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Kajian Simulasi Dinamika Molekul Adsorpsi Hidrogen pada Carbone Nanotube dengan Variasi Chirality dan Temperatur Menggunakan Kode LAMMPS
Pub Date : 2021-05-31 DOI: 10.23960/jemit.v2i2.58
Erika Marinda Mufida, Sri Wahyu Suciyati, Gurum Ahmad Pauzi, Amir Supriyanto
Hydrogen adsorption has been simulated on carbon nanotubes for optimum hydrogen absorption. Parameters that affect the amount of hydrogen absorbed have been studied, such as the effect of chirality and temperature on hydrogen absorption in CNTs. The simulation method of hydrogen adsorption on carbone nanotubes uses molecular dynamics simulation code LAMMPS, applies Lennard-Jones interatomic potential and hydrogen atom movement using Van Der Waals force with Microcanonical Ensemble. Data analysis is the output of LAMPS in the form of data in XYZ format. The data contains information in the form of integration steps, number of atoms, temperature, pressure, potential energy, kinetic energy, volume, van der Waals energy, total simulation time and hydrogen absorption. The simulation results show that the optimum absorption occurs at run 10000 and a temperature of 100 K, for armchair chirality of 10 atoms, chirality of 12 atoms and zigzag chrality of 5 atoms. Formation of hydrogen coordinates with Avogadro software, formation of CNT coordinates with VMD software and visualization of hydrogen adsorption on CNTs using VMD software.
模拟了碳纳米管对氢的吸附,以获得最佳的吸氢效果。研究了影响吸氢量的参数,如手性和温度对CNTs中吸氢量的影响。采用分子动力学模拟程序LAMMPS模拟碳纳米管上的氢吸附,采用Lennard-Jones原子间势和微正则系综下范德华力的氢原子运动。数据分析是lamp以XYZ格式的数据形式输出的。数据包含积分步骤、原子数、温度、压力、势能、动能、体积、范德华能、总模拟时间和氢吸收率等信息。模拟结果表明,10个原子的扶手椅手性、12个原子的手性和5个原子的之字形手性在运行10000次和温度为100 K时产生最佳吸收。用Avogadro软件生成氢坐标,用VMD软件生成碳纳米管坐标,用VMD软件可视化碳纳米管上的氢吸附。
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引用次数: 0
Pengaruh Variasi Polivinilpirolidon (PVP) Terhadap Pembentukan Serat Nano TiO2 Menggunakan Metode Electrospinning 多肽异位对利用电旋法形成纳米纤维的影响
Pub Date : 2021-01-31 DOI: 10.23960/jemit.v2i1.49
Vega Rahmawati Ar, Posman Manurung, J. Junaidi, Pulung Karo Karo
Research on the formation of TiO2 nanofiber has been carried out with PVP variations of 1.1; 1,2; 1.3; 1.4 and 1.5 grams using electrospinning. This study aims to determine the effect of PVP variation on the viscosity and morphology of TiO2 nanofibers and to determine the crystal structure of the fibers. Synthesis of TiO2 was carried out using the sol-gel method. TTIP is used as a precursor, ethanol as a solvent, acetic acid as a catalyst and PVP as a fiber-forming polymer. The results of the viscosity measurement show that the amount of PVP used in the sample is directly proportional to the level of solution viscosity. Based on the results of SEM characterization, it showed relatively uniform nanofiber morphology with fiber diameter ranging from 94 nm - 735 µm. The results of TEM characterization showed that the size of TiO2 nanofiber particles ranged from 7-15 nm. The results of XRD analysis showed that the crystal structures formed at a calcination temperature of 450 oC were the anatase and rutile phases.
在PVP变化为1.1的条件下,对TiO2纳米纤维的形成进行了研究;1、2;1.3;1.4和1.5克使用静电纺丝。本研究旨在确定PVP变化对TiO2纳米纤维粘度和形貌的影响,并确定纤维的晶体结构。采用溶胶-凝胶法制备TiO2。TTIP为前驱体,乙醇为溶剂,乙酸为催化剂,PVP为成纤维聚合物。粘度测量结果表明,样品中PVP的用量与溶液粘度水平成正比。SEM表征结果表明,其纳米纤维形态较为均匀,纤维直径在94 nm ~ 735µm之间。TEM表征结果表明,TiO2纳米纤维颗粒的尺寸在7 ~ 15 nm之间。XRD分析结果表明,在450℃煅烧时形成的晶体结构为锐钛矿相和金红石相。
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引用次数: 0
Ekstrak Daun Pandan Sebagai Inhibitor Korosi Baja St37 Dalam Larutan NaCl 3% dengan Suhu Perendaman 27°C dan 40°C
Pub Date : 2021-01-31 DOI: 10.23960/jemit.v2i1.130
Siti Fatkhul Ulum, Ediman Ginting, S. Sembiring
The extract of pandan leaf used as corrosion inhibitor of St37 steel in NaCl 3% solution. To determine the effect of inhibitor concentration and immersion temperature on steel corrosion is done with variation of inhibitor concentration there were 0, 1,8, 1,2, and 1,4% and temperature variation is 27°C and 40°C. Corrosion rate testing is done by weight loss method. Increased corrosion rate along with increasing sample weight loss. Inhbitor pandan leaf extract were the most efficient at concentration of 1.2% with soaking temperature at 27°C and 40°C. Samples were also in the characterization of XRD and SEM-EDS. The XRD results showed that the highest Fe peak was formed in a sample using a 1.2% inhibitor concentration and the lowest Fe peak in the sample without inhibitor. The SEM characterization results also showed that in samples without inhibitors look more corroded, and in samples using 1.2% inhibitor concentrations look slightly corroded. These results were reinforced by the percentage of corrosion products shown in EDS results.
用香兰叶提取物作为St37钢在NaCl 3%溶液中的缓蚀剂。为了确定缓蚀剂浓度和浸泡温度对钢腐蚀的影响,在27°C和40°C的温度下,缓蚀剂浓度分别为0、1、8、1、2和1、4%。腐蚀速率测试采用失重法进行。随着样品重量损失的增加,腐蚀速率增加。在27°C和40°C浸泡温度下,浓度为1.2%的香兰叶提取物的抑菌效果最好。并对样品进行了XRD和SEM-EDS表征。XRD结果表明,当缓蚀剂浓度为1.2%时,铁峰最高,未添加缓蚀剂时铁峰最低。SEM表征结果还表明,在没有抑制剂的样品中,看起来腐蚀更严重,而在使用1.2%抑制剂的样品中,看起来腐蚀轻微。EDS结果中显示的腐蚀产物百分比加强了这些结果。
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引用次数: 0
Pengaruh Variasi Kadar CaCO3 terhadap Pertumbuhan Fase Superkonduktor BPSCCO–2212 Menggunakan Metode Pencampuran Basah CaCO3变化对BPSCCO - 2212超导相位的影响,采用了一种湿润的混合方法
Pub Date : 2021-01-31 DOI: 10.23960/jemit.v2i1.37
Rianggi Wahyuni Pratiwi, Suprihatin, Simon Sembiring, Roniyus Marjunus
This research was conducted to determine the effect of CaCO3 levels on the formation of superconducting phase BPSCCO - 2212 by calculating the level of purity of the phases formed and looking at the microstructure. The variation of CaCO3 was 0.95, 1.00, 1.05 and 1.10 mole using the wet mixing method. The samples were calcined at 800 ° C for 10 hours, and sintered at 820 ° C for 20 hours. Synthesized samples were characterized using X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The XRD’s chacterization results show that the level of purity of the formed phases increases with increasing Ca levels with maximum point at BPSCCO-2212/1.10 mole. The highest volume fraction was 79,06% in the BPSCCO-2212/1.10 sample. While the lowest volume fraction was 72.10% in the BPSCCO-2212/0.95 sample. Meanwhile, the highest degree of orientation was 20.59% at BPSCCO-2212/0.95. The lowest degree of orientation was 8.46% at BPSCCO-2212/1.10. SEM’s chacterization results show of all samples have been oriented altought not perfect yet and have relatively little space between slabs (voids).
本研究通过计算所形成相的纯度和观察微观结构来确定CaCO3水平对BPSCCO - 2212超导相形成的影响。采用湿混合法,CaCO3的变化量分别为0.95、1.00、1.05和1.10 mol。样品在800℃下煅烧10小时,在820℃下烧结20小时。利用x射线衍射(XRD)和扫描电镜(SEM)对合成的样品进行了表征。XRD表征结果表明,随着Ca含量的增加,形成相的纯度逐渐提高,其最大值为BPSCCO-2212/1.10摩尔。BPSCCO-2212/1.10样品的最高体积分数为79,06%。而BPSCCO-2212/0.95样品的最低体积分数为72.10%。同时,BPSCCO-2212/0.95的取向度最高,为20.59%。BPSCCO-2212/1.10的取向度最低,为8.46%。扫描电镜的表征结果表明,所有样品的取向虽然还不完善,并且板之间的空间(空隙)相对较小。
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引用次数: 0
Penggunaan Metode Taguchi untuk Menentukan Kondisi Parameter Optimum Pada Pembuatan CaO dari Batu Kapur (CaCO-3) 使用田口方法确定石灰石曹(caco3)生产的最佳参数的状态
Pub Date : 2021-01-31 DOI: 10.23960/jemit.v2i1.46
Lilik Widia, Roniyus Marjunus, S. Sudibyo
Research has been carried out to determine the optimum conditions for making quicklime (CaO) using the Taguchi Method. CaO is the burning result of limestone (CaCO_3) in calcination process by releasing of CO_2 gas until CaO solids occur. The limestone was calcined at 950^o c. The Taguchi Method is a quality improvement technique with the selection of the most influential parameters of the making of process CaO. The parameters are particle size, CaO mass, heating temperature and stirring time. The XRF results show that the levels of CaO after the Taguchi Method design has increased from 98.779% to 98.814%. The XRD results show that the CaO phase is amorphous. The phase which were formed by calcination are Lime (CaO), Quartz (SiO_2) and Hematite (〖Fe〗_2 O_3). Based on the SEM results, the morphology of CaCO_3 has an irregular particle size and tends to be a granular solid due to the presence of impurity. Meanwhile, the results of the EDS analysis show that the content of Calcium (Ca) is quite high. From the design results of the Taguchi Method, the optimum conditions is obtained at a particle size of 140 mesh, 75 gr CaO mass, heating temperature 70^o c and stirring time 0,5 hour.
对田口法生产生石灰的最佳工艺条件进行了研究。CaO是石灰石(CaCO_3)在煅烧过程中释放出CO_2气体,直至形成CaO固体的产物。在950℃下对石灰石进行了煅烧。田口法是一种质量改进技术,选取了影响CaO工艺制作的最重要参数。参数为粒径、CaO质量、加热温度和搅拌时间。XRF结果表明,采用田口法设计后,CaO的含量由98.779%提高到98.814%。XRD结果表明,CaO相呈非晶态。煅烧形成的相为石灰(CaO)、石英(SiO_2)和赤铁矿(〖Fe〗_2 O_3)。SEM结果表明,由于杂质的存在,CaCO_3的形貌呈不规则的颗粒状固体。同时,能谱分析结果表明,样品中钙(Ca)含量较高。根据田口法的设计结果,得到最佳条件为粒径140目,CaO质量75 g,加热温度70℃,搅拌时间0.5 h。
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引用次数: 0
Rancang Bangun Purwarupa Pemilah Nanas Berdasarkan Tingkat Kematangan Menggunakan Mikrokontroler Blue Pill STM32F103C8T6
Pub Date : 2020-11-30 DOI: 10.23960/JEMIT.V1I3.27
Friska Tiara Desy, Arif Surtono, Amir Supriyanto, J. Junaidi
The research about a design of prototype automatic pineapple sorting has been done with a belt conveyor system using a Blue Pill STM32F103C8T6 microcontroller. This research was conducted to create a prototype that can sort pineapples based on maturity level by classified unripe, ripe, and fully ripe. Sorting pineapple against the pineapple ripeness classification was carried out by a simulation process using serial data of index maturity sent from the PC monitor serial to microcontroller via serial communication. The serial data sent in character format was an integer 1; 2; 3; 4; 5; 6; and 7. The conveyor using a chain with gear transmission system and a DC motor as a drive. The results showed that the instument is capable of carrying a maximum load of pineapple fruit of 1.0 kg with a transport speed of 27,98 cm/s and can perform pineapple ripeness sorting with an accuracy more than 90%.
采用Blue Pill STM32F103C8T6单片机,设计了菠萝自动分拣样机。本研究的目的是建立一个可以根据成熟度等级对菠萝进行分类的原型,分为未熟、成熟和完全成熟。利用上位机监控串口通过串行通信发送到单片机的指标成熟度串行数据,根据菠萝成熟度分类对菠萝进行了分类仿真。以字符格式发送的串行数据为整数1;2;3;4;5;6;和7。该输送机采用链式带齿轮传动系统和直流电机作为传动装置。结果表明,该仪器最大可承载1.0 kg的菠萝果实,运输速度为2798 cm/s,可进行菠萝成熟度分选,分选精度达90%以上。
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引用次数: 3
Efektivitas Ekstrak Daun Jambu Biji (Psidium Guajava l.) Sebagai Inhibitor Pada Baja Karbon St37 dalam Medium Korosif NaCl 3% 番石榴叶提取物的效力。作为碳钢St37的抑制剂在腐蚀性3%的介质中
Pub Date : 2020-11-30 DOI: 10.23960/jemit.v1i3.128
Dian Mardiana, Ediman Ginting, Agus Riyanto
The effectiveness of guava leaf extract as an inhibitor of St37 carbon steel in a corrosive medium of 3% NaCl had been researched. The concentration of guava leaf extract inhibitor was used 0%. 3%. 5% and 7% with immersion time of 4 and 8 days. Corrosion rate testing was done by weight loss method. The results of the research at each immersion time, showed that the optimum concentration of leaf guava extract to inhibit corrosion is 7% and the longer time immersion resulted in decreasing corrosion rate on St37 carbon steel. The maximum effectiveness of inhibitor occurred at 7% concentration with 8 days immersion time which is 70,12%. Characterization using Scanning Electron Microscopy (SEM) in sample St37-4-7 and St37-8-7 not all surfaces corroded, but on samples St37-4-0 and St37-8-0 almost all samples were corroded. This is reinforced with eds results in which sample St37-8-0 and St37-4-0 have a lower FeO content than sample St37-8-7 and St37-4-7. The X-Ray Diffraction (XRD) result shows that the phase was Fe.
研究了番石榴叶提取物在3% NaCl腐蚀介质中对St37碳钢的缓蚀作用。番石榴叶提取物抑制剂浓度为0%。3%。5%和7%,浸泡时间分别为4和8天。用失重法测定腐蚀速率。研究结果表明,在不同浸泡时间下,番石榴叶提取物的最佳腐蚀抑制浓度为7%,浸泡时间越长,对St37碳钢的腐蚀速率越低。当浓度为7%、浸泡时间为8 d时,抑制剂的有效性达到70,12%。在St37-4-7和St37-8-7样品中,并非所有表面都被腐蚀,但在St37-4-0和St37-8-0样品中,几乎所有样品都被腐蚀。eds结果强化了这一点,样品St37-8-0和St37-4-0的FeO含量低于样品St37-8-7和St37-4-7。x射线衍射(XRD)结果表明,其相为Fe。
{"title":"Efektivitas Ekstrak Daun Jambu Biji (Psidium Guajava l.) Sebagai Inhibitor Pada Baja Karbon St37 dalam Medium Korosif NaCl 3%","authors":"Dian Mardiana, Ediman Ginting, Agus Riyanto","doi":"10.23960/jemit.v1i3.128","DOIUrl":"https://doi.org/10.23960/jemit.v1i3.128","url":null,"abstract":"The effectiveness of guava leaf extract as an inhibitor of St37 carbon steel in a corrosive medium of 3% NaCl had been researched. The concentration of guava leaf extract inhibitor was used 0%. 3%. 5% and 7% with immersion time of 4 and 8 days. Corrosion rate testing was done by weight loss method. The results of the research at each immersion time, showed that the optimum concentration of leaf guava extract to inhibit corrosion is 7% and the longer time immersion resulted in decreasing corrosion rate on St37 carbon steel. The maximum effectiveness of inhibitor occurred at 7% concentration with 8 days immersion time which is 70,12%. Characterization using Scanning Electron Microscopy (SEM) in sample St37-4-7 and St37-8-7 not all surfaces corroded, but on samples St37-4-0 and St37-8-0 almost all samples were corroded. This is reinforced with eds results in which sample St37-8-0 and St37-4-0 have a lower FeO content than sample St37-8-7 and St37-4-7. The X-Ray Diffraction (XRD) result shows that the phase was Fe.","PeriodicalId":15738,"journal":{"name":"Journal of Energy, Material, and Instrumentation Technology","volume":"30 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73853796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analisis Potensi Energi Listrik Pikohidro dari Sumber Air Pegunungan Serta Upaya Peningkatan Daya Listrik dengan Memanfaatkan Rangkaian Joule Thief 分析山水区Pikohidro电能的潜力,并通过利用Joule Thief系列来增加电力
Pub Date : 2020-11-30 DOI: 10.23960/JEMIT.V1I3.32
A. Soleh, Amir Supriyanto, Arif Surtono
The research about picohydro power plant system has been developed in recent years. However, there is a problem in output power when using too small water debit on it. Output power can improved with a generator module and joule thief module. The generator module uses a turbine that the diameter is 4 cm to drive a permanent magnet generator while the joule thief module consists of a charger controller to control charging process of battery, 3200 mAh lithium-ion battery for storing electric power generated by the generator and a joule thief circuit to increase the electrical power that stored in the battery. This device has been tested by using 7 variations of water debit that is 0.06 liters/second, 0.066 liters/second, 0.071 liters/second, 0.077 liters/second, 0.093 liters/second, 0.138 liters/second, and 0.14 liters/second. The results showed that the increasement of power generated when water debit are increased. The maximum power generated in this power generation system is 7.75 W and its able to supply power for LED lights 220 V 3 W for 165 minutes.
近年来,人们对水力发电系统的研究得到了很大的发展。但是,当使用过小的水借时,会出现输出功率的问题。输出功率可以提高与发电机模块和焦耳小偷模块。发电机模块采用直径为4厘米的涡轮驱动永磁发电机,焦耳小偷模块由控制电池充电过程的充电器控制器、存储发电机产生的电能的3200毫安锂离子电池和增加存储在电池中的电能的焦耳小偷电路组成。本装置采用0.06升/秒、0.066升/秒、0.071升/秒、0.077升/秒、0.093升/秒、0.138升/秒、0.14升/秒等7种不同的用水量进行了测试。结果表明,随着用水量的增加,发电量也随之增加。该发电系统的最大功率为7.75 W,可为LED灯供电220v 3w,持续165分钟。
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引用次数: 0
Analisis Suhu Dan Konsentrasi Karbondioksida dalam Kotak Pendingin Terhadap Susut Bobot dan Umur Simpan Buah Nanas (Ananas Comosus L. Merr) Berbasis MIT App Inventor 2 基于麻省理工学院应用程序开发者2的冷箱中二氧化碳的温度和浓度的分析
Pub Date : 2020-11-30 DOI: 10.23960/JEMIT.V1I3.31
Yulinda Nugraeni, Sri Wahyu Suciyati, Gurum Ahmad Pauzi, Amir Supriyanto
Shrinkage of weight loss and shelf life of pineapples is influenced by high temperatures and CO2 concentrations. This study aims to analyze the influence of temperature and CO2 concentration on weight loss and shelf life pineapple in a fridge cooler. The analysis data is obtained from a monitoring tool that has even the ESP8266 module to connect the Arduino with wifi through an application made with MIT App Inventor 2 so that data can be displayed with android. The downside of this application is that if the cellular data network is weak or non-existent, data recording will stop. The results showed that the monitoring tool was able to send data successfully. During data collection, the temperature was 7.82oC - 11.05oC, the CO2 concentration was 457.20 ppm - 490.77 ppm, the weight loss on ripe pineapple was 1.84%, 2.63%, and the weight loss on raw fruit 1.36% - 3.52%. Then from these data the CO2 concentration affects the respiration process, respiration affects the decay process. Whereas temperature affects the physical changes of pineapple fruit so that the shelf life of pineapples can last up to 22 days.
高温和二氧化碳浓度对菠萝的减重收缩和保质期有影响。本研究旨在分析温度和CO2浓度对菠萝在冰箱冷藏箱中的减重和保质期的影响。分析数据来自一个监控工具,该工具甚至有ESP8266模块,通过MIT App Inventor 2制作的应用程序将Arduino与wifi连接起来,以便与android一起显示数据。这个应用程序的缺点是,如果蜂窝数据网络很弱或不存在,数据记录将停止。结果表明,该监控工具能够成功发送数据。采集过程中,温度为7.82℃~ 11.05℃,CO2浓度为457.20 ppm ~ 490.77 ppm,成熟菠萝失重1.84%、2.63%,生果失重1.36% ~ 3.52%。从这些数据来看,二氧化碳浓度影响呼吸过程,呼吸作用影响衰变过程。而温度会影响菠萝果实的物理变化,因此菠萝的保质期可以长达22天。
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引用次数: 0
Monitoring Data Perubahan Suhu, CO dan CO2 Secara Real Time Menggunakan MySQL 监测数据Perubahan, CO dan CO2 Secara实时Menggunakan MySQL
Pub Date : 2020-08-31 DOI: 10.23960/JEMIT.V1I2.25
Randi Setiawan, W. Warsito, J. Junaidi, Sri Wahyu Suciyati
This research is related to making a system to display data on temperature changes, CO, and CO2 monitoring results in real time make use of MySQL. The measuring instrument used consisted of an MQ-7 sensor to detect CO gas, a MQ-135 sensor to detect CO2 gas, a DHT-22 sensor to measure the temperature and a microcontroller as a control system. Measurement data is displayed on the PC server using an interface created through the Visual Basic 2010 program and saved to the Mysql database. In this research, a baudrate of 19200 bps was used so that data transmission could be faster so that it supported realtime data transmission. Based on the research, it was found that the greater the boudrate value used, the faster time it takes to send data. In this study, a baudrate of 19200 bps was used so that data transmission could be faster so that it supported realtime data transmission. Based on the research, it was found that the greater the boltrate value used, the faster time it takes to send data. Based on the results of tests conducted, MySQL monitoring system is running well. The MySQL can display data on temperature changes, CO, and CO2 measurement data in the form of tables in real time.
本课题的研究是利用MySQL实现一个实时显示温度变化数据、CO和CO2监测结果的系统。所使用的测量仪器由MQ-7传感器检测CO气体,MQ-135传感器检测CO2气体,DHT-22传感器测量温度和微控制器作为控制系统组成。测量数据通过Visual Basic 2010程序创建的界面显示在PC服务器上,并保存到Mysql数据库中。本研究采用19200bps的波特率,使数据传输速度更快,支持实时数据传输。通过研究发现,使用的边界值越大,发送数据的时间越快。本研究采用19200bps的波特率,使数据传输速度更快,支持实时数据传输。通过研究发现,使用的boltrate值越大,发送数据的时间就越快。从测试结果来看,MySQL监控系统运行良好。MySQL可以以表的形式实时显示温度变化、CO和CO2测量数据。
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引用次数: 1
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Journal of Energy, Material, and Instrumentation Technology
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