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Integration of multivariate statistical analysis, geochemical modeling, and irrigation water quality assessment in the aquifers of the South-Atlas Tinghir-Errachidia-Boudenib basin (Pre-African Trough, Morocco) 将多元统计分析、地球化学建模和灌溉水质评价纳入南阿特拉斯廷吉尔-埃拉希迪亚-布德尼布盆地(摩洛哥,非洲前槽)的含水层中
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-09 DOI: 10.1016/j.jafrearsci.2024.105444
Fadoua Laghrib , Sahar Elkasmi , Tarik Bahaj , Azddine Barbot , Mostapha Bouzekraoui , Mohamed Hilali , Youssef Touiss , Mohamed Draoui , Othmane Hammani , Fatima Benammi , Rachid Ben Aakame , Myrieme Walid
Irrigation development commonly results in the onset of salinization and soil alkalinization, to different degrees, and the irrigation water quality index (IWQI) is the main method utilized globally to assess water quality. This study aims to investigate the hydrogeochemical characteristics and irrigation suitability of groundwater in the South-Atlas region, one of the arid regions in the southeastern part of Morocco, using Principal Component Analysis (PCA) was applied to identify the main factors influencing groundwater quality and Hierarchical Cluster Analysis (HCA) was then used to classify the water samples into distinct groups based on their hydrogeochemical properties. The research also evaluates groundwater suitability for irrigation using several irrigation water quality indices (IWQIs) such as irrigation water quality index (IWQI), Sodium Adsorption Ratio (SAR), Percent Sodium (Na%), Permeability Index (PI), magnesium hazard (MH), and Potential salinity (PS) assisted by geochemical modeling and the Piper trilinear diagram. Fifty groundwater samples were systematically collected in February 2023 from various aquifers (Senonian, Infracenomanian, Quaternary, and Paleozoic) based on their geographical distribution and hydrogeological significance. The Piper diagram reflecting Ca-Mg-Cl-SO4 followed by Na-K-Cl-SO4 and Ca-Mg-HCO3 water facies under the stress of evaporation, saltwater intrusion and reverse ion exchange processes.
The results of the IWQI indicated that, roughly speaking, 0% of the samples fell into the unrestricted category, 46% had leaching restrictions ranging from low to moderate, and 54% of the samples were classified as high to severely limited, meaning that only high salt tolerance plants can be irrigated with groundwater.
The Senonian samples demonstrated excellent SAR, Na%, and PI, values, whereas most groundwater samples from other aquifers showed good to permissible suitability for irrigation. The study identified water-rock interactions, particularly in the Infracenomanian aquifer, and the use of agricultural fertilizers as significant factors affecting groundwater composition.
灌溉发展通常会导致不同程度的盐碱化和土壤碱化,灌溉水质量指数(IWQI)是全球评估水质的主要方法。本研究旨在调查南阿特拉斯地区(摩洛哥东南部干旱地区之一)地下水的水文地质化学特征和灌溉适宜性,采用主成分分析法(PCA)确定影响地下水水质的主要因素,然后采用层次聚类分析法(HCA)根据水文地质化学特征将水样分为不同的组别。该研究还利用灌溉水水质指数(IWQI)、钠吸附率(SAR)、钠百分比(Na%)、渗透指数(PI)、镁危害(MH)和潜在盐度(PS)等灌溉水水质指数,并在地球化学模型和派普三线图的辅助下,对地下水的灌溉适宜性进行了评估。2023 年 2 月,根据不同含水层(元古代、下元古代、第四纪和古生代)的地理分布和水文地质意义,系统收集了 50 个地下水样本。Piper 图反映了在蒸发、盐水入侵和反向离子交换过程压力下的 Ca-Mg-Cl-SO4 水相,其次是 Na-K-Cl-SO4、Ca-Mg-HCO3 水相。IWQI 的结果表明,粗略地说,0% 的样本属于无限制类别,46% 的样本具有从低到中度的浸出限制,54% 的样本被归类为高度到严重限制类别,这意味着只有耐盐性高的植物才能用地下水灌溉。该研究发现,水与岩石之间的相互作用(尤其是在 Infracenomanian 含水层中)以及农业化肥的使用是影响地下水成分的重要因素。
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引用次数: 0
Remote sensing and magnetic characterization of the Au mineralization and its structural implications: Meatiq dome, Eastern Desert, Egypt 金矿化的遥感和磁性特征及其结构影响:埃及东部沙漠 Meatiq 穹顶
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-09 DOI: 10.1016/j.jafrearsci.2024.105442
M. Abdelwahed , M. Abdelazeem , A.A. Eldougdoug , M.M. Gobashy , Y.M. Abd El-Rahman , S. Said , A. Abdelhalim
This article examines hydrothermally altered ophiolitic ultramafic rocks (HAOU), specifically Listvenite, which are thrust over the Meatiq dome in the context of gold mineralization. These rocks represent gneissic complexes located in Egypt's eastern desert. The analyses presented herein are essential for understanding the distribution of sheared serpentinite on and beneath the surface and the underlying domal structure. This study offers critical insights into the distribution of serpentinite at Meatiq. It combines remote sensing, aerial and ground magnetic data with petrological, geochemical, and geological analyses to create precise geological maps of potential subsurface igneous structures commonly linked to gold mineralization. Remote sensing is used to test for rock differentiation; intensive field geological investigations were conducted along several traverses. Petrographic and geochemical analysis of selected samples confirmed Au content in some localities. Additionally, tomographic inversion of the collected magnetic land profiles has unveiled previously unidentified subsurface distributions of magnetic susceptibilities, which are essential for explaining the observed surface magnetic anomalies and for understanding the subsurface arrangement of various rock units. Results show that the HAOU rocks have a lower magnetic susceptibility signature relative to the adjacent serpentinites, the serpentinite from South Meatiq shows relatively high gold content, and the gold content decreases with carbonation and alteration of the serpentinite into talc-carbonate, as detected geochemically. The procedure followed in the present study can be regionally applied to studying HAOU rocks of similar geologic conditions. The novelty of this study, beyond the introduction of a novel workflow, lies in the revelation that the rocks forming the Meatiq dome are in thrust contact with steeply dipping suprastructure units.
本文结合金矿化研究了热液蚀变蛇绿岩超基性岩(HAOU),特别是Listvenite,这些岩石被推覆在Meatiq圆顶上。这些岩石是位于埃及东部沙漠的片麻岩复合体。本文介绍的分析对于了解地表和地下剪切蛇绿岩的分布以及下伏穹隆结构至关重要。这项研究为了解梅阿提克蛇绿岩的分布提供了重要依据。它将遥感、航空和地面磁力数据与岩石学、地球化学和地质分析相结合,绘制出与金矿化相关的潜在地下火成岩结构的精确地质图。利用遥感技术测试岩石分异;沿着几条穿越路线进行了深入的实地地质调查。对选定样本进行的岩相学和地球化学分析证实了某些地方的金含量。此外,对收集到的磁性地层剖面进行层析反演,揭示了以前未发现的地表下磁感应强度分布,这对于解释观测到的地表磁异常和了解不同岩石单元的地表下排列情况至关重要。结果表明,相对于邻近的蛇纹岩,HAOU 岩石具有较低的磁感应强度特征,南梅阿提克的蛇纹岩显示出相对较高的含金量,而且正如地球化学所探测到的那样,金含量随着碳化和蛇纹岩蚀变为滑石碳酸盐而降低。本研究中遵循的程序可在地区范围内用于研究地质条件类似的 HAOU 岩石。本研究的新颖之处不仅在于引入了新的工作流程,还在于揭示了形成 Meatiq 圆顶的岩石与陡倾的上基底单元呈推力接触。
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引用次数: 0
The community structure of recent ostracods in the Burullus lagoon, Egypt 埃及布卢卢斯泻湖近代桡足类的群落结构
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-09 DOI: 10.1016/j.jafrearsci.2024.105443
Sherif M. El Baz , Abdalla Shahin , Ahmed Al Furjany
This work concentrates on the recent ostracod community from the bottom sediments of Burullus lagoon (BuL), Egypt. It aims to identify the impacts of the environmental factors such salinity, substrate and pH on the ostracod community. Only four ostracod species are identified, Cyprideis torosa, Leptocythere castanea, Loxoconcha elliptica and Cypridopsis vidua. The results reflect the abundance of a sole tolerant species, C. torosa (79.59–100 %, with an average of 94.18 %), in all sites. Actually, this conclusion reflects the dominance of unfavorable conditions for increasing the biodiversity in the lagoon. Moreover, the associated benthic foraminiferal assemblage suffers from the rarity of species and the abundance of one tolerant species, Ammonia tepida. Therfore, there is an urgent need to understand the environmental conditions in the BuL. The measured low salinities are suitable for the survival of only brackish ostracod species. Moreover, the distribution and structure of the ostracod assemblage are mainly controlled by the type of bottom sediments. Actually, as the content of sand increases, particularly at sites near the connection to the sea, low numbers of individuals are recorded, whereas the number of living species increases in muddy substrate. Furthermore, the sites with sandy substrate display thick-walled carapaces, while the others with muddy substrate possess thin-walled carapaces. Also, the occurrence of Cypridopsis vidua is restricted only to the muddy substrate. In terms of the hydraulic conditions, the highest abundance of living species is recorded in the southern part, where the quiet conditions prevail. The lagoon water is alkaline, so pH has no observed effects on the ostracod community. Accordingly, salinity, sediment types and hydraulic conditions play the major role in controlling the abundabce, diversity and distribution of ostracods in the study area. Geographically, the identified ostracod species are broadly distributed in the brackish lagoons of the Mediterranean region.
这项工作主要研究埃及布卢卢斯泻湖(BuL)底层沉积物中的近期桡足类群落。其目的是确定盐度、底质和 pH 值等环境因素对骨桡动物群落的影响。只确定了四种桡足类,即 Cyprideis torosa、Leptocythere castanea、Loxoconcha elliptica 和 Cypridopsis vidua。研究结果表明,在所有地点,只有 C. torosa(79.59%-100%,平均 94.18%)是唯一的耐受性物种。实际上,这一结论反映出不利条件在增加泻湖生物多样性方面占主导地位。此外,相关底栖有孔虫的种类稀少,只有一种耐受性强的物种 Ammonia tepida 数量丰富。因此,迫切需要了解布劳群岛的环境条件。测量到的低盐度只适合咸水桡足类的生存。此外,浮游动物群的分布和结构主要受底层沉积物类型的控制。实际上,随着沙子含量的增加,特别是在靠近海边的地点,记录到的个体数量较少,而在泥质底层,生活物种的数量有所增加。此外,底质为沙质的地点显示出厚壁的甲壳,而底质为泥质的地点则显示出薄壁的甲壳。此外,Cypridopsis vidua 的出现也仅限于泥质底质。在水文条件方面,南部地区的生物物种数量最多,因为那里的环境较为安静。泻湖水呈碱性,因此没有观察到 pH 值对桡足类群落的影响。因此,盐度、沉积物类型和水力条件在控制研究区内桡足类的丰度、多样性和分布方面起着主要作用。从地理位置上看,已确定的桡足类物种广泛分布于地中海地区的咸水泻湖。
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引用次数: 0
Constraints of the regional deformation on the hydrothermal veins in Ousdrat and Aït Ahmane ore deposits (Bou Azzer-El Graara inlier, central Anti-Atlas, Morocco): Implications for mineral exploration 区域变形对 Ousdrat 和 Aït Ahmane 矿床热液矿脉的制约(摩洛哥阿特拉斯中部 Bou Azzer-El Graara 山脉):对矿产勘探的影响
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-09 DOI: 10.1016/j.jafrearsci.2024.105441
Saber Salmi , Ezzoura Errami , Abdellatif Jouhari , Jamal El Kabouri , Nasser Ennih , Omar Outaaoui , Said Ilmen , Younes Moundi , Abdelhak Karfal , Lhou Maacha
The overlap of tectonic and magmatic events in the Bou Azzer-El Graara inlier causes a complexity for understanding the absolute and/or relative chronology between the deformation and the hydrothermal system. In the central northern part of the Bou Azzer-El Graara inlier, syn-orogenic ca. 650 Ma Aït Ahmane and Ousdrat plutons have been deformed under NE-SW shortening and with metamorphic conditions. These plutons are affected by fault systems with four mains directions: N015, N090, N140, and N040. The last two fault systems are the most mineralized and they are weakly constrained in the frame of deformation phases affecting the Bou Azzer inlier, and filling style. In addition, Pan-African, WACadomian or Hercynian origin of NE-SW faults is not yet reached. This contribution aims to clarify these issues based on structural, textural and morphological of these faults and veins. Our analyses highlight that most of these structures were formed through open-space filling and crack-seal-slip mechanisms. N140 contacts faults between serpentinite and quartz diorite experienced multiple reactivations during the WACadomian stages. The oldest activation was in ductile condition and later reactivated in a transpression to transtension regime leading to the development of N040 faults as sinistral antithetic faults due to NNE stress evolution. Field observations suggest that N040 structures affect late Ediacaran Ouarzazate Group, but not the Adoudounian Formation, highlight their WACadomian origine. The N040 structures preserve metric to microscopic cataclastic shear zones. This evolution suggests that the hydrothermal system in the Bou Azzer inlier shifted from ductile-brittle hydrothermal style along the N140 foliated contact to a brittle regime along the N040 sinistral-normal faults. Some intra-vein microtextures suggest that this hydrothermal fluid was emplaced in a predominantly extensional and tectonically active environment, as evidenced by extensional relay, syntaxial and antiaxial textures, and elongated grains. Consequently, a detailed analysis of the morphology, textures, filling types, and fault movements is an essential and important tool for establishing the relative chronology of deformation in front of the N140 and N040 veins.
Bou Azzer-El Graara 山脉的构造事件和岩浆事件相互重叠,给了解变形和热液系统之间的绝对和/或相对年代学带来了复杂性。在 Bou Azzer-El Graara 山脉中部偏北地区,约 650 Ma 的 Aït Ahmane 和 Ousdrat 同源岩体在 NE-SW 向缩短和变质条件下发生了变形。这些岩块受到四个主要方向断层系统的影响:N015、N090、N140 和 N040。后两个断层系统的矿化程度最高,但在影响布阿泽尔(Bou Azzer)岩体的变形阶段和充填方式的框架内,对它们的约束较弱。此外,东北-西南断层的泛非、瓦卡托米亚或海西起源尚未确定。本文旨在根据这些断层和矿脉的结构、纹理和形态澄清这些问题。我们的分析强调,这些结构大多是通过开敞空间充填和裂缝-密封-滑动机制形成的。蛇绿岩与石英闪长岩之间的 N140 接触断层在瓦卡多姆期经历了多次重新激活。最古老的活化是在韧性条件下进行的,后来在转位到转张力机制下重新活化,导致 N040 断层因 NNE 应力演化而发展成正弦反断层。实地观察表明,N040 构造影响了埃迪卡拉晚期的瓦尔扎扎特组,但没有影响阿杜杜年地层,这凸显了其起源于瓦卡多米期。N040 构造保留了微尺度的碎屑剪切带。这种演变表明,布阿泽尔内层的热液系统从沿 N140 褶皱接触的韧性-脆性热液方式转变为沿 N040 正弦正断层的脆性热液方式。一些脉内微观纹理表明,这种热液主要赋存于延伸和构造活跃的环境中,延伸中继、句法和反轴纹理以及拉长的晶粒就是证明。因此,对形态、纹理、充填类型和断层运动进行详细分析,是确定 N140 和 N040 矿脉前方变形相对年代的重要工具。
{"title":"Constraints of the regional deformation on the hydrothermal veins in Ousdrat and Aït Ahmane ore deposits (Bou Azzer-El Graara inlier, central Anti-Atlas, Morocco): Implications for mineral exploration","authors":"Saber Salmi ,&nbsp;Ezzoura Errami ,&nbsp;Abdellatif Jouhari ,&nbsp;Jamal El Kabouri ,&nbsp;Nasser Ennih ,&nbsp;Omar Outaaoui ,&nbsp;Said Ilmen ,&nbsp;Younes Moundi ,&nbsp;Abdelhak Karfal ,&nbsp;Lhou Maacha","doi":"10.1016/j.jafrearsci.2024.105441","DOIUrl":"10.1016/j.jafrearsci.2024.105441","url":null,"abstract":"<div><div>The overlap of tectonic and magmatic events in the Bou Azzer-El Graara inlier causes a complexity for understanding the absolute and/or relative chronology between the deformation and the hydrothermal system. In the central northern part of the Bou Azzer-El Graara inlier, syn-orogenic ca. 650 Ma Aït Ahmane and Ousdrat plutons have been deformed under NE-SW shortening and with metamorphic conditions. These plutons are affected by fault systems with four mains directions: N015, N090, N140, and N040. The last two fault systems are the most mineralized and they are weakly constrained in the frame of deformation phases affecting the Bou Azzer inlier, and filling style. In addition, Pan-African, WACadomian or Hercynian origin of NE-SW faults is not yet reached. This contribution aims to clarify these issues based on structural, textural and morphological of these faults and veins. Our analyses highlight that most of these structures were formed through open-space filling and crack-seal-slip mechanisms. N140 contacts faults between serpentinite and quartz diorite experienced multiple reactivations during the WACadomian stages. The oldest activation was in ductile condition and later reactivated in a transpression to transtension regime leading to the development of N040 faults as sinistral antithetic faults due to NNE stress evolution. Field observations suggest that N040 structures affect late Ediacaran Ouarzazate Group, but not the Adoudounian Formation, highlight their WACadomian origine. The N040 structures preserve metric to microscopic cataclastic shear zones. This evolution suggests that the hydrothermal system in the Bou Azzer inlier shifted from ductile-brittle hydrothermal style along the N140 foliated contact to a brittle regime along the N040 sinistral-normal faults. Some intra-vein microtextures suggest that this hydrothermal fluid was emplaced in a predominantly extensional and tectonically active environment, as evidenced by extensional relay, syntaxial and antiaxial textures, and elongated grains. Consequently, a detailed analysis of the morphology, textures, filling types, and fault movements is an essential and important tool for establishing the relative chronology of deformation in front of the N140 and N040 veins.</div></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":"220 ","pages":"Article 105441"},"PeriodicalIF":2.2,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Petrogenetic relationships between Paleoproterozoic granitoids and rare-element pegmatites from Dibilo (Liptako, West Niger, West African Craton) 古新生代花岗岩与 Dibilo(西非克拉通尼日尔西部 Liptako)稀有元素伟晶岩之间的成岩关系
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-04 DOI: 10.1016/j.jafrearsci.2024.105440
Sofiyane Abdourahamane Attourabi , Marieke Van Lichtervelde , Mallam Mamane Hallarou , Yacouba Ahmed , Mahamane Moustapha Sanda Chékaraou , Amadou Abdourhamane Toure
The rare-element pegmatites of Dibilo form intrusions in a tonalitic gneiss of the Paleoproterozoic Téra-Ayorou pluton about 4 km from the contact zone with the Diagorou-Darbani greenstone belt, in the Nigerien Liptako (NE portion of the Man Ridge of the West African Craton). The general objective of the present study is to determine the petrogenetic relationships between the granitoids and the Dibilo pegmatites through a multidisciplinary approach combining petrology, geochemistry, structural geology and metallogeny. Two generations of granitoids have been distinguished at Dibilo. A first generation of metaluminous to weakly peraluminous granitoids (tonalitic gneiss, metadiorite and two-mica granitic gneiss) constitute a calc-alkaline series. Trace element geochemical signatures suggest that these granitoids were emplaced in an island arc and subduction zone context. A second generation of granitoids (leucogranites), encompassing two-mica, muscovite and two-mica-garnet granites, are peraluminous and calc-alkaline. These leucogranites are fertile, i.e., rich in incompatible elements, with Li concentrations attaining 250 ppm in the richest. A model of partial melting shows that they could derive from the partial melting of Li-rich metadiorite, which is itself highly enriched in lithium (150 ppm). One sample of migmatite has Li contents of 300 ppm, which evidences the fertile nature of the tonalitic-dioritic-granitic gneiss complex.
Three types of pegmatite have been identified at Dibilo: sterile pegmatites (type I), peraluminous and poorly evolved; Nb-Ta pegmatites (type II-a) and Nb-Ta, Mo pegmatites (type II-b), moderately evolved, peraluminous, respectively mineralized with columbite-group minerals (type II-a) and columbite-group minerals and Mo-bearing sulfide (type II-b); and highly evolved, peraluminous Li and Nb-Ta pegmatites (type III) mineralized with spodumene and columbite-group minerals. The type I barren pegmatites share similarities with the leucogranites and could also originate from the partial melting of the dioritic gneiss. The highly evolved type II-a, type II-b and type III pegmatites correspond to the residual liquids resulting from the fractional crystallization of leucogranites. Therefore, we propose that the Dibilo rare-element pegmatites derive from both fractional crystallization and partial melting processes within the tonalitic-dioritic-granitic complex.
迪比洛稀有元素伟晶岩形成于距尼日尔利普塔科(西非克拉通马恩海脊东北部)与迪亚哥鲁-达尔巴尼绿岩带接触带约 4 公里处的古新生代 Téra-Ayorou 岩体中的色质片麻岩的侵入体。本研究的总体目标是通过结合岩石学、地球化学、构造地质学和成矿学的多学科方法,确定花岗岩和迪比洛伟晶岩之间的岩石成因关系。迪比洛的花岗岩分为两代。第一代金属铝至弱过铝花岗岩(黑云母片麻岩、透辉石和双云母花岗片麻岩)构成了钙碱性系列。微量元素地球化学特征表明,这些花岗岩是在岛弧和俯冲带背景下形成的。第二代花岗岩(白花岗岩)包括双云母花岗岩、蕈云母花岗岩和双云母石榴石花岗岩,均为过铝和钙碱性。这些白花岗岩是肥沃的,即富含不相容元素,最富含的锂浓度达到 250 ppm。局部熔融模型显示,它们可能来自富锂偏闪长岩的局部熔融,而偏闪长岩本身就富含锂(150 ppm)。有一个伟晶岩样本的锂含量达到了百万分之 300,这证明了辉绿岩-闪长岩-花岗岩片麻岩复合体的肥沃性质。在迪比洛发现了三种类型的伟晶岩:不育伟晶岩(I 型),过铝,演化程度低;铌钽伟晶岩(II-a 型)和铌钽、钼伟晶岩(II-b 型),中度演化,过铝,分别含有铌铁矿族矿物(II-a 型)和铌铁矿族矿物及含钼硫化物(II-b 型);以及高度演化、过铝的锂和铌钽伟晶岩(III 型),矿化物为闪锌矿和铌铁矿族矿物。I 型贫瘠伟晶岩与白榴石有相似之处,也可能源自闪长岩片麻岩的部分熔融。高度演化的Ⅱ-a型、Ⅱ-b型和Ⅲ型伟晶岩与白榴石部分结晶产生的残留液体相对应。因此,我们认为,迪比洛稀有元素伟晶岩源于辉绿岩-闪长岩-花岗岩复合体中的碎裂结晶和部分熔融过程。
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引用次数: 0
Physico-thermal and geochemical behavior and alteration of the Au indicator gangue hydrothermal quartz at the Kubi Gold ore deposits 库比金矿床金指示剂煤矸石热液石英的物理-热学和地球化学行为及蚀变作用
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-04 DOI: 10.1016/j.jafrearsci.2024.105439
Gabriel K. Nzulu, Lina Rogström, Jun Lu, Hans Högberg, Per Eklund, Lars Hultman, Martin Magnuson
Altered and gangue quartz in hydrothermal veins from the Kubi Gold deposit in Dunkwa on Offin in the central region of Ghana are investigated for possible Au-associated indicator minerals and to provide the understanding and increase the knowledge of the mineral hosting and alteration processes in quartz. X-ray diffraction, air annealing furnace, differential scanning calorimetry, energy dispersive X-ray spectroscopy, and transmission electron microscopy have been applied on different quartz types outcropping from surface and bedrocks at the Kubi Gold Mining to reveal the material properties at different temperatures. From the diffraction results of the fresh and annealed quartz samples, we find that the samples contain indicator and the impurity minerals iron disulfide, biotite, titanium oxide, and magnetite. These minerals, under oxidation process between 574 and 1400 °C temperatures experienced hematite alterations and a transformation from α-quartz to β-quartz and further to cristobalite as observed from the calorimetry scans for hydrothermally exposed materials. The energy dispersive spectroscopy revealed elemental components of Fe, S, Mg, K, Al, Ti, Na, Si, O, and Ca contained in the samples, and these are attributed to the impurity phase minerals observed in the diffraction. The findings also suggest that during the hydrothermal flow regime, impurity minerals and metals can be trapped by voids and faults. Under favorable temperature conditions, the trapped minerals can be altered to change color at different depositional stages by oxidation and reduction processes leading to hematite alteration which is a useful indicator minerals in mineral exploration.
对加纳中部地区奥芬河畔敦夸的库比金矿床热液矿脉中的蚀变石英和矸石石英进行了研究,以寻找可能的金相关指示矿物,并了解和增加有关石英中矿物寄存和蚀变过程的知识。对库比金矿地表和基岩出露的不同类型石英采用了 X 射线衍射、空气退火炉、差示扫描量热仪、能量色散 X 射线光谱仪和透射电子显微镜,以揭示不同温度下的材料特性。从新鲜和退火石英样品的衍射结果来看,我们发现样品中含有指示剂和杂质矿物二硫化铁、生物铁、氧化钛和磁铁矿。这些矿物在 574 至 1400 °C 的氧化过程中发生了赤铁矿化,并从α-石英转变为β-石英,然后进一步转变为霞石。能量色散光谱显示了样品中含有的 Fe、S、Mg、K、Al、Ti、Na、Si、O 和 Ca 等元素成分,这些元素可归因于衍射中观察到的杂相矿物。研究结果还表明,在热液流动过程中,杂质矿物和金属会被空隙和断层困住。在有利的温度条件下,被截留的矿物会在不同的沉积阶段通过氧化和还原过程改变颜色,从而导致赤铁矿蚀变,这是矿产勘探中一种有用的指示矿物。
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引用次数: 0
Paleoenvironmental conditions across the Coniacian-Santonian in the Kometan Formation, northeastern Iraq: Insights from planktonic foraminifera distribution, mineralogy and geochemistry 伊拉克东北部科米坦地层科尼亚期-桑顿期的古环境条件:浮游有孔虫分布、矿物学和地球化学的启示
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-29 DOI: 10.1016/j.jafrearsci.2024.105437
Mohammed A. Sulaiman , Ali I. Al-Juboury , Majid M. Al Mutwali , Irfan Sh Asaad , David L. Dettman , Nasir Alarifi , Fathy Abdalla , Giovanni Zanoni , Harry Rowe
The paleoenvironmental conditions during the Coniacian-Santonian interval within the Kometan Formation in northeastern Iraq have been analyzed through the distribution of depth-related planktonic foraminifera in the carbonate rocks (limestone and marly limestone) of the Kometan Formation using standard washing method for soft samples and thin section method for hard samples supported by mineralogical investigations, geochemical analysis and stable isotopic δ13C and δ18O data. The findings indicate that saline marine waters and a hot, dry to semi-arid climate with low to medium oxygen conditions were conducive to deposition, which was characterized by high organic productivity due to marine transgression. The study revealed that the distribution of shallow water forms (SWF) of globular-shaped foraminifera, compared to deep water forms (DWF) of keeled-shaped genera, along with δ13C data from the late Turonian-early Campanian succession, indicated a relatively low sea level throughout the Late Turonian period. The water level began to rise in the early Coniacian, continuing gradually until the late Coniacian, when a noticeable increase in sea level was observed. This elevated sea level persisted through the early and late Santonian periods, before starting to drop. A slight marine transgression was noted at the beginning of the early Campanian period, followed by a significant drop in sea level. During the late Turonian, a subtropical climate prevailed. Temperature increased during the early to middle Coniacian, decreased slightly at the beginning of the late Coniacian, and then rose again at the end of the late Coniacian, indicating a shift from tropical to subtropical climatic conditions. Similar hot climatic conditions persisted in a tropical-subtropical climate during the early to late Santonian and early Campanian, with a relative temperature drop near the end of the early Campanian. No evidence of an oceanic anoxic event (OAE3) was found in the Kometan Formation during the late Coniacian–early Santonian period. The hypothesized event, based on biostratigraphy, facies analysis, stable isotopes, geochemical evidence, and field study, was limited to demonstrating an increase in the ratio of keeled chamber planktonic foraminifera compared to globular chamber ones. This ratio increase of the keeled chamber types is believed to result from a deepening sedimentary environment due to rising sea levels, creating organic matter-rich beds with high productivity and relatively low oxygen conditions during the Coniacian-Santonian boundary.
在矿物学研究、地球化学分析和稳定同位素 δ13C 和 δ18O 数据的支持下,采用软样本标准洗涤法和硬样本薄片法,通过科米坦地层碳酸盐岩 (石灰岩和泥质灰岩)中与深度有关的浮游有孔虫的分布,分析了伊拉克东北部科米坦地层中科 尼阿世-山童期的古环境条件。研究结果表明,含盐海水和中低氧条件下的炎热、干燥至半干旱气候有利于沉积,而沉积的特点是海相侵蚀造成的高有机生产力。研究发现,与龙骨状有孔虫属的深水形态(DWF)相比,球状有孔虫的浅水形态(SWF)的分布,以及晚都仑世-早坎潘世演替的δ13C 数据表明,整个晚都仑世时期的海平面相对较低。海平面在海盆纪早期开始上升,并逐渐持续到海盆纪晚期,此时海平面明显上升。海平面的上升一直持续到山顿纪早期和晚期,然后开始下降。在坎帕尼亚早期,海平面略有下降,随后海平面显著下降。在都龙纪晚期,亚热带气候盛行。气温在冠亚纪早中期有所上升,冠亚纪晚期开始时略有下降,冠亚纪晚期结束时又有所上升,表明气候条件已从热带转向亚热带。在山顿纪早期至晚期以及坎盘纪早期,类似的炎热气候条件在热带-亚热带气候条件下持续存在,坎盘纪早期末期温度相对下降。在科米坦构造中没有发现科尼亚期晚期-山统早期发生过海洋缺氧事件(OAE3)的证据。根据生物地层学、岩相分析、稳定同位素、地球化学证据和实地考察,假设的事件仅限于证明龙骨状腔浮游有孔虫的比例比球状腔浮游有孔虫的比例有所增加。龙骨腔类型有孔虫比例的增加被认为是海平面上升导致沉积环境加深的结果,在科尼阿克-山口迭纪边界形成了富含有机质的海床,具有高生产力和相对低氧的条件。
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引用次数: 0
Sequence stratigraphic architecture and depositional evolution of the early Eocene-early Miocene Al Jabal Al Akhdar carbonate successions, N Cyrenaica Promontory, NE Libya – Interplay of tectonics and eustasy 利比亚东北部昔兰尼加岬角早始新世-中新世早期 Al Jabal Al Akhdar 碳酸盐岩层序地层结构与沉积演化--构造与蚀变的相互作用
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-26 DOI: 10.1016/j.jafrearsci.2024.105438
Muneer Abdalla, Salah Hassan, Akram Zafir, Abdlsaid Ibrahem, Ahmad Issa
The interactions of tectonics and eustasy on the stratigraphic architectural evolution of the early Eocene-early Miocene Al Jabal Al Akhdar carbonate sedimentary successions were evaluated. This evaluation was achieved through detailed analyses of microfacies, depositional interpretation, and sequence stratigraphic framework of five measured sections located within the Al Jabal Al Akhdar Uplift, northeast Libya. The study interval was subdivided into distinct microfacies based on lithological changes, grain size and components, sedimentary texture and structures, fossil contents, color, and vertical stacking pattern. Six major depositional settings were delineated: restricted lagoon, open marine lagoon, platform margin and shoals, platform-margin reefs, foreslope, and middle to lower slope. Four third-order unconformity-bounded depositional sequences were identified based on vertical and lateral facies distribution, variations in fossil contents, and diagenetic features. Each sequence is composed of a transgressive-regressive interval, except for the younger sequence, which only contains a transgressive unit. Four evolutionary stages are recognized: initiation, growth, high-relief platform, and subaerial exposure. Subsidence resulting from tectonism and sediment loading, coupled with rising sea-level, created the accommodation space for the sedimentation of the studied carbonates. Repeated eustatic sea-level fluctuations controlled the internal stratigraphic heterogeneity and sequence development. Tectonic uplift caused a major sea-level retreat, resulting in the emersion of the carbonate sequences. The pre-existing Mesozoic and Paleocene sequences that underwent major uplift during the Late Cretaceous-early Eocene formed a shallow-water positive-antecedent topography for the formation of the carbonate sediments. This study establishes a carbonate sequence stratigraphic hierarchy of different cyclic sedimentation orders and improves our knowledge of sedimentary and stratigraphic architectural evolution and depositional mechanisms of carbonate platforms in an inverted basin setting. This knowledge can aid in predicting the distribution of lithofacies and depositional systems of economic importance.
该研究评估了构造和侵蚀作用对早始新世-中新世早期 Al Jabal Al Akhdar 碳酸盐沉积层序结构演变的影响。通过对位于利比亚东北部 Al Jabal Al Akhdar 隆起带的五个测量断面的微地貌、沉积解释和层序地层框架进行详细分析,完成了这项评估工作。根据岩性变化、颗粒大小和成分、沉积质地和结构、化石含量、颜色和垂直堆积模式,研究区间被细分为不同的微地层。划分了六种主要沉积环境:限制性泻湖、开放性海洋泻湖、平台边缘和浅滩、平台边缘礁石、前坡和中下部斜坡。根据垂直和横向面层分布、化石含量的变化以及成岩特征,确定了四个三阶无断裂沉积序列。除较年轻的序列只包含一个迭压单元外,每个序列都由一个迭压-迭压区间组成。四个演化阶段分别为:起始阶段、生长阶段、高隆起平台阶段和次隆起阶段。构造运动和沉积物负载造成的沉降,加上海平面上升,为所研究的碳酸盐岩的沉积创造了容纳空间。反复的震旦纪海平面波动控制着内部地层的异质性和层序的发展。构造隆升导致海平面大幅后退,从而形成了碳酸盐岩序列。在晚白垩世-早始新世期间经历大隆起的中生代和古新世序列形成了碳酸盐沉积物形成的浅水正前缘地形。这项研究建立了不同循环沉积次序的碳酸盐序列地层层次,增进了我们对倒置盆地环境中碳酸盐平台的沉积和地层结构演化及沉积机制的了解。这些知识有助于预测具有重要经济意义的岩相和沉积系统的分布。
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引用次数: 0
Tectonic evolution and structural geology of the Jurassic succession in the Zubair oil field, southern Iraq 伊拉克南部祖拜尔油田侏罗纪演替的构造演化和构造地质学
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-26 DOI: 10.1016/j.jafrearsci.2024.105436
Aymen Adil Lazim , Amna M. Handhal , Fraidoon Najm Rashid
This study investigates the structural style and tectonic evolution of Jurassic succession in southern Iraq, within the Zubair oil field, which are crucial for charging oil to the Cretaceous reservoirs, utilized 3-D seismic reflection data to explore its complex geological history. The field is located in the Mesopotamian plain on the northeast Arabian Plate in southern Iraq. Four folds recognized: Hammar, Shuaiba, Rafdyia, and Safwan, each shaped by specific geodynamic processes. Hammar, Shuaiba, and Safwan are characterized as salt-related folds, influenced by salt tectonics. Rafdyia is identified as a compression-related fold formed due to the convergence of the Arabian and Eurasian plates. Forty-seven faults were identified, with diversity patterns and spatial distributions suggesting a tectonic history marked by three distinct phases: extensional tectonics, extensional with concurrent salt activity, and plate convergence. These phases have created a series of graben structures that, along with the identified folds, highlight the role of three primary tectonic processes: basement tectonics, salt dynamics, and plate interactions in shaping the structural style of the Zubair oil field during the Jurassic time.
本研究利用三维地震反射数据,对伊拉克南部祖拜尔油田内侏罗系演替的构造样式和构造演化进行了研究,这些构造样式和构造演化对于向白垩系储层充油至关重要。该油田位于伊拉克南部阿拉伯板块东北部的美索不达米亚平原。已确认的褶皱有四个:哈马褶皱、舒艾巴褶皱、拉夫迪亚褶皱和萨夫万褶皱,每个褶皱都由特定的地球动力过程形成。Hammar、Shuaiba 和 Safwan 是与盐有关的褶皱,受到盐构造的影响。拉夫第亚被确定为与压缩有关的褶皱,是由于阿拉伯板块和欧亚板块交汇而形成的。已确定的断层有 47 个,其多样性模式和空间分布表明其构造历史分为三个不同阶段:伸展构造、与盐活动同时发生的伸展构造以及板块汇聚。这些阶段形成了一系列地堑结构,与已发现的褶皱一起,凸显了三个主要构造过程的作用:基底构造、盐动力学和板块相互作用在侏罗纪时期塑造了祖拜尔油田的构造风格。
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引用次数: 0
Mesozoic clastic provenance during post-rift evolution of the Essaouira Agadir Basin, Northern Morocco 摩洛哥北部索维拉-阿加迪尔盆地断裂后演化过程中的中生代碎屑岩出处
IF 2.2 4区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-26 DOI: 10.1016/j.jafrearsci.2024.105429
Emmanuel Roquette , Aude Duval-Arnould , Orrin Bryers , Stefan Schröder , Tim Luber , Ian Millar , Rémi Charton , Luc Bulot , Jonathan Redfern
This study combines several provenance tools, analysis of published structural and geodynamic data, integrated with Low-Temperature Thermochronology (LTT) and time-Temperature Modelling (tTM) to reconstruct the evolution of source-to-sink systems feeding the Essaouira-Agadir Basin (EAB) during the Jurassic (Toarcian, Bathonian, and Kimmeridgian) and Lower Cretaceous (Hauterivian and Barremian).
LTT and tTM define timing and rate of subsidence and exhumation of the hinterland and allows modelling of the predicted age and lithology of eroding rock units from the most-likely source locations through time. Extrapolation of predicted surface geology allows recognition of the lithology of sedimentary overburden in the hinterland, much of which has been subsequently eroded and is not preserved in the modern surfical geological record.
Heavy mineral, petrography and detrital zircon data analysis was carried out on fluvial and shallow marine sandstones sampled from Jurassic and Cretaceous sections across in the EAB. The results document changing sediment source terrains through time. In the Early and Middle Jurassic, the heavy mineral and detrital zircon signature correlates with a Palaeozoic source, suggesting provenance was dominantly from erosion of Cambrian and Ordovician sandstone in the Central and Western Anti-Atlas. From the Late Jurassic to Early Cretaceous, the heavy mineral and zircon signatures have a strong affinity with Triassic sediments. This indicates a provenance switch to the exhuming West Moroccan Arch (MAM and Western Meseta), interpreted to have been largely covered by Triassic continental red beds at the time.
The results help in predicting sediment delivery offshore, into the deep-water basin, where sandstones are a target for hydrocarbon exploration. Defining timing of input, location and composition helps to de-risk exploration. All the intervals examined contained discrete fluvial systems entering in the EAB, suggesting multiple periods of clastic delivery. Results suggest the Middle Jurassic and Hauterivian and Barremian intervals offer the optimum time for delivery of coarse clastics to the shelf margin, and potentially into the deep basin. The source to sink maps developed in this study further characterize these systems, their provenance and timing.
这项研究结合了多种探源工具、对已公布的构造和地球动力学数据的分析,并与低温热成年学(LTT)和时间-温度模型(ttm)相结合,重建了侏罗纪(托阿尔克纪、巴斯顿纪和基默里德纪)和下白垩统(豪特里维纪和巴雷姆纪)期间索维拉-阿加迪尔盆地(EAB)的源-汇系统的演变。LTT 和 tTM 确定了腹地沉降和掘起的时间和速度,并可对最有可能的来源地侵蚀岩石单元的年龄和岩性进行预测建模。通过对预测的地表地质进行推断,可以识别腹地沉积覆盖层的岩性,其中大部分沉积覆盖层后来被侵蚀,没有保留在现代地表地质记录中。分析结果表明,沉积物来源地形随着时间的推移而不断变化。在早侏罗世和中侏罗世,重矿物和碎屑锆石特征与古生代来源相关,表明来源主要是寒武纪和奥陶纪砂岩在中西部反阿特拉斯地区的侵蚀。从晚侏罗世到早白垩世,重矿物和锆石特征与三叠纪沉积物有很强的亲缘关系。这些结果有助于预测沉积物向近海深水盆地的输送情况,该盆地的砂岩是油气勘探的目标。确定输入时间、地点和成分有助于降低勘探风险。所研究的所有区间都包含进入 EAB 的离散河流系统,这表明碎屑岩的输送经历了多个时期。研究结果表明,中侏罗世、豪特里维世和巴里米亚世时期是向大陆架边缘输送粗碎屑岩的最佳时期,也可能是向深海盆地输送碎屑岩的最佳时期。本研究绘制的源汇图进一步描述了这些系统、其来源和时间。
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Journal of African Earth Sciences
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