Groundwater is the primary source of freshwater in arid and semi-arid regions such as Dodoma, Tanzania, where surface water is scarce. This study assessed the hydrochemical characteristics and pollution status of groundwater in the Dodoma region using water quality indices and multivariate statistical approaches. Thirty-five groundwater samples were collected from boreholes distributed across different geological and land-use settings. Laboratory analyses revealed that the groundwater is generally alkaline (pH 5.8–8.2) with total dissolved solids (TDS) ranging from 135 mg/L to 1780 mg/L and electrical conductivity (EC) between 210 μS/cm and 2740 μS/cm. The dominant cations and anions followed the order Na+ > Ca2+ > Mg2+ > K+ and Cl− > SO42− > HCO3− > NO3−, respectively. Piper and base-exchange plots classified the groundwater as mainly of the Cl(SO4)–Na and Na+–SO42- types, indicating mineralization dominated by rock–water interaction and evaporation. The Pollution Index of Groundwater (PIG) classified 74.3 % of samples as insignificantly polluted, 17.1 % as low pollution, and 8.6 % as moderate pollution, while the Percentage Pollution Index (PPI) indicated that contamination was primarily anthropogenic. Water Quality Index (WQI) values ranged from 42 to 255, showing that 61.2 % of samples were of poor to very poor quality for drinking. Irrigation suitability assessment showed that 97.1 % of samples were suitable for salt-tolerant crops based on the permeability index and salinity hazard classification. Overall, groundwater mineralization in Dodoma is controlled by both geogenic and anthropogenic processes, emphasizing the need for regular monitoring and mitigation of human-induced contamination.
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