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Kinetic Model and Parameters Optimization for Tangkou Bituminous Coal by the Bi-Gaussian Function and Shuffled Complex Evolution 汤口烟煤动力学模型及参数优化的双高斯函数和shuffle复杂演化
Pub Date : 2021-12-01 DOI: 10.2139/ssrn.3892178
Juan Zhang, L. Sun, Yu Zhong, Yanming Ding, Wenzhou Du, Kaihua Lu, Jia Jia
In this paper, a new kinetic model for thermal degradation of Tangkou bituminous coal was presented. The pyrolysis process was described by the deconvolution method and global optimization algorithm . The sample was investigated in a thermogravimetric analyzer at the heating rates of 10, 20, 40 and 60 K/min in nitrogen. The reaction curves of each stage and the contribution of each stage to the total reaction were estimated by the deconvolution method with bi-Gaussian function. The total mass loss was explained as the sum of three stages: main pyrolysis, secondary depolymerization and secondary repolymerization. Then, Friedman and Coats-Redfern methods were used to evaluate the kinetic parameters based on the separated thermogravimetric data at 10, 40 and 60 K/min. These possible regions and obtained parameters provided a guide for the search range and initial value of Shuffled Complex Evolution (SCE) algorithm for the optimal scheme. The optimized results showed that the experimental curve was in good agreement with the simulation curve, which indicated the reliability of the new scheme. Eventually, the pyrolysis process at 20 K/min was speculated. The good fitting showed the great potential of the proposed three-stage scheme in describing and forecasting the pyrolysis behavior of Tangkou coal.
提出了一种新的唐口烟煤热降解动力学模型。采用反褶积法和全局优化算法对热解过程进行描述。样品在氮中以10、20、40和60 K/min的加热速率在热重分析仪中进行研究。用双高斯函数反褶积法估计了各阶段的反应曲线和各阶段对总反应的贡献。总质量损失可解释为主热解、二次解聚和二次再聚合三个阶段的总和。然后,利用Friedman和Coats-Redfern方法对分离得到的10、40和60 K/min下的热重数据进行动力学参数评估。这些可能区域和得到的参数为shuffle Complex Evolution (SCE)算法的搜索范围和初始值提供了指导。优化结果表明,实验曲线与仿真曲线吻合较好,表明了新方案的可靠性。最后,对20 K/min下的热解过程进行了推测。拟合效果良好,表明所提出的三阶段方案在描述和预测塘口煤热解行为方面具有很大的潜力。
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引用次数: 7
Multi-Objective Optimization of a Microchannel Membrane-Based Absorber with Inclined Grooves Based on CFD and Machine Learning 基于CFD和机器学习的倾斜槽微通道膜基吸收器多目标优化
Pub Date : 2021-12-01 DOI: 10.2139/ssrn.3892177
Zengguang Sui, Yunren Sui, Wei Wu
A novel microchannel membrane-based absorber with inclined grooves is proposed and studied by a three-dimensional CFD model. Parametric analysis is carried out to analyze the effects of structural parameters on the absorption rate and pressure drop. Results indicate that the groove introduces a swirling effect in the solution channel, interrupting the boundary layer at the solution-membrane interface and increasing the solution residence time inside the microchannel. The absorption rate in the grooved channel is up to 1.55 times higher, while the pressure drop is 0.77 -0.96 times lower. To optimize the novel absorber geometries and maximize the integrated performance, the Pareto front is obtained by performing a multi-objective optimization, in which a machine learning method based on ANN and NSGA-II is developed. The optimal design parameters from the Pareto front are identified by two well-known decision-making methods, LINMAP and TOPSIS. Compared to the basic smooth channel, these methods generate 1.41 and 1.47 times improvement in volumetric cooling capacities, at a much lower solution pressure drop. Moreover, a high absorption rate equivalent to that of a 200 mm-thick smooth channel is achieved by LINMAP and TOPSIS, with pressure drops lower by 6.29 and 5.63 times, respectively.
提出了一种新型的倾斜槽微通道膜基吸收器,并对其进行了三维CFD模型研究。通过参数分析,分析了结构参数对吸收率和压降的影响。结果表明,该沟槽在溶液通道中引入了旋流效应,打断了溶液-膜界面的边界层,增加了溶液在微通道内的停留时间。槽状通道的吸收率提高了1.55倍,压降降低了0.77 ~ 0.96倍。为了优化新型减振器的几何形状并使其综合性能最大化,采用基于神经网络和NSGA-II的机器学习方法进行了多目标优化,得到了Pareto前沿。利用LINMAP和TOPSIS两种著名的决策方法从Pareto前沿确定最优设计参数。与基本的光滑通道相比,这些方法在更低的溶液压降下,体积冷却能力提高了1.41倍和1.47倍。此外,LINMAP和TOPSIS获得了相当于200 mm厚光滑通道的高吸收率,压降分别降低了6.29倍和5.63倍。
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引用次数: 13
Catalytic Pyrolysis of Biomass Over Fe-Modified Hierarchical ZSM-5: Insights into Mono-Aromatics Selectivity and Pyrolysis Behavior Using PY-GC/MS and TG-FTIR fe改性ZSM-5催化热解生物质:利用PY-GC/MS和TG-FTIR研究单芳烃选择性和热解行为
Pub Date : 2021-12-01 DOI: 10.2139/ssrn.3872438
Yingkai Li, N. Nishu, Dominic Yellezuome, Meiyun Chai, Chong Li, Ronghou Liu
Abstract Catalytic pyrolysis has recently aroused great interest for the high potential in upgrading bio-oils as renewable energy. However, conventional catalysts often exert diffusion resistance to large intermediate oxygenates. In this study, Fe-modified hierarchical ZSM-5 prepared by alkali and Fe loading of 2, 4, 6, 8 wt% were characterized by the analysis of XRD, BET, TEM, and NH3-TPD. Catalytic pyrolysis of poplar sawdust via Fe-modified hierarchical ZSM-5 was conducted using Py-GC/MS and TG-FTIR. The results indicated that alkali treatment and Fe loading of the catalyst introduced a hierarchical and porous structure and improved its acidity, leading to high mono-aromatics and olefins selectivity. The hierarchical ZSM-5 with 4 wt% Fe loading exhibited superior performance with high selectivity towards mono-aromatics of 15.30%. TG-FTIR analysis shows the volatiles release characteristics and FTIR spectra were consistent with pyrolysis behavior. Kinetic analysis reveals Fe-modified hierarchical ZSM-5 lowers the apparent activation energy in catalytic pyrolysis of poplar sawdust.
摘要催化热解作为一种具有巨大潜力的可再生能源,近年来引起了人们的广泛关注。然而,传统的催化剂往往对大的中间氧化物产生扩散阻力。本文通过XRD、BET、TEM和NH3-TPD等分析手段,对碱、载铁量分别为2、4、6、8 wt%制备的Fe改性层次化ZSM-5进行了表征。采用Py-GC/MS和TG-FTIR对fe改性ZSM-5催化热解杨木木屑进行了研究。结果表明,碱处理和载铁使催化剂具有层次性和多孔性结构,提高了催化剂的酸度,提高了对单芳烃和烯烃的选择性。负载铁重量为4 wt%的分级ZSM-5对单一芳烃的选择性为15.30%,表现出优异的性能。TG-FTIR分析表明,挥发分释放特征和FTIR光谱与热解行为一致。动力学分析表明,fe修饰的分级ZSM-5降低了杨木木屑催化热解的表观活化能。
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引用次数: 26
MoTe2 on Metal-Organic Framework Derived MoO2/N-Doped Carbon Rods for Enhanced Sodium-Ion Storage Properties 金属有机骨架衍生MoO2/ n掺杂碳棒上的MoTe2增强钠离子存储性能
Pub Date : 2021-12-01 DOI: 10.2139/ssrn.3940125
Yi-Jie Zhang, Yingying Gao, Xiaoge Wang, Q. Ye, Ya Zhang, Yuehua Wu, Shu-Han Chen, B. Ruan, D. Shi, T. Jiang, Fangchang Tsai, N. Ma
Sodium-ion batteries (SIBs) are highly potential for next-generation electrochemical energy storage because of their abundant resources and low prices. Transition metal dichalcogenides (TMDCs) have an excellent capacity, high electrical conductivity, and diverse structures. However, its volume expansion and tendency to restack during charge/discharge cycles lead to inferior electrochemical properties, limiting its development in the battery field. Herein, we synthesized MoO2/NC rods covered with MoTe2 nanosheets on the surface (MoTe2@MoO2/NC) by a high-temperature solid-phase synthesis method based on Mo-MOF a sacrificial template for sodium-ion batteries. The MoO2 core enhances the electron transfer efficiency as a conductive backbone and prevents the volume expansion of MoTe2 nanosheets. Meanwhile, the MoTe2 nanosheets are tightly wrapped around the MoO2 core, significantly reducing the ion diffusion path. Furthermore, the C and N doped substrates with conductivity ensure the integrity of the structure and enhance the conductivity of the electrodes. Benefiting from these advantages, MoTe2@MoO2/NC delivered a high electrochemical performance with high capacity (~463.9 mAh g-1), superior fast-charge discharge ability (~294.7, and 258.3 mAh g-1 at 5, and 10 A g-1, respectively). Even at a high current density of 1 A g-1, the specific capacity was maintained at about 328.3 mAh g-1 after 100 cycles.
钠离子电池以其丰富的资源和低廉的价格在新一代电化学储能领域具有很大的应用潜力。过渡金属二硫族化合物(TMDCs)具有优良的容量、高导电性和多种结构。但由于其体积膨胀和在充放电循环过程中的再堆叠倾向,导致其电化学性能较差,限制了其在电池领域的发展。本文采用基于钠离子电池牺牲模板Mo-MOF的高温固相合成方法合成了表面覆盖MoTe2纳米片的MoO2/NC棒(MoTe2@MoO2/NC)。MoO2核心作为导电骨架提高了电子传递效率,防止了MoTe2纳米片的体积膨胀。同时,MoTe2纳米片紧密包裹在MoO2核心周围,大大减少了离子的扩散路径。此外,具有导电性的C和N掺杂衬底确保了结构的完整性并提高了电极的导电性。得益于这些优势,MoTe2@MoO2/NC提供了高电化学性能,具有高容量(~463.9 mAh g-1),卓越的快速充电放电能力(分别在5和10 a g-1下~294.7和258.3 mAh g-1)。即使在1 a g-1的高电流密度下,经过100次循环后,比容量仍保持在约328.3 mAh g-1。
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引用次数: 5
Heterogeneous Policy Effects on the Export of Photovoltaic and Wind Energy Components: Evidence from a Matching Estimator 异质政策对光伏和风能组件出口的影响:来自匹配估计器的证据
Pub Date : 2021-05-12 DOI: 10.2139/ssrn.3875190
Yasuhiro Ogura
The vast dissemination of renewable energy (RE) has been enhanced by government policy, with a commensurate increase in the trade of the components. Previous studies have analyzed the effect of policies and the knowledge stock of exporter countries on their export of RE components. However, potential bias from confounding, i.e., correlation of GDP and knowledge stock to both the policy and the export, has not yet been controlled. This study applies matching methods to analyze the effect of feed-in tariffs (FITs) and renewable portfolio standards (RPS) on the export of photovoltaic (PV) and wind energy components. The estimation results indicate the contrasting effect of policies on PV and wind energy components. FIT and RPS in exporter countries are negatively associated with PV export, while the policies in importer countries show a positive effect on their imports. Meanwhile, FIT in exporter countries is positively associated with their export of wind energy components. Manufacturers might prioritize supplying to the domestic market rather than exporting PV components. On the other hand, manufacturers of wind energy components might maintain their export competitiveness with support from FITs. A positive policy effect on the export of RE components might be conditional on how the additional profit is secured for domestic manufacturers.
政府政策加强了可再生能源的广泛推广,组件的贸易也相应增加。以往的研究分析了政策和出口国知识储备对可再生能源零部件出口的影响。然而,混淆的潜在偏差,即GDP和知识存量与政策和出口的相关性,尚未得到控制。本文采用匹配方法分析了上网电价(fit)和可再生能源投资组合标准(RPS)对光伏(PV)和风能组件出口的影响。估算结果显示了政策对光伏和风能组件的不同影响。出口国的FIT和RPS与光伏出口负相关,而进口国的政策则对其进口产生积极影响。同时,出口国的FIT与其风能组件的出口呈正相关。制造商可能会优先考虑供应国内市场,而不是出口光伏组件。另一方面,风能组件制造商可以在补贴政策的支持下保持其出口竞争力。对可再生能源零部件出口的积极政策效果可能取决于如何确保国内制造商的额外利润。
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引用次数: 0
Removal of Heavy Metals from Wastewaters with Biochar Pyrolyzed from MgAl-LDH-Coated Rice Husk: Mechanism and Application mgal - ldh包覆稻壳热解生物炭脱除废水中的重金属:机理及应用
Pub Date : 2021-01-01 DOI: 10.2139/ssrn.3929867
Anyu Li, Yue Zhang, Wenzhang Ge, Yutong Zhang, Lihu Liu, Guohong Qiu
This study reports a MgAl–LDH rice husk biochar composite (MgAl–LDH@RHB) with a regular hydrotalcite structure synthesized by a simple hydrothermal method, which was then used to remove Cd(II) and Cu(II) from water. The influencing factors on the adsorption performance were determined through batch adsorption experiments, and the adsorption characteristics and cycling capacity were evaluated with eight models and adsorption-desorption experiments. The results showed that the adsorption of Cd(II) and Cu(II) by MgAl–LDH@RHB was conformed to the Langmuir-Freundlich model and PSO kinetics model, indicating single-layer chemical adsorption. Besides, the theoretical maximum adsorption capacities for Cd(II) and Cu(II) were 112.40 and 101.39 mg g –1 , respectively. The adsorption of Cd(II) and Cu(II) by MgAl–LDH@RHB was dominated by surface precipitation and ion exchange. Our findings reveal the mechanism for the heavy metal removal by MgAl–LDH@RHB and provide a theoretical reference for agricultural waste disposal and water pollution control.
本研究采用简单水热法合成了具有规则水滑石结构的MgAl - ldh稻壳生物炭复合材料(MgAl - LDH@RHB),并将其用于脱除水中的Cd(II)和Cu(II)。通过批量吸附实验确定了影响吸附性能的因素,并通过8种吸附模型和吸附-解吸实验对吸附特性和循环容量进行了评价。结果表明:MgAl - LDH@RHB对Cd(II)和Cu(II)的吸附符合Langmuir-Freundlich模型和PSO动力学模型,为单层化学吸附;对Cd(II)和Cu(II)的理论最大吸附量分别为112.40 mg g -1和101.39 mg g -1。MgAl - LDH@RHB对Cd(II)和Cu(II)的吸附以表面沉淀和离子交换为主。研究结果揭示了MgAl - LDH@RHB去除重金属的机理,为农业废弃物处理和水污染控制提供理论参考。
{"title":"Removal of Heavy Metals from Wastewaters with Biochar Pyrolyzed from MgAl-LDH-Coated Rice Husk: Mechanism and Application","authors":"Anyu Li, Yue Zhang, Wenzhang Ge, Yutong Zhang, Lihu Liu, Guohong Qiu","doi":"10.2139/ssrn.3929867","DOIUrl":"https://doi.org/10.2139/ssrn.3929867","url":null,"abstract":"This study reports a MgAl–LDH rice husk biochar composite (MgAl–LDH@RHB) with a regular hydrotalcite structure synthesized by a simple hydrothermal method, which was then used to remove Cd(II) and Cu(II) from water. The influencing factors on the adsorption performance were determined through batch adsorption experiments, and the adsorption characteristics and cycling capacity were evaluated with eight models and adsorption-desorption experiments. The results showed that the adsorption of Cd(II) and Cu(II) by MgAl–LDH@RHB was conformed to the Langmuir-Freundlich model and PSO kinetics model, indicating single-layer chemical adsorption. Besides, the theoretical maximum adsorption capacities for Cd(II) and Cu(II) were 112.40 and 101.39 mg g –1 , respectively. The adsorption of Cd(II) and Cu(II) by MgAl–LDH@RHB was dominated by surface precipitation and ion exchange. Our findings reveal the mechanism for the heavy metal removal by MgAl–LDH@RHB and provide a theoretical reference for agricultural waste disposal and water pollution control.","PeriodicalId":163818,"journal":{"name":"EnergyRN EM Feeds","volume":"262 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116238400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Support Vector Machine Regression Predicts Energy Consumption and Conservation Attitude in Households 支持向量机回归预测家庭能源消耗与节能态度
Pub Date : 1900-01-01 DOI: 10.2139/ssrn.3869532
B. Vojdani, M. Yegane, Julian Lang
The purpose of this study is twofold. First, causal mechanisms underlying the effect of changing attitudes on behavioral change are investigated. Second, recommendations are presented to improve the understanding of how attitudes and behavioral patterns of energy consumption in the residential sector can change. To that end, a theoretical model is developed and tested with empirical data. Also systematically investigates the association strength of each input variable with each of the output variables using various classical statistical analysis tools to identify the most strongly related input variables. Thereafter, three learning approaches, namely, multiple linear regression, polynomial linear regression, and support vector regression, are applied to predict the changing attitude and pattern of behavior variables. Results show that the performance of SVR with kernel radial basis function and polynomial regression hat of other forecasting models. However, the significant nonlinearity between inputs and outputs should be further developed to improve forecast precision. The study shows that cognitive factors are the most decisive factor in behavioral patterns and that the behavioral approach is strongly affected. Moreover, motivations and cognitive factors were found to have the most substantial effect on changing patterns of behaviors.
这项研究的目的是双重的。首先,研究态度改变对行为改变影响的因果机制。其次,提出了建议,以提高对住宅部门能源消费态度和行为模式如何改变的理解。为此,建立了一个理论模型,并用实证数据进行了检验。还使用各种经典统计分析工具系统地调查每个输入变量与每个输出变量的关联强度,以确定最强烈相关的输入变量。然后,运用多元线性回归、多项式线性回归和支持向量回归三种学习方法预测行为变量的态度变化和模式变化。结果表明,基于核径向基函数和多项式回归的支持向量回归的预测效果优于其他预测模型。然而,为了提高预测精度,需要进一步开发输入和输出之间的显著非线性。研究表明,认知因素是行为模式中最具决定性的因素,对行为方式的影响很大。此外,动机和认知因素对改变行为模式的影响最大。
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引用次数: 0
Motion Analysis and Modulation of Steel Particle Swarm in High-Pressure Tank for Particle Impact Drilling 颗粒冲击钻孔高压储罐中钢颗粒群运动分析与调节
Pub Date : 1900-01-01 DOI: 10.2139/ssrn.3924301
Weidong Zhou, Luopeng Li, Zizhen Wang, Xianbo Lei, Weidong Zhang, Fangxiang Wang
Particle Impact Drilling (PID) is a new technology to effectively improve the rate of penetration (ROP) for oil and gas drilling in hard and strongly abrasive formations. In this paper, numerical simulation method is used to analyze the motion characteristics and the modulation method of particle swarm in high-pressure tank for the particle injection system based on differential pressure ejection in PID. The numerical simulation results show that: when there is no modulation elements, the motion of particle swarm in the high-pressure tank follows an asymmetric funnel flow with pulsating state, which could be divided into vertical flow domain, fast flow domain, slow flow domain and stagnation domain. The unstable dynamic arching effect of the funnel flow, the viscous effect of the liquid bridge force and the collapsing effect of the particle swarm could probably lead to the blockage of the discharge port of the high-pressure tank. When the semiapex angles of the high-pressure tank decreases, the volume flow rate of particles increases and the stagnation domain becomes smaller, but it becomes easier to form arching and blockage. The modelling results indicate that the pulsation of the funnel flow is minimum when the semiapex angle is 45° without the mutilation element, which means the funnel flow of the particle swarm is relatively stable. By introducing a conical modulating element above the discharge port, the unstable funnel flow of the particle swarm could be transformed to an overall uniform flow. The modelling results indicate that the installation height of the modulation element has the greatest influence on the pulsation degree. The optimized parameters for the conical modulation element based on numerical modelling tests are 70° for the vertex angle, 35mm for the length of the flank and 70mm for the installation height.
颗粒冲击钻井(PID)是一种有效提高硬、强磨蚀地层油气钻井机械钻速的新技术。本文采用数值模拟的方法,分析了基于差压喷射PID的颗粒喷射系统高压罐内粒子群的运动特性和调制方法。数值模拟结果表明:当不存在调制元件时,高压罐内粒子群的运动遵循不对称的漏斗流动,并具有脉动状态,可分为垂直流域、快速流域、慢速流域和滞止流域。漏斗流的不稳定动力拱效应、液桥力的粘性效应和粒子群的坍塌效应都可能导致高压罐出料口堵塞。高压罐半顶点角减小时,颗粒体积流量增大,滞止区域变小,但更容易形成拱状和堵塞。模拟结果表明,当半尖角为45°时,无破坏元件时漏斗流动脉动最小,说明颗粒群漏斗流动相对稳定。通过在出料口上方引入锥形调制元件,可以将颗粒群的不稳定漏斗流转变为整体均匀流。仿真结果表明,调制元件的安装高度对脉动程度的影响最大。基于数值模拟试验的优化参数为顶角70°,翼长35mm,安装高度70mm。
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引用次数: 1
Decision Analysis Related to Solar Farms Investments Based on AHP & Fuzzy AHP for Sustainable Energy Production 基于层次分析法和模糊层次分析法的太阳能发电场投资决策分析
Pub Date : 1900-01-01 DOI: 10.2139/ssrn.3933576
Rida Azmi, H. Amar, E. Diop, Cédric Stéphane Tekouabou Koumetio, Jérôme Chenal
Renewable solar energy is the most preferable clean energy source with no environmental impacts. The Marrakech Safi region (Morocco) context, with its arid and semi-arid climate, can ensure sustainable energy production oriented to green economy. The paper aims to perform a decision analysis using the Analysis Hierarchical Process (AHP) and Fuzzy AHP to identify the potential areas for solar farms. The adopted approaches used fifteen factors to produce two suitability maps. Fuzzy logic was used to minimize the subjectivity related to the factor notation. The factors’ weights were reevaluated using the sensitivity analysis (SA) to assess their influence by comparing the theoretical and the effective weights. SA was conducted to explain the difference between the models. Results show that the suitable areas to host the solar farms cover more than 35% (1,300 Ha) of the region, using AHP and F-AHP. Moreover, the similarity analysis performed demonstrated that the 32% unequal areas between AHP and F-AHP can be explained by the factors’ weights and the difference of the approaches used. The climatic potential and the geographic location of the study area offer a large suitable area for exploiting solar farms. Findings constitute decision-making support for stakeholders for solar farm investments
可再生太阳能是目前最理想的无污染清洁能源。马拉喀什萨菲地区(摩洛哥)的干旱和半干旱气候可以确保以绿色经济为导向的可持续能源生产。本文旨在使用层次分析法(AHP)和模糊层次分析法(Fuzzy AHP)进行决策分析,以确定太阳能发电场的潜在区域。所采用的方法使用15个因素来产生两个适宜性图。采用模糊逻辑最小化因子符号的主观性。通过比较理论权重和有效权重,采用敏感性分析(SA)对各因素的权重进行重新评估。采用SA来解释模型之间的差异。结果表明,采用层次分析法和f -层次分析法,适宜建设太阳能发电场的面积占该地区面积的35%以上(1300 Ha)。此外,相似性分析表明,AHP与F-AHP之间32%的不平等区域可以用因子权重和所使用方法的差异来解释。研究区域的气候潜力和地理位置为开发太阳能发电场提供了一个大的合适区域。研究结果为太阳能发电场投资的利益相关者提供了决策支持
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引用次数: 1
Investigation of the Battery Temperature Gradient and its Influence on Battery Aging from Different Thermal Management Methods Under the Application of Electric Tools 电动工具应用下不同热管理方式下电池温度梯度及其对电池老化影响的研究
Pub Date : 1900-01-01 DOI: 10.2139/ssrn.3873131
Ruifei Ma, Jin He, Yaoqiu Qian, Yelin Deng
Due to its spatial efficiency, phase-change materials (PCMs) are particularly welcomed in the application of the electric tools where extremely high current at 10~15 C-rate is needed. With the Samsung 18650 20R Nickel-Cobalt-Manganese batteries, this study explores the temperature distribution from battery core to surface at extreme working current (15 C) with thermal conductive or storage wrapping materials including HDPE, thermal conductive sheet, thermal conductive adhesive, and PCMs. The proposed temperature distribution prediction model is validated with experimental data. The results indicate that the best battery surface temperature decrease is 18.60 ℃ when 2mm PCMs are applied. The discharge capacity of batteries is thus prolonged by 80-100 % compared to the naked battery cell. On the other hand, the battery core temperature reduction is much lower, only by 6.40 ℃ (from 139.70 ℃ to 133.29 ℃). Accordingly, the internal temperature gradient rises from 35.92 ℃ to 48.12 ℃. This is due to the heat generation exceeded the heat exported from the core to the outside under the 15C working condition of the electric tool. The study further evaluates the effects of high temperature gradient and finds that the capacity fade 90-250 % times faster with 2mm PCMs wrapping.
由于其空间效率,相变材料(PCMs)在需要10~15 c速率的极高电流的电动工具应用中特别受欢迎。本研究以三星18650 20R镍钴锰电池为研究对象,探索了在极端工作电流(15℃)下,从电池芯到电池表面的温度分布,采用导热或存储包装材料,包括HDPE、导热片、导热胶和pcm。用实验数据验证了所提出的温度分布预测模型。结果表明,当采用2mm pcm时,电池表面温度下降幅度最大,为18.60℃。与裸电池相比,电池的放电容量延长了80- 100%。另一方面,电池芯温度降低幅度要小得多,仅降低6.40℃(从139.70℃降至133.29℃)。相应的,内部温度梯度由35.92℃上升到48.12℃。这是由于电动工具在15C工况下产生的热量超过了芯向外输出的热量。研究进一步评估了高温梯度的影响,发现2mm pcm封装的容量衰减速度快90- 250%。
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引用次数: 0
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