Chin Ho Kirk, Chiang Yon Douglas Chong, Xingyang Wang, Jianguo Sun, Qi Zhao, John Wang
Ceramic membranes are taking center stage for separation technologies in water treatment. Among them, ceramic nanofiltration membranes are at the forefront of membrane technologies. The desalination of seawater using ceramic nanofiltration membranes is a potential application toward increasing the global water supply and tackling water scarcity. However, while the high fabrication cost poses a challenge to their large-scale applications, high-value separation applications can help to offset the overall cost. In this regard, ceramic nanofiltration membranes can also be explored as a viable option for high-value lithium extraction from the waste seawater brine. In order to determine the potential of nanofiltration ceramic membranes for desalination and lithium recovery from seawater, the current efficiency of salt rejection across various operation parameters must be thoroughly evaluated. Specifically, the interactions between the Donnan exclusion, steric exclusion, zeta potential, and salt concentration play an important role in determining the salt rejection efficiency. Several strategies are then proposed to guide ceramic nanofiltration membranes toward potentially practical applications regarding desalination and lithium recovery.
{"title":"Nanofiltration Ceramic Membranes as a Feasible Two-Pronged Approach toward Desalination and Lithium Recovery","authors":"Chin Ho Kirk, Chiang Yon Douglas Chong, Xingyang Wang, Jianguo Sun, Qi Zhao, John Wang","doi":"10.1002/gch2.202300151","DOIUrl":"10.1002/gch2.202300151","url":null,"abstract":"<p>Ceramic membranes are taking center stage for separation technologies in water treatment. Among them, ceramic nanofiltration membranes are at the forefront of membrane technologies. The desalination of seawater using ceramic nanofiltration membranes is a potential application toward increasing the global water supply and tackling water scarcity. However, while the high fabrication cost poses a challenge to their large-scale applications, high-value separation applications can help to offset the overall cost. In this regard, ceramic nanofiltration membranes can also be explored as a viable option for high-value lithium extraction from the waste seawater brine. In order to determine the potential of nanofiltration ceramic membranes for desalination and lithium recovery from seawater, the current efficiency of salt rejection across various operation parameters must be thoroughly evaluated. Specifically, the interactions between the Donnan exclusion, steric exclusion, zeta potential, and salt concentration play an important role in determining the salt rejection efficiency. Several strategies are then proposed to guide ceramic nanofiltration membranes toward potentially practical applications regarding desalination and lithium recovery.</p>","PeriodicalId":12646,"journal":{"name":"Global Challenges","volume":"8 2","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gch2.202300151","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139556378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hakan Aygun, Mohammad Rauf Sheikhi, Hakan Caliskan
In this study, thermodynamic analysis is implemented to the kerosene-fuelled high by-pass turbofan (HBP-TF) engine to assess entropy, exergy, environmental, and sustainability metrics for different design variables such as pressure ratio of high-pressure compressor (HPC-PR) ranging from 7.5 to 8.5 and turbine inlet temperature (TIT) varying from 1400 to 1525 K considering variable needs in the aviation industry. As a novelty, entropic improvement potential (EIP) index for turbomachinery components and specific irreversibility production for the whole engine are calculated. Sustainability-based parameters for different cases are compared with the baseline values of the HBP-TF engine. The combustor has the highest entropy production of 44.4425 kW K−1 at the baseline. The higher TIT increases the entropy production of the combustor by 16.56%, whereas the higher HPC-PR decreases it by 5.83%. The higher TIT and HPC-PR favorably affect the sustainable efficiency factor of the engine, which is observed as 1.5482 at baseline and increases by 4.5% and 0.058% with the increment of TIT and HPC-PR, respectively. The higher TIT and higher HPC-PR results in lowering sustainability of the engine. The specific irreversibility production of the engine decreases by 3.78% and 0.1171% respectively, as TIT and HPC-PR reach the highest point considered in the study.
{"title":"Thermodynamics, Environmental and Sustainability Impacts of a Turbofan Engine Under Different Design Conditions Considering Variable Needs in the Aviation Industry","authors":"Hakan Aygun, Mohammad Rauf Sheikhi, Hakan Caliskan","doi":"10.1002/gch2.202300205","DOIUrl":"10.1002/gch2.202300205","url":null,"abstract":"<p>In this study, thermodynamic analysis is implemented to the kerosene-fuelled high by-pass turbofan (HBP-TF) engine to assess entropy, exergy, environmental, and sustainability metrics for different design variables such as pressure ratio of high-pressure compressor (HPC-PR) ranging from 7.5 to 8.5 and turbine inlet temperature (TIT) varying from 1400 to 1525 K considering variable needs in the aviation industry. As a novelty, entropic improvement potential (EIP) index for turbomachinery components and specific irreversibility production for the whole engine are calculated. Sustainability-based parameters for different cases are compared with the baseline values of the HBP-TF engine. The combustor has the highest entropy production of 44.4425 kW K<sup>−1</sup> at the baseline. The higher TIT increases the entropy production of the combustor by 16.56%, whereas the higher HPC-PR decreases it by 5.83%. The higher TIT and HPC-PR favorably affect the sustainable efficiency factor of the engine, which is observed as 1.5482 at baseline and increases by 4.5% and 0.058% with the increment of TIT and HPC-PR, respectively. The higher TIT and higher HPC-PR results in lowering sustainability of the engine. The specific irreversibility production of the engine decreases by 3.78% and 0.1171% respectively, as TIT and HPC-PR reach the highest point considered in the study.</p>","PeriodicalId":12646,"journal":{"name":"Global Challenges","volume":"8 2","pages":""},"PeriodicalIF":4.9,"publicationDate":"2024-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gch2.202300205","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139495368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dongxiao Li, Anurag Yadav, Hong Zhou, Kaustav Roy, Pounraj Thanasekaran, Chengkuo Lee
Metal-organic frameworks (MOFs) that are the wonder material of the 21st century consist of metal ions/clusters coordinated to organic ligands to form one- or more-dimensional porous structures with unprecedented chemical and structural tunability, exceptional thermal stability, ultrahigh porosity, and a large surface area, making them an ideal candidate for numerous potential applications. In this work, the recent progress in the design and synthetic approaches of MOFs and explore their potential applications in the fields of gas storage and separation, catalysis, magnetism, drug delivery, chemical/biosensing, supercapacitors, rechargeable batteries and self-powered wearable sensors based on piezoelectric and triboelectric nanogenerators are summarized. Lastly, this work identifies present challenges and outlines future opportunities in this field, which can provide valuable references.
{"title":"Advances and Applications of Metal-Organic Frameworks (MOFs) in Emerging Technologies: A Comprehensive Review","authors":"Dongxiao Li, Anurag Yadav, Hong Zhou, Kaustav Roy, Pounraj Thanasekaran, Chengkuo Lee","doi":"10.1002/gch2.202300244","DOIUrl":"10.1002/gch2.202300244","url":null,"abstract":"<p>Metal-organic frameworks (MOFs) that are the wonder material of the 21st century consist of metal ions/clusters coordinated to organic ligands to form one- or more-dimensional porous structures with unprecedented chemical and structural tunability, exceptional thermal stability, ultrahigh porosity, and a large surface area, making them an ideal candidate for numerous potential applications. In this work, the recent progress in the design and synthetic approaches of MOFs and explore their potential applications in the fields of gas storage and separation, catalysis, magnetism, drug delivery, chemical/biosensing, supercapacitors, rechargeable batteries and self-powered wearable sensors based on piezoelectric and triboelectric nanogenerators are summarized. Lastly, this work identifies present challenges and outlines future opportunities in this field, which can provide valuable references.</p>","PeriodicalId":12646,"journal":{"name":"Global Challenges","volume":"8 2","pages":""},"PeriodicalIF":4.9,"publicationDate":"2023-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gch2.202300244","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139068411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Niranjana Sundararajan, Heena Shabnam Habeebsheriff, Karthikkumar Dhanabalan, Vo Huu Cong, Ling Shing Wong, Ranjithkumar Rajamani, Bablu Kumar Dhar
Green nanotechnology, an emerging field, offers economic and social benefits while minimizing environmental impact. Nanoparticles, pivotal in medicine, pharmaceuticals, and agriculture, are now sourced from green plants and microorganisms, overcoming limitations of chemically synthesized ones. In agriculture, these green-made nanoparticles find use in fertilizers, insecticides, pesticides, and fungicides. Nanofertilizers curtail mineral losses, bolster yields, and foster agricultural progress. Their biological production, preferred for environmental friendliness and high purity, is cost-effective and efficient. Biosensors aid early disease detection, ensuring food security and sustainable farming by reducing excessive pesticide use. This eco-friendly approach harnesses natural phytochemicals to boost crop productivity. This review highlights recent strides in green nanotechnology, showcasing how green-synthesized nanomaterials elevate crop quality, combat plant pathogens, and manage diseases and stress. These advancements pave the way for sustainable crop production systems in the future.
{"title":"Mitigating Global Challenges: Harnessing Green Synthesized Nanomaterials for Sustainable Crop Production Systems","authors":"Niranjana Sundararajan, Heena Shabnam Habeebsheriff, Karthikkumar Dhanabalan, Vo Huu Cong, Ling Shing Wong, Ranjithkumar Rajamani, Bablu Kumar Dhar","doi":"10.1002/gch2.202300187","DOIUrl":"10.1002/gch2.202300187","url":null,"abstract":"<p>Green nanotechnology, an emerging field, offers economic and social benefits while minimizing environmental impact. Nanoparticles, pivotal in medicine, pharmaceuticals, and agriculture, are now sourced from green plants and microorganisms, overcoming limitations of chemically synthesized ones. In agriculture, these green-made nanoparticles find use in fertilizers, insecticides, pesticides, and fungicides. Nanofertilizers curtail mineral losses, bolster yields, and foster agricultural progress. Their biological production, preferred for environmental friendliness and high purity, is cost-effective and efficient. Biosensors aid early disease detection, ensuring food security and sustainable farming by reducing excessive pesticide use. This eco-friendly approach harnesses natural phytochemicals to boost crop productivity. This review highlights recent strides in green nanotechnology, showcasing how green-synthesized nanomaterials elevate crop quality, combat plant pathogens, and manage diseases and stress. These advancements pave the way for sustainable crop production systems in the future.</p>","PeriodicalId":12646,"journal":{"name":"Global Challenges","volume":"8 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2023-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gch2.202300187","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139036423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Separating valuable materials such as dyes from wastewater using membranes and returning them to the production line is a desirable environmental and economical procedure. However, sometimes, besides filtration, adsorption, and separation processes, pollutant destruction also can be suitable using photocatalytic membranes. The art of producing nanohybrid materials in contrast with nanocomposites encompasses nanomaterial synthesis as a new product with different properties from raw materials for nanohybrids versus the composition of nanomaterials for nanocomposites. According to the findings of this research, confirming proper synthesis of nanohybrid is one challenge that can be overcome by different analyses, other researchers' reports, and the theoretical assessment of physical or chemical reactions. The application of organic-inorganic nanomaterials and frameworks is another challenge that is discussed in the present work. According to the findings, Nanohybrid Membranes (NHMs) can achieve 100% decolorization, but cannot eliminate salts and dyes, although the removal efficiency is notable for some salts, especially divalent salts. Hydrophilicity, antifouling properties, flux, pressure, costs, usage frequency, and mechanical, chemical, and thermal stabilities of NHMs should be considered.
{"title":"Advances in Nanohybrid Membranes for Dye Reduction: A Comprehensive Review","authors":"Mahsa Taheri","doi":"10.1002/gch2.202300052","DOIUrl":"10.1002/gch2.202300052","url":null,"abstract":"<p>Separating valuable materials such as dyes from wastewater using membranes and returning them to the production line is a desirable environmental and economical procedure. However, sometimes, besides filtration, adsorption, and separation processes, pollutant destruction also can be suitable using photocatalytic membranes. The art of producing nanohybrid materials in contrast with nanocomposites encompasses nanomaterial synthesis as a new product with different properties from raw materials for nanohybrids versus the composition of nanomaterials for nanocomposites. According to the findings of this research, confirming proper synthesis of nanohybrid is one challenge that can be overcome by different analyses, other researchers' reports, and the theoretical assessment of physical or chemical reactions. The application of organic-inorganic nanomaterials and frameworks is another challenge that is discussed in the present work. According to the findings, Nanohybrid Membranes (NHMs) can achieve 100% decolorization, but cannot eliminate salts and dyes, although the removal efficiency is notable for some salts, especially divalent salts. Hydrophilicity, antifouling properties, flux, pressure, costs, usage frequency, and mechanical, chemical, and thermal stabilities of NHMs should be considered.</p>","PeriodicalId":12646,"journal":{"name":"Global Challenges","volume":"8 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gch2.202300052","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138951076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
To discharge the colored effluents from industries there needs to be effective and affordable treatment options. Adsorption using reduced graphene oxide (rGO) as an adsorbent is a prominent one. In this study, green coffee bean extract (GCBE) is utilized as a safe reducing agent for the reduction of graphene oxide (GO) to synthesize rGO. The formation of rGO is confirmed by a new peak in the UV–vis spectra at 275 nm and a diffraction peak in the XRD patterns at 22°. The effective formation of rGO is further substantiated by a change in the GO peak's properties in the FTIR, EDX, and Raman spectra and a weight loss change in TGA. The SEM and TEM analyses demonstrate the effective production of the nano-sheets of rGO having exfoliated and segregated in a few layers. Furthermore, the obtained rGO exhibited outstanding efficacy in wastewater cleanup, effectively adsorbing MB as a prototype organic dye. The kinetics and isotherm study suggested that the adsorption leads by the chemisorption and monolayer formation on the homogeneous surface of rGO. The maximum adsorption capacity is found to be 89.3 mg g−1. This process offers a fresh opportunity for the economical and safe production of rGO for wastewater treatment.
{"title":"Green Coffee Bean Extract Assisted Facile Synthesis of Reduced Graphene Oxide and Its Dye Removal Activity","authors":"A.B.M. Nazmul Islam, Prianka Saha, Md. Emran Hossain, Md. Ahsan Habib, Kaykobad Md. Rezaul Karim, Md. Mahiuddin","doi":"10.1002/gch2.202300247","DOIUrl":"10.1002/gch2.202300247","url":null,"abstract":"<p>To discharge the colored effluents from industries there needs to be effective and affordable treatment options. Adsorption using reduced graphene oxide (rGO) as an adsorbent is a prominent one. In this study, green coffee bean extract (GCBE) is utilized as a safe reducing agent for the reduction of graphene oxide (GO) to synthesize rGO. The formation of rGO is confirmed by a new peak in the UV–vis spectra at 275 nm and a diffraction peak in the XRD patterns at 22°. The effective formation of rGO is further substantiated by a change in the GO peak's properties in the FTIR, EDX, and Raman spectra and a weight loss change in TGA. The SEM and TEM analyses demonstrate the effective production of the nano-sheets of rGO having exfoliated and segregated in a few layers. Furthermore, the obtained rGO exhibited outstanding efficacy in wastewater cleanup, effectively adsorbing MB as a prototype organic dye. The kinetics and isotherm study suggested that the adsorption leads by the chemisorption and monolayer formation on the homogeneous surface of rGO. The maximum adsorption capacity is found to be 89.3 mg g<sup>−1</sup>. This process offers a fresh opportunity for the economical and safe production of rGO for wastewater treatment.</p>","PeriodicalId":12646,"journal":{"name":"Global Challenges","volume":"8 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gch2.202300247","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138951629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aurélie Van Wylick, Hubert Rahier, Lars De Laet, Eveline Peeters
Concrete, a widely used building material, often suffers from cracks that lead to corrosion and degradation. A promising solution to enhance its durability is the use of fungi as self-healing agents, specifically by harnessing their ability to promote calcium carbonate (CaCO3) precipitation on their cell walls. However, the ideal conditions for CaCO3 precipitation by the filamentous fungal species Trichoderma reesei are still unclear. In this study, the biomineralization properties of T. reesei in liquid media are investigated. Two different calcium sources, calcium chloride (CaCl2) and calcium lactate are tested, at varying concentrations and in the presence of different nutritional sources that support growth of T. reesei. This study also explores the effects on fungal growth upon adding cement to the medium. Calcium lactate promotes greater fungal biomass production, although less crystals are formed as compared to samples with CaCl2. An increasing calcium concentration positively influences fungal growth and precipitation, but this effect is hindered upon the addition of cement. The highest amounts of biomass and calcium carbonate precipitation are achieved with potato dextrose broth as a nutritional source. By identifying the optimal conditions for CaCO3 precipitation by T. reesei, this study highlights its potential as a self-healing agent in concrete.
{"title":"Conditions for CaCO3 Biomineralization by Trichoderma Reesei with the Perspective of Developing Fungi-Mediated Self-Healing Concrete","authors":"Aurélie Van Wylick, Hubert Rahier, Lars De Laet, Eveline Peeters","doi":"10.1002/gch2.202300160","DOIUrl":"10.1002/gch2.202300160","url":null,"abstract":"<p>Concrete, a widely used building material, often suffers from cracks that lead to corrosion and degradation. A promising solution to enhance its durability is the use of fungi as self-healing agents, specifically by harnessing their ability to promote calcium carbonate (CaCO<sub>3</sub>) precipitation on their cell walls. However, the ideal conditions for CaCO<sub>3</sub> precipitation by the filamentous fungal species <i>Trichoderma reesei</i> are still unclear. In this study, the biomineralization properties of <i>T. reesei</i> in liquid media are investigated. Two different calcium sources, calcium chloride (CaCl<sub>2</sub>) and calcium lactate are tested, at varying concentrations and in the presence of different nutritional sources that support growth of <i>T. reesei</i>. This study also explores the effects on fungal growth upon adding cement to the medium. Calcium lactate promotes greater fungal biomass production, although less crystals are formed as compared to samples with CaCl<sub>2</sub>. An increasing calcium concentration positively influences fungal growth and precipitation, but this effect is hindered upon the addition of cement. The highest amounts of biomass and calcium carbonate precipitation are achieved with potato dextrose broth as a nutritional source. By identifying the optimal conditions for CaCO<sub>3</sub> precipitation by <i>T. reesei</i>, this study highlights its potential as a self-healing agent in concrete.</p>","PeriodicalId":12646,"journal":{"name":"Global Challenges","volume":"8 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gch2.202300160","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138948437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Erwan Paineau, Gilberto Teobaldi, Pablo Jiménez-Calvo
To date, imogolite nanotubes (INTs) have been primarily used for environmental applications such as dye and pollutant degradation. However, imogolite's well-defined porous structure and distinctive electro-optical properties have prompted interest in the system's potential for energy-relevant chemical reactions. The imogolite structure leads to a permanent intrawall polarization arising from the presence of bifunctional surfaces at the inner and outer tube walls. Density functional theory simulations suggest such bifunctionality to encompass also spatially separated band edges. Altogether, these elements make INTs appealing candidates for facilitating chemical conversion reactions. Despite their potential, the exploitation of imogolite's features for photocatalysis is at its infancy, thence relatively unexplored. This perspective overviews the basic physical-chemical and optoelectronical properties of imogolite nanotubes, emphasizing their role as wide bandgap insulator. Imogolite nanotubes have multifaceted properties that could lead to beneficial outcomes in energy-related applications. This work illustrates two case studies demonstrating a step-forward on photocatalytic hydrogen production achieved through atomic doping or metal co-catalyst. INTs exhibit potential in energy conversion and storage, due to their ability to accommodate functions such as enhancing charge separation and influencing the chemical potentials of interacting species. Yet, tapping into potential for energy-relevant application needs further experimental research, computational, and theoretical analysis.
迄今为止,伊莫高石纳米管(INTs)主要用于染料和污染物降解等环境应用。然而,伊莫高石定义明确的多孔结构和独特的电光特性激发了人们对该系统进行能量相关化学反应潜力的兴趣。由于在管内壁和管外壁存在双官能团表面,因此埃莫沸石结构会导致永久性的管内极化。密度泛函理论模拟表明,这种双功能性还包括空间上分离的带边。总之,这些因素使 INT 成为促进化学转换反应的理想候选材料。尽管具有潜力,但利用imogolite的特性进行光催化的研究还处于起步阶段,因此相对来说还没有被探索。本文概述了伊莫高石纳米管的基本物理化学和光电特性,强调了其作为宽带隙绝缘体的作用。伊莫高石纳米管具有多方面的特性,可在能源相关应用中产生有益的结果。这项工作通过两个案例研究,展示了通过原子掺杂或金属共催化剂实现光催化制氢的进步。INTs 具有增强电荷分离和影响相互作用物种化学势等功能,因此在能量转换和储存方面具有潜力。然而,要挖掘 INT 在能源相关应用方面的潜力,还需要进一步的实验研究、计算和理论分析。
{"title":"Imogolite Nanotubes and Their Permanently Polarized Bifunctional Surfaces for Photocatalytic Hydrogen Production","authors":"Erwan Paineau, Gilberto Teobaldi, Pablo Jiménez-Calvo","doi":"10.1002/gch2.202300255","DOIUrl":"10.1002/gch2.202300255","url":null,"abstract":"<p>To date, imogolite nanotubes (INTs) have been primarily used for environmental applications such as dye and pollutant degradation. However, imogolite's well-defined porous structure and distinctive electro-optical properties have prompted interest in the system's potential for energy-relevant chemical reactions. The imogolite structure leads to a permanent intrawall polarization arising from the presence of bifunctional surfaces at the inner and outer tube walls. Density functional theory simulations suggest such bifunctionality to encompass also spatially separated band edges. Altogether, these elements make INTs appealing candidates for facilitating chemical conversion reactions. Despite their potential, the exploitation of imogolite's features for photocatalysis is at its infancy, thence relatively unexplored. This perspective overviews the basic physical-chemical and optoelectronical properties of imogolite nanotubes, emphasizing their role as wide bandgap insulator. Imogolite nanotubes have multifaceted properties that could lead to beneficial outcomes in energy-related applications. This work illustrates two case studies demonstrating a step-forward on photocatalytic hydrogen production achieved through atomic doping or metal co-catalyst. INTs exhibit potential in energy conversion and storage, due to their ability to accommodate functions such as enhancing charge separation and influencing the chemical potentials of interacting species. Yet, tapping into potential for energy-relevant application needs further experimental research, computational, and theoretical analysis.</p>","PeriodicalId":12646,"journal":{"name":"Global Challenges","volume":"8 6","pages":""},"PeriodicalIF":4.9,"publicationDate":"2023-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/gch2.202300255","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139036379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}