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Optical band gap engineering of phosphotungstic acid upon hybridization with hexamine-nickel and -cobalt for solar/visible light photocatalysis: a combined experimental and theoretical approach 磷钨酸与六亚胺-镍和-钴杂化用于太阳/可见光光催化的光学带隙工程:实验与理论相结合的方法
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-30 DOI: 10.1080/09500340.2023.2241568
M. Taghdiri, F. Akbarian, Aezam Dehghani-Firoozabadi, R. Behjatmanesh-Ardakani, S. Banitaba, Hamid Reza Zare-Mehrjardi
Two new organic hybrids of phosphotungstic acid (PTA) were prepared by means of hexamine complexes of nickel and cobalt. The effects of complexes were studied on the photocatalytic activity of PTA. The hybrids were characterized by elemental analyses, FTIR, powder XRD and TGA. The optical band gaps of phosphotungstate-hexamine-nickel and phosphotungstate-hexamine-cobalt were estimated from the diffuse reflectance spectra using the Tauc plots. Dye adsorption and photocatalytic properties of hybrids were tested by decolorizing of model dye solutions methylene blue, rhodamine B and methyl orange. Band gap engineering of the hybrids was investigated using the quantum chemical calculations based on density functional theory through variation in the composition. Theoretical analysis demonstrates how the band gap of these hybrids can be adjusted with variation in their composition. The scavengers were used to suggest photodegradation mechanism. The degradation advanced through the excitation of hybrid by light, followed the oxidation of dye by superoxide radicals.
利用镍和钴的六胺配合物制备了两种新型磷钨酸有机杂化物。研究了配合物对PTA光催化活性的影响。通过元素分析、红外光谱、粉末X射线衍射和热重分析对其进行了表征。利用Tauc图从漫反射光谱中估算了磷钨酸盐六胺镍和磷钨酸盐钴的光学带隙。通过对亚甲基蓝、罗丹明B和甲基橙模型染料溶液的脱色,测试了杂化物对染料的吸附和光催化性能。利用基于密度泛函理论的量子化学计算,通过成分的变化,研究了杂化物的带隙工程。理论分析表明,这些杂化物的带隙是如何随着其组成的变化而调整的。清除剂被用来提示光降解机制。降解是通过光激发杂化物,然后通过超氧化物自由基氧化染料来进行的。
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引用次数: 0
Hyperspectral images classification for white blood cells with attention-aided convolutional neural networks and fusion network 基于注意辅助卷积神经网络和融合网络的白细胞高光谱图像分类
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-30 DOI: 10.1080/09500340.2023.2248634
Weidong Shao, Chunxu Zhang, Jinghan Wang, Xiaolin He, Dongxia Wang, Yan Lv, Yue An, Huihui Wang
The classification of White blood cells (WBCs) plays an important role. However, the traditional method of blood smear analysis is laborious. This paper presented a classification method of WBCs based on hyperspectral images and Deep learning (DL). The U-net network was proposed to extract spectral features of WBCs region of interest (ROI) under the pseudo-color images with specific hyperspectral images (420.8, 557.2 and 667.4 nm). For spectral features and the pseudo-colour images of hyperspectral data, attention-aided one and two-dimensional convolutional neural networks were applied to establish WBCs classification models, respectively. The overall average accuracy can reach 94.20% and 92.60%, respectively. A fusion network was constructed to make full use of the spectral and image spatial features, and its classification accuracy reached 96.20%. In terms of overall average accuracy, the fusion network model was the optimal, but for individual types of WBCs, each network had its own unique advantages.
白细胞(wbc)的分类起着重要的作用。然而,传统的血液涂片分析方法是费力的。提出了一种基于高光谱图像和深度学习的白血细胞分类方法。提出了U-net网络在特定高光谱图像(420.8、557.2和667.4 nm)的伪彩色图像下提取wbc感兴趣区域(ROI)光谱特征。针对光谱特征和高光谱数据的伪彩色图像,分别采用注意力辅助的一维卷积神经网络和二维卷积神经网络建立wbc分类模型。整体平均准确率分别达到94.20%和92.60%。构建了充分利用光谱和图像空间特征的融合网络,分类准确率达到96.20%。就整体平均准确率而言,融合网络模型是最优的,但对于单个类型的白细胞,每种网络都有其独特的优势。
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引用次数: 0
Astrophotonics-assisted 5G communication system within radio astronomy areas without introducing RFI effects 射电天文领域内的天体光子学辅助5G通信系统,不引入RFI效应
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-30 DOI: 10.1080/09500340.2023.2219780
R. Karembera, J. Jena, T. Gibbon
We have demonstrated spectrum sharing and coexistence between a 5G network and a radio telescope without causing interference to the radio astronomer. This was realized by using optical heterodyning between two distributed feedback (DFB) semiconductor lasers as a flex-spectrum photonic RF transmitter. The 5G network was designed to identify and avoid any radio frequency interference (RFI). The generated 5G RF carrier signal is used as the primary RF data carrier for the 5G network. A second RF signal, acting as noise signal, is introduced to the 5G network using an electrical mixer. When the frequencies at the mixer ports are the same, an error signal is generated which triggers the control circuit of the 5G network to correct for the RFI by shifting the primary RF data carrier of the 5G network to a new RF carrier frequency. An impressive RFI correction time of about 3 milliseconds was recorded.
我们已经证明了5G网络和射电望远镜之间的频谱共享和共存,而不会对射电天文学家造成干扰。这是通过使用两个分布式反馈(DFB)半导体激光器之间的光外差作为弯曲频谱光子RF发射器来实现的。5G网络旨在识别和避免任何射频干扰(RFI)。生成的5G射频载波信号被用作5G网络的主要射频数据载波。第二个射频信号作为噪声信号,使用电混频器引入5G网络。当混频器端口处的频率相同时,产生错误信号,该错误信号触发5G网络的控制电路通过将5G网络中的主RF数据载波移位到新的RF载波频率来校正RFI。记录了大约3毫秒的令人印象深刻的RFI校正时间。
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引用次数: 0
Eight-channel C-Band demultiplexer based on one-dimensional photonic crystals defected with lithium niobate 基于铌酸锂缺陷一维光子晶体的八通道C波段解复用器
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-30 DOI: 10.1080/09500340.2023.2250475
Khedr M. Abohassan, H. S. Ashour, S. Taya, Malek G. Daher
We propose an eight-channel Dense Wavelength Division Demultiplexer (DWDM) device based on one-dimensional photonic crystal (1-D PC) structures defected with lithium niobate (LiNbO3) thin films. The demultiplexer operates in the C-band window (1460–1560 nm), which belongs to the ITU grid for DWDM applications. The desired output wavelength is achieved by applying the proper external electric field to the LiNbO3 layer at various temperatures. The transfer matrix method (TMM) is used to simulate the transmittance spectrum. Efficient output channels with transmittances of about 90% are attained. An excellent quality factor of 30919 and a very small line width of 0.05 nm are exceptional values acquired by the output channels. A very small channel spacing of 0.182 nm is attained without compromising the crosstalk, which reaches a minimum value of −34 dB. The astounding characteristics of the eight channels reveal that the proposed demultiplexer could be a potentially efficient device for DWDM networks.
我们提出了一种基于铌酸锂(LiNbO3)薄膜缺陷的一维光子晶体(1-D PC)结构的八通道密集波分复用器(DWDM)器件。多路分解器在C波段窗口(1460–1560 nm),属于DWDM应用的ITU网格。通过在各种温度下向LiNbO3层施加适当的外部电场来实现期望的输出波长。采用传递矩阵法对透射光谱进行了模拟。获得了透射率约为90%的有效输出通道。30919的卓越品质因数和0.05的极小线宽 nm是由输出通道获得的异常值。0.182的非常小的通道间距 在不影响串扰的情况下获得nm,串扰达到−34的最小值 dB。八个信道的惊人特性表明,所提出的多路分解器可能是DWDM网络的潜在高效设备。
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引用次数: 0
The relative Fresnel goos-Hänchen phase crossover and its applications in quantum computation 相对菲涅耳goos-Hänchen相位交叉及其在量子计算中的应用
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-30 DOI: 10.1080/09500340.2023.2250472
S. A. Carvalho, G. T. Cruz, J. Huguenin, W. F. Balthazar
In this work, we present the relative Fresnel (Goos-Hänchen) phase crossover between the total internal reflection and diffusion regimes by employing polarization tomography. This powerful technique not only enables us to access information about the amplitude and relative phase of the state for total reflection but also facilitates the identification of the transition between these regimes. In all cases, the experimental data are in very good agreement with the theoretical predictions. As an application, we propose the use of the GH phase to implement a phase gate, which is an essential requirement for universal computation. In this context, our system offers a more cost-effective and alternative set up to implement the phase gate and simulate compensator devices.
在这项工作中,我们通过偏振层析成像提出了全内反射和扩散区域之间的相对菲涅耳(Goos-Hänchen)相位交叉。这种强大的技术不仅使我们能够获得关于全反射状态的振幅和相对相位的信息,而且有助于识别这些状态之间的过渡。在所有情况下,实验数据都与理论预测非常一致。作为一个应用,我们建议使用GH相位来实现相位门,这是通用计算的基本要求。在这种情况下,我们的系统提供了一种更具成本效益和替代性的设置,以实现相位门和模拟补偿器设备。
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引用次数: 0
Nanosecond passively Q-switched Nd: YVO4 laser based on BP/InSe saturable absorber 基于BP/InSe可饱和吸收体的纳秒级被动调Q Nd:YVO4激光器
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-12 DOI: 10.1080/09500340.2023.2234506
Jianlei Wang, Lingbo Cai, Liangyue Xie, Jun Liu, Zijun Zhong, Zhi Liu, Jing Han, Xianfeng Meng, Quan‐lan Xiao, Chun Wang
We report on a compact 808 nm diode-pumped passively Q-switched (PQS) Nd:YVO4 laser at 1064 nm with black phosphorus (BP)/ indium selenide (InSe) heterostructure as a saturable absorber (SA). When the transmission of the output coupler (OC) was 30%, the maximum continuous-wave (CW) output power of 10.3 W was obtained with a slope efficiency of 52.4% under the incident pump power of 22 W. The maximum average output power of 3.1 W was obtained at 9.29 W pump power, corresponding to the repetition rate of 598 kHz and the pulse width of 455 ns during pulse operation, further power scaling was limited by the damage threshold of the saturable absorber mirror (SAM). The results sufficiently validated that two-dimensional (2D) BP/InSe heterostructure could be used as an optical modulator for near-IR pulsed laser sources.
我们报道了一个契约808 1064纳米二极管泵浦的被动调Q Nd:YVO4激光器 nm,以黑磷(BP)/硒化铟(InSe)异质结构作为可饱和吸收体(SA)。当输出耦合器(OC)的传输率为30%时,在22W的入射泵浦功率下,获得了10.3W的最大连续波(CW)输出功率,斜率效率为52.4%。在9.29W的泵浦功率下获得了3.1W的最大平均输出功率,对应于598kHz的重复频率和455的脉冲宽度 ns时,可饱和吸收镜(SAM)的损伤阈值限制了进一步的功率缩放。结果充分验证了二维(2D)BP/InSe异质结构可以用作近红外脉冲激光源的光调制器。
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引用次数: 0
Experimental optimization design synthesis and up-conversion luminescence properties of YNbO4:Ho3+/Yb3+ YNbO4:Ho3+/Yb3的实验优化设计合成及上转换发光性能+
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-12 DOI: 10.1080/09500340.2023.2234505
Sheng Liu, Duan Gao, Li Wang, Wenbin Song, Qianmiao Yu, Yongbo Wen, Xilai Zhang
In order to obtain the maximum green up-conversion luminescence intensity of Ho3+/Yb3+ co-doped YNbO4, a uniform design and a quadratic general rotation combination design were applied to optimize the doping concentration. The concentration of the rare earth corresponding to the strongest green luminescence intensity was determined to be 10% Ho3+/34.9% Yb3+. Maximum luminous intensity of green light tested under 980 nm excitation was 157373.266, which was close to the theoretical calculated integral intensity value of 157290.825. The variation of the up-conversion luminescence spectra at different power density of the 980 nm laser was characterized. According to the formula fitting, the up-conversion luminescence process is a two-photon process. Meanwhile, the temperature sensing characteristic of the samples has been discussed. Finally, the CIE coordinates were analyzed and calculated to be (0.297, 0.692).
为了获得Ho3+/Yb3+共掺杂YNbO4的最大绿色上转换发光强度,采用均匀设计和二次通用旋转组合设计来优化掺杂浓度。对应于最强绿色发光强度的稀土的浓度被确定为10%Ho3+/34.9%Yb3+。980nm激发下测试的绿光最大发光强度为157373.266,接近理论计算的积分强度值157290.825。表征了980nm激光在不同功率密度下上转换发光光谱的变化。根据公式拟合,上转换发光过程是一个双光子过程。同时,对样品的温度传感特性进行了讨论。最后,分析并计算出CIE坐标为(0.297,0.692)。
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引用次数: 0
Spatial intensity correlations of Mathieu speckle fields Mathieu散斑场的空间强度相关性
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-12 DOI: 10.1080/09500340.2023.2232886
C. Acevedo, Yezid Torres Moreno, J. Guzmán-Sepúlveda, A. Dogariu
Analytical expressions are derived for the spatial coherence function of a speckle field that is generated by the scattering of a Mathieu beam from a random phase mask by following the Fresnel diffraction theory. The general results in the free-space propagation show that the intensity correlation factor is a function of the order of the Mathieu beam, and it evolves spatially as the speckle field propagates. Also, we demonstrate that the intensity correlation factor is non-evolving with the propagation distance in the far-field regime when a lens is placed at the focal distance after the diffuser. The results of this analysis can be used in applications where random fields need to be engineered with structured light beams.
根据菲涅耳衍射理论,导出了由Mathieu光束从随机相位掩模散射产生的散斑场的空间相干函数的解析表达式。自由空间传播的一般结果表明,强度相关因子是Mathieu光束阶数的函数,并且它随着散斑场的传播而在空间上演化。此外,我们证明了当透镜放置在漫射器之后的焦距处时,在远场区域中,强度相关因子不随传播距离而变化。该分析的结果可用于需要用结构化光束设计随机场的应用中。
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引用次数: 0
A study on the design, morphology and electro-optical properties of polymer dispersed liquid crystal films doped with Sudan black B dye 苏丹黑B染料掺杂聚合物分散液晶膜的设计、形貌及电光性能研究
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-12 DOI: 10.1080/09500340.2023.2232897
F. Ahmad, M. Jamil, Park Woo Hyun, M. Luqman, Shagufta Sajjad, M. Baloch
To fabricate and use PDLC-based smart windows, electro-optical (EO) properties such as high transparency at low driving voltages, high contrast ratios (CR), and a wide viewing angle are critical. Thus, there is always a need to either develop new materials with excellent performance or to improve the existing ones. Doping materials (other than the LC and polymeric materials) such as dyes and nanomaterials, can also be used to adjust the EO properties. Sudan black B (SBB) dye and newly available LC material were doped in PDLC material in order to address such a scenario. In our investigation, we found that the doping SBB dye at a weight ratio of 1wt%and LC material with 60 wt% into NOA65 prepolymer PDLC resulted in a great performance of PDLC devices e.g. a high CR response (8.8) and high transmittance even at a low deriving voltage (5 Volt).
为了制造和使用基于PDLC的智能窗口,电光(EO)特性,例如在低驱动电压下的高透明度、高对比度(CR)和宽视角是至关重要的。因此,总是需要开发具有优异性能的新材料或改进现有材料。掺杂材料(LC和聚合物材料除外),如染料和纳米材料,也可用于调节EO性能。苏丹黑B(SBB)染料和新获得的LC材料被掺杂在PDLC材料中,以解决这种情况。在我们的研究中,我们发现在NOA65预聚物PDLC中掺杂1wt%重量比的SBB染料和60wt%的LC材料导致了PDLC器件的良好性能,例如,即使在低的导出电压(5V)下也具有高CR响应(8.8)和高透射率。
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引用次数: 0
Ultrafast laser micromachining of angled surfaces in fused silica 熔融二氧化硅斜角表面的超快激光微加工
IF 1.3 4区 物理与天体物理 Q4 OPTICS Pub Date : 2023-03-12 DOI: 10.1080/09500340.2023.2232898
Y. Dogan
Angled surfaces are significant for obtaining complex 3D glass structures to be employed in precise optical components such as light guides. However, it is challenging to fabricate angled structures in glass with high precision. In this study, femtosecond laser irradiation followed by a chemical etching process is used to create a 45-degree angled surface. The roughness values of the angled top and bottom surfaces are compared and the parameters are optimized to achieve maximum surface quality. A 45-degree angled surface with <300 nm roughness and <±0.5° deviation is obtained in a given area of 1 × 1.5 mm2. Using this approach, various complex structures have been successfully fabricated with high quality and precision. Results indicate that this method can be adapted to the high-precision glass manufacturing industry.
成角度的表面对于获得在诸如光导之类的精确光学部件中使用的复杂3D玻璃结构是重要的。然而,在玻璃中高精度地制造成角度结构是具有挑战性的。在这项研究中,使用飞秒激光照射,然后进行化学蚀刻工艺,形成45度角的表面。比较倾斜的顶部表面和底部表面的粗糙度值,并优化参数以实现最大的表面质量。小于300的45度斜面 nm的粗糙度和<±0.5°的偏差 × 1.5平方毫米。使用这种方法,已经成功地以高质量和高精度制造了各种复杂结构。结果表明,该方法适用于高精度玻璃制造业。
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引用次数: 0
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Journal of Modern Optics
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