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From rubbles to digital material bank. A digital methodology for construction and demolition waste management in post-disaster areas 从废墟到数字资料库。灾后地区建筑和拆除废物管理的数字方法
Pub Date : 2023-06-30 DOI: 10.35208/ert.1290843
Pio Lorenzo Cocco, R. Ruggiero
In 2020, European countries generated 807 mln tons of construction and demolition waste (CDW), accounting for 37.5% of total waste production. The UE Waste Framework Directive of 2008 established as a priority goal to increase the percentage of reuse, recycling and recovery of nonhazardous construction waste to a minimum of 70% by 2020. Pending the report that will define compliance with this goal, the average percentage currently stands at around 50%, of which only 3% involves upcycling operations. This doctoral research defines an operational methodology aimed at implementing digital processes for circularity in the AEC sector, with a focus on post-earthquake emergency Italian contexts. The treatment of CDW in earthquake-affected areas for the purpose of recovery/reuse, in a perspective of circularity, represents an underexplored field and limited, as in the rest of UE, to downcycling operations. By defining planning strategies and digital tools and procedures, the research aims to facilitate the reuse of building elements from post-earthquake demolition and reconstruction operations. The final output of the research consists of a cloud database, a Digital Material Bank (DMB), of informed building elements from post-earthquake selective demolition operations that can be reused in the construction market as a secondary raw material. The CDW management of the 2016 Central Italy earthquake is identified as the scope of application, with a focus on the situation in the Marche region. Finally, the main limitations and possible future scenarios of the research are reported.
2020年,欧洲国家产生了8.07亿吨建筑和拆除垃圾(CDW),占废物总产量的37.5%。2008年的《废物利用框架指令》确立了一个优先目标,即到2020年将无害建筑废物的再利用、再循环和回收比例提高到至少70%。在报告确定是否符合这一目标之前,目前的平均比例约为50%,其中只有3%涉及升级回收业务。这项博士研究定义了一种操作方法,旨在实施AEC部门的循环数字流程,重点关注意大利地震后的紧急情况。从循环的角度来看,地震灾区以回收/再利用为目的的CDW处理是一个未开发的领域,并且与欧洲其他地区一样,仅限于降级循环操作。通过定义规划策略和数字工具和程序,研究旨在促进震后拆除和重建作业中建筑元素的再利用。研究的最终成果包括一个云数据库,一个数字材料银行(DMB),其中包含了震后选择性拆除操作中的建筑元素,这些元素可以作为次要原材料在建筑市场上重复使用。2016年意大利中部地震的CDW管理被确定为应用范围,重点关注马尔凯地区的情况。最后,报告了本研究的主要局限性和可能的未来前景。
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引用次数: 0
Occurrence of bromide and bromate in chlorinated indoor swimming pools, and associated health risks 氯化室内游泳池中溴化物和溴酸盐的出现及其相关的健康风险
Pub Date : 2023-06-30 DOI: 10.35208/ert.1267181
Yetkin Dumanoglu, Mesut Genisoglu, S. C. Sofuoglu
Swimming is a physical activity that is accessible to people of all ages in all seasons. However, continuous organic and inorganic precursor load and disinfectant dosing make pool water chemistry much more complex than other disinfected waters. Carcinogenic bromate compound is one of the hundreds of disinfection by-products in pool water. The occurrence of bromate in pool waters depends on the precursor content of filling water, the disinfection process, operating parameters, and the purity of disinfectants. While the average filling water bromide concentrations of University Campus indoor swimming pool in Gülbahçe –Urla (SP1) and Buca public indoor swimming pool (SP2) were determined to be 182 μg/L and 11.0 μg/L, respectively, the average bromate concentrations of SP1 and SP2 were 59.4 μg/L and 68.3 μg/L. Estimated chronic-toxic health risks of accidental ingestion of pool water during swimming (between 10-3 and 10-1) were lower than the threshold level (‘1’). Although the carcinogenic risks in central tendency scenario (
游泳是一项任何季节、任何年龄的人都可以参加的体育活动。然而,连续的有机和无机前体负荷以及消毒剂的添加使泳池水的化学性质比其他消毒水复杂得多。致癌物溴酸盐化合物是泳池水中数百种消毒副产物之一。泳池水中溴酸盐的出现取决于灌装水的前体含量、消毒工艺、操作参数和消毒剂的纯度。g lbahale -Urla公共室内游泳池(SP1)和Buca公共室内游泳池(SP2)的溴酸盐平均浓度分别为182和11.0 μg/L, SP1和SP2的溴酸盐平均浓度分别为59.4和68.3 μg/L。游泳时意外摄入泳池水的估计慢性毒性健康风险(介于10-3和10-1之间)低于阈值水平(' 1 ')。虽然在集中趋势情景下的致癌风险(
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引用次数: 0
Improved portable generator performance with bio-ethanol fuel and its impact on bio-sustainability 生物乙醇燃料改进便携式发电机性能及其对生物可持续性的影响
Pub Date : 2023-06-30 DOI: 10.35208/ert.1286121
K. RAMYA SRİ, P. Sambandam, Balaji Boopathi̇, Deepak JAMES RAJ, E. Kader
Clean air, renewable energy, climate change, safe environments, and the opportunity to live in a healthy community are just a few of the many issues that fall under the umbrella of environmental sustainability. The creation of bioenergy and biomaterials has the potential to retain the energy-environment relationship while simultaneously fostering cleaner, lower-carbon settings. Scientists are investigating renewable energy sources like ethanol to enhance sustainability and the planet›s health. Fuel ethanol is a feasible alternative to gasoline since it has a lower carbon footprint and a higher energy density. This research summarizes ethanol›s potential as a bio-sustainable fuel option for portable generators in India. Bio-ethanol testing was done on a portable generator with an ethanol-gasoline blend, and the findings are presented in this study. Compared to using standard gasoline, the results show 9% to 25% increased thermal efficiency and 6% to 28% decreased fuel usage. The results showed a decrease of 6%–23% in carbon monoxide and 3%–11% in unburned hydrocarbon emissions.
清洁的空气、可再生能源、气候变化、安全的环境,以及生活在健康社区的机会,这些只是环境可持续性所涉及的众多问题中的一小部分。生物能源和生物材料的创造有可能保持能源与环境的关系,同时促进更清洁、更低碳的环境。科学家们正在研究像乙醇这样的可再生能源,以提高可持续性和地球的健康。燃料乙醇是一种可行的汽油替代品,因为它具有更低的碳足迹和更高的能量密度。这项研究总结了乙醇作为印度便携式发电机的生物可持续燃料选择的潜力。生物乙醇测试是在使用乙醇-汽油混合物的便携式发电机上进行的,研究结果发表在本研究中。与使用标准汽油相比,结果显示热效率提高了9%至25%,燃料使用量减少了6%至28%。结果表明,一氧化碳排放量减少6%-23%,未燃烧碳氢化合物排放量减少3%-11%。
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引用次数: 0
Green Design or Multiple Re-useable Product Packaging as Regards Solid Waste in Selected Areas in Awka Metropolis, Nigeria 绿色设计或多种可重复使用的产品包装,关于固体废物在选定地区在Awka大都市,尼日利亚
Pub Date : 2023-06-19 DOI: 10.35208/ert.1285944
Ayorinde Samuel Oluyemi, Azuka OGBOGU-NZOİWU
This study enumerates how product packaging amount to solid wastes among other Awka MSW constituents with the view to unfold green design or multiple re-useable product packaging as achievable means of minimizing solid waste in Awka Metropolis, Nigeria. Perhaps, there are locations with well managed or minimized packaging waste; accordingly, this study includes the review of some literatures on Awka MSW so as to note the extent of studies that have been published and made available in trendy media. Thus, the study is descriptive, literature-based and naturalistic observation -based in terms of estimated counting during the visitation to the selected areas. The findings reveal that studies on solid waste characterization, health, perception, behaviour of the populace in relation to solid waste and sustainability are ubiquitous. Still, the aspect of product packaging waste in the Awka metropolis has not been extensively studied; thus, present study fills this gap by aiming at unfolding green design or multiple re-useable product packaging as achievable means of minimizing solid waste in Awka Metropolis, Nigeria. However, this study in concord with prior studies shows that the product package among other solid waste occurs in a similar way in residential locations except other locations such as markets, schools, hospitals, municipal and industrial areas which have more of the litters of non-green packaging materials. Example is the plastic package with the largest quantity of generated solid waste within selected location in relation to other solid waste. Thus, the policy approach under which producers are given significant responsibility for waste prevention/diversion of post-consumer products should be ongoing through Private - Public Sector Partnerships (PPP) harmonized with EPR. This can be done by enhancing the concern of everybody (manufactures, consumers, organizations and other entrepreneurs including waste pickers/scavengers). Situation where by producers persuade the consumers through gainful or attractive means to return used product packages can be encouraged. Thus, the present study unfolds green design or multiple reuses of product packages as a means of attaining zero waste in Awka metropolis.
本研究列举了产品包装如何在其他Awka MSW成分之间产生固体废物,以展现绿色设计或多种可重复使用的产品包装,作为最大限度地减少尼日利亚Awka大都市固体废物的可实现手段。也许,有些地方有良好的管理或最小化包装废物;因此,本研究包括对一些关于Awka MSW的文献的回顾,以注意到已经发表的研究的程度,并在时尚媒体上提供。因此,该研究是描述性的,以文献为基础,以自然观察为基础,在访问选定区域期间进行估计计数。调查结果表明,关于固体废物特性、健康、观念、民众对固体废物的行为和可持续性的研究无处不在。然而,在Awka大都市的产品包装废弃物方面还没有广泛的研究;因此,目前的研究填补了这一空白,旨在展开绿色设计或多种可重复使用的产品包装作为可实现的手段,最大限度地减少固体废物在Awka大都市,尼日利亚。然而,本研究与先前的研究一致表明,除了市场、学校、医院、市政和工业区等其他地点有更多的非绿色包装材料垃圾外,其他固体废物中的产品包装以类似的方式发生在居民区。例如,与其他固体废物相比,在选定地点产生固体废物最多的塑料包装。因此,应通过与环保责任相协调的私营-公共部门伙伴关系(PPP),使生产者承担预防废物/转移消费后产品的重大责任。这可以通过提高每个人(制造商、消费者、组织和其他企业家,包括拾荒者/拾荒者)的关注来实现。鼓励生产者通过有收益或有吸引力的手段说服消费者退回使用过的产品包装。因此,本研究揭示了绿色设计或产品包装的多次重复使用作为实现Awka大都市零浪费的手段。
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引用次数: 0
Acoustic Safety Assessment of Palm Oil Mill Workers 棕榈油加工厂工人的声学安全评价
Pub Date : 2023-06-19 DOI: 10.35208/ert.1230728
A. Azodo, Smith Okwuchi Onyekwere
Mechanization of work processes in agro-based industries through the employment of improved tools and/or equipment powered by either fuel or diesel engines reduce tedium and drudgery on the workers as well as improve the overall productivity and production. However, it also leads to health threat to the workers through environmental noise pollution. This study assessed the occupational noise exposure of workers in three different palm oil mills. The noise level was measured using a noise metering device (model 1352) and noise descriptors (L10, L50, L90, Lav, LAeq, Tspl, DOSE (%) and TWA). The occupational health effects of noise exposure were deduced using a semi-structured questionnaire. The noise exposure was assessed during the palm nut digestion, and nut and pulp separation job operations as the noise emanates from the diesel powered engine, palm nut digester and nut and pulp separator. The average noise levels obtained from the palm oil mills during palm nut digestion, 99.36 (SD = 4.16) dBA and pulp separation, 98.18 (SD = 3.07) dBA, exceeded the recommended 85 dBA for an 8-hour exposure period permissible noise exposure limit standard by the NIOSH. The self-reported effect of the noise exposure level on the workers was interference with communication - 100%, tinnitus - 70%, ringing sensation - 76.75%, and noise stress - 73.30% of the workers. This research will inform the operators of the need for appropriate personal protective equipment usage and equip Government regulatory agencies to make appropriate regulations in order to protect oil mill workers.
通过使用由燃料或柴油发动机提供动力的改进工具和/或设备,农业基础工业的工作过程机械化减少了工人的单调乏味和苦差事,并提高了整体生产力和产量。但是,环境噪声污染也对工人的健康造成威胁。本研究评估了三家不同棕榈油厂工人的职业噪音暴露。使用噪声测定仪(型号1352)和噪声描述符(L10、L50、L90、Lav、LAeq、Tspl、DOSE(%)和TWA)测量噪声级。采用半结构式问卷,推断噪声暴露对职业健康的影响。分析了棕榈仁消化、果仁与纸浆分离作业过程中的噪声暴露,主要噪声源为柴油发动机、棕榈仁消化机和果仁与纸浆分离机。棕榈油加工厂在棕榈坚果消化过程中获得的平均噪音水平为99.36 (SD = 4.16) dBA,果肉分离过程中获得的平均噪音水平为98.18 (SD = 3.07) dBA,超过了NIOSH建议的8小时暴露期允许噪音暴露限值标准85 dBA。自述噪声暴露水平对工人的影响为干扰交流(100%)、耳鸣(70%)、鸣感(76.75%)和噪声应激(73.30%)。这项研究将告知操作人员需要适当的个人防护设备的使用,并使政府管理机构能够制定适当的法规,以保护油厂工人。
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引用次数: 1
Interpretation of Odor Complaint Records with BTEX Pollutants and Meteorological Factors: Çorlu case study 用BTEX污染物和气象因子解释气味投诉记录:Çorlu个案研究
Pub Date : 2023-05-31 DOI: 10.35208/ert.1235618
C. B. Özkal, L. Tecer
Air pollution in urban areas increases as a result of emitted air from different sources within the mixing layer of troposphere. Air pollution and/or odor pollution may arise from; point (industrial), line (urban:traffic, polluted water bodies and flows) and clustered emission sources like (waste, wastewater, and urban due to improper waste management). Odor pollution is amongst the primary reasons behind environmental nuisance and occurrence of citizen complaints. Frequent exposure to odorous compounds and/or odor nuisance are increasingly associated with air pollution problems. Besides, there is no universally accepted environmental odor management method reported so far. Level of air pollutants emission (based on fuel quality, industrial development, population, population density, etc.), distance of emission sources to residential areas, topography and geographical conditions and meteorological conditions are amongst the factors that have influence on imposed level of air pollution and odor pollution in cities. As the number of citizen-generated data (CGD) projects in Europe is very likely to grow, this study is built on the citizen odor complaint data (based on frequency, intensity, duration, odor tone and location (defined as FIDOL factors) collected in Çorlu/Tekirdağ through the GIS integrated public participated odor complaint collection platform, namely the Çorlu KODER mobile application. The annual odor complaint data was briefly introduced and given an evaluation with the mobile app users demographic information. The obtained data between August 28-November 2 of 2021, was subjected to interpretative evaluation and statistical analysis with BTEX (benzene, toluene, ethylene benzene and xylen) concentrations representative of odorous Volatile organic carbon(VOC), inorganic air pollution concentrations and meteorological factors. In light of the obtained results, temperature, wind speed, relative humidity and toluene concentration were found to play a significant role on the number of citizen odor complaints. The average Toluene/benzene ratios obtained during the study show that; non-traffic sources contribute significantly to VOC emissions. Based on statistical analysis findings concerning BTEX measurements and number of odor complaints; transportation mechanism from neighbouring OIZ settlements become a prominent justification and support the hypothesis that residential areas of Corlu are under the effect of industrial air pollution and odor pollution constituents. Also, windspeed have a determining role on increase of odor complaints issues, specifically within certain intervals (below 2.4 m/s, the average number of odor complaints tend to increase, while above this level odor complaints are diminished)
城市地区的空气污染由于对流层混合层内不同来源的空气排放而增加。空气污染及/或气味污染可能来自以下方面:点(工业)、线(城市:交通、受污染的水体和水流)和集群式排放源(废物、废水和由于废物管理不当而导致的城市)。气味污染是造成环境滋扰和市民投诉发生的主要原因之一。经常接触有气味的化合物和/或气味滋扰日益与空气污染问题联系在一起。此外,目前还没有普遍接受的环境气味管理方法。空气污染物排放水平(基于燃料质量、工业发展、人口、人口密度等)、排放源到居民区的距离、地形和地理条件以及气象条件是影响城市空气污染和气味污染水平的因素之一。由于欧洲公民生成数据(CGD)项目的数量很可能会增长,因此本研究是建立在通过GIS综合公众参与气味投诉收集平台(即Çorlu KODER移动应用程序)在Çorlu/ tekirdaul收集的公民气味投诉数据(基于频率、强度、持续时间、气味色调和位置(定义为FIDOL因素)之上的。简要介绍了年度气味投诉数据,并结合移动应用用户人口统计信息进行了评价。对获取的2021年8月28日至11月2日的数据,采用代表恶臭性挥发性有机碳(VOC)的BTEX(苯、甲苯、乙苯和二甲苯)浓度、无机空气污染浓度和气象因素进行解释评价和统计分析。结果表明,温度、风速、相对湿度和甲苯浓度对市民气味投诉数量有显著影响。研究中得到的平均甲苯/苯比表明:非交通来源对挥发性有机化合物的排放量贡献很大。基于BTEX测量和气味投诉数量的统计分析结果;邻近OIZ住区的运输机制成为Corlu居民区受到工业空气污染和气味污染成分影响的重要理由和支持。此外,风速对气味投诉问题的增加起决定性作用,特别是在一定的时间间隔内(低于2.4 m/s,平均气味投诉数量趋于增加,而高于此水平,气味投诉减少)。
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引用次数: 0
Composition and Characteristics of Excavated Materials from a Legacy Waste Dumpsite: Potential of Landfill Biomining 一个遗留垃圾场挖掘材料的组成和特性:填埋场生物采矿的潜力
Pub Date : 2023-05-18 DOI: 10.35208/ert.1245574
A. Ghosh, S. Kartha
Landfill biomining (LFBM) has been proposed as a viable method for the reclamation of legacy waste dumpsites as well as the subsequent recovery of valuable resources and land value spaces. Despite these advantages, the potential of LFBM faces a significant challenge due to the composition, characteristics and end-use of the excavated materials. This paper assesses the composition of the excavated waste obtained during the LFBM operation of the four legacy waste heaps at the Boragaon dumpsite in North-East India and determines the physicochemical characteristics crucial for the material and energy recovery from the key reclaimed fractions. The compositional analysis revealed that the proportion of combustible and non-combustible fractions decreases from the youngest heap HP4 to the oldest heap HP1 due to variations in the consumption habits of the local community and the inadequate recycling of recyclable materials. However, the proportion of fine fraction (FF) shows an increasing trend from HP4 to HP1, suggesting enhanced biodegradation of easily degradable waste over the years. The proximate and energy content analysis suggest that refuse-derived fuel (RDF) preparation is the most suitable valorization option for the combustible fractions since surface defilements are too high for good quality material recovery. The elevated amount of organic matter and leachable heavy metals indicate that unrestricted reuse of FF as earth-fill material can cause long-term settlements and groundwater contamination, respectively. Even though every dumpsite is different in characteristics, the findings of this case study can assist in developing new strategies for recycling excavated waste.
垃圾填埋场生物采矿(LFBM)已被提出作为一种可行的方法来回收遗留垃圾场,以及随后回收有价值的资源和土地价值空间。尽管有这些优势,但由于挖掘材料的组成、特性和最终用途,LFBM的潜力面临着重大挑战。本文评估了在印度东北部Boragaon垃圾场的四个遗留废物堆的LFBM操作中获得的挖掘废物的组成,并确定了从关键回收组分中回收材料和能量的关键物理化学特性。成分分析表明,由于当地社区消费习惯的变化和可回收材料的回收不足,可燃和不可燃组分的比例从最年轻堆HP4到最古老堆HP1递减。然而,从HP4到HP1,细粒分数(FF)的比例呈增加趋势,表明易降解废物的生物降解能力随着时间的推移而增强。近似分析和能量含量分析表明,由于表面污染太高,无法实现高质量的材料回收,垃圾衍生燃料(RDF)制备是可燃馏分最合适的增值选择。有机质和可浸出重金属含量的升高表明,无限制地回用FF填土会分别造成长期沉降和地下水污染。尽管每个垃圾场的特点不同,但本案例研究的结果可以帮助制定回收挖掘废物的新策略。
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引用次数: 0
RECYCLING DOMESTIC SEWAGE SLUDGE TO AGRICULTURAL AND FARMING AREAS IN LINE WITH SUSTAINABLE DEVELOPMENT GOALS (SDG) 根据可持续发展目标,将生活污水污泥回收到农业和养殖区
Pub Date : 2023-05-18 DOI: 10.35208/ert.1225027
Damla ÇAPAN MUSTAFAOĞLU, Ş. Korkmaz, Zeynep Ceylan
Corresponding to the rapid increase in population, the increase in the number of domestic wastewater treatment plants, as well as the increase in domestic sludge levels above acceptable levels, pave the way to utilize sewage sludge in a variety of different applications and usage areas. Using sewage sludge in agriculture, landscape plant cultivation, and other agricultural areas has a number of advantages, including the ability to make rational use of waste without damaging the environment as well as delivering fertilizer benefits to the plant due to the high organic matter content of the wastewater sludge. Aside from these advantages, the most serious drawbacks of waste sewage are pathogenic bacteria, heavy metal contamination, and the presence of potentially hazardous compounds. The use of existing waste in the soil in appropriate proportions and in methods that are compatible with ecological life, on the other hand, will contribute to the fertilization of agricultural areas, providing an alternative to the fertilizer industry. The Sustainable Development Goals (SDGs), also known as the Global Goals, are a global call to action to end poverty, safeguard the environment, and guarantee that everyone lives in peace and prosperity. It is expected that this research will help to promote awareness about the reuse of waste within the context of a sustainable environment, as well as shed light on the application of sewage sludge to agricultural fields in accordance with the Sustainable Development Goals. Furthermore, the support for sewage sludge recycling in agricultural regions for long-term development goals is shown.
与人口的快速增长相对应,生活污水处理厂数量的增加,以及生活污泥水平高于可接受水平的增加,为污水污泥在各种不同应用和使用领域的利用铺平了道路。在农业、景观植物栽培和其他农业领域使用污水污泥具有许多优点,包括能够在不破坏环境的情况下合理利用废物,以及由于废水污泥的高有机质含量而为植物提供肥料效益。除了这些优点之外,废水最严重的缺点是致病菌、重金属污染和潜在有害化合物的存在。另一方面,以适当的比例和与生态生命相容的方法利用土壤中的现有废物,将有助于农业地区的施肥,为化肥工业提供一种替代办法。可持续发展目标(sdg),也被称为全球目标,是一项全球行动呼吁,旨在消除贫困,保护环境,并确保每个人都生活在和平与繁荣中。预计这项研究将有助于提高在可持续环境背景下对废物再利用的认识,并根据可持续发展目标阐明污水污泥在农业领域的应用。此外,还显示了对农业地区污水污泥循环利用的长期发展目标的支持。
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引用次数: 0
Utilization Potential of Poultry Litter Ash as Phosphorus-Based Fertilizer 禽死灰作为磷基肥料的利用潜力
Pub Date : 2023-05-09 DOI: 10.35208/ert.1243895
İ. Acar
A large quantity of poultry litter is globally generated as a result of expanding poultry industry. From several alternative technologies, one of the most feasible management for this waste is combustion, which exhausts poultry litter ash (PLA) as the main by-product. In this study, a PLA sample was examined for its utilization potential as a raw material for phosphorus-based fertilizer. According to the experimental results, Ca, P and K were determined as the major elements in the PLA sample with 29.54, 6.13 and 4.96%, respectively. Although the sample contains 2472 ppm Zn and 922 ppm Cu, their solubility determined by the leaching test is below the toxicity limit for hazardous waste. In terms of the major elements, about 290 mg/l Ca was detected in the leachate, resulting in a pH value higher than 13, whereas P concentration was found only 0.0092 mg/l. These two crucial results constitute the major difficulties for direct use of the PLA as a fertilizer. On the other hand, a usable P-rich product with low heavy metal contents and neutral pH can be obtained through acidification, heavy metal removal and neutralization processes. However, in this case, the feasibility of processes to be used should be carefully considered in economic point of view. In conclusion, direct application of the PLA sample examined as P-based fertilizer is not possible without any pre-treatments mainly due to its very high alkalinity and the low water solubility of P.
由于家禽业的扩大,全球产生了大量的家禽垃圾。从几种替代技术中,对这种废物的最可行的管理方法之一是燃烧,其排出的主要副产品是家禽垃圾灰(PLA)。本研究考察了聚乳酸样品作为磷基肥料原料的利用潜力。实验结果表明,PLA样品中Ca、P和K的含量分别为29.54%、6.13%和4.96%。虽然样品中锌含量为2472 ppm,铜含量为922 ppm,但浸出试验确定的溶解度低于危险废物的毒性限值。在主要元素方面,渗滤液中Ca含量约为290 mg/l, pH值大于13,P含量仅为0.0092 mg/l。这两个关键的结果构成了直接使用PLA作为肥料的主要困难。另一方面,通过酸化、重金属去除和中和等工艺,可获得重金属含量低、pH值中性的富p产品。但是,在这种情况下,应从经济角度仔细考虑所采用的方法的可行性。综上所述,未经任何预处理,不可能直接将PLA样品作为P基肥料施用,这主要是由于PLA样品的碱度非常高,而P的水溶性很低。
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引用次数: 0
Investigation of Conversion of Sunflower Oil Production Wastes to High Value Compounds by Supercritical CO2 超临界CO2法将葵花籽油废渣转化为高值化合物的研究
Pub Date : 2023-05-02 DOI: 10.35208/ert.1245691
Müberra Nur Kiliçarslan, M. E. Argun
The evaluation of wastes from edible oil production industry has increasing importance because of resources deficiency and growing population day by day. It was aimed to investigate the recovery potential of oil and valuable components such as total phenolic contents (TPC), total flavonoid content (TFC) and antioxidant activities with conventional and green extraction methods from edible sunflower oil production wastes. Firstly, Soxhlet extraction was applied on the waste samples from filtration of the oil and then supercritical CO2 (SC- CO2) extraction was performed to compare extraction yield. The statistical evaluation of the SC- CO2 extraction experiments was conducted with the Minitab Software program. It was concluded that 37% extraction yield was obtained with the mixture of perlite and waste sample, while the highest recovery was observed as 27% for the perlite-free sample. The interaction of independent variables (temperature and pressure) on the recovery yields were determined as significant (p=0.002). Pressure was detected more effective on the valuable substance contents of the extracts than temperature. The most efficient conditions were 50 oC and 22.1 MPa for oil recovery, while 60 oC and 20 MPa for valuable substance recovery.
随着资源的匮乏和人口的日益增长,食用油工业废弃物的评价日益重要。以食用葵花籽油生产废弃物为研究对象,考察常规提取法和绿色提取法对葵花籽油中油脂、总酚含量、总黄酮含量及抗氧化活性的回收潜力。首先对油过滤后的废样进行索氏萃取,然后进行超临界CO2 (SC- CO2)萃取,比较萃取率。利用Minitab软件程序对SC- CO2萃取实验进行统计评价。结果表明,废样品与珍珠岩混合提取得率为37%,不含珍珠岩的样品回收率最高,为27%。自变量(温度和压力)对回收率的交互作用被确定为显著(p=0.002)。压力对提取物中有价物质含量的影响比温度更大。在50℃、22.1 MPa条件下采收率最高,在60℃、20 MPa条件下采收率最高。
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引用次数: 0
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Environmental Research and Technology
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