首页 > 最新文献

issue 2最新文献

英文 中文
Bioremediation of actual soil samples with high levels of crude oil using a bacterial consortium isolated from two polluted sites: investigation of the survival of the bacteria 利用从两个污染地点分离的细菌联合体对含高水平原油的实际土壤样品进行生物修复:细菌存活的调查
Pub Date : 2018-09-26 DOI: 10.30955/gnj.002681
R. SamarghandiM.
In this study, actual soil samples, taken from Kharg Island, Iran, with high levels of total petroleum hydrocarbons (TPHs) were bioremediated by a bacterial consortium. The strains were: Pseudomonas sp., Stenotrophomonas sp., Achromobacter sp., Brevibacillus sp. and Staphylococcus sp., which were isolated from two highly polluted sites: Kharg Island and Kermanshah Oil Refinery. The bacteria were identified and confirmed by biochemical tests and the PCR assay. In order to isolate the bacteria, the enrichment method, in which crude oil (2%) was utilized as the sole source of carbon and energy, was used. The results showed that the adapted bacterial consortium could degrade nearly 60% of the pollution. Also, it was found that after 100 days of bioremediation only Brevibacillus sp. could survive in the environment.
在这项研究中,实际的土壤样品,从Kharg岛,伊朗,具有高水平的总石油烃(TPHs)是由细菌财团的生物修复介导。菌株为假单胞菌、窄养单胞菌、无色杆菌、短芽孢杆菌和葡萄球菌,分别从Kharg岛和Kermanshah炼油厂两个高污染地点分离得到。通过生化试验和PCR法对细菌进行了鉴定和确认。为了分离细菌,采用以原油(2%)为唯一碳源和能量来源的富集法。结果表明,适应菌群可降解近60%的污染物。经过100天的生物修复,发现只有短芽孢杆菌能在环境中存活。
{"title":"Bioremediation of actual soil samples with high levels of crude oil using a bacterial consortium isolated from two polluted sites: investigation of the survival of the bacteria","authors":"R. SamarghandiM.","doi":"10.30955/gnj.002681","DOIUrl":"https://doi.org/10.30955/gnj.002681","url":null,"abstract":"In this study, actual soil samples, taken from Kharg Island, Iran, with high levels of total petroleum hydrocarbons (TPHs) were bioremediated by a bacterial consortium. The strains were: Pseudomonas sp., Stenotrophomonas sp., Achromobacter sp., Brevibacillus sp. and Staphylococcus sp., which were isolated from two highly polluted sites: Kharg Island and Kermanshah Oil Refinery. The bacteria were identified and confirmed by biochemical tests and the PCR assay. In order to isolate the bacteria, the enrichment method, in which crude oil (2%) was utilized as the sole source of carbon and energy, was used. The results showed that the adapted bacterial consortium could degrade nearly 60% of the pollution. Also, it was found that after 100 days of bioremediation only Brevibacillus sp. could survive in the environment.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78317377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Nano Zero-Valent Iron Supported on Activated Carbon: Effect of AC/nZVI Ratio on Removal of Nickel Ion from Water 活性炭负载纳米零价铁:AC/nZVI比对水中镍离子去除的影响
Pub Date : 2018-09-14 DOI: 10.30955/gnj.002718
S. Gungor
The present study investigated the possible effect of contact time, initial nickel concentration, and adsorbent concentration on removing Ni (II) ion, which is toxic to living organisms, from the aqueous media using nano zero valent iron (nZVI) and nano zero valent iron coated powdered activated carbon. A large portion of the nickel removal was achieved in a contact time of five minutes. A removal efficiency of barely 24% was able to be achieved only using activated carbon, while the nickel removal was achieved by approximately 80% using 200 mg/L nZVI. On the other hand, the efficiency was observed to increase up to 99% even with the particle containing the lowest nZVI in the experimental studies using the AC-nZVI nanoparticles containing AC at a rate of 25%, 50% and 75%. Adsorption capacity was increased from 125 mg/g and 820 mg/g for activated carbon and nZVI, respectively to 1190 mg/g for 50% AC-nZVI. Based on our study results, the effect of nZVI is promoted when nZVI is synthesized together with activated carbon. The Freundlich model was also found the best to represent the isotherm modeling made for nZVI.
采用纳米零价铁(nZVI)和纳米零价铁包覆粉末活性炭,研究了接触时间、初始镍浓度和吸附剂浓度对水介质中Ni (II)离子的去除可能产生的影响。大部分镍的去除是在5分钟的接触时间内完成的。仅使用活性炭,镍的去除率仅为24%,而使用200 mg/L的nZVI,镍的去除率约为80%。另一方面,在25%、50%和75%含AC-nZVI纳米颗粒的实验研究中,即使颗粒中含有最低的nZVI,效率也提高了99%。活性炭和nZVI的吸附量分别从125 mg/g和820 mg/g增加到50% AC-nZVI的1190 mg/g。根据我们的研究结果,当与活性炭一起合成nZVI时,可以提高nZVI的效果。Freundlich模型也被认为最能代表nZVI的等温线模型。
{"title":"Nano Zero-Valent Iron Supported on Activated Carbon: Effect of AC/nZVI Ratio on Removal of Nickel Ion from Water","authors":"S. Gungor","doi":"10.30955/gnj.002718","DOIUrl":"https://doi.org/10.30955/gnj.002718","url":null,"abstract":"The present study investigated the possible effect of contact time, initial nickel concentration, and adsorbent concentration on removing Ni (II) ion, which is toxic to living organisms, from the aqueous media using nano zero valent iron (nZVI) and nano zero valent iron coated powdered activated carbon. A large portion of the nickel removal was achieved in a contact time of five minutes. A removal efficiency of barely 24% was able to be achieved only using activated carbon, while the nickel removal was achieved by approximately 80% using 200 mg/L nZVI. On the other hand, the efficiency was observed to increase up to 99% even with the particle containing the lowest nZVI in the experimental studies using the AC-nZVI nanoparticles containing AC at a rate of 25%, 50% and 75%. Adsorption capacity was increased from 125 mg/g and 820 mg/g for activated carbon and nZVI, respectively to 1190 mg/g for 50% AC-nZVI. Based on our study results, the effect of nZVI is promoted when nZVI is synthesized together with activated carbon. The Freundlich model was also found the best to represent the isotherm modeling made for nZVI.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"304 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91552190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Assessment of Lead and Cadmium in Groundwater Sources Used for Drinking puposes in Jijel (northeastern Algeria). 吉耶勒(阿尔及利亚东北部)饮用用地下水中铅和镉的评估。
Pub Date : 2018-08-08 DOI: 10.30955/gnj.002747
N. Balli
Groundwater is one of the important sources of drinking water In Jijel (northeastern Algeria). Various analyses have shown critical concentrations of lead and cadmium in several groundwater sources used for drinking. The aim of this study is to evaluate the contamination by lead and cadmium of boreholes and hand-dug wells located in the catchment of the Nile River. Therefore, chemical analysis was performed on drinking water samples from eight boreholes; tow hand dug wells and one spring supplying Jijel city in drinking water. The water samples were examined for the presence of cadmium and lead using the SAA- 6200 Atomic Absorption Spectrophotometer (Shimadzu Corporation). The results of this study show high concentrations of lead (ranged from 72.84±0.26 to 458.95±0.55 μg.L-1) and cadmium (ranged from 12.41±0.88 to 33±0.38 μg.L-1) in all water samples. These concentrations far exceeded permissible values according to the WHO are drinking water posing a potential health risk for the public. The water quality in the studied area of Nile River basin must be considered very low.
地下水是吉耶勒(阿尔及利亚东北部)饮用水的重要来源之一。各种分析表明,几种饮用地下水中铅和镉的浓度已达到临界水平。本研究的目的是评估位于尼罗河集水区的钻孔和手挖井的铅和镉污染。为此,对8个钻孔的饮用水样本进行了化学分析;两口手挖井和一口泉水供应吉济市的饮用水。使用SAA- 6200原子吸收分光光度计(岛津公司)检测水样中镉和铅的存在。研究结果表明,所有水样均含有高浓度铅(72.84±0.26 ~ 458.95±0.55 μg.L-1)和镉(12.41±0.88 ~ 33±0.38 μg.L-1)。这些浓度远远超过了世界卫生组织的允许值,对公众的饮用水构成了潜在的健康风险。尼罗河流域研究区水质必须考虑到很低。
{"title":"Assessment of Lead and Cadmium in Groundwater Sources Used for Drinking puposes in Jijel (northeastern Algeria).","authors":"N. Balli","doi":"10.30955/gnj.002747","DOIUrl":"https://doi.org/10.30955/gnj.002747","url":null,"abstract":"Groundwater is one of the important sources of drinking water In Jijel (northeastern Algeria). Various analyses have shown critical concentrations of lead and cadmium in several groundwater sources used for drinking. The aim of this study is to evaluate the contamination by lead and cadmium of boreholes and hand-dug wells located in the catchment of the Nile River. Therefore, chemical analysis was performed on drinking water samples from eight boreholes; tow hand dug wells and one spring supplying Jijel city in drinking water. The water samples were examined for the presence of cadmium and lead using the SAA- 6200 Atomic Absorption Spectrophotometer (Shimadzu Corporation). The results of this study show high concentrations of lead (ranged from 72.84±0.26 to 458.95±0.55 μg.L-1) and cadmium (ranged from 12.41±0.88 to 33±0.38 μg.L-1) in all water samples. These concentrations far exceeded permissible values according to the WHO are drinking water posing a potential health risk for the public. The water quality in the studied area of Nile River basin must be considered very low.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"150 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77427363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Photocatalytic removal of cefazolin from aqueous solution by AC prepared from mango seed+ZnO under UV irradiation 芒果籽+ZnO制备AC光催化去除水溶液中头孢唑啉的研究
Pub Date : 2018-08-07 DOI: 10.30955/gnj.002588
M. Samarghandi, A. Rahmani, G. Asgari, Ghobad Ahmadidoost, A. Dargahi
Presence of antibiotics in the environment specially in aqueous environments is considered a major warning about health and environment. Thus, this study aims the efficiency of coupled process of Activated Carbon (AC) prepared from mango seed+ZnO under UV irradiation as an advanced oxidation process in removing cefazolin antibiotic from aqueous solutions. This experimental study was carried out in a discontinuous reaction chamber with volume of one liter. In this process, the effect of initial pH parameters of the environment (3– 9), initial concentration of cefazolin (20 – 200 mg/L), concentration of modified, photocatalyzer (20 – 100 mg/L) and reaction time (10 – 60 min) were studied. The pilot used consisted of a low pressure mercury lamp with a 55-watt beam radiation power inside the steel chamber. The kinetic of the process was studied based on pseudo first order kinetics. Results showed that the highest removal efficiency of cefazolin antibiotics in the reaction of UV/AC + ZnO, at optimal conditions of pH= 3, contact time of 60 min, initial concentration of 100 mg/L and modified photocatalyzer of 0.1 g/L was equal to 96%. The kinetic model determined for the process followed kinetic model of pseudo- first order kinetics with high correlation of (R2 = 0.99). Results of present study revealed that photocatalyzer process of nanoparticles oxidation on synthetic activated carbon can be effectively used as an advanced oxidation reaction to remove cefazolin and similar pollutants.
抗生素在环境中的存在,特别是在水环境中,被认为是对健康和环境的重大警告。因此,本研究旨在考察紫外辐照下芒果籽+氧化锌制备活性炭(AC)作为高级氧化工艺对头孢唑林抗生素的去除效果。本实验研究在容积为1升的不连续反应室中进行。考察了初始环境pH(3 ~ 9)、头孢唑啉初始浓度(20 ~ 200 mg/L)、改性剂浓度、光催化剂浓度(20 ~ 100 mg/L)、反应时间(10 ~ 60 min)等因素对反应的影响。飞行员使用的是一盏低压汞灯,在钢腔内具有55瓦的光束辐射功率。基于准一级动力学研究了该过程的动力学。结果表明,在pH= 3、接触时间为60 min、初始浓度为100 mg/L、改性光催化剂用量为0.1 g/L的条件下,头孢唑啉类抗生素在UV/AC + ZnO反应中去除率最高,达到96%。确定的动力学模型为准一级动力学模型,相关系数为(R2 = 0.99)。研究结果表明,纳米颗粒在合成活性炭上的光催化氧化工艺可以有效地作为一种高级氧化反应去除头孢唑啉等污染物。
{"title":"Photocatalytic removal of cefazolin from aqueous solution by AC prepared from mango seed+ZnO under UV irradiation","authors":"M. Samarghandi, A. Rahmani, G. Asgari, Ghobad Ahmadidoost, A. Dargahi","doi":"10.30955/gnj.002588","DOIUrl":"https://doi.org/10.30955/gnj.002588","url":null,"abstract":"Presence of antibiotics in the environment specially in aqueous environments is considered a major warning about health and environment. Thus, this study aims the efficiency of coupled process of Activated Carbon (AC) prepared from mango seed+ZnO under UV irradiation as an advanced oxidation process in removing cefazolin antibiotic from aqueous solutions. This experimental study was carried out in a discontinuous reaction chamber with volume of one liter. In this process, the effect of initial pH parameters of the environment (3– 9), initial concentration of cefazolin (20 – 200 mg/L), concentration of modified, photocatalyzer (20 – 100 mg/L) and reaction time (10 – 60 min) were studied. The pilot used consisted of a low pressure mercury lamp with a 55-watt beam radiation power inside the steel chamber. The kinetic of the process was studied based on pseudo first order kinetics. Results showed that the highest removal efficiency of cefazolin antibiotics in the reaction of UV/AC + ZnO, at optimal conditions of pH= 3, contact time of 60 min, initial concentration of 100 mg/L and modified photocatalyzer of 0.1 g/L was equal to 96%. The kinetic model determined for the process followed kinetic model of pseudo- first order kinetics with high correlation of (R2 = 0.99). Results of present study revealed that photocatalyzer process of nanoparticles oxidation on synthetic activated carbon can be effectively used as an advanced oxidation reaction to remove cefazolin and similar pollutants.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"25 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90967111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 40
Dye removal abilities of the mesophilic and thermophilic biomass: a kinetics study 中温和亲热生物质的脱染能力:动力学研究
Pub Date : 2018-08-07 DOI: 10.30955/gnj.002608
Mesophilic biomass and thermophilic biomass samples were isolated and used to remove Dorasyn Red dye from aqueous solutions. The biosorption kinetics of dye uptake by four different types of biomass at three temperatures (20, 30, and 40 °C) were investigated using pseudo-first order kinetics, pseudo-second order kinetics, intraparticle diffusion, Elovich, and Bangham models. The pseudo-second-order kinetics model and the first stage of the intraparticle diffusion model were effective in describing the experimental kinetics data. The biosorption results showed that the mesophilic biomass samples could be useful for removing dye under acidic conditions.
分离了中温生物质的和亲热生物质的样品,并用于从水溶液中去除Dorasyn Red染料。采用拟一级动力学、拟二级动力学、颗粒内扩散、Elovich和Bangham模型研究了四种不同类型生物质在三种温度(20、30和40°C)下对染料的生物吸附动力学。拟二级动力学模型和一级颗粒内扩散模型是对实验动力学数据的有效描述。结果表明,在酸性条件下,中亲水性生物质样品可用于脱除染料。
{"title":"Dye removal abilities of the mesophilic and thermophilic biomass: a kinetics study","authors":"","doi":"10.30955/gnj.002608","DOIUrl":"https://doi.org/10.30955/gnj.002608","url":null,"abstract":"Mesophilic biomass and thermophilic biomass samples were isolated and used to remove Dorasyn Red dye from aqueous solutions. The biosorption kinetics of dye uptake by four different types of biomass at three temperatures (20, 30, and 40 °C) were investigated using pseudo-first order kinetics, pseudo-second order kinetics, intraparticle diffusion, Elovich, and Bangham models. The pseudo-second-order kinetics model and the first stage of the intraparticle diffusion model were effective in describing the experimental kinetics data. The biosorption results showed that the mesophilic biomass samples could be useful for removing dye under acidic conditions.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79888971","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A preliminary effort to reduce carcinogenic polycyclic aromatic hydrocarbons from diesel exhaust by using different blends of diesel and synthesized Biodiesel 通过使用不同的柴油和合成生物柴油混合物来减少柴油废气中致癌的多环芳烃
Pub Date : 2018-08-06 DOI: 10.30955/gnj.002549
V. Kumar, P. Vikas, Saruchi, R. Sharma, A. Masih, N. C. Kothiyal
In the present investigation, an attempt for the reduction of six hazardous air Pollutants (HAPs) from diesel exhaust by different blends of diesel and biodiesel has been made. The synthesis of biodiesel has been done from Jetrofa, Linseed Castor and Karanja oils which are commonly used in the Indian market. Blending of diesel with biodiesel was done in different ratios (20 to 40 %) for the estimation of carcinogenic HAPs from the exhaust of a Honda engine (EBK 2010AC Model). The order of HAPs emission from engine exhaust by using diverse blends were Diesel>Jatropha-diesel>Linseed-diesel>Castor-diesel> Karanja-diesel. The maximum reduction of HAPs was established in the following ratio 40% (Biodiesel):60% (Diesel). B(a)P and Chrysene were the two individual aromatic hydrocarbons (AHCs) found in higher concentration in almost all blending fuels, ranging between 50 ng/µl to 101.1 ng/µl. The emission of almost all AHCs reduces by Blending of Diesel with Biodiesel. This was the first comprehensive information which showed the reduction of carcinogenic pollutants from diesel exhaust.
在本研究中,尝试通过不同的柴油和生物柴油混合物来减少柴油废气中的六种有害空气污染物。生物柴油的合成已经从印度市场上常用的亚麻籽蓖麻油和Karanja油中完成。将柴油与生物柴油按不同比例(20%至40%)混合,以估计本田发动机(EBK 2010AC型号)废气中的致癌性HAPs。不同混合燃料对发动机尾气中HAPs排放的影响顺序为:柴油>麻疯子-柴油>亚麻籽-柴油>蓖麻-柴油> karanja -柴油。hap的最大减少量为40%(生物柴油):60%(柴油)。B(a)P和Chrysene是几乎所有混合燃料中浓度较高的两种单独的芳烃(AHCs),浓度范围在50 ng/µl至101.1 ng/µl之间。柴油与生物柴油混合后,几乎所有AHCs的排放量都减少了。这是第一次全面的资料显示减少了柴油废气中的致癌污染物。
{"title":"A preliminary effort to reduce carcinogenic polycyclic aromatic hydrocarbons from diesel exhaust by using different blends of diesel and synthesized Biodiesel","authors":"V. Kumar, P. Vikas, Saruchi, R. Sharma, A. Masih, N. C. Kothiyal","doi":"10.30955/gnj.002549","DOIUrl":"https://doi.org/10.30955/gnj.002549","url":null,"abstract":"In the present investigation, an attempt for the reduction of six hazardous air Pollutants (HAPs) from diesel exhaust by different blends of diesel and biodiesel has been made. The synthesis of biodiesel has been done from Jetrofa, Linseed Castor and Karanja oils which are commonly used in the Indian market. Blending of diesel with biodiesel was done in different ratios (20 to 40 %) for the estimation of carcinogenic HAPs from the exhaust of a Honda engine (EBK 2010AC Model). The order of HAPs emission from engine exhaust by using diverse blends were Diesel>Jatropha-diesel>Linseed-diesel>Castor-diesel> Karanja-diesel. The maximum reduction of HAPs was established in the following ratio 40% (Biodiesel):60% (Diesel). B(a)P and Chrysene were the two individual aromatic hydrocarbons (AHCs) found in higher concentration in almost all blending fuels, ranging between 50 ng/µl to 101.1 ng/µl. The emission of almost all AHCs reduces by Blending of Diesel with Biodiesel. This was the first comprehensive information which showed the reduction of carcinogenic pollutants from diesel exhaust.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"32 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78945225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Kinetics and adsorption studies of lead (II) onto activated carbon using low cost adsorbents 低成本吸附剂对铅(II)在活性炭上的吸附动力学研究
Pub Date : 2018-08-02 DOI: 10.30955/gnj.002532
The removal of Lead (II) from aqueous solutions using Fagopyrum esculentum Moench (Buckwheat) and Bambusa vulgaris (common bamboo) as adsorbents was investigated. The effects of various experimental parameters such as initial concentration, contact time and pH have been studied using batch adsorption technique. All the Adsorption isotherm models fitted well with the adsorption data. However, Freundlich isotherm displayed a better fitting model than the other two isotherm models due to high correlation coefficient (R2). This indicates the applicability of multilayer coverage of the Pb (II) on the surface of adsorbent. The adsorption kinetics was studied using four simplified models and it was found to follow the pseudo-second-order kinetic model which confirmed the applicability of the model. The adsorption mechanism was found to be chemisorption and the rate-limiting step was mainly surface adsorption.
研究了以荞麦和竹材为吸附剂对铅(II)的去除效果。采用间歇吸附技术研究了初始浓度、接触时间和pH等实验参数对吸附效果的影响。所得吸附等温线模型与吸附数据拟合良好。而Freundlich等温线由于具有较高的相关系数(R2),其拟合效果较好。这说明了Pb (II)在吸附剂表面多层覆盖的适用性。采用四种简化模型对吸附动力学进行了研究,发现其符合准二级动力学模型,证实了模型的适用性。吸附机理以化学吸附为主,限速步骤以表面吸附为主。
{"title":"Kinetics and adsorption studies of lead (II) onto activated carbon using low cost adsorbents","authors":"","doi":"10.30955/gnj.002532","DOIUrl":"https://doi.org/10.30955/gnj.002532","url":null,"abstract":"The removal of Lead (II) from aqueous solutions using Fagopyrum esculentum Moench (Buckwheat) and Bambusa vulgaris (common bamboo) as adsorbents was investigated. The effects of various experimental parameters such as initial concentration, contact time and pH have been studied using batch adsorption technique. All the Adsorption isotherm models fitted well with the adsorption data. However, Freundlich isotherm displayed a better fitting model than the other two isotherm models due to high correlation coefficient (R2). This indicates the applicability of multilayer coverage of the Pb (II) on the surface of adsorbent. The adsorption kinetics was studied using four simplified models and it was found to follow the pseudo-second-order kinetic model which confirmed the applicability of the model. The adsorption mechanism was found to be chemisorption and the rate-limiting step was mainly surface adsorption.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77562723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Effects of using Tamarindus indica Seeds as a natural coagulant aid in landfill leachate treatment 柽柳种子作为天然混凝剂处理垃圾渗滤液的效果
Pub Date : 2018-07-27 DOI: 10.30955/gnj.002462
Aziz H.A, Y. Y.C., Syed Zainal S.F.F, Ramli S.F
Uncontrolled landfill leachate generation portends danger to the environment and aquatic ecosystem, especially without prior treatment before discharge. The application of Al-based coagulants, such as polyaluminum chloride (PACl), has the potential of introducing Al residuals into water bodies. Therefore, an alternative natural coagulant was recommended to reduce the usage of Al-based coagulants. In this study, a coagulation–flocculation process using the combination of PACl as coagulant and Tamarindus indica seed (TiS) as coagulant aid was used in treating the landfill leachate from the Alor Pongsu Landfill Site in Malaysia. Some of the optimum operational conditions determined were the pH and dosage of the coagulant aid, and their effect was considered on parameters, such as suspended solids (SS), color, and COD, using standard jar test procedures. The combination of TiS flocculant reduced the dosage of PACl coagulant from 5,000 mg/L to 2,750 mg/L with removal efficiencies of 99.3%, 97.3%, and 67.4% for SS, color, and COD, respectively.
垃圾渗滤液的产生未经控制,特别是在排放前未经处理,对环境和水生生态系统构成威胁。铝基混凝剂的应用,如聚氯化铝(PACl),有可能将铝残留物引入水体。因此,推荐一种替代的天然混凝剂来减少铝基混凝剂的使用。本研究以PACl为混凝剂,柽柳种子(TiS)为助凝剂,采用混凝-絮凝工艺处理马来西亚Alor Pongsu垃圾填埋场的垃圾渗滤液。确定的一些最佳操作条件是助凝剂的pH和用量,以及它们对悬浮物(SS)、颜色和COD等参数的影响,使用标准罐测试程序。TiS混凝剂可将PACl混凝剂的投加量从5000 mg/L降至2750 mg/L,对SS、颜色和COD的去除率分别达到99.3%、97.3%和67.4%。
{"title":"Effects of using Tamarindus indica Seeds as a natural coagulant aid in landfill leachate treatment","authors":"Aziz H.A, Y. Y.C., Syed Zainal S.F.F, Ramli S.F","doi":"10.30955/gnj.002462","DOIUrl":"https://doi.org/10.30955/gnj.002462","url":null,"abstract":"Uncontrolled landfill leachate generation portends danger to the environment and aquatic ecosystem, especially without prior treatment before discharge. The application of Al-based coagulants, such as polyaluminum chloride (PACl), has the potential of introducing Al residuals into water bodies. Therefore, an alternative natural coagulant was recommended to reduce the usage of Al-based coagulants. In this study, a coagulation–flocculation process using the combination of PACl as coagulant and Tamarindus indica seed (TiS) as coagulant aid was used in treating the landfill leachate from the Alor Pongsu Landfill Site in Malaysia. Some of the optimum operational conditions determined were the pH and dosage of the coagulant aid, and their effect was considered on parameters, such as suspended solids (SS), color, and COD, using standard jar test procedures. The combination of TiS flocculant reduced the dosage of PACl coagulant from 5,000 mg/L to 2,750 mg/L with removal efficiencies of 99.3%, 97.3%, and 67.4% for SS, color, and COD, respectively.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"26 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73461893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
Kinetic, isotherm and thermodynamic investigations of nitrite (NO2–) removal from water by anion exchange resins 阴离子交换树脂去除水中亚硝酸盐(NO2 -)的动力学、等温线和热力学研究
Pub Date : 2018-07-24 DOI: 10.30955/gnj.002433
This study presents the evaluation of a strong base (Purolite A200) and weak base (Purolite PFA847) polymeric anion exchange resins for nitrite removal. The different parameters on the removal of NO2– were investigated in batch sorption mode. Common isotherm models; Langmuir and Freundlich, were used in order to present a description of the equilibrium data. Experimental results showed that the equilibrium data tend to follow Freundlich isotherm model for weak base resin and Langmuir model for strong base resin. The sorption of NO2– on anion exchange resins was found to follow the pseudo-second order kinetic model. The values of thermodynamic parameters proved that ion exchange reaction of NO2– onto such resins are endothermic (ΔH > 0).
研究了强碱(Purolite A200)和弱碱(Purolite PFA847)聚合物阴离子交换树脂对亚硝酸盐的去除效果。在间歇吸附模式下,考察了不同吸附参数对NO2 -去除率的影响。常用等温线模型;Langmuir和Freundlich,被用来描述平衡数据。实验结果表明,弱碱树脂的平衡数据服从Freundlich等温模型,强碱树脂的平衡数据服从Langmuir等温模型。阴离子交换树脂对NO2 -的吸附符合准二级动力学模型。热力学参数值证明NO2 -与树脂的离子交换反应为吸热反应(ΔH > 0)。
{"title":"Kinetic, isotherm and thermodynamic investigations of nitrite (NO2–) removal from water by anion exchange resins","authors":"","doi":"10.30955/gnj.002433","DOIUrl":"https://doi.org/10.30955/gnj.002433","url":null,"abstract":"This study presents the evaluation of a strong base (Purolite A200) and weak base (Purolite PFA847) polymeric anion exchange resins for nitrite removal. The different parameters on the removal of NO2– were investigated in batch sorption mode. Common isotherm models; Langmuir and Freundlich, were used in order to present a description of the equilibrium data. Experimental results showed that the equilibrium data tend to follow Freundlich isotherm model for weak base resin and Langmuir model for strong base resin. The sorption of NO2– on anion exchange resins was found to follow the pseudo-second order kinetic model. The values of thermodynamic parameters proved that ion exchange reaction of NO2– onto such resins are endothermic (ΔH > 0).","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"66 4 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84254564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
A comprehensive evaluation of the level of noise pollution in hospitals of Kermanshah University of Medical Sciences 克尔曼沙阿医科大学医院噪声污染水平综合评价
Pub Date : 2018-07-23 DOI: 10.30955/gnj.002416
Noise pollution higher than the standard values intensifies the patients' disease and also has negative effects on hospital staff. This study aimed to determine the level of noise pollution in the Kermanshah hospitals and also to compare obtained data with national and international standards. Multifunctional sound level meter (Model CEL – 450), has been applied for determining the sound level in different parts of a hospital in 3 different time of day (morning, visiting hours (evening), and night) for working day and holiday. The highest level was on working days and it was 60.24±5.76 dB. The average noise level on holiday was 58.15±5.44 dB. Generally, the average noise level in all studied hospitals was higher than the standard levels. The results of the analyses showed that when the P=0.003, there’s a significant difference between the average noise levels on different days. According to the results of the studies, it is necessary to plan and take managerial and technical – engineering measures to reduce the noise levels to standard levels.
高于标准值的噪声污染加重了患者的病情,对医院工作人员也有负面影响。这项研究旨在确定克尔曼沙医院的噪音污染水平,并将获得的数据与国家和国际标准进行比较。多功能声级计(CEL - 450型),用于在工作日和节假日的3个不同时间(上午、探视时间(晚上)和晚上)测定医院不同部位的声级。在工作日最高,为60.24±5.76 dB。假期平均噪声为58.15±5.44 dB。总体而言,所有医院的平均噪声水平均高于标准水平。分析结果表明,当P=0.003时,不同天的平均噪声水平之间存在显著差异。根据研究结果,有必要规划并采取管理和技术工程措施,将噪声水平降低到标准水平。
{"title":"A comprehensive evaluation of the level of noise pollution in hospitals of Kermanshah University of Medical Sciences","authors":"","doi":"10.30955/gnj.002416","DOIUrl":"https://doi.org/10.30955/gnj.002416","url":null,"abstract":"Noise pollution higher than the standard values intensifies the patients' disease and also has negative effects on hospital staff. This study aimed to determine the level of noise pollution in the Kermanshah hospitals and also to compare obtained data with national and international standards. Multifunctional sound level meter (Model CEL – 450), has been applied for determining the sound level in different parts of a hospital in 3 different time of day (morning, visiting hours (evening), and night) for working day and holiday. The highest level was on working days and it was 60.24±5.76 dB. The average noise level on holiday was 58.15±5.44 dB. Generally, the average noise level in all studied hospitals was higher than the standard levels. The results of the analyses showed that when the P=0.003, there’s a significant difference between the average noise levels on different days. According to the results of the studies, it is necessary to plan and take managerial and technical – engineering measures to reduce the noise levels to standard levels.","PeriodicalId":14606,"journal":{"name":"issue 2","volume":"10 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88058800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
issue 2
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1