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Competitive biosorption of rare-earth elements on bacterial biomass: equilibrium and kinetic studies 稀土元素在细菌生物量上的竞争性生物吸附:平衡和动力学研究
Pub Date : 2022-07-29 DOI: 10.54392/irjmt2244
Jordão C.S, G. E.C
Previous studies showed that chemical modified Bacillus subtilis biomass possessed the high potential for recovery rare-earth elements, and, in this study, mathematical models were applied to explain the B. subtilis biomass La3+ and Sm3+ ions sorption capacity. The experimental isotherm data were analyzed using Langmuir, Freundlich, Temkin, and DRK equations. Both Langmuir and Freundlich isotherms models that fit the equilibrium data. Temkin model showed that it occurs physisorption. In more dilute solutions, the adsorption preference follows the order La3+ > Sm3+. With the increase in the concentration of rare-earth elements, there is an inversion in the preference for Sm3+ > La3+. The results demonstrate that the optimum model for describing the kinetics of the biosorption of both rare-earth elements is the pseudo-second-order model as well as the viability of recovering lanthanum using bacterial biomass sorbents, a practical technique.
前人的研究表明,化学修饰的枯草芽孢杆菌生物量具有较高的稀土回收潜力,本研究采用数学模型来解释枯草芽孢杆菌生物量对La3+和Sm3+离子的吸附能力。实验等温线数据采用Langmuir, Freundlich, Temkin和DRK方程进行分析。Langmuir和Freundlich等温线模型都符合平衡数据。Temkin模型显示其发生物理吸附。在较稀的溶液中,吸附偏好顺序为La3+ > Sm3+。随着稀土元素浓度的增加,Sm3+ > La3+的偏好发生反转。结果表明,描述这两种稀土元素的生物吸附动力学的最佳模型是拟二阶模型,以及利用细菌生物量吸附剂回收镧的可行性,这是一种实用的技术。
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引用次数: 0
Parabolic Model for Optimum Dry Film Thickness (DFT) of Corrosion Protective Coatings 腐蚀防护涂层最佳干膜厚度的抛物线模型
Pub Date : 2022-07-27 DOI: 10.54392/irjmt2242
Anyanwu K.O
This study proposes a model for calculating the optimum dry film thickness of corrosion protective Coatings. It was assumed that the graph of coating thickness against corrosion rate is a parabola whose coordinates at turning point consists of optimum thickness and minimum corrosion rate. On this basis, equation of parabola was formed. Three equations of parabola were also formed with three assumed thicknesses, taking arbitrarily with their corresponding corrosion rates of the coated metals. From the equations, a 3x3 matrix was derived. From the solution of the matrix, equations for optimum thickness, minimum corrosion rates and corrosion rate of uncoated specimen were obtained. It is assumed that with this model a technical ground shall be established, upon which the optimum thicknesses of corrosion protective coatings shall be recommended.
本文提出了一种计算防腐涂层最佳干膜厚度的模型。假设涂层厚度随腐蚀速率的变化曲线为抛物线,其拐点坐标为最佳涂层厚度与最小腐蚀速率。在此基础上,建立了抛物线方程。在三个假设厚度下,形成了三个抛物线方程,任意取其对应的涂层金属腐蚀速率。由方程推导出一个3x3矩阵。通过对基体的求解,得到了涂层试样的最佳厚度、最小腐蚀速率和腐蚀速率方程。假定有了这个模型,应该建立一个技术基础,并在此基础上推荐最佳的防腐涂层厚度。
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引用次数: 0
Evaluation of Four Tillage Methods Operating parameters by Overall index using Analytical Hierarchy Procedure and Compromise Programming Technique in the Gezira Heavy Clay Soils 利用层次分析法和妥协规划技术综合评价格孜拉重粘性土4种耕作方法的操作参数
Pub Date : 2022-07-27 DOI: 10.54392/irjmt2243
Abdelkarim D. Elfadil, O. Abbas, Adil Bashir Karar, H. I. Mohammed
This work was excuted during seasons 2018/2019, and 2019/2020, in Tayba Block-the Sudan - Gezira central clay plains, to evaluate the field operation performance of four land preparation methods using three tillage equipment: chisel plow "intensive tillage", disc harrow "medium tillage", ridger "minimum or reduced tillage" and no tillage machine. An overall operation index is estimated from four measured machine operating characteristics. Diagnosis of land preparation methods was made using analytical hierarchy method for weight assignment for assignment of relative weights for the operating parameters, and compromise programming technique for ranking of tillage methods. The experiment was conducted as a factorial experiment with RCBD, the LSD test at 1%and 5 % was used to compare between means. Results indicate that no significant differences (P<0.05) in field efficiency between Chisel plow and ridger and harrow showed the least efficiency value. There is significant differences in fuel consumption rate between all treatments with highest consumption is by Chisel plow and lowest is by ridger. The significantly highest rear wheel slippage is attained by ridger while there is no significant differences in that resulted from chisel or disc harrow. The significantly highest field capacity (P<0.05) is attained by ridger followed by harrow and then chisel plow. The analytical hierarchy procedure ranked the machines operation indicators in descending order by weight values of 1.02, 0.62, 0.29 and 0.12 for. Multi-criteria analysis by compromise programming technique results in overall indices of tillage equipments: ridger, chisel plow, disc harrow in descending values of 67.53, 61.00, and 57.29 respectively. The overall performance index (OPI) for the operation of the agricultural equipment could be used to take the tillage decision-making process by selecting the most effective machinery to give optimum seed bed with minimum energy input. However, it is not possible to calculate the overall index for no tillage method because without using a machine there is no fuel consumption, no field efficiency, no field capacity, and no wheel slippage. This imply that for heavy clay soils of Gezira Scheme and in other similar environments it is recommended to use reduced tillage "ridging only" as the most technically feasible tillage method, other wise use chisel plowing if funds are available.
本研究于2018/2019和2019/2020两季在Tayba区块-苏丹- Gezira中部粘土平原开展,旨在评估使用三种耕作设备的四种整地方法的田间作业性能:凿子犁“集约耕作”、盘耙“中等耕作”、ridger“最少或减少耕作”和免耕机。从四个测量的机器运行特性中估计出总体运行指标。采用层次分析法对各操作参数进行权重分配,采用折衷规划技术对各耕作方法进行排序,对整地方法进行诊断。实验采用RCBD的析因实验,采用1%和5%的LSD检验进行均数比较。结果表明,凿子犁与犁脊犁的田间效率差异不显著(P<0.05),耙犁的田间效率值最低。各处理间的燃料消耗率差异显著,其中凿子犁的燃料消耗率最高,犁式的燃料消耗率最低。显著最高的后轮滑移是由山脊而没有显著差异,导致凿子或圆盘耙。犁铧犁的耕地容量显著最高(P<0.05),其次是耙犁,最后是凿犁。采用层次分析法对各机器运行指标按权重值1.02、0.62、0.29、0.12从高到低排序。采用折衷规划技术进行多准则分析,犁耙、凿犁、盘耙的综合指标分别下降67.53、61.00、57.29。利用农机设备运行的综合性能指标(OPI)进行耕作决策,选择最有效的机械,以最小的能量投入提供最优的种床。然而,不耕法的总体指标是无法计算的,因为不使用机器就没有燃料消耗,没有田间效率,没有田间容量,没有车轮打滑。这意味着,对于Gezira计划的重粘土土壤和其他类似环境,建议使用减少耕作“只垄”作为技术上最可行的耕作方法,否则,如果有资金,则使用凿子耕作。
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引用次数: 0
A Review on Application of 3D Printing Principles in Infrastructure Industry and its Impact on Evolution of the Industry 3D打印原理在基础设施行业的应用及其对行业演进的影响
Pub Date : 2022-06-15 DOI: 10.54392/irjmt2241
Avinash Varma K, Kaushik S Chundury, Narendra Kumar B
As 3D printing emerging to be a much-matured technology, its range of uses are now seemed to be infinite. 3D printing is now beyond the stage where it was only observed as a prototyping solution. From a simple artwork and playing toys to ready to live in buildings and also transplantable organs, the technology could potentially last until our imaginations die. From automobile to consumer goods manufacturing industries, organizations across various industries are trying to observe the advantages 3D printing has got to offer for production. With such acknowledgements, organizations are now trying to find their ways to incorporate this technology in their respective industries, whose applications could potentially extend from tooling to spare/replacement parts and sometimes till a full-fledged end-use ready product. While 3D printing looks like a most exciting new normal for organizations who are planning to streamline their prototyping technology, its prospects for the non-tech consumer world is also evolving rapidly. Additive Manufacturing in construction can be seen as an option that could contribute towards complete automation in the infrastructure industry. The method offers advantages in the aspects of design, sustainability and also efficiency. This work scopes for a comprehensive approach to advance the technology in construction and proposes research potentials, challenges, and future scope. The potential of 3dcp for automation advances all other practices in prospects like exclusion of form work, precise design execution, waste reduction and extremely low consumption of time. The real-time status and futuristic approaches to be adopted are briefed in the paper and also the scope for sustainability over other practices are detailed in the paper.
随着3D打印成为一项非常成熟的技术,它的使用范围似乎是无限的。3D打印现在已经超越了仅仅作为原型解决方案来观察的阶段。从简单的艺术品和玩具到准备住进建筑物和移植器官,这项技术可能会持续到我们的想象力消失。从汽车到消费品制造行业,各行各业的组织都在尝试观察3D打印为生产提供的优势。有了这样的认可,组织现在正试图找到将该技术纳入各自行业的方法,其应用程序可能从工具扩展到备用/替换部件,有时甚至扩展到成熟的最终用途产品。虽然3D打印看起来是那些计划简化原型技术的组织最令人兴奋的新常态,但它对非技术消费世界的前景也在迅速发展。建筑领域的增材制造可以被视为一种有助于实现基础设施行业完全自动化的选择。该方法在设计、可持续性和效率方面具有优势。这项工作涵盖了全面推进建筑技术的方法,并提出了研究潜力、挑战和未来的范围。3dcp在自动化方面的潜力推动了所有其他实践的发展,如排除表单工作,精确的设计执行,减少浪费和极低的时间消耗。本文简要介绍了将采用的实时状态和未来方法,并详细介绍了可持续性优于其他实践的范围。
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引用次数: 0
Treatability study of Carcinogenic Waste and its Assessment of Environmental Risk 致癌废物可处理性研究及其环境风险评价
Pub Date : 2022-05-25 DOI: 10.54392/irjmt2233
S. Roy, U. Roy
Carcinogenic as well as chemotherapeutic waste is potential hazard to the environment because it is a type of toxic waste according by EPA (Environmental Protection Agency). The procedure of disposal of carcinogenic waste inside hospital, chemical industry and pharmaceutical industry is important concern for our society. The contribution from the Indian Judiciary in its own way to bring effective legal control of these hazardous substances and waste. Moreover, the problems related to judicial issues in tackling the technical issues and the executive inaction make it inevitable to have a separate system of administration of environmental justice and supervisory system so that our environment will be protected. The present paper investigates the treatability study of carcinogenic waste and its assessment of associated environmental risk according to the Indian hazardous substances and waste laws.
根据美国环境保护署(EPA)的说法,致癌和化疗废物对环境有潜在危害,因为它们是一种有毒废物。医院、化工、医药等行业的致癌废物处理程序是社会关注的重要问题。印度司法机构以自己的方式对这些有害物质和废物进行有效的法律管制。此外,在解决技术问题时存在的司法问题和行政上的不作为,使得环境司法的行政管理和监督制度的分离成为我国环境保护的必然。本文根据印度有害物质和废物法对致癌废物的可处理性研究及其相关环境风险评估进行了研究。
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引用次数: 0
Determination of the Durability of Polyurethane Coating on Mild Steel in Various Soil Media 低碳钢聚氨酯涂层在不同土壤介质中耐久性的测定
Pub Date : 2022-05-24 DOI: 10.54392/irjmt2232
Anyanwu K.O, Anyakwo A.N, Ndukwe A.I, C. O., C. A.P.
In this paper, effort has been made to determine the durability of polyurethane coating on mild steel in acid, alkaline and neutral soil. A total of 42 mild steel coupons were used. Out of the 42 coupons, 21 were coated with polyurethane and the remaining 21 were left uncoated. Acid soil (pH = 4.5), Alkaline soil (pH =13.5) and neutral soil (pH = 6.8) were used as the test media. Seven each of the coated and uncoated coupons were buried in each soil media. On weekly basis, one coated and one uncoated coupon were withdrawn from each of the soil media and reweighed. The durability of the coating in each soil media was calculated using a proposed model. From the results obtained, the durability of polyurethane coating was found to be 7.0yrs, 4.5yrs and 2.9yrs in neutral, acid and alkaline soil respectively.
本文对低碳钢表面聚氨酯涂层在酸性、碱性和中性土壤中的耐久性进行了试验研究。共使用了42根低碳钢板。在42张优惠券中,21张涂上了聚氨酯,其余21张没有涂上。试验介质为酸性土壤(pH = 4.5)、碱性土壤(pH =13.5)和中性土壤(pH = 6.8)。在每种土壤介质中分别埋入7个涂布和未涂布的样品。每周一次,从每种土壤介质中取出一个包膜和一个未包膜的券并重新称重。利用提出的模型计算了不同土壤介质中涂层的耐久性。结果表明,聚氨酯涂料在中性、酸性和碱性土壤中的耐久性分别为7.0年、4.5年和2.9年。
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引用次数: 1
Modelling of Stress in Public Transport 公共交通的应力模拟
Pub Date : 2022-04-18 DOI: 10.54392/irjmt2231
M. E. Ergin
The quality of the public transport system is an important factor in determining passenger travel satisfaction and it leads to a better quality of life. Quality of life depends on the quality of services provided in the city. Satisfaction is strongly related to the perception of the users. Many people use public transport on their everyday trips and this paper investigates how road users perceive the public transportation system and the place of the stress factor in this perception. Furthermore, willingness to pay analysis was also carried out, and the amount of additional charge for a less stressful trip was included as a new variable in the model. The binomial logit model is used as a method in this study. As a result, the trip time and the home-based work trips increase the stress level in travel rises. Stress level affects the perception of public transport users, and therefore, users tend to stay away from the stress.
公共交通系统的质量是决定乘客出行满意度的重要因素,它会带来更好的生活质量。生活质量取决于城市提供的服务质量。满意度与用户的感知密切相关。许多人在日常出行中使用公共交通工具,本文调查了道路使用者如何感知公共交通系统以及这种感知中压力因素的位置。此外,还进行了支付意愿分析,并将压力较小的旅行的额外费用作为一个新变量纳入模型。本研究采用二项逻辑模型作为研究方法。因此,旅行时间和在家工作的旅行增加了旅行中的压力水平。压力水平影响公共交通用户的感知,因此,用户倾向于远离压力。
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引用次数: 0
Wind Driven Optimization Approach based Multi-objective Optimal Power Flow and Emission Index Optimization 基于多目标最优潮流和排放指标优化的风力优化方法
Pub Date : 2022-03-11 DOI: 10.54392/irjmt2223
Nabil Mezhoud, B. Ayachi, Ahmed Bahri
This paper proposes one of the optimization methods based on atmospheric motion. It is a global optimization nature-inspired method such as Wind Driven Optimization (WDO) approach to solve the Optimal Power Flow (OPF) and Emission Index (EI) in electric power systems. Our main aim is to minimize an objective function necessary for a best balance between the energy production and its consumption, which is presented as a nonlinear function, taking into account of the equality and inequality constraints. The WDO approach is nature-inspired, population based iterative heuristic optimization algorithm for multi-dimensional and multi-modal problems. WDO method have been examined and tested on the standard IEEE 30-bus system and IEEE 57-bus system with different objectives that reflect total active power generation cost, the active power losses and the emission index. The results of used method have been compared and validated with known references published recently. The results are promising and show the effectiveness and robustness of proposed approach.
本文提出了一种基于大气运动的优化方法。它是求解电力系统最优潮流(OPF)和排放指标(EI)的一种全局优化方法,类似于风力驱动优化(WDO)方法。我们的主要目标是最小化能源生产和消费之间最佳平衡所必需的目标函数,考虑到等式和不等式约束,这是一个非线性函数。WDO方法是一种受自然启发、基于种群的多维多模态迭代启发式优化算法。WDO方法在标准的IEEE 30总线系统和IEEE 57总线系统上进行了测试,测试的目标不同,反映了总有功发电成本、有功损耗和排放指标。将所采用方法的结果与最近发表的文献进行了比较和验证。结果表明了该方法的有效性和鲁棒性。
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引用次数: 1
Recovery of Metal Values from Secondary Resource 二次资源中金属价值的回收
Pub Date : 2022-02-23 DOI: 10.54392/irjmt2222
M. Rabah, Omaima A El Qady, Shaimaa A Abou El Kassem
The ‎‎input waste was KanthalA4 grade alloy spired in 8-25 mm outer diameter. A sample weighing ≈250 g was leached in HCl or aqua regia at ‎‎room temperature. The acidic leachate was filtered and the pH value was increased ‎to ‎‎4.0 -9.2 with the addition of 3 M ammonia solution. The leachate was freed from iron by H2O2 addition. Chromium ions were separated from nickel ions by pH adjustment and solvent extraction using Lewatite MP 600 ionic exchanger. Ammonium hydroxide gave insoluble hydroxide ppt that was ‎‎filtered and washed. Different organic salts of acetate Ni(OCOCH3)2, oxalate C2O4, citrate C6H6O5 with ∆E of 74.16 KJ/ mol with Ni and 139.33 KJ/ mol with Cr. Inorganic ‎salts were also prepared like Ni(NO3)2.6H2O, dichloride NiCl2, basic carbonate NiCO3.2Ni(OH)2 as well as free ‎metals ‎of nickel and chromium. The effect of the process parameters was ‎studied. The time of synthesis decreased by stirring at 300 rpm by about 11 %. Ascorbic acid solution reduces the Ni and Cr hydroxide to their respective free metal to give spherical nanoparticles ‎having the molecular size of 15-35 nanometer. SEM showed that Ni particles are ‎spherical in morphology. XRD and XDS showed Ni and Cr are pure.
输入废料为外径8 ~ 25mm的KanthalA4级尖顶合金。称重≈250g的样品在室温下用盐酸或王水浸出。对酸性渗滤液进行过滤,加入3 M氨水将pH值提高到4.0 ~ 9.2。通过添加H2O2使渗滤液脱除铁。采用lewaite MP 600离子交换剂,通过pH调节和溶剂萃取分离了铬离子和镍离子。氢氧化铵产生不溶性氢氧化铵ppt,经过滤和洗涤。不同有机盐类分别为:醋酸镍(OCOCH3)2、草酸C2O4、柠檬酸C6H6O5,含Ni的∆E为74.16 KJ/ mol,含Cr的∆E为139.33 KJ/ mol。还制备了Ni(NO3)2.6H2O、二氯NiCl2、碱式碳酸NiCO3.2Ni(OH)2等无机盐以及游离金属镍和铬。研究了工艺参数的影响。在300转/分的转速下搅拌可使合成时间缩短约11%。抗坏血酸溶液将Ni和Cr还原为各自的游离金属,得到分子尺寸为15-35纳米的球形纳米颗粒。扫描电镜显示,Ni颗粒呈球状。XRD和XDS表明Ni和Cr是纯的。
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引用次数: 0
Development of Mathematical Model for Percentage of Elongation of TIG Welded Duplex Stainless Steel 双相不锈钢TIG焊接伸长率数学模型的建立
Pub Date : 2022-02-05 DOI: 10.54392/irjmt2221
Sandip Mondal, G. Nandi, P. K. Pal
Quality strongly depends on good mechanical properties of any manufacturing material. Similarly, quality of Tungsten Inert Gas (TIG) welding of Duplex Stainless Steel (DSS) depends on good mechanical properties like percentage of elongation, ultimate tensile strength etc. Better Percentage of Elongation (PE) is produced using proper welding parameters and their values at the time of TIG welding. In this study, TIG welding has been done on ASTM/UNS 2205 duplex stainless steel materials. A new mathematical model is developed using non-linear regression analysis for the prediction of percentage of elongation. The variables used in the prediction models are selected welding parameters like welding current, gas flow rate and speed of welding. A residual plot for PE has been developed to validate the mathematical model. Calculation of percentage deviation for PE has been made. Comparison of measured and predicted PE value has been done by graphical representation. The relationship between percentage of elongation and the welding parameters has been illustrated graphically by surface plots and contour plots as well. Combined effects of any pair of input parameters on PE are represented graphically with the help of three-dimensional surface plots. According to this analysis, the models provide good PE with the data used in this study.
质量在很大程度上取决于任何制造材料的良好机械性能。同样,双相不锈钢(DSS)的钨惰性气体(TIG)焊接质量取决于良好的机械性能,如伸长率,极限抗拉强度等。采用适当的焊接参数及其在TIG焊接时的取值,可以获得较好的伸长率。在本研究中,ASTM/UNS 2205双相不锈钢材料进行了TIG焊接。利用非线性回归分析,建立了预测伸长率的数学模型。预测模型中使用的变量是选定的焊接参数,如焊接电流、气体流量和焊接速度。建立了PE残差图来验证数学模型。对PE的百分比偏差进行了计算。用图形表示方法对实测值和预测值进行了比较。用曲面图和等高线图图解了伸长率与焊接参数的关系。利用三维曲面图,以图形的形式表示任意一对输入参数对PE的综合影响。根据这一分析,该模型提供了良好的PE在本研究中使用的数据。
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引用次数: 0
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International Research Journal of Multidisciplinary Technovation
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