Pub Date : 2020-01-01DOI: 10.5474/geologija.2020.001
René H. B. Fraaije, B. Bakel, J. Jagt, P. Skupien
Subsequent to a preliminary report on a handful of paguroid remains from the Tithonian (uppermost Jurassic) to lower Berriasian (Lower Cretaceous) Štramberk Limestone in Moravia (eastern Czech Republic), published in 2013, several field campaigns were organised by our research team during the summers of 2012–2015 and 2018. These resulted in the recovery of additional paguroid shields (or, anterior carapaces) that form the basis of the present study. The currently available material documents a diverse paguroid fauna. In fact, it ranks
{"title":"Paguroid anomurans from the upper Tithonian–lower Berriasian of Štramberk, Moravia (Czech Republic)","authors":"René H. B. Fraaije, B. Bakel, J. Jagt, P. Skupien","doi":"10.5474/geologija.2020.001","DOIUrl":"https://doi.org/10.5474/geologija.2020.001","url":null,"abstract":"Subsequent to a preliminary report on a handful of paguroid remains from the Tithonian (uppermost Jurassic) to lower Berriasian (Lower Cretaceous) Štramberk Limestone in Moravia (eastern Czech Republic), published in 2013, several field campaigns were organised by our research team during the summers of 2012–2015 and 2018. These resulted in the recovery of additional paguroid shields (or, anterior carapaces) that form the basis of the present study. The currently available material documents a diverse paguroid fauna. In fact, it ranks","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70908990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.5474/geologija.2020.010
J. Wallaard, René H. B. Fraaije, J. Jagt, A. Klompmaker, B. Bakel
For the first time, a paguroid shield is recorded from upper Miocene reefal strata (Koronia Member, Pakhna Formation) that crop out along the northern margin of the Troodos Massif, north of the village of Mitsero, Cyprus. Described here as Paguristes joecollinsi sp. nov., it constitutes the first paguroid shield known from Miocene deposits. The paucity of Cenozoic paguroid shields can probably be linked to a collecting bias in view of their relatively small size; in addition, suitable gastropod shells and internal moulds of such should be screened for ‘hidden’ hermit crabs.
{"title":"The first record of a paguroid shield (Decapoda, Anomura, Annuntidiogenidae) from the Miocene of Cyprus","authors":"J. Wallaard, René H. B. Fraaije, J. Jagt, A. Klompmaker, B. Bakel","doi":"10.5474/geologija.2020.010","DOIUrl":"https://doi.org/10.5474/geologija.2020.010","url":null,"abstract":"For the first time, a paguroid shield is recorded from upper Miocene reefal strata (Koronia Member, Pakhna Formation) that crop out along the northern margin of the Troodos Massif, north of the village of Mitsero, Cyprus. Described here as Paguristes joecollinsi sp. nov., it constitutes the first paguroid shield known from Miocene deposits. The paucity of Cenozoic paguroid shields can probably be linked to a collecting bias in view of their relatively small size; in addition, suitable gastropod shells and internal moulds of such should be screened for ‘hidden’ hermit crabs.","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"254 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70909293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.5474/geologija.2020.002
G. Schweigert, J. Härer
Two new species of Late Jurassic erymid lobsters, Stenodactylina devillezi sp. nov. and geigerae sp. nov., are described on the basis of isolated, but well-preserved chelipeds from the upper Kimmeridgian of Swabia and the lower Tithonian of Bavaria, respectively. The incomplete nature of the material indicates that these lobsters were not autochthonous elements of the Plattenkalk lagoons, but resulted from predation in nearby shallow-water settings.
{"title":"New erymid lobsters from the Nusplingen and Usseltal formations (Upper Jurassic) of southwest Germany","authors":"G. Schweigert, J. Härer","doi":"10.5474/geologija.2020.002","DOIUrl":"https://doi.org/10.5474/geologija.2020.002","url":null,"abstract":"Two new species of Late Jurassic erymid lobsters, Stenodactylina devillezi sp. nov. and geigerae sp. nov., are described on the basis of isolated, but well-preserved chelipeds from the upper Kimmeridgian of Swabia and the lower Tithonian of Bavaria, respectively. The incomplete nature of the material indicates that these lobsters were not autochthonous elements of the Plattenkalk lagoons, but resulted from predation in nearby shallow-water settings.","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70909041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.5474/geologija.2020.009
M. Hyžný, R. Gašparič, A. Dulai
The crab species Plagiolophus sulcatus Beurlen, 1939 from the Oligocene (Rupelian) Kiscell Clay of Hungary is revised and its holotype is reillustrated for the first time since its original publication. Material from the upper Oligocene (Chattian) of Trbovlje (Slovenia) is here considered conspecific with P. sulcatus . Attribution of this species to the genus Glyphithyreus , as proposed by Hiroaki Karasawa and Carrie Schweitzer in 2004, is confirmed. Glypthithyreus sulcatus differs from congeners in possessing protogastric regions that are subtriangular in outline and in having fewer and coarser tubercles on elevated carapace regions.
{"title":"Revision of species Plagiolophus sulcatus Beurlen, 1939 (Decapoda, Brachyura) from the Oligocene of Hungary and Slovenia","authors":"M. Hyžný, R. Gašparič, A. Dulai","doi":"10.5474/geologija.2020.009","DOIUrl":"https://doi.org/10.5474/geologija.2020.009","url":null,"abstract":"The crab species Plagiolophus sulcatus Beurlen, 1939 from the Oligocene (Rupelian) Kiscell Clay of Hungary is revised and its holotype is reillustrated for the first time since its original publication. Material from the upper Oligocene (Chattian) of Trbovlje (Slovenia) is here considered conspecific with P. sulcatus . Attribution of this species to the genus Glyphithyreus , as proposed by Hiroaki Karasawa and Carrie Schweitzer in 2004, is confirmed. Glypthithyreus sulcatus differs from congeners in possessing protogastric regions that are subtriangular in outline and in having fewer and coarser tubercles on elevated carapace regions.","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70909281","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.5474/geologija.2020.005
S. L. Jakobsen, René H. B. Fraaije, J. Jagt, B. Bakel
During recent decades, decapod crustacean faunas from middle Danian (lower Paleocene) strata at Faxe (Sjælland, Denmark) have been studied in detail. However, paguroid anomurans have not yet been described formally. Two new species of hermit crab have lately been recognised in the collections of the Geomuseum Faxe. Percentages of total paguroid assemblages and feeding behaviour derived from the morphology of its chelae indicate that one of these, Dardanus faxensis sp. nov., as a generalist, was better adapted to inhabit the deep-water reefal environment of the Faxe carbonates than the more specialised, suspension-feeding Paguristes frigoscopulus sp. nov.
{"title":"New early Paleocene (Danian) paguroids from deep-water coral/bryozoan mounds at Faxe, eastern Denmark","authors":"S. L. Jakobsen, René H. B. Fraaije, J. Jagt, B. Bakel","doi":"10.5474/geologija.2020.005","DOIUrl":"https://doi.org/10.5474/geologija.2020.005","url":null,"abstract":"During recent decades, decapod crustacean faunas from middle Danian (lower Paleocene) strata at Faxe (Sjælland, Denmark) have been studied in detail. However, paguroid anomurans have not yet been described formally. Two new species of hermit crab have lately been recognised in the collections of the Geomuseum Faxe. Percentages of total paguroid assemblages and feeding behaviour derived from the morphology of its chelae indicate that one of these, Dardanus faxensis sp. nov., as a generalist, was better adapted to inhabit the deep-water reefal environment of the Faxe carbonates than the more specialised, suspension-feeding Paguristes frigoscopulus sp. nov.","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70909109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.5474/geologija.2020.003
R. Gašparič, C. Robins, L. Gale
A new species of squat lobster, Mesogalathea ardua sp. nov., is described on the basis of newly collected dorsal carapaces from an Upper Jurassic reefal limestone olistolith at Velika Strmica. The fossiliferous olistolith is situated within Upper Cretaceous flysch-type deposits, but originally formed within the central parastromatoporoid zone of a Jurassic reef complex. Mesogalathea ardua sp. nov. represents the first formal description of a Jurassic squat lobster from Slovenia and extends the known palaeobiogeographical distribution of galatheoid anomurans.
{"title":"Mesogalathea ardua sp. nov., a new species of squat lobster (Decapoda, Galatheidae) from the Upper Jurassic olistolith at Velika Strmica (Dolenjska, Slovenia)","authors":"R. Gašparič, C. Robins, L. Gale","doi":"10.5474/geologija.2020.003","DOIUrl":"https://doi.org/10.5474/geologija.2020.003","url":null,"abstract":"A new species of squat lobster, Mesogalathea ardua sp. nov., is described on the basis of newly collected dorsal carapaces from an Upper Jurassic reefal limestone olistolith at Velika Strmica. The fossiliferous olistolith is situated within Upper Cretaceous flysch-type deposits, but originally formed within the central parastromatoporoid zone of a Jurassic reef complex. Mesogalathea ardua sp. nov. represents the first formal description of a Jurassic squat lobster from Slovenia and extends the known palaeobiogeographical distribution of galatheoid anomurans.","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70909051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-30DOI: 10.5474/geologija.2019.015
A. Koroša, N. Mali
{"title":"Occurence of pesticides in Dravsko polje aquifer","authors":"A. Koroša, N. Mali","doi":"10.5474/geologija.2019.015","DOIUrl":"https://doi.org/10.5474/geologija.2019.015","url":null,"abstract":"","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"62 1","pages":"301-319"},"PeriodicalIF":0.0,"publicationDate":"2019-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45310981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-30DOI: 10.5474/geologija.2019.010
T. Kanduč, T. Verbovšek, Rok Novak, R. Jacimovic
In this multi-elemental study, 34 elements (Ag, As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Eu, Fe, Ga, Hg, Hf, K, La, Mo, Na, Nd, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, U, Yb, Zn and Zr) were analysed in Slovenian coals from operative (Velenje) and non-operative (Kanižarica and Senovo) coal mines and an imported Indonesia coal using k0-Instrumental Neutron Activation Analysis (k0-INAA) and compared to inductively coupled plasma-mass spectroscopy (ICP-MS). Weaker regressions between both methods ICP-MS and k0-INAA are obtained for following elements: Cs, Co, Eu, Se, Sm and Tb with low concentration (below 1 mg/kg). The k0-INAA data are comparable to the ICP-MS data for the majority of elements. The levels of major elements measured with k0-INAA are as follows: Ca>Fe>K>Na>Sr>Ba. Minor and trace elements, as well as rare earth elements (REEs), are comparable with coal values worldwide. Data of trace elements in coal are important since they are related to air emissions. According to our data obtained with both methods (ICP-MS and k0-INAA) we can conclude that concentrations of trace elements, which impact to human health and are combusted (Indonesian and Velenje coal) in Slovenia are comparable to world averages coal. Izvleček V tej raziskavi smo izmerili s k0-INAA (instrumentalno nevtronsko aktivacijsko analizo) metodo nekaj izbranih slovenskih premogov iz velenjskega premogovnika in ne operativnih premogovnikov: Kanižarica in Senovo. Prav tako smo s to metodo analizirali vzorec iz Indonezije (uvožen premog) in ga primerjali z že objavljenimi rezultati pridobljenimi z ICP – MS (masna spektrometrija z induktivno sklopljeno plazmo) metodo. S k0-INAA metodo smo določili naslednje elemente: Ag, As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Eu, Fe, Ga, Hg, Hf, K, La, Mo, Na, Nd, Rb, Sb , Sc, Se, Sm, Sr, Ta, Tb, Th, U, Yb, Zn in Zr. Rezultati meritev pridobljeni s k0-INAA metodo so za večino elementov, obravnavanih v tej raziskavi, primerljivi z rezultati meritev pridobljenih z ICP-MS metodo. Slabše regresije med metodami ICP-MS in k0-INAA dobimo le pri nekaterih elementih (Cs, Co, Eu, Se, Sm and Tb) za katere so značilne nizke koncentracije (pod 1 mg/kg). Koncentracije glavnih elementov merjenih s k0-INAA metodo v premogu se znižujejo kot sledi: Ca> Fe> K> Na> Sr> Ba. Elementi z nizkimi koncentracijami in elementi redkih zemelj (REE) so primerljivi z vrednostmi premoga po vsem svetu. Podatki slednih elementov v premogu so pomembni, ker so povezani z emisijami v zraku. Glede na naše podatke pridobljene z obema metodama (ICPMS, k0-INAA) lahko zaključimo, da so koncentracije slednih elementov, ki vplivajo na človekovo zdravje in jih sežigamo (premog iz Velenja in Indonezije) v Sloveniji primerljivi s povprečnimi vrednostmi svetovnih premogov. GEOLOGIJA 62/2, 219-236, Ljubljana 2019 https://doi.org/10.5474/geologija.2019.010 220 Tjaša KANDUČ, Timotej VERBOVŠEK, Rok NOVAK & Radojko JAĆIMOVIĆ Introduction The chemical analysis of coal includes, as well as, proximate (Kha
在该多元素研究中，使用k0仪器中子活化分析（k0 INAA）对斯洛文尼亚运营（Velenje）和非运营（Kanižarica和Senovo）煤矿的煤和进口印度尼西亚煤中的34种元素（Ag、As、Au、Ba、Br、Ca、Cd、Ce、Co、Cr、Cs、Eu、Fe、Ga、Hg、Hf、K、La、Mo、Na、Nd、Rb、Sb、Sc、Se、Sm、Sr、Ta、Tb、Th、U、Yb、Zn和Zr）进行了分析，并与电感耦合进行了比较等离子体质谱（ICP-MS）。对于以下元素，ICP-MS和k0-INAA两种方法之间的回归较弱：低浓度（低于1 mg/kg）的Cs、Co、Eu、Se、Sm和Tb。k0-INAA数据与大多数元素的ICP-MS数据相当。k0 INAA测定的主要元素含量为：Ca>Fe>K>Na>Sr>Ba。微量元素和微量元素以及稀土元素（REE）与全球煤炭价值相当。煤中微量元素的数据很重要，因为它们与空气排放有关。根据我们用这两种方法（ICP-MS和k0-INAA）获得的数据，我们可以得出结论，影响人类健康并在斯洛文尼亚燃烧的微量元素（印尼和维伦杰煤炭）的浓度与世界平均煤炭相当。Izvleček V tej raziskavi smo izmerili s k0 INAA。Prav tako smo s to metodo analizirali vzorec iz Indonezije（uvožen premg）in ga primerjali zže objavljenimi rezultati pridobljenimi z ICP–MS（masna specktrometrija z induktivno sklopljeno plazmo）metodo。S k0 INAA金属元素：Zr中的Ag、As、Au、Ba、Br、Ca、Cd、Ce、Co、Cr、Cs、Eu、Fe、Ga、Hg、Hf、K、La、Mo、Na、Nd、Rb、Sb、Sc、Se、Sm、Sr、Ta、Tb、Th、U、Yb、Zn。Rezultati meritev pridobljeni s k0 INAA metodo so za večino elementov，obravnavanih v tej raziskavi，primerljivi z Rezultti meritev pridobljenih z ICP-MS metodo。Slabše regresije在k0 INAA中用ICP-MS测定了元素（Cs、Co、Eu、Se、Sm和Tb）的含量（pod 1 mg/kg）。Koncentracije glavnih elementov merjenih s k0 INAA metodo v premogu se znižujejo kot sledi：Ca>Fe>K>Na>Sr>Ba。元素z nizkimi koncentracijami in Elementi redkih zemelj（REE）so primerljivi z vrednostmi premoga po-vsem svetu。波达特基·斯莱德尼赫·elementov v premogu so pomembni，ker so povezani z emisijami v zraku。Glede naše podatke pridobljene z obema metodama（ICPMS，k0 INAA）lahko zaključimo，da so koncentracije slednih elementov，ki vplivajo načlovekovo zdravje in jih sežigamo（premg iz Velenja in Indonezije）v Sloveniji primerljivi s povprečnimi vrednostmi svetovnih premov。GEOLOGIJA 62/2219-2362019卢布尔雅那https://doi.org/10.5474/geologija.2019.010220 Tjaša KANDUČ，Timotej VERBOVŠEK，Rok NOVAK&Radojko JAÍIMOVIÍ。通常，这些元素是使用电感耦合等离子体质谱法（ICP-MS）（Finkelman等人，2018）和仪器中子活化分析法（k0-INAA）（Wagner和Matiane，2018，Lin et al.，2018）测量的。其他测定微量元素的方法包括电感耦合等离子体发射光谱法（ICP-OES）（Finkelman等人，2018）、氢化物发生原子吸收光谱法（HAAS）（Chen等人，2011）和X射线荧光光谱法（XRF）（Chen et al.，2011）。众所周知，这些微量元素可以以多种化学形式或存在模式存在，这决定了环境、经济和技术影响，在某些情况下可能具有重大影响（Finkelman，19952018）。煤中通常以无机和有机形式存在25种潜在有害微量元素（Radenovič，2006）。其中As、Be、Cd、Cr、Co、Hg、Mn、Ni、Pb、Se、Sb和U都是潜在的空气污染物（Gürdal，2008）。Ketris和Yudovich（2009）在煤克拉克值表中包括稀土元素、钇和钪（REY+Sc），这是对全球煤炭进行地球化学比较的一个非常有用的工具。印尼的煤通常灰分和硫含量较低，但挥发性物质含量较高。它们被归类为低热值的低阶煤。硫含量从0.1%到1%不等（互联网1）。本研究中Velenje样品的TOT S元素组成（wt%，干基）从1.4%到3.9%不等，Kanižarica从1.6%到2.2%不等，Senovo从1.9%不等（BurnikŠturm等人，2009）。Brezigar等人（1987）详细描述了Velenje盆地的地质组成。 Velenje盆地的起源与Šoštanj和Smrekovec断层之间的迁移有关。在盆地前上新世基底中，Velenje断层东北侧以三叠纪碳酸盐岩和白云石为主，而断层西南侧以渐新世至中新世碎屑岩为主，主要由泥灰岩、砂岩和火山碎屑岩组成。Velenje盆地形成过程中的碱性富钙环境也导致了相对较高的凝胶化程度，显著高于在其他褐煤中观察到的凝胶化水平（Markič和Sachshofer，1997；Šlejkovec和Kanduč，2005；Markić和Sachsehofer，2010）以及我们研究中调查的煤。在Velenje褐煤的情况下，碱度和凝胶化之间有着众所周知的关系。钙含量最高的褐煤样品也是凝胶化最强的样品（Markič&Sachsenhofer，1997）。褐煤样品的岩石类型宏观描述是根据国际煤岩委员会（ICCP，1993）提供的褐煤（褐煤）岩石类型分类标准确定的，BurnikŠturm等人（2009）对此进行了描述。本研究中，Velenje开挖场-50/C的所有样本均被归类为凝胶化碎屑褐煤（Kandučet al.，2018）。BurnikŠturm等人（2009）及其参考文献（Brezigar，19
{"title":"Multielemental composition of some Slovenian coals determined with k0 -INAA method and comparison with ICP-MS method","authors":"T. Kanduč, T. Verbovšek, Rok Novak, R. Jacimovic","doi":"10.5474/geologija.2019.010","DOIUrl":"https://doi.org/10.5474/geologija.2019.010","url":null,"abstract":"In this multi-elemental study, 34 elements (Ag, As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Eu, Fe, Ga, Hg, Hf, K, La, Mo, Na, Nd, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, U, Yb, Zn and Zr) were analysed in Slovenian coals from operative (Velenje) and non-operative (Kanižarica and Senovo) coal mines and an imported Indonesia coal using k0-Instrumental Neutron Activation Analysis (k0-INAA) and compared to inductively coupled plasma-mass spectroscopy (ICP-MS). Weaker regressions between both methods ICP-MS and k0-INAA are obtained for following elements: Cs, Co, Eu, Se, Sm and Tb with low concentration (below 1 mg/kg). The k0-INAA data are comparable to the ICP-MS data for the majority of elements. The levels of major elements measured with k0-INAA are as follows: Ca>Fe>K>Na>Sr>Ba. Minor and trace elements, as well as rare earth elements (REEs), are comparable with coal values worldwide. Data of trace elements in coal are important since they are related to air emissions. According to our data obtained with both methods (ICP-MS and k0-INAA) we can conclude that concentrations of trace elements, which impact to human health and are combusted (Indonesian and Velenje coal) in Slovenia are comparable to world averages coal. Izvleček V tej raziskavi smo izmerili s k0-INAA (instrumentalno nevtronsko aktivacijsko analizo) metodo nekaj izbranih slovenskih premogov iz velenjskega premogovnika in ne operativnih premogovnikov: Kanižarica in Senovo. Prav tako smo s to metodo analizirali vzorec iz Indonezije (uvožen premog) in ga primerjali z že objavljenimi rezultati pridobljenimi z ICP – MS (masna spektrometrija z induktivno sklopljeno plazmo) metodo. S k0-INAA metodo smo določili naslednje elemente: Ag, As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Eu, Fe, Ga, Hg, Hf, K, La, Mo, Na, Nd, Rb, Sb , Sc, Se, Sm, Sr, Ta, Tb, Th, U, Yb, Zn in Zr. Rezultati meritev pridobljeni s k0-INAA metodo so za večino elementov, obravnavanih v tej raziskavi, primerljivi z rezultati meritev pridobljenih z ICP-MS metodo. Slabše regresije med metodami ICP-MS in k0-INAA dobimo le pri nekaterih elementih (Cs, Co, Eu, Se, Sm and Tb) za katere so značilne nizke koncentracije (pod 1 mg/kg). Koncentracije glavnih elementov merjenih s k0-INAA metodo v premogu se znižujejo kot sledi: Ca> Fe> K> Na> Sr> Ba. Elementi z nizkimi koncentracijami in elementi redkih zemelj (REE) so primerljivi z vrednostmi premoga po vsem svetu. Podatki slednih elementov v premogu so pomembni, ker so povezani z emisijami v zraku. Glede na naše podatke pridobljene z obema metodama (ICPMS, k0-INAA) lahko zaključimo, da so koncentracije slednih elementov, ki vplivajo na človekovo zdravje in jih sežigamo (premog iz Velenja in Indonezije) v Sloveniji primerljivi s povprečnimi vrednostmi svetovnih premogov. GEOLOGIJA 62/2, 219-236, Ljubljana 2019 https://doi.org/10.5474/geologija.2019.010 220 Tjaša KANDUČ, Timotej VERBOVŠEK, Rok NOVAK & Radojko JAĆIMOVIĆ Introduction The chemical analysis of coal includes, as well as, proximate (Kha","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"62 1","pages":"219-236"},"PeriodicalIF":0.0,"publicationDate":"2019-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48612534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-30DOI: 10.5474/geologija.2019.008
M. Miler, Tanja Mašera, N. Zupančič, S. Jarc
Common rock-forming and accessory minerals in marbles from various localities in Slovenia were studied using scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS). Minerals and their chemical composition were identified in order to verify the variability of mineral assemblages in marbles from different localities in Slovenia. The analysis showed that marbles from Košenjak are the most mineralogically diverse, followed by Pohorje and finally Strojna marbles. Common rock-forming minerals calcite and dolomite are more abundant in Pohorje marbles where calcite contains higher levels of magnesium but no strontium and iron as compared with Strojna and Košenjak marbles. Accessory minerals like quartz, mica, titanite, apatite, rutile, zircon, chlorite group minerals, kaolinite and iron oxides/hydroxides were found in marbles from all localities. Clinopyroxene, amphibole, epidote and smectite group minerals, talc, tungsten-bearing ilmenorutile, psilomelane and bismuth oxides/carbonates, were observed only in marbles from Pohorje, while tourmaline and allanite group minerals, thorite or huttonite, chalcopyrite and synchysite group minerals were detected in marbles from Košenjak and Strojna. Variations in mineral assemblages in marbles from different locations are likely a consequence of different sedimentary environment and conditions and metamorphic grade of marble. These differences indicate that marbles from Košenjak and Strojna are genetically different from those from Pohorje and probably reflect mineral composition of the protolith. Thus, they enable rough distinction between more distant locations, but not between individual sub-localities.
{"title":"Characteristics of minerals in Slovenian marbles","authors":"M. Miler, Tanja Mašera, N. Zupančič, S. Jarc","doi":"10.5474/geologija.2019.008","DOIUrl":"https://doi.org/10.5474/geologija.2019.008","url":null,"abstract":"Common rock-forming and accessory minerals in marbles from various localities in Slovenia were studied using scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS). Minerals and their chemical composition were identified in order to verify the variability of mineral assemblages in marbles from different localities in Slovenia. The analysis showed that marbles from Košenjak are the most mineralogically diverse, followed by Pohorje and finally Strojna marbles. Common rock-forming minerals calcite and dolomite are more abundant in Pohorje marbles where calcite contains higher levels of magnesium but no strontium and iron as compared with Strojna and Košenjak marbles. Accessory minerals like quartz, mica, titanite, apatite, rutile, zircon, chlorite group minerals, kaolinite and iron oxides/hydroxides were found in marbles from all localities. Clinopyroxene, amphibole, epidote and smectite group minerals, talc, tungsten-bearing ilmenorutile, psilomelane and bismuth oxides/carbonates, were observed only in marbles from Pohorje, while tourmaline and allanite group minerals, thorite or huttonite, chalcopyrite and synchysite group minerals were detected in marbles from Košenjak and Strojna. Variations in mineral assemblages in marbles from different locations are likely a consequence of different sedimentary environment and conditions and metamorphic grade of marble. These differences indicate that marbles from Košenjak and Strojna are genetically different from those from Pohorje and probably reflect mineral composition of the protolith. Thus, they enable rough distinction between more distant locations, but not between individual sub-localities.","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"62 1","pages":"175-187"},"PeriodicalIF":0.0,"publicationDate":"2019-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44580502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-30DOI: 10.5474/geologija.2019.014
Teja Ceru, A. Gosar
Karst as an extremely complex and heterogeneous system, that presents a great challenge for the ground penetrating radar (GPR). However, properly planed GPR surveys can provide additional information about the shallow subsurface, where most karst processes take place. Due to the specific nature of the karst terrain, the introductory part presents some obstacles and adaptive approaches to karst research. An analysis of the published literature revealed that the GPR is most commonly used for detecting caves and subsidence areas and for preventing collapses in urban areas and for construction interventions. This is followed by exploration of karst aquifers, epikarst and quarry research. Some non-established applications are also presented, such as the use of a georadar in exploration of unroofed caves and cave sediments. The main purpose of this article is to demonstrate and evaluate the possibilities of using a georadar in different karst environments, to encourage its use in some new applications, and to emphasize the necessity of an interdisciplinary approach in such studies. GEOLOGIJA 62/2, 279-300, Ljubljana 2019 https://doi.org/10.5474/geologija.2019.014
{"title":"Application of ground penetrating radar in karst environments: An overview","authors":"Teja Ceru, A. Gosar","doi":"10.5474/geologija.2019.014","DOIUrl":"https://doi.org/10.5474/geologija.2019.014","url":null,"abstract":"Karst as an extremely complex and heterogeneous system, that presents a great challenge for the ground penetrating radar (GPR). However, properly planed GPR surveys can provide additional information about the shallow subsurface, where most karst processes take place. Due to the specific nature of the karst terrain, the introductory part presents some obstacles and adaptive approaches to karst research. An analysis of the published literature revealed that the GPR is most commonly used for detecting caves and subsidence areas and for preventing collapses in urban areas and for construction interventions. This is followed by exploration of karst aquifers, epikarst and quarry research. Some non-established applications are also presented, such as the use of a georadar in exploration of unroofed caves and cave sediments. The main purpose of this article is to demonstrate and evaluate the possibilities of using a georadar in different karst environments, to encourage its use in some new applications, and to emphasize the necessity of an interdisciplinary approach in such studies. GEOLOGIJA 62/2, 279-300, Ljubljana 2019 https://doi.org/10.5474/geologija.2019.014","PeriodicalId":12743,"journal":{"name":"Geologija","volume":"62 1","pages":"279-300"},"PeriodicalIF":0.0,"publicationDate":"2019-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44813693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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