indicators starkly challenge this ideal. In 2024, Earth Overshoot Day, marking the date when resource consumption exceeds Earth's capacity to regenerate those resources, fell on August 1, highlighting the ongoing ecological deficit.[6] Further, as of 2023, six of the nine planetary boundaries have been transgressed, placing humanity outside the Earth's safe operating space. These include climate change, biodiversity loss, freshwater use, land change, biogeochemical flows, and novel entities.[2]

Tackling these sustainability challenges is complex, and it requires collaboration across fields, as no single discipline can fully grasp or resolve these systemic issues and develop innovative, viable, and practical solutions. Despite the recognised need for interdisciplinary approaches to help solve these complex problems, the integration of different disciplines remains bound to barriers and challenges.[7, 8]

In the context of research and academia, the concept of sustainability appeared in the mid-1980s.[9] However, disciplines such as business, economics, law, science, design, and engineering have traditionally operated within distinct silos, with limited potential for cross-disciplinary synergy. As a result, the interest and focus of these fields often differ, with each discipline prioritizing unique questions to shape their approach to sustainability. For instance, business scholars focus on sustainability through the lenses of management, economics, international business, strategy, organizational and consumer behavior, and econo

21世纪面临着一场全球性危机,生物多样性丧失、气候变化、资源枯竭(由人类活动引起)、技术中断和经济不平等交织在一起,对可持续发展构成挑战。[1,2]这些相互关联的问题使可持续发展成为一个重要的概念最初关注环境问题已经演变成一个丰富的、多维的概念,可持续发展现在将经济和社会因素与生态问题结合起来,产生了广泛而动态的可持续发展话语。可持续发展已成为政策、商业和学术界的核心目标,其巨大而持久的影响将继续塑造国家和国际议程,并推动各部门的行动。bbb可持续性和可持续发展强调人类发展和经济增长不应威胁到人类、动物、生态系统或地球的稳定然而,目前的指标明显挑战了这一理想。2024年8月1日是“地球超载日”(Earth Overshoot Day),标志着资源消耗超过地球再生能力的日期,突显出持续的生态赤字此外,截至2023年,九个行星边界中的六个已经被越过,将人类置于地球安全操作空间之外。这些挑战包括气候变化、生物多样性丧失、淡水利用、土地变化、生物地球化学流动和新实体。应对这些可持续发展挑战是复杂的,需要跨领域的合作,因为没有一个学科可以完全掌握或解决这些系统性问题,并制定出创新、可行和实用的解决方案。尽管人们认识到需要跨学科的方法来帮助解决这些复杂的问题,但不同学科的整合仍然受到障碍和挑战的束缚。[7,8]在研究和学术界的背景下,可持续性的概念是在20世纪80年代中期出现的然而,商业、经济、法律、科学、设计和工程等学科传统上在不同的领域内运作,跨学科协同的潜力有限。因此,这些领域的兴趣和重点往往不同,每个学科优先考虑独特的问题,以形成他们的可持续发展方法。例如,商业学者通过管理学、经济学、国际商务、战略、组织和消费者行为以及经济可行性等视角关注可持续性[10,11],而科学学者则通过实证观察、建模和实验分析来探索环境和生态维度。[12-14]工程研究人员强调技术进步、工艺优化和材料效率以实现可持续的工程过程,[15,16]法律学者通过制定监管框架、强制执行合规以及制定平衡经济发展与环境和社会责任的政策,在可持续性方面发挥着至关重要的作用。[17,18]尽管这些观点具有共同的目标和互补性,但研究方法、理论框架和出版规范的差异往往会阻碍有意义的合作。b[19]整合商业、经济、法律、科学、设计和工程研究的一个根本挑战源于它们不同的认识论和方法论传统,因为“两个对立的学科可以看同一件事,也可以看不同的事情。”[20,第11页]商业研究通常采用建构主义或解释主义认识论,通过案例研究、民族志和话语分析等定性方法探索可持续性,这些方法服务于理论阐述和生成,而不是检验同样,法律研究也经常结合实证方法,包括定性案例研究和比较法律分析,以评估可持续性法律在实践中的有效性和实施情况相比之下,科学在很大程度上依赖于实证主义和后实证主义的方法,运用经验方法、实地实验和计算模型,利用一般规则、原则和系统技术来分析环境变化工程研究同样植根于实证主义传统,依靠定量方法、对照实验和模拟建模来开发可持续发展的技术解决方案。b[24]然而,这些不同的研究范式使得很难建立共同的基础。虽然每个领域都旨在为理论建设做出贡献,但它们在理论的发展方式上有所不同,因为每个学科都依赖于一套不同的观察类别和意义。 [20]例如,商业优先考虑战略影响,科学侧重于基础发现和环境影响,工程强调技术可行性和优化,法律研究检查监管框架,治理机制和合规结构,以确保可持续性政策的可执行性和有效性。因此,在任何跨学科合作的开始,建议建立一个关于语言和术语的共同基础,以实现问题的共享框架,并学习彼此学科的关键术语以及研究方法。认识论和方法上的分歧也延伸到出版规范和同行评审过程,每个学科都要求研究成果符合自己的既定标准商业和经济研究遵循严格的双盲审查过程,这被发现具有较低的接受率和广泛和更关键的修订,往往导致出版周期长达三年。另一方面,科学和工程研究经常采用单盲(只对作者隐藏审稿人的身份)或开放的审稿过程,从而导致更短的发表时间。然而,单盲过程可能会产生偏见,比如男性通讯作者的接受率要高得多评审系统和期望的这些差异可能会给跨学科研究造成障碍,因为来自一个领域的学者可能很难达到另一个领域的方法和编辑标准。结果,知识的产生往往受到特定期刊出版规范的影响,而不是关注对推进知识和为实践和政策提供信息最关键的东西。此外,由于资金结构、研究激励和行业参与模式的差异,跨学科合作仍然具有挑战性。科学和工程研究通常由政府和行业资助的项目推动,旨在解决特定的技术或生态问题,而商业和经济研究更有可能得到优先考虑理论贡献的学术资助的支持。此外,与商业或法律研究相比,科学和工程研究通常需要更多的资金,因为它们依赖于资源密集型和有形资产,如基础设施、实验室、设备和研究人员。此外,即使研究人员从事跨学科项目,他们也常常面临获得资金的困难,这主要是由于资助机构的项目优先级不同这些错位导致了孤立的项目,阻碍了跨学科的合作。然而,这些错位也显示了一个未开发的机会,可以相互学习,并将技术创新和科学发现与商业战略、设计和政策相结合。这突出了商业、经济、法律、科学、设计和工程研究人员之间合作的必要性,以通过综合方法开发技术上可行、科学上合理、经济上可行的综合可持续解决方案。此外,弥合这一学科鸿沟还需要学术界、工业界和政策制定者之间加强合作,以确保与行业相关的研究整合了商业、科学、设计和工程的观点,并尝试更实际的可持续性解决方案。例如,商业和法律学者可以对市场采用、监管和立法挑战以及消费者行为提供见解。与此同时,科学学者提供环境影响和自然资源管理的关键数据,工程师和设计师能够开发可持续的生产过程,可再生能源系统和生态高效的设计。特别是对成功合作和设计思维的案例研究,可以为未来的研究提供有价值的模型,并突出将跨学科专业知识整合到可持续性方面的最佳做法。全球挑战旨在通过为商业、经济、法律、科学、设计和工程等领域的研究人员提供跨学科对话与合作的平台,解决这些差异。通过汇集不同的认识论和方法论方法和观点,我们的目标是协调学科差异,整合这些见解,以加速可持续发展知识的进步,并为紧迫的环境和社会问题创造可行的解决方案。 作为跨学科研究领域的领先期刊之一,我们以这一重点为期刊的核心,鼓励关注可持续发展的跨领域性质的贡献,并尽可能提出整合商业、经济、法律、科学、设计和工程见解的框架。这并不意味着我们需要一次整合所有这些不同的学科,而是要有批判性思维,根据手头的问题找到合适的专家。因此,在《全球挑战》中,我们感兴趣的是理论、设计思维、现实世界的例子和评论文章,这些文章展示了成功的跨学科合作,并引入了弥合这些领域之间差距的新方法,以促进可持续发展。简而言之,《全球挑战》渴望建立新的研究范式,超越传统和孤立的学科界限,促进更有效、及时和可扩展的可持续性解决方案,同时尊重作者所在学科的独特性和差异。通过这种方式,我们欢迎来自不同领域的想法,并提供机会来严格审查和整合它们,以实现更大的潜在影响。在可持续发展的重点,全球挑战邀请高质量的概念,经验和方法论文,强调可持续发展问题的复杂性和相互联系的本质。鼓励提交新的见解,批判性地审视现有方法,包括治理和监管结构,并提出创新的框架、方法、新的伙伴关系和资助途径。作者声明无利益冲突。
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引用次数: 0
Potential Waste-to-Wealth Strategy for Combining Medical Surgical Gloves-Derived Pyrolysis Oil with Pentanol and Nanoparticles: Experimental Analysis on Engine Behaviors 医用外科手套衍生热解油与戊醇和纳米颗粒相结合的潜在废物转化财富策略:发动机行为的实验分析
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-06-28 DOI: 10.1002/gch2.202500031
T Sathish, Ümit Ağbulut, Jayant Giri, Moaz Al-lehaibi, Ahmad O. Hourani, Anh Tuan Hoang

In this work, the applicability of surgical glove waste pyrolysis oil (SGWPO) combined with pentanol and nano-additives (silicon dioxide (SiO2) and nano-graphene) as a substitute fuel for a 5.2 kW-diesel engine is experimentally conducted, aiming to analyze the test engine's performance and emission characteristics. Neat SGWPO could reach 8.6% less BTE, 32.24%, 18.27%, 36.17%, and 9.72% higher NOx, smoke, CO, and HC emissions than diesel at full load. However, blending SGWPO with 25% pentanol by volume and 100 ppm of SiO2 nanoparticles or 100 ppm of nanographene could improve the engine results. The obtained results of the nanographene-included SGWPO/pentanol blend are lower than SiO2-included SGWPO/pentanol blend compared to neat SGWPO. Indeed, the nano-SiO2-added SGWPO/pentanol blend demonstrated 9.72% higher BTE and 36.81%, 29.1%, 33.06%, and 25.67% reduced NOx, smoke, CO, and hydrocarbon emissions, respectively, compared to neat SGWPO. Therefore, nano-SiO2-included SGWPO/pentanol is recommended as an alternative fuel for diesel engine operation without any modifications. The recommended nanofuel blend usage in engines simultaneously supports much higher engine performance along with reduced emissions, showing the dual benefits of the waste-to-wealth strategy of surgical glove waste.

本研究对医用手套废热解油(SGWPO)与戊醇、纳米添加剂(二氧化硅(SiO2)和纳米石墨烯)联合作为5.2 kw柴油机替代燃料的适用性进行了实验研究,旨在分析试验发动机的性能和排放特性。纯SGWPO在满负荷工况下,BTE比柴油低8.6%,NOx、smoke、CO和HC排放量分别高32.24%、18.27%、36.17%和9.72%。然而,将SGWPO与体积为25%的戊醇和100 ppm的SiO2纳米粒子或100 ppm的纳米石墨烯混合可以改善发动机的性能。与纯SGWPO相比,含纳米石墨烯的SGWPO/戊醇共混物的所得结果低于含sio2的SGWPO/戊醇共混物。事实上,与纯SGWPO相比,添加纳米sio2的SGWPO/戊醇混合物的BTE提高了9.72%,NOx、烟雾、CO和碳氢化合物的排放量分别降低了36.81%、29.1%、33.06%和25.67%。因此,建议使用含纳米sio2的SGWPO/戊醇作为柴油发动机的替代燃料,无需任何修改。在发动机中推荐使用纳米燃料混合物,同时支持更高的发动机性能和减少排放,显示了手术手套废物变废为宝战略的双重好处。
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引用次数: 0
Can the Thermal Runaway of a Thionyl Chloride Cells Generate a Shock Wave? 亚硫酰氯电池的热失控会产生激波吗?
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-06-26 DOI: 10.1002/gch2.202500140
Juliette Charbonnel, Sébastien Dubourg, Etienne Testard, Thibaut Rochard, Christophe Magnier, David Brun-Buisson, Rémi Vincent

Due to their high energy density, thionyl chloride technology are used in a wide range of applications in the aerospace industry. These cells consist of a lithium metal anode and a SOCl2 liquid cathode. The safety problems posed by these cells received particular attention in the 70 and 80s. However, the generation of shock waves during thermal runaway has never been demonstrated. In this article, for the second time, aerial shock waves are characterized for cells composed of lithium metal. Although the TNT equivalent of thionyl chloride cells is widely dispersed between 0.008 and 0.3 g. Its impact on the mechanical structures of the battery module should not be neglected, nor should its impact on people.

由于其高能量密度,亚硫酰氯技术在航空航天工业中有着广泛的应用。这些电池由锂金属阳极和SOCl2液体阴极组成。这些电池带来的安全问题在70年代和80年代受到了特别关注。然而,热失控过程中激波的产生从未被证实。在本文中,第二次对由锂金属组成的电池进行了航空冲击波的表征。虽然亚硫酰氯细胞的TNT当量广泛分布在0.008至0.3 g之间。它对电池模块机械结构的影响不容忽视,对人的影响也不容忽视。
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引用次数: 0
Bactericidal, Virucidal, and Biocompatible Properties of 3D Printed Materials Enhanced with Copper and Zinc Nanoparticles 铜和锌纳米颗粒增强的3D打印材料的杀菌、杀毒和生物相容性
IF 6.4 4区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-06-16 DOI: 10.1002/gch2.202500106
Andrei-Florin Sandu, Lauren Acton, Phillip Gould

The heightened spread of pathogens due to population growth, urbanization, and climate change presents significant health challenges, exacerbated by high transmission, virulence, antimicrobial resistance (AMR), and novel variants. Hospital-acquired infections (HAI) affect 1 in 31 hospitalized patients, costing $28.4 billion annually. This study introduces a novel approach to pathogen control by integrating copper and zinc oxide nanoparticles into 3D printed Stereolithography (SLA) materials. The 3D impregnated material demonstrates reproducibility and efficacy across different 3D platforms, showcasing complete bactericidal/fungicidal effects against twelve diverse species and a 4 log virucidal activity on eight clinically relevant viral species within 2 h. No significant cytotoxicity is observed in primary human keratinocytes after 2 h of contact. The material maintains its antipathogenic activity after a year of accelerated ageing, suggesting enhances stability and performance over time. This method addresses the limitations of conventional cleaning and surface spraying, which often fall short in efficacy and longevity; for the first time, the incorporation of commercially available nanoparticles into 3D printable materials offers a versatile long-lasting antipathogenic and biocompatible solution for high-contact surfaces in public and clinical settings, reducing the need for cleaning surfaces while limiting infection rates, the threat of AMR, and other future infectious outbreaks.

由于人口增长、城市化和气候变化,病原体的传播加剧,带来了重大的健康挑战,并因高传播、毒力、抗微生物药物耐药性(AMR)和新变种而加剧。医院获得性感染(HAI)影响了31名住院患者中的1人,每年造成284亿美元的损失。本研究介绍了一种将铜和氧化锌纳米颗粒整合到3D打印立体光刻(SLA)材料中的新型病原体控制方法。3D浸渍材料在不同的3D平台上表现出可重复性和有效性,在2小时内对12种不同的物种具有完全的杀菌/杀真菌作用,对8种临床相关病毒具有4倍的杀病毒活性。接触2小时后,未观察到人类角化细胞有明显的细胞毒性。这种材料在经过一年的加速老化后仍能保持其抗病原体活性,这表明随着时间的推移,其稳定性和性能有所提高。该方法解决了传统清洁和表面喷涂的局限性,这些局限性往往在功效和寿命方面不足;首次将商业上可用的纳米颗粒结合到3D打印材料中,为公共和临床环境中的高接触表面提供了一种多功能持久的抗致病性和生物相容性解决方案,减少了清洁表面的需要,同时限制了感染率、抗菌素耐药性的威胁和其他未来的传染病爆发。
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引用次数: 0
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