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Photocatalytic Degradation of Methyl blue by TiO2 Nanoparticles Incorporated in Cement 水泥纳米TiO2光催化降解甲基蓝的研究
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v20i1.1042
Ban Alshabander, Mays Bassim Abd-Alkader
In this study, titanium dioxide (TiO2) nanoparticles incorporated with cement were synthesis by a simple casting method as a function concentration of TiO2 (0.2, 0.4, 0.8, 1, and 2 wt%). The prepared samples were characterized using the technique of Field Emission Scanning Electron Microscope (FESEM) and UV-Visible spectrophotometer, which was used to measure the adsorption spectra. The observed photocatalytic efficiency of TiO2 nanoparticles (NP) incorporated with cement was investigated by decomposing the dye methyl blue (MB) solution under sunlight irradiation. According to the slope, the value of the k constant at the best sample is 0.8wt%, k=0.8265 min-1. FESEM image of the TiO2/cement with 0.8 wt% content show the TiO2 NPs were well-attached to cement particles, and they covered the cement surface. The increase in photocatalytic (PC) activity was due to an increase of TiO2 concentration in the cement, which best occur of 0.8 wt% of TiO2 in cement. The degradation at the MB (5ppm) was 98.864 % after 120 min under sunlight irradiation. The method involves easily and simply preparing TiO2/cement that is used in self-cleaning and studying the effect of different festive factors, including the concentration of the dye. The preparation of TiO2/cement was successful as a photocatalyst for a self-cleaning surface.
在本研究中,以TiO2的功能浓度(0.2、0.4、0.8、1、2 wt%)为条件,通过简单铸造法合成了与水泥掺入的二氧化钛纳米颗粒。采用场发射扫描电镜(FESEM)和紫外可见分光光度计对制备的样品进行了表征,并用紫外可见分光光度计测定了样品的吸附光谱。通过在日光照射下分解甲基蓝(MB)染料溶液,考察了水泥掺入TiO2纳米颗粒(NP)的光催化效率。由斜率可知,最佳样本处k常数值为0.8wt%, k=0.8265 min-1。掺量为0.8 wt%的TiO2/水泥的FESEM图像显示,TiO2 NPs与水泥颗粒附着良好,覆盖在水泥表面。光催化(PC)活性的增加主要是由于水泥中TiO2浓度的增加,当水泥中TiO2浓度为0.8 wt%时,光催化(PC)活性最好。在MB (5ppm)条件下,辐照120 min,降解率为98.864%。该方法简单易行地制备了用于自清洁的TiO2/水泥,并研究了不同节日因素(包括染料浓度)的影响。二氧化钛/水泥的制备成功地作为自清洁表面的光催化剂。
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引用次数: 1
Evaluation of Resonance Strengths and Reaction Rates of 22Ne (p, gamma) 23Na Nuclear Reaction at Thermonuclear Energies 热核能下22Ne (p, γ) 23Na核反应共振强度和反应速率的评价
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v21i1.1086
Ahmed A.Selman
At thermal energies near stellar conditions, nuclear reactions are sensitive to resonance strengths of the nuclear reaction cross-section. In this paper, the resonance strengths of  nuclear reaction were evaluated numerically by means of nuclear reaction rate calculations using a written Matlab code, at the energies of interest in stellar nuclear reactions. The results were compared with standard reaction before and after application of a statistical analyses, to select the best parameters that made theoretical results as close as possible to the standard values. Fitting was made for different temperature ranges up to 10 GK, 0.6 GK and 0.25 GK. The evaluated results showed that as the temperature range becomes narrower, more error is added to the evaluated strengths. A proper strength value based on the most recent measured one suggested the difference of at least one order of magnitude can be solved using a numerical evaluation for energies less than 650 keV.
在接近恒星的热能条件下,核反应对核反应截面的共振强度很敏感。本文利用编写的Matlab代码,通过核反应速率计算,对恒星核反应中感兴趣的能量下的核反应共振强度进行了数值计算。应用统计分析方法将结果与标准反应前后进行比较,以选择最佳参数,使理论结果尽可能接近标准值。配件适用于不同的温度范围,最高可达10 GK, 0.6 GK和0.25 GK。评估结果表明,随着温度范围的缩小,评估强度的误差增加。根据最近测量的强度值,一个合适的强度值表明,对于小于650 keV的能量,可以用数值计算来解决至少一个数量级的差异。
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引用次数: 0
Calculation Mars – Earth distance and Mars orbital elements with Julian date 用儒略历计算火星-地球距离和火星轨道元素
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v21i1.1081
Atared Y. Qahtan
In this paper, the Mars orbital elements were calculated. These orbital elements—the major axis, the inclination (i), the longitude of the ascending node (W), the argument of the perigee (w), and the eccentricity (e)—are essential to knowing the size and shape of Mars' orbit. The quick basic program was used to calculate the orbital elements and distance of Mars from the Earth from 25/5/1950 over 10000 days. These were calculated using the empirical formula of Meeus, which depended on the Julian date, which slightly changed for 10000 days; Kepler's equation was solved to find Mars' position and its distance from the Sun. The ecliptic and equatorial coordinates of Mars were calculated. The distance between Mars and the center of the Earth, in astronomical units (A.U.), was calculated. RM-E(min) was found to be between 0.4763 and 0.5108, and RM-E(max) was found to be between 2.548 and 2.6259. Furthermore, the findings revealed that the Mars orbital elements have changed over time. 
本文对火星轨道要素进行了计算。这些轨道元素——长轴、倾角(i)、升交点经度(W)、近地点角(W)和偏心率(e)——对于了解火星轨道的大小和形状至关重要。快速基本程序用于计算从1950年5月25日开始的10000天内火星与地球的轨道元素和距离。这些都是用Meeus的经验公式计算出来的,该公式依赖于儒略历,儒略历在10000天内略有变化;人们解出了开普勒方程,从而找到了火星的位置和它到太阳的距离。计算了火星的黄道坐标和赤道坐标。火星和地球中心之间的距离,以天文单位(au)计算。RM-E(min)在0.4763 ~ 0.5108之间,RM-E(max)在2.548 ~ 2.6259之间。此外,研究结果还表明,火星轨道元素随着时间的推移而发生了变化。
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引用次数: 0
FTIR and electrical behavior of blend electrolytes based on (PVA/PVP) 基于(PVA/PVP)的共混电解质的FTIR和电学行为
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v20i1.1093
Fatima ALjubouri, Mohammed Kadhim Jawad
Solution cast method was used to create the polymer electrolytes. Under certain circumstances, the electrolyte content of polymers was determined using constant percent PVA/PVP(50:50),EC and PC (1:1) with various quantities of KI (10, 20, 30, 40, 50 wt. %) and iodine I2 = 10 % of salt wt. The complicated formation of polymer blends was validated by FTIR investigations. Electrical conductivity was measured using an impedance analyzer at frequencies ranging from 50 Hz to 1MHz and temperatures ranging from 293 K to 343 K. At ambient temperature, an electrolyte with 50% KI content had a higher electrical conductivity value of 5.3 10-3 (S/cm). The magnitude of electrical conductivity increased as salt content and temperature rose. The blend electrolytes' greater dielectric at lower frequencies might be owing to the dipoles having enough time to align with the electric field, resulting in stronger polarisation. The reduction in activation energy (Ea) suggests that faster-conducting electrolytes prefer to move with less energy.
采用溶液铸造法制备聚合物电解质。在一定的条件下,聚合物的电解质含量采用固定比例的PVA/PVP(50:50),EC和PC(1:1),不同数量的KI (10,20,30,40,50 wt. %)和碘I2 = 10%的盐wt来测定。FTIR研究证实了聚合物共混物的复杂形成。电导率测量使用阻抗分析仪,频率范围为50 Hz至1MHz,温度范围为293 K至343 K。常温下,KI含量为50%的电解质电导率较高,为5.3 10-3 (S/cm)。随着含盐量和温度的升高,电导率的幅度增大。混合电解质在较低频率下的更大介电可能是由于偶极子有足够的时间与电场对齐,从而产生更强的极化。活化能(Ea)的降低表明,导电快的电解质倾向于以更少的能量运动。
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引用次数: 0
Investigate Indian Costus Plasma Parameters using Q-Switched Laser Nd: YAG 用调q激光Nd: YAG研究印度Costus等离子体参数
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v21i1.1083
Alyaa Hussein, Hadder M. Abdullah
The Indian costus plasma properties are investigated including electron temperature (Te), "electron density (ne)", "plasma frequency (fp)", " Debye sphere length", and amount of Debye(Nd),  using the spectrum of optical emission technique. There are several energies used, with ranging from 300 to 600 mJ. The Boltzmann Plot is used to calculate the temperature; where as Stark's Line Broadening is used to calculate the electron density. The Indian costus was spectroscopically examined in the air with the laser  at 10 cm away from the target and the optical fiber  at 0.5 cm away. The results were obtained for an electron temperature range of (1.8-2.2) electron volts (ev) and a wavelength range of (300-600) nm. The XRF analysis reveals that the Indian costus contains a variety of minerals, each with a different percentage, which explains why the optical emission spectrum has so many peaks. When the laser energy is  (between 300 and 600 mJ) the  "optical emission spectroscopy (OES) "has been  used to analyze the plasma spectrum of the Indian costus in the air. The results shows that as the laser energy grew, the amount of Debye will be greater i-e (Nd) >>>1,  which is one of the plasma properties.
利用光谱发射技术研究了印度costus等离子体的电子温度(Te)、电子密度(ne)、等离子体频率(fp)、德拜球长度(Debye)和德拜量(Nd)等特性。有几种能量被使用,范围从300到600兆焦耳。用玻尔兹曼图计算温度;其中斯塔克线展宽法用于计算电子密度。在空气中,激光距离目标10厘米,光纤距离目标0.5厘米,对印度服装进行光谱检测。结果表明,电子温度范围为1.8 ~ 2.2电子伏特(ev),波长范围为300 ~ 600 nm。XRF分析显示,印度古斯特含有多种矿物质,每种矿物质的百分比都不同,这就解释了为什么光学发射光谱有这么多峰。当激光能量在300 ~ 600 mJ之间时,光学发射光谱(OES)已被用于分析空气中印度古斯特的等离子体光谱。结果表明,随着激光能量的增大,Debye的量会增大i-e (Nd) >>>1,这是等离子体的性质之一。
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引用次数: 0
FTIR and electrical behavior of blend electrolytes based on (PVA/PVP) 基于(PVA/PVP)的共混电解质的FTIR和电学行为
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v21i1.1093
Fatima ALjubouri, Mohammed Kadhim Jawad
Solution cast method was used to create the polymer electrolytes. Under certain circumstances, the electrolyte content of polymers was determined using constant percent PVA/PVP(50:50),EC and PC (1:1) with various quantities of KI (10, 20, 30, 40, 50 wt. %) and iodine I2 = 10 % of salt wt. The complicated formation of polymer blends was validated by FTIR investigations. Electrical conductivity was measured using an impedance analyzer at frequencies ranging from 50 Hz to 1MHz and temperatures ranging from 293 K to 343 K. At ambient temperature, an electrolyte with 50% KI content had a higher electrical conductivity value of 5.3 10-3 (S/cm). The magnitude of electrical conductivity increased as salt content and temperature rose. The blend electrolytes' greater dielectric at lower frequencies might be owing to the dipoles having enough time to align with the electric field, resulting in stronger polarisation. The reduction in activation energy (Ea) suggests that faster-conducting electrolytes prefer to move with less energy.
采用溶液铸造法制备聚合物电解质。在一定的条件下,聚合物的电解质含量采用固定比例的PVA/PVP(50:50),EC和PC(1:1),不同数量的KI (10,20,30,40,50 wt. %)和碘I2 = 10%的盐wt来测定。FTIR研究证实了聚合物共混物的复杂形成。电导率测量使用阻抗分析仪,频率范围为50 Hz至1MHz,温度范围为293 K至343 K。常温下,KI含量为50%的电解质电导率较高,为5.3 10-3 (S/cm)。随着含盐量和温度的升高,电导率的幅度增大。混合电解质在较低频率下的更大介电可能是由于偶极子有足够的时间与电场对齐,从而产生更强的极化。活化能(Ea)的降低表明,导电快的电解质倾向于以更少的能量运动。
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引用次数: 0
Geographical Distribution of Landfills in the Outskirts of Baghdad Governorate using the GIS 利用GIS研究巴格达省郊区垃圾填埋场的地理分布
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v21i1.1080
Zehraanajim ZehraaNajim
The problem of solid waste from domestic, industrial, commercial and medical sources is one of the most important problems facing the local administration in all Iraqi cities. The danger of this problem increases with the rapid increase in the population, changing lifestyles, consumption patterns, limited land suitable for landfill, and high costs of collection and disposal. This research aims to solve these problems by determining the locations of current landfills located in the outskirts of Baghdad Governorate. The ArcGIS program was used, where the sites of the landfills were determined on the map and through the available data about the areas. it was concluded that the existing landfill sites do not meet environmental conditions and standards. According to the statistics of 2016/2020, which the amount of waste in some areas has increased, and decreased in others. The results show that each of 16 municipalities at the outskirts of Baghdad Governorate has only one landfill. The Al-Zuhur district is one of the most waste-producing areas, according to the statistics of the years 2016/2020, due to the high population ratio in that area. Mahmudiyah was recorded among high rate waste production areas, as the amount of waste in 2016 was 49,000 tons, but decreased slightly in 2020 to 48,000 tons. The research recommends following the health and environmental foundations in proper planning for the establishment of waste dumps, as well as the necessity of activating the role of geographic information systems in the field of proper waste management and environmental planning.
家庭、工业、商业和医疗来源的固体废物问题是伊拉克所有城市地方行政部门面临的最重要问题之一。随着人口的迅速增长、生活方式和消费模式的改变、适合填埋的土地有限以及收集和处置费用高昂,这一问题的危险性也在增加。本研究旨在通过确定目前位于巴格达省郊区的垃圾填埋场的位置来解决这些问题。使用ArcGIS程序,在地图上通过有关该地区的可用数据确定垃圾填埋场的位置。结论是,现有的垃圾填埋场不符合环境条件和标准。根据2016/2020年的统计,其中一些地区的垃圾量增加了,而另一些地区则减少了。结果显示,巴格达省郊区的16个市镇中,每个市镇只有一个垃圾填埋场。根据2016/2020年的统计数据,由于该地区的人口比例高,Al-Zuhur地区是产生废物最多的地区之一。Mahmudiyah被记录为高废物产出率地区之一,2016年的废物量为49,000吨,但在2020年略有下降至48,000吨。该研究建议在适当规划建立废物倾倒场时遵循健康和环境基础,以及必须在适当废物管理和环境规划领域发挥地理信息系统的作用。
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引用次数: 1
Theoretical Computation of Electron Density in Laser-Induced Carbon Plasma using Anisimov Model 用Anisimov模型理论计算激光诱导碳等离子体中电子密度
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v21i1.1082
Mohammed Alhamadani
In this work, electron number density calculated using Matlab program code with the writing algorithm of the program. Electron density was calculated using Anisimov model in a vacuum environment. The effect of spatial coordinates on the electron density was investigated in this study. It was found that the Z axis distance direction affects the electron number density (ne). There are many processes such as excitation; ionization and recombination within the plasma that possible affect the density of electrons. The results show that as Z axis distance increases electron number density decreases because of the recombination of electrons and ions at large distances from the target and the loss of thermal energy of the electrons in high distance with the progress of time and at a certain coordinate. The target is carbon (Graphite). The results were selected in four dimensions where three of them belong to spatial coordinates x, y, z and the fourth dimension is the electron density (ne).
在本工作中,利用Matlab程序代码计算电子数密度,并编写程序的算法。利用Anisimov模型计算了真空环境下的电子密度。本文研究了空间坐标对电子密度的影响。发现Z轴距离方向影响电子数密度(ne)。有许多过程,如激发;等离子体内部可能影响电子密度的电离和重组。结果表明,随着Z轴距离的增加,电子数密度随着时间的推移和某一坐标上电子与离子在离靶较远的地方发生复合以及电子在离靶较远的地方的热能损失而减小。目标是碳(石墨)。结果在四个维度上选择,其中三个维度属于空间坐标x, y, z,第四个维度是电子密度(ne)。
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引用次数: 0
Bandwidth Improvement of a Cone-Inverted Cylindrical and Cross Hybrids Dielectric Resonator Antennas 锥形-倒圆柱形和交叉混合介质谐振器天线的带宽改进
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v21i1.1084
N. Areebi, J. N. Jabir
In this work, two cone-inverted cylindrical and cross-hybrid dielectric resonator antennas are stacked and excited by the coaxial probe method with an operating standard resonant frequency of 5.438 GHz. A drawback of these standard Dielectric Resonator Antennas (DRAs) is their narrow bandwidth. For good antenna performance, a stacked DR geometry and a thick dielectric substrate having a low dielectric constant are desired since this provides large bandwidth, better radiation power, reduces conductor loss and nonappearance of surface waves. Many approaches, such as changing the shape of the dielectric resonator, have been used to enhance bandwidth. Using DRA, having the lowest dielectric constant, increases the bandwidth and the electromagnetic energy. In the current work, bandwidth improvement was significantly achieved by the proposed geometry by varying the antenna size.  A novel hybrid DRA configuration is used to increase the bandwidth of the antenna to 89.27% and 149.23% due to cone-inverted cylindrical and cross-hybrid dielectric resonator antennas, respectively. The DRA is designed numerically via Finite Difference Time Domain (FDTD) method. Several parameters like return loss, input impedance (verified at ) and radiation pattern are calculated. Furthermore, the stacked-hybrid technique is used to enhance the antenna's performance which is useful for broadband communication and the demand of wireless.
本文采用同轴探针法对两个锥形倒圆柱形和交叉混合介质谐振器天线进行堆叠和激励,工作标准谐振频率为5.438 GHz。这些标准介质谐振器天线(DRAs)的一个缺点是它们的带宽很窄。为了获得良好的天线性能,需要堆叠DR几何结构和具有低介电常数的厚介质基板,因为这可以提供大带宽,更好的辐射功率,减少导体损耗和表面波的不可见性。许多方法,如改变介电谐振器的形状,已被用来提高带宽。使用具有最低介电常数的DRA,增加了带宽和电磁能量。在目前的工作中,通过改变天线尺寸,所提出的几何形状显著提高了带宽。采用了一种新型的混合DRA结构,将天线带宽分别提高到89.27%和149.23%,分别采用了锥形倒圆柱形和交叉混合介质谐振器天线。采用时域有限差分法(FDTD)对DRA进行了数值设计。计算了回波损耗、输入阻抗(验证点)和辐射方向图等参数。此外,还采用了叠加混合技术来提高天线的性能,以满足宽带通信和无线需求。
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引用次数: 0
Design and Construction of a Dust Detection System using Infrared Laser: The Case of Dust Storms in Baghdad in the Summer 2022 红外激光粉尘探测系统的设计与建设——以2022年夏季巴格达沙尘暴为例
Pub Date : 2023-03-01 DOI: 10.30723/ijp.v21i1.1077
Faten Abdel-Wahhab Abdel-Razzaq, A. A. Dhaigham, Sameer Khudhur Yaseen
Iraq suffers from serious pollution with harmful particles that have important direct and indirect effects on human activities and human health. In this research, a system for detecting pollutants in the air was designed and manufactured using infrared laser technology. This system was used to detect the presence of pollutants in the dust storms that swept the city of Baghdad which could have a negative impact on human health and living organisms.The designed detection system based on the use of infrared laser (IR) with a wavelength of 1064 nm was used for the purposes of detecting pollutants based on the scattering of the laser beam from these pollutants. The system was aligned to obtain the best signal for the scattered rays, which were detected using a digital storage oscilloscope.These studies were conducted during the dust storms that occurred intensely in Baghdad in the months (April, May, June and July) of the year 2022. Where multiple samples were taken at different periods in these storms, measurements were also done during the storm. The types of polluting elements found in the dust of the storms are: carbon, bromine, chlorine, hydrocarbons alcohol, ether, hydroxyl group, carbon, C=C (aromatic ring), nitrogen dioxide (aromatic nitro), and carbon monoxide. The value ​​of dust pollutant concentrations is (125.67 mg. m-3).
伊拉克受到有害粒子的严重污染,对人类活动和人类健康产生重要的直接和间接影响。本研究利用红外激光技术,设计并制造了一套空气污染物检测系统。该系统用于检测横扫巴格达市的沙尘暴中是否存在可能对人类健康和生物产生负面影响的污染物。设计了基于波长为1064 nm的红外激光器的检测系统,利用激光对污染物的散射特性对污染物进行检测。利用数字存储示波器对散射射线进行了检测,并对系统进行了校准以获得最佳的散射信号。这些研究是在2022年4月、5月、6月和7月巴格达发生强烈沙尘暴期间进行的。在这些风暴的不同时期采集了多个样本,在风暴期间也进行了测量。在沙尘暴尘埃中发现的污染元素类型有:碳、溴、氯、碳氢化合物、醇、醚、羟基、碳、C=C(芳香环)、二氧化氮(芳香硝基)和一氧化碳。粉尘污染物浓度值为(125.67 mg)。m3)。
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引用次数: 0
期刊
Iraqi Journal of Physics (IJP)
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