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Unleashing the Casual Impact of House Prices on Air Quality: Evidence from Chinese Cities 释放房价对空气质量的偶然影响:来自中国城市的证据
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-08-30 DOI: 10.1155/2023/1338261
B. Zeng, S. Fahad, Gang Wang, A. Nassani, Rima H. Binsaeed
With the rapid development of the real estate industry in China, urban air quality is inevitably affected. By using data of Chinese cities located in the Yangtze River Delta from 2009 to 2018, this paper is aim at examining the casual impact of house prices on air quality. By considering the endogenous problems, in this study, first, the birth rate of the previous six years and the area of state-owned land supply per capita in the previous year are taken as instrumental variables of house price. Second, the two-stage least squares method is used to assess the causal impact of house price on air quality. The findings of this study show that there is no significant relationship between urban house prices and air quality, and these results are obtained without considering the endogenous problem. While, after considering the endogenous problem, urban house prices showed a significant negative effect on overall air quality, especially for low administrative level cities. The increase in house prices has hindered the improvement of air quality mainly through the blind-scale expansion of real estate development investments and the inhibitory effect of innovation.
随着中国房地产业的快速发展,城市空气质量不可避免地受到影响。本文利用2009年至2018年中国长三角城市的数据,旨在研究房价对空气质量的随机影响。考虑到内生问题,本研究首先将前六年的出生率和前一年人均国有土地供应面积作为房价的工具变量。其次,采用两阶段最小二乘法评估房价对空气质量的因果影响。本文的研究结果表明,城市房价与空气质量之间不存在显著的关系,并且这些结果是在没有考虑内生问题的情况下得出的。而考虑内生问题后,城市房价对整体空气质量呈现显著的负向影响,尤其是对低行政级别城市。房价上涨主要通过房地产开发投资的盲目规模扩张和创新的抑制作用阻碍了空气质量的改善。
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引用次数: 0
Evidence of Unrecognized Indoor Exposure to Toxic Chlorophenols and Odorous Chloroanisoles in Denmark, Finland, and Norway 丹麦、芬兰和挪威室内暴露于有毒氯酚和有气味氯苯甲醚的证据
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-08-28 DOI: 10.1155/2023/2585089
J. Lorentzen, Lars-Erik Harderup, G. Johanson
Production and use of chlorophenols (CPs) are being phased out around the globe, but with considerable lag in some highly populated countries. The process could be incentivized by leading countries sharing their experiences on problems that occurred, including the built environment. We previously reported that Swedish industry and authorities promoted CPs, including pentachlorophenol (PCP), as wood preservatives in buildings for decades. Yet, Swedish indoor research did not recognize exposure to the hazardous CPs and their odor potent derivatives, the chloroanisoles (CAs), which smell like mold and still evolve from legacy preservatives in damp building structures. We hypothesized that the toxic CPs and odorous CAs could be key players for health and odor problems not only in Sweden but also in the neighboring Nordic countries. We found no reports in scientific medical literature of CPs being used in buildings in these countries. However, grey literature shows that CPs were indeed used, even during building booms, in house exteriors, constructions, and interiors, from the 1950s up to the late 1970s (Denmark) and even the 1990s (Finland and Norway). One application of CPs was in houses erected on dampness-prone house foundations, conditions ideal for formation of odorous CAs through microbial methylation. Furthermore, our searches suggest that these problematic chemicals played hitherto unrecognized key roles when indoor air research evolved. Thus, odor became an important aspect of the “sick building syndrome” in Denmark and an early warning sign of health risks in Finland, as asthma and allergy were attributed to “dampness and mold.” None of the countries addressed the possible links between odor and health effects and exposure to CAs and CPs. In conclusion, our results suggest that unrecognized indoor exposure to toxic CPs and odorous CAs has mislead Nordic indoor air research for decades.
氯酚的生产和使用正在全球范围内逐步淘汰,但在一些人口稠密的国家存在相当大的滞后。这一进程可以通过主要国家分享他们在发生的问题上的经验来激励,包括建筑环境。我们之前报道过,瑞典工业和当局几十年来一直在推广CPs,包括五氯酚(PCP),作为建筑物中的木材防腐剂。然而,瑞典的室内研究并没有发现暴露于有害的氯化石蜡及其气味强的衍生物氯苯甲醚(CAs)中,氯苯甲醚闻起来像霉菌,仍然是从潮湿建筑结构中的遗留防腐剂演变而来的。我们假设有毒的氯化石蜡和有气味的氯化石蜡不仅在瑞典而且在邻近的北欧国家都可能是健康和气味问题的关键因素。我们在科学医学文献中没有发现在这些国家的建筑物中使用cp的报告。然而,灰色文献表明,从20世纪50年代到70年代末(丹麦)甚至90年代(芬兰和挪威),即使在建筑繁荣时期,CPs也确实被用于房屋的外部、建筑和内部。CPs的一个应用是在容易受潮的房屋基础上建造的房屋,这是通过微生物甲基化形成有气味的CAs的理想条件。此外,我们的研究表明,这些有问题的化学物质在室内空气研究的发展过程中发挥了迄今为止未被认识到的关键作用。因此,在丹麦,气味成为“病态建筑综合症”的一个重要方面,在芬兰,气味是健康风险的早期预警信号,因为哮喘和过敏被归因于“潮湿和发霉”。没有一个国家涉及气味和健康影响与接触氯化碳和氯化碳之间的可能联系。总之,我们的研究结果表明,几十年来,未被认识到的室内暴露于有毒的CPs和有气味的CAs误导了北欧室内空气研究。
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引用次数: 0
Assessment of Nicotine Degradation in Cigarette Smoke under Different Storage Conditions (Light and Duration) 不同贮存条件(光照和贮存时间)下卷烟烟气中尼古丁降解的评价
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-08-17 DOI: 10.1155/2023/8814709
Young-Ji An, Yong-Hyun Kim
Nicotine, the primary component of cigarette smoke, is not only addictive but also indirectly contributes to lung diseases by increasing heart rate and blood pressure upon inhalation. Therefore, managing nicotine content in cigarette smoke necessitates accurate quantitative analysis. Nicotine from cigarette smoke is collected using a Cambridge filter, subjected to solvent extraction, and analyzed using instrumental techniques. However, since nicotine is susceptible to light-induced oxidation, losses may occur during pretreatment, reducing result reliability. This study assesses nicotine loss under various lighting conditions and storage durations. Nicotine collected in Cambridge filters is exposed to dark, visible radiation, and UV radiation (254 nm) for different time intervals (0–48 h), and the nicotine content is analyzed and compared. In dark conditions, a 1.6% decline in nicotine concentration occurs after 48 h. With visible radiation, a 9% reduction is observed, while under UV exposure, the concentration decreases by 16.9%. The UV radiation-associated decrease in nicotine concentration is −0.335% h−1, exhibiting strong linearity ( R 2 = 0.9465 ). Consequently, significant nicotine loss in Cambridge filter-collected samples is influenced by storage duration and lighting conditions. This study’s findings can enhance the accuracy of nicotine quantification in cigarette smoke, thereby improving the understanding of nicotine’s harmful effects in cigarette smoke.
尼古丁是香烟烟雾的主要成分,不仅会使人上瘾,而且吸入后会增加心率和血压,从而间接导致肺部疾病。因此,控制香烟烟雾中的尼古丁含量需要精确的定量分析。香烟烟雾中的尼古丁使用剑桥过滤器收集,经过溶剂萃取,并使用仪器技术进行分析。然而,由于尼古丁易受光诱导氧化,在预处理过程中可能会发生损失,从而降低结果的可靠性。本研究评估了尼古丁在不同光照条件和储存时间下的损失。在不同的时间间隔(0-48 h)下,将Cambridge过滤嘴中收集的尼古丁分别暴露在暗光、可见光和254 nm的紫外线下,分析和比较尼古丁的含量。在黑暗条件下,48小时后尼古丁浓度下降1.6%。在可见光照射下,浓度下降9%,而在紫外线照射下,浓度下降16.9%。与紫外线辐射相关的尼古丁浓度下降为- 0.35% h - 1,呈强线性关系(r2 = 0.9465)。因此,剑桥过滤器收集的样品中尼古丁的显著损失受到储存时间和光照条件的影响。本研究的发现可以提高香烟烟雾中尼古丁定量的准确性,从而提高对香烟烟雾中尼古丁有害影响的认识。
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引用次数: 0
Using Low-Cost Sensing Technology to Assess Ambient and Indoor Fine Particulate Matter Concentrations in New York during the COVID-19 Lockdown 利用低成本传感技术评估新冠肺炎封锁期间纽约环境和室内细颗粒物浓度
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-08-16 DOI: 10.3390/air1030015
Justin Holder, Jamelia Jordan, K. Johnson, A. Akinremi, D. Roberts-Semple
Air pollution is a leading cause of death in the United States and is associated with adverse health outcomes, including increased vulnerability to coronavirus disease 2019 (COVID-19). The AirBeam2 was used to measure particulate matter with a diameter of 2.5 μm or smaller (PM2.5) to investigate differences between indoor and ambient levels at seven private homes in New York during and after the COVID-19 lockdown. Measurements taken in 2020 fall, 2021 winter, and 2022 fall showed that at 90% of the sites, indoor PM2.5 levels exceeded outdoor levels both during and after the COVID-19 lockdown, p = 0.03, possibly exceeding safety levels. Higher indoor PM2.5 levels attributed to little or no ventilation in the basement and kitchens from cooking and smoke were greater in fall than in winter. Higher ambient PM2.5 levels were attributed to vehicular traffic at a street-facing sampling site. PM2.5 sources identified in this study may help in devising control strategies to improve indoor air quality (IAQ) and consequently alleviate respiratory health effects. These findings may be used as a basis for in-house modifications, including natural ventilation and the use of air purifiers to reduce exposures, mitigate future risks, and prevent potential harm to vulnerable residents.
在美国,空气污染是导致死亡的主要原因之一,并与不良健康结果有关,包括更容易感染2019年冠状病毒病(COVID-19)。AirBeam2用于测量直径小于2.5 μm的颗粒物(PM2.5),以调查纽约7个私人住宅在新冠肺炎封锁期间和之后室内和环境水平的差异。在2020年秋季、2021年冬季和2022年秋季进行的测量显示,在90%的地点,在COVID-19封锁期间和之后,室内PM2.5水平都超过了室外水平,p = 0.03,可能超过了安全水平。由于地下室和厨房很少或没有通风,做饭和冒烟,室内PM2.5水平在秋季高于冬季。在一个面向街道的采样点,较高的环境PM2.5水平归因于车辆交通。本研究确定的PM2.5来源可能有助于制定控制策略,以改善室内空气质量(IAQ),从而减轻呼吸道健康影响。这些发现可以作为室内改造的基础,包括自然通风和使用空气净化器,以减少暴露,减轻未来的风险,并防止对脆弱居民的潜在伤害。
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引用次数: 0
Experimental Study of the TVOC Distribution in a Car Cabin 汽车舱内挥发性有机化合物分布的实验研究
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-08-09 DOI: 10.3390/air1030014
Nadir Hafs, Mokhtar Djeddou, A. Benabed, G. Fokoua, A. Mehel
The vehicle in-cabin is subject to several types of pollutants infiltrating from the outdoors or emitted directly inside it, such as Volatile Organic Compounds (VOCs). The concentration of TVOC (total volatile organic compounds) is the result of the emission from different equipment surfaces that compose the car cabin. In the present study, the experimental characterization of TVOC emission from the interior surfaces of a car cabin is discussed by considering the influence of two parameters: the temperature and ventilation modes. A measurement location grid was used to measure TVOC’s emissions from 267 points on all surfaces of the car’s interior equipment. Three different temperatures and two ventilation modes (recirculation and outdoor air) were investigated. The results indicate that the concentration of TVOC increases with the temperature inside the cabin with a contribution that varies with the type of cabin equipment including the dashboard, center console, seats, and carpets. On the other hand, the concentration distributions of TVOC showed relative differences of 10–13% and 2–5% for surface and volumetric measurements, respectively. This implies no preferential positioning of the in-cabin probe for TVOC volumetric concentration measurements. In addition, the recirculation ventilation mode results in a higher accumulation of TVOC; therefore, higher concentrations are measured.
车内的车辆会受到从室外渗透或直接在车内排放的几种污染物的影响,例如挥发性有机化合物(VOCs)。TVOC(总挥发性有机化合物)的浓度是由组成车厢的不同设备表面排放的结果。在本研究中,通过考虑温度和通风方式两个参数的影响,讨论了汽车舱室内表面TVOC排放的实验表征。测量位置网格用于测量汽车内部设备所有表面上267个点的TVOC排放。研究了三种不同的温度和两种通风模式(再循环和室外空气)。结果表明,TVOC浓度随客舱内温度升高而升高,且随客舱设备类型(仪表盘、中控台、座椅和地毯)的不同而变化。另一方面,在表面和体积测量中,TVOC浓度分布的相对差异分别为10-13%和2-5%。这意味着机舱内探头对于TVOC体积浓度测量没有优先定位。此外,再循环通风方式导致TVOC积累较高;因此,测量到更高的浓度。
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引用次数: 0
Application of Data-Driven Building Information Modeling in the Visual Simulation of Disease Transmission and Route with Pipeline System 数据驱动的建筑信息模型在管道系统疾病传播路径可视化仿真中的应用
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-08-08 DOI: 10.1155/2023/7068735
Chen-Yu Pan, H. Hsu, Ko-Wei Huang, Ya-Hua Lin
Currently, preventing epidemics is an extremely critical global topic. Using present data to quickly conduct virus simulations is a difficult but interesting problem, especially when real situations are difficult to experimentally demonstrate. In the past, most studies have used package software for disease transmission simulation, but this approach is limited by availability and software cost. Therefore, we propose a visual simulation of disease transmission using building information modeling data and a 3D model using Unity. The results show that the proposed method can effectively predict the probability and route of disease transmission; it also verifies that the vertical pipeline on the floor plane is conducive to the spread of the virus (90%), and disease transmission on the plane gradually expands outward from the starting room and has a higher probability of spreading (80%) from the opposite room. In addition, a vertical pipeline was simulated using a toilet exhaust air ventilation pipeline, from which it can be observed that the adjacent floors have a higher diffusion probability (70%). It has also been confirmed that distance is the primary factor affecting disease transmission. This framework may provide designers and managers further protection against the spread of future epidemics.
当前,预防流行病是一个极其重要的全球性课题。利用现有数据快速进行病毒模拟是一个困难但有趣的问题,特别是当真实情况难以通过实验证明时。过去的研究大多采用软件包软件进行疾病传播模拟,但这种方法受到可用性和软件成本的限制。因此,我们建议使用建筑信息建模数据和使用Unity的3D模型来可视化模拟疾病传播。结果表明,该方法能有效预测疾病传播的概率和途径;也验证了地板平面上的垂直管道有利于病毒的传播(90%),平面上的疾病传播从起始房间逐渐向外扩展,从对面房间传播的概率更高(80%)。另外,使用厕所排风通风管道模拟垂直管道,可以看出相邻楼层具有更高的扩散概率(70%)。距离也是影响疾病传播的主要因素。这个框架可以为设计人员和管理人员提供进一步的保护,防止未来流行病的蔓延。
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引用次数: 0
Effects of Ionization on the Filtration of Fine and Ultrafine Particles in Indoor Air 电离对室内空气中细、超细颗粒物过滤的影响
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-07-29 DOI: 10.1155/2023/6359137
Pranav Muthukrishnan, F. Farahi
As we spend approximately 80% of our time indoors, improving indoor air quality is necessary to lessen the spread and impacts of respiratory diseases and other health issues caused by particle pollution. Currently, in many countries, the primary method of cleaning indoor air is by using better, higher-grade filters in a recirculating air system or increasing ventilation with outdoor air. One way to supplement these time-tested approaches is by implementing ionization. We used a bipolar ionizer to test the removal efficiency of filters on different particle sizes with and without ionization. Calibrated cigarettes were used to generate smoke into a 28-cubic-meter chamber with a recirculating air handling system. It was found that ionization had a 275% increase in the removal efficiency of the most penetrating particle sizes (100-500 nm). We conclude that ionization drastically improves the filter removal efficiency of fine and ultrafine particles in indoor environments.
由于我们大约80%的时间是在室内度过的,改善室内空气质量对于减少呼吸系统疾病的传播和影响以及由颗粒污染引起的其他健康问题是必要的。目前,在许多国家,清洁室内空气的主要方法是在再循环空气系统中使用更好、等级更高的过滤器或增加室外空气的通风。对这些久经考验的方法进行补充的一种方法是实施电离。我们使用双极电离器来测试不同粒径的过滤器在电离和不电离的情况下的去除效率。经过校准的香烟被用来在一个28立方米的房间里产生烟雾,房间里有一个循环空气处理系统。结果表明,对于穿透性最强的粒径(100 ~ 500 nm),离子处理的去除率提高了275%。我们得出结论,电离大大提高了室内环境中细颗粒和超细颗粒的过滤器去除效率。
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引用次数: 0
Di-(2-Ethylhexyl) Phthalate (DEHP) in House Dust in Canadian Homes: Behaviors and Associations with Housing Characteristics and Consumer Products 二-(2-乙基己基)邻苯二甲酸酯(DEHP)在加拿大家庭的室内灰尘:行为和关联的住房特点和消费产品
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-07-25 DOI: 10.1155/2023/4655289
Luyao Zhang, G. Navaranjan, T. Takaro, S. Bernstein, L. Jantunen, W. Lou, P. Mandhane, T. Moraes, J. Scott, E. Simons, S. Turvey, P. Subbarao, J. Brook
Background. Di-(2-ethylhexyl) phthalate (DEHP), which is ubiquitous in indoor environments, was the predominant phthalate measured in house dust in the Canadian CHILD Cohort and was found to be associated with a large increased risk of childhood asthma. Objective. To inform interventions by identifying sources of DEHP in dust and assessing behaviors related to DEHP concentrations in house dust. Methods. DEHP levels were measured in 726 dust samples collected at ~3 months of age in CHILD as well as in ~50 homes at two time points (June and November) in the CHILD pilot study. DEHP metabolites were measured in urine for a subset of the ~3-month-old infants. Housing characteristics were assessed at the time of dust and urine collection. Numerous factors from these surveys were investigated as potential sources of DEHP using univariate analyses and multivariable regressions. Correlations between DEHP in dust and urinary metabolites and between repeat dust samples were examined to study the relationship between dust measurement and DEHP exposure. Results. Overall, DEHP dust concentrations were higher for lower-income families. Homes with vinyl flooring in the kitchen and bathroom showed higher levels of DEHP than those without vinyl flooring. The quantity of vinyl furniture and the presence of mold were associated with higher DEHP concentrations, while the use of mattress covers reduced concentration. No other significant associations were found. DEHP concentrations in dust were consistent over 6 months, although the correlation between dust and DEHP metabolites in urine was low. Conclusion. DEHP in house dust persisted over multiple months, contributed to infant internal exposure, and was associated with specific housing characteristics. These findings may inform the public on their choice of building materials and products, as well as future policies, aimed at reducing the health risk associated with exposures in the indoor environment especially for children.
背景。二-(2-乙基己基)邻苯二甲酸酯(DEHP)在室内环境中普遍存在,是加拿大儿童队列中房屋灰尘中测量到的主要邻苯二甲酸酯,并被发现与儿童哮喘风险的大幅增加有关。目标。通过确定粉尘中DEHP的来源和评估与室内粉尘中DEHP浓度相关的行为,为干预措施提供信息。方法。在CHILD试点研究中,在两个时间点(6月和11月)对儿童3个月大时和50个家庭中收集的726份粉尘样本进行了DEHP水平测量。在约3个月大的婴儿的尿液中测量DEHP代谢物。在收集灰尘和尿液时评估住房特征。通过单变量分析和多变量回归,研究了这些调查中的许多因素作为DEHP的潜在来源。研究了粉尘中DEHP与尿代谢物以及重复粉尘样品之间的相关性,以研究粉尘测量与DEHP暴露之间的关系。结果。总体而言,低收入家庭的DEHP粉尘浓度较高。厨房和浴室铺有乙烯基地板的家庭比没有乙烯基地板的家庭显示出更高的DEHP水平。乙烯基家具的数量和霉菌的存在与较高的DEHP浓度有关,而床垫套的使用降低了浓度。没有发现其他显著的关联。灰尘中的DEHP浓度在6个月内保持一致,尽管灰尘与尿液中DEHP代谢物之间的相关性很低。结论。房屋灰尘中的DEHP持续数月,导致婴儿内部暴露,并与特定的房屋特征有关。这些调查结果可能会告知公众如何选择建筑材料和产品,以及未来的政策,旨在减少与室内环境暴露有关的健康风险,特别是对儿童而言。
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引用次数: 0
Molecular Characteristics, Sources, and Health Risk Assessment of Gaseous Carbonyl Compounds in Residential Indoor and Outdoor Environments in a Megacity of Northwest China 西北特大城市住宅室内外环境中气态羰基化合物的分子特征、来源及健康风险评价
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-07-25 DOI: 10.1155/2023/7769354
Lu Li, W. Dai, M. Shen, Xinyi Niu, Tafeng Hu, Jing Duan, Junjie Cao, Zhenxing Shen, K. Ho, J. Li
Carbonyl compounds (CCs) in indoor air pose a significant threat to residents’ health and have garnered considerable attention in recent years. However, most studies have focused on low-molecular-weight carbonyl compounds (LMW-CCs) and have underestimated the impact of high-molecular-weight ones (HMW-CCs), causing a failure to comprehensively understand their effects on health. In this study, we analyzed twenty carbonyls in the indoor and outdoor air at typical residential communities in a megacity in Northwest China by using high-performance liquid chromatography (HPLC) coupled with a photodiode array detector (DAD). The total concentration of indoor carbonyls was 1.4-3.4 times that of outdoor carbonyls. In addition, the concentration of indoor carbonyls was much higher during the heating season than that during the nonheating season. Conversely, the concentration of outdoor carbonyls was higher during the nonheating season than that during the heating season. The principal component analysis (PCA) revealed that indoor carbonyl pollution was primarily influenced by building materials, cooking fume, and wooden furniture. Formaldehyde exposure in indoor environments posed a greater health risk to children than acetaldehyde exposure. HMW-CCs were the primary contributors to indoor odor pollution, which was considered a significant cause of sick building syndrome (SBS). Our findings underscore the crucial role of HMW-CCs in indoor environments in exerting adverse impacts on health.
室内空气中的羰基化合物对居民健康构成严重威胁,近年来引起了人们的广泛关注。然而,大多数研究都集中在低分子量羰基化合物(lmw - cc)上,低估了高分子量羰基化合物(hmw - cc)的影响,导致未能全面了解它们对健康的影响。本研究采用高效液相色谱法(HPLC)结合光电二极管阵列检测器(DAD)对西北某特大城市典型住宅小区室内和室外空气中的20种羰基进行了分析。室内羰基的总浓度是室外羰基的1.4 ~ 3.4倍。此外,采暖季室内羰基浓度明显高于非采暖季。相反,非采暖季室外羰基浓度高于采暖季。主成分分析表明,室内羰基污染主要受建筑材料、烹饪油烟和木制家具的影响。室内环境中的甲醛暴露比乙醛暴露对儿童的健康风险更大。hmw - cc是室内气味污染的主要来源,被认为是病态建筑综合征(SBS)的重要原因。我们的研究结果强调了室内环境中hmw - cc对健康产生不利影响的关键作用。
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引用次数: 0
Investigation of CO2-Sorption Characteristics of Readily Available Solid Materials for Indoor Direct Air Capturing 室内直接捕风固体材料对co2吸附特性的研究
IF 5.8 2区 环境科学与生态学 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2023-07-14 DOI: 10.1155/2023/8821044
Lukas Baus, S. Nehr, Nobutaka Maeda
Direct air capturing (DAC) is an energy demanding process for CO2-removal from air. Ongoing research focuses on the potential of indoor air as DAC-feed to profit from currently unused energetic synergies between DAC and the built environment. In this work, we investigated the performance of three different readily available, solid DAC-adsorbers under typical indoor environmental conditions of 16-25°C, 25-60% relative humidity (RH), and CO2-concentrations of less than 800 ppm above atmospheric concentrations. The measured mass-specific CO2-adsorption capacities of K2CO3-impregnated activated carbon, polyethylenimine-snow (PEI-snow), and polyethylenimine (PEI) on silica amount to 6.5 ± 0.3   mg   g − 1 , 52.9 ± 4.9   mg   g − 1 , and 56.9 ± 4.2   mg   g − 1 , respectively. Among the three investigated adsorber materials, PEI on silica is the most promising candidate for DAC-applications as its synthesis is rather simple, the CO2-desorption is feasible at moderate conditions of about 80°C at 100 mbar, and the competing co-adsorption of water does not strongly affect the CO2-adsorption under the investigated experimental conditions.
直接空气捕获(DAC)是从空气中去除二氧化碳的耗能过程。正在进行的研究侧重于室内空气作为DAC馈源的潜力,以从DAC和建筑环境之间目前未使用的能量协同效应中获利。在这项工作中,我们研究了三种不同的现成的固体dac吸附剂在典型的室内环境条件下的性能:16-25°C, 25-60%相对湿度(RH), co2浓度低于大气浓度800ppm。k2co3浸渍活性炭、聚乙烯亚胺-雪(PEI-snow)和聚乙烯亚胺(PEI)在二氧化硅上的吸附量分别为6.5±0.3 mg g−1、52.9±4.9 mg g−1和56.9±4.2 mg g−1。在所研究的三种吸附材料中,二氧化硅上的PEI是最有希望应用于dac的材料,因为它的合成相当简单,在大约80°C和100 mbar的中等条件下co2解吸是可行的,并且在所研究的实验条件下,水的竞争共吸附对co2的吸附没有强烈的影响。
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引用次数: 0
期刊
Indoor air
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