Pub Date : 2024-06-11DOI: 10.1016/j.jafrearsci.2024.105316
Almost all igneous rocks are composed of silicate minerals; carbonatites are the main exception to this rule. They form only a minor proportion of the continental crust but are of fundamental scientific and economic importance. These rocks, originally described as a limestone (Kaiserstuhl, Germany) or magmatic limestone (Alnö, Sweden), were recognized in 1921 by W. C. Brøgger as a distinct magmatic rock type under the name “Karbonatite” in the Fen complex (Norway). Extensive field mapping in Africa, and particularly studies within the Chilwa Alkaline Province (Malawi), have led to the discovery of diverse intrusive and extrusive carbonatites. The latter, including the Fort Portal volcanic field in Uganda, Rufunsa Province in Zambia, and Oldoinyo Lengai volcano in Tanzania (the only volcano ever to have been seen to erupt carbonatites), have been exceptionally important in the recognition of carbonatites as truly magmatic rocks. The possibility of the existence of carbonate melts has been confirmed and shown by experimental studies of diverse carbonate systems with added volatile components (H2O, F) and alkali elements (Na, K). The study of the Oldoinyo Lengai gregoryite-nyerereite carbonatites, which are mineralogically and compositionally different from all known carbonatites worldwide, has led to long-lasting discussions about the origin of carbonatites. This includes composition of primary/parental carbonate melt, derivation of carbonatites by either liquid immiscibility or fractional crystallization, carbonatite evolution, and especially, the possible genetic relationships between alkali-rich and alkali-poor carbonatites. The rapid alteration of Oldoinyo Lengai carbonatites and their transformation to calcite carbonatite-like rocks has been proposed as the explanation for the absence of alkali-rich carbonatites in the geological past. Detailed mineralogical studies have shown that the occurrence of nyerereite is not restricted to Oldoinyo Lengai and that this mineral is now known to occur in other carbonatites (e.g., Guly, Kovdor, Oka, Kerimasi), alkaline rocks, and kimberlites (and even in diamond). This would suggest compositionally different mantle-derived melts enriched in alkali elements. In addition, carbonatite tephra has an important role in the preservation of some key paleontologic and anthropologic localities in East Africa. Despite these important discoveries, several problems related to carbonatite petrogenesis are not yet resolved. Future work is required, and carbonatites within Africa, with its key localities, may help to solve these problems.
几乎所有火成岩都由硅酸盐矿物组成,碳酸盐岩是主要的例外。它们只占大陆地壳的一小部分,但却具有重要的科学和经济意义。这些岩石最初被描述为石灰岩(德国凯泽斯图尔)或岩浆石灰岩(瑞典阿尔诺),1921 年,W. C. Brøgger 以 "卡氏碳酸盐岩 "为名,在芬恩复合体(挪威)中将其确认为一种独特的岩浆岩类型。在非洲进行的广泛实地测绘,特别是在奇尔瓦碱性省(马拉维)进行的研究,发现了多种侵入和挤出碳酸盐岩。后者包括乌干达的 Fort Portal 火山带、赞比亚的 Rufunsa 省和坦桑尼亚的 Oldoinyo Lengai 火山(唯一一座喷发出碳酸盐岩的火山),对于确认碳酸盐岩是真正的岩浆岩异常重要。对添加了挥发性成分(H2O、F)和碱元素(Na、K)的各种碳酸盐系统进行的实验研究证实并显示了碳酸盐熔体存在的可能性。Oldoinyo Lengai 绿泥石-聂拉体碳酸盐岩在矿物学和成分上与世界上所有已知的碳酸盐岩都不同,对这些碳酸盐岩的研究引发了关于碳酸盐岩起源的长期讨论。讨论内容包括原生/母体碳酸盐熔体的成分、碳酸盐岩通过液态不溶性或点状结晶衍生、碳酸盐岩的演化,尤其是富碱碳酸盐岩和贫碱碳酸盐岩之间可能存在的遗传关系。有人提出,Oldoinyo Lengai 碳酸盐岩的快速蚀变及其向方解石碳酸盐岩类岩石的转变,是过去地质中不存在富碱碳酸盐岩的原因。详细的矿物学研究表明,尼雷石的出现并不局限于奥尔多尼约伦盖,目前已知这种矿物还出现在其他碳酸盐岩(如古利、科夫多、奥卡、克里马西)、碱性岩和金伯利岩中(甚至出现在金刚石中)。这表明地幔产生的熔体成分不同,富含碱元素。此外,碳酸盐岩凝灰岩在保存东非一些重要的古生物学和人类学地点方面发挥了重要作用。尽管有这些重要发现,但与碳酸盐岩成岩有关的几个问题仍未解决。今后需要开展工作,非洲境内的碳酸盐岩及其主要地点可能有助于解决这些问题。
{"title":"Carbonatite research: The African Legacy","authors":"","doi":"10.1016/j.jafrearsci.2024.105316","DOIUrl":"10.1016/j.jafrearsci.2024.105316","url":null,"abstract":"<div><p>Almost all igneous rocks are composed of silicate minerals; carbonatites are the main exception to this rule. They form only a minor proportion of the continental crust but are of fundamental scientific and economic importance. These rocks, originally described as a limestone (Kaiserstuhl, Germany) or magmatic limestone (Alnö, Sweden), were recognized in 1921 by W. C. Brøgger as a distinct magmatic rock type under the name “Karbonatite” in the Fen complex (Norway). Extensive field mapping in Africa, and particularly studies within the Chilwa Alkaline Province (Malawi), have led to the discovery of diverse intrusive and extrusive carbonatites. The latter, including the Fort Portal volcanic field in Uganda, Rufunsa Province in Zambia, and Oldoinyo Lengai volcano in Tanzania (the only volcano ever to have been seen to erupt carbonatites), have been exceptionally important in the recognition of carbonatites as truly magmatic rocks. The possibility of the existence of carbonate melts has been confirmed and shown by experimental studies of diverse carbonate systems with added volatile components (H<sub>2</sub>O, F) and alkali elements (Na, K). The study of the Oldoinyo Lengai gregoryite-nyerereite carbonatites, which are mineralogically and compositionally different from all known carbonatites worldwide, has led to long-lasting discussions about the origin of carbonatites. This includes composition of primary/parental carbonate melt, derivation of carbonatites by either liquid immiscibility or fractional crystallization, carbonatite evolution, and especially, the possible genetic relationships between alkali-rich and alkali-poor carbonatites. The rapid alteration of Oldoinyo Lengai carbonatites and their transformation to calcite carbonatite-like rocks has been proposed as the explanation for the absence of alkali-rich carbonatites in the geological past. Detailed mineralogical studies have shown that the occurrence of nyerereite is not restricted to Oldoinyo Lengai and that this mineral is now known to occur in other carbonatites (e.g., Guly, Kovdor, Oka, Kerimasi), alkaline rocks, and kimberlites (and even in diamond). This would suggest compositionally different mantle-derived melts enriched in alkali elements. In addition, carbonatite tephra has an important role in the preservation of some key paleontologic and anthropologic localities in East Africa. Despite these important discoveries, several problems related to carbonatite petrogenesis are not yet resolved. Future work is required, and carbonatites within Africa, with its key localities, may help to solve these problems.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141409803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-08DOI: 10.1016/j.jafrearsci.2024.105315
Yvan Demonstel Ntomb , Louise Marie Ngo Bidjeck Bondje , Eugène Pascal Binam Mandeng , Jacques Wassouo Wadjou , François Ndong Bidzang , Simon Ngos III
The present work deals with the behaviour of major, trace and rare earth elements in three weathering profiles (P1, P2, P3) developed on syenites from Ina pluton in central Cameroon. The mineralogical composition of weathering materials was determined using X-ray diffraction analysis. Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) have been used to determine the geochemical composition of parent syenites and the overlying weathered materials. The parent rocks of the studied profiles are quartz alkali syenites and alkali syenite. They have metaluminous character, granular porphyroid texture and were emplaced in a subduction context. Macroscopically, the weathering profiles mainly show from bottom to top: (i) coarse saprolite; (ii) fine saprolite; (iii) nodular horizon and (iv) superficial loose clay horizon. The upslope profiles (P1, P2) are less developed than the slope profile (P3). The alteration (CIA, MIA and PIA) and lateritisation (IOL) indices values show that upslope weathering profiles are characterised by moderate weathering and weak lateritization while, slope profile is intensely weathered and weak to moderate lateritization. Kaolinite, quartz, gibbsite and alkali feldspars are the common minerals to all 3 profiles. Illite, ilmenite, hematite and magnetite are specific to profiles P1 and P2, while halloysite and goethite are only present in P3 weathering profile. Geochemical data and mass balances show that SiO2, K2O, Na2O, CaO, MgO, P2O5, some LILE (Ba, Sr, Rb) and Zn are leached with varying intensities in the studied profiles. Inversely, Al2O3, Fe2O3, TiO2, Cs, Pb, HFSE and some transition elements (Ni, Co, Cr, V, Cu) are enriched overall. REE contents increase in the weathering products of P1 and P2 profiles mainly in deep horizons while they decrease in those of P3 profile. The highest Y contents are recorded in the lower horizons of all the weathering profiles. The HFSE, REE and certain transition elements (Ni, Co, Cr, V and Cu) distribution are controlled by clays (kaolinite, halloysite, illite), iron and aluminium sesquioxides (hematite, magnetite, goethite and gibbsite), secondary phosphate minerals such as florencite and residual accessory minerals such as apatite. The negative anomalies observed in most weathering materials are related to the reducing conditions of the environment reflected by very low Eh (-32- 87.7 mv) and moderate pH (4.7–6.9) values. The positive anomalies registered at the top horizons of studied profiles are due to the fixation of Ce3+ cations by adsorption on the surface of iron and aluminium hydroxides or by the presence of Ce4+ in the residual accessory minerals such as zircon. It could also be explained by external influences such as solutions and/or solids that may have affected their
{"title":"Major and trace elements behaviour in three weathering profiles developed on syenitic rocks in Ina pluton (syenitic set of Linté, Central Cameroon)","authors":"Yvan Demonstel Ntomb , Louise Marie Ngo Bidjeck Bondje , Eugène Pascal Binam Mandeng , Jacques Wassouo Wadjou , François Ndong Bidzang , Simon Ngos III","doi":"10.1016/j.jafrearsci.2024.105315","DOIUrl":"https://doi.org/10.1016/j.jafrearsci.2024.105315","url":null,"abstract":"<div><p>The present work deals with the behaviour of major, trace and rare earth elements in three weathering profiles (P1, P2, P3) developed on syenites from Ina pluton in central Cameroon. The mineralogical composition of weathering materials was determined using X-ray diffraction analysis. Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) have been used to determine the geochemical composition of parent syenites and the overlying weathered materials. The parent rocks of the studied profiles are quartz alkali syenites and alkali syenite. They have metaluminous character, granular porphyroid texture and were emplaced in a subduction context. Macroscopically, the weathering profiles mainly show from bottom to top: (i) coarse saprolite; (ii) fine saprolite; (iii) nodular horizon and (iv) superficial loose clay horizon. The upslope profiles (P1, P2) are less developed than the slope profile (P3). The alteration (CIA, MIA and PIA) and lateritisation (IOL) indices values show that upslope weathering profiles are characterised by moderate weathering and weak lateritization while, slope profile is intensely weathered and weak to moderate lateritization. Kaolinite, quartz, gibbsite and alkali feldspars are the common minerals to all 3 profiles. Illite, ilmenite, hematite and magnetite are specific to profiles P1 and P2, while halloysite and goethite are only present in P3 weathering profile. Geochemical data and mass balances show that SiO<sub>2</sub>, K<sub>2</sub>O, Na<sub>2</sub>O, CaO, MgO, P<sub>2</sub>O<sub>5</sub>, some LILE (Ba, Sr, Rb) and Zn are leached with varying intensities in the studied profiles. Inversely, Al<sub>2</sub>O<sub>3</sub>, Fe<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, Cs, Pb, HFSE and some transition elements (Ni, Co, Cr, V, Cu) are enriched overall. REE contents increase in the weathering products of P1 and P2 profiles mainly in deep horizons while they decrease in those of P3 profile. The highest Y contents are recorded in the lower horizons of all the weathering profiles. The HFSE, REE and certain transition elements (Ni, Co, Cr, V and Cu) distribution are controlled by clays (kaolinite, halloysite, illite), iron and aluminium sesquioxides (hematite, magnetite, goethite and gibbsite), secondary phosphate minerals such as florencite and residual accessory minerals such as apatite. The negative anomalies observed in most weathering materials are related to the reducing conditions of the environment reflected by very low Eh (-32- 87.7 mv) and moderate pH (4.7–6.9) values. The positive anomalies registered at the top horizons of studied profiles are due to the fixation of Ce<sup>3+</sup> cations by adsorption on the surface of iron and aluminium hydroxides or by the presence of Ce<sup>4+</sup> in the residual accessory minerals such as zircon. It could also be explained by external influences such as solutions and/or solids that may have affected their ","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141303298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-08DOI: 10.1016/j.jafrearsci.2024.105313
Reda A. El-Arafy, Hussein F. Abd El Salam, Mohammed A. Shaheen, Ahmed E. Abdel Gawad
The study aims to assess the effectiveness of using ASTER, Landsat 9, and airborne geophysical data to generate maps depicting hydrothermally altered regions and their correlation with radioactive-mineralized zones in Egypt's Um Had area. Various image processing methods were applied, including color composite images, band ratios, selective principal component analyses, and lineament extraction with enhancement procedures. The ASTER ratios identified the three types of hydrothermal alterations; phyllic, argillic, and propylitic, with other significant alteration zones related to mineralization. Airborne gamma-ray spectrometry contour maps displayed marked varied levels of total count (T.C), eU, eTh, and K, ranging from 1.2 to 21.2 Ur, 0.5 to 12.34 ppm, 1.45 to 28 ppm, and 0.13 to 3.65 %, respectively. The highest anomalies of these radioelements concentration have coincided with the alkali feldspar granite and along their intrusive contact zone with the Hammamat Group sedimentary rocks. Higher anomalies are well recorded in the center and eastern regions of Um Had's, according to the radioelements composite image. The lowest concentrations of these radioelements are associated with gneiss, ophiolitic mélange, metavolcanic, Hammamat Group sedimentary rocks, Taref Formation, and Wadi sediments. To mitigate local magnetic effects, the total aeromagnetic data was reduced to the north magnetic pole (RTP). Power spectrum analysis of the RTP data identified distinct magnetic wavelengths for regional-residual components. In order to identify near-surface magnetic lineaments, such as contacts, shear zones, faults, and dykes, advanced algorithms were applied to the RTP data data. The lineaments derived from ASTER and airborne magnetic data revealed dominant fault systems characterized by E–W, NE, NNW, NW and N–S trends, governing the structural framework of the study area. Depth levels of geological contacts and faults that represented pathways for altered and mineralized zones reached more than 1200 m (Euler deconvolution). These findings highlight the consistent results obtained when combining ASTER data with airborne survey data, allowing for the identification of hydrothermally altered zones and primary conductive zones.
{"title":"Integrative mapping of radioactive and alteration zones in Um Had plutons, Egypt: Using Landsat 9, ASTER imagery, and airborne geophysical data","authors":"Reda A. El-Arafy, Hussein F. Abd El Salam, Mohammed A. Shaheen, Ahmed E. Abdel Gawad","doi":"10.1016/j.jafrearsci.2024.105313","DOIUrl":"https://doi.org/10.1016/j.jafrearsci.2024.105313","url":null,"abstract":"<div><p>The study aims to assess the effectiveness of using ASTER, Landsat 9, and airborne geophysical data to generate maps depicting hydrothermally altered regions and their correlation with radioactive-mineralized zones in Egypt's Um Had area. Various image processing methods were applied, including color composite images, band ratios, selective principal component analyses, and lineament extraction with enhancement procedures. The ASTER ratios identified the three types of hydrothermal alterations; phyllic, argillic, and propylitic, with other significant alteration zones related to mineralization. Airborne gamma-ray spectrometry contour maps displayed marked varied levels of total count (T.C), eU, eTh, and K, ranging from 1.2 to 21.2 Ur, 0.5 to 12.34 ppm, 1.45 to 28 ppm, and 0.13 to 3.65 %, respectively. The highest anomalies of these radioelements concentration have coincided with the alkali feldspar granite and along their intrusive contact zone with the Hammamat Group sedimentary rocks. Higher anomalies are well recorded in the center and eastern regions of Um Had's, according to the radioelements composite image. The lowest concentrations of these radioelements are associated with gneiss, ophiolitic mélange, metavolcanic, Hammamat Group sedimentary rocks, Taref Formation, and Wadi sediments. To mitigate local magnetic effects, the total aeromagnetic data was reduced to the north magnetic pole (RTP). Power spectrum analysis of the RTP data identified distinct magnetic wavelengths for regional-residual components. In order to identify near-surface magnetic lineaments, such as contacts, shear zones, faults, and dykes, advanced algorithms were applied to the RTP data data. The lineaments derived from ASTER and airborne magnetic data revealed dominant fault systems characterized by E–W, NE, NNW, NW and N–S trends, governing the structural framework of the study area. Depth levels of geological contacts and faults that represented pathways for altered and mineralized zones reached more than 1200 m (Euler deconvolution). These findings highlight the consistent results obtained when combining ASTER data with airborne survey data, allowing for the identification of hydrothermally altered zones and primary conductive zones.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141303413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-08DOI: 10.1016/j.jafrearsci.2024.105311
Temitayo D. Johnson , Oladotun A. Oluwajana , Erepamo J. Omietimi , Abiodun E. Ayo-Bali , Oyinebielador D. Odondiri , Chinedu O. Igili , Nils Lenhardt
The Dahomey Basin, located in southwestern Nigeria, is an energy-rich frontier basin with sedimentary successions consisting of both (onshore) terrestrial and (offshore) marine deposits. Since the discovery of several bitumen seeps, tar sands, and oil and gas shows offshore the basin and the successful production of the Aje Field, the basin has gained immense interest from academia and industry. Nevertheless, surface and subsurface research focusing on paleoclimatic conditions, primary productivity, anoxic conditions, paleowater depth, and hydrodynamic influence in the Dahomey Basin is less documented. To reconstruct paleoenvironmental conditions, subsurface data from the Araromi-Obu (A1) and Idiobiolayo (A15) cores were used. The average chemical index of alteration (CIA) values ranging from 63.01 to 94.88 reflect varying degrees of weathering intensity in the sediment source area of the Cretaceous Araromi Formation. These values show a transition from relatively low to considerably high degrees of weathering in the source region of the Araromi Formation. The analysis of CIA values and Ga/Rb, Sr/Cu, Sr/Ba, Ca/Al, and 100*Mg/Al ratios suggests that the Araromi Formation was deposited in a brackish to marine environment.
Furthermore, chemical alteration-sensitive geochemical indicators revealed prevailing warm, humid tropical climates during the late Cretaceous period, with likely minor arid intervals. In addition, the geochemical markers used (Ba/Al, U/Th, Ni/Co, authigenic uranium (Uau), P/Ti, and [(Fe2O3 + CaO + MgO)/(SiO2 + Al2O3)] indicate poor paleoproductivity for the Araromi Formation deposited in an oxygen-rich marginal to shallow marine environment. The upper Cretaceous period was characterised by fluctuating hydrodynamic circulation, with a weak hydrodynamic regime in core A1 and transitioning to strong hydrodynamic conditions in core A15. The inferred paleowater depth corresponds to the salinity measurements, with the A1 core displaying elevated salinity, indicating a greater depth compared to the A15 core, which was deposited in a shallower environment and displays lower salinity.
{"title":"Elemental geochemistry of Cretaceous deposits in the Dahomey Basin (Nigeria): Implications for paleoclimatic and paleoenvironmental reconstructions","authors":"Temitayo D. Johnson , Oladotun A. Oluwajana , Erepamo J. Omietimi , Abiodun E. Ayo-Bali , Oyinebielador D. Odondiri , Chinedu O. Igili , Nils Lenhardt","doi":"10.1016/j.jafrearsci.2024.105311","DOIUrl":"10.1016/j.jafrearsci.2024.105311","url":null,"abstract":"<div><p>The Dahomey Basin, located in southwestern Nigeria, is an energy-rich frontier basin with sedimentary successions consisting of both (onshore) terrestrial and (offshore) marine deposits. Since the discovery of several bitumen seeps, tar sands, and oil and gas shows offshore the basin and the successful production of the Aje Field, the basin has gained immense interest from academia and industry. Nevertheless, surface and subsurface research focusing on paleoclimatic conditions, primary productivity, anoxic conditions, paleowater depth, and hydrodynamic influence in the Dahomey Basin is less documented. To reconstruct paleoenvironmental conditions, subsurface data from the Araromi-Obu (A1) and Idiobiolayo (A15) cores were used. The average chemical index of alteration (CIA) values ranging from 63.01 to 94.88 reflect varying degrees of weathering intensity in the sediment source area of the Cretaceous Araromi Formation. These values show a transition from relatively low to considerably high degrees of weathering in the source region of the Araromi Formation. The analysis of CIA values and Ga/Rb, Sr/Cu, Sr/Ba, Ca/Al, and 100*Mg/Al ratios suggests that the Araromi Formation was deposited in a brackish to marine environment.</p><p>Furthermore, chemical alteration-sensitive geochemical indicators revealed prevailing warm, humid tropical climates during the late Cretaceous period, with likely minor arid intervals. In addition, the geochemical markers used (Ba/Al, U/Th, Ni/Co, authigenic uranium (Uau), P/Ti, and [(Fe<sub>2</sub>O<sub>3</sub> + CaO + MgO)/(SiO<sub>2</sub> + Al<sub>2</sub>O<sub>3</sub>)] indicate poor paleoproductivity for the Araromi Formation deposited in an oxygen-rich marginal to shallow marine environment. The upper Cretaceous period was characterised by fluctuating hydrodynamic circulation, with a weak hydrodynamic regime in core A1 and transitioning to strong hydrodynamic conditions in core A15. The inferred paleowater depth corresponds to the salinity measurements, with the A1 core displaying elevated salinity, indicating a greater depth compared to the A15 core, which was deposited in a shallower environment and displays lower salinity.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141397039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-08DOI: 10.1016/j.jafrearsci.2024.105314
Faris A. Abanumay , Mohamed G. Abdelsalam , Andrew B. Katumwehe
This study uses Landsat Thematic Mapper (TM), Shuttle Radar Topography Mission (SRTM) Digital Elevation Model (DEM), and aeromagnetic data to examine possible reactivation of the Ediacaran, NE-trending Ad Damm Fault Zone (AFZ) and the Fatima Fault Zone (FFZ) in the western Arabian Shield. Reactivation is by latest Paleogene to Neogene and Quaternary structures of the Red Sea. The AFZ is the tectonic boundary between the Tonian Jeddah terrane in the northwest and the Asir terrane to the southeast of the Arabian Shield. The AFZ and FFZ coincide with possible onshore continuation of a transform fault that separates the sea floor spreading segment of the Red Sea in the south from its transitional segment to the north. It has been suggested that the AFZ is a candidate for the formation of a future onshore transform fault that would result in an eastward jump of the Red Sea sea floor spreading center onto the Arabian Shield. The future spreading center will follow the latest Neogene to Quaternary volcanic rocks (Harrat) that are exposed on the eastern side of the Red Sea. The Landsat TM image and the SRTM DEM show that the AFZ dissects the Red Sea topographic escarpment, and both the AFZ and FFZ control paleo-drainage system (wadis). The aeromagnetic data show that there is a ∼100 km wide zone between the AFZ and FFZ dominated by NE-trending short wavelength magnetic anomalies, possibly related to regional tectonic fabric. Additionally, the aeromagnetic data show that both fault zones dissect NW-trending short wavelength magnetic anomalies, interpreted as latest Paleogene to earliest Neogene dike swarms associated with the opening of the Red Sea. This dissection also includes possible Red Sea related narrow marginal grabens and horsts that were formed onshore and offshore parallel to the Red Sea shoreline. Red Sea-related structure might have reactivated the AFZ and FFZ.
{"title":"On-land manifestation of along-strike transitioning of the Red Sea from continental rifting to sea floor spreading","authors":"Faris A. Abanumay , Mohamed G. Abdelsalam , Andrew B. Katumwehe","doi":"10.1016/j.jafrearsci.2024.105314","DOIUrl":"10.1016/j.jafrearsci.2024.105314","url":null,"abstract":"<div><p>This study uses Landsat Thematic Mapper (TM), Shuttle Radar Topography Mission (SRTM) Digital Elevation Model (DEM), and aeromagnetic data to examine possible reactivation of the Ediacaran, NE-trending Ad Damm Fault Zone (AFZ) and the Fatima Fault Zone (FFZ) in the western Arabian Shield. Reactivation is by latest Paleogene to Neogene and Quaternary structures of the Red Sea. The AFZ is the tectonic boundary between the Tonian Jeddah terrane in the northwest and the Asir terrane to the southeast of the Arabian Shield. The AFZ and FFZ coincide with possible onshore continuation of a transform fault that separates the sea floor spreading segment of the Red Sea in the south from its transitional segment to the north. It has been suggested that the AFZ is a candidate for the formation of a future onshore transform fault that would result in an eastward jump of the Red Sea sea floor spreading center onto the Arabian Shield. The future spreading center will follow the latest Neogene to Quaternary volcanic rocks (Harrat) that are exposed on the eastern side of the Red Sea. The Landsat TM image and the SRTM DEM show that the AFZ dissects the Red Sea topographic escarpment, and both the AFZ and FFZ control paleo-drainage system (wadis). The aeromagnetic data show that there is a ∼100 km wide zone between the AFZ and FFZ dominated by NE-trending short wavelength magnetic anomalies, possibly related to regional tectonic fabric. Additionally, the aeromagnetic data show that both fault zones dissect NW-trending short wavelength magnetic anomalies, interpreted as latest Paleogene to earliest Neogene dike swarms associated with the opening of the Red Sea. This dissection also includes possible Red Sea related narrow marginal grabens and horsts that were formed onshore and offshore parallel to the Red Sea shoreline. Red Sea-related structure might have reactivated the AFZ and FFZ.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141411757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-07DOI: 10.1016/j.jafrearsci.2024.105303
E. Ould Mohamed Navee , D. Baratoux , H. Chennaoui Aoudjehane , H. Si Mhamdi , M. Raji
Mauritania, with its ancient (Archean to Paleoproterozoic) and desertic terrains and gentle relief, has been under-explored in terms of impact structures. To date, two confirmed impact craters, namely Tenoumer and Aouelloul, and four circular structures for which an impact origin has been suggested, are known in Mauritania. This work aims at a systematic exploration of circular structures in Mauritania and provide a comprehensive database to support their exploration and elucidate their origin. This approach includes multi-scale search on Google Earth images, and a preliminary assessment of their origin using available geological, geophysical, and geochemical data as well as Digital Elevation Models. A total of 50 new circular structures were detected during our survey, adding to four candidates previously identified. They are distributed throughout the territory with an important fraction of them being located in the Taoudeni basin. The diameters of these structures vary from 60 m to 7.5 km with a right-skewed distribution. A preliminary assessment of the possible origins of these circular structures is proposed and the most promising candidates for potential meteoritic impact sites are listed for future investigations.
{"title":"Systematic search of circular structures using satellite imagery to identify potential new impact structures in Mauritania","authors":"E. Ould Mohamed Navee , D. Baratoux , H. Chennaoui Aoudjehane , H. Si Mhamdi , M. Raji","doi":"10.1016/j.jafrearsci.2024.105303","DOIUrl":"10.1016/j.jafrearsci.2024.105303","url":null,"abstract":"<div><p>Mauritania, with its ancient (Archean to Paleoproterozoic) and desertic terrains and gentle relief, has been under-explored in terms of impact structures. To date, two confirmed impact craters, namely Tenoumer and Aouelloul, and four circular structures for which an impact origin has been suggested, are known in Mauritania. This work aims at a systematic exploration of circular structures in Mauritania and provide a comprehensive database to support their exploration and elucidate their origin. This approach includes multi-scale search on Google Earth images, and a preliminary assessment of their origin using available geological, geophysical, and geochemical data as well as Digital Elevation Models. A total of 50 new circular structures were detected during our survey, adding to four candidates previously identified. They are distributed throughout the territory with an important fraction of them being located in the Taoudeni basin. The diameters of these structures vary from 60 m to 7.5 km with a right-skewed distribution. A preliminary assessment of the possible origins of these circular structures is proposed and the most promising candidates for potential meteoritic impact sites are listed for future investigations.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1464343X24001365/pdfft?md5=9c303517089da32907485ec16a792da8&pid=1-s2.0-S1464343X24001365-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141393064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The South Rifian Ridges are located in northern Morocco, to the south of the Gibraltar Arc, and constitute a portion of the south Rifian corridor in the Rif belt front. These active fault-related folds, separated by the Volubilis piggy back basin, were structured since the Late Miocene due to the reactivation of Triassic graben fault systems in the context of the Eurasia-Africa convergence.
For the first time, a combination of morphotectonic and gravity analysis coupled with field Kinematic data have been used to characterize the main structures responsible for the Late Miocene to recent evolution of the area.
The morphotectonic analysis based on the dynamics of drainage network analysis allowed the isobase lineament mapping to depict a general view of the tectonic framework of the South Rifian Ridges. The interpretation of gravity data, including maps derived from the Bouguer and residual anomalies, allowed subsurface geometric features characterization and revealed buried salt diapirs to establish a new structural map. Evidenced structures confirm previously interpreted ones and support the presence of new masked faults, with the presence of compressional and extensive deformations. The main inferred structures are the NW-SE oriented buried Prerif Nappe fronts. Rooted faults related to the main ridges show reverse displacement and are expressed by high-angle reverse faults, while the NW oriented normal faults within Volubilis basin, in the field, are probably related to an active subsidence. This event is related to the current NW-SE continental collision, within a context of transition from thin to thick skinned tectonics. Our results shed light on the Miocene to Quaternary tectonics that have taken part in the closure of the South Rifain marine gateway.
{"title":"Role of preexisting faults in the structural configuration of the South Rifian Ridges, Northern Morocco: Contribution of isobase maps and gravity data","authors":"Afaf Amine , Hmidou El Ouardi , Mustapha Elabouyi , Salma Zerouali Masror , Mohamed Saadi , Mansour Al-Hashim , Morad Taher , Mohamed El Amrani , Ammar Oudy , Nabil Mdiker , Hicham Benbaqqal","doi":"10.1016/j.jafrearsci.2024.105309","DOIUrl":"https://doi.org/10.1016/j.jafrearsci.2024.105309","url":null,"abstract":"<div><p>The South Rifian Ridges are located in northern Morocco, to the south of the Gibraltar Arc, and constitute a portion of the south Rifian corridor in the Rif belt front. These active fault-related folds, separated by the Volubilis piggy back basin, were structured since the Late Miocene due to the reactivation of Triassic graben fault systems in the context of the Eurasia-Africa convergence.</p><p>For the first time, a combination of morphotectonic and gravity analysis coupled with field Kinematic data have been used to characterize the main structures responsible for the Late Miocene to recent evolution of the area.</p><p>The morphotectonic analysis based on the dynamics of drainage network analysis allowed the isobase lineament mapping to depict a general view of the tectonic framework of the South Rifian Ridges. The interpretation of gravity data, including maps derived from the Bouguer and residual anomalies, allowed subsurface geometric features characterization and revealed buried salt diapirs to establish a new structural map. Evidenced structures confirm previously interpreted ones and support the presence of new masked faults, with the presence of compressional and extensive deformations. The main inferred structures are the NW-SE oriented buried Prerif Nappe fronts. Rooted faults related to the main ridges show reverse displacement and are expressed by high-angle reverse faults, while the NW oriented normal faults within Volubilis basin, in the field, are probably related to an active subsidence. This event is related to the current NW-SE continental collision, within a context of transition from thin to thick skinned tectonics. Our results shed light on the Miocene to Quaternary tectonics that have taken part in the closure of the South Rifain marine gateway.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141314519","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-07DOI: 10.1016/j.jafrearsci.2024.105310
George Bennett , Alfred Said , Samwel Lupyana , Athanas Simon Macheyeki , Ceven Shemsanga
The Dodoma region located in Central Tanzania is a semi-arid area characterised by scarce surface water resources. Because of climate change and dependence on groundwater resources in the Dodoma urban area, there is currently an increased demand for water due to low groundwater recharge and high groundwater withdrawals due to the growing population. There is therefore a need to explore potential deep aquifer systems around the Dodoma urban area to meet the increasing water demand. This study uses lithological logs, pumping tests, and electromagnetic survey data to delineate the subsurface lithologies to locate potential deep aquifer system in the area. Results show that the shallow aquifer system is unconfined in some areas with resistivity values ranging from 11 to 28 Ωm and semi-confined in other areas with resistivity values ranging from 19 to 27 Ωm. The unconfined aquifer extends up to 60 m, while the semi-confined aquifer extends between 50–55 m and 65–120 m. The study found a potential deep aquifer system at a depth of between 200 and 290 m, with resistivity values ranging from 11 to 20 Ωm. Currently, this deep aquifer system has not been exploited as most boreholes in the area are only up to 150 m deep. The main lithology in the study area is weathered and fractured granite, with different degrees of weathering and fracturing, indicating a hard-rock aquifer system. This study adds valuable knowledge on the location of potential deep aquifer systems in the area for proper groundwater utilisation and management.
{"title":"Assessment to locate potential deep aquifer systems using lithological logs, pumping tests and electromagnetic surveys in hard rock terrain of Dodoma urban area, Tanzania","authors":"George Bennett , Alfred Said , Samwel Lupyana , Athanas Simon Macheyeki , Ceven Shemsanga","doi":"10.1016/j.jafrearsci.2024.105310","DOIUrl":"https://doi.org/10.1016/j.jafrearsci.2024.105310","url":null,"abstract":"<div><p>The Dodoma region located in Central Tanzania is a semi-arid area characterised by scarce surface water resources. Because of climate change and dependence on groundwater resources in the Dodoma urban area, there is currently an increased demand for water due to low groundwater recharge and high groundwater withdrawals due to the growing population. There is therefore a need to explore potential deep aquifer systems around the Dodoma urban area to meet the increasing water demand. This study uses lithological logs, pumping tests, and electromagnetic survey data to delineate the subsurface lithologies to locate potential deep aquifer system in the area. Results show that the shallow aquifer system is unconfined in some areas with resistivity values ranging from 11 to 28 Ωm and semi-confined in other areas with resistivity values ranging from 19 to 27 Ωm. The unconfined aquifer extends up to 60 m, while the semi-confined aquifer extends between 50–55 m and 65–120 m. The study found a potential deep aquifer system at a depth of between 200 and 290 m, with resistivity values ranging from 11 to 20 Ωm. Currently, this deep aquifer system has not been exploited as most boreholes in the area are only up to 150 m deep. The main lithology in the study area is weathered and fractured granite, with different degrees of weathering and fracturing, indicating a hard-rock aquifer system. This study adds valuable knowledge on the location of potential deep aquifer systems in the area for proper groundwater utilisation and management.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141308190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The Tadaout-Tizi n’Rsas (TTR) polymetallic (Pb, Cu, Zn) vein field, located at the southeastern of the Moroccan eastern Anti-Atlas, is hosted in sedimentary sandstone formations of the Ktaoua Group of the upper Ordovician. These deposits are reported to be late Variscan to Post-variscan in age, and are related to the emplacement of late Permian doleritic magma event outcropping in the Tafilalet region. Structural and paragenetic studies of the TTR mineralization deposit were conducted in order to establish a general model of the mineralization. A two-stage model of the formation of the mineralized veins of the TTR vein field is proposed herein. The first episode is attributed to the late Variscan phase. It is a trantensive regime characterized by the presence of lenticular structures related to the normal dextral movement of the major faults. This episode is coeval with the emplacement and brecciation of the polymetallic mineralization of the TTR vein field (galena, chalcopyrite, sphalerite, and pyrite). The second episode is associated with normal faults, during the extensional phase corresponding to the tectonic relaxation of shortening (Upper Permian) and more probably during the Atlantic rifting. It is characterized by the formation of a banded texture of mineralization.
{"title":"Mineralogical characterization and structural control of the Tadaout-Tizi n’Rsas vein field (eastern Anti-Atlas Morocco)","authors":"Mustapha Ait Daoud , Omar Saidi , Brahim Es-Sabbar , Abdelhafid Essalhi , Brahim Karaoui , Mourad Essalhi , Abdeslam Toummite","doi":"10.1016/j.jafrearsci.2024.105298","DOIUrl":"https://doi.org/10.1016/j.jafrearsci.2024.105298","url":null,"abstract":"<div><p>The Tadaout-Tizi n’Rsas (TTR) polymetallic (Pb, Cu, Zn) vein field, located at the southeastern of the Moroccan eastern Anti-Atlas, is hosted in sedimentary sandstone formations of the Ktaoua Group of the upper Ordovician. These deposits are reported to be late Variscan to Post-variscan in age, and are related to the emplacement of late Permian doleritic magma event outcropping in the Tafilalet region. Structural and paragenetic studies of the TTR mineralization deposit were conducted in order to establish a general model of the mineralization. A two-stage model of the formation of the mineralized veins of the TTR vein field is proposed herein. The first episode is attributed to the late Variscan phase. It is a trantensive regime characterized by the presence of lenticular structures related to the normal dextral movement of the major faults. This episode is coeval with the emplacement and brecciation of the polymetallic mineralization of the TTR vein field (galena, chalcopyrite, sphalerite, and pyrite). The second episode is associated with normal faults, during the extensional phase corresponding to the tectonic relaxation of shortening (Upper Permian) and more probably during the Atlantic rifting. It is characterized by the formation of a banded texture of mineralization.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141303299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-07DOI: 10.1016/j.jafrearsci.2024.105307
Khaled Albriki , Wei Guoqi , Feiyu Wang , Rajab El Zaroug , Abdulati Abdullah
In this study, we investigated the nature and characteristics of petroleum fluids in a super-global basin situated in the central north of Libya. With over 100 discovered fields (comprising oil and gas), this study aimed to understand the basin's petroleum accumulation mechanism (PAM), thereby shedding light on the factors contributing to significant petroleum discoveries in North Africa (Libya). The primary objective of this study was to provide a detailed regional refined oil family distribution and new insights into the total petroleum system (TPS) of the basin. This analysis was based on the integration of regional geology and organic geochemistry. Additionally, we utilized the physical properties of petroleum, such as API and sulphur content (%S), to obtain a better understanding of the regional physical nature of petroleum types and properties. Organic geochemical data for the basin fields were compiled, focusing on key biological marker and carbon isotope (‰ δ13C) data for saturated and aromatic compounds. These data were used to understand the origin, depositional source, and thermal maturity of the generated, migrated, and accumulated petroleum fluids. The study established specific types of organofacies and their relationships with petroleum phase characteristics, including type and quality, categorized into known groups (e.g., B, C, and D/E). Hierarchical cluster analysis (HCA) and map-based presentation approaches were used to determine the spatial types and distributions of oil and gas families in the basin. This was achieved by selecting the input parameters from various datasets and defining the significant parameters to characterize the distribution patterns. The findings indicate that the bulk fluid of the Sirt Basin primarily resembled Brent oil, which was characterized by a very low sulphur content (less than 1.4%). The API gravity ranged from 30 to 65, reflecting a diverse range of oil types within the basin. The crude oils in the basin were primarily derived from marine organofacies, predominantly from type B. This inference is supported by related biomarkers such as regular steranes and isoprenoids. Furthermore, the analysis of carbon isotopes provided a similar indication, with values ranging from −32 to −27 for ‰ δ13C for saturates and −31.2 to −25.4 ‰ δ13C for aromatic compounds. The thermal maturity biomarker ratio (Ts/Ts + Tm) of the Sirt Basin crude oils varied from 0.35 to 0.92, suggesting different levels of thermal maturity, typically ranging from the mid to late mature stages. This observation is consistent with the indication based on the 22S/22S + 22R ratio. The basin exhibited four dominant oil families and eight subfamilies with the same geochemical characteristics (HCA-based analysis), including early and later generations, relatively sulphurized oils, and condensate families.
{"title":"Nature and occurrence, geochemical characteristics, and families of the crude oils in Sirt Basin, Libya: Implication for super rift basin petroleum system","authors":"Khaled Albriki , Wei Guoqi , Feiyu Wang , Rajab El Zaroug , Abdulati Abdullah","doi":"10.1016/j.jafrearsci.2024.105307","DOIUrl":"10.1016/j.jafrearsci.2024.105307","url":null,"abstract":"<div><p>In this study, we investigated the nature and characteristics of petroleum fluids in a super-global basin situated in the central north of Libya. With over 100 discovered fields (comprising oil and gas), this study aimed to understand the basin's petroleum accumulation mechanism (PAM), thereby shedding light on the factors contributing to significant petroleum discoveries in North Africa (Libya). The primary objective of this study was to provide a detailed regional refined oil family distribution and new insights into the total petroleum system (TPS) of the basin. This analysis was based on the integration of regional geology and organic geochemistry. Additionally, we utilized the physical properties of petroleum, such as API and sulphur content (%S), to obtain a better understanding of the regional physical nature of petroleum types and properties. Organic geochemical data for the basin fields were compiled, focusing on key biological marker and carbon isotope (‰ δ<sup>13</sup>C) data for saturated and aromatic compounds. These data were used to understand the origin, depositional source, and thermal maturity of the generated, migrated, and accumulated petroleum fluids. The study established specific types of organofacies and their relationships with petroleum phase characteristics, including type and quality, categorized into known groups (e.g., B, C, and D/E). Hierarchical cluster analysis (HCA) and map-based presentation approaches were used to determine the spatial types and distributions of oil and gas families in the basin. This was achieved by selecting the input parameters from various datasets and defining the significant parameters to characterize the distribution patterns. The findings indicate that the bulk fluid of the Sirt Basin primarily resembled Brent oil, which was characterized by a very low sulphur content (less than 1.4%). The API gravity ranged from 30 to 65, reflecting a diverse range of oil types within the basin. The crude oils in the basin were primarily derived from marine organofacies, predominantly from type B. This inference is supported by related biomarkers such as regular steranes and isoprenoids. Furthermore, the analysis of carbon isotopes provided a similar indication, with values ranging from −32 to −27 for ‰ δ<sup>13</sup>C for saturates and −31.2 to −25.4 ‰ δ<sup>13</sup>C for aromatic compounds. The thermal maturity biomarker ratio (Ts/Ts + Tm) of the Sirt Basin crude oils varied from 0.35 to 0.92, suggesting different levels of thermal maturity, typically ranging from the mid to late mature stages. This observation is consistent with the indication based on the 22S/22S + 22R ratio. The basin exhibited four dominant oil families and eight subfamilies with the same geochemical characteristics (HCA-based analysis), including early and later generations, relatively sulphurized oils, and condensate families.</p></div>","PeriodicalId":14874,"journal":{"name":"Journal of African Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141397541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}