The variety of hazards with a potential impact on cultural heritage requires a multidisciplinary approach and a preliminary overview of the existing methods for risk assessment in order to define a comprehensive hazard taxonomy. The starting point of the research thus aims to build a multidisciplinary framework to support the risk assessment process according to the classification of cultural heritage based on the harmonization of European vocabularies’ definitions and protocols. To collect the necessary information, such as hazard classification, indicators, indices and thresholds, a series of methodologies was adopted: analysis of the main international protocols and the EU Research projects related to risk assessment in cultural heritage, expert-based knowledge and a systematic literature review. The research aims to fill a gap in the field of quantitative and indicator-based risk assessment that does not present a unique and all-encompassing framework capable of collecting the main natural and anthropic risks along with the related taxonomy in a single repository. The framework has been set up to be consulted by researchers, professionals and public administrations to support the evaluation process of potential risks on tangible outdoor heritage enabling users to incrementally add exposure and vulnerability data for each specific risk.
{"title":"A Framework for a Hazard Taxonomy to Support Risk Assessment of Tangible Outdoor Heritage","authors":"Alessandra Battisti, A. Figliola, M. Santarelli","doi":"10.3390/heritage7060140","DOIUrl":"https://doi.org/10.3390/heritage7060140","url":null,"abstract":"The variety of hazards with a potential impact on cultural heritage requires a multidisciplinary approach and a preliminary overview of the existing methods for risk assessment in order to define a comprehensive hazard taxonomy. The starting point of the research thus aims to build a multidisciplinary framework to support the risk assessment process according to the classification of cultural heritage based on the harmonization of European vocabularies’ definitions and protocols. To collect the necessary information, such as hazard classification, indicators, indices and thresholds, a series of methodologies was adopted: analysis of the main international protocols and the EU Research projects related to risk assessment in cultural heritage, expert-based knowledge and a systematic literature review. The research aims to fill a gap in the field of quantitative and indicator-based risk assessment that does not present a unique and all-encompassing framework capable of collecting the main natural and anthropic risks along with the related taxonomy in a single repository. The framework has been set up to be consulted by researchers, professionals and public administrations to support the evaluation process of potential risks on tangible outdoor heritage enabling users to incrementally add exposure and vulnerability data for each specific risk.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141266038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
George Volanis, Demitrios Galanakis, N. Bolanakis, Emmanuel Maravelakis, Ruben Paul Borg, Georgios E. Stavroulakis
The stability of rock cliffs is a longstanding issue and is of practical significance. This case study demonstrates the application and use of advanced 3D modeling techniques, concentrating on the geological formations of the Xrobb l-Ġħaġin peninsula on the south-east coast of Malta, where the Xrobb l-Ġħaġin Neolithic site is located. In order to utilize a static and dynamic analysis of the investigated scenario, a 3D finite element model (FEM) of the geological formation in which the monument is set had to be created. To this end, 3D scanning, unmanned aerial vehicles (UAVs), and oblique photogrammetry were first used with state-of-the-art commercial packages for mesh reconstruction. As a result, a geometric and finite element model (FEM) was created, suitable for both static and dynamic analysis. In the second stage, a parametric investigation of the material properties of the structural system of the geological substrate was sought. The structural response of the system was evaluated for different loading scenarios assuming nonlinear finite element analysis. Collapse case scenarios were investigated for standard and weakened materials, predicting which components would collapse first and under which case of weakened materials the collapse occurs. Among other aspects, the main novelty of this paper lies in the integrated approach and multidisciplinary paradigm that supplement the available historical knowledge for this specific cultural heritage Neolithic site towards its conservation.
{"title":"Modelling and Stability Assessment of the Rock Cliffs and Xrobb l-Ġħaġin Neolithic Structure in Malta","authors":"George Volanis, Demitrios Galanakis, N. Bolanakis, Emmanuel Maravelakis, Ruben Paul Borg, Georgios E. Stavroulakis","doi":"10.3390/heritage7060138","DOIUrl":"https://doi.org/10.3390/heritage7060138","url":null,"abstract":"The stability of rock cliffs is a longstanding issue and is of practical significance. This case study demonstrates the application and use of advanced 3D modeling techniques, concentrating on the geological formations of the Xrobb l-Ġħaġin peninsula on the south-east coast of Malta, where the Xrobb l-Ġħaġin Neolithic site is located. In order to utilize a static and dynamic analysis of the investigated scenario, a 3D finite element model (FEM) of the geological formation in which the monument is set had to be created. To this end, 3D scanning, unmanned aerial vehicles (UAVs), and oblique photogrammetry were first used with state-of-the-art commercial packages for mesh reconstruction. As a result, a geometric and finite element model (FEM) was created, suitable for both static and dynamic analysis. In the second stage, a parametric investigation of the material properties of the structural system of the geological substrate was sought. The structural response of the system was evaluated for different loading scenarios assuming nonlinear finite element analysis. Collapse case scenarios were investigated for standard and weakened materials, predicting which components would collapse first and under which case of weakened materials the collapse occurs. Among other aspects, the main novelty of this paper lies in the integrated approach and multidisciplinary paradigm that supplement the available historical knowledge for this specific cultural heritage Neolithic site towards its conservation.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141271206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Mozas-Calvache, J. M. Gómez-López, José Luis Pérez-García, D. Vico-García, V. Barba-Colmenero, Alberto Fernández-Ordóñez
This study describes the methodology and main results obtained after applying several geomatic techniques, based on the fusion of data acquired by several sensors, to document the recovery works carried out in an abandoned church. A century ago, the façade was moved to a museum to ensure its preservation. In addition to documentary purposes, a secondary goal is the virtual repositioning of a model of this element on that of the church. The method takes advantage of the potential of each technique, considering the acquisition of geometry based mainly on laser scanning techniques and radiometry on photogrammetry. The results include 3D models and orthoimages, which are used to perform a stratigraphic study. The 3D model of the façade has been repositioned in the general one, considering common geometries previously fitted in both models and repeating part of the photogrammetric process, using masks to define the image areas related to the church and the façade. Therefore, we obtained a 3D model with the façade included in it. This procedure has demonstrated its feasibility despite the existence of different environmental conditions in both areas. Using these results, we have also developed a BIM to allow for the management of future restoration works.
{"title":"Multi-Sensor Geomatic Techniques for the 3D Documentation and Virtual Repositioning of Elements of the Church of S. Miguel (Jaén, Spain)","authors":"A. Mozas-Calvache, J. M. Gómez-López, José Luis Pérez-García, D. Vico-García, V. Barba-Colmenero, Alberto Fernández-Ordóñez","doi":"10.3390/heritage7060137","DOIUrl":"https://doi.org/10.3390/heritage7060137","url":null,"abstract":"This study describes the methodology and main results obtained after applying several geomatic techniques, based on the fusion of data acquired by several sensors, to document the recovery works carried out in an abandoned church. A century ago, the façade was moved to a museum to ensure its preservation. In addition to documentary purposes, a secondary goal is the virtual repositioning of a model of this element on that of the church. The method takes advantage of the potential of each technique, considering the acquisition of geometry based mainly on laser scanning techniques and radiometry on photogrammetry. The results include 3D models and orthoimages, which are used to perform a stratigraphic study. The 3D model of the façade has been repositioned in the general one, considering common geometries previously fitted in both models and repeating part of the photogrammetric process, using masks to define the image areas related to the church and the façade. Therefore, we obtained a 3D model with the façade included in it. This procedure has demonstrated its feasibility despite the existence of different environmental conditions in both areas. Using these results, we have also developed a BIM to allow for the management of future restoration works.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141272850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Alicia Hueto-Escobar, F. Vegas, C. Mileto, María Lidón de Miguel
Knowledge on the state of conservation and vulnerability of traditional techniques when faced with the most common degradation phenomena is vital in order to propose the most suitable conservation and maintenance actions. This article presents the systematic review of 1218 half-timbered walls found throughout Spain, enabling the identification of a total of 27 material lesions, classified by atmospheric, biological or anthropic origin, and 9 structural lesions due to stress or excessive deformation. Their qualitative and quantitative analysis has focused on the frequency of the individual lesions and the possible correlation with different constructive characteristics, such as the materials used, the geometry of the framework and the presence of plinths, eaves and protective rendering. Almost the entire sample presents some degree of material degradation, mostly atmospheric lesions of limited severity, such as superficial atmospheric erosion and chromatic alteration and dehydration of the timber. In terms of structural lesions, half-timbered walls are seen to be more vulnerable to this type of deformation. Considering the risk of loss affecting all traditional architecture, it becomes particularly important to promote the continued maintenance of half-timbered walls in order to reduce the influence of material lesions caused by atmospheric agents. Subsequently, suitable criteria for intervention are established in order to reduce the effect of anthropic lesions and structural degradation phenomena, particularly linked to a lack of maintenance and modifications of anthropic origin.
{"title":"Reflections on the Decay Mechanisms of Half-Timbered Walls in Traditional Spanish Architecture: Statistical Analysis of Material and Structural Damage","authors":"Alicia Hueto-Escobar, F. Vegas, C. Mileto, María Lidón de Miguel","doi":"10.3390/heritage7060136","DOIUrl":"https://doi.org/10.3390/heritage7060136","url":null,"abstract":"Knowledge on the state of conservation and vulnerability of traditional techniques when faced with the most common degradation phenomena is vital in order to propose the most suitable conservation and maintenance actions. This article presents the systematic review of 1218 half-timbered walls found throughout Spain, enabling the identification of a total of 27 material lesions, classified by atmospheric, biological or anthropic origin, and 9 structural lesions due to stress or excessive deformation. Their qualitative and quantitative analysis has focused on the frequency of the individual lesions and the possible correlation with different constructive characteristics, such as the materials used, the geometry of the framework and the presence of plinths, eaves and protective rendering. Almost the entire sample presents some degree of material degradation, mostly atmospheric lesions of limited severity, such as superficial atmospheric erosion and chromatic alteration and dehydration of the timber. In terms of structural lesions, half-timbered walls are seen to be more vulnerable to this type of deformation. Considering the risk of loss affecting all traditional architecture, it becomes particularly important to promote the continued maintenance of half-timbered walls in order to reduce the influence of material lesions caused by atmospheric agents. Subsequently, suitable criteria for intervention are established in order to reduce the effect of anthropic lesions and structural degradation phenomena, particularly linked to a lack of maintenance and modifications of anthropic origin.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141269328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Charlène Pelé-Meziani, Aymeric Raimon, J. Mevellec, Elodie Guilminot
On the occasion of the reopening of the Dobrée Museum (Nantes, France), two statuettes of Egyptian origin, representing Harpocrate and Isis, were studied to shed light on the presence of the blue-green efflorescence on their surface. The efflorescence on the Harpocrate statuette was identified as being chalconatronite, while that which was present on the Isis statuette corresponded to sodium copper formate/acetate, probably due to the evolution of chalconatronite in an environment containing VOCs. The efflorescence appeared to be sensitive to the cyclic variation in relative humidity whereas it seemed stable. An experimental curative treatment to halt the reappearance was carried out. A series of pure water baths extracted a significant quantity of sodium. The treatment appeared effective and reduced the risk of a recrudescence of the efflorescence for both statuettes. However, when the efflorescence was dissolved on the Isis statuette, other compounds appeared to react with water, leading to acidification and a potential reaction with the lead in the alloy. A layer of lead carbonate/acetate on the surface appeared. The objects were then dried and protected with a highly concentrated acrylic varnish. They are currently being monitored to identify any new efflorescence that may appear during display.
{"title":"Experimental Study of Chalconatronite: From Its Identification to the Treatment of Copper Alloy Objects","authors":"Charlène Pelé-Meziani, Aymeric Raimon, J. Mevellec, Elodie Guilminot","doi":"10.3390/heritage7060135","DOIUrl":"https://doi.org/10.3390/heritage7060135","url":null,"abstract":"On the occasion of the reopening of the Dobrée Museum (Nantes, France), two statuettes of Egyptian origin, representing Harpocrate and Isis, were studied to shed light on the presence of the blue-green efflorescence on their surface. The efflorescence on the Harpocrate statuette was identified as being chalconatronite, while that which was present on the Isis statuette corresponded to sodium copper formate/acetate, probably due to the evolution of chalconatronite in an environment containing VOCs. The efflorescence appeared to be sensitive to the cyclic variation in relative humidity whereas it seemed stable. An experimental curative treatment to halt the reappearance was carried out. A series of pure water baths extracted a significant quantity of sodium. The treatment appeared effective and reduced the risk of a recrudescence of the efflorescence for both statuettes. However, when the efflorescence was dissolved on the Isis statuette, other compounds appeared to react with water, leading to acidification and a potential reaction with the lead in the alloy. A layer of lead carbonate/acetate on the surface appeared. The objects were then dried and protected with a highly concentrated acrylic varnish. They are currently being monitored to identify any new efflorescence that may appear during display.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141277264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A major source in the research on Baltic cultural history (Latvia, Estonia), including studies dedicated to the clothing of local inhabitants, are the drawings and descriptions of Johann Christoph Brotze (1742–1823), which date back to the turn of the 18th and 19th centuries. They contain references to dyes and dyeing methods used by local peasants. The information recorded by J. C. Brotze, although fragmentary, is valuable because researchers lack documentary sources about the dyeing methods used in the 18th century in the territory of present-day Latvia. Additional research yields more extensive information about the contents of the descriptions. The current article will describe the experimental method that enabled the establishment of the specific dyeing technique, which, using Bixa orellana L., was employed to obtain the particular orange color referred to in the descriptions.
约翰-克里斯托夫-布罗兹（Johann Christoph Brotze，1742-1823 年）的图画和描述是研究波罗的海文化史（拉脱维亚、爱沙尼亚），包括研究当地居民服饰的主要资料，这些图画和描述可以追溯到 18 世纪和 19 世纪之交。其中提到了当地农民使用的染料和染色方法。J. C. Brotze 记录的信息虽然零散，但却很有价值，因为研究人员缺乏有关 18 世纪在现今拉脱维亚境内使用的染色方法的文献资料。额外的研究可以获得有关描述内容的更多信息。本文将介绍一种实验方法，通过这种方法可以确定特定的染色技术，即使用 Bixa orellana L.来获得描述中提到的特定橙色。
{"title":"Technology of Dyeing beyond Text","authors":"Anete Karlsone","doi":"10.3390/heritage7060127","DOIUrl":"https://doi.org/10.3390/heritage7060127","url":null,"abstract":"A major source in the research on Baltic cultural history (Latvia, Estonia), including studies dedicated to the clothing of local inhabitants, are the drawings and descriptions of Johann Christoph Brotze (1742–1823), which date back to the turn of the 18th and 19th centuries. They contain references to dyes and dyeing methods used by local peasants. The information recorded by J. C. Brotze, although fragmentary, is valuable because researchers lack documentary sources about the dyeing methods used in the 18th century in the territory of present-day Latvia. Additional research yields more extensive information about the contents of the descriptions. The current article will describe the experimental method that enabled the establishment of the specific dyeing technique, which, using Bixa orellana L., was employed to obtain the particular orange color referred to in the descriptions.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141099636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. Elshaer, Mansour A. Alyahya, Alaa M. S. Azazz, Sameh Fayyad
This study explores the interrelationship between community attachment in AlUla Heritage City (located in Saudi Arabia) and tourists’ green consumption practices, testing support for green tourism development as a mediator. The old historical city of AlUla, a significant city experiencing ongoing preservation and tourism development, represents an adequate context for exploring the link between community attachment and green tourism practices. This study employs a quantitative approach, including surveys with 328 local residents of AlUla. A structural equation modeling partial least square (PLS-SEM) analysis is conducted to explore the indirect influence of community attachment on tourists’ green consumption through the mediating role of support for green tourism development. The findings indicated a positive path from community attachment in AlUla to tourists’ tendencies toward green consumption behavior. Moreover, the mediating effects of support for green tourism development suggested that a deep sense of community attachment improves tourists’ support for green practices in the tourism sector. This study adds to the extended body of the literature on place attachment and green tourism by emphasizing the significance of community place attachment in stimulating tourists’ green consumption practices. Several practical implications for policymakers seeking to promote green tourism practices in heritage cities like AlUla are explored from the study results.
{"title":"Community Attachment to AlUla Heritage Site and Tourists’ Green Consumption: The Role of Support for Green Tourism Development","authors":"I. Elshaer, Mansour A. Alyahya, Alaa M. S. Azazz, Sameh Fayyad","doi":"10.3390/heritage7060126","DOIUrl":"https://doi.org/10.3390/heritage7060126","url":null,"abstract":"This study explores the interrelationship between community attachment in AlUla Heritage City (located in Saudi Arabia) and tourists’ green consumption practices, testing support for green tourism development as a mediator. The old historical city of AlUla, a significant city experiencing ongoing preservation and tourism development, represents an adequate context for exploring the link between community attachment and green tourism practices. This study employs a quantitative approach, including surveys with 328 local residents of AlUla. A structural equation modeling partial least square (PLS-SEM) analysis is conducted to explore the indirect influence of community attachment on tourists’ green consumption through the mediating role of support for green tourism development. The findings indicated a positive path from community attachment in AlUla to tourists’ tendencies toward green consumption behavior. Moreover, the mediating effects of support for green tourism development suggested that a deep sense of community attachment improves tourists’ support for green practices in the tourism sector. This study adds to the extended body of the literature on place attachment and green tourism by emphasizing the significance of community place attachment in stimulating tourists’ green consumption practices. Several practical implications for policymakers seeking to promote green tourism practices in heritage cities like AlUla are explored from the study results.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141105475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. Basso, Alicia McGeachy, Maria Goretti Mieites Alonso, Federica Pozzi, Roxanne Radpour, Monica Katz
The Hispanic Society Museum & Library (HSML) holds a collection of nine viceregal barniz de Pasto objects, made by Indigenous artisans in the 17th and 18th centuries. Designed to imitate Asian lacquers and intended for European aesthetic tastes, barniz de Pasto is an example of Indigenous technique and knowledge that has survived to the present day. An in-depth analysis of five of these barniz de Pasto objects, dated to the first half and last quarter of the 17th century based on their iconography, was carried out through a combination of non-invasive and micro-invasive techniques, including portable X-ray fluorescence (pXRF) spectroscopy to investigate the possible presence of inorganic pigments, and fiber-optics reflectance spectroscopy (FORS) and reflectance imaging spectroscopy (RIS) to provide molecular information on colorants and their distributions across the objects. Dyes and pigments were also identified using Raman spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, and liquid chromatography/mass spectrometry (LC/MS). The nature of the resin was determined by FTIR and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS), while the decoration stratigraphy and composition were analyzed by scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). This paper confirms the use of mopa mopa, the resin used in the barniz de Pasto technique, in two objects not previously analyzed, and identifies indigo, insect-based red, calomel, lead white, and an unknown flavonol-based yellow dye, and challenges the use of calomel as a temporal marker for these works. Taken together, these results expand our understanding of the material use and explorations undertaken by artists during this time period to create such elaborate and enduring objects.
西班牙协会博物馆和图书馆（HSML）收藏了九件由土著工匠在 17 和 18 世纪制作的巴尼兹-德-帕斯托（barniz de Pasto）饰品。barniz de Pasto 的设计模仿亚洲漆器，旨在迎合欧洲人的审美趣味，是土著技术和知识流传至今的典范。我们采用非侵入式和微侵入式技术，包括便携式 X 射线荧光光谱仪 (pXRF) 调查可能存在的无机颜料，以及光纤反射光谱仪 (FORS) 和反射成像光谱仪 (RIS)，提供着色剂的分子信息及其在器物上的分布情况，对其中五件巴尼斯德帕斯托器物进行了深入分析。此外，还使用拉曼光谱、傅立叶变换红外（FTIR）光谱和液相色谱/质谱（LC/MS）对染料和颜料进行了鉴定。傅立叶变换红外光谱和热解气相色谱/质谱法（Py-GC/MS）确定了树脂的性质，扫描电子显微镜与能量色散 X 射线光谱法（SEM-EDS）分析了装饰层和成分。本文证实了在两件以前未分析过的物品中使用了 mopa mopa（一种用于 barniz de Pasto 技术的树脂），并确定了靛蓝、昆虫红、甘汞、铅白和一种未知的黄酮醇基黄色染料，同时对使用甘汞作为这些作品的时间标记提出了质疑。总之，这些结果拓展了我们对这一时期艺术家使用材料和进行探索的理解，从而创造出如此精致和经久耐用的物品。
{"title":"Seventeenth-Century Barniz de Pasto Objects from the Collection of the Hispanic Society Museum & Library: Materiality and Technology","authors":"E. Basso, Alicia McGeachy, Maria Goretti Mieites Alonso, Federica Pozzi, Roxanne Radpour, Monica Katz","doi":"10.3390/heritage7050125","DOIUrl":"https://doi.org/10.3390/heritage7050125","url":null,"abstract":"The Hispanic Society Museum & Library (HSML) holds a collection of nine viceregal barniz de Pasto objects, made by Indigenous artisans in the 17th and 18th centuries. Designed to imitate Asian lacquers and intended for European aesthetic tastes, barniz de Pasto is an example of Indigenous technique and knowledge that has survived to the present day. An in-depth analysis of five of these barniz de Pasto objects, dated to the first half and last quarter of the 17th century based on their iconography, was carried out through a combination of non-invasive and micro-invasive techniques, including portable X-ray fluorescence (pXRF) spectroscopy to investigate the possible presence of inorganic pigments, and fiber-optics reflectance spectroscopy (FORS) and reflectance imaging spectroscopy (RIS) to provide molecular information on colorants and their distributions across the objects. Dyes and pigments were also identified using Raman spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, and liquid chromatography/mass spectrometry (LC/MS). The nature of the resin was determined by FTIR and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS), while the decoration stratigraphy and composition were analyzed by scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). This paper confirms the use of mopa mopa, the resin used in the barniz de Pasto technique, in two objects not previously analyzed, and identifies indigo, insect-based red, calomel, lead white, and an unknown flavonol-based yellow dye, and challenges the use of calomel as a temporal marker for these works. Taken together, these results expand our understanding of the material use and explorations undertaken by artists during this time period to create such elaborate and enduring objects.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141125448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Diego Tamburini, F. Sabatini, S. Berbers, Maarten R. van Bommel, Ilaria Degano
This article reviews the research recently undertaken to characterise and identify early synthetic dyes (ESDs) and synthetic organic pigments (SOPs) as well as study their degradation pathways with a focus on cultural heritage applications. Since the invention of the first fully synthetic dye in 1856, these materials have been used in a variety of historic objects and artworks, such as textiles, furniture, prints, paintings, drawings, etc. The synthesis of new dyes and their implementation into pigment formulations were rapid phenomena, so that by the beginning of the 20th century, thousands of new molecules were patented and commercialised. This review will focus on these early formulations synthesised up to approximately 1914 and the outbreak of World War I. ESDs and SOPs represent a challenge from an analytical point of view. Molecular databases are fundamental for the unequivocal identification of these compounds, but reference materials are not always readily available. A combination of analytical techniques is often needed for characterisation, especially in the case of SOPs, which have both organic and inorganic components. Furthermore, the degradation of these molecules can jeopardise their detection in historic objects that have been exposed to light, humidity and temperature fluctuations. Nevertheless, ESDs and SOPs are important research tools. As the dates of their first synthesis are often known with precision, based on patent information, their detection can be used to refine the production date of objects. Additionally, their trade from Europe to the world and their adoption in artistic practices around the globe is an active area of research.
{"title":"An Introduction and Recent Advances in the Analytical Study of Early Synthetic Dyes and Organic Pigments in Cultural Heritage","authors":"Diego Tamburini, F. Sabatini, S. Berbers, Maarten R. van Bommel, Ilaria Degano","doi":"10.3390/heritage7040094","DOIUrl":"https://doi.org/10.3390/heritage7040094","url":null,"abstract":"This article reviews the research recently undertaken to characterise and identify early synthetic dyes (ESDs) and synthetic organic pigments (SOPs) as well as study their degradation pathways with a focus on cultural heritage applications. Since the invention of the first fully synthetic dye in 1856, these materials have been used in a variety of historic objects and artworks, such as textiles, furniture, prints, paintings, drawings, etc. The synthesis of new dyes and their implementation into pigment formulations were rapid phenomena, so that by the beginning of the 20th century, thousands of new molecules were patented and commercialised. This review will focus on these early formulations synthesised up to approximately 1914 and the outbreak of World War I. ESDs and SOPs represent a challenge from an analytical point of view. Molecular databases are fundamental for the unequivocal identification of these compounds, but reference materials are not always readily available. A combination of analytical techniques is often needed for characterisation, especially in the case of SOPs, which have both organic and inorganic components. Furthermore, the degradation of these molecules can jeopardise their detection in historic objects that have been exposed to light, humidity and temperature fluctuations. Nevertheless, ESDs and SOPs are important research tools. As the dates of their first synthesis are often known with precision, based on patent information, their detection can be used to refine the production date of objects. Additionally, their trade from Europe to the world and their adoption in artistic practices around the globe is an active area of research.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140369351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vincent Gaffney, Rachel Harding, S. Fitch, James Walker, Victoria Boothby, Andrew Iain Fraser
Development of the continental shelf has accelerated significantly as nations around the world seek to harness offshore renewable energy. Many areas marked for development align with submerged palaeolandscapes. Poorly understood and difficult to protect, these vulnerable, prehistoric landscapes provide specific challenges for heritage management. Indeed, there now appears to be a schism between what underwater cultural heritage policy intends and what it is achieving in practice. Shortcomings in international and national legislature ensures that large parts of the continental shelf, including areas under development, may have little or no legal protection. Increasingly impacted by extensive development, these unique cultural landscapes are ever more at risk. However, heritage challenges posed by such development also create opportunities. An immense amount of data is being generated by development, and there is an opportunity to establish broader cooperative relationships involving industrial stakeholders, national curators, government bodies, and heritage professionals. As a matter of urgency, the archaeological community must better engage with the offshore sector and development process. If achieved, we may revolutionise our knowledge of submerged prehistoric settlement and land use. Otherwise, our capacity to reconstruct prehistoric settlement patterns, learn from past climate change, or simply manage what are among the best-preserved postglacial landscapes globally may be irreparably undermined.
{"title":"Winds of Change: Urgent Challenges and Emerging Opportunities in Submerged Prehistory, a Perspective from the North Sea","authors":"Vincent Gaffney, Rachel Harding, S. Fitch, James Walker, Victoria Boothby, Andrew Iain Fraser","doi":"10.3390/heritage7040093","DOIUrl":"https://doi.org/10.3390/heritage7040093","url":null,"abstract":"Development of the continental shelf has accelerated significantly as nations around the world seek to harness offshore renewable energy. Many areas marked for development align with submerged palaeolandscapes. Poorly understood and difficult to protect, these vulnerable, prehistoric landscapes provide specific challenges for heritage management. Indeed, there now appears to be a schism between what underwater cultural heritage policy intends and what it is achieving in practice. Shortcomings in international and national legislature ensures that large parts of the continental shelf, including areas under development, may have little or no legal protection. Increasingly impacted by extensive development, these unique cultural landscapes are ever more at risk. However, heritage challenges posed by such development also create opportunities. An immense amount of data is being generated by development, and there is an opportunity to establish broader cooperative relationships involving industrial stakeholders, national curators, government bodies, and heritage professionals. As a matter of urgency, the archaeological community must better engage with the offshore sector and development process. If achieved, we may revolutionise our knowledge of submerged prehistoric settlement and land use. Otherwise, our capacity to reconstruct prehistoric settlement patterns, learn from past climate change, or simply manage what are among the best-preserved postglacial landscapes globally may be irreparably undermined.","PeriodicalId":12934,"journal":{"name":"Heritage","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140370001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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