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Chemical stability and environmental characterization of alkali-activated mine tailings generated using a MgCO3/MgO industrial residue MgCO3/MgO工业渣碱活化尾矿的化学稳定性及环境特性
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-22 DOI: 10.1016/j.gexplo.2025.107886
Antonio J. Diosdado-Aragón , José Miguel Dávila , Manuel A. Caraballo
Mining tailings are commonly combined with ordinary Portland cement (OPC) and water to form a paste used for mine gallery backfilling (MGBF). Although OPC remains the most frequent choice, alternative alkaline reagents such as Mg(OH)2 are being investigated due to several limitations: its high cost, a significant carbon footprint associated with its production, and limited long-term durability, especially because of its vulnerability to sulfate attack. This study examines how the use of a MgCO3/MgO industrial residue affects the environmental behavior of alkali-activated pastes in a wide range of mine tailings (MTs), considering the results obtained from different tests: ABA test, leaching test according to UNE 12457-4 and uniaxial compressive strength (UCS) tests. Various paste formulations were generated using different MgCO3/MgO concentrations and six very different types of MTs spanning a wide range mineralogical, chemical and acid potential characteristic. As a main conclusion, all alkali-activated pastes, when compared with the original MTs, showed a very important improvement of their environmental behavior, marked by a consistent reduction of their acid generation potential, a water quality improvement of their leachates and their new consideration of inert wastes according to the European regulation for waste acceptance at landfills. While dynamic long-term leaching experiments and reactive transport geochemical models are advisable to better understand the behavior of these type of mine residues under real conditions and in the long term (decades to centuries); the present study shows how the combined application of ABA and UNE 12457-4 tests can offers a reliable initial environmental characterization of alkali-activated mine pastes.
矿山尾矿通常与普通硅酸盐水泥(OPC)和水混合成膏体,用于巷道回填(MGBF)。尽管OPC仍然是最常用的选择,但由于以下几个限制,人们正在研究替代碱性试剂,如Mg(OH)2:成本高,生产过程中碳足迹大,长期耐用性有限,特别是因为它容易受到硫酸盐的侵蚀。本研究考察了MgCO3/MgO工业残留物的使用如何影响各种尾矿(mt)中碱活性膏体的环境行为,并考虑了不同试验的结果:ABA试验、UNE 12457-4的浸出试验和单轴抗压强度(UCS)试验。使用不同的MgCO3/MgO浓度和六种非常不同类型的MTs生成不同的膏体配方,这些MTs具有广泛的矿物学,化学和酸势特征。作为一个主要结论,所有碱活化膏体,与原来的mt相比,表现出非常重要的改善其环境行为,其标志是其产酸潜力的持续减少,其渗滤液的水质改善以及根据欧洲垃圾填埋场废物接收法规对惰性废物的新考虑。动态长期浸出实验和反应输运地球化学模型可以更好地理解这类矿渣在实际条件下和长期(几十年至几百年)的行为;本研究表明,ABA和UNE 12457-4试验的联合应用如何能够为碱活化矿膏提供可靠的初始环境表征。
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引用次数: 0
Metallogenic process of the metasedimentary rock-hosted HREE deposit at Guangshui (Hubei Province, Central China) 湖北广水变质沉积岩型三稀土矿床成矿过程
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-20 DOI: 10.1016/j.gexplo.2025.107880
Cheng-Lai Deng , Shao-Yong Jiang , Xue-Wen Yuan , Hui-Min Su , Wei Wang
Guangshui (Hubei Province, Central China) is an exceptional heavy rare earth element (HREE) deposit that occurred within a series of metasedimentary rock (e.g. leptynite). This study integrates detailed petrography with in situ U-Pb geochronology, Nd isotope systematics, and mineral chemistry of the principal REE phases—gadolinite, fergusonite, monazite and xenotime—to reconstruct the timing, sources and mechanisms of mineralization. Two generations of each mineral are recognized on the basis of crystal habit and paragenesis: Gad-I/II, Fgs-I/II, Mnz-I/II, Xtm-I/II. U-Pb dating of Mnz-I yields an age of 239 ± 13 Ma, while Xtm-I records 210 ± 6 Ma. These ages coincide with prograde and retrograde stages of Triassic high-grade metamorphism in the Dabie orogen, underscoring a direct link between regional metamorphism and HREE mobilization. Petrological observations indicate that the Mnz-I marks the crystallization of the earliest HREE assemblage (Fgs-I + Gad-I), whereas Xtm-I brackets the final stage of HREE mineralization. Geochemical variations between the two mineral generations are evident. Mnz-I and Mnz-II exhibit low Th contents, consistent with a hydrothermal origin. Mnz-II is spatially associated with Xtm-II, and its pronounced HREE enrichment coincides with HREE depletion from Xtm-I to Xtm-II, suggesting that Xtm-II formed via alteration of Xtm-I. Positive Ce anomalies in Fgs-I and Gad-I suggest crystallization under oxidizing conditions. Combined with petrological evidence and geochemical variation, the composition of Gad-II may have affected by coeval hydrothermal zircon crystallization. For Fgs-II, hydrothermal alteration likely facilitated substitution of LREE and Ca for HREE and Y at the A-site. Nd isotope compositions of Mnz-I (εNd(t) = −5.1 to −5.6; TDM2 = 1.38–1.43 Ga) and Mnz-II (εNd(t) = −4.8 to −5.8; TDM2 = 1.38–1.45 Ga) indicate a crustal source for the ore-forming materials, most likely derived from Mesoproterozoic rocks. Regionally, the phosphorus-rich Huangmailing Formation and Triassic metamorphism played critical roles in HREE enrichment. Overall, the Guangshui deposit exemplifies HREE mineralization controlled by metamorphism and fluid–rock interaction during continental collision, firmly tying its metallogenesis to the Triassic evolution of the Dabie orogen.
湖北广水是一个特殊的重稀土矿床,赋存于一系列变质沉积岩(如瘦斑岩)中。本研究结合详细的岩石学、原位U-Pb年代学、Nd同位素系统学和主要稀土相(钆长石、褐长石、单氮石和xenotime)的矿物化学,重建了成矿的时间、来源和机制。根据晶体习性和共生关系,每种矿物可分为两代:Gad-I/II、gs- i /II、Mnz-I/II、Xtm-I/II。Mnz-I的U-Pb年龄为239±13 Ma,而Xtm-I的年龄为210±6 Ma。这些年龄与大别造山带三叠纪高变质作用的进、退阶段相吻合,表明区域变质作用与三稀土元素活动有直接联系。岩石学观察表明,Mnz-I标志着最早的HREE组合结晶(fg - i + Gad-I),而Xtm-I则标志着HREE成矿的最后阶段。两代矿物之间的地球化学差异是明显的。Mnz-I和Mnz-II的Th含量较低,与热液成因一致。Mnz-II与Xtm-II存在空间关联,其明显的HREE富集与从Xtm-I到Xtm-II的HREE耗竭相吻合,表明Xtm-II是由Xtm-I的蚀变形成的。gs- 1和gad - 1的正Ce异常提示在氧化条件下结晶。结合岩石学证据和地球化学变化,认为Gad-II的组成可能受到同时期热液锆石结晶的影响。对于gs- ii,热液蚀变可能促进了LREE和Ca取代了a位的HREE和Y。Mnz-I的Nd同位素组成(εNd(t) =−5.1 ~−5.6;TDM2 = 1.38 - -1.43 Ga)和Mnz-II(εNd (t) =−4.8−5.8;TDM2 = 1.38 ~ 1.45 Ga)表明成矿物质可能来源于中元古代岩石。从区域上看,富磷黄麦岭组和三叠系变质作用对稀土元素富集起关键作用。综上所述,广水矿床是受大陆碰撞过程中变质作用和流-岩相互作用控制的稀土矿化矿床,其成矿作用与大别造山带三叠纪演化密切相关。
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引用次数: 0
Ore-forming process and fluid development at Nanpo Au deposit, Luang Prabang-Loei Belt (NW Laos): Evidence from H-O-S-Pb isotopes and inclusions 老挝琅勃拉邦-洛伊带南坡金矿成矿过程与流体发育:来自H-O-S-Pb同位素和包裹体的证据
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-20 DOI: 10.1016/j.gexplo.2025.107883
Wei Wang , Hui Li , Jie Gan , Fuhao Xiong , Yu Gan , Bin Wang , Junqing Mu , Huan Liu
The Luang Prabang-Loei tectonic belt, as a significant polymetallic metallogenic belt within the Southeast Asian Tethys tectonic domain, hosts numerous gold deposits. However, the current understanding of the genetic types and mineralization processes of these gold deposits remains insufficient, which restricts the advancement of regional metallogenic theories. This study focuses on the newly discovered large-scale Nanpo gold deposit in this metallogenic belt. By systematically conducting analyses of ore deposit geological characteristics, fluid inclusion testing, and H-O-S-Pb isotope analyses, it aims to reveal the sources of ore-forming materials, clarify the properties and evolutionary patterns of ore-forming fluids, and further elucidate the genetic mechanism and the process of mineralization of the deposit. The orebodies of the Nanpo gold deposit typically have lenticular, stratoid, and veined shapes, which are clearly controlled by ductile shear zones. The ores are mainly of two types: quartz vein type and altered rock type. Based on the interpenetrating relationship of veins and the symbiotic assembly of minerals, the metallogenic process of the Nanpo gold deposit can be divided into three stages: (I) quartz-sericite-gold-poor pyrite stage, (II) quartz-polymetallic sulphide stage, and (III) quartz-carbonate mineral stage. With the help of studies on fluid inclusion petrography, microscopic thermometry and laser Raman spectroscopy, it can be found that there are three main types of fluid inclusions in the deposit, namely, NaCl-H2O, NaCl-CO2-H2O and pure CO2. In general terms, they are part of a NaCl - H2O - CO2 ± CH4 ± N2 low-temperature to intermediate-temperature/low-salinity fluid system. Using the isotopes S-Pb can be seen, the ore - forming materials come to a large extent from the homogenized lower crust - upper mantle. The H - O isotopes suggest that the ore - forming fluids were of metamorphic water which had an affinity to meteoric waters in the later stage. These evidences suggest that the Nanpo gold deposit is a typical orogenic gold deposit, and its formation is closely associated with the collisional orogeny in Indo - China block after the Paleo — Tethys closed. This study provides a theoretical foundation for the advancement of regional metallogenic theories and offers guidance for regional mineral exploration.
Luang Prabang-Loei构造带是东南亚特提斯构造域中重要的多金属成矿带,拥有大量金矿床。然而,目前对这些金矿床的成因类型和成矿过程认识不足,制约了区域成矿理论的发展。本文以该成矿带新发现的大型南坡金矿床为研究对象。系统开展矿床地质特征分析、流体包裹体测试、H-O-S-Pb同位素分析,揭示成矿物质来源,明确成矿流体性质及演化模式,进一步阐明矿床的成因机制和成矿作用过程。南坡金矿床矿体具有典型的透镜状、层状和脉状矿体,明显受韧性剪切带控制。矿石主要为石英脉型和蚀变岩型两种类型。根据矿脉互穿关系和矿物共生组合,将南坡金矿床成矿过程划分为3个阶段:(1)石英—绢云母—贫金黄铁矿阶段、(2)石英—多金属硫化物阶段和(3)石英—碳酸盐矿物阶段。通过流体包裹体岩石学、显微测温和激光拉曼光谱研究发现,矿床中流体包裹体主要有3种类型,分别为NaCl-H2O、NaCl-CO2-H2O和纯CO2。一般来说,它们是NaCl - H2O - CO2±CH4±N2低温到中温/低盐度流体体系的一部分。利用S-Pb同位素可以看出,成矿物质在很大程度上来自均质化的下地壳-上地幔。氢氧同位素表明成矿流体为变质水,后期与大气水有亲缘关系。这些证据表明,南坡金矿床是典型的造山带型金矿床,其形成与古特提斯闭合后印支地块的碰撞造山作用密切相关。该研究为区域成矿理论的发展提供了理论基础,对区域矿产勘查具有指导意义。
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引用次数: 0
Genesis and magmatic-hydrothermal evolution of the Silurian Pingtan W deposit, Nanling Range, South China: Constraints from scheelite and apatite geochemistry and geochronology 南岭志留系平潭钨矿成因及岩浆-热液演化:来自白钨矿和磷灰石地球化学及年代学的制约
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-20 DOI: 10.1016/j.gexplo.2025.107884
Hongfei Di , Yong-Jun Shao , David Chew , Jian-Feng Chen , Wen-Jie Fang , Yi-Qu Xiong
A cluster of Silurian W mineralization events have been reported in South China but the ore-forming processes remain not well-constrained, impeding a comprehensive understanding of deposit genesis and hindering the deployment of further exploration programs. In this study, we examine the newly discovered Silurian Pingtan W deposit as a case study. We undertook a comprehensive study of microtextures and geochemistry on scheelite and apatite, and U–Pb geochronology on apatite to determine the timing of W mineralization as well as the origin and evolution of the ore-forming fluids. Based on BSE and CL images, we identify two types of scheelite (Sch) and apatite (Ap): Sch A (A1 and A2) and Ap I in the altered granite-scheelite stage, and Sch B (B1 and B2) and Ap II in the quartz-scheelite stage. The Mo contents and Eu/Eu* ratios of multi-stage scheelite suggest a decrease in fluid fO2 from the early to late stages within each mineralization phase. The Eu/Eu* ratios of multi-stage apatite indicate an increase in fluid fO2 from the altered granite-scheelite stage to the quartz-scheelite stage. The Y/Ho ratios of these phases of apatite and scheelite growth imply that the initial fluids originated from the host porphyritic biotite monzogranite, and early-stage apatite crystallization led to the depletion of Y and Ho in scheelite. A support vector machine biplot shows that Ap I is magmatic in origin, while Ap II is hydrothermal in origin. The hydrothermal Ap II yields a U–Pb age of 433.7 ± 9.7 Ma (2σ, MSWD = 1.9), aligning with the emplacement ages (431–430 Ma) of the porphyritic biotite monzogranite. These data imply that the Pingtan W deposit represents a typical altered-granite type W deposit genetically linked to its host Silurian porphyritic biotite monzogranite. In addition, the estimated F and Cl contents in melt and fluid based on their contents in apatite indicate that the volatile-rich altered porphyritic biotite monzogranite has great W mineralization potential. Considering previous studies on the Silurian W mineralization, we propose that the Silurian may represent another significant period for W mineralization in South China, with contemporaneous highly evolved and volatile-rich granites serving as a new exploration target for W deposits.
华南地区已报道了一系列志留系W型成矿事件,但成矿过程仍未得到很好的约束,这阻碍了对矿床成因的全面认识,并阻碍了进一步勘探计划的部署。本文以新发现的志留系平潭钨矿为例进行了研究。对白钨矿和磷灰石进行了显微结构和地球化学综合研究,对磷灰石进行了U-Pb年代学研究,确定了钨的成矿时间、成矿流体的起源和演化。根据BSE和CL图像,确定了白钨矿(Sch)和磷灰石(Ap)两种类型:蚀变花岗岩白钨矿阶段的Sch A (A1和A2)和Ap I,以及石英白钨矿阶段的Sch B (B1和B2)和Ap II。多期白钨矿Mo含量和Eu/Eu*比值表明,各成矿期流体fO2由早到晚呈递减趋势。多期磷灰石Eu/Eu*比值表明,从蚀变花岗白钨矿期到石英白钨矿期,流体fO2增加。磷灰石和白钨矿生长各阶段的Y/Ho比值表明,初始流体来源于寄主斑岩型黑云母二长花岗岩,磷灰石早期结晶导致白钨矿中Y和Ho的耗蚀。支持向量机双标图显示,Apⅰ为岩浆成因,Apⅱ为热液成因。热液Apⅱ的U-Pb年龄为433.7±9.7 Ma (2σ, MSWD = 1.9),与斑岩型黑云母二长花岗岩的侵位年龄(431 ~ 430 Ma)一致。这些资料表明,平潭钨矿床是一个典型的蚀变花岗岩型钨矿床,其成因与寄主志留系斑岩型黑云母二长花岗岩有关。此外,根据磷灰石中F和Cl的含量估算熔体和流体中F和Cl的含量,表明富挥发性蚀变斑岩黑云母二长花岗岩具有较大的W成矿潜力。结合前人对志留系钨成矿作用的研究,我们认为志留系可能是华南钨成矿的另一个重要时期,同时期高演化、富挥发物质的花岗岩可能是钨矿床新的找矿目标。
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引用次数: 0
Airborne hyperspectral mapping and shortwave infrared spectroscopy of white mica from the Baiyanghe uranium district, Northwest China, with applications in exploration 白洋河铀矿区白云母航空高光谱成图与短波红外光谱分析及其勘探应用
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-19 DOI: 10.1016/j.gexplo.2025.107881
Qingjun Xu , Zhixin Zhang , Jing Wang , Ruiwei Li , Chuan Zhang , Yilong Wang , Ding Wu , Fawang Ye
Airborne hyperspectral and shortwave infrared (SWIR) spectroscopy technology has significant advantages and application prospects in the fine identification and mapping of alteration minerals. The white mica spectra contain rich geological information, including the hydrothermal environment in which white mica formed and its relationship with mineralization. How variations in the chemical components, temperature, and pH of hydrothermal fluid constrain the Al–OH wavelengths of white mica in meso-epithermal deposits is still debated. Moreover, the relationships between uranium mineralization and the spectral parameters of white mica in hydrothermal uranium deposits are poorly understood. In this study, we present shortwave infrared airborne spectral imager (SASI) hyperspectral data, SWIR FieldSpec4 hyperspectral data, petrography data, and geochemical data, including those from X-ray diffraction (XRD), electron probe microanalysis (EPMA), and hydrogen and oxygen isotopes, for white mica from the Baiyanghe uranium district. The SASI airborne hyperspectral alteration mineral mapping shows that the distribution of white mica exhibits distinct zoning characteristics. The SWIR and XRD analyses indicate that the alteration minerals are mainly quartz, chlorite, and illite, with Al–OH absorption wavelengths ranging from 2190 nm to 2220 nm. The geochemical compositions indicate an obvious Tschermak substitution in white mica and suggest that variations in the Al–OH wavelengths of white mica are affected mainly by the Fe and Mg contents and Fe/(Fe + Mg) ratios in addition to the wall rock composition and hydrothermal fluid. The presence of Al-rich (Si-poor) white mica with a shorter Al–OH wavelength at approximately 2200 nm indicates a relatively high-temperature and acidic hydrothermal environment. In contrast, the presence of Al-poor (Si-rich) white mica with a longer Al–OH wavelength at approximately 2200 nm suggests a relatively low-temperature and neutral hydrothermal environment. In addition, white micas close to uranium mineralization in the northern contact zone between the Yangzhuang granite porphyry and the Devonian intermediate–acid volcanic rocks of the Baiyanghe uranium district have shorter Al–OH wavelengths, greater illite spectral maturity index (ISM) values, and lower full width at half maximum at approximately 2200 nm (FWHM2200) values than those not associated with uranium mineralization. The spatial distributions and variations in the Al–OH wavelengths, ISM values, and FWHM2200 values for white mica suggest that a hydrothermal mineralization center may be located in the northern contact zone, indicating that white mica can be used as an important indicator of alteration minerals for uranium exploration in the Xuemisitan uranium metallogenic belt or other hydrothermal deposits.
航空高光谱与短波红外(SWIR)光谱技术在蚀变矿物精细识别与填图中具有显著的优势和应用前景。白云母光谱包含丰富的地质信息,包括白云母形成的热液环境及其与成矿作用的关系。热液流体的化学成分、温度和pH值的变化如何限制中低温热液矿床中白色云母的Al-OH波长仍然存在争议。此外,热液铀矿床中白色云母光谱参数与铀矿化的关系尚不清楚。利用短波红外机载光谱成像仪(SASI)高光谱、SWIR FieldSpec4高光谱、岩石学、x射线衍射(XRD)、电子探针微量分析(EPMA)、氢、氧同位素等地球化学数据对白洋河铀矿区的白色云母进行了研究。SASI航空高光谱蚀变矿物填图显示,白云母的分布具有明显的分带特征。SWIR和XRD分析表明,蚀变矿物主要为石英、绿泥石和伊利石,Al-OH吸收波长在2190 ~ 2220 nm之间。白云母的地球化学组成显示出明显的Tschermak取代,表明白云母的Al-OH波长变化主要受Fe、Mg含量和Fe/(Fe + Mg)比值的影响,此外还受围岩组成和热液的影响。富al(贫si)白云母的存在,其Al-OH波长较短,约为2200 nm,表明其存在相对高温的酸性热液环境。相比之下,贫铝(富硅)白云母的存在,其Al-OH波长较长,约为2200 nm,表明存在相对低温和中性的热液环境。此外,白洋河铀矿区阳庄花岗斑岩与泥盆系中酸性火山岩北部接触带靠近铀矿化的白色云母Al-OH波长较短,伊丽石光谱成熟度指数(ISM)值较大,在约2200 nm处半最大值全宽(FWHM2200)值较低。白云母Al-OH波长、ISM值和FWHM2200值的空间分布和变化表明,北接触带可能存在热液成矿中心,表明白云母可作为雪米斯滩铀成矿带或其他热液矿床蚀变矿物的重要指示物。
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引用次数: 0
The lithium mineralization potential of Pan-African pegmatites in Mozambique 莫桑比克泛非伟晶岩的锂成矿潜力
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-08-19 DOI: 10.1016/j.gexplo.2025.107882
Violeta Lavínia Bunzula , Axel Müller , Muriel Erambert , Valby van Schijndel , Bernhard Schulz , Jens Götze , Sabine Gilbricht , Jiří Sláma , Siri Simonsen
The Pan-African rare-element pegmatites of the Alto Ligonha Pegmatite District in northern Mozambique contain abundant Li-rich micas and primary Li aluminosilicates, such as spodumene. Given the rising global demand for Li in the manufacture of Li-ion batteries, these pegmatites are viewed as potential hard rock sources of Li. In this study, five pegmatites from the Alto Ligonha region were investigated to gain a better understanding of the fractionation processes of pegmatite melts that lead to Li enrichment and to assess the economic potential of the Li mineralization. Mica, quartz, and spodumene collected from various zones within these pegmatites were analyzed. Contents of Li, Rb, Cs, Ta, and Tl in mica and of Li and Al in quartz reveal a very strong internal fractionation of the pegmatite melt with progressing crystallization. Li2O contents in micas increase from 0.1 to 1.4 wt% in the wall zones, to 0.3–1.7 wt% in the intermediate zones, to 1.5–3.8 wt% in the core zones and up to 5.4 wt% in the core zone pockets. Using known mica/melt Li partition coefficients, the Li contents of the melt at the initial crystallization stage was calculated to be between 315 and 3910 ppm for the Li-rich pegmatites. The Li saturation of about 5000 ppm in respect to spodumene crystallization was exceeded for most pegmatites at the final core-zone crystallization. The theoretical calculations confirm field observations that spodumene occurs in pegmatite core zones only. The analyzed spodumene show low and variable bulk Li2O contents between 1.2 and 3.0 wt%. The low Li contents in spodumene are mainly the result of kaolinization due to tropical weathering. The final deposition of the released Li, however, could not be identified. Inferred resource calculations revealed that the investigated pegmatites contain low Li2O tonnages. However, spodumene as well as Li-rich mica might be mined selectively as a by-product of gemstone and columbite-tantalite mining.
莫桑比克北部Alto Ligonha伟晶岩区泛非稀有元素伟晶岩含有丰富的富锂云母和原生锂铝硅酸盐,如锂辉石。鉴于锂离子电池制造对锂的全球需求不断上升,这些伟晶岩被视为锂的潜在硬岩来源。本文对上利贡尼亚地区的5种伟晶岩进行了研究,以更好地了解导致Li富集的伟晶岩熔体分选过程,并评估Li矿化的经济潜力。分析了从这些伟晶岩的不同区域收集的云母、石英和锂辉石。云母中Li、Rb、Cs、Ta、Tl含量和石英中Li、Al含量显示出极强的晶化过程。云母中Li2O含量在岩壁区增加0.1 ~ 1.4 wt%,在中间区增加0.3 ~ 1.7 wt%,在核心区增加1.5 ~ 3.8 wt%,在核心区袋状区增加5.4 wt%。利用已知的云母/熔体Li分配系数,计算出富锂伟晶岩熔体在初始结晶阶段的Li含量在315 ~ 3910 ppm之间。大部分伟晶岩在岩心区最终结晶时,锂辉石结晶的锂饱和度超过了5000 ppm左右。理论计算证实了锂辉石只存在于伟晶岩核心区的野外观测结果。所分析的锂辉石Li2O含量低且多变,在1.2 ~ 3.0 wt%之间。锂辉石中Li含量低主要是热带风化作用导致高岭土化的结果。然而,李获释后的最终证词无法确定。推断资源计算表明,所调查的伟晶岩含有低Li2O吨数。然而,锂辉石和富锂云母可以作为宝石和铌钽矿开采的副产物选择性开采。
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引用次数: 0
Major, trace, and Rare Earth Element (REE) characteristics of the mentebteb lateritic iron deposit, northern Ethiopia 埃塞俄比亚北部mentebteb红土铁矿床的主要、痕量和稀土元素特征
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-26 DOI: 10.1016/j.gexplo.2025.107869
Teklay Gidey , Miruts Hagos , Yeman Gebru , Bheemalingeswara , Azeb Gebremicale
Rare earth elements (REEs) fractionation and accumulation in Mentebteb lateritic Fe deposits are the key processes with direct implications for REE exploration in weathered terrains. This study investigates the distribution, mobility, and controls on REE behavior across a lateritic weathering profile, using an integrated approach that combines petrographic analysis, X-ray Powder Diffraction (XRD), and geochemical techniques such as Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The profile is divided into three main horizons: a lateritic iron horizon, a clay-rich lateritic horizon, and ferruginous sandstone. In the lateritic iron horizon, hematite is identified as the dominant Fe-bearing mineral, with subordinate goethite and accessory quartz, feldspar, and kaolinite. The Geochemical data reveal that REEs are differentially fractionated and enriched along the profile, with Fe-oxyhydroxides playing a major role in REE accumulation, particularly in the lateritic iron horizon. The positive correlations between Fe, Cr, V, Co, Ni, and ΣLREE/ΣHREE ratios suggest selective sorption and co-precipitation of REEs with Fe phases in the lateritic iron horizon. In contrast, the negative correlation between Al₂O₃ and these elements in the upper lateritic horizon suggests a negligible role of clay minerals in REE retention. However, Al₂O₃ exhibits variable correlations with V (r = 0.27; r = −0.37), Cr (r = 0.61; r = −0.79), Ni (r = 0.52; r = −0.48), and Co (r = 0.65; r = −0.52) in the clay-rich lateritic and ferruginous sandstone layers, indicating that clay minerals influence element mobility in the clay-rich horizon but have minimal impact in the ferruginous sandstone. REE fractionation patterns is evidenced by La/Y ratios is depleted in the lateritic iron horizon (La/Y < 1, 0.87–0.99) and enriched in the clay-rich horizon (La/Y > 1, 1.08–1.36) and ferruginous sandstone (La/Y > 1, 1.27–1.76). These variations in the REE dispersion and fractionation trends are controlled by weathering intensity, redox conditions, acid dissolution, mineral breakdown and differential solubility effects which drive leaching, complexation, and secondary enrichment processes. The observed REE behavior underscores the importance of lateritization in concentrating critical metals and provides geochemical criteria for vectoring towards REE-enriched zones. This study highlights the importance of lateritization processes in REE accumulation and provides a framework for REE exploration in weathered Fe deposits, particularly in lateritic terrains.
稀土元素在Mentebteb红土型铁矿床中的分馏和富集是风化地形中稀土元素勘探的关键过程。本研究利用岩石学分析、x射线粉末衍射(XRD)和地球化学技术(如电感耦合等离子体原子发射光谱法(ICP-AES)和电感耦合等离子体质谱法(ICP-MS))相结合的综合方法,研究了红土风化剖面中稀土元素的分布、迁移率和行为控制。剖面分为三个主要层:红土铁层、富粘土红土层和含铁砂岩层。在红土铁层位,赤铁矿为主要含铁矿物,针铁矿次之,石英、长石、高岭石为辅。地球化学资料显示,稀土元素沿剖面呈差异分异富集,其中铁氧氢氧化物在稀土元素富集中起主要作用,特别是在红土铁层位。Fe、Cr、V、Co、Ni和ΣLREE/ΣHREE比值呈正相关,表明稀土在红土铁层中与Fe相有选择性吸附和共沉淀。而上红土层位Al₂O₃与这些元素的负相关表明粘土矿物对REE的保留作用可以忽略不计。然而,Al₂O₃与V表现出变量相关性(r = 0.27;r =−0.37),Cr (r = 0.61;r =−0.79),Ni (r = 0.52;r =−0.48),Co (r = 0.65;R =−0.52),说明黏土矿物对富粘土层中元素迁移率有影响,但对富粘土层中元素迁移率影响较小。稀土分异模式由La/Y比值在红土铁层位(La/Y <;1, 0.87-0.99),富集于富粘土层(La/Y >;1, 1.08-1.36)和含铁砂岩(La/Y >;1, 1.27 - -1.76)。这些稀土元素分散和分选趋势的变化受风化强度、氧化还原条件、酸溶、矿物分解和差异溶解度效应的控制,这些影响因素驱动浸出、络合和二次富集过程。观察到的稀土元素行为强调了红土化在富集关键金属中的重要性,并为向稀土富集带方向方向提供了地球化学标准。该研究强调了红土化过程在稀土元素聚集中的重要性,并为风化铁矿,特别是红土地的稀土元素勘探提供了框架。
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引用次数: 0
Improving spatial interpolation for anomaly analysis in presence of sparse, clustered or imprecise data sets 改进空间插值的异常分析存在稀疏,聚类或不精确的数据集
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-21 DOI: 10.1016/j.gexplo.2025.107868
Stéphane Belbèze , Jérémy Rohmer , Dominique Guyonnet , Philippe Négrel , Timo Tarvainen
In this study, we present a new method of interpolation and anomaly detection especially designed for sparse, clustered or imprecise environmental data (SIC). Such data cannot be processed by current state of the art spatial methods and models, including the most widely used, such as kriging. Indeed, the statistics obtained on SIC data (on the order of 5–30) do not allow us to define a covariance or to calibrate the numerous hyper-parameters of sophisticated Bayesian or deep image prior models. We therefore adapted an information dissemination algorithm to handle SIC data. This probabilistic model has been enriched (anisotropy, de-clustering, auto-variography, multi-support, treatment of covariates, and censored data) in a way that fully meets the needs for environmental SIC data and can be used in conjunction with hybrid propagation of epistemic and aleatoric uncertainties and anomaly detection, whatever their mathematical form. The new interpolator for anomaly detection was applied on a very small set of 13 sparse data points characteristic of small-scale environmental studies, on digital-challenge datasets and on two real datasets, i.e., a large-scale geochemical dataset and a SIC urban soil dataset. Results highlight the added value of the proposed algorithm, that is able to pinpoint anomalies in SIC data, while avoiding in particular the smoothing effects of certain previous methods.
在本研究中,我们提出了一种专门针对稀疏、聚类或不精确环境数据(SIC)的插值和异常检测新方法。目前最先进的空间方法和模型无法处理这些数据,包括最广泛使用的空间方法和模型,如克里格。事实上,在SIC数据上获得的统计数据(在5-30的数量级上)不允许我们定义协方差或校准复杂贝叶斯或深度图像先验模型的众多超参数。因此,我们采用了一种信息传播算法来处理SIC数据。这种概率模型已经被丰富(各向异性、去聚类、自动变异、多支持、协变量处理和审查数据),以一种完全满足环境SIC数据需求的方式,可以与认知和任意不确定性的混合传播以及异常检测结合使用,无论其数学形式如何。本文将新的异常检测插值器应用于小尺度环境研究的13个稀疏数据点、数字挑战数据集和两个真实数据集,即大尺度地球化学数据集和SIC城市土壤数据集。结果突出了所提出算法的附加价值,即能够精确定位SIC数据中的异常,同时特别避免了某些先前方法的平滑效果。
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引用次数: 0
Indoor radon and its relationship with rock uranium concentration in western Liguria (Italy) 意大利利古里亚西部地区室内氡及其与岩石铀浓度的关系
IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-17 DOI: 10.1016/j.gexplo.2025.107867
Linda Bonorino , Gianluca Beccaris , Paolo Chiozzi , Andrea Cogorno , Elga Filippi , Sonja Prandi , Massimo Verdoya
We recorded indoor radon concentrations in dwellings and measured uranium, thorium and potassium contents in rocks of western Liguria (Italy). This area, characterised by a wide geo-lithological variability with rocks spanning from sedimentary to metasedimentary and metavolcanic, was never deeply investigated for indoor radon or uranium concentration. High levels of indoor radon concentration, exceeding 200 Bq m−3, were recorded in buildings located on the pre-Mesozoic basement that crops out for approximately 65 % of the survey area and shows a maximum average uranium concentration of about 7 mg kg−1. The uranium and the indoor radon concentrations measured on the same lithological groups are strictly correlated. Indoor radon concentrations >200 Bq m−3 are mostly recorded when the rock uranium content exceeds 4.5 mg kg−1. We suggest that the uranium‑radon correlation can be used as an effective baseline for studies of radon potential evaluation.
我们记录了住宅室内氡浓度,并测量了利古里亚西部(意大利)岩石中的铀、钍和钾含量。该地区的特点是地质岩性变化很大,岩石从沉积岩到变质沉积岩和变质火山岩都有,但从未对室内氡或铀浓度进行过深入调查。在位于中生代前基底的建筑物中记录到的室内氡浓度高,超过200 Bq m - 3,约占调查区域的65%,显示出最高平均铀浓度约为7 mg kg - 1。在同一岩性群上测得的铀浓度与室内氡浓度具有严格的相关性。当岩石铀含量超过4.5 mg kg - 1时,室内氡浓度多为200 Bq m - 3。我们认为铀-氡相关性可以作为氡电位评价研究的有效基线。
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引用次数: 0
Corrigendum to “Molybdenum and gold distribution variances within Iranian copper porphyry deposits” [J. Geochem. Explor. 261 (June 2024) 107471] “伊朗铜斑岩矿床中钼和金的分布差异”[J]。Geochem。探索者号。261(2024年6月)107471]
IF 3.3 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2025-07-11 DOI: 10.1016/j.gexplo.2025.107854
Seyed Mehran Heidari , Peyman Afzal , Behnam Sadeghi
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引用次数: 0
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Journal of Geochemical Exploration
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