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2014 North African Workshop on Dielectic Materials for Photovoltaic Systems (NAWDMPV)最新文献

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SIMS and auger investigation of thin a-SiC and a-SiC:H films by Up-Down sputtering DC magnetron, impact on optical properties 采用上下溅射直流磁控管对a-SiC和a-SiC:H薄膜进行了SIMS和螺旋钻的研究,对其光学性能的影响
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997619
M. Ouadfel, A. Keffous, A. Cheriet, C. Yaddaden, N. Gabouze, Y. Belkacem, A. Khelloufi, H. Menari, M. Siad
This article deals with an early growth study of hydrogenated and non-hydrogenated amorphous silicon carbide thin films (a-SiC:H, a-SiC). Sample have been elaborated at room temperature by a new configuration (Up-down) sputtering d.c. magnetron technique, using a 6H-SiC polycrystalline target onto p-Si(100) and glass substrates. The infrared spectra reveal the existence of a band located at 740 cm-1, which corresponds to Si-C stretching mode of amorphous silicon carbide. The SIMS and AES profiles show a c-face for both a-SiC:H and a-SiC. Films elaborated with this configuration (Up-down) are stoichiometric, with a ratio 28Si/12C = 0.95, compared to the one elaborated with conventional configuration (Down-up), which is 1.75. The optical gap is 1.84 eV and 1.48 eV for a-SiC: H and a-SiC respectively. This behavior of optical gap may be related to the hydrogen concentration present in the films or other impurities inducing such a decrease in optical gap.
本文讨论了氢化和非氢化非晶碳化硅薄膜(a-SiC:H, a-SiC)的早期生长研究。利用6H-SiC多晶靶在p-Si(100)和玻璃衬底上,采用一种新的结构(上下)溅射直流磁控技术,在室温下制备了样品。红外光谱显示在740 cm-1处存在一个条带,对应于非晶碳化硅的Si-C拉伸模式。a- sic:H和a- sic的SIMS和AES谱均呈c型。与传统结构(Down-up)制备的薄膜相比,这种结构(Up-down)制备的薄膜具有化学计量性,其比值为28Si/12C = 0.95。a-SiC: H和a-SiC的光隙分别为1.84 eV和1.48 eV。这种光学间隙的行为可能与薄膜中存在的氢浓度或其他杂质导致光学间隙减小有关。
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引用次数: 3
Preparation and intercalation reactions of nano-structural materials, Mn-Al LDH 纳米结构材料Mn-Al LDH的制备及其插层反应
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997598
S. Hamouda, Salima Bouteraa, M. Sellami, N. Bettahar
Hydrotalcite (HT) or hydrotalcite-like compounds (HTlc) are layered double hydroxides belonging to the class of anionic clays. The structure of these compounds are very similar to that of brucite, Mg(OH)2, where some of Mg2+ represented as [M(II)] are isomorphously replaced by Al3+ represented as [M(III)] and the net positive charge is compensated by the inter-layered exchangeable anion (An-). LDH has been receiving increasing attention in recent years, owing to its potential technological applications such as catalysis, electrode, optical memory, separator, adsorbent, precursor for composite materials, and ion exchange. The general formula of these compounds can be represented as: [M(II)1-xM(III)x(OH)2]·Anx/n·mH2O with M(II) and M(III) as metal cations and An- as exchangeable anion. LDHs also possess relatively large surface areas and high anion-exchange capacities. Because of these properties, LDHs have been studied for removing toxic anionic species from aqueous systems. Thermal decomposition of these materials by calcination above 420°C results in the formation of high surface area basic mixed oxides which are reported to be potential candidates in catalyzing various reactions involved in the synthesis of a variety of fine chemicals. Indeed at this temperature, the as formed mixed oxides solid solution can regenerate upon rehydratation the HT structure with the suitable anions present in solution. Therefore, this so-called reconstruction process may be used to improve the sorption of anionic species. The LDH has been synthesized by the coprecipitation method at pH constant. The material has been obtained with [Mn/Al] molar ratio of 2.0. The product is characterized by X-ray diffraction (XRD), spectroscopy infra red (FTIR), and differential thermal analysis / thermo gravimetric analysis (DTA/TG). Dosages of polluted solutions have been realized by spectrometry UV visible.
水滑石(HT)或类水滑石化合物(HTlc)是属于阴离子粘土类的层状双氢氧化物。这些化合物的结构与水镁石Mg(OH)2非常相似,其中一些Mg2+(表示为[M(II)])被Al3+(表示为[M(III)])同构取代,净正电荷被层间可交换阴离子(An-)补偿。LDH由于其在催化、电极、光存储、分离器、吸附剂、复合材料前驱体、离子交换等方面的潜在技术应用,近年来受到越来越多的关注。这些化合物的通式可表示为:[M(II)1-xM(III)x(OH)2]·Anx/n·mH2O,其中M(II)和M(III)为金属阳离子,An-为可交换阴离子。LDHs还具有相对较大的表面积和较高的阴离子交换能力。由于这些性质,LDHs已被研究用于从水系统中去除有毒阴离子。这些材料在420°C以上煅烧的热分解会形成高表面积的碱性混合氧化物,据报道,这些氧化物是催化各种精细化学品合成中涉及的各种反应的潜在候选者。事实上,在这个温度下,当溶液中存在合适的阴离子时,形成的混合氧化物固溶体可以在再水合后再生HT结构。因此,这种所谓的重建过程可用于改善阴离子的吸附。在pH恒定条件下,采用共沉淀法合成了LDH。得到了[Mn/Al]摩尔比为2.0的材料。通过x射线衍射(XRD)、红外光谱(FTIR)和差热分析/热重分析(DTA/TG)对产物进行了表征。用紫外可见光谱法测定了污染溶液的剂量。
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引用次数: 4
Effect of molecular weight of monomer on the processes of phase separation during the elaboration of composite materials type PDLC 复合材料型PDLC制备过程中单体分子量对相分离过程的影响
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997613
Z. H. Belaid, A. Berrayah, F. Abdoune, L. Méchernène, L. Zair, Ulrich Maschke
Polymer Dispersed Liquid Crystals (PDLC) were elaborated by polymerization induced phase separation under ultraviolet (UV). A binary systems use in this study is composed of monomer of different molecular weights (TPGDA, PPGDA540 and PPGDA900), and 70 Wt.% of liquid crystal 5CB. The results showed a rapid decrease of the transmission of the LC droplet formation, followed by an enhancement of the transmission due to a thermal effect generated by exothermic curing, thermal diffusivity between components of the mixture monomers / LC, IR spectrum and high intensity of UV radiation emitted by LC3 lamp. PDLC films prepared exhibit different morphologies depending on the composition of the initial mixture, the UV dose, the molecular weight of the monomer and the nature of a LC. To quantify the effect of the molecular weight of the monomer on the kinetics of phase separation of the reactive mixtures, we realized a theoretical study that has given us a good accord with experiment.
采用紫外光聚合相分离法制备了聚合物分散液晶(PDLC)。本研究中使用的二元体系由不同分子量的单体(TPGDA、PPGDA540和PPGDA900)和70 Wt.%的液晶5CB组成。结果表明,LC液滴形成后透射率迅速下降,随后由于放热固化产生的热效应、单体/ LC混合物组分之间的热扩散系数、红外光谱和LC3灯发出的高强度紫外辐射而增强透射率。根据初始混合物的组成、紫外线剂量、单体的分子量和LC的性质,所制备的PDLC薄膜表现出不同的形貌。为了量化单体分子量对反应混合物相分离动力学的影响,我们进行了与实验结果吻合较好的理论研究。
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引用次数: 1
Improvement of the photovoltaic conversion efficiency using nanostructuring in intermediate-band photovoltaic solar cells 利用纳米结构提高中波段光伏太阳能电池的光电转换效率
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997594
H. Mammar, A. Benmansour, M. Bouzaki
Nanostructuring is one of the most developed technologies that are able to improve considerably the photovoltaic conversion for low cost. This approach removes certain limitations of current technology; the photons that have low energy and do not participate in the photovoltaic conversion. Also, the photons that have a high energy that sell their excess energy in phonons' form. This work focuses on intermediate band solar cells introduced by material with a high-energy gap, an intermediate energy level, by quantum dots or quantum wells of some nanometers. This study attempts to show the great interest of this approach by calculating first, the efficiency limits of solar cell Shockley and interests in the intermediate-band photovoltaic solar cells approach by studying the parameters affecting their performances as well as the choice of materials and energy level of the nanostructure. All this, is achieved through the simulation software Matlab. The mathematical model developing stretches of photon emission by sun until the photovoltaic conversion in the semiconductor material.
纳米结构技术是目前最发达的技术之一,它能够以较低的成本大大提高光伏转换的效率。这种方法消除了当前技术的某些限制;具有低能量且不参与光伏转换的光子。此外,具有高能量的光子以声子的形式出售其多余的能量。本研究的重点是利用具有高能间隙的材料、中间能级、量子点或某些纳米级的量子阱引入中间能带太阳能电池。本研究试图通过首先计算太阳能电池的Shockley效率极限,并通过研究影响其性能的参数以及纳米结构的材料和能级的选择,来展示该方法的巨大兴趣。这一切,都是通过仿真软件Matlab实现的。该数学模型发展了太阳对光子发射的延伸,直到半导体材料中的光伏转换。
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引用次数: 1
Study of a photovoltaic system connected to the network and simulated by the code PVSYST 光伏并网系统的研究,并通过代码PVSYST进行仿真
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997605
Chadel Meriem, Benyoucef Boumdiene, Chadel Asma, Bouzaki Mustapha Mohamed, Soufi Aicha
The document provided a general understanding of solar energy and how solar technology can be applied in practice to supply the lighting needs of the premise. The site analysis Tlemcen, weather data, is the design of the predicted value of the PV system. We present the analysis using the software PVSYST to optimize the system design for the premise. Simulation and calculation was made by taking into account the inclination and direction of a photovoltaic generator consider. The proposed photovoltaic system is mainly composed of 3 unit inverter, 3 batteries and 66 photovoltaic modules with nominal power 9.9kWc.
该文件提供了对太阳能的一般认识以及如何在实践中应用太阳能技术来提供照明需求的前提。现场分析了特莱姆森的气象数据,是设计光伏系统的预测值。本文采用PVSYST软件进行分析,以优化系统设计为前提。考虑了光伏发电机组的倾角和方向,进行了仿真计算。该光伏系统主要由3台逆变器、3节蓄电池和66个光伏组件组成,标称功率为9.9kWc。
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引用次数: 11
Dielectric and electrical properties of PANI composite films 聚苯胺复合薄膜的介电性能和电学性能
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997612
D. Mezdour, M. Tabellout, J. Bardeau, S. Sahli
The present work deals with the preparation of films from polymeric core-shell particles. Our approach is based on the chemical polymerization of a very thin layer of polyaniline (PANI) around particles of transparent polymers (polyamide and polystyrene). Films are then obtained by dissolving the two type synthesized core-shell powders in dichloromethane and m-Cresol respectively. Electrical properties were investigated using a dielectric relaxation spectrometer. Both composite films exhibited a percolative behaviour and a well established dc conductivity for high PANI concentration related to the conductive properties of the PANI spanning clusters. This property allows using such films in semi-conductive applications. For polyamide films, high dielectric constants were obtained at 5 wt. % of PANI allowing their use as high k-dielectrics compatibles with organic printed circuit boards.
本文研究了用高分子核壳粒子制备薄膜的方法。我们的方法是基于透明聚合物(聚酰胺和聚苯乙烯)颗粒周围一层非常薄的聚苯胺(PANI)的化学聚合。然后将合成的两种核壳粉末分别溶解在二氯甲烷和间甲酚中得到薄膜。电学性质用介电弛豫光谱仪进行了研究。两种复合膜都表现出渗透行为和良好的直流导电性,这与聚苯胺跨越簇的导电性能有关。这种特性允许在半导体应用中使用这种薄膜。对于聚酰胺薄膜,在5 wt. %的聚苯胺中获得高介电常数,允许它们作为高k介电剂与有机印刷电路板兼容。
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引用次数: 1
Effect of ecological treatment on adhesion of woven flax fibers in epoxy matrix 生态处理对亚麻织物在环氧基体中附着力的影响
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997596
A. Triki, M. Karray, C. Poilâne, P. Picart, M. Gargouri
Surface treatment of woven flax fibers was investigated as means of improving their adhesion in epoxy matrix. Flax fibers were treated in two ways : (i) with enzymatic treatments using pectinase enzymes and (ii) with pectinase enzymes/detergent, respectively. For this reason, dielectric measurements were performed in the frequency range from 10-1 Hz to 106 Hz and temperature interval from 40 °C to 200 °C. Studies of dielectric relaxations in these composites revealed the presence of three relaxation processes namely the orientation polarization imputed to the presence of polar water molecules in flax fibers, the relaxation process associated with conductivity occurring as a result of the carriers charges diffusion noted for high temperature above glass transition and low frequencies, and interfacial polarization effect or Maxwell-Wagner-Sillars (MWS) relaxation that is attributable to the accumulation of charges at the flax fibers/epoxy resin interfaces. Analysis of this latter using the Havriliak-Negami model revealed that the adhesion fibers/matrix was improved by the addition of the detergent treatment to the enzymatic one.
研究了机织亚麻纤维的表面处理方法,以提高其在环氧基体中的附着力。采用果胶酶法和果胶酶/洗涤剂法对亚麻纤维进行酶处理。因此,介电测量的频率范围为10-1 Hz至106 Hz,温度范围为40°C至200°C。对这些复合材料介电弛豫的研究揭示了三个弛豫过程的存在,即取向极化归因于亚麻纤维中极性水分子的存在,弛豫过程与导电性有关,这是由于载流子电荷扩散引起的高温玻璃化转变和低频,和界面极化效应或麦克斯韦-瓦格纳-西拉(MWS)弛豫,这是由于在亚麻纤维/环氧树脂界面上电荷的积累。使用Havriliak-Negami模型对后者进行分析,发现在酶处理的基础上加入洗涤剂处理可以改善纤维/基质的粘附性。
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引用次数: 1
Innovative emitter design for low-cost silicon based heterostructure solar cells 低成本硅基异质结构太阳能电池的创新发射极设计
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997604
M. Boumaour, A. Bahfir, S. Sali, S. Kermadi, L. Zougar, N. Ouarab
N+ transparent conductor oxides (TCO's) can be a valuable and low-cost alternative to conventional thermally diffused emitter of silicon based solar cells. With reduced resistivities by appropriate doping and considering lattice mismatch and energy band offsets at the interface with p-silicon substrate, predictive study by numerical simulation shows comparable performance between ZnS:Al and TiO2:Nb with conversion efficiencies >16%. Furthermore, a back surface field achieved by a thin Sb2Te3 can enhance the efficiency with values higher than 18.5%.
N+透明导体氧化物(TCO)可以作为传统的硅基太阳能电池热扩散发射器的一种有价值且低成本的替代品。通过适当掺杂降低电阻率,并考虑到与p-硅衬底界面处的晶格失配和能带偏移,通过数值模拟的预测研究表明,ZnS:Al和TiO2:Nb的转换效率可达16%以上。此外,薄层Sb2Te3形成的后表面电场可以提高效率,其值高于18.5%。
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引用次数: 3
Electrostatic actuation of a silicon membrane to control the injected fluid volume by a micro pump 静电驱动硅膜,通过微泵控制注入流体的体积
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997607
N. Benmoussa, A. Guen, B. Bouazza, R. Otmani
This paper is to study the phenomenon of electrostatic actuation of a silicon membrane for injecting a sufficient quantity of fluid and in particular medication with a micro pump. The latter becomes a void of first choice for the treatment of diseases such as diabetes that requires the use of a syringe for insulin injection. With the development of MEMS technology, the injection of insulin is transmitted through a micro pump located outside the human body and connected to a subcutaneous cannula to control the dosage depending on the need body. The idea is to take the patient's blood glucose and compared with a reference value. Based on the obtained difference, an electronic system calculates the volume of insulin and the number of units required to be injected to stabilize blood glucose levels. The micropump is constituted by a silicon membrane electrostatically actuated by a DC voltage V. This actuation causes deformation of the membrane leading to the opening of the first micro valve and the introduction of a unit volume in the chamber internal micro pump through the first pipe. The annulment of the voltage V leads to the return of the membrane at equilibrium. This causes the closure of the first valve and the opening of the second micro valve which will inject the fluid into the second pipe.
本文研究静电驱动硅膜的现象,用微泵注入足量的液体,特别是药物。后者成为治疗糖尿病等需要使用注射器注射胰岛素的疾病的首选。随着MEMS技术的发展,胰岛素的注射通过位于人体外部的微型泵传输,并连接到皮下插管,根据需要的身体控制剂量。这个想法是取病人的血糖,并与参考值进行比较。根据得到的差值,电子系统计算胰岛素的体积和稳定血糖水平所需注射的单位数。微泵由直流电压v静电驱动的硅膜构成,该驱动引起膜的变形,导致第一微阀打开,并通过第一管道将单位体积引入腔室内部微泵。电压V的取消导致膜回到平衡状态。这导致第一个阀门关闭,第二个微型阀门打开,将流体注入第二个管道。
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引用次数: 0
Evidence of lateral coupling phenomenon in self-assembled InAs/InP(001) quantum dots characterized by photoluminescence spectroscopy (PLS) 光致发光光谱(PLS)表征自组装InAs/InP(001)量子点中横向耦合现象的证据
Pub Date : 2014-12-29 DOI: 10.1109/NAWDMPV.2014.6997602
F. Besahraoui, M. Bouslama, M. Ghafour, Z. Lounis, K. Hamaida
We have characterized with photoluminescence spectroscopy (PLS) the optoelectronic properties of self-assembled InAs quantum islands (QIs) grown on InP(001) substrate. InAs/InP(001) QIs are grown by Molecular Beam Epitaxy (MBE) method in optimized conditions of temperature and gas pressure. From Polarized Photoluminescence (PPL) measurements, we have deduced that InAs quantum islands have an isotropic quantum dots (QDs) shape. Through the excitation density PL measurements, we have checked the origin of the PL peaks. The observed PL peaks are related to a ground states of two families of InAs/InP(001) quantum dots. Through the study of the excitation density - PL spectra, we have evidenced the presence of a lateral coupling phenomenon between the two families of InAs/InP(001) quantum dots. In this case, the ground states are infected by this phenomenon which is considered, in this situation, a degradation source of the optoelectronic devices.
利用光致发光光谱(PLS)表征了生长在InP(001)衬底上的自组装InAs量子岛(QIs)的光电特性。采用分子束外延(MBE)法在优化的温度和气压条件下生长InAs/InP(001) QIs。从偏振光致发光(PPL)测量中,我们推断出InAs量子岛具有各向同性量子点(QDs)形状。通过对激发密度PL的测量,我们检查了PL峰的来源。观测到的PL峰与两族InAs/InP(001)量子点的基态有关。通过对激发密度- PL光谱的研究,我们证明了InAs/InP(001)量子点两族之间存在横向耦合现象。在这种情况下,基态受到这种现象的感染,在这种情况下,这种现象被认为是光电器件的退化源。
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引用次数: 0
期刊
2014 North African Workshop on Dielectic Materials for Photovoltaic Systems (NAWDMPV)
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