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Factors Influencing Waste Generation in Buildings Project in South-West, Nigeria 影响尼日利亚西南部建筑垃圾产生的因素
Pub Date : 2020-01-01 DOI: 10.35248/2252-5211.20.10.371
S. Tongo, Oluwatayo Aa, Adeboye Ba
The study was aimed to assess the factors influencing waste generation in buildings project in southwestern, Nigeria. The study randomly sampled 261 professionals through a questionnaire survey. Tables and figures were used to present the collected data and ranking and percentage were used to analyze the data collected. It was revealed that Design (Frequent design changes and poor design) lack of early contractor involvement, last-minute client requirement, engagement of inexperience designer, undefined project brief, poor design quality are the most important factors that influence l waste generation during buildings project. It was recommended that site operatives and craft men should be equipped with waste minimization knowledge, they should carry along in every management decision regarding waste management plan development as a major player on sites.
本研究旨在评估影响尼日利亚西南部建筑项目产生废物的因素。该研究通过问卷调查随机抽取了261名专业人士。使用表格和数字来展示收集到的数据,并使用排名和百分比来分析收集到的数据。结果表明,设计(频繁的设计变更和糟糕的设计)缺乏早期承包商参与,客户最后一刻的要求,缺乏经验的设计师参与,不明确的项目简介,设计质量差是影响建筑项目中废物产生的最重要因素。会议建议,场址操作人员和工艺人员应具备尽量减少废物的知识,他们应作为场址的主要参与者,参与有关制订废物管理计划的每一项管理决定。
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引用次数: 10
Comparison of Technologies to Serve Waste to Energy Conversion 服务于废物转化为能源的技术比较
Pub Date : 2020-01-01 DOI: 10.35248/2252-5211.20.10.372
Rafey A, Prabhat K, M. Samar
The increasing demand of energy has led to a chaos among the existing energy sources whether it may be thermal, nuclear, hydro or solar power. Hence, it becomes important for an alternate, feasible and sustainable energy source. Municipal solid waste (MSW) serves as an efficient and reliable option for the conversion of waste to energy since long. But the problem exists with the conversion technology which imposes restriction on its use. This paper discusses the different conversion technologies which include incineration, pyrolysis, gasification and biomethanation. The technologies are compared on various physical and chemical parameters with keen interest on environmental sustainability of the waste to energy (WtE) system. The evaluation results reveal that the biological methods are best suited for the waste to energy conversion with least degradation of the environment. Other methods such as incineration, pyrolysis and gasification are quite efficient and give a high yield but they harm the environment in the form of harmful gaseous emissions which certainly lead to global warming and greenhouse effect. This study can overall contribute to the development of more efficient and specific WtE technology which would help lower the MSW reaching the landfills generating cleaner energy to serve the future generation.
不断增长的能源需求导致了现有能源之间的混乱,无论是热能、核能、水力还是太阳能。因此,寻找一种可替代的、可行的和可持续的能源变得非常重要。长期以来,城市固体废物(MSW)一直是废物转化为能源的有效和可靠的选择。但转换技术存在问题,限制了其使用。本文讨论了不同的转化技术,包括焚烧、热解、气化和生物甲烷化。对各种技术进行了物理和化学参数的比较,并对废物转化能源系统的环境可持续性产生了浓厚的兴趣。评价结果表明,生物方法最适合于废物转化为能源,且对环境的破坏最小。其他方法,如焚烧、热解和气化,效率很高,产量也很高,但它们以有害气体排放的形式危害环境,这肯定会导致全球变暖和温室效应。这项研究整体上有助发展更有效率和更有针对性的废物处理技术,有助减少到达堆填区的都市固体废物,产生更清洁的能源,为下一代服务。
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引用次数: 13
Comparison of Lidocaine and Tramadol Premedication in Attenuating Propofol Injection Pain at Comprehensive Specialized Teaching Hospital of Ethiopia: A comparative Cross-Sectional Study 埃塞俄比亚综合专科教学医院利多卡因与曲马多预用药在减轻异丙酚注射疼痛中的比较:比较横断面研究
Pub Date : 2020-01-01 DOI: 10.35248/2155-6148.20.11.979
Metages Hunie, Mulualem Sitot, Wosenyeleh Ademasu, Efrem Fenta, Amanu Gashaw, Diriba Teshome
Background: Propofol is a widely used drug for the induction of anesthesia and often causes severe, sharp, stinging, or burning pain on the injection that can be distressing to the patient. Premedication with opioids, lidocaine, slow injection, and using a large vein for injection has been tried to combat the problem though there is controversy. The study aims to assess the effectiveness of intravenous lidocaine and Tramadol in reducing the incidence and severity of pain on Propofol injection for the adult elective surgical patient in Tikur Anbessa Comprehensive Specialized Teaching Hospital, Addis Ababa Ethiopia from February 1, 2018-March 30, 2018. G.C. Materials and Methods: Comparative cross-sectional study design was employed on a sample of 156 patients divided into two groups of 78. Participants who were 18-60 years old, underwent general anesthesia, and induced with Propofol as well as premedicated with lidocaine or Tramadol were included in the study. Patient interviews, chart review, and pretested questionnaires were employed for data collection. Collected data was analyzed using SPSS version 23. Mann-Whitney U test and chi-square test were used to compare continuous and categorical variables respectively. P-value<0.05 was considered as statistically significant.. Result: The incidence of propofol injection pain after pretreatments with lidocaine (n=78) was 23.1% and the incidence of propofol injection pain after pretreatments with tramadol (n=78) was 34.6% with a p-value of 0.112. The severity of pain expressed in the median and interquartile range of NRS score was 0 (0-2.25) in lidocaine and 0 (0-3) in tramadol group which was comparable between lidocaine and tramadol group with no statistically significant difference between two groups with (P=0.669). Conclusion: Both Lidocaine and tramadol might reduce the incidence and severity of Propofol injection pain. Anesthetists should consider the use of both lidocaine and tramadol as pretreatment for the attenuation of propofol injection pain.
背景:异丙酚是一种广泛用于麻醉诱导的药物,通常在注射处引起严重、尖锐、刺痛或灼痛,可使患者感到痛苦。虽然存在争议,但用阿片类药物、利多卡因、缓慢注射和使用大静脉注射等预先用药已经试图解决这个问题。本研究旨在评估2018年2月1日至2018年3月30日在埃塞俄比亚亚的斯亚贝巴Tikur Anbessa综合专科教学医院静脉注射利多卡因和曲马多对降低异丙酚注射成人择期手术患者疼痛发生率和严重程度的效果。材料与方法:采用比较横断面研究设计,将156例患者分为两组,每组78例。参与者年龄在18-60岁,接受全身麻醉,异丙酚诱导以及利多卡因或曲马多预用药。数据收集采用患者访谈、图表回顾和预测问卷。收集的数据使用SPSS version 23进行分析。连续变量和分类变量的比较分别采用Mann-Whitney U检验和卡方检验。p值<0.05认为有统计学意义。结果:利多卡因预处理后异丙酚注射疼痛发生率为23.1% (n=78),曲马多预处理后异丙酚注射疼痛发生率为34.6% (p值为0.112)。NRS评分中位数和四分位数范围内,利多卡因组疼痛程度为0(0-2.25),曲马多组疼痛程度为0(0-3),两组间具有可比性,两组间差异无统计学意义(P=0.669)。结论:利多卡因和曲马多可降低异丙酚注射痛的发生率和严重程度。麻醉师应考虑同时使用利多卡因和曲马多作为预处理,以减轻异丙酚注射疼痛。
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引用次数: 1
Plastic Waste Recycling Practice in Natore District, Bangladesh 孟加拉国纳托雷区的塑料废物回收实践
Pub Date : 2020-01-01 DOI: 10.35248/2252-5211.20.10.392
Rahman Mm, Shafkath Es, R. Ma
This study is aimed to find out the plastic waste recycling practice in Natore District as it has become the biggest concern for the environment. A questionnaire-based survey at 11 shops was conducted in 4 upazila of Natore district. The study found that the there are three types of plastic waste is being recycled or processed in Natore area which are pet bottles (PB), hard plastic processed (HP 1) and hard plastic non-processed (HP2). The collection shops size is around 3777 ± 2160 sq/ft in whereas the processing shops size is 13513 ± 7686 sq/ft. On average 6 people work in each type of shops, aged from 20 to 35 years and women are less involved in this sector. Worker mostly earned 270 BDT on average pay day. Collection shops collect 1400 ± 70.72 kg (1.54 ton) and processing shops collect 970 ± 29.86 kg (1.069 ton) plastic waste every week that contributes 0.14 % of the total plastic waste recycled in Bangladesh. Price of the products is a bit unstable. However, in general PB, HP1 and HP2 are bought 10-12 20-30 and 5-7 BDT/kg respectively and sold to industry on 17-18, 45-50, 10 BDT/kg respectively, for final recycle.
本研究的目的是了解塑料废物回收的做法,在Natore区,因为它已经成为最大的环境问题。在纳托尔区4个区11家商店进行了问卷调查。研究发现,在Natore地区有三种类型的塑料垃圾被回收或处理,分别是pet瓶(PB),处理硬塑料(hp1)和未处理硬塑料(HP2)。收集店的面积约为3777±2160平方英尺,而加工店的面积为13513±7686平方英尺。每种类型的商店平均有6人在工作,年龄在20至35岁之间,妇女参与这一部门的人数较少。工人们的平均工资日大多为270比特币。收集店每周收集1400±70.72千克(1.54吨)塑料废物,加工店每周收集970±29.86千克(1.069吨)塑料废物,占孟加拉国回收塑料废物总量的0.14%。这个产品的价格有点不稳定。然而,一般来说,PB、HP1和HP2分别购买10-12、20-30和5-7 BDT/kg,并分别在17-18、45-50和10 BDT/kg出售给工业,用于最终回收。
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引用次数: 1
Open Drainages Effecting for People in their Day to Day Life and Drainage Wastage Effecting the River in Theni District 露天排水对人们日常生活的影响,以及排水废物对泰尼地区河流的影响
Pub Date : 2020-01-01 DOI: 10.35248/2252-5211.20.10.380
Amudha Ondiveerappan
The present study is considering the drainage coming into the rivers and affecting people’s lives in Theni district, India. The Varaha (Varahanadhi) is a small river that flows through the town of Periyakulam in Theni district of the state of Tamil Nadu in India. It joins the Vaigai River near Marugalpatti. In today’s time the the Varaha river, once considered sacred, is fast becoming an open drain since the drainage water had been diverted to it. The Panchayat Union waste and Municipality waste has been directed to the river. People living along the banks complain of mosquitoes and presenting with sicknesses. They require closed drainages to prevent getting sick. Indian officials have said that to consider with an alternate drainage system to be created at the cost of about Rupees twenty-six crores. Survey and questions to the people living near this open drainage complained that the Indian officials had taken surveys, and nothing has been done so far, considering the money has been paid.
目前的研究正在考虑排入河流并影响印度Theni地区人们生活的排水。Varaha (Varahanadhi)是一条小河,流经印度泰米尔纳德邦Theni地区的Periyakulam镇。它在Marugalpatti附近加入Vaigai河。今天,曾经被认为是神圣的瓦拉哈河,由于排水被转移到这里,正在迅速成为一个开放的排水沟。Panchayat联盟和市政府的垃圾被直接排入这条河。居住在河岸上的人们抱怨蚊子,并出现了疾病。他们需要封闭的排水系统来防止生病。印度官员表示,要考虑耗资约2.6亿卢比的替代排水系统。对居住在露天排水渠附近的人们进行的调查和提问抱怨说,印度官员进行了调查,但考虑到钱已经支付,到目前为止什么都没有做。
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引用次数: 1
Effect of Pretreatment on the Biogas Production from Energy Plant Using Batch Reactor 间歇式反应器预处理对能源厂沼气生产的影响
Pub Date : 2019-04-18 DOI: 10.35248/2252-5211.19.9.365
Nagendra Kumar, D. Pant
The proposed study aims at biogas potential estimation of sugar beet using different total solid concentration and pretreatment methods. The effect of alkali (Sodium hydroxide), acid (Hydrochloric acid) and mechanical (particle size reduction) pretreatment of sugar beet over un-pretreated substrate have been investigated for the potential of biogas production using biphasic continuous bio digester–TEAM (TERI’s Enhanced Acidification and Methanation) process (50 kg/day capacity) developed by TERI+. The estimation of biogas potential of sugar beet has also been studied in single phase batch digester (2 L capacity) using three different Total Solids (TS) concentration viz. 5%, 7.5% and 10%. However the effect of particle size reduction was also studied in two phase digester. The biogas yield from single phase batch digester fed with 5% TS, 7.5% TS, 10% TS, were recorded as 44 m3/ton, 58 m3/ton, 57 m3/ton of substrate fed respectively whereas the yield from un-pretreated, HCl (6%; v/v) pretreated and NaOH (1%; w/v) pretreated sugar beet are, 72 m3/ton, 60 m3/ton and 61 m3/ton respectively. The biogas yield from mechanically pulverized is estimated to be 90 m3/ton which is 25% more than not pretreated substrate that too in Total Hydraulic Time (HRT) of less than six days.
本研究旨在利用不同的总固体浓度和预处理方法对甜菜的沼气潜力进行估算。利用TERI+开发的双相连续生物沼气池- team (TERI的强化酸化和甲烷化)工艺(50 kg/天容量),研究了碱(氢氧化钠)、酸(盐酸)和机械(减小粒径)预处理对甜菜未经预处理的基质的影响。在容量为2 L的单相间歇式沼气池中,采用总固体浓度为5%、7.5%和10%的三种不同浓度,对甜菜的沼气潜力进行了估计。此外,还研究了两相消化器对颗粒大小的影响。以5% TS、7.5% TS、10% TS为基质的单相间歇式沼气池的沼气产量分别为44 m3/t、58 m3/t、57 m3/t,而未经预处理的HCl (6%;v/v)和NaOH (1%;W /v)预处理甜菜分别为72 m3/吨、60 m3/吨和61 m3/吨。机械粉碎的沼气产量估计为90立方米/吨,比未预处理的基质多25%,而且总水力时间(HRT)少于6天。
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引用次数: 0
Investigating the Possibility of Using Recycled Industrial Wastewater Instead of Potable Water in Concrete Mixture 探讨用再生工业废水代替混凝土混合料中饮用水的可能性
Pub Date : 2019-01-07 DOI: 10.35248/2252-5211.19.9.362
Amir Hossein Askariyeh
Iran is located in the Middle East with a population of approximately 81 million people (2017). The Middle East in general and Iran in particular are located in an arid region of the world. Iran has a chronic shortage of water. It is estimated there is some form of drought in 97 percent of the country. In an 8-month period (September 23, 2017-May 21, 2018) the country has received 151.5 millimeters of rain while the long-term averages are 214.6 millimeters which indicates a 29-perecnt drop in mean precipitation nationwide. The driving factors behind water shortages are numerous. Some are natural and others man-made. One of the biggest factors is population growth. The population of Iran doubled between 1976 and 2001, going from 33 million to 66 million Iranians. The population is still rising, and currently stands at over 80 million people. And as this figure rises, the volume of renewable water resources available per capita drops. It is already critically low. 35% of the populations are living in areas experiencing water shortages and droughts. Global warming is contributing to bodies of water drying out, and the problem is expected to worsen as climate change increases. The socio-economic changes happening alongside this exacerbate the problem. Fresh water is a precious commodity here. Population and economic growth has increased the demand for fresh water in the region. Limited supply and increased demand has created a challenge for governments and construction industry. Therefore this article is investigating the possibility of using alternative sources of water with the aim of reducing the demand for the limited supply of fresh water. Ibrahim al Ghusain and his Colleague used car wash wastewater on investigate effect of reusing wastewater in concrete mixture in different situation as Temperature and long term and varying degrees of treatment on compressive strength and they found that territory treated car wash wastewater has more compressive strength than others [1]. In another case Shahiron Shahidana and his colleagues worked on effect of reusing car wash wastewater in different quantity for measuring, tensile strength and Modulus of Elasticity (MOE) and compressive strength of concrete. In this paper was shown the optimum percentage of car wash wastewater as fresh water replacement in concrete mixes is 20% [2]. For the purpose of the article recycled industrial wastewater from an industrial park in the city of Yazd of Iran was used in mixing concrete and its effect on compressive strength of concrete was analyzed. Concrete samples for testing purposes were mixed using ordinary Portland cement and common aggregate used in concrete work for general construction purposes. Samples were prepared according to ASTM standard of C 192 and after curing in the laboratoryenvironment for different periods they were crushed to determine the compressive strength. In this experiment test results indicated that all samples prepared with treated industria
伊朗位于中东,人口约8100万(2017年)。中东,特别是伊朗位于世界的干旱地区。伊朗长期缺水。据估计,全国97%的地区都存在某种形式的干旱。2017年9月23日至2018年5月21日8个月期间,全国降雨量为151.5毫米,而长期平均降雨量为214.6毫米,全国平均降雨量下降29%。水资源短缺背后的驱动因素有很多。有些是自然的,有些是人为的。最大的因素之一是人口增长。1976年至2001年间,伊朗人口翻了一番,从3300万增加到6600万。人口仍在增长,目前已超过8000万。随着这个数字的上升,人均可再生水资源的数量下降。它已经处于极低水平。35%的人口生活在缺水和干旱的地区。全球变暖正在导致水体干涸,随着气候变化的加剧,这个问题预计会恶化。与此同时发生的社会经济变化加剧了这一问题。淡水在这里是一种珍贵的商品。人口和经济增长增加了该地区对淡水的需求。有限的供应和不断增长的需求给政府和建筑行业带来了挑战。因此,本文正在研究使用替代水源的可能性,目的是减少对有限供应的淡水的需求。Ibrahim al Ghusain和他的同事利用洗车废水研究了在不同温度、时间和不同处理程度下回用废水对混凝土混合料抗压强度的影响,发现经过区域处理的洗车废水比其他处理的抗压强度更高[1]。在另一个案例中,Shahiron Shahidana和他的同事研究了不同量的洗车废水回用对混凝土抗拉强度、弹性模量(MOE)和抗压强度的影响。本文表明,在混凝土混合料中,洗车废水作为淡水替代的最佳比例为20%[2]。本文以伊朗亚兹德市某工业园区回收的工业废水为原料,对其对混凝土抗压强度的影响进行了分析。用于测试目的的混凝土样品使用普通波特兰水泥和用于一般建筑目的的混凝土工作的普通骨料混合。试样按ASTM c192标准制备,在实验室环境中养护不同时间后进行压碎,测定抗压强度。在本实验中,测试结果表明,用处理过的工业废水制备的所有样品都比用饮用水制备的样品具有更高的抗压强度。这一发现显示了通过使用替代水源进行混凝土混合来节约淡水供应的有希望的结果。
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引用次数: 2
Anaerobic Digestion of Vegetable Wastes for Biogas Production in Single Chamber and Double Chamber Reactors 单室和双室反应器中植物废弃物厌氧消化产气研究
Pub Date : 2019-01-01 DOI: 10.35248/2252-5211.19.9.369
A. Jalil, Santosh Karmaker, Samiul Basar, Shamsul Hoque
The compositions of solid wastes of a rural market of Bangladesh and the results of two sets of laboratory experiments on biogas generation from the easily biodegradable wastes under daily feed condition are presented in this paper. Cow dung, cauliflower stick, papaya and potato were the major biodegradable wastes. Daily average composition of the biodegradable wastes was used in the experiments. The average Total Solids (TS) and Volatile Solids (VS) concentrations of the raw substrate were determined as 18.90% and 15.10% respectively. The experimental setups were placed in a large closed chamber containing two room heaters. The room heaters were operated alternatively at 35°C to maintain a favorable condition for anaerobic digestion of the substrate. In the first setup, a single chamber reactor and a double chamber reactor were used. In the single chamber reactor, 750 g wastes and required amount of inoculum were added initially to make the effective volume of 2 L. For the double chamber reactor, each chamber was initially fed with 350 g wastes and inoculum was added to make the effective volume of 1 L. The single chamber reactor was operated for 58 days and the double chamber reactor was run for 23 days. From the 2nd day of operation, each reactor was fed daily with a mixture of 18.75 g wastes and the required volume of tap water to make the total volume of 50 mL after taking out equal volume of slurry from the reactor. The second set of experiment was similar to the double chamber reactor of the first setup, but it was operated for 54 days including the last 16 days operation at room temperature as the heaters became out of order. In case of the first setup, the temperature varied from 31°C to 36°C and the rate of biogas generation was not affected due to this variation. The results of the experiments revealed that for the Organic Loading Rate (OLR) of 1.42 g VS/L/d, the daily stable biogas generation rate was 0.22 m3/kg of VS added for the single chamber reactor, and apparently the daily stable average rate of biogas production was 0.37 m3/kg of VS added for the double chamber reactor. During the second set of experiment, the temperature varied in between 32°C and 36°C when the chamber-heater was on and the rate of biogas generation was not affected, and the stable rate of biogas generation was 0.26 m3/kg of VS added for the OLR of 1.42 g VS/L/d. The temperature of the chamber varied from 22°C to 25°C when the heater became out of order and the sudden drop of the temperature by about 10°C affected the rate of biogas production greatly. At the ambient temperature, the stable rate of biogas generation was only 0.08 m3/kg of VS added.
本文介绍了孟加拉国农村市场固体废物的组成,以及在日投料条件下易生物降解废物产沼气的两组实验室实验结果。牛粪、花椰菜棒、木瓜和土豆是主要的可生物降解废弃物。实验采用生物可降解废物的日平均组成。测定了原料底物的平均总固形物(TS)和挥发性固形物(VS)浓度分别为18.90%和15.10%。实验装置被放置在一个封闭的大房间里,里面有两个房间加热器。室内加热器在35°C交替操作,以保持对底物厌氧消化的有利条件。在第一次设置中,使用了单室反应器和双室反应器。单室反应器初始投加750 g废物和所需接种量,使有效体积为2 l。双室反应器初始投加350 g废物,接种量使有效体积为1 l,单室反应器运行58天,双室反应器运行23天。从运行第2天开始,每天向每个反应器投喂18.75 g废物和所需体积的自来水,从反应器中取出等体积的浆液,使其总体积为50 mL。第二组实验与第一次设置的双室反应器相似,但由于加热器出现故障,在室温下运行了54天,其中最后16天在室温下运行。在第一次设置的情况下,温度从31°C变化到36°C,沼气的产生速率不受此变化的影响。实验结果表明,在有机负荷率(OLR)为1.42 g VS/L/d的条件下,单室反应器的日稳定产气率为0.22 m3/kg VS,双室反应器的日稳定产气率为0.37 m3/kg VS。在第二组实验中,当室内加热器开启时,温度在32℃~ 36℃之间变化,不影响产气速率,在OLR为1.42 g VS/L/d的条件下,稳定的产气速率为0.26 m3/kg VS。当加热器出现故障时,气室温度在22 ~ 25℃之间变化,温度突然下降约10℃,极大地影响了沼气的产率。在环境温度下,添加VS的稳定产气率仅为0.08 m3/kg。
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引用次数: 2
Suitability of Kibuye Market Organic Waste for Composting as a Means of Solid Waste Management for Kisumu City 基布耶市场有机废物堆肥作为基苏木市固体废物管理手段的适宜性
Pub Date : 2019-01-01 DOI: 10.35248/2252-5211.19.9.370
J. Oloo, F. Awuor
Purpose: Organic waste comprises most of the waste in dumpsites in Kenya and this causes environmental challenges at such sites. With Kisumu as a case study, the purpose of this work was to explore the suitability of organic wastes from Kibuye market, hotels and livestock farms for compost manure making as a means of organic solid waste management. Methods: The study was cross-sectional in design. Compost manure was prepared from organic market waste, hotel food remains and livestock dung. Samples were then taken to a laboratory to test for the content of nitrogen, phosphorous (P2O5) using TES/06/TM/21 and TES/06/TM/24 methods respectively and potassium (K2O) using Atomic Absorption Spectrometry (AAS) method as well as for heavy metals (Cd, Cu, Fe, Pb) while the Ph of the compost was tested by KS-158 method. Results: Laboratory tests for the presence of important crop elements were Nitrogen (0.4%), Phosphorous (0.4%), and Potassium (0.9%) whereas for heavy metals were Cd=Nil, Cu=10.1, Fe=1.08, Pb=Nil, and pH=8.4. Conclusion: It is safe to use organic waste from Kibuye as augmented by those from hotels and livestock farms for composting as a means of organic solid waste management if other supporting systems are in place.
目的:有机废物构成了肯尼亚垃圾场的大部分废物,这给这些垃圾场带来了环境挑战。本研究以基苏木为例,探讨来自基布耶市场、酒店和畜牧场的有机废物是否适合作为有机固体废物管理的一种手段进行堆肥。方法:采用横断面设计。堆肥是由有机市场废物,酒店食物残渣和牲畜粪便制备的。将样品送到实验室,分别用TES/06/TM/21和TES/06/TM/24法测定氮、磷(P2O5)含量,用原子吸收光谱法(AAS)测定钾(K2O)含量以及重金属(Cd、Cu、Fe、Pb)含量,用KS-158法测定Ph。结果:对重要作物元素的实验室检测为氮(0.4%)、磷(0.4%)和钾(0.9%),而对重金属的实验室检测为Cd=零、Cu=10.1、Fe=1.08、Pb=零和pH=8.4。结论:如果其他配套系统到位,利用基布耶的有机废物,加上酒店和畜牧场的有机废物进行堆肥作为有机固体废物管理的一种手段是安全的。
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引用次数: 2
Distribution of Natural Radionuclides, Rare Earth Elements, Metals and Metalloids in a Phosphogypsum Stockpile 磷石膏贮存中天然放射性核素、稀土元素、金属及类金属的分布
Pub Date : 2019-01-01 DOI: 10.35248/2252-5211.19.9.363
M. Madruga, M. Prudencio, José Corisco, J. Mihálik, R. Marques, Marta Santos, M. Reis, I. Paiva, M. Dias
A first detailed study of phosphogypsum (PG) from a stockpile in Barreiro (Portugal) was performed aiming for a better characterization of this industrial waste deposit, considering its enhanced content in natural radionuclides and toxic metals, making it a potential contamination source to the Tejo estuary. Whole samples and aggregates of these wastes resulting from phosphate industries were analysed by neutron activation, gamma-spectrometry, X-ray diffraction and scanning electron microscopy. This work clearly shows that a significant chemical heterogeneity in the PG occurs due to the existence of aggregates with different compositions randomly distributed. Among these aggregates, the dark grey ones have high concentrations of Sc, Cr, Zn, Ga, Ba, REE, Ta, W, Th and U and the highest concentrations of 226Ra and 210Pb. The separation of these dark aggregates prior to any application of the PG would lead to a safer reuse of these wastes. The chemical patterns, including the REE distribution with a significant negative Ce anomaly, found in PG, are certainly related with the geochemical signatures of the phosphate rocks used as raw material. This PG stockpile may play a significant role as a radioactive source in the Tejo estuarine environment.
考虑到其天然放射性核素和有毒金属的含量增加,使其成为特茹河口的潜在污染源,为了更好地表征这种工业废物沉积物,对巴雷罗(葡萄牙)储存的磷石膏(PG)进行了首次详细研究。利用中子活化、伽马能谱法、x射线衍射和扫描电子显微镜分析了磷酸盐工业产生的这些废物的整个样品和集合体。这项工作清楚地表明,由于存在随机分布的不同组成的聚集体,PG中发生了显著的化学异质性。深灰色团聚体中Sc、Cr、Zn、Ga、Ba、REE、Ta、W、Th和U的含量较高,226Ra和210Pb的含量最高。在任何应用PG之前分离这些深色聚集体将导致这些废物的更安全的再利用。PG中稀土元素分布具有显著的负Ce异常,其化学模式与作为原料的磷矿的地球化学特征有关。这种PG储存可能在特霍河河口环境中作为放射源发挥重要作用。
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引用次数: 3
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International Journal of Waste Resources
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