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ANALYSIS OF THE RADON CONCENTRATIONS IN NATURAL MINERAL AND TAP WATER USING LUCAS CELLS TECHNIQUE 利用LUCAS细胞技术分析天然矿物和自来水中的氡浓度
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-09-27 DOI: 10.3846/jeelm.2022.17411
M. Calin, A. Ion, I. Radulescu, C. Simion, M. Mincu, I. Ion
The aims of this study were to determine the radon concentration in natural mineral and tap water and to estimate the resulting ingestion doses received by adults. Physical-chemical characteristics of water samples have also been investigated. In the last years have been an increase of water consumption of both, natural mineral and tap, many sources and producers being available on the market. Thus, the physical-chemical and radiologic parameters of water must be in compliance with the Drinking Water Directive (DWD). Thus, the study presents an assessment of the radioactivity due to 222Rn and 3H in several mineral natural water samples from the north region of Romania, but also in several tap water samples. The methods used were based on gamma spectrometry, gross alpha-beta measurements and beta spectroscopy, but also ICP-MS for chemical parameters. The results of this work showed that the geology and rock types clearly influence the water radon concentration. The radon concentration is lower in the water that passes through sedimentary rocks than that passing through granitic rocks. An important aspect of this work is to provide reliable information regarding radon and tritium concentrations. Radon concentration varied between 0.15±0.05 Bq/L and 11.35±2.97 Bq/L in the natural mineral water samples and between 0.17±0.05 Bq/L and 8.51±2.34 Bq/L in the tap water samples. An estimation of annual effective radiation dose based on the sample results was also made. Calculated values for ingestion dose due to regular consumption of water does not induce a health risk because of the intake of various radionuclides contained in the water. The maximum values being of 47.38 µSv/y. The determined values for the collected samples are below recommended reference levels, but more important aspect is that this study emphasise environmental sustainability in the investigated area.
这项研究的目的是确定天然矿物和自来水中的氡浓度,并估计成年人由此摄入的剂量。还对水样的物理化学特性进行了研究。在过去的几年里,天然矿物和自来水的消耗量都在增加,市场上有许多水源和生产商。因此,水的物理化学和放射学参数必须符合饮用水指令(DWD)。因此,该研究对罗马尼亚北部地区的几个矿物天然水样本以及几个自来水样本中222Rn和3H的放射性进行了评估。所使用的方法基于伽马光谱法、总α-β测量法和β光谱法,但也基于化学参数的ICP-MS。研究结果表明,地质和岩石类型对水氡浓度有明显的影响。穿过沉积岩的水中的氡浓度低于穿过花岗岩的水中的氡气浓度。这项工作的一个重要方面是提供关于氡和氚浓度的可靠信息。天然矿泉水中氡浓度在0.15±0.05 Bq/L和11.35±2.97 Bq/L之间变化,自来水样品中氡浓度在0.17±0.05 Bq/L和8.51±2.34 Bq/L之间变化。还根据样本结果估算了年有效辐射剂量。由于摄入了水中所含的各种放射性核素,由于经常用水而产生的摄入剂量计算值不会引起健康风险。最大值为47.38µSv/y。所收集样本的测定值低于建议的参考水平,但更重要的是,本研究强调了调查区域的环境可持续性。
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引用次数: 1
ROLE OF THERMODYNAMIC PROCESSES IN PLANT LEAF GAS EXCHANGE SYSTEM FOR ASSIMILATION OF CO2 EMISSIONS FROM THE AMBIENT AIR 植物叶片气体交换系统中热力学过程对吸收环境空气中CO2排放的作用
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-09-22 DOI: 10.3846/jeelm.2022.17409
Algimantas Sirvydas, T. Ūksas, P. Kerpauskas, R. Čingienė
When temperature in the leaf gas exchange system changes, the thermodynamic parameters describing the condition of moist air also change. A temperature change of 1 oC in plant leaf tissues leads to a change in partial water vapour pressure of 144 Pa in the gas exchange cavities. Then a temperature decrease of 1 oC in a plant leaf produces 0.897 g of condensate, from 1 m3 of air in leaf ventilation cavities on the surface. When the temperature of plant leaves in the leaf ventilation system changes, the total water vapor state on the inner surface of the leaves changes, and the water vapor state in the stomatal cavities changes. The thickness of the formed condensate film on the plant leaf canal wall surfaces depends on the canal diameter and temperature change. The paper presents information about the mechanism of water formation and thermodynamic processes in the plant leaf gas exchange system participating in the process of assimilation. The formation and change of the internal surfaces of the stomatal cavities of the water film sheet allow the participation of chemical processes in the assimilation of CO2 emissions from the environment.
当叶片气体交换系统中的温度发生变化时,描述湿空气状态的热力学参数也会发生变化。植物叶片组织温度每变化1℃,气体交换腔内水蒸气分压就会变化144 Pa。然后,植物叶片的温度每降低1摄氏度,就会产生0.897克冷凝水,来自叶片表面通风腔中的1立方米空气。当植物叶片在叶片通风系统中的温度发生变化时,叶片内表面的总水汽状态发生变化,气孔内的水汽状态也发生变化。植物叶片沟道壁面上形成的凝结膜的厚度取决于沟道直径和温度的变化。本文介绍了植物叶片气体交换系统参与同化过程的水分形成机理和热力学过程。水膜片气孔腔内表面的形成和变化使吸收环境中二氧化碳排放的化学过程得以参与。
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引用次数: 0
THE DEVELOPMENT STAGE OF XIAMEN CITY AND RELATED ENVIRONMENT EVOLUTION 厦门城市发展阶段及其环境演变
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-09-06 DOI: 10.3846/jeelm.2022.17407
Tianhai Zhang, Lina Tang, Y. Wen, Chenxing Wang
A model of environmental evolution of cities, especially in East Asia, is said to follow four stages. The pathways to the fourth stage of eco-city are not always clear, but need to be contextual. This research extended the original stage model of environmental evolution to describe urban development and its impact on the environment, especially integrated a model comprise of density, mix and accessibility (DMA) for urbanization and applied Ecological Footprint (EF) concept for pressure on eco-environment. The research analyzed the Xiamen City in China through the first three stages in order to gain insights how the city might be able to hasten its transition to the fourth stage of an eco-city. As expected, the development of Xiamen City and its environmental impacts has very obvious stage characteristic. Before 2010, Xiamen City got through a long time of Stage I (poverty stage); and in the period of 2010 to 2019, Xiamen experienced the Stage II (industrial pollution stage) and Stage III (mass consumption stage) crossly. The new built-up land in the decade of 2000–2010 is much larger than the previous 10 years from 1989 to 2000, 5 times more. Meanwhile, compared with 1980–1995, the ecological deficit also enlarged greatly in period of 1995–2010. Considering up to 2019 Xiamen still has large amount of energy consumption and high level output of industry solid waste, Xiamen should take measures of adjusting the industrial structure, promoting the green industry and planning the urban growth boundary to achieve the eco-city stage.
城市环境演变的模式,特别是在东亚,据说遵循四个阶段。通往生态城市第四阶段的路径并不总是清晰的,但需要有语境。本研究扩展了原有的环境演化阶段模型来描述城市发展及其对环境的影响,特别是整合了城市化的密度、混合和可达性(DMA)模型和应用生态足迹(EF)概念来描述生态环境压力。本研究通过前三个阶段对中国厦门市进行了分析,以了解厦门市如何加速向生态城市第四阶段的过渡。正如预期的那样,厦门市的发展及其环境影响具有非常明显的阶段性特征。2010年以前,厦门市经历了漫长的第一阶段(贫困阶段);2010 - 2019年,厦门经历了第二阶段(工业污染阶段)和第三阶段(大众消费阶段)。2000 - 2010年10年间新增建设用地比1989 - 2000年10年间增加了5倍。与1980-1995年相比,1995-2010年期间生态赤字也大幅扩大。截至2019年,厦门市仍存在能耗大、工业固体废物产出量高的问题,应采取调整产业结构、推进绿色产业、规划城市增长边界等措施,实现生态城阶段。
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引用次数: 0
COMPARISON OF REMAINING COAL-BURNING ASH-BASED ON CD, PB, AND HG CONCENTRATION AT DIFFERENT TEMPERATURES: A CASE STUDY IN ACEH PROVINCE 不同温度下基于cd、pb和hg浓度的剩余燃煤灰的比较:以亚齐省为例研究
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-08-05 DOI: 10.3846/jeelm.2022.16294
A. Gani, Erdiwansyah Erdiwansyah, R. E. Sardjono, M. Mariana, R. Mamat
This study aims to investigate the efficiency level of absorption of heavy metals Cd, Pb, and Hg. Combustion is carried out using coal with the addition of absorbent ratios of 2%, 4%, 6%, 8%, and 10%. The adsorbent used is natural zeolite which is widely available and inexpensive. This study provides practical implications for the easy and inexpensive removal of heavy metal emissions during combustion. The results show that the maximum efficiency level for Cd metal reached 22.96% which was recorded at a temperature of 600 °C for an adsorbent ratio of 10%. The maximum efficiency level of Pb metal from the experimental results was obtained at a temperature of 600 °C with an adsorbent ratio of 10% to 10.83%. Meanwhile, the efficiency level for Hg metal produced was 0.05% which was recorded at the adsorbent ratio of 10% at 800 °C. The maximum total capacity of Pb metal for each tested combustion temperature was 600 °C 39.85 mg/kg, 700 °C 25.43 mg/kg, and 800 °C 7.21 mg/kg. On the other words, the higher the combustion temperature tested, the lower the absorption efficiency rate obtained.
本研究的目的是研究重金属Cd、Pb、Hg的吸收效率水平。燃烧采用煤,吸附剂添加比例分别为2%、4%、6%、8%和10%。所使用的吸附剂是天然沸石,这种吸附剂广泛可用且价格低廉。该研究为在燃烧过程中简单廉价地去除重金属排放提供了实际意义。结果表明,在温度为600℃、吸附剂比例为10%时,对金属镉的吸附效率最高可达22.96%。实验结果表明,在温度为600℃,吸附剂比例为10% ~ 10.83%的条件下,金属铅的吸附效率最高。同时,在800℃条件下,吸附剂比例为10%时,对金属汞的收率为0.05%。各测试燃烧温度下Pb金属的最大总容量分别为600℃39.85 mg/kg、700℃25.43 mg/kg和800℃7.21 mg/kg。换句话说,燃烧温度越高,获得的吸收效率越低。
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引用次数: 0
COLUMN STUDY FOR THE CU(II) REMOVAL BY THE COCONUT SHELL FROM AQUEOUS SOLUTION – MLR AND GA MODELING 椰壳去除水溶液中cu (ii)的柱状研究- MLR和ga模型
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-06-17 DOI: 10.3846/jeelm.2022.16764
Shreyashi Sarkar, Nirjhar Bar, S. Das
Adsorption characteristics of locally available inexpensive natural adsorbent coconut shells were studied for Cu(II) removal. The present study adsorption process was carried through a fixed bed column to find out the breakthrough characteristics. The variation of operating variables is investigated, pH 6, influence Cu(II) concentration (10–30 mg·L–1), bed height (5–15 cm), the flow rate (10–30 ml·min–1). The suitability of various kinetic models has been tested. Maximum adsorption capacity, qe according to Thomas model, was 30.09 mg·g–1obtained at 20 ml/min, flow rate, 30 mg·L–1 metal solution, and 15 cm bed height. The correlation coefficient of the Thomas model ranges from 0.8260 to 0.9839. Besides this, according to the statistical parameters of the Yoon-Nelson and Yan et al. models, proving that the experimental data are suitable for this model. The statistical and GA modeling of the experimental data has also been performed successfully.
研究了当地廉价的天然吸附剂椰子壳对Cu(II)的吸附特性。本研究的吸附过程是通过固定床柱进行的,以找出突破性的特征。研究了操作变量的变化,pH 6,影响Cu(II)浓度(10-30 mg·L–1),床高(5-15 cm),流速(10-30 ml·min–1)。已经测试了各种动力学模型的适用性。根据Thomas模型,最大吸附容量qe为30.09 mg·g–1,在20 ml/min、流速、30 mg·L–1金属溶液和15 cm床高下获得。托马斯模型的相关系数在0.8260到0.9839之间。此外,根据Yoon Nelson和Yan等人模型的统计参数,证明实验数据适用于该模型。还成功地对实验数据进行了统计和遗传算法建模。
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引用次数: 0
PREPARATION AND CHARACTERIZATION OF MESOPOROUS CERIUM OXIDE FOR TOXIC AS(V) REMOVAL: PERFORMANCE AND MECHANISTIC STUDIE 介孔氧化铈的制备及性能研究
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-06-14 DOI: 10.3846/jeelm.2022.16749
U. Sahu, Sandip Mandal, S. Sahu, Narayan Gouda, R. Patel
In the present work, the adsorption of carcinogenic pentavalent arsenic (As(V)) from an aqueous solution was studied using mesoporous cerium oxide (MCO). The MCO was synthesized in the precipitation process and confirmed by FT-IR, SEM-EDX, XRD, and BET instrumental techniques. Batch adsorption showed that 95% of As(V) was removed in the optimum conditions of 0.60 g/L adsorbent dose, 10 mg/L initial concentration, time 30 min, and pH 3. Pseudo-secondorder kinetics and the Langmuir isotherm model were fitted to the experimental data. The MCO had a high surface area of 191.97 m2/g and a maximum adsorption capacity of 58.25 mg/g at pH 3. MCO could be able to remove 88% and 82% in the first and second cycles after being desorbed with 0.1 M NaOH solution. The Zeta potential and FTIR studies suggested that electrostatic attraction and ligand exchange mechanisms were responsible for As(V) adsorption.
在本工作中,使用介孔氧化铈(MCO)研究了致癌五价砷(As(V))从水溶液中的吸附。在沉淀过程中合成了MCO,并通过FT-IR、SEM-EDX、XRD和BET仪器技术进行了证实。分批吸附实验表明,在吸附剂用量为0.60g/L、初始浓度为10mg/L、时间为30min、pH为3的最佳条件下,As(V)的去除率为95%。拟二阶动力学和Langmuir等温线模型与实验数据进行了拟合。MCO在pH 3下具有191.97m2/g的高表面积和58.25mg/g的最大吸附容量。MCO在用0.1M NaOH溶液解吸后,在第一次和第二次循环中可以去除88%和82%。Zeta电位和FTIR研究表明,静电吸引和配体交换机制是As(V)吸附的原因。
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引用次数: 1
GREEN SYNTHESIS OF IRON-OXIDE NANOPARTICLES USING SCRAP IRON AS PRECURSOR FOR THE REMOVAL OF PB (II) FROM AQUEOUS MEDIUM 以废铁为前驱体绿色合成氧化铁纳米颗粒去除水介质中的铅(ii)
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-06-14 DOI: 10.3846/jeelm.2022.16747
Mohd Taqui, Snehamayee Das, T. Kamilya, Sandip Mondal, Surabhi Chaudhuri
In the present study, low-cost, environmentally friendly, single-step, high productive novel Iron-oxide nanoparticles (NPs) were prepared from scrap iron using a green synthesis method to remove Pb (II) from aqueous solution. The characterization of synthesized nanoparticles was conducted by UV-vis spectroscopy. The crystalline structure and the phase change were clarified by XRD. FE-SEM was done to know the morphology of iron oxide nanoparticles, and the average surface area of 46.856 m2/g was found by the BET surface area analyzer. The XRD plot shows that the obtained magnetite Fe3O4 combines FeO and Fe2O3 as the synthesis was conducted in the open atmosphere. The SEM images confirm the formation of iron oxide nanoparticles with a size of 31 nm. The removal efficiency of the adsorbent was carried out by optimizing the different operational parameters like pH, time, adsorbent dosage, initial concentration of metal ion, contact time by batch studies. The obtained pHzpc (pH 5.7) value indicates that the adsorption process will be favorable at higher pH. The maximum removal efficiency and uptake capacity of lead were 98% and 68.07 mg/g, respectively. Adsorption data obtained were analyzed with Langmuir and Freundlich isotherm equations. The equilibrium data are fitted by Langmuir isotherm in a superior way than that of Freundlich isotherm. The results show that homogeneous adsorption of the metal ion favors heterogeneous adsorption. The maximum adsorption capacity of iron oxide NPs was calculated through Langmuir isotherm was Qmax (68.07) mg/g. Moreover, the adsorption of metal ions with time was also analyzed with the pseudo 1st and pseudo 2nd kinetic equations. The kinetic data are fitted more in the pseudo 2nd order reaction. Adsorption capacity calculated through pseudo 2nd order equation was qe (51.81) mg/g. This literature verifies that NPs synthesized from scrap iron as precursors prove to be an attractive option for removing heavy metals.
在本研究中,以废铁为原料,采用绿色合成方法制备了低成本、环保、单步、高产的新型氧化铁纳米颗粒(NP),以去除水溶液中的Pb(II)。用紫外-可见光谱法对合成的纳米颗粒进行了表征。通过XRD对其晶体结构和相变进行了分析。进行FE-SEM以了解氧化铁纳米颗粒的形态,并且通过BET表面积分析仪发现平均表面积为46.856m2/g。XRD图显示,当在开放气氛中进行合成时,所获得的磁铁矿Fe3O4结合了FeO和Fe2O3。SEM图像证实了尺寸为31nm的氧化铁纳米颗粒的形成。通过分批研究,优化不同的操作参数,如pH、时间、吸附剂用量、金属离子的初始浓度、接触时间,以提高吸附剂的去除效率。所获得的pHzpc(pH5.7)值表明,在较高的pH下,吸附过程将是有利的。铅的最大去除率和吸收能力分别为98%和68.07mg/g。用Langmuir和Freundlich等温线方程对获得的吸附数据进行分析。Langmuir等温线拟合平衡数据的方法优于Freundlich等温线。结果表明,金属离子的均相吸附有利于非均相吸附。通过Langmuir等温线计算出氧化铁纳米粒子的最大吸附量为Qmax(68.07)mg/g。此外,还用伪一阶和伪二阶动力学方程分析了金属离子随时间的吸附。动力学数据更多地拟合在拟二阶反应中。通过拟二阶方程计算的吸附容量为qe(51.81)mg/g。该文献证实,以废铁为前体合成的纳米颗粒被证明是去除重金属的一种有吸引力的选择。
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引用次数: 4
IN-SITU REMEDIATION OF HEAVY METAL CONTAMINATED SITES THROUGH MECHANICAL STABILIZATION USING INDUSTRIAL WASTE PRODUCTS 利用工业废弃物进行机械稳定的重金属污染场地原位修复
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-06-08 DOI: 10.3846/jeelm.2022.17077
R. Raja, S. Pal, A. Karmakar
The present study aimed to assess the stabilization performance of fly ash, blast furnace slag and quick lime for heavy metals in contaminated soil at a landfill site at Kolkata, West Bengal, India. The physical properties and strength parameters of the contaminated soil substantially increased after additives application. Moreover, the heavy metal concentrations in the leachate of the polluted soil were found almost nil after optimum blending of the additives mechanically with the soil and post-curing for 7 days. The numerical modeling studies were also carried out using PLAXISTM 3D software to ascertain the improvement of safety factor and deformation caused at the foundation level of an embankment constructed on such stabilized soil. The vertical displacement of the embankment founded on stabilized soil reduced from 194.3 to 136.3 mm and the safety factor of the embankment slope (1 V:1.5 H) increased from 2.5 to 3.2 under drained condition.
本研究旨在评估粉煤灰、高炉矿渣和生石灰对印度西孟加拉邦加尔各答某垃圾填埋场污染土壤中重金属的稳定性能。添加添加剂后,污染土壤的物理性质和强度参数均有明显提高。与土壤机械调配最佳添加剂,养护7 d后,污染土壤渗滤液中重金属含量基本为零。利用PLAXISTM 3D软件进行了数值模拟研究,以确定在这种稳定土上施工的路堤的安全系数和地基变形的改善情况。排水条件下,稳定土路基竖向位移由194.3 mm减小到136.3 mm,路基边坡安全系数(1 V:1.5 H)由2.5提高到3.2。
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引用次数: 0
TRENDS AND PERFORMANCES OF THE ALGAL BIOFUEL: A BIBLIOMETRIC APPROACH 藻类生物燃料的发展趋势和性能&文献计量法
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-06-06 DOI: 10.3846/jeelm.2022.16746
Conghao Gao, Huaijia Xin, Shu Yang, Zhuo Li, Shulin Liu, Bin Xu, Tianyang Zhang, S. Dutta, Yulin Tang
The paper systematically presents a survey of the literature on algal biofuel by a bibliometric assessment. Based on 10,201 articles extracted from the Science Citation Index Expanded database during 1980–2019, a knowledge-generating system about algal biofuel has been established through analysis of publication performance, social networks, citations analysis and keywords analysis. Annual publication output in algal biofuel research has rapidly increased, particularly over the past decade. “Bioresource Technology” is the most outstanding journal when all analysis indices have been taken into account. The USA ranks 1st with 2,151 publications and has a high supremacy in international research collaborations. Through the analysis of keywords, the research trends of algae biofuel in algae selection, cultivation, harvesting, extraction, conversion and bioproducts are reviewed. The future of algal biofuel is quite promising, however, for its commercial production, several technical challenges like large-scale algal biomass production, cheap harvesting technology, etc. have to be met a-priori.
本文通过文献计量学的方法对藻类生物燃料的文献进行了系统的综述。基于1980-2019年间从科学引文索引扩展数据库中提取的10201篇文章,通过对出版物绩效、社交网络、引文分析和关键词分析,建立了藻类生物燃料的知识生成系统。藻类生物燃料研究的年度出版物产量迅速增加,特别是在过去十年中。综合所有分析指标,《生物资源技术》是最优秀的期刊。美国以2151份出版物位居第一,在国际研究合作中占据绝对优势。通过关键词分析,综述了藻类生物燃料在藻类选择、培养、收获、提取、转化和生物制品等方面的研究进展。藻类生物燃料的未来是非常有希望的,然而,对于其商业生产来说,必须事先应对一些技术挑战,如大规模藻类生物质生产、廉价的收获技术等。
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引用次数: 1
SUSTAINABLE ENERGY-EFFICIENT CONVERSION OF WASTE TEA LEAVES TO REDUCING SUGAR: OPTIMIZATION AND LIFE-CYCLE ENVIRONMENTAL IMPACT ASSESSMENT 废茶叶可持续节能转化为还原糖:优化及全生命周期环境影响评价
IF 1.3 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Pub Date : 2022-05-31 DOI: 10.3846/jeelm.2022.16744
R. Chakraborty, Oindrila Roy
Innovative protocols involving energy-proficient pretreatment of waste tea leaves (WTL) for preparation of cellulose and its subsequent photocatalytic hydrolysis (PH) for production of total reducing sugar (TRS) have been reported. The WTL was subjected to alkali pretreatment (60 °C, 1 h) followed by bleaching (employing peracetic acid, 65 °C, 2 h) in a quartz halogen irradiated batch reactor (QHIBR) for efficient separations of lignin and hemicellulose fractions to produce WTL derived cellulose fiber (WTLDCF; 94.5% cellulose). Consequent PH of WTLDCF in QHIBR using combination of Amberlyst-15 and nano-TiO2 catalysts was optimized (parameters: 40 min, 70 °C, 1:30 WTLDCF to water weight ratio and 5 wt. % catalyst concentration) employing Taguchi design that provided maximum 68.25% TRS yield. The QHIBR demonstrated faster hydrolysis and superior energy-efficiency over conventional reactor owing to quartz halogen irradiation. Life cycle assessment indicated an acceptable global warming potential of 2.215 kg CO2 equivalent; thus, establishing an energy-efficient environmentally sustainable WTL valorization process.
创新方案涉及废茶叶预处理(WTL)制备纤维素及其随后的光催化水解(PH)生产总还原糖(TRS)。WTL经碱预处理(60℃,1 h),再经过氧乙酸漂白(65℃,2 h),在石英卤素辐照间歇式反应器(QHIBR)中有效分离木质素和半纤维素组分,生产WTL衍生纤维素纤维(WTLDCF;94.5%纤维素)。采用田口设计优化了Amberlyst-15和纳米tio2复合催化剂QHIBR中WTLDCF的PH(参数:40 min, 70°C, 1:30 WTLDCF与水的重量比,5 wt. %的催化剂浓度),TRS收率最高为68.25%。由于石英卤素辐照,QHIBR比传统反应器具有更快的水解速度和更高的能效。生命周期评估表明,可接受的全球变暖潜势为2.215 kg CO2当量;从而建立一个节能、环保、可持续的WTL增值过程。
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引用次数: 0
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Journal of Environmental Engineering and Landscape Management
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