In this study, titanium dioxide (TiO2) nanoparticles incorporated with cement were synthesized by a simple casting method as a function of the concentration of TiO2 (0.2, 0.4, 0.8, 1, and 2 wt%). The prepared samples were characterized using the techniques of Field Emission Scanning Electron Microscope (FESEM) and UV-Visible spectrophotometer, which were used to measure the adsorption spectra. The observed photocatalytic efficiency of TiO2 nanoparticles (NP) incorporated with cement was investigated by decomposing the dye methyl blue (MB) solution under sunlight irradiation. According to the slope, the value of the k constant at the best sample is 0.8 wt%, k = 0.8265 min-1. FESEM images of the TiO2/cement with 0.8 wt% content show the TiO2 NPs were well-attached to cement particles, and they covered the cement surface. The increase in photocatalytic (PC) activity was due to an increase in TiO2 concentration in the cement, which best occurs at 0.8 wt% of TiO2 in cement. The degradation at the MB (5 ppm) was 98.864 % after 120 min of sunlight irradiation. The method involves easily and simply preparing TiO2/cement that is used in self-cleaning and studying the effect of different festive factors, including the concentration of the dye. The preparation of TiO2/cement was successful as a photocatalyst for a self-cleaning surface.
{"title":"Photocatalytic Degradation of Methyl blue by TiO2 Nanoparticles Incorporated in Cement","authors":"Ban Alshabander, None Mays Bassim Abd-Alkader","doi":"10.30723/ijp.v21i1.1042","DOIUrl":"https://doi.org/10.30723/ijp.v21i1.1042","url":null,"abstract":"In this study, titanium dioxide (TiO2) nanoparticles incorporated with cement were synthesized by a simple casting method as a function of the concentration of TiO2 (0.2, 0.4, 0.8, 1, and 2 wt%). The prepared samples were characterized using the techniques of Field Emission Scanning Electron Microscope (FESEM) and UV-Visible spectrophotometer, which were used to measure the adsorption spectra. The observed photocatalytic efficiency of TiO2 nanoparticles (NP) incorporated with cement was investigated by decomposing the dye methyl blue (MB) solution under sunlight irradiation. According to the slope, the value of the k constant at the best sample is 0.8 wt%, k = 0.8265 min-1. FESEM images of the TiO2/cement with 0.8 wt% content show the TiO2 NPs were well-attached to cement particles, and they covered the cement surface. The increase in photocatalytic (PC) activity was due to an increase in TiO2 concentration in the cement, which best occurs at 0.8 wt% of TiO2 in cement. The degradation at the MB (5 ppm) was 98.864 % after 120 min of sunlight irradiation. The method involves easily and simply preparing TiO2/cement that is used in self-cleaning and studying the effect of different festive factors, including the concentration of the dye. The preparation of TiO2/cement was successful as a photocatalyst for a self-cleaning surface.","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136095224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Coaxial (wire-cylinder) electrodes arrangements are widely used for electrostatic deposition of dust particles in flue gases, when a high voltage is applied to electrodes immersed in air and provide a strongly non-uniform electric field. The efficiency of electrostatic filters mainly depends on the value of the applied voltage and the distribution of the electric field. In this work, a two-dimensional computer simulation was constructed to study the effect of different applied voltages (20, 22, 25, 26, 28, 30 kV) on the inner electrode and their effect on the efficiency of the electrostatic precipitator. Finite Element Method (FEM) and COMSOL Multiphysics software were used to simulate the cross section of a wire cylinder. The results showed that the velocity of the liquid and the charge accumulation of the particles increased with the increase of the applied voltage and also the efficiency of the precipitator increased and reached 100% with an applied voltage of 30 kV.
{"title":"Numerical Simulation for Cylindrical Electrostatic Precipitator: Effect of the Applied Voltage","authors":"Athraa A. Hussein, Thamir H. Khalaf","doi":"10.30723/ijp.v20i4.1035","DOIUrl":"https://doi.org/10.30723/ijp.v20i4.1035","url":null,"abstract":"Coaxial (wire-cylinder) electrodes arrangements are widely used for electrostatic deposition of dust particles in flue gases, when a high voltage is applied to electrodes immersed in air and provide a strongly non-uniform electric field. The efficiency of electrostatic filters mainly depends on the value of the applied voltage and the distribution of the electric field. In this work, a two-dimensional computer simulation was constructed to study the effect of different applied voltages (20, 22, 25, 26, 28, 30 kV) on the inner electrode and their effect on the efficiency of the electrostatic precipitator. Finite Element Method (FEM) and COMSOL Multiphysics software were used to simulate the cross section of a wire cylinder. The results showed that the velocity of the liquid and the charge accumulation of the particles increased with the increase of the applied voltage and also the efficiency of the precipitator increased and reached 100% with an applied voltage of 30 kV.","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76222138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the present work, it had been measured the concentration of radon gas (CRn) for (10) samples of cement used in constructions before and after painting them using enamel paint, purchased from the local markets, to see the extent of its ability to reduce emissions of Rn-222 in the air. These samples were obtained from different sources available in the local markets in Baghdad and other provinces. The measurements were done by the American-made detector (RAD7). The results showed that the highest CRn in the air emitted from cement samples after coating was in the cement sample (Iranian origin) where the concentration was (58.27 Bq/m3) while the lowest CRn was found in building material samples in the white cement sample (Turkish origin) was (15.74 Bq/m3). In view of the present results, it has been confirmed that the concentration of Rn-222 emitted into the air in all building material samples is below the agency's permissible limit (ICRP).
{"title":"Studying the Possibility of using Paint to Reduce the Amount of Radon Gas Emitted from Cement","authors":"Ehsan Abdul, Hussein Soleman, Firas Hashem, Salim Karim","doi":"10.30723/ijp.v20i4.1049","DOIUrl":"https://doi.org/10.30723/ijp.v20i4.1049","url":null,"abstract":"In the present work, it had been measured the concentration of radon gas (CRn) for (10) samples of cement used in constructions before and after painting them using enamel paint, purchased from the local markets, to see the extent of its ability to reduce emissions of Rn-222 in the air. These samples were obtained from different sources available in the local markets in Baghdad and other provinces. The measurements were done by the American-made detector (RAD7). The results showed that the highest CRn in the air emitted from cement samples after coating was in the cement sample (Iranian origin) where the concentration was (58.27 Bq/m3) while the lowest CRn was found in building material samples in the white cement sample (Turkish origin) was (15.74 Bq/m3). In view of the present results, it has been confirmed that the concentration of Rn-222 emitted into the air in all building material samples is below the agency's permissible limit (ICRP). ","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87950353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. L. Sheu, K. O. Suleman, Q. A. Adeniji, Ismaheel Aderogba Azeez
This study reported the investigation of the Radio Frequency (RF) signal propagation of Global System for Mobile Communications (GSM) coverage in Emmanuel Alayande College of Education (EACOED), Oyo, Oyo State, Nigeria. The study aims at amplifying the quality of service and augment end users' sensitivity of the wireless services operation. The drive test method is adopted with estimation of coverage level and received signal strength. The Network Cell Info Lite application installed in three INFINIX GSM mobile phones was employed to take the measurement of the signal strength received from the transmitting stations of different mobile networks. The results of the study revealed that MTN has the maximum signal strength with a mean value of - 68.33 dBm, directly followed by Globacom (-80.41 dBm) and Airtel with -83.13 dBm. The Airtel signal has a conspicuously invariable poor performance with coverage level of 41.66 %. Conversely, the MTN and Globacom signal reception are observed to surpass the Airtel network within the college premises with 83.33 % and 60.41 % coverage level respectively. This implies that the signal quality for MTN and Globacom networks were comparatively disseminated within the college with inconsequential fluctuations in quality while Airtel signal is subsided and weaken. The poor performance in some areas was due to the presence of physical impediments and far distances location of base station antennas in the promulgation locations. This study therefore suggested that Airtel and Globacom Base Transceiver Stations (BTS) should be positioned within the college to improve good network reportage level.
{"title":"Investigation of Radio Frequency Signal Propagation of Wireless Services in Oyo, Oyo State, South Western Nigeria","authors":"A. L. Sheu, K. O. Suleman, Q. A. Adeniji, Ismaheel Aderogba Azeez","doi":"10.30723/ijp.v20i4.1014","DOIUrl":"https://doi.org/10.30723/ijp.v20i4.1014","url":null,"abstract":"This study reported the investigation of the Radio Frequency (RF) signal propagation of Global System for Mobile Communications (GSM) coverage in Emmanuel Alayande College of Education (EACOED), Oyo, Oyo State, Nigeria. The study aims at amplifying the quality of service and augment end users' sensitivity of the wireless services operation. The drive test method is adopted with estimation of coverage level and received signal strength. The Network Cell Info Lite application installed in three INFINIX GSM mobile phones was employed to take the measurement of the signal strength received from the transmitting stations of different mobile networks. The results of the study revealed that MTN has the maximum signal strength with a mean value of - 68.33 dBm, directly followed by Globacom (-80.41 dBm) and Airtel with -83.13 dBm. The Airtel signal has a conspicuously invariable poor performance with coverage level of 41.66 %. Conversely, the MTN and Globacom signal reception are observed to surpass the Airtel network within the college premises with 83.33 % and 60.41 % coverage level respectively. This implies that the signal quality for MTN and Globacom networks were comparatively disseminated within the college with inconsequential fluctuations in quality while Airtel signal is subsided and weaken. The poor performance in some areas was due to the presence of physical impediments and far distances location of base station antennas in the promulgation locations. This study therefore suggested that Airtel and Globacom Base Transceiver Stations (BTS) should be positioned within the college to improve good network reportage level. ","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88933398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this work, zinc oxide nanoparticles (ZnONPs) and sawdust/epoxy composite (20:80) were mixed using a simple molding method with different ZnONPs concentrations of (0.1, 0.3, 0.5, 0.7, and 1.0 %). The samples of the nanocomposites were characterized by the Scanning Electron Microscopy (SEM) technique to demonstrate the homogeneity of the prepared ZnONPs/nanocomposites. The photocatalytic activity of the samples was examined using the methylene blue (MB) dye as a pollutant solution, through evaluation of the efficiency of the prepared compound in the treatment of organic pollutants under illumination by sunlight. The photocatalytic results showed that after 240 minutes of exposure to sunlight, the sample prepared using (0.5 vol.% of ZnONPs) appeared to rapid degradation of MB dye, with photolysis efficiency of 89% and 71% for dye concentrations 5 and 10 ppm, respectively. Wettability results confirmed that the water contact angles of samples (WCAs) were affected by the concentration of ZnONPs.
{"title":"Photocatalytic Activity and Wettability Properties of ZnO/Sawdust/Epoxy Composites","authors":"Safaa Ahmed Al-Lhaibi, Ban Mazin Al-Shabander","doi":"10.30723/ijp.v20i4.1051","DOIUrl":"https://doi.org/10.30723/ijp.v20i4.1051","url":null,"abstract":"In this work, zinc oxide nanoparticles (ZnONPs) and sawdust/epoxy composite (20:80) were mixed using a simple molding method with different ZnONPs concentrations of (0.1, 0.3, 0.5, 0.7, and 1.0 %). The samples of the nanocomposites were characterized by the Scanning Electron Microscopy (SEM) technique to demonstrate the homogeneity of the prepared ZnONPs/nanocomposites. The photocatalytic activity of the samples was examined using the methylene blue (MB) dye as a pollutant solution, through evaluation of the efficiency of the prepared compound in the treatment of organic pollutants under illumination by sunlight. The photocatalytic results showed that after 240 minutes of exposure to sunlight, the sample prepared using (0.5 vol.% of ZnONPs) appeared to rapid degradation of MB dye, with photolysis efficiency of 89% and 71% for dye concentrations 5 and 10 ppm, respectively. Wettability results confirmed that the water contact angles of samples (WCAs) were affected by the concentration of ZnONPs. ","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88517396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The ground-state properties of exotic 18N and 20F nuclei, including the neutron, proton and matter densities and related radii are investigated using the two-body model of within Gaussian (GS) and Woods Saxon (WS) wave functions. The long tail is evident in the computed neutron and matter densities of these nuclei. The plane wave Born approximation (PWBA) is calculate the elastic form factors of these exotic nuclei. The variation in the proton density distributions due to the presence of the extra neutrons in 18N and 20F leads to a major difference between the elastic form factors of these exotic nuclei and their stable isotopes 14N and 19F. The reaction cross sections for these nuclei are investigated using the Kox and Glauber models. Furthermore, the Glauber model is employed to calculate the matter radii of these exotic nuclei. The calculated results for the selected exotic nuclei are in a good agreement with the experimental data.
{"title":"Elastic Form Factors and Matter Density Distributions of Some Neutron-Rich Nuclei","authors":"Hawraa K. Mahdi, A. Abdullah","doi":"10.30723/ijp.v20i4.1013","DOIUrl":"https://doi.org/10.30723/ijp.v20i4.1013","url":null,"abstract":"The ground-state properties of exotic 18N and 20F nuclei, including the neutron, proton and matter densities and related radii are investigated using the two-body model of within Gaussian (GS) and Woods Saxon (WS) wave functions. The long tail is evident in the computed neutron and matter densities of these nuclei. The plane wave Born approximation (PWBA) is calculate the elastic form factors of these exotic nuclei. The variation in the proton density distributions due to the presence of the extra neutrons in 18N and 20F leads to a major difference between the elastic form factors of these exotic nuclei and their stable isotopes 14N and 19F. The reaction cross sections for these nuclei are investigated using the Kox and Glauber models. Furthermore, the Glauber model is employed to calculate the matter radii of these exotic nuclei. The calculated results for the selected exotic nuclei are in a good agreement with the experimental data. ","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86320533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Recently, research has focused on non-thermal plasma (NTP) technologies as a way to remove volatile organic compounds from the air stream, due to its distinctive qualities, which include a quick reaction at room temperature. In this work, the properties of the plasma generated by the dielectric barrier discharge (DBD) system and by a glass insulator were studied. Plasma was generated at different voltages (3, 4, 6, 7, 8 kV ) with a fixed distance between the electrodes of 5 mm, and a constant argon gas flow rate of (2.5) I/min. DBD plasma emission spectra were recorded for each voltage. The Boltzmann plot method was used to calculate the electron temperature in the plasma ( ), and the Stark expansion method was used to calculate the electron density ( ). The decomposition of organic compounds (cyclohexane) was also studied using DBD plasma. The results showed that the potential difference between the two electrodes has a clear effect on the plasma parameters, as the temperature of the electrons and the density of electrons increase with the increase in the potential difference between the two electrodes. The DBD plasma system proved to be a good way to decompose volatile organic compounds, as the results proved the emission of hydrogen gas as one of the dissociation products of cyclohexane.
{"title":"Study the Effect of Dielectric Barrier Discharge (DBD) Plasma on the Decomposition of Volatile Organic Compounds","authors":"Hiba Qassim Farag, Saba J. Kadhem","doi":"10.30723/ijp.v20i4.1056","DOIUrl":"https://doi.org/10.30723/ijp.v20i4.1056","url":null,"abstract":"Recently, research has focused on non-thermal plasma (NTP) technologies as a way to remove volatile organic compounds from the air stream, due to its distinctive qualities, which include a quick reaction at room temperature. In this work, the properties of the plasma generated by the dielectric barrier discharge (DBD) system and by a glass insulator were studied. Plasma was generated at different voltages (3, 4, 6, 7, 8 kV ) with a fixed distance between the electrodes of 5 mm, and a constant argon gas flow rate of (2.5) I/min. DBD plasma emission spectra were recorded for each voltage. The Boltzmann plot method was used to calculate the electron temperature in the plasma ( ), and the Stark expansion method was used to calculate the electron density ( ). The decomposition of organic compounds (cyclohexane) was also studied using DBD plasma. The results showed that the potential difference between the two electrodes has a clear effect on the plasma parameters, as the temperature of the electrons and the density of electrons increase with the increase in the potential difference between the two electrodes. The DBD plasma system proved to be a good way to decompose volatile organic compounds, as the results proved the emission of hydrogen gas as one of the dissociation products of cyclohexane.","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78361661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The purpose of this study was to find out the connection between the water parameters that were examined in the laboratory and the water index acquired from the examination of the satellite image of the study area. This was accomplished by analysing the Landsat-8 satellite picture results as well as the geographic information system (GIS). The primary goal of this study is to develop a model for the chemical and physical characteristics of the Al-Abbasia River in Al-Najaf Al-Ashraf Governorate. The water parameters employed in this investigation are as follows: (PH, EC, TDS, TSS, Na, Mg, K, SO4, Cl, and NO3). To collect the samples, ten sampling locations were identified, and the satellite image was obtained on the same day. Geographical information systems (GIS) are commonly used for the process of projecting the coordination often Stations Along Al-Abbasia River in the image of the satellite (Landsat-8) to then analyze the spectral reflections of the items and then treat the data obtained after the analysis process by using (SPSS) Software to find the correlation coefficient and regression equations. Because of the high connections between water metrics and the water index, four regression models were discovered. These models can be used to predict the four water variables (EC, SO4, Cl, and NO3) at any point along the Al-Abbasia River directly from the satellite image.
{"title":"Detection of Physical and Chemical Parameters Using Water Indices (NDWI, MNDWI, NDMI, WRI, and AWEI) for Al-Abbasia River in Al-Najaf Al-Ashraf Governorate Using Remote Sensing and Geographic Information System (GIS) Techniques","authors":"Rusul Al-Hakeem, Qusai Y. Al-Kubaisi","doi":"10.30723/ijp.v20i4.1021","DOIUrl":"https://doi.org/10.30723/ijp.v20i4.1021","url":null,"abstract":"The purpose of this study was to find out the connection between the water parameters that were examined in the laboratory and the water index acquired from the examination of the satellite image of the study area. This was accomplished by analysing the Landsat-8 satellite picture results as well as the geographic information system (GIS). The primary goal of this study is to develop a model for the chemical and physical characteristics of the Al-Abbasia River in Al-Najaf Al-Ashraf Governorate. The water parameters employed in this investigation are as follows: (PH, EC, TDS, TSS, Na, Mg, K, SO4, Cl, and NO3). To collect the samples, ten sampling locations were identified, and the satellite image was obtained on the same day. Geographical information systems (GIS) are commonly used for the process of projecting the coordination often Stations Along Al-Abbasia River in the image of the satellite (Landsat-8) to then analyze the spectral reflections of the items and then treat the data obtained after the analysis process by using (SPSS) Software to find the correlation coefficient and regression equations. Because of the high connections between water metrics and the water index, four regression models were discovered. These models can be used to predict the four water variables (EC, SO4, Cl, and NO3) at any point along the Al-Abbasia River directly from the satellite image.","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90655037","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A metal-assisted chemical etching process employing p-type silicon wafers with varied etching durations is used to produce silicon nanowires. Silver nanoparticles prepared by chemical deposition are utilized as a catalyst in the formation of silicon nanowires. Images from field emission scanning electron microscopy confirmed that the diameter of SiNWs grows when the etching duration is increased. The photoelectrochemical cell's characteristics were investigated using p-type silicon nanowires as working electrodes. Linear sweep voltammetry (J-V) measurements on p-SiNWs confirmed that photocurrent density rose from 0.20 mA cm-2 to 0.92 mA cm-2 as the etching duration of prepared SiNWs increased from 15 to 30 min. The conversion efficiency (ƞ) was 0.47 for p-SiNWs prepared with a 15-minute etching time and 0.75 for p-SiNWs prepared with a 30-minute etching time. The cyclic voltammetry (CV) experiments performed at various scan rates validated the faradic behavior of p-SiNWS prepared for 15 and 30 min of etching. Because of the slow ion diffusion and the increased scanning rate, the capacitance decreased with increasing scanning rate. Mott-Schottky (M-S) investigation showed a significant carriers concentration of 3.66×1020 cm-3. According to the results of electrochemical impedance spectroscopy (EIS), the SiNWs photocathode prepared by etching for 30 min had a charge transfer resistance of 25.27 Ω, which is low enough to enhance interfacial charge transfer.
采用金属辅助化学蚀刻工艺，采用不同蚀刻时间的p型硅片制备硅纳米线。利用化学沉积法制备的银纳米粒子作为硅纳米线形成的催化剂。场发射扫描电镜图像证实，随着刻蚀时间的延长，SiNWs的直径增大。以p型硅纳米线为工作电极，研究了该光化学电池的性能。线性扫描伏安法(J-V)测量证实，随着刻蚀时间从15分钟增加到30分钟，p-SiNWs的光电流密度从0.20 mA cm-2增加到0.92 mA cm-2。刻蚀时间为15分钟的p-SiNWs的转换效率为0.47，刻蚀时间为30分钟的p-SiNWs的转换效率为0.75。在不同扫描速率下进行的循环伏安(CV)实验验证了蚀刻15和30分钟制备的p-SiNWS的faradic行为。由于离子扩散缓慢和扫描速率的增加，电容随扫描速率的增加而减小。Mott-Schottky (M-S)调查显示，载体浓度显著为3.66×1020 cm-3。电化学阻抗谱(EIS)结果表明，蚀刻30 min制备的SiNWs光电阴极的电荷转移电阻为25.27 Ω，足以增强界面电荷转移。
{"title":"Preparation of Silicon Nanowires Photocathode for Photoelectrochemical Water Splitting","authors":"Zainab K. Ali, Mazin A. Mahdi","doi":"10.30723/ijp.v20i4.1070","DOIUrl":"https://doi.org/10.30723/ijp.v20i4.1070","url":null,"abstract":"A metal-assisted chemical etching process employing p-type silicon wafers with varied etching durations is used to produce silicon nanowires. Silver nanoparticles prepared by chemical deposition are utilized as a catalyst in the formation of silicon nanowires. Images from field emission scanning electron microscopy confirmed that the diameter of SiNWs grows when the etching duration is increased. The photoelectrochemical cell's characteristics were investigated using p-type silicon nanowires as working electrodes. Linear sweep voltammetry (J-V) measurements on p-SiNWs confirmed that photocurrent density rose from 0.20 mA cm-2 to 0.92 mA cm-2 as the etching duration of prepared SiNWs increased from 15 to 30 min. The conversion efficiency (ƞ) was 0.47 for p-SiNWs prepared with a 15-minute etching time and 0.75 for p-SiNWs prepared with a 30-minute etching time. The cyclic voltammetry (CV) experiments performed at various scan rates validated the faradic behavior of p-SiNWS prepared for 15 and 30 min of etching. Because of the slow ion diffusion and the increased scanning rate, the capacitance decreased with increasing scanning rate. Mott-Schottky (M-S) investigation showed a significant carriers concentration of 3.66×1020 cm-3. According to the results of electrochemical impedance spectroscopy (EIS), the SiNWs photocathode prepared by etching for 30 min had a charge transfer resistance of 25.27 Ω, which is low enough to enhance interfacial charge transfer.","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72775414","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
According to Chandra Survey Observatory Near-Asteroid Belt Comets, the solar wind's contact with the comet produces a variety of spectral characteristics. The study of X-ray spectra produced by charge exchange is presented here. The spectrum of a comet can reveal a lot about its composition. This study has concentrated on the elemental abundance in six different comets, including 17P/Holmes, C/1999T1, C/2013A1, 9p/Temple1, and 103p/Hartley2 (NEAT). Numerous aspects of the comet's dynamics allow it to behave in a unique manner as it gets closer to the Near-Asteroid Belt. These characteristics are being examined, and some studies are still ongoing. The computations allow us to observe, for instance, how the composition of a comet's upper atmosphere affects how much gas it produces. For several comet morphologies, both linear and nonlinear, bow shock, contact surface, and stagnation point are investigated in relation to gas production rate. Our results shed light on the complex interactions between cometary ions and the solar wind. An increase in gas production rate was shown to be significantly correlated with sharp drops in average molecular weight.
{"title":"X-Ray Emission Spectroscopy Analysis for Near-Asteroid Belt of Atmospheric of the Comets","authors":"Rasha S. Najm, Salman Z. Khalaf, Khaleel I. Abood","doi":"10.30723/ijp.v20i3.1006","DOIUrl":"https://doi.org/10.30723/ijp.v20i3.1006","url":null,"abstract":" According to Chandra Survey Observatory Near-Asteroid Belt Comets, the solar wind's contact with the comet produces a variety of spectral characteristics. The study of X-ray spectra produced by charge exchange is presented here. The spectrum of a comet can reveal a lot about its composition. This study has concentrated on the elemental abundance in six different comets, including 17P/Holmes, C/1999T1, C/2013A1, 9p/Temple1, and 103p/Hartley2 (NEAT). Numerous aspects of the comet's dynamics allow it to behave in a unique manner as it gets closer to the Near-Asteroid Belt. These characteristics are being examined, and some studies are still ongoing. The computations allow us to observe, for instance, how the composition of a comet's upper atmosphere affects how much gas it produces. For several comet morphologies, both linear and nonlinear, bow shock, contact surface, and stagnation point are investigated in relation to gas production rate. Our results shed light on the complex interactions between cometary ions and the solar wind. An increase in gas production rate was shown to be significantly correlated with sharp drops in average molecular weight.","PeriodicalId":14653,"journal":{"name":"Iraqi Journal of Physics (IJP)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84047812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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