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Aging Characteristics of Ceramifiable Silicone Rubber Nanocomposites Exposed to Electrolytic Solution 陶瓷硅橡胶纳米复合材料在电解溶液中的老化特性
IF 3.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-03-06 DOI: 10.1109/TDEI.2025.3548973
Jatoth Varun;Palash Mishra;Addala Dharanish;Ayman El Hag;R. Sarathi;Mithun Mondal
The capability to transform into a flame-retardant ceramic body when encountering high temperatures makes low melting glass (LMG) powder an effective additive for room temperature vulcanized (RTV) silicone rubber composites, which are used as coating materials for outdoor high-voltage insulators operating in harsh environments. In this context, the present study examines the impact of nano LMG powder (LMGP) on the aging characteristics of 5 wt% boron nitride (BN)-doped silicone rubber nanocomposites exposed to a strong electrolytic aqueous ammonium chloride (NH4Cl) solution. LMG nanofiller was added in varying weight percentages of 3 and 7 wt%. Except for the 7 wt% LMG-doped composite, a distinct dip in weight gain, indicating higher degradation and detachment of filler particles, was noted in all the composites during diffusion test. Aging-induced deterioration of surface morphology is well evident in 3-D microscopy, contact angle, and Fourier transform infrared (FTIR) spectroscopic test results, which clearly demonstrate increased surface roughness and scissioning of side chains (Si-CH $_{{3}}text {)}$ and backbone chains (Si-O–Si) in silicone rubber matrix of all the composites postaging. Furthermore, antipollution performance and thermal properties of all the test specimens were evaluated through inclined plane tracking and erosion test, thermogravimetric analysis (TGA), and IR thermography. The test results demonstrated that LMG-doped composites showed better tracking and erosion resistance, higher thermal stability, and lower surface temperature distribution during inclined plane tracking (IPT) compared to the only BN specimen before and after aging. The experimental results revealed that the 7 wt% LMG composite exhibited better resistance to degradation caused by the NH4Cl solution.
低温玻璃(LMG)粉末在高温下可以转化为阻燃陶瓷体,这使得它成为室温硫化(RTV)硅橡胶复合材料的有效添加剂,用于在恶劣环境下工作的室外高压绝缘子的涂层材料。在此背景下,本研究考察了纳米LMG粉末(LMGP)对5wt %氮化硼(BN)掺杂硅橡胶纳米复合材料暴露于强电解氯化铵(NH4Cl)溶液中的老化特性的影响。以3 wt%和7 wt%的不同重量百分比加入LMG纳米填料。除了掺杂7wt % lmg的复合材料外,在扩散测试中,所有复合材料的重量增加都有明显的下降,这表明填料颗粒的降解和脱离程度更高。在三维显微镜、接触角和傅里叶变换红外(FTIR)光谱测试结果中,老化引起的表面形貌恶化非常明显,这清楚地表明,所有复合材料的表面粗糙度增加,硅橡胶基体中的侧链(Si-CH $_{{3}}text{)}$和主链(Si-O-Si)断裂。此外,通过斜面跟踪和侵蚀试验、热重分析(TGA)和红外热像仪对所有试样的抗污染性能和热性能进行了评价。实验结果表明,与单纯的BN试样相比,掺杂lmg的复合材料具有更好的跟踪和耐蚀性,更高的热稳定性和更低的表面温度分布。实验结果表明,7 wt% LMG复合材料具有较好的抗NH4Cl溶液降解性能。
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引用次数: 0
Lifespan Evaluation of HTV Silicone Rubber in Outdoor Composite Insulators Considering Temperature Cycling and Corona Discharge 考虑温度循环和电晕放电的HTV硅橡胶室外复合绝缘子寿命评价
IF 3.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-03-06 DOI: 10.1109/TDEI.2025.3567210
Shiyin Zeng;Wendong Li;Xin Zhao;Yanan Peng;Yuelin Liu;Xinyi Yan;Guanjun Zhang
The reliability of high-voltage overhead lines is strongly correlated to the status of outdoor insulators, which is correlated to the condition of high-temperature vulcanized silicone rubber (HTV-SR) used as insulator sheds. Current research pays attention to HTV-SR’s degradation under different environmental stresses (e.g., temperature and corona discharge). However, the lifetime assessment of the aged HTV-SR is unclear, and the effect of temperature cycling is seldom considered. In this study, a remaining useful lifetime (RUL) prediction method for HTV-SR is proposed, which considers both temperature cycling and corona discharge. Accelerated lifetime tests of HTV-SR are conducted, and the key parameters of the model are determined by the experimental data. Thus, a formula for quantitative RUL prediction is put forward, which indicates that when the cyclic temperature is $5.5~^{circ }$ C $sim 21.3~^{circ }$ C and the electric field strength at the sample surface is 4.5 and 6.8 kV/cm, the RUL with 90% reliability is 25.9 and 8.4 years. Furthermore, verification of the prediction model is conducted using the elongation at break of field-aged insulators with different operation times. This study provides a method to estimate the RUL of HTV-SR materials, which can guide the maintenance of outdoor insulators of power transmission lines.
高压架空线路的可靠性与室外绝缘子的状态密切相关,而室外绝缘子的状态又与高温硫化硅橡胶(hhtv - sr)用作绝缘子棚的状况有关。目前的研究重点是HTV-SR在不同环境应力(如温度和电晕放电)下的降解。然而,对HTV-SR的寿命评估尚不明确,且很少考虑温度循环的影响。在本研究中,提出了一种同时考虑温度循环和电晕放电的HTV-SR剩余使用寿命预测方法。对HTV-SR进行了加速寿命试验,并根据试验数据确定了模型的关键参数。由此,提出了RUL定量预测公式,当循环温度为$5.5~^{circ}$ C $ sim为21.3~^{circ}$ C,样品表面电场强度为4.5和6.8 kV/cm时,RUL的可靠性分别为25.9和8.4年。利用不同运行次数的现场老化绝缘子断裂伸长率对预测模型进行了验证。本研究提供了一种估算HTV-SR材料RUL的方法,可以指导输电线路室外绝缘子的维护。
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引用次数: 0
Ultrathin Films of Liquid Crystal Obtained via Organic Molecular Beam Deposition Method 有机分子束沉积法制备超薄液晶薄膜
IF 2.9 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-02-26 DOI: 10.1109/TDEI.2025.3546175
Anna Drzewicz;Michael Wübbenhorst
The miniaturization of devices causes an increase in scientists’ interest in the possibility of creating and characterizing ultrathin layers of liquid crystals. Using organic molecular beam deposition (OMBD), organic thin layers are produced in ultrahigh vacuum by single molecule deposition on a cold substrate. In this article, we verify the possibility of creating thin films of liquid crystal below the glass transition temperature by the OMBD method. We also investigated the effect of various OMBD deposition parameters on the layer thickness and the $alpha $ -relaxation dynamics of the compound under study. Some striking differences in relaxation dynamics related to glass-forming behavior are observed in ultrathin films compared to the bulk. We show that real time, in situ dielectric relaxation spectroscopy can be successfully applied to study the dynamic glass transition in geometric confinement, not only for simple glass-forming liquids but also for glass-forming liquid crystals using OMBD.
器件的小型化使科学家们对制造和表征超薄液晶层的可能性的兴趣增加。采用有机分子束沉积(OMBD)技术,在超高真空条件下在冷衬底上单分子沉积生成有机薄层。在本文中,我们验证了用OMBD方法在玻璃化转变温度以下制备液晶薄膜的可能性。我们还研究了不同的OMBD沉积参数对所研究化合物的层厚和$ α $弛豫动力学的影响。在超薄膜中,与大块相比,与玻璃形成行为有关的弛豫动力学有一些显著的差异。我们证明了实时、原位介电弛豫光谱可以成功地用于研究几何约束下的动态玻璃化转变,不仅适用于简单的玻璃化液体,也适用于使用OMBD的玻璃化液晶。
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引用次数: 0
Locating Water-Tree Degraded Cable Section by Measuring Residual Charges Induced by Voltage Pulse Wave 通过测量电压脉冲波产生的残余电荷定位水树退化电缆段
IF 3.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-02-24 DOI: 10.1109/TDEI.2025.3545010
May Thin Khaing;Koki Watanabe;Tatsuya Sakoda;Toru Takayama;Kazunori Miyazaki
A residual charge method is useful for measuring water tree in 22-kV crosslinked polyethylene (XLPE) cable systems. However, the conventional residual charge method cannot locate a water-tree degraded cable section because the time-resolved signal response from a water-tree degradation section cannot be obtained. In this study, we inject a sine wave pulse with a frequency of 1 MHz into measuring object cables when ac voltage is applied to the cables to release trapped charges due to the water-tree. We examine to locate a water-tree degraded cable section in 22-kV XLPE cable systems, including water-tree degraded cables and a Y-branch cable joint. The time-resolved residual charges induced by the voltage pulse induced by an injection coil (IJ coil) can locate a water-tree degraded cable section.
剩余电荷法可用于测量22kv交联聚乙烯(XLPE)电缆系统中的水树。然而,传统的剩余电荷法无法定位水树退化电缆段,因为无法获得水树退化电缆段的时间分辨信号响应。在本研究中,我们向测量对象电缆注入频率为1 MHz的正弦波脉冲,同时对电缆施加交流电压,以释放由于水树而被捕获的电荷。我们研究了在22kv交联聚乙烯电缆系统中定位水树退化电缆部分,包括水树退化电缆和y分支电缆接头。由注入线圈(IJ线圈)产生的电压脉冲产生的时间分辨残余电荷可以定位水树退化电缆段。
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引用次数: 0
Benzydamine-Loaded Casein Nanospheres Embedded in Polyelectrolyte Multilayers 聚电解质多层包埋的苯胺负载酪蛋白纳米球
IF 2.9 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-02-24 DOI: 10.1109/TDEI.2025.3542349
Asya Viraneva;Maria Marudova;Bissera Pilicheva;Aleksandar Grigorov;Nikolay Zahariev;Sofia Milenkova;Temenuzhka Yovcheva
Polyelectrolyte multilayers (PEMs) films containing benzydamine hydrochloride (Benz)-loaded casein nanoparticles are developed aiming to increase the structure drug loading efficiency and to prolong the drug release. The multilayers are built on biodegradable polyester substrates, which are previously charged in a corona discharge. Medium viscosity sodium alginate (SA) is used as a partner in the multilayer formulation. The SA and the casein nanoparticles are deposited on the substrate using the layer-by-layer (LbL) deposition technique. The drug loading efficiency and the release kinetics in artificial saliva are determined spectrophotometrically.
为了提高结构载药效率和延长药物释放时间,研制了含盐酸苄胺(Benz)纳米酪蛋白的聚电解质多层膜(PEMs)。多层材料是建立在可生物降解的聚酯基板上,在电晕放电中预先充电。中等粘度的海藻酸钠(SA)被用作多层配方中的合作伙伴。采用逐层沉积技术将SA和酪蛋白纳米颗粒沉积在衬底上。用分光光度法测定了该药物在人工唾液中的载药效率和释放动力学。
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引用次数: 0
A Method of Kernel Principal Component Analysis and Machine Learning Algorithms for Fault Diagnosis of Power Transformers 电力变压器故障诊断的核主成分分析与机器学习算法
IF 3.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-02-20 DOI: 10.1109/TDEI.2025.3543337
Zhou Li;Fanrong Wang
As one of the most important equipment in the power system, it is of great significance to conduct fault diagnosis research on transformers. Aiming at the problem of difficult selection of parameters for support vector machine (SVM) in transformer fault diagnosis, a fault diagnosis model based on the improved pelican optimization algorithm (IPOA) optimized SVM is proposed. First, the standard pelican optimization algorithm (POA) is enhanced by introducing the Tent chaotic mapping, Levy flight strategy, and adaptive weighting strategy, and the superiority of the IPOA algorithm is verified by comparing its performance with other intelligent algorithms across four test functions. Second, feature dimensionality reduction of the data samples is performed using kernel principal component analysis (KPCA), and the IPOA algorithm is used to optimize the SVM parameters and then establish the transformer fault diagnosis model based on IPOA-SVM. Finally, the POA-SVM, northern goshawk optimization (NGO)-SVM, GWO-SVM, whale optimization algorithm (WOA)-SVM, and particle swarm optimization (PSO)-SVM models are used to conduct comparative experiments with the proposed method. The results show that the diagnostic accuracy of the IPOA-SVM model reaches 95%, which is 3.75%, 5.0%, 6.25%, 7.5%, and 8.75% higher than that of the POA-SVM, NGO-SVM, GWO-SVM, WOA-SVM, and PSO-SVM diagnostic models, respectively; and the proposed model exhibits better stability and greater adaptability.
变压器作为电力系统中最重要的设备之一,对其进行故障诊断研究具有重要意义。针对支持向量机(SVM)在变压器故障诊断中参数选择困难的问题,提出了一种基于改进的鹈鹕优化算法(IPOA)优化支持向量机的故障诊断模型。首先,通过引入Tent混沌映射、Levy飞行策略和自适应加权策略,对标准鹈鹕优化算法(POA)进行了增强,并在四个测试功能上与其他智能算法进行性能比较,验证了IPOA算法的优越性。其次,利用核主成分分析(KPCA)对数据样本进行特征降维,并利用IPOA算法对SVM参数进行优化,建立基于IPOA-SVM的变压器故障诊断模型;最后,利用POA-SVM、北苍鹰优化(NGO)-SVM、GWO-SVM、鲸鱼优化算法(WOA)-SVM和粒子群优化(PSO)-SVM模型与所提方法进行对比实验。结果表明:IPOA-SVM模型的诊断准确率达到95%,分别比POA-SVM、NGO-SVM、GWO-SVM、WOA-SVM和PSO-SVM诊断模型高3.75%、5.0%、6.25%、7.5%和8.75%;该模型具有较好的稳定性和适应性。
{"title":"A Method of Kernel Principal Component Analysis and Machine Learning Algorithms for Fault Diagnosis of Power Transformers","authors":"Zhou Li;Fanrong Wang","doi":"10.1109/TDEI.2025.3543337","DOIUrl":"https://doi.org/10.1109/TDEI.2025.3543337","url":null,"abstract":"As one of the most important equipment in the power system, it is of great significance to conduct fault diagnosis research on transformers. Aiming at the problem of difficult selection of parameters for support vector machine (SVM) in transformer fault diagnosis, a fault diagnosis model based on the improved pelican optimization algorithm (IPOA) optimized SVM is proposed. First, the standard pelican optimization algorithm (POA) is enhanced by introducing the Tent chaotic mapping, Levy flight strategy, and adaptive weighting strategy, and the superiority of the IPOA algorithm is verified by comparing its performance with other intelligent algorithms across four test functions. Second, feature dimensionality reduction of the data samples is performed using kernel principal component analysis (KPCA), and the IPOA algorithm is used to optimize the SVM parameters and then establish the transformer fault diagnosis model based on IPOA-SVM. Finally, the POA-SVM, northern goshawk optimization (NGO)-SVM, GWO-SVM, whale optimization algorithm (WOA)-SVM, and particle swarm optimization (PSO)-SVM models are used to conduct comparative experiments with the proposed method. The results show that the diagnostic accuracy of the IPOA-SVM model reaches 95%, which is 3.75%, 5.0%, 6.25%, 7.5%, and 8.75% higher than that of the POA-SVM, NGO-SVM, GWO-SVM, WOA-SVM, and PSO-SVM diagnostic models, respectively; and the proposed model exhibits better stability and greater adaptability.","PeriodicalId":13247,"journal":{"name":"IEEE Transactions on Dielectrics and Electrical Insulation","volume":"32 5","pages":"3068-3077"},"PeriodicalIF":3.1,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145210034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Two-Dimensional Charge Characteristics in HVDC GIL Insulators: A Simulation Study 高压直流GIL绝缘子二维电荷特性的仿真研究
IF 3.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-02-20 DOI: 10.1109/TDEI.2025.3544165
Xi Pang;Peng Liu;Pengfei Zhang;Zongliang Xie;Tianlei Xu;Dingxin Wei;Zongren Peng
The long-term synergistic effects of high-voltage direct current (HVDC) and temperature gradients inevitably stimulate charge accumulation in gas-insulated transmission line (GIL) insulators, which significantly increases the risk of insulation failure. Due to the limitations in charge measurement techniques, it is crucial to develop effective methods for accurately simulating and evaluating the dynamic charge behaviors of GIL insulators under complex operating conditions. In this study, we present a 2-D bipolar charge transport and interaction (2-D BCTI) model that accounts for both space charge and surface charge dynamics. Such a model is employed to investigate the charge behaviors of HVDC GIL insulators under varying electric fields, polarization time, and voltage polarities. Our findings indicate that higher voltages and extended polarization time lead to increased charge migration and localized accumulation within the insulator. Further analysis reveals that the surface potential at the high-voltage terminal interface is predominantly influenced by the tangential current ( ${J}_{text {s}}$ ) along the insulator’s surface and bulky current ( ${J}_{text {v}}$ ) passing through the insulator. In other regions of the basin insulator, such as the shielding ring and grounding terminal, ${J}_{text {s}}$ is the dominant factor. This study provides valuable theoretical insights into the interaction between surface and space charge, offering a foundation for optimizing the insulation design of HVDC GIL systems.
高压直流(HVDC)和温度梯度的长期协同作用不可避免地刺激气体绝缘输电线路(GIL)绝缘子中的电荷积累,从而显著增加绝缘失效的风险。由于电荷测量技术的局限性,开发有效的方法来准确模拟和评估GIL绝缘子在复杂工作条件下的动态电荷行为是至关重要的。在这项研究中,我们提出了一个二维双极电荷传输和相互作用(二维BCTI)模型,该模型同时考虑了空间电荷和表面电荷动力学。利用该模型研究了高压直流GIL绝缘子在不同电场、极化时间和电压极性下的电荷行为。我们的研究结果表明,较高的电压和延长的极化时间导致绝缘体内电荷迁移和局部积累增加。进一步分析表明,高压端子界面处的表面电位主要受沿绝缘子表面的切向电流(${J}_{text {s}}$)和通过绝缘子的大电流(${J}_{text {v}}$)的影响。在盆绝缘子的其他区域,如屏蔽环和接地端子,${J}_{text {s}}$是主导因素。该研究为研究表面电荷与空间电荷之间的相互作用提供了有价值的理论见解,为优化高压直流GIL系统的绝缘设计提供了基础。
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引用次数: 0
A Methodology for Accelerated Thermal Aging of an Automotive Hairpin Stator 汽车发夹定子加速热老化方法研究
IF 3.1 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-02-19 DOI: 10.1109/TDEI.2025.3543806
Juan M. Gonzalez;Leon K. Rodrigues;Filippos Beza-Florentin;Claudiu Butnaru;Mariusz Mikula;Ana Neves;João V. Sarrico
This study presents a comprehensive exploration of the thermal aging of hairpin stators from a newly commissioned assembly line, tailored for automotive applications. The novelties in this article include a methodological approach that preserves material and process representativeness by testing stators directly from production. To increase sample size and stress the turn-to-turn failure mode, the star point connection is removed. Accelerated thermal aging is achieved by selecting the most aggressive set of temperatures, and expediting thermal index (TI) calculations without compromising accuracy. A detailed examination of the control parameters in the diagnostic sub-cycle is undertaken, including visual inspection, withstand voltage, capacitance, and step-by-step (SBS) impulse test with partial discharge inception voltage detection. Winding capacitance emerges as a crucial variable for tracking sample degradation, with its aging trend influenced by the measurement voltage. The introduction of the Physics of Failure (PoF) prompts an investigation into the impregnation resin as a potential factor contributing to the relatively low attained TI. The fault isolation process is generalized in a flowchart applicable to various motor types, extending its utility beyond the automotive domain.
这项研究提出了一个全面的探索发夹定子的热老化,从一个新委托的装配线,专门为汽车应用。本文的新颖之处包括一种方法方法,通过直接从生产中测试定子来保持材料和工艺的代表性。为了增加样本量并强调匝间失效模式,星点连接被移除。通过选择最激进的温度,加速热老化,加速热指数(TI)的计算,而不影响精度。对诊断子周期中的控制参数进行了详细的检查,包括目视检查、耐压、电容和逐步(SBS)脉冲试验,其中包括局部放电起始电压检测。绕组电容是跟踪样品退化的关键变量,其老化趋势受测量电压的影响。失效物理(PoF)的引入促使人们对浸渍树脂作为导致TI相对较低的潜在因素进行了研究。故障隔离过程被概括成一个适用于各种电机类型的流程图,将其应用范围扩展到汽车领域之外。
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引用次数: 0
Characteristic of Surface Streamer Discharge Under the AC–DC Composite Voltage 交直流复合电压下表面流线型放电特性研究
IF 2.9 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-02-19 DOI: 10.1109/TDEI.2025.3543792
Xiaobo Meng;Lin Lin;Hao Li;Hongwei Mei;Liming Wang
The external insulation of the equipment in the valve hall of ultra high voltage (UHV) dc converter station must be able to withstand ac-dc combined voltage influences. Investigating the surface discharge characteristics of external insulation under ac-dc combined voltage is currently a significant research topic. The investigation into the surface streamer characteristics under ac-dc combined voltage is instrumental in elucidating the mechanism of surface flashover. The streamer characteristics of different phases in a single cycle under ac-dc combined voltage were determined by conducting surface streamer discharge tests. The relationship between surface streamer characteristics and different phases under ac-dc combined voltage was summarized. By comparing the test results of surface streamer discharge under dc voltage, this study analyzed the effect mechanism of ac-dc combined voltage on surface streamer characteristics. The directional motion of space charge under ac-dc combined voltage was identified as the primary determinant of surface streamer characteristics.
特高压直流换流站阀厅内设备的外绝缘必须能够承受交直流组合电压的影响。研究交直流复合电压下外绝缘的表面放电特性是当前一个重要的研究课题。研究交直流复合电压作用下的表面闪络特性,有助于阐明表面闪络的机理。通过表面流光放电试验,确定了交直流复合电压下单周期内不同相位的流光特性。总结了交直流复合电压下表面流光特性与不同相位的关系。通过对比直流电压下表面流线型放电试验结果,分析交直流组合电压对表面流线型特性的影响机理。交直流复合电压作用下空间电荷的定向运动是影响表面流光特性的主要因素。
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引用次数: 0
Mechanisms for DC Breakdown Strength Degradation in Epoxy/Glass Fiber Composites Under Long-Term Aging 环氧/玻璃纤维复合材料长期老化下直流击穿强度下降的机理
IF 2.9 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-02-19 DOI: 10.1109/TDEI.2025.3543794
Ji Liu;Pengfei Wang;Chao Zhang;Zuning Huang;Longfei Zhang;Zhen Li
In modern power systems, the proportion of epoxy/glass fiber (EP/GF) composites that served as the primary insulation composites in electrical equipment is steadily increasing. These devices suffer long-term electrical, thermal, and vibrational stresses during operation, leading to degradation and finally insulation failures. However, the underlying electrical-thermal–vibrational aging mechanisms of the dc breakdown performance of EP/GF composites remain unclear. In this work, combined electrical-thermal–vibrational aging experiments (1080 h) were performed on the prepared EP/GF composites. Infrared spectrum, dielectric spectrum, surface potential decay (SPD), and breakdown tests were used to characterize the functional groups, side-chain dynamics, trap levels, and dc breakdown strength of aged EP/GF composites. The research indicates that after long-term aging, the dc breakdown strength of EP/GF composites first increases by 5.8% at 72 h and then decreases by 20.6% at 1080 h. The aging of EP/GF composites is divided into recrosslinking and degradation stages. The recrosslinking stage enhances the dc breakdown strength of the EP/GF composites by reducing free volume before 72 h. While in the degradation stage, chain breaking and oxidation of epoxy chains steadily occur, introducing abundant short chains and polar groups (carbonyl and ester groups), improving free volume fraction, and accelerating chains’ dynamic. The improved free volume fraction accelerates electron avalanche in the electric field, stimulating charges to escape from traps and causing dc breakdown strength to considerably decrease during 72–1080 h.
在现代电力系统中,环氧/玻璃纤维(EP/GF)复合材料作为主要绝缘材料在电气设备中的比例正在稳步增加。这些设备在运行过程中承受长期的电、热、振动应力,导致性能退化,最终导致绝缘失效。然而,EP/GF复合材料直流击穿性能的电-热-振动老化机制尚不清楚。对制备的EP/GF复合材料进行了1080 h的电-热-振动复合时效实验。利用红外光谱、介电光谱、表面电位衰减(SPD)和击穿测试表征老化EP/GF复合材料的官能团、侧链动力学、陷阱能级和直流击穿强度。研究表明,EP/GF复合材料的直流击穿强度在72 h时先提高5.8%,在1080 h时下降20.6%,EP/GF复合材料的老化过程分为重交联和降解两个阶段。重交联阶段通过减少72 h前的自由体积,提高了EP/GF复合材料的直流击穿强度。降解阶段,环氧链的断链和氧化稳定发生,引入了大量的短链和极性基团(羰基和酯基),提高了自由体积分数,加速了链的动态变化。自由体积分数的提高加速了电场中的电子雪崩,刺激电荷从陷阱中逸出,导致直流击穿强度在72 ~ 1080 h内显著降低。
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引用次数: 0
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