The Achemmach region, located east of the El Hammam district in northeastern Central Morocco, is characterized by significant tin mineralization. This mineralization is hosted in E-W trending Late Visean tourmaline-bearing brecciated veins developed within sandstones and mudstones, contrasting with barren NE-SW trending tourmaline structures. Electron microprobe analyses reveal that tourmalines from the barren zones belong to metamorphic-type schorl-dravite solid solutions (up to 50 mol% dravite), whereas those from mineralized zones are granitic schorlites with significant fluorine contents (up to 0.15 apfu F). A paragenetic assemblage composed of cassiterite, stannite, chalcopyrite, arsenopyrite, pyrite, and sphalerite was identified from surface and core samples. Stannite, abundant in the mineralized veins, forms through reactions between cassiterite and Cu-rich fluids contemporaneous with chalcopyrite precipitation. Quartz, tourmaline, calcite, and fluorite constitute the principal gangue minerals. Stannite contains minor Au (up to 350 ppm) and Ag (up to 0.27 wt%), whereas cassiterite hosts up to 790 ppm Au and 600 ppm Ag. Fluid inclusion studies in quartz from tourmalinized veins indicate a progressive evolution from vapor-to supercritical aqueous fluids trapped at conditions between 500 °C/700 bar and 150 °C/100 bar. Fluids from barren veins show higher salinities than those from mineralized zones, reflecting a more metamorphic origin. The hydrothermal evolution of the Achemmach tin-bearing breccias involves two key stages: (1) trapping of vapor-rich fluids at ∼600 °C/1 kbar with salinity of ∼13.5 wt% NaCl equiv., and (2) prolonged boiling down to ∼100 °C, evidenced by increased fluid salinities.
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