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Preparation and photoluminescence study of rare-earth-free red emitting La3Ga5SiO14:Mn4+phosphors 无稀土红色发光 La3Ga5SiO14:Mn4+ 磷酸盐的制备与光致发光研究
IF 1.3 4区 材料科学 Q3 Materials Science Pub Date : 2024-02-24 DOI: 10.1142/s1793604724500097
Youxin Lou, Yuguo Yang, Zi Yang, Chaofeng Zhu, Haifeng Zhou, Ping Zhao, Xuping Wang

Given the growing interest in eco-friendly lighting solutions, the use of high-quality phosphors has become integral to the advancement of all-solid white light-emitting diodes (WLEDs). One novel phosphor, La3Ga5SiO14:Mn4+ (LGS), has been successfully synthesized via a high-temperature solid-state reaction. The crystal structure of LGS is classified as belonging to the trigonal phase, with a space group P321. The excitation spectrum exhibits a wide peak within the wavelength range of 280–440 nm. It emits a highly intense red light, with a peak emission occurring at 715 nm within the spectral range of 670–740 nm is attributed to the transition of Mn4+ from 4A2g to 4T2g. LGS:Mn4+ demonstrates a favorable quantum efficiency of 16% when doped with a concentration of 0.25 mol% Mn. The decay curve of LGS:Mn4+ exhibits a pattern of decreasing lifetime as the dopant concentration increases. Additionally, the LGS:Mn4+ products demonstrate a CIE chromaticity of (0.688, 0.2644), which is located within the deep red light region. All the aforementioned findings support the potential application of LGS:Mn4+ specimens in WLEDs, thereby contributing to the progress of environmentally friendly and energy-efficient lighting.

鉴于人们对环保照明解决方案的兴趣与日俱增,使用高质量的荧光粉已成为全固态白光发光二极管(WLED)发展不可或缺的一部分。一种新型荧光粉 La3Ga5SiO14:Mn4+ (LGS) 已通过高温固态反应成功合成。LGS 的晶体结构属于三方相,空间群为 P321。其激发光谱在 280-440 nm 波长范围内呈现出一个较宽的峰值。它发出高强度的红光,在 670-740 纳米波长范围内的 715 纳米波长处有一个发射峰,这是由于 Mn4+ 从 4A2g 转变为 4T2g 所造成的。当掺入浓度为 0.25 摩尔% 的 Mn 时,LGS:Mn4+ 的量子效率为 16%。随着掺杂浓度的增加,LGS:Mn4+ 的衰变曲线呈现出寿命递减的模式。此外,LGS:Mn4+ 产物的 CIE 色度为 (0.688, 0.2644),位于深红光区域。上述所有研究结果都支持 LGS:Mn4+ 试样在 WLED 中的潜在应用,从而为环保节能照明的发展做出贡献。
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IF 1.3 4区 材料科学 Q3 Materials Science Pub Date : 2024-01-26 DOI: 10.1142/s1793604724510135
Xianghui Zhang, Yige Zhao, Junge Li, Qianqian Wang, Yanyan Yin, Xin Zhao
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{"title":"High performance electrode based on platinum nanoparticle-silicon nanowire nanohybrid and aptamer for detection of Escherichia coli","authors":"Zhiqian Song, Lei Jiang, Chao Gao, Qiwei Qiao, Chenggang Geng, Xiaodong Wang","doi":"10.1142/s1793604724500073","DOIUrl":"https://doi.org/10.1142/s1793604724500073","url":null,"abstract":"","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139625098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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{"title":"Modulation mechanism of electronic and optical properties of Cs2SnX6(X = Cl, Br and I) under hydrostatic or uniaxial pressure","authors":"Cheng Peng, Jianwei Wei, Junhua Wu, Zengwei Ma, Chenkai Qiao, Hui Zeng","doi":"10.1142/s1793604724510123","DOIUrl":"https://doi.org/10.1142/s1793604724510123","url":null,"abstract":"","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139449914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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{"title":"Microstructures and electromagnetic interference shielding properties of 2D defective Mo1.33C (MXene)","authors":"Jiaxin Yang, Zhaohui Chen, Xiaodan Chi, Tao Yu, Wenyu Deng, Yanjun Lu, Lijun Qi, Shuang Yuan, Qiang Wang, Weibin Cui","doi":"10.1142/s179360472440006x","DOIUrl":"https://doi.org/10.1142/s179360472440006x","url":null,"abstract":"","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138996331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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{"title":"Surface modification of TiNb alloys by hydrothermal-precalcification treatment and its excellent in vitro osteogenic bioactivity","authors":"Hanfeng Zhu, Lin Zheng, X. Liao, Gang Li","doi":"10.1142/s1793604724510093","DOIUrl":"https://doi.org/10.1142/s1793604724510093","url":null,"abstract":"","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138970691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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{"title":"Fabrication and multiphysics numerical investigations of carbon fiber structural batteries","authors":"Jianhai Liang, Chunzhi Du","doi":"10.1142/s179360472451007x","DOIUrl":"https://doi.org/10.1142/s179360472451007x","url":null,"abstract":"","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138998824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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{"title":"Degradation of sodium butylxanthate in flotation wastewater by natural pyrite via visible light-assisted advanced oxidation processes: a comprehensive study","authors":"Jiawei Fan, Jinpeng Wang, Lisha Jiang, Yubiao Li, Xiaoyong Wu","doi":"10.1142/s179360472451010x","DOIUrl":"https://doi.org/10.1142/s179360472451010x","url":null,"abstract":"","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139001117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Functional Materials Letters
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