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Lunar tidal cycle forcing on estuarine hydrodynamics and water quality patterns and implications for suspended sediment-borne contaminant transport: Case study of SE coast of Nigeria 月潮循环对河口水动力和水质模式的强迫作用及其对悬浮沉积物污染物输送的影响:尼日利亚东南海岸的案例研究
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-27 DOI: 10.1016/j.jafrearsci.2026.106044
Effiom E. Antia
Knowledge of longevity of sediment-borne contaminants in estuaries is central to contingency planning of coastal regions worldwide. Inter-comparison of the response patterns of estuarine hydrodynamic and water quality parameters to tidal forcing at time scale of semidiurnal and lunar tidal cycle is crucial to this effort. Results of above parameters at two contiguous mesotidal estuaries (Imo River and Qua Iboe River) on the southeastern coast of Nigeria are presented based on synoptic monitoring of 50 successive semidiurnal tidal cycles. The time-series patterns of studied parameters in the estuaries showed considerable compatibility. Both estuaries displayed increased velocities (tidal peak, tidal stage-averaged and tidal cycle residual) and tidal cycle net excursion lengths with increase in tidal amplitude. Their transparency depths were shallowest at spring tides while water colour, pH and salinity were lowest at neap tides. The estuaries are prone to export sediment-borne contaminants on a long term, but at a faster rate at spring than neap tide. This is based on > 80 % frequency of ebb-asymmetric net excursion length and averaged spring to neap tide net excursion length ratios of 2.1–2.4. Of wider application is the prospect of utilizing the predictive relations on contaminant import-export drivers to rank longevity of contaminants in comparable estuaries.
了解河口沉积物携带污染物的寿命对全世界沿海地区的应急规划至关重要。在半日和月潮周期的时间尺度上,比较河口水动力和水质参数对潮汐强迫的响应模式至关重要。根据50个连续的半日潮周期天气监测,给出了上述参数在尼日利亚东南沿海两个连续的中潮汐河口(伊莫河和夸伊博河)的结果。河口研究参数的时间序列模式表现出相当大的相容性。随着潮汐幅值的增加,两个河口的速度(潮峰、潮段平均和潮周期剩余)和潮周期净偏移长度均有所增加。它们的透明深度在大潮时最浅,而水的颜色、pH和盐度在小潮时最低。河口长期易向外输出泥沙污染物,但春季的输出速度比小潮时快。这是基于退潮不对称净偏移长度>; 80%的频率和平均大潮与小潮净偏移长度比值为2.1-2.4。更广泛的应用前景是利用污染物进出口驱动因素的预测关系对可比河口污染物的寿命进行排序。
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引用次数: 0
Toward a refined framework for upper Albian-lower Turonian ammonite biostratigraphy: case study from the Aurès Basin (NE Algeria), and regional correlation with Western Europe, central Tunisia, and the Western Interior Seaway 为上阿尔比—下Turonian菊石生物地层学建立一个完善的框架:以aur<s:1>盆地(阿尔及利亚东北部)为例,并与西欧、突尼斯中部和西部内陆海道进行区域对比
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-27 DOI: 10.1016/j.jafrearsci.2026.106046
Aida Bensekhria , Mhammed Abdeldjalil , Rabah Bouhata , Meriem Khelali
This study presents the first integrated interregional correlation of the upper Albian–lower Turonian stratigraphic record of the Aurès Basin (northeast Algeria) within a broad Tethyan–Atlantic framework, integrating lithostratigraphy, ammonite biostratigraphy, and palaeogeography based on three stratigraphically logged and sampled sections along a southwest–northeast transect. Four successive formations were identified: Grès Rouges, Taghrout Ameur Gray Marls, Zeouei, and Yabous formations, representing a continuous upper Albian to lower Turonian record. Eight ammonite biozones were identified and correlated: StoliczkaiaInterval Zone (upper Albian), Mantelliceras cf. mantelli Partial Range Zone (lower Cenomanian), Mantelliceras dixoni Interval Zone (upper-lower Cenomanian), Cunnigtoniceras inerme Interval Zone (Lower-middle Cenomanian), Acanthoceras cf. rhotomagense Interval Zone (middle Cenomanian), Acanthoceras amphibolum Total Range Zone (upper-middle Cenomanian), Neolobites vibrayeanus/Eucalycoceras pentagonum Total Range Zone (early upper Cenomanian), and Pseudaspidoceras flexuosum Interval Zone (lower Turonian). Comparative analysis of twelve biozones in Northwest Europe and nineteen in Western Interior reveals broad synchrony in zonal development, but also highlights palaeobiogeographic differentiation driven by climatic gradients, provincialism and marine barriers. The Cunningtoniceras inerme and Conlinoceras tarrantense Zones establish robust links with the Western Interior, whereas the absence of P. flexuosum in Boreal Europe marks a persistent Tethyan–Boreal faunal divide. Transgressive events and the opening of the South Atlantic broadened marine corridors along the Tethyan edge, facilitating ammonite dispersal and promoting both endemism and cosmopolitanism. The Oceanic Anoxic Event 2 (OAE2) had divergent biotic impacts, diminishing variety in Boreal Europe while preserving or enhancing it in North Africa and the Western Interior. Overall, the Aurès ammonite record demonstrates that the basin functioned as a key southern Tethyan palaeogeographic corridor, providing critical constraints for refining global ammonite biostratigraphic frameworks and understanding upper Albian-lower Turonian transcontinental marine connectivity.
本研究首次在广泛的特提亚-大西洋格架中对aur盆地(阿尔及利亚东北部)的上阿尔伯拉罕-下Turonian地层记录进行了区域间的综合对比,综合了岩石地层学、鹦鹉螺生物地层学和古地理,并基于西南-东北样带的三个地层测井和采样剖面进行了对比。确定了四个连续的地层:gr s rouge、Taghrout Ameur Gray Marls、Zeouei和Yabous地层,代表了连续的上阿尔比统到下Turonian的记录。确定了8个鹦鹉螺生物带并进行了对比:stoliczkaiinterrange Zone(上阿尔比世),Mantelliceras cf. mantelli部分Range Zone(下Cenomanian), Mantelliceras dixoni区间Zone(下Cenomanian), Cunnigtoniceras inme区间Zone(中下Cenomanian), Acanthoceras cf. rhotomagense区间Zone(中Cenomanian), Acanthoceras amphibolum总Range Zone(中上Cenomanian), Neolobites vibrayeanus/Eucalycoceras pentagonum总Range Zone(上Cenomanian早期),和假aspidoceras flexuosum间隔带(下Turonian)。通过对欧洲西北部12个生物带和欧洲西部内陆19个生物带的对比分析,揭示了其地带性发展具有广泛的同步性,但也突出了气候梯度、地域差异和海洋屏障驱动的古生物地理差异。Cunningtoniceras inme和Conlinoceras tarrantense带与西部内陆建立了牢固的联系,而在欧洲北部没有P. flexuosum标志着一个持续的Tethyan-Boreal动物区隔。海侵事件和南大西洋的开放拓宽了特提斯边缘的海洋走廊,促进了菊石的扩散,促进了地方主义和世界主义。海洋缺氧事件2 (OAE2)对生物的影响具有多样性,在北欧减少了生物多样性,而在北非和西部内陆则保持或增强了生物多样性。总体而言,aur菊石记录表明,该盆地是南部特提斯古地理走廊的重要组成部分,为完善全球菊石生物地层格架和了解上阿尔比世-下Turonian期跨大陆海相连通性提供了重要的约束条件。
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引用次数: 0
Diagenesis and hydraulic flow characteristics of the Paleozoic Shifa sandstones in the western desert, Egypt: Implications for new prospective reservoir targets 埃及西部沙漠古生代Shifa砂岩成岩作用及水力流动特征:对新的远景储层目标的启示
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-24 DOI: 10.1016/j.jafrearsci.2026.106040
Ahmed Ismail Mahmoud , Xiaodong Ma , Shib Sankar Ganguli , Ahmed Shakkar , Ahmed M. Metwally , Walid M. Mabrouk , Mahmoud Leila
The Paleozoic reservoirs of Shifa Formation sandstones in Egypt's Western Desert are deeply buried (>3500 m) and poorly explored, with significant uncertainties concerning the controls of depositional and diagenetic attributes on their hydraulic flow properties. In this regard, we integrate geophysical, petrographical, petrophysical and machine learning results to investigate spatiotemporal evolution of different reservoir rock types (RRTs) and hydraulic flow zones. We found that eodiagenetic infiltration of clays, kaolinite cementation, and mesogenetic quartz overgrowth are the key burial modifications controlling the evolution of the pore network of the Shifa sandstones. Two sandstone microfacies were reported: quartz arenite and kaolinitic quartz arenite. Petrographic analysis demonstrates that early diagenesis significantly degraded the reservoir quality of the kaolinite-rich sandstones, while mesodiagenesis has a mild impact on the sandstones' pore system. Lithofacies analysis reveals that the lower part of the Shifa succession consists mainly of mudstones and kaolinitic quartz arenites, which exhibit lower porosity and permeability compared to quartz arenite sandstones. The stratigraphic modified Lorenz plot (SMLP) and 3D property models demonstrate that the spatial distribution of quartz arenite sandstones predominantly controls fluid flow conduits. Bayesian neural network (BNN) models demonstrated their effectiveness in estimating the permeability of the Shifa sandstones microfacies, thereby improving the predictability of the best RRTs. These findings showcase the promising potential of BNN and integrated reservoir characterization analyses for developing reliable hydrocarbon exploration strategies in the region, thereby offering economic benefits.
埃及西部沙漠Shifa组古生代砂岩储层埋藏深(>3500 m),勘探程度低,沉积和成岩属性对其水力流动特性的控制存在很大的不确定性。在这方面,我们整合了地球物理、岩石学、岩石物理和机器学习的结果,研究了不同储层岩石类型(RRTs)和水力流动带的时空演化。研究发现,粘土的古成岩渗透作用、高岭石胶结作用和中生石英过度生长是控制Shifa砂岩孔隙网络演化的关键埋藏改造。砂岩微相有石英砂岩和高岭石石英砂岩两种。岩石学分析表明,早期成岩作用明显降低了富高岭石砂岩的储层质量,而中成岩作用对砂岩孔隙系统的影响较小。岩相分析表明,石法序列下部主要为泥岩和高岭石质石英砂质砂岩,其孔隙度和渗透率低于石英砂质砂岩。地层修正洛伦兹图(SMLP)和三维物性模型表明,石英砂质砂岩的空间分布主要控制流体的流动管道。贝叶斯神经网络(BNN)模型在估算Shifa砂岩微相渗透率方面证明了其有效性,从而提高了最佳rrt的可预测性。这些发现显示了BNN和综合储层表征分析在该地区制定可靠的油气勘探策略方面的巨大潜力,从而提供了经济效益。
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引用次数: 0
Mineral chemistry and whole-rock geochemistry of highly fractionated post-collisional granites in the Hangaliya gold mine area, Arabian-Nubian Shield, Egypt 埃及阿拉伯-努比亚地盾Hangaliya金矿高分选后碰撞花岗岩矿物化学及全岩地球化学
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-22 DOI: 10.1016/j.jafrearsci.2026.106031
Heba S. Mubarak , Mokhles K. Azer , Adel A. Surour , Hilmy E. Moussa , Paul D. Asimow , Mona Kabesh , Faris A. Abanumay
The granitic rocks in Wadi Hangaliya, in the south Eastern Desert of Egypt, represent an offshoot of the Gebel Nugrus intrusion. They include alkali feldspar granite, syenogranite, sheared granite, and highly mineralized granite in the vicinity of the well-known Hangaliya gold mine. Geochemically, the suite has peraluminous, calc-alkaline, and highly fractionated characteristics. Whole-rock geochemical data indicate overall enrichment in rare-earth elements; light rare earth elements are enriched compared to heavy rare earth elements and there are prominent negative Eu anomalies. Heterogeneity is noted in ratios of elements that are similarly incompatible during fractionation (K/Rb, Zr/Rb and Ba/Nb). Field relations and geochemical characteristics of the granite suite are consistent with generation of parental magma in a post-collisional tectonic setting through partial melting of a juvenile igneous crustal source, followed by extensive fractional crystallization with some upper crustal contamination. Some samples are garnet-bearing, with an almandine-dominated composition often associated with magmatic garnets crystallized from I-type magma at low pressure. Two arsenic-bearing phases were found and studied in the Hangaliya gold mine samples: scorodite [FeAsO4 · 2H2O] and arsenosiderite [Ca2Fe3(AsO4)3O2 · 3H2O], which is considered to have formed by alteration of arsenopyrite and scorodite. Gold alloys were readily detected in Hangaliya gold mine samples and are characterized by variable Au contents (31–83 wt%).
位于埃及东南部沙漠的Wadi Hangaliya的花岗岩代表了Gebel Nugrus入侵的一个分支。它们包括碱长石花岗岩、正长花岗岩、剪切花岗岩以及在著名的Hangaliya金矿附近高度矿化的花岗岩。地球化学上,该套具有过铝质、钙碱性和高分馏特征。全岩地球化学资料显示稀土元素整体富集;轻稀土元素较重稀土元素富集,Eu负异常显著。分馏过程中相似不相容的元素(K/Rb, Zr/Rb和Ba/Nb)的比例存在异质性。花岗岩组的场关系和地球化学特征与碰撞后构造背景下母岩浆的形成一致,母岩浆是由幼年火成岩地壳源的部分熔融形成的,随后是广泛的分离结晶,并有一定的上层地壳污染。部分样品含石榴石,其组成以铝榴石为主,常与低压下由i型岩浆结晶而成的岩浆石榴石有关。在汉加里亚金矿样品中发现并研究了两种含砷物相:铁云母[FeAsO4·2H2O]和砷黄铁矿[Ca2Fe3(AsO4)3O2·3H2O],认为它们是由毒砂和铁云母蚀变形成的。汉加里亚金矿样品中易检出金合金,其特征是金含量变化较大(31 ~ 83 wt%)。
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引用次数: 0
Geotechnical behaviour of organic soil modified with natural pumice and zeolite: Implications for sustainable use of volcanic raw materials for soil stabilization 用天然浮石和沸石改性有机土壤的岩土力学行为:对土壤稳定可持续利用火山原料的影响
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-21 DOI: 10.1016/j.jafrearsci.2026.106037
Suleyman Demir
This study presents the effect of zeolite (NZ) and pumice powder (PP) on some engineering properties of an organic soil. Organic soil treated with NZ and PP separately, with 10, 20, 30, and 40 % additive ratios, was investigated with compaction, fall cone, and unconfined compression (UC) tests, and a model. The axial stress values from UC tests were fitted using a second-order polynomial response surface model (RSM). The sensitivity of the model was investigated with partial derivative plots. The findings showed that the liquid limit and optimum water content (wopt) values of organic soil decreased with both NZ and PP additions. 40 % PP and NZ improved the maximum dry density (γdmax) value of organic soil by 16 % and 7.2 %, respectively. Unconfined compressive strength (qu) value of organic soil increased by 18 %, with 40 % PP additions. 10 % NZ and PP additions increased the energy absorption capacity value of clean organic soil by 36 % and 13 %, respectively. At a given content, PP-treated organic soil exhibited a greater qu than NZ-treated organic soil. SEM photos of treated specimens showed some interparticle contacts between additives, which contributed to the strength improvement of the mixtures. The RSM revealed the coefficients of determination (R2) values of 0.93 and 0.97 for PP and NZ-treated mixtures, respectively. Sensitivity analysis showed that the stress is governed by strain at small deformation levels, while the additive content decreased the strain softening at large strain levels. Consequently, this study presents important insights into the macro and micro-mechanics of PP and NZ-stabilized organic soils.
研究了沸石(NZ)和浮石粉(PP)对有机土壤某些工程性质的影响。采用压实、落锥、无侧限压缩(UC)试验和模型,研究了添加比例分别为10%、20%、30%和40%的NZ和PP处理的有机土壤。采用二阶多项式响应面模型(RSM)拟合UC试验的轴向应力值。用偏导数图考察了模型的灵敏度。结果表明:添加NZ和PP后,有机土壤的液限和最佳含水量(wopt)值均降低。40% PP和NZ分别使有机土壤最大干密度(γdmax)值提高16%和7.2%。当PP添加量为40%时,有机土的无侧限抗压强度(qu)值提高18%。添加10%的NZ和PP可使清洁有机土壤的能量吸收能力值分别提高36%和13%。在一定含量下,pp处理的有机土壤比nz处理的有机土壤表现出更大的qu。处理后试样的SEM照片显示,添加剂之间存在一定的颗粒间接触,这有助于提高混合物的强度。RSM结果显示,PP和nz处理的混合物的决定系数(R2)分别为0.93和0.97。敏感性分析表明,在小变形水平下,应力受应变控制,而在大变形水平下,添加剂含量降低了应变软化。因此,该研究对PP和nz稳定有机土壤的宏观和微观力学具有重要意义。
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引用次数: 0
Airborne gamma-ray spectrometry survey over the Bou Azzer-El Graara Inlier (Central Anti-Atlas, Morocco): implications for mineral exploration 在Bou Azzer-El Graara Inlier(摩洛哥中部Anti-Atlas)上空的机载伽玛射线能谱测量:对矿产勘探的影响
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-21 DOI: 10.1016/j.jafrearsci.2026.106038
Fouzia Anzar , Saïd Ilmen , Mohammed Jaffal , Abderrahmane Soulaimani
This study provides a comprehensive analysis of airborne gamma-ray spectrometry (GRS) data from the Bou Azzer–El Graara inlier in the central Anti-Atlas Mountains of Morocco. This region is geologically complex, renowned for its Pan-African suture zone and abundant cobalt, copper, and uranium mineralization. High-resolution GRS data, acquired during helicopter surveys in 1998 and 1999, were processed to map the distribution and ratios of naturally occurring radioactive elements (uranium, thorium, and potassium) and to delineate anomalous areas associated with hydrothermal alteration and mineralization. The integration of geological and remote sensing data revealed significant spatial correlations. Cobalt mineralization exhibited a high eU/K ratio, indicating the presence of uranium-rich hydrothermal fluids during cobalt deposit formation. The occurrence of copper mineralization correlates with typical eTh/K anomalies in felsic volcanic systems. Radiometric dating data also identified uranium-rich mineralization zones, primarily located within the Ediacaran volcanic rocks. Tectonic analysis revealed major fault activity controlling fluid flow and alteration patterns, thus aiding in orebody localization. Ternary K-eU-eTh maps further distinguished lithological units and alteration halos. These results highlight the value of gamma-ray spectrometry (GRS) in rapid and efficient mineral exploration, particularly in the exploration of cobalt deposits associated with uranium anomalies. The study recommends further ground-based radiometric surveys in the Bou Azzer mining area to optimize target locations and highlights the potential of uranium-focused gamma-ray spectrometry for cobalt exploration in complex Pan-African geological contexts.
本研究对来自摩洛哥中部反阿特拉斯山脉的Bou Azzer-El Graara盆地的机载伽马射线能谱(GRS)数据进行了全面分析。该地区地质复杂,以其泛非缝合带和丰富的钴、铜和铀矿化而闻名。在1998年和1999年直升机调查期间获得的高分辨率GRS数据经过处理,绘制了自然发生的放射性元素(铀、钍和钾)的分布和比例,并描绘了与热液蚀变和矿化有关的异常区域。地质和遥感数据的整合显示出显著的空间相关性。钴矿化表现出较高的eU/K比值,表明钴矿床形成过程中存在富铀热液。铜成矿的赋存与长英质火山系统中典型的eTh/K异常有关。放射性测年数据还确定了富铀矿化带,主要位于埃迪卡拉纪火山岩中。构造分析揭示了主要断裂活动控制流体流动和蚀变模式,从而有助于矿体定位。三元K-eU-eTh图进一步区分了岩性单元和蚀变晕。这些结果突出了伽马射线能谱(GRS)在快速有效的矿产勘探中的价值,特别是在与铀异常相关的钴矿床的勘探中。该研究建议在Bou Azzer矿区进行进一步的地面辐射测量,以优化目标位置,并强调在复杂的泛非地质背景下,铀聚焦伽马射线能谱法在钴勘探方面的潜力。
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引用次数: 0
Predictive study of tsunami impact on the southwestern Atlantic coast of Morocco 海啸对摩洛哥西南大西洋海岸影响的预测研究
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-21 DOI: 10.1016/j.jafrearsci.2026.106025
Mohamed Outiskt , Soufiane Tichli , Maria Ana Baptista , Said El Moussaoui , Khadija Aboumaria
Tsunamis have historically affected the Moroccan Atlantic coast, resulting in significant human and socio-economic consequences. This study presents the first tsunami risk assessment specifically focused on the city of Agadir, a major urban and economic hub in southwestern Morocco. By simulating the 1755 Lisbon tsunami and evaluating its potential impact on Agadir, we fill a critical gap in the existing literature, which has largely overlooked this vulnerable coastal city. Agadir's dense urban fabric, thriving tourism sector, and strategic harbor make it particularly susceptible to tsunami-induced disruptions. We analyze four credible earthquake scenarios, previously identified in scientific literature as potential triggers of the 1755 event, using the NSWING (Nonlinear Shallow Water with Nested Grids) numerical simulation model. The results, visualized through high-resolution maps of maximum wave heights and inundation distances, reveal significant vulnerability, with wave heights ranging from 0.1 to 5.3 m and inundation distances reaching up to 310 m inland. These findings offer vital insight for local authorities and policymakers, providing a scientific foundation for enhancing tsunami preparedness, resilience strategies, and public awareness initiatives in Agadir.
历史上,海啸曾影响摩洛哥大西洋沿岸,造成严重的人类和社会经济后果。本研究首次对摩洛哥西南部主要城市和经济中心阿加迪尔市进行了海啸风险评估。通过模拟1755年里斯本海啸并评估其对阿加迪尔的潜在影响,我们填补了现有文献中的一个关键空白,这些文献在很大程度上忽视了这个脆弱的沿海城市。阿加迪尔密集的城市结构、繁荣的旅游业和战略港口使其特别容易受到海啸造成的破坏。我们使用NSWING(非线性浅水嵌套网格)数值模拟模型分析了四种可信的地震情景,这些情景先前在科学文献中被确定为1755年事件的潜在触发因素。通过最高浪高和淹没距离的高分辨率地图显示,结果显示出严重的脆弱性,浪高范围为0.1至5.3米,内陆淹没距离可达310米。这些发现为地方当局和决策者提供了重要的见解,为加强阿加迪尔的海啸防备、抗灾战略和提高公众意识举措提供了科学基础。
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引用次数: 0
Groundwater quality, pollution sources, and health risk assessment in a mining-dominated district: A case study from Atiwa West, Ghana 以采矿为主地区的地下水质量、污染源和健康风险评估:来自加纳阿提瓦西部的案例研究
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-21 DOI: 10.1016/j.jafrearsci.2026.106029
Roland Asare , Raymond Webrah Kazapoe , Obed Fiifi Fynn , Samuel Dzidefo Sagoe , Joseph Turkson , Kwabina Ibrahim , Patrick Asamoah Sakyi , Frank Kwakye Nyame
This study examined groundwater hydrogeochemistry, pollution sources, and health risks in the mining-dominated Atiwa West District of Ghana using 56 borehole and well samples collected in dry and wet seasons. Electrical conductivity and total dissolved solids ranged from 67.2 to 692 μS/cm and 33.6–389 mg/L, respectively, classifying the water as fresh. Iron (mean 2.05 mg/L, wet) and manganese (mean 0.33 mg/L, wet) exceeded WHO aesthetic limits, while arsenic (max 0.006 mg/L) and mercury (max 0.002 mg/L) approached guideline values. Principal Component Analysis explained over 80 % of variance, linking carbonate weathering, redox mobilization of Fe–Mn, and sulphide oxidation as key geochemical controls, with anthropogenic contributions evident in wet-season recharge. Saturation index modeling showed persistent undersaturation of evaporite minerals (gypsum, halite, sylvite), indicating active dissolution, while carbonate minerals (calcite, aragonite, dolomite) were near equilibrium to supersaturated, reflecting their buffering role in aquifers. Water Quality Index (WQI) ranged from excellent (<25) to very poor (>200), with deteriorated quality more common near mining and agricultural zones in the wet season. HHRA results indicate that most risks remain within acceptable limits, though non-carcinogenic HI exceedances reached 3.97 percent in adults and 7.66 percent in children during the dry season, declining to 2.43 percent and 4.83 percent in the wet season. Cancer risk exceedances affected 8.02 percent of adults and 12.69 percent of children in the dry season, reducing to 5.60 percent and 9.26 percent in the wet season, with Mn and Cu as the dominant contributors to non-carcinogenic risk.
本研究利用在干湿季节收集的56个钻孔和井样,检查了加纳以采矿为主的Atiwa西区的地下水水文地球化学、污染源和健康风险。电导率和总溶解固形物分别为67.2 ~ 692 μS/cm和33.6 ~ 389 mg/L,属于淡水。铁(平均2.05毫克/升,湿法)和锰(平均0.33毫克/升,湿法)超过了世卫组织的美学限制,而砷(最高0.006毫克/升)和汞(最高0.002毫克/升)接近指导值。主成分分析解释了80%以上的差异,将碳酸盐风化、铁锰氧化还原动员和硫化物氧化作为关键的地球化学控制因素,在雨季补给中有明显的人为贡献。饱和指数模拟显示,蒸发岩矿物(石膏、岩盐、钾盐)持续欠饱和,表明溶蚀作用活跃,而碳酸盐矿物(方解石、文石、白云石)接近平衡至过饱和,反映了它们在含水层中的缓冲作用。水质指数(WQI)从优秀(<25)到极差(>200)不等,在雨季,水质恶化在矿区和农业区附近更为常见。HHRA的结果表明,大多数风险仍然在可接受的范围内,尽管非致癌性的HI在旱季超过了3.97%的成人和7.66%的儿童,在雨季下降到2.43%和4.83%。在旱季,癌症风险超标影响了8.02%的成年人和12.69%的儿童,在雨季减少到5.60%和9.26%,Mn和Cu是非致癌风险的主要贡献者。
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引用次数: 0
Geochemical evidence for a thermogenic oil-associated gas petroleum system for JDT field in Abu El Gharadig basin, Egypt 埃及Abu El Gharadig盆地JDT油田热成油气系统的地球化学证据
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.jafrearsci.2026.106036
Mohamed A. Agamy , Mahmoud Y. Zein El Din , Mohamed M. El Nady , Walid A. Makled
This study presents a comprehensive geochemical assessment of rock samples and natural gas data to evaluate the petroleum system of the Abu El Gharadig Basin. The investigation focuses on the Upper Cretaceous Abu Roash (C –G) members and Middle Jurassic Khatatba Formation which represent the principal source rocks in the basin. Total organic carbon (TOC) and Rock-Eval pyrolysis analyses reveal significant organic richness, with TOC values reaching up to 3.14 wt%, and hydrogen index (HI) values peaking at 489 mg HC/g TOC indicative of Type II kerogen. This indicates a strong potential for liquid hydrocarbon generation. Thermal maturity parameters including Tmax (430–448 °C) and vitrinite reflectance (Ro = 0.50–0.92 %) confirm that these source rocks lie within the oil window, with deeper intervals approaching peak maturity. Geochemical characterization of natural gas from the Apollonia reservoir further supports this interpretation. The gases are gas associated with oil generation with elevated wetness and high ethane concentrations, indicating an association with condensates derived from the thermal cracking of liquid hydrocarbons. The absence of isotopic alteration suggests efficient migration and preservation. Basin modeling shows that hydrocarbon generation in the Abu El Gharadig basin began in the Early Cretaceous, with major oil-to-gas conversion occurring much later, and structural traps forming beforehand to secure these accumulations. Collectively, the results confirm a dynamic and effective petroleum system within the Abu El Gharadig Basin, with the Abu Roash and Khatatba formations as key hydrocarbon sources driving both generation and expulsion processes. Collectively, the results confirm a dynamic and effective petroleum system within the Abu El Gharadig Basin, where the Abu Roash and Khatatba formations as key hydrocarbon sources driving both generation and expulsion processes.
通过岩石样品和天然气资料的综合地球化学评价,对Abu El Gharadig盆地的含油气系统进行了评价。以上白垩统Abu Roash (C -G)段和中侏罗统Khatatba组为主要烃源岩。总有机碳(TOC)和岩石热解分析显示有机质丰度显著,TOC值高达3.14 wt%,氢指数(HI)峰值为489 mg HC/g TOC,为ⅱ型干酪根。这表明该区具有强大的生烃潜力。热成熟度参数Tmax(430 ~ 448℃)和镜质组反射率(Ro = 0.50 ~ 0.92%)证实这些烃源岩位于油窗内,层段越深,成熟度越接近峰值。来自Apollonia储层的天然气地球化学特征进一步支持了这一解释。这些气体是与产油有关的气体,具有较高的湿度和较高的乙烷浓度,表明与液态烃热裂解产生的凝析油有关。同位素变化的缺失表明了有效的迁移和保存。盆地模拟表明,Abu El Gharadig盆地的生烃始于早白垩世,主要的油气转化发生在晚得多的时间,构造圈闭的形成提前确保了这些聚集。总的来说,研究结果证实了Abu El Gharadig盆地内存在一个动态而有效的石油系统,Abu Roash和Khatatba组是驱动生排过程的关键烃源。总的来说,这些结果证实了Abu El Gharadig盆地内存在一个动态和有效的石油系统,其中Abu Roash和Khatatba组是驱动生排过程的关键烃源。
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引用次数: 0
Magnetic susceptibility records and sequence stratigraphy in shallow-water carbonates, fluvial-deltaic, and organic / phosphatic-rich deposits: Insights from the Paleogene-Neogene of Central and NE Tunisia 浅水碳酸盐岩、河流三角洲和富有机/富磷矿床的磁化率记录和层序地层学:来自突尼斯中部和东北部古近系-新近系的启示
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.jafrearsci.2026.106024
Jihede Haj Messaoud , Hela Fakhfakh Ben Jemai , Chokri Yaich , Hanen Kamoun , Sameh Khaled , Zied Chikhaoui
Magnetic susceptibility is recognized as a predictive tool in reservoir identification, mineral exploration, and sequence stratigraphy; however, its controlling factors in mixed carbonate–siliclastic systems remain insufficiently understood. This study aims to elucidate the primary drivers of magnetic susceptibility variability by examining carbonate and siliciclastic systems from central and northeastern Tunisia. We specifically assess the relationships between magnetic susceptibility, lithology, facies, and mineralogy, with attention to the modifying effects of diagenetic processes and the occurrence of phosphate and organic matter enrichment. Our methodological approach integrates high-resolution magnetic susceptibility measurements with detailed sedimentological logging, facies analysis, carbonate content, and mineralogical characterization. In siliciclastic-dominated systems, distal fine-grained sediments yield elevated magnetic susceptibility values due to higher concentrations of magnetic minerals. At the same time, coarser facies tend to exhibit lower or negative magnetic susceptibility values. In carbonate settings, elevated magnetic susceptibility values are typically associated with regressive phases, while reduced values are observed during transgressions. Diagenetic modifications exert a substantial impact on the magnetic susceptibility signal. Dolomitization typically reduces magnetic susceptibility by replacing magnetic-bearing carbonate mud with less magnetic dolomite crystals, diluting the original signal. Intervals with phosphate are often marked by enhanced magnetic susceptibility values, reflecting the concentration of iron-bearing phases associated with phosphate mineralization. Organic-rich layers exhibit a mixed magnetic susceptibility response: in some cases, magnetic susceptibility increases due to the formation or preservation of authigenic magnetite under reducing early diagenetic conditions, whereas in other cases, magnetic susceptibility decreases, likely reflecting the absence of magnetic mineral formation or their dissolution under highly anoxic conditions. These findings emphasize the complex interplay of factors influencing magnetic susceptibility and demonstrate its potential as a valuable tool for sequence stratigraphy and mineralogical exploration in both siliciclastic and carbonate settings.
磁化率被认为是储层识别、矿产勘探和层序地层学的预测工具;然而,在碳酸盐-硅橡胶混合体系中,其控制因素尚不清楚。本研究旨在通过研究突尼斯中部和东北部的碳酸盐和硅屑体系来阐明磁化率变异的主要驱动因素。我们特别评估了磁化率、岩性、相和矿物学之间的关系,并注意了成岩作用对磷矿赋存和有机质富集的影响。我们的方法将高分辨率磁化率测量与详细的沉积学测井、相分析、碳酸盐含量和矿物学表征相结合。在硅塑料为主的体系中,由于磁性矿物浓度较高,远端细粒沉积物的磁化率值升高。同时,较粗相的磁化率值往往较低或为负。在碳酸盐环境中,磁化率值的升高通常与回退相有关,而在海侵期间观察到磁化率值的降低。成岩作用对磁化率信号有重要影响。白云化通常通过用磁性较弱的白云石晶体取代含磁性的碳酸盐泥浆来降低磁化率,从而稀释了原始信号。含磷酸盐层段通常以磁化率值增强为标志,反映了与磷矿化有关的含铁相的浓度。富有机物层表现出混合的磁化率响应:在某些情况下,磁化率增加是由于早期成岩条件下自生磁铁矿的形成或保存,而在其他情况下,磁化率降低,可能反映了磁性矿物形成的缺乏或它们在高度缺氧条件下的溶解。这些发现强调了影响磁化率的因素之间复杂的相互作用,并证明了磁化率作为一种有价值的层序地层学和矿物学勘探工具的潜力,无论是在硅屑和碳酸盐环境中。
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引用次数: 0
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Journal of African Earth Sciences
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