{"title":"Research on the Application of WO3 Gas Sensor Based on Noble Metals Modification in Cable Fire Detection","authors":"Dongting Yao, Qiming Qin, Zhenkun Lu, Xiang Pan, Youbin Xia, Yin Cheng","doi":"10.1142/s1793604724500139","DOIUrl":"https://doi.org/10.1142/s1793604724500139","url":null,"abstract":"","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140683084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-04-11DOI: 10.1142/s1793604724510299
Thi-My-Hanh Nguyen, P. Tran, Quoc-Tuan Le, Quoc-Dat Le, Van-Duong Luong, Cao-Ngoc-Hong Nguyen, Thanh-Tung Duong
{"title":"Spray Pyrolysis Deposited NiO Film as a Hole-Injection Layer for CsPbBr3 Nanocrystal–Based Light-Emitting Diodes","authors":"Thi-My-Hanh Nguyen, P. Tran, Quoc-Tuan Le, Quoc-Dat Le, Van-Duong Luong, Cao-Ngoc-Hong Nguyen, Thanh-Tung Duong","doi":"10.1142/s1793604724510299","DOIUrl":"https://doi.org/10.1142/s1793604724510299","url":null,"abstract":"","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140712883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The transformation of discarded eggshells (ES) into high value-added materials through technological means and the realization of turning waste ES “stone into gold” are of great significance to the environment and sustainable economic development. CuS is a typical semiconductor with broad and powerful light absorption properties, which is widely used in photocatalytic wastewater remediation. However, the high recombination rate of CuS photogenerated electron-hole pairs limits its application. In this study, a novel waste eggshell-derived ES/CuS heterojunction photocatalyst is innovatively constructed using an adsorption-precipitation method to realize the efficient degradation of ciprofloxacin (CIP) under visible light. The results showed that the ES/CuS heterojunction photocatalyst, under visible light irradiation, could degrade CIP (20 mg/L) with a degradation efficiency of 93.7% at 5 h (including 1 h of dark reaction), which compared to the degradation efficiency of CuS (52.3%) its CIP removal was significantly increased by a factor of 1.78, and showed good stability and reusability. The superior CIP degradation performance is mainly attributed to the introduction of ES to improve the separation efficiency of CuS photogenerated carriers and can participate in redox reactions through the formation of e and h on the surface of heterojunctions under visible light irradiation, which generation of oxidizing powerful .O2 radicals which can also directly oxidize CIP. This work provides a new perspective on the reuse of waste ES and the design of CuS catalysts.
{"title":"Efficient degradation of ciprofloxacin by waste eggshells derived ES/CuS heterostructure under visible light","authors":"Guanghong Zhao, Yuan Wei, Yubing Liu, Chao Liu, Hongyu Wang, Xin Li, Ronghui Liu, Yanyan Jiang, Yulan Zhang, Yuhui Gao, Gaofeng Shi, Guoying Wang","doi":"10.1142/s1793604724510196","DOIUrl":"https://doi.org/10.1142/s1793604724510196","url":null,"abstract":"<p>The transformation of discarded eggshells (ES) into high value-added materials through technological means and the realization of turning waste ES “stone into gold” are of great significance to the environment and sustainable economic development. CuS is a typical semiconductor with broad and powerful light absorption properties, which is widely used in photocatalytic wastewater remediation. However, the high recombination rate of CuS photogenerated electron-hole pairs limits its application. In this study, a novel waste eggshell-derived ES/CuS heterojunction photocatalyst is innovatively constructed using an adsorption-precipitation method to realize the efficient degradation of ciprofloxacin (CIP) under visible light. The results showed that the ES/CuS heterojunction photocatalyst, under visible light irradiation, could degrade CIP (20 mg/L) with a degradation efficiency of 93.7% at 5 h (including 1 h of dark reaction), which compared to the degradation efficiency of CuS (52.3%) its CIP removal was significantly increased by a factor of 1.78, and showed good stability and reusability. The superior CIP degradation performance is mainly attributed to the introduction of ES to improve the separation efficiency of CuS photogenerated carriers and can participate in redox reactions through the formation of e<span><math altimg=\"eq-00001.gif\" display=\"inline\" overflow=\"scroll\"><msup><mrow></mrow><mrow><mo stretchy=\"false\">−</mo></mrow></msup></math></span><span></span> and h<span><math altimg=\"eq-00002.gif\" display=\"inline\" overflow=\"scroll\"><msup><mrow></mrow><mrow><mo stretchy=\"false\">+</mo></mrow></msup></math></span><span></span> on the surface of heterojunctions under visible light irradiation, which generation of oxidizing powerful .O<sub>2</sub><span><math altimg=\"eq-00003.gif\" display=\"inline\" overflow=\"scroll\"><msup><mrow></mrow><mrow><mo stretchy=\"false\">−</mo></mrow></msup></math></span><span></span> radicals which can also directly oxidize CIP. This work provides a new perspective on the reuse of waste ES and the design of CuS catalysts.</p>","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140324990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-12DOI: 10.1142/s1793604724510184
Bin Gu, Guangyu Wen, Bo Zhang, Jhonatan Rodriguez-Pereira, Tomas Wagner
In recent years, 2D metal nanomaterials have emerged as a novel class of 2D materials owing to their unique physiochemical properties. In this paper, memristive devices (CuAl(BE)/Cu (SiO2)/W(TE)) were fabricated utilizing 2D CuAl materials with different compositions as electrodes. After exfoliation by sonication, the minimum thickness of the freestanding single layer of 2D Cu Alwas only 1.5 nm. Furthermore, the distribution of SET thresholds was determined by the composition of the 2D CuAl
{"title":"Influence of 2D CuxAl(100−x) electrodes on the CuxAl(100−x)/Cu21(SiO2)79/W memristive device","authors":"Bin Gu, Guangyu Wen, Bo Zhang, Jhonatan Rodriguez-Pereira, Tomas Wagner","doi":"10.1142/s1793604724510184","DOIUrl":"https://doi.org/10.1142/s1793604724510184","url":null,"abstract":"<p>In recent years, 2D metal nanomaterials have emerged as a novel class of 2D materials owing to their unique physiochemical properties. In this paper, memristive devices (Cu<span><math altimg=\"eq-00009.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span><span></span>Al<span><math altimg=\"eq-00010.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mo stretchy=\"false\">(</mo><mn>1</mn><mn>0</mn><mn>0</mn><mo stretchy=\"false\">−</mo></mrow></msub></math></span><span></span><span><math altimg=\"eq-00011.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span><span></span><span><math altimg=\"eq-00012.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mo stretchy=\"false\">)</mo></mrow></msub></math></span><span></span>(BE)/Cu <span><math altimg=\"eq-00013.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mn>2</mn><mn>1</mn></mrow></msub></math></span><span></span>(SiO<sub>2</sub>)<span><math altimg=\"eq-00014.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mn>7</mn><mn>9</mn></mrow></msub></math></span><span></span>/W(TE)) were fabricated utilizing 2D Cu<span><math altimg=\"eq-00015.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span><span></span>Al <span><math altimg=\"eq-00016.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mo stretchy=\"false\">(</mo><mn>1</mn><mn>0</mn><mn>0</mn><mo stretchy=\"false\">−</mo></mrow></msub></math></span><span></span><span><math altimg=\"eq-00017.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span><span></span><span><math altimg=\"eq-00018.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mo stretchy=\"false\">)</mo></mrow></msub></math></span><span></span> materials with different compositions as electrodes. After exfoliation by sonication, the minimum thickness of the freestanding single layer of 2D Cu<span><math altimg=\"eq-00019.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span><span></span> Al<span><math altimg=\"eq-00020.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mo stretchy=\"false\">(</mo><mn>1</mn><mn>0</mn><mn>0</mn><mo stretchy=\"false\">−</mo></mrow></msub></math></span><span></span><span><math altimg=\"eq-00021.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span><span></span><span><math altimg=\"eq-00022.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mo stretchy=\"false\">)</mo></mrow></msub></math></span><span></span>was only 1.5 nm. Furthermore, the distribution of SET thresholds was determined by the composition of the 2D Cu<span><math altimg=\"eq-00023.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span><span></span>Al<span><math altimg=\"eq","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140153094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-12DOI: 10.1142/s1793604724500103
Jianmin Li, Han Zhao, Kang Ma, Yikai Fu, Haitao Dai, Zhixiang Sun, Hong-Ying Gao
Solution-processed metal halide perovskite nanocrystals show promise for various potential optoelectronic applications and the exploration of the fundamental physics underlying them. However, the electronic properties of individual nanocrystals have not been thoroughly studied. Here, we applied low-temperature scanning tunneling microscopy to investigate the properties of metal halide perovskite CsPbI2Br nanocrystals with a diameter in the range of 10–20 nm. Sub-monolayer dispersions of the nanocrystal on highly oriented pyrolytic graphite and gold thin film substrates were achieved. Using scanning tunneling microscopy, we resolved topographies of individual nanocrystals on the gold film, and their electronic properties were probed by scanning tunneling spectroscopy. In our experiment, no obvious dependence of the extracted energy gap on the nanocrystal size and shape was found, which is consistent with the reported small exciton Bohr radius in metal halide perovskite materials. Additionally, we observed that the energy gaps of some nanocrystals are smaller than that of the bulk, suggesting the influence of factors such as deep-level defects/traps, ion migration, etc. on the electronic structure.
{"title":"Electronic properties of individual CsPbI2Br nanocrystals investigated by LT-STM","authors":"Jianmin Li, Han Zhao, Kang Ma, Yikai Fu, Haitao Dai, Zhixiang Sun, Hong-Ying Gao","doi":"10.1142/s1793604724500103","DOIUrl":"https://doi.org/10.1142/s1793604724500103","url":null,"abstract":"<p>Solution-processed metal halide perovskite nanocrystals show promise for various potential optoelectronic applications and the exploration of the fundamental physics underlying them. However, the electronic properties of individual nanocrystals have not been thoroughly studied. Here, we applied low-temperature scanning tunneling microscopy to investigate the properties of metal halide perovskite CsPbI<sub>2</sub>Br nanocrystals with a diameter in the range of 10–20 nm. Sub-monolayer dispersions of the nanocrystal on highly oriented pyrolytic graphite and gold thin film substrates were achieved. Using scanning tunneling microscopy, we resolved topographies of individual nanocrystals on the gold film, and their electronic properties were probed by scanning tunneling spectroscopy. In our experiment, no obvious dependence of the extracted energy gap on the nanocrystal size and shape was found, which is consistent with the reported small exciton Bohr radius in metal halide perovskite materials. Additionally, we observed that the energy gaps of some nanocrystals are smaller than that of the bulk, suggesting the influence of factors such as deep-level defects/traps, ion migration, etc. on the electronic structure.</p>","PeriodicalId":12701,"journal":{"name":"Functional Materials Letters","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140153152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}