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Effects of Hydrogen Peroxide Concentration on Properties of Black Silicon Fabricated by Two-Step Silver-Assisted Wet Chemical Etching for Photovoltaics 过氧化氢浓度对两步银辅助湿法化学蚀刻制备的光伏用黑硅性能的影响
Pub Date : 2022-06-01 DOI: 10.30723/ijp.v20i2.985
Auwal Abdulkadir, M. Z. Pakhuruddin
Crystalline silicon (c-Si) has low optical absorption due to its high surface reflection of incident light. Nanotexturing of c-Si which produces black silicon (b-Si) offers a promising solution. In this work, effect of H2O2 concentrations towards surface morphological and optical properties of b-Si fabricated by two-step silver-assisted wet chemical etching (Ag-based two-step MACE) for potential photovoltaic (PV) applications is presented. The method involves a 30 s deposition of silver nanoparticles (Ag NPs) in an aqueous solution of AgNO3:HF (5:6) and an optimized etching in HF:H2O2:DI H2O solution under 0.62 M, 1.85 M, 2.47 M, and 3.7 M concentrations of H2O2 at 5 M HF. On the b-Si, nanowires with 250-950 nm heights and an average diameter of 150-280 nm are obtained. Low concentrations of H2O2 result in denser nanowires with an average length of 900-950 nm and diameters of about 150-190 nm. The b-Si exhibit outstanding broadband antireflection due to the refractive index grading effect represented as WAR within the 300-1100 nm wavelength region. B-Si obtained after etching in a solution with 0.62 M concentration of H2O2, demonstrate WAR of 7.5%. WAR of 7.5% results in an absorption of up to 95.5 % at a wavelength of 600 nm. The enhanced broadband light absorption yields maximum potential short-circuit current density (Jsc(max)) of up to 38.2 mA/cm2, or 45.2% enhancement compared to the planar c-Si reference.
晶体硅(c-Si)由于其对入射光的高表面反射而具有低的光吸收。c-Si纳米织构制备黑硅(b-Si)提供了一个很有前途的解决方案。在这项工作中,H2O2浓度对两步银辅助湿化学蚀刻(银基两步MACE)制备的潜在光伏(PV)应用的b-Si表面形貌和光学性质的影响。该方法包括在AgNO3:HF(5:6)的水溶液中沉积银纳米粒子(Ag NPs) 30 s,并在HF:H2O2:DI H2O溶液中,在5 M HF下,在浓度为0.62 M, 1.85 M, 2.47 M和3.7 M的H2O2中进行优化蚀刻。在b-Si上,得到了高度为250 ~ 950 nm,平均直径为150 ~ 280 nm的纳米线。低浓度的H2O2导致纳米线密度更大,平均长度为900-950 nm,直径约为150-190 nm。由于在300-1100 nm波长范围内的折射率分级效应(WAR), b-Si表现出优异的宽带抗反射性能。在浓度为0.62 M的H2O2溶液中蚀刻得到的B-Si, WAR值为7.5%。7.5%的WAR在600纳米波长处的吸收率高达95.5%。增强的宽带光吸收产生的最大潜在短路电流密度(Jsc(max))高达38.2 mA/cm2,与平面c-Si基准相比提高了45.2%。
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引用次数: 1
Enhanced Mechanical Property of Acrylic Polymer/Graphene/Carbon Fibers Hybrid for Water Proof Coating 增强丙烯酸聚合物/石墨烯/碳纤维复合防水涂料力学性能的研究
Pub Date : 2022-06-01 DOI: 10.30723/ijp.v20i2.982
T. M. Abbas, Seenaa I. Hussein
In this work, some mechanical properties of the polymer coating were improved by preparing a hybrid system containing Graphene (GR) of different weight percentages (0.25, 0.5, 1, and 2wt%) with 5wt% carbon fibres (CF) and added to a polymer coating by using casting method. The properties were improved as GR was added with further improvement on adding 5wt% of CF. The impact strength of acrylic polymer with GR increases with increasing weight ratio‏‏ of GR; maximum value was obtained when the polymer coating was incorporated with 1wt% GR and 5wt% CF. The impact strength of acrylic polymer with GR and GR/CF composites incorporated with GR at 1wt% and CF at 5wt%. Hardness increase with increasing weight ratio of Gr and a significant improvement was observed at 1wt% GR and 5wt% CF content. The tensile strength increases more significantly than the acrylic polymer with GR and GR/CF composites incorporated with GR at 1wt% and CF at 5wt%. Pull-off strength for the polymer coating with GR and CF was greater than for the acrylic polymer coating.
在这项工作中,通过制备含有不同重量百分比(0.25、0.5、1和2wt%)的石墨烯(GR)和5wt%的碳纤维(CF)的混合体系,并通过铸造法将其添加到聚合物涂层中,从而改善了聚合物涂层的一些机械性能。当CF添加量为5wt%时,丙烯酸聚合物的抗冲击强度随GR质量比的增加而增加;聚合物涂层中GR和CF的掺入量分别为1wt%和5wt%,丙烯酸聚合物和GR/CF复合材料的冲击强度分别为1wt%和5wt%。硬度随Gr重量比的增加而增加,当Gr含量为1wt%、CF含量为5wt%时,硬度有显著提高。与添加GR和GR/CF的丙烯酸聚合物相比,添加GR为1wt%和CF为5wt%的复合材料的抗拉强度提高更明显。含GR和CF的聚合物涂层的脱拉强度大于丙烯酸聚合物涂层。
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引用次数: 1
Evaluation of Mechanical Properties for Epoxy reinforced with palm oil /Zinc oxide composites 棕榈油/氧化锌环氧树脂增强复合材料的力学性能评价
Pub Date : 2022-06-01 DOI: 10.30723/ijp.v20i2.978
Diyar J. Hassana, N. Ali
In this research, the effect of reinforcing epoxy resin composites with a filler derived from chopped agriculture waste from oil palm (OP). Epoxy/OP composites were formed by dispersing (1, 3, 5, and 10 wt%) OP filler using a high-speed mechanical stirrer utilizing a hand lay-up method. The effect of adding zinc oxide (ZnO) nanoparticles, with an average size of 10-30 nm, with different wt% (1,2,3, and 5wt%) to the epoxy/oil palm composite,  on the behavior of an epoxy/oil palm composite was studied with different ratios (1,2,3, and 5wt%) and an average size of  10-30 nm.  Fourier Transform Infrared (FTIR) spectrometry and mechanical properties (tensile, impact, hardness, and wear rate) were used to examine the composites. The FTIR results show a strong interaction between ZnO and oil palm fiber and epoxy resin. Tensile strength was reduced from 22.78 MPa to 19.03 MPa for the epoxy/OP composite as the wt% of OP was increased but increased to 29.224MPa for epoxy /oil palm / 5% ZnO samples. Young modulus increased from 1.9 MPa to 4.3 MPa while elongation decreased (9.6 to 6.8 %) with the increase of wt% OP and ZnO. The impact and hardness increased for all composites between (6.94 - 10.8 KJ/m2) and between (80.8- 84.55 KJ/m2) respectively. Also, wear resistance of the epoxy/OP and epoxy/OP/ZnO samples increased with the increase of wt% OP and ZnO. This studied in order to provide a new step in the utilization of green nanoparticle fillers for sustainable and renewable structural products for biodegradability.
本研究以油棕农业废弃物为填料,对环氧树脂复合材料进行补强。环氧/OP复合材料是通过使用高速机械搅拌器利用手铺法分散(1、3、5和10 wt%)的OP填料形成的。研究了在环氧树脂/油棕复合材料中添加不同wt%(1、2、3和5wt%)的氧化锌纳米颗粒(ZnO)对环氧树脂/油棕复合材料性能的影响,氧化锌纳米颗粒的平均粒径为10-30 nm,添加比例为1、2、3和5wt%。采用傅里叶变换红外光谱(FTIR)和力学性能(拉伸、冲击、硬度和磨损率)对复合材料进行了检测。红外光谱结果表明,氧化锌与油棕纤维和环氧树脂之间存在较强的相互作用。随着OP wt%的增加,环氧树脂/OP复合材料的抗拉强度从22.78 MPa降低到19.03 MPa,而环氧树脂/油棕/ 5% ZnO样品的抗拉强度提高到29.224MPa。随着wt% OP和ZnO的增加,杨氏模量从1.9 MPa增加到4.3 MPa,伸长率从9.6 ~ 6.8%下降。所有复合材料的冲击和硬度分别在(6.94 ~ 10.8 KJ/m2)和(80.8 ~ 84.55 KJ/m2)之间增加。环氧/OP和环氧/OP/ZnO样品的耐磨性随OP和ZnO的wt%的增加而增加。本研究旨在为绿色纳米颗粒填料在可生物降解的可持续可再生结构产品中的应用提供新的途径。
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引用次数: 2
Statistical Analysis and Forecasting of Rainfall Patterns and Trends in Gombe North-Eastern Nigeria 尼日利亚东北部贡贝地区降雨模式和趋势的统计分析和预测
Pub Date : 2022-06-01 DOI: 10.30723/ijp.v20i2.989
Abe A. O., Q. A. Adeniji, Rabiu J. A., Adegboyega O., Raheem I. O., Rasaki M.G., Sada S. M., F. L.
Rainfall in Nigeria is highly dynamic and variable on a temporal and spatial scale. This has taken a more pronounced dimension due to climate change. In this study, Standard Precipitation Index (SPI) and Mann-Kendall test statistical tools were employed to analyze rainfall trends and patterns in Gombe metropolis between 1990 and 2020 and the ARIMA model was used for making the forecast for ten (10) years. Daily rainfall data of 31 years obtained from Nigerian Meteorological Agency, (NIMET) was used for the study. The daily rainfall data was subjected to several analyses. Standard precipitation index showed that alternation of wet and dry period conditions had been witnessed in the study area. The result obtained showed that there is an upward trend in the annual rainfall amount received in Gombe over the last 31 years at a rate of 3.98 mm/year. The results for the forecast shows that the annual rainfall to be received in Gombe continues in a range above the mean which serves as an indication that the decade will experience more wet years than dry years. The study concludes that the pattern of rainfall in Gombe is a cyclic pattern. The current trend may affect soil moisture, flooding and subsequently lead to ecological change. The study recommends that inhabitants of the study areas should plan their cropping season based on climatic information of their area.
尼日利亚的降雨在时间和空间尺度上是高度动态和可变的。由于气候变化,这一问题更加突出。本研究采用标准降水指数(SPI)和Mann-Kendall检验统计工具分析了贡贝大都市1990 - 2020年的降水趋势和模式,并采用ARIMA模式进行了10年的预测。研究使用了尼日利亚气象局(NIMET) 31年的日降雨量数据。对日降雨量数据进行了多次分析。标准降水指数表明,研究区存在干湿交替现象。结果表明,近31 a贡贝地区年降水量呈上升趋势,以3.98 mm/年的速率上升。预测结果表明,贡贝的年降雨量继续高于平均值,这表明十年来湿润年将多于干旱年。该研究得出结论,贡贝的降雨模式是一个循环模式。目前的趋势可能会影响土壤湿度、洪水,进而导致生态变化。该研究建议,研究地区的居民应该根据他们所在地区的气候信息来规划他们的种植季节。
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引用次数: 1
Synthesis and Characterization of Ternary BexZn1-xO Nano Thin Films prepared by Pulsed Laser Deposition Technique 脉冲激光沉积技术制备BexZn1-xO三元纳米薄膜及其表征
Pub Date : 2022-06-01 DOI: 10.30723/ijp.v20i2.983
A. Abed, M. Hussein
         Beryllium Zinc Oxide (BexZn1-xO) ternary nano thin films were deposited using the pulsed laser deposition (PLD) technique under a vacuum condition of 10-3 torr at room temperature on glass substrates with different films thicknesses, (300, 600 and 900 nm). UV-Vis spectra study found the optical band gap for Be0.2Zn0.8O to be  (3.42, 3.51 and 3.65 eV) for the (300, 600 and 900nm) film thicknesses, respectively which is larger than the value of zinc oxide ZnO (3.36eV) and smaller than that of beryllium oxide BeO (10.6eV). While the X-ray diffraction (XRD) pattern analysis of ZnO, BeO and Be 0.2 Zn 0.8 O powder and nano-thin films indicated a hexagonal polycrystalline wurtzite structure. The crystal structure showed a preferential orientation line at (101). Besides the nano thin film Be0.5Zn0.5O has all orientations of ZnO and BeO. Moreover, the calculated average crystallite size for nano thin film was 16.48 nm.  The surface morphology of the nano thin films investigated by atomic force microscope (AFM) showed a decrease in the average grain sizes (94.8, 79.2 and 59.4 nm) with the increase of films thickness due to quantum confinement effect.
采用脉冲激光沉积(PLD)技术,在10-3 torr的真空条件下,在300、600和900 nm的不同薄膜厚度的玻璃衬底上沉积了铍氧化锌(BexZn1-xO)三元纳米薄膜。紫外可见光谱研究发现,Be0.2Zn0.8O在(300、600和900nm)薄膜厚度下的光学带隙分别为(3.42、3.51和3.65 eV),大于氧化锌ZnO (3.36eV),小于氧化铍BeO (10.6eV)。而ZnO、BeO和Be 0.2 Zn 0.8 O粉末及纳米薄膜的x射线衍射(XRD)分析显示为六方多晶纤锌矿结构。晶体结构在(101)处呈现优先取向线。此外,Be0.5Zn0.5O纳米薄膜具有ZnO和BeO的所有取向。计算得到纳米薄膜的平均晶粒尺寸为16.48 nm。原子力显微镜(AFM)观察纳米薄膜的表面形貌发现,由于量子约束效应,随着薄膜厚度的增加,平均晶粒尺寸(94.8 nm、79.2 nm和59.4 nm)减小。
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引用次数: 0
Electro spinning of Polycaprolactone / Hydroxyapatite Composites in Wound Dressing Application 电纺丝聚己内酯/羟基磷灰石复合材料在伤口敷料中的应用
Pub Date : 2022-03-01 DOI: 10.30723/ijp.v20i1.703
Ali Hasan Mohsan, N. Ali
Polycaprolactone polymer is widely used in medical applications due to its biocompatibility. Electro spinning was used to create poly (ε- caprolactone) (PCL) nanocomposite fiber mats containing hydroxyapatite (HA) at concentrations ranging from 0.05 to 0.4% wt. The chemical properties of the fabricated bio composite fibers were evaluated using FTIR and morphologically using field-emission scanning-electron microscopy (FESEM), Porosity, contact angle, as well as mechanical testing(Young Modulus and Tensile strength) of the nanofibers were also studied. The FTIR results showed that all the bonds appeared for the pure PCL fiber and the PCL/HA nano fibers. The FESEM nano fiber showed that the fiber diameter increased from 54.13 to 155.79 (nm) at the HA values from (0.05 % and 1%wt.).Porosity, wettability of (PCL/HA) composites has improved, and the contact angle has decreased from 103.59o to 85.57o for fibrous scaffolds. The inclusion of hydroxyapatite increased the tensile strength of nano fiber scaffolds, and the maximum tensile strength of 0.4% percent was about 0.127 MPa, with a lowering in elongation to 40%.
聚己内酯聚合物具有良好的生物相容性,在医学上有着广泛的应用。采用静电纺丝法制备了浓度为0.05 ~ 0.4%的羟基磷灰石(HA)聚ε-内酯(PCL)纳米复合纤维毡。利用红外光谱(FTIR)和场发射扫描电镜(FESEM)对制备的生物复合纤维的化学性能进行了评价,并对纳米纤维的孔隙率、接触角以及力学性能(杨氏模量和抗拉强度)进行了研究。FTIR结果表明,纯PCL纤维和PCL/HA纳米纤维都出现了所有的键。FESEM纳米纤维显示,在(0.05%和1%wt.)的HA值下,纤维直径从54.13 nm增加到155.79 nm。(PCL/HA)复合材料的孔隙率、润湿性均有所改善,纤维支架的接触角从103.59°降低到85.57°。羟基磷灰石的掺入提高了纳米纤维支架的抗拉强度,0.4%的掺入最大抗拉强度约为0.127 MPa,伸长率降至40%。
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引用次数: 0
Psoriasis Treatment by Using Narrowband-UVB Phototherapy 窄带uvb光疗治疗银屑病
Pub Date : 2022-03-01 DOI: 10.30723/ijp.v20i1.971
Layth M. Karim, N. A. Al-Ani, Marwa H. Abbas
Ultraviolet light radiation is applied to treat Plaque Psoriasis disease by targeted phototherapy. This is available through Narrowband-UVB light radiation devices peaked at wavelength 311 nm. Ten cases were chosen as a study group, 8 males aged 22-40 years old, and 2 females aged 25 and 32 years old who were exposed to ultraviolet light radiation. Their recovery or improvement was followed weekly. Different doses were used according to the severity of the lesion and as a trial for the outcome. The dose was given two times a week, starting with 200mJ/cm2, and subsequently increased by 100 or 200 mJ/cm2 reaching a maximum dose as tolerated by each individual patient. Improvement was observed after 4 – 6 weeks. The patient stays in the treatment cabinet for a few seconds to several minutes according to the individual case which depends on the area of the body being treated. Treatment was stopped for two patients due to in toleration to the recommended dose. It was observed that good treatment results were obtained for the other 8 patients. The recovery rate from the disease was in the range of 50-100%. This is depending on the duration of the occurrence of the disease and the reduction of the size of the affected area on ​​the skin for each individual patient after treatment.
紫外线辐射应用于斑块型银屑病的靶向光疗。这可以通过窄带uvb光辐射设备在波长311纳米处达到峰值。选择10例为研究组,男性8例,年龄22 ~ 40岁,女性2例,年龄25 ~ 32岁。每周追踪他们的恢复或改善情况。根据病变的严重程度使用不同的剂量,并作为结果的试验。剂量每周给予两次,从200mJ/cm2开始,随后增加100或200mJ/cm2,达到每个患者耐受的最大剂量。4 - 6周后观察到改善。病人在治疗柜中停留几秒钟到几分钟,根据具体情况而定,这取决于接受治疗的身体部位。由于对推荐剂量的耐受,两名患者停止了治疗。其余8例患者均获得良好的治疗效果。该疾病的痊愈率在50-100%之间。这取决于疾病发生的持续时间以及治疗后每个患者皮肤上受影响区域的缩小程度。
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引用次数: 1
Simulation of Small Radio Telescope Antenna Parameters at Frequency of 1.42 GHz 1.42 GHz频率下小型射电望远镜天线参数仿真
Pub Date : 2022-03-01 DOI: 10.30723/ijp.v20i1.726
Uday E Jallod, H. Mahdi, Kamal M. Abood
The paper presents an overview of theoretical aspects of small radio telescope antenna parameters. The basic parameters include antenna beamwidth, antenna gain, aperture efficiency, and antenna temperature. These parameters should be carefully studied since they have vital effects on astronomical radio observations. The simulations of antenna parameters were carried out to assess the capability and the efficiency of small radio telescopes to observe a point source at a specific frequency. Two-dimensional numerical simulations of a uniform circular aperture antenna are implemented at different radii. The small diameter values are chosen to be varied between (1-10) m. This study focuses on a small radio telescope with a diameter of 3 m since this telescope is very common in the world. The simulated results of this study illustrated that the power pattern of a 3 m antenna has a half-power beamwidth of approximately 5 degrees. Also, the maximum peak antenna temperature is estimated to be more than 3000 K. All of these results were in good agreement with observations of the neutral hydrogen spectral line at the frequency of 1.42 GHz using a small radio telescope.
本文对小型射电望远镜天线参数的理论研究进行了综述。基本参数包括天线波束宽度、天线增益、孔径效率和天线温度。这些参数对天文射电观测有至关重要的影响,因此应该仔细研究。为了评估小型射电望远镜观测特定频率点源的能力和效率,对天线参数进行了仿真。对均匀圆孔径天线在不同半径下进行了二维数值模拟。选择的小直径值在(1-10)m之间变化。由于这种望远镜在世界上很常见,因此本研究的重点是直径为3 m的小型射电望远镜。仿真结果表明,3米天线的功率方向图具有约5度的半功率波束宽度。此外,天线的最大峰值温度估计超过3000 K。这些结果与用小型射电望远镜观测到的1.42 GHz频率的中性氢谱线相吻合。
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引用次数: 1
The Confinement Profile Effect on the Optical Properties in Different Inverse-shaped Single InGaN/GaN Quantum Wells 不同反形状InGaN/GaN单量子阱中约束剖面对光学性质的影响
Pub Date : 2022-03-01 DOI: 10.30723/ijp.v20i1.965
R. En-nadir, Haddou El Ghazi, Walid Belaid, H. Abboudi, F. Jabouti, A. Jorio, I. Zorkani
In this work, the effects of size, and temperature on the linear and nonlinear optical properties in InGaN/GaN inverse parabolic and triangular quantum wells (IPQW and ITQW) for different concentrations at the well center were theoretically investigated. The indium concentrations at the barriers were fixed to be always xmax = 0.2. The energy levels and their associated wave functions are computed within the effective mass approximation. The expressions of optical properties are obtained analytically by using the compact density-matrix approach. The linear, nonlinear, and total absorption coefficients depending on the In concentrations at the well center are investigated as a function of the incident photon energy for different values of temperature and quantum wells size. The results show that the In concentrations, size and temperature have a significant effect on these optical properties. The positions of the resonance peaks of the absorption coefficients were blue-shifted under increasing indium compositions in the quantum wells (InGaN) and temperature while they were red-shifted with the increase in the thickness of the wells. Moreover, the amplitudes of the resonance peaks were enhanced under the increase of the In composition, the temperature, and the thickness of the quantum wells. The optical absorption in ITQW structure is slightly greater than that in IPQW one.
本文从理论上研究了不同浓度的InGaN/GaN逆抛物型和三角形型量子阱(IPQW和ITQW)中尺寸和温度对其线性和非线性光学性质的影响。屏障处的铟浓度固定为xmax = 0.2。在有效质量近似内计算能级及其相关波函数。利用紧致密度矩阵法解析得到了光学性质的表达式。研究了不同温度和量子阱尺寸下入射光子能量与阱中心In浓度之间的线性、非线性和总吸收系数关系。结果表明,In浓度、尺寸和温度对这些光学性质有显著影响。吸收系数共振峰的位置随着量子阱(InGaN)中铟含量的增加和温度的升高而发生蓝移,而随着量子阱厚度的增加而发生红移。此外,共振峰的振幅随着铟的组成、温度和量子阱厚度的增加而增强。ITQW结构的光吸收略大于IPQW结构。
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引用次数: 3
Preparation of a Composite of Copper Oxide Nanoparticles with Carbon by Exploding Graphite Rod in Aqueous Suspension 水悬浮液中石墨棒爆炸法制备纳米氧化铜-碳复合材料
Pub Date : 2022-03-01 DOI: 10.30723/ijp.v20i1.961
Sawsan H. Abdulla, H. Humud, F. Mustafa
In this work, the effect of preparing a composite of copper oxide nanoparticles with carbon on some of its optical properties was studied. The composite preparing process was carried out by exploding graphite electrodes in an aqueous suspension of copper oxide. The properties of the plasma which is formed during the explosion were studied using emission spectroscopy in order to determine the most important elements that are present in the media. The electron’s density and their energy, which is the main factor in the composite process, were determined. The particle properties were studied before and after the exploding process. The XRD showed an additional peak in the copper oxides pattern corresponding to the hexagonal graphite structure for the composite. The UV-visible absorbance for the composite was significantly enhanced. The direct bandgap decreased from 2.55 to 2.4 eV, and the indirect bandgap decreased from 1.1 to 1 eV, for the composite.
本文研究了纳米氧化铜与碳复合材料的制备对其光学性能的影响。采用爆炸石墨电极在氧化铜水悬浮液中制备复合材料。用发射光谱法研究了爆炸中形成的等离子体的性质,以便确定介质中存在的最重要的元素。测定了复合过程中影响电子密度和电子能量的主要因素。对爆炸前后的颗粒性质进行了研究。XRD结果表明,复合材料的六方石墨结构在铜氧化物谱图中有一个附加峰。复合材料的紫外可见吸光度明显增强。复合材料的直接带隙从2.55 eV减小到2.4 eV,间接带隙从1.1 eV减小到1 eV。
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引用次数: 0
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Iraqi Journal of Physics (IJP)
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