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Nanoparticles Based Single and Tandem Stable Solar Selective Absorber Coatings with Wide Angular Solar Absorptance 具有广角太阳吸收能力的纳米颗粒单、串联稳定太阳能选择性吸收膜
Pub Date : 2022-08-01 DOI: 10.2139/ssrn.3927616
K. Phani Kumar, S. Mallick, S. Sakthivel
Solar selective absorber coatings with wide angular solar absorptance aids in attaining high photothermal conversion efficiency for solar thermal systems. In this regard, nanoparticles-based absorber coatings were developed on SS 304 by combining the impregnation method, solvothermal process, and dip-coating technique. Developed nanocomposite (SiO 2 nanoparticles in transition metal oxide matrix) based single layer absorber coating with nano void textured surface, exhibits solar absorptance of 0.92 and spectral emittance of 0.12. MgF 2 nanoparticles based anti-reflective layer on single-layer absorber coating improves the solar absorptance to 0.94 by destructive interference mechanism. Both nanoparticles based single and tandem absorber coatings show wide angular solar absorptance of 0.88 and 0.89, respectively, at an incident angle of 50°. Besides, developed absorber coatings show lower thermal emissivity of 0.17 and good photothermal conversion efficiencies at high operating temperatures (400 - 500 °C). These developed absorber coatings offer excellent thermal stability at an open atmospheric condition till operating temperature, such as 400 °C for 100 h. Selective nature with wide angular solar absorptance and low heat loss behaviour of stable absorber coating shows the photothermal conversion efficiency of 91% can improve the performance of receiver tubes in solar thermal systems.
具有广角太阳能吸收率的太阳能选择性吸收涂层有助于太阳能热系统获得较高的光热转换效率。为此,将浸渍法、溶剂热法和浸涂技术相结合,在SS 304上研制了纳米颗粒基吸收剂涂层。研制了纳米复合材料(过渡金属氧化物基体中的二氧化硅纳米颗粒)单层吸收涂层,其表面具有纳米空洞织构,太阳吸收率为0.92,光谱发射率为0.12。单层吸收体涂层上基于mgf2纳米颗粒的减反射层通过相消干涉机制将太阳吸收率提高到0.94。当入射角度为50°时,纳米颗粒单层和串联吸收膜的宽角太阳吸收率分别为0.88和0.89。此外,所开发的吸收剂涂层在高工作温度(400 - 500°C)下具有较低的热辐射率0.17和良好的光热转换效率。这些开发的吸收涂层在开放大气条件下具有优异的热稳定性,直到工作温度,例如400°C 100小时。稳定的吸收涂层具有广角太阳能吸收的选择性和低热损失行为,表明光热转换效率为91%,可以提高太阳能热系统中接收管的性能。
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引用次数: 8
Effects of Climate on Renewable Energy Sources and Electricity Supply in Norway 气候对挪威可再生能源和电力供应的影响
Pub Date : 2022-07-01 DOI: 10.2139/ssrn.3940150
I. Haddeland, J. Hole, E. Holmqvist, V. Koestler, M. Sidelnikova, C. A. Veie, M. Wold
Hydro power inflow, wind power, solar power and electricity demand in Norway are estimated based on meteorological data for the period 1961-2020. The installed capacity of the production technologies is kept constant at 2020 levels throughout the analyses. Correlations within and between power sources, and trends in electricity production and consumption are investigated. Wind power production shows a higher correlation with electricity demand than hydro inflow and solar power at daily and monthly time scales. For wind and solar, correlations between power plants decrease distinctly with distance, whereas for hydro inflow the correlation dependence on distance is less clear. Hydro power inflow shows an increasing trend during the time period studied, and the relative increase is largest during the winter season. Wind and solar power production are only marginally affected by climate differences in the study period. Electricity consumption decreases somewhat during the 60-year period, due to increasing average temperatures. The combined effect is a slightly increasing trend in long term estimated electricity surplus. Although a surplus of electricity exists at the mean annual level, additional available electricity in the form of reservoir storage or import is needed to maintain security of supply within the country.
挪威的水力发电流入、风力发电、太阳能发电和电力需求是根据1961-2020年期间的气象数据估计的。在整个分析过程中,生产技术的装机容量保持在2020年的水平不变。研究了电源内部和之间的相关性以及电力生产和消费的趋势。在日和月时间尺度上,风电发电量与电力需求的相关性高于水电和太阳能发电量。对于风能和太阳能,发电厂之间的相关性随着距离的增加而明显降低,而对于水力入流,对距离的相关性依赖则不太明显。在研究时段内,水电入流呈增加趋势,其中冬季相对增幅最大。在研究期间,风能和太阳能的生产只受到气候差异的轻微影响。由于平均气温上升,60年期间的用电量有所下降。综合影响是长期估计的电力盈余略有增加的趋势。虽然在年平均水平上存在电力过剩,但需要以水库储存或进口的形式提供额外的电力,以维持国内供应的安全。
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引用次数: 4
Thermal Interactions Among Vertical Geothermal Borehole Fields 垂直地热井田的热相互作用
Pub Date : 2022-05-01 DOI: 10.2139/ssrn.3946173
L. Cassina, L. Laloui, A. F. Rotta Loria
Borehole heat exchanger applications are growing every day – so pronouncedly that many borehole fields will likely operate in dense installation areas in the foreseeable future. In these conditions, the thermal interactions that inherently characterize the operation of most borehole heat exchanger fields will have the potential to develop between neighboring fields, with detrimental effects on the performance and efficiency of such installations in the absence of appropriate designs strategies. Currently, insufficient knowledge is accessible on thermal interaction effects among borehole heat exchanger fields and only a few approaches allow to effectively consider such effects in the design of these heat exchangers. This paper expands the limited competence on thermal interaction effects among borehole heat exchanger fields and presents and validates a methodology to facilitate the design of such heat exchangers. With reference to a virtual operation of multiple vertical borehole fields in the Loop district of Chicago, USA, the work highlights significant thermal interactions among neighboring borehole fields. The proposed methodology allows correcting the design of borehole fields to avoid overexploitation of the geothermal resource and the insurgence of litigation cases between geothermal users, representing a powerful approach to cope with thermal interaction effects among geothermal boreholes at scale.
井内热交换器的应用每天都在增长,因此在可预见的未来,许多井内油田可能会在密集的安装区域运行。在这种情况下,大多数井内热交换器作业固有的热相互作用将有可能在邻近油田之间发展,在缺乏适当设计策略的情况下,对此类装置的性能和效率产生不利影响。目前,对于井下换热场之间的热相互作用效应的认识还不够充分,只有少数几种方法能够在井下换热场的设计中有效地考虑这种效应。本文拓展了钻孔换热场间热相互作用效应研究的局限性,提出并验证了一种简化钻孔换热场设计的方法。通过对美国芝加哥Loop地区多个垂直井眼场的虚拟作业,该工作突出了邻近井眼场之间显著的热相互作用。所提出的方法允许纠正钻孔田的设计,以避免地热资源的过度开发和地热用户之间的诉讼案件的爆发,代表了大规模应对地热钻孔之间的热相互作用效应的有力方法。
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引用次数: 3
Efficient Methanol Dehydration to DME and Light Hydrocarbons by Submicrometric ZrO2-ZSM-5 Fibrillar Catalysts with a Shell-Like Structure 壳状结构的亚微米ZrO2-ZSM-5纤维状催化剂催化甲醇脱水制备二甲醚和轻烃
Pub Date : 2022-05-01 DOI: 10.2139/ssrn.3944569
J. Palomo, M. A. Rodríguez-Cano, José Berruezo-García, J. Rodríguez-Mirasol, T. Cordero
Zeolites are widely used in many applications, such as catalysis and adsorption processes. The use of these materials in a nanometric size would be of great interest for these applications, due to the better performance they could exhibit in terms of avoiding intraparticle mass and heat transfer limitations. However, this small particle size results in high pressure drops in adsorption columns and fixed-bed reactors, making these materials non-applicable directly in the nanometric size. In this work, ZrO 2 fibers with a mean size of 275 nm and the presence of small well-defined ZSM-5 zeolite aggregates of 550 nm in size around the ZrO 2 submicrometric fibers, in the form of a shell-like structure, have been prepared by electrospinning technique, which resulted very active for the synthesis of DME and light olefins via methanol dehydration. The submicrometric fibrillar catalysts, without any further modification, could be easily structured inside a fixed-bed reactor, which worked very efficiently in terms of heat and mass transfer, avoiding, at the same time, the usual pressure drops problems of fixed-bed reactors working with catalyst particles of submicrometric size. Methanol conversion and selectivity to DME and light hydrocarbons could be finely controlled, for a given set reaction conditions, by tuning the zeolite loading in the structured catalyst. Apparent kinetic parameters for the selective methanol dehydration to DME were calculated assuming a reversible second order rate expression and an activation energy of 75 kJ/mol was obtained.
沸石在催化和吸附过程中有着广泛的应用。这些材料在纳米尺度上的使用将对这些应用产生极大的兴趣,因为它们在避免颗粒内质量和传热限制方面可以表现出更好的性能。然而,这种小颗粒尺寸导致吸附柱和固定床反应器中的高压降,使这些材料不能直接应用于纳米尺寸。本研究采用静电纺丝技术制备了平均尺寸为275 nm的ZrO - 2纤维,并在ZrO - 2亚微米纤维周围以壳状结构的ZSM-5小沸石聚集体存在,其大小为550 nm,具有良好的定义,对甲醇脱水合成二甲醚和轻烯烃具有很强的活性。这种亚微米级的纤维催化剂,无需任何进一步的修改,可以很容易地在固定床反应器中进行结构设计,这在传热和传质方面非常有效,同时避免了固定床反应器处理亚微米级催化剂颗粒时常见的压降问题。在给定的反应条件下,通过调整结构催化剂中沸石的负载,可以很好地控制甲醇的转化率和二甲醚和轻烃的选择性。采用可逆二阶速率表达式计算了甲醇选择性脱水制二甲醚的表观动力学参数,得到活化能为75 kJ/mol。
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引用次数: 10
Investigating Risks in Renewable Energy in Oil-Producing Countries Through Multi-Criteria Decision-Making Methods Based on Interval Type-2 Fuzzy Sets: A Case Study of Iran 基于区间2型模糊集的多准则决策方法研究产油国可再生能源风险——以伊朗为例
Pub Date : 2022-04-01 DOI: 10.2139/ssrn.3940146
R. Shahnazi, M. Alimohammadlou
Despite the importance of relying on renewable energy sources, oil-producing countries, especially Iran, encounter numerous risks associated with the generation of such energy sources. The present study investigated the risks in renewable energy in Iran. As the first investigation addressing this problem in Iran, the study methodologically improved the probability-impact matrix by employing multi-criteria decision-making (MDCM) methods and using interval type-2 fuzzy sets. The results showed that most important macro-level risks facing Iran’s renewable energy generation were “inflation and price fluctuations”, “corruption”, “complex licensing procedures”, “research and development and the capacity of domestic technology”, “sanctions”, “exchange rate fluctuations”, and “property rights and contractual risks.” Following these macro-level risks, there were important specific risks both in the general field of energy and renewable energy including “geographical risks”, “non-renewable energy prices”, “electricity prices”, “a lack of a coherent renewable energy policy”, “the impact of climate change on revenue rates”, and “financial risks.” To respond to such risks, it would be necessary to formulate coherent and integrated policies.
尽管依赖可再生能源很重要,但石油生产国,尤其是伊朗,在生产可再生能源的过程中遇到了许多风险。本研究调查了伊朗可再生能源的风险。作为伊朗针对该问题的首次调查,该研究通过采用多准则决策(MDCM)方法和区间2型模糊集,在方法上改进了概率-影响矩阵。结果表明,伊朗可再生能源发电面临的最重要的宏观风险是"通货膨胀和价格波动"、"腐败"、"复杂的许可程序"、"研发和国内技术能力"、"制裁"、"汇率波动"和"产权和合同风险"。在这些宏观层面的风险之后,在能源和可再生能源的一般领域还有一些重要的具体风险,包括“地理风险”、“不可再生能源价格”、“电价”、“缺乏连贯的可再生能源政策”、“气候变化对收入率的影响”和“金融风险”。为了应对这些风险,有必要制定连贯和综合的政策。
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引用次数: 5
A Short-Term Wind Powerprediction Model Based on CEEMD and WOA-KELM 基于CEEMD和WOA-KELM的短期风电功率预测模型
Pub Date : 2022-03-01 DOI: 10.2139/ssrn.3915521
Yunfei Ding, Zijun Chen, Hongwei Zhang, Xin Wang, Yingzhuang Guo
Effective short-term wind power prediction is crucial to the optimal dispatching, stability, and operation cost control of a power system. In order to deal with the intermittent and fluctuating characteristics of wind power timing series signals, a hybrid forecasting model is proposed, based on Complementary Ensemble Empirical Mode Decomposition (CEEMD) and Whale Optimization Algorithm (WOA)- Kernel Extreme Learning Machine (KELM), to predict short-term wind power. Firstly, the non-stationary wind power time series is decomposed into a series of relatively stationary components by CEEMD. Then, the components are used as the training set for the KELM prediction model, in which the initial values and thresholds are optimized by WOA. Finally, the predicted output values of each component are superimposed, to obtain the final prediction of the wind power values. The experimental results show that the proposed prediction method can reduce the complexity of the prediction with a small reconstruction error. Furthermore, performance is greater, in terms of prediction accuracy and stability, with lower computational cost than other benchmark models.
有效的风电短期预测是电力系统优化调度、稳定运行和控制运行成本的关键。针对风电时序信号的间歇性和波动性特点,提出了一种基于互补集成经验模态分解(CEEMD)和鲸鱼优化算法(WOA)-核极限学习机(KELM)的混合预测模型,用于短期风电预测。首先,利用CEEMD将非平稳风电时间序列分解为一系列相对平稳的分量。然后,将这些分量作为KELM预测模型的训练集,利用WOA对KELM预测模型的初始值和阈值进行优化。最后将各分量的预测输出值进行叠加,得到最终的风电预测值。实验结果表明,所提出的预测方法可以降低预测的复杂性,且重建误差较小。此外,在预测精度和稳定性方面,与其他基准模型相比,性能更高,计算成本更低。
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引用次数: 48
The Impact of Hourly Pricing for Renewable Generation Projects in Brazil 巴西可再生能源发电项目小时定价的影响
Pub Date : 2022-03-01 DOI: 10.2139/ssrn.3940148
Isabella Marchetti, E. E. Rego
The hourly price of the Brazilian electricity market came into operation in 2021, changing the previous pricing policy that worked in a weekly basis. The impact that this change has on wind and solar generators' business may be a cause for attention, since in an hourly price scenario with collateral and daily financial settlements, wind and solar power generators may be subject to a large financial exposure into the short-term market. Thus, the present article has as its main goal the evaluation of the impact caused on the intrinsic value of wind and solar power projects with the adoption of the new hourly pricing policy in the electricity sector compared to the old weekly pricing policy. To this end, a financial economic model was developed for generic and hypothetical wind and solar farms in the Brazilian electricity sector to find its fair value operating under two different pricing scenarios. The value of these farms was also sensitized through Monte Carlo simulations, after assigning probability distributions for certain model inputs.
巴西电力市场的小时价格于2021年开始运行,改变了之前以周为基础的定价政策。这一变化对风能和太阳能发电业务的影响可能值得关注,因为在有抵押品和每日财务结算的小时价格情景中,风能和太阳能发电可能会受到短期市场的大量金融风险。因此,本文的主要目标是评估在电力部门采用新的小时定价政策与旧的周定价政策相比,对风能和太阳能发电项目内在价值的影响。为此,为巴西电力部门的通用和假设的风能和太阳能发电场开发了一个金融经济模型,以找出其在两种不同定价情景下的公允价值。在为某些模型输入分配概率分布后,这些农场的价值也通过蒙特卡罗模拟敏感化。
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引用次数: 5
Visualization of Interactions between Depressurization-Induced Hydrate Decomposition and Heat/Mass Transfer 减压诱导的水合物分解与传热传质之间相互作用的可视化
Pub Date : 2022-01-01 DOI: 10.2139/ssrn.3888185
Xuan Kou, Jingchun Feng, Xiaosen Li, Yi Wang, Zhaoyang Chen
Visual evidences to understand the interactions between hydrate decomposition and heat/mass transfer are currently lacking. This study proceeds from the hydrate morphology to visualize the interactions between depressurization-induced hydrate decomposition and heat/mass transfer from different scales. Reactor-scale hydrate distribution evolution shows that the dominant influencing factor of hydrate decomposition transforms from heat transfer to mass transfer. More importantly, pore-scale visual evidences suggest that the mass transfer of gas shows significant effects on hydrate morphology evolution. Specifically, the limited gas diffusion in liquid phase could lead to the hydrate morphology evolution from patchy pore-filling to “grain-bridging” during hydrate decomposition. The combination of grain-bridging hydrate together with the water layer that wraps the hydrate is termed as “hydrate bridge” in this work. It is also worth noting that the grain-bridging hydrate could accelerate fluid flow in pores according to our seepage simulation results. These findings may have solved the long-standing problem of the abnormal changing trend of physical properties with the decrease in hydrate saturation during hydrate decomposition by providing direct experimental evidences. Since physical properties of hydrate-bearing sediments play important roles in hydrate decomposition, the hydrate morphology evolution characteristics analyzed here are valuable for hydrate exploitation in field tests.
目前还缺乏直观的证据来理解水合物分解和热/质传递之间的相互作用。本研究从水合物形态出发,从不同尺度上可视化减压诱导的水合物分解与传热传质之间的相互作用。反应器尺度的水合物分布演化表明,影响水合物分解的主要因素由传热向传质转变。更重要的是,孔隙尺度的视觉证据表明,气体的传质对水合物的形态演化有显著的影响。在水合物分解过程中,气体在液相中的有限扩散会导致水合物形态由斑块状孔隙填充向“颗粒桥接”演变。颗粒桥接水合物与包裹水合物的水层的结合在本研究中被称为“水合物桥”。同样值得注意的是,根据我们的渗流模拟结果,颗粒桥接水合物可以加速流体在孔隙中的流动。这些发现提供了直接的实验证据,解决了长期存在的水合物分解过程中物性随水合物饱和度降低而出现异常变化趋势的问题。由于含水合物沉积物的物理性质对水合物的分解起着重要作用,因此本文所分析的水合物形态演化特征对水合物的现场开采具有一定的指导意义。
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引用次数: 11
Simulation of Two In-Line Wind Turbines Using an Incompressible Finite Volume Solver Coupled with a Blade Element Model 用不可压缩有限体积求解器耦合叶片单元模型对两台直列风力机进行仿真
Pub Date : 2021-12-01 DOI: 10.2139/ssrn.3887455
B. Elie, G. Oger, L. Vittoz, D. Le Touzé
The present study addresses the first steps of development and validation of a coupled Finite Volume-Blade Element Model (FV-BEM) simulation tool dedicated to offshore wind turbine farm modeling. The fluid domain is solved using the incompressible formulation of the CFD solver Grid-flow. The turbines are taken into account using FAST (from NREL) and their effects are imposed into the fluid domain through an actuator line model (ALM) for which specific enhancements are proposed. The Grid-flow solver and its two-way coupling with the aero-elastic modules from FAST is introduced and detailed. The simulation of the case of two in-line wind turbines using the FV-BEM coupling proposed is presented, together with comparisons against experimental results for validation purposes. Finally, a discussion on performances, advantages and limitations of the formulation proposed is provided.
本研究解决了开发和验证有限体积-叶片单元模型(FV-BEM)耦合仿真工具的第一步,该工具专门用于海上风力发电场建模。采用CFD求解器网格流的不可压缩公式求解流体域。使用FAST(来自NREL)考虑涡轮机,并通过执行器线模型(ALM)将其影响施加到流体域,并提出了具体的增强功能。详细介绍了FAST中网格流求解器及其与气动弹性模块的双向耦合。给出了采用FV-BEM耦合的两台直列风力机的仿真结果,并与实验结果进行了比较。最后,对所提出的配方的性能、优点和局限性进行了讨论。
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引用次数: 2
Enhancing Anaerobic Digestion of Pharmaceutical Industries Wastewater with the Composite Addition of Zero Valent Iron (ZVI) and Granular Activated Carbon (GAC) 零价铁(ZVI)与颗粒活性炭(GAC)复合添加强化制药废水厌氧消化
Pub Date : 2021-12-01 DOI: 10.2139/ssrn.3949242
Chenbo Dai, Libin Yang, Jun Wang, Dezhen Li, Yalei Zhang, Xuefei Zhou
Anaerobic digestion of pharmaceutical wastewater is challenged by its contained toxic compounds which limits the stability and efficiency of methane production and organic degradation. In this study, zero valent iron (ZVI) and granular activated carbon (GAC) were added with different strategies to improve anaerobic digestion of pharmaceutical wastewater. The results confirmed synergy effects of ZVI+GAC for both COD removal (increased by 13.4%) and methane production (increased by 11.0%). Furthermore, ZVI+GAC improved the removal of pharmaceutical intermediates, in particular, the residues (%) of dehydroepiandrosterone (DHEA) and 2,2'-methylenebis(6-tert-butyl-4-methylphenol) were only 30.48 ± 6.53 and 39.92 ± 4.50, and effectively reduced biotoxicity. The promoted results were attributed to the establishment of direct interspecies electron transfer (DIET). Microbial community analysis revealed that ZVI+GAC decreased species evenness and richness in bacterial whereas increased in archaeal. The relative abundance of acetotrophic methanogens decreased but hydrogenotrophic and methylotrophic methanogens increased, which broadening the pathway of methane production.
制药废水的厌氧消化受到其含有有毒化合物的挑战,这限制了甲烷生产和有机降解的稳定性和效率。以零价铁(zero valent iron, ZVI)和颗粒活性炭(granular activated carbon, GAC)为研究对象,通过不同的添加策略改善制药废水的厌氧消化。结果证实了ZVI+GAC对COD去除率(提高13.4%)和甲烷产量(提高11.0%)的协同效应。ZVI+GAC提高了对药物中间体的去除率,特别是脱氢表雄酮(DHEA)和2,2′-亚甲基双(6-叔丁基-4-甲基苯酚)的残留量(%)仅为30.48±6.53和39.92±4.50,有效降低了生物毒性。这一促进结果归因于直接种间电子转移(DIET)的建立。微生物群落分析表明,ZVI+GAC降低了细菌的物种均匀度和丰富度,增加了古细菌的物种均匀度和丰富度。乙营养型产甲烷菌相对丰度降低,氢营养型和甲基营养型产甲烷菌相对丰度增加,拓宽了产甲烷途径。
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引用次数: 19
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