Volatile threshold-switching (TS) devices have been used as selectors and to simulate neurons in neural networks. It is necessary to find new ways to improve their performance. The randomness of conductive filament (CF) growth and the endurance of the devices are urgent issues at present. Here, we explored embedded Ag nanoislands (NIs) in HfO2-based TS devices to limit the position of the CF and facilitate its growth at the same time. The Au/Ag(2 nm)/HfO2(4 nm)/Ag NIs/Au volatile TS devices exhibited forming-free characteristics with improved endurance compared with the devices without Ag NIs, which was ascribed to the enhanced localization of the electrical field and increased oxygen vacancies in HfO2 induced by the Ag NIs. A mechanism was proposed to explain the volatile TS behaviors of the devices. The Ag NIs and the thickness of the HfO2 layers played key roles in whether the devices required forming. This work shows that the use of metal NIs is an effective and convenient way to improve the performance of TS devices.
{"title":"The Effects of Ag Nanoislands on the Volatile Threshold-Switching Behaviors of Au/Ag/HfO2/Ag Nanoislands/Au Devices","authors":"Fanlin Long, Yichuan Zhang, Zhaozhu Qu, Peiwen Lv, Baolin Zhang","doi":"10.1155/2023/6675683","DOIUrl":"https://doi.org/10.1155/2023/6675683","url":null,"abstract":"Volatile threshold-switching (TS) devices have been used as selectors and to simulate neurons in neural networks. It is necessary to find new ways to improve their performance. The randomness of conductive filament (CF) growth and the endurance of the devices are urgent issues at present. Here, we explored embedded Ag nanoislands (NIs) in HfO2-based TS devices to limit the position of the CF and facilitate its growth at the same time. The Au/Ag(2 nm)/HfO2(4 nm)/Ag NIs/Au volatile TS devices exhibited forming-free characteristics with improved endurance compared with the devices without Ag NIs, which was ascribed to the enhanced localization of the electrical field and increased oxygen vacancies in HfO2 induced by the Ag NIs. A mechanism was proposed to explain the volatile TS behaviors of the devices. The Ag NIs and the thickness of the HfO2 layers played key roles in whether the devices required forming. This work shows that the use of metal NIs is an effective and convenient way to improve the performance of TS devices.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"52 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74761617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yazdan Choghazardi, H. Azimian, Alireza Montazer Abadi, Milad Mohammadi Khoshisani, Fereshteh Vaziri Nezamdoust, H. Gholamhosseinian
The aim of this study was to assess the radiosensitivity of bismuth sulfide nanoparticles conjugated with a synthetic agonist analog of gonadotropin-releasing hormones in targeted radiotherapy for breast cancer. After synthesis and characterization of nanoparticles, cytotoxicity of nanoparticles was measured by MTT assay, and the survival fraction was determined by colony formation assay. Finally, flow cytometry was performed to identify the mechanism of radiosensitization. Characterization results determined the spherical shape of Bi2S3@BSA with an average size of 8.649 ± 1.6 nm, and Fourier transform infrared confirmed the successful binding of triptorelin to the surface of the nanoparticles. MTT test results show that the Bi2S3@BSA–triptorelin did not cause any toxicity ( P < 0.05 ) even up to 75 μg/ml. At all doses of ionizing radiation, colony formation assays showed that the nontoxic concentration of Bi2S3@BSA–triptorelin significantly increased cell death in MCF-7 cells compared to Bi2S3@BSA ( P < 0.05 ). The apoptosis test also confirmed colony formation assay results at all doses and introduced apoptosis as a mechanism of radiosensitivity produced by nanoparticles. Certainly, targeted bismuth sulfide nanoparticles can be a good candidate for increasing radiosensitivity against tumor cells.
{"title":"Radiosensitivity Enhancement using Triptorelin Conjugated Bismuth Sulfide Nanoparticles (Bi2S3@BSA) in Radiotherapy for Breast Cancer Cells","authors":"Yazdan Choghazardi, H. Azimian, Alireza Montazer Abadi, Milad Mohammadi Khoshisani, Fereshteh Vaziri Nezamdoust, H. Gholamhosseinian","doi":"10.1155/2023/5485632","DOIUrl":"https://doi.org/10.1155/2023/5485632","url":null,"abstract":"The aim of this study was to assess the radiosensitivity of bismuth sulfide nanoparticles conjugated with a synthetic agonist analog of gonadotropin-releasing hormones in targeted radiotherapy for breast cancer. After synthesis and characterization of nanoparticles, cytotoxicity of nanoparticles was measured by MTT assay, and the survival fraction was determined by colony formation assay. Finally, flow cytometry was performed to identify the mechanism of radiosensitization. Characterization results determined the spherical shape of Bi2S3@BSA with an average size of 8.649 ± 1.6 nm, and Fourier transform infrared confirmed the successful binding of triptorelin to the surface of the nanoparticles. MTT test results show that the Bi2S3@BSA–triptorelin did not cause any toxicity (\u0000 \u0000 P\u0000 <\u0000 0.05\u0000 \u0000 ) even up to 75 μg/ml. At all doses of ionizing radiation, colony formation assays showed that the nontoxic concentration of Bi2S3@BSA–triptorelin significantly increased cell death in MCF-7 cells compared to Bi2S3@BSA (\u0000 \u0000 P\u0000 <\u0000 0.05\u0000 \u0000 ). The apoptosis test also confirmed colony formation assay results at all doses and introduced apoptosis as a mechanism of radiosensitivity produced by nanoparticles. Certainly, targeted bismuth sulfide nanoparticles can be a good candidate for increasing radiosensitivity against tumor cells.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"75 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89015062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sabyasachi Ghosh, Swarup Roy, Jishu Naskar, R. K. Kole
The environmental, economic, and operational limits associated with the physical, chemical, and microbiological techniques for the production of nanoparticles (NPs) are the principal obstructions to their rapid commercial applications in various fields including food packaging and sensing to ensure food quality and safety. Over the years, many reports revealed that the nanotechnological (metal-based NPs) application facilitates an alternate, interactive, reliable, as well as simple technology in the food industries and packaging sector. In this review, we summarized the usage of plant extract for the biosynthesis of bimetallic (Au–Ag) and monometallic counterpart NPs. Further, the impact of reaction conditions and identification of reactive phytochemicals with the reaction mechanism of these nanoparticles was reviewed. The recent progress on the applications of Ag, Au, or Au–Ag NPs in food quality analysis and food packaging was comprehensively discussed. The safety aspect of the nanoparticles for food sector use was also briefly stated.
{"title":"Plant-Mediated Synthesis of Mono- and Bimetallic (Au–Ag) Nanoparticles: Future Prospects for Food Quality and Safety","authors":"Sabyasachi Ghosh, Swarup Roy, Jishu Naskar, R. K. Kole","doi":"10.1155/2023/2781667","DOIUrl":"https://doi.org/10.1155/2023/2781667","url":null,"abstract":"The environmental, economic, and operational limits associated with the physical, chemical, and microbiological techniques for the production of nanoparticles (NPs) are the principal obstructions to their rapid commercial applications in various fields including food packaging and sensing to ensure food quality and safety. Over the years, many reports revealed that the nanotechnological (metal-based NPs) application facilitates an alternate, interactive, reliable, as well as simple technology in the food industries and packaging sector. In this review, we summarized the usage of plant extract for the biosynthesis of bimetallic (Au–Ag) and monometallic counterpart NPs. Further, the impact of reaction conditions and identification of reactive phytochemicals with the reaction mechanism of these nanoparticles was reviewed. The recent progress on the applications of Ag, Au, or Au–Ag NPs in food quality analysis and food packaging was comprehensively discussed. The safety aspect of the nanoparticles for food sector use was also briefly stated.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"31 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88532118","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Qaeed, Abdulmajeed H. Hendi, Asad A. Thahe, Saleh M. Al-Maaqar, A. M. Osman, A. Ismail, A. Mindil, Alharthi A. Eid, F. Aqlan, E. Al-Nahari, A. Obaid, M. K. Warsi, A. Saif, A. Al-Farga
Our work was devoted to studying the effect of different concentrations of Mentha spicata aqueous extract on the green synthesis of silver nanoparticles (AgNPs) in order to obtain the most effective of these concentrations for bacteria inhibitory activity. Different concentrations of the aqueous M. spicata extract (0.25, 0.50, 0.75, and 1.00 mM) were used as biological solvent to synthesize AgNPs by means of the reduction method. The crystal structure and morphology of the NPs were characterized UV–vis spectra, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The inhibition effect of AgNPs on Escherichia coli was studied to determine the minimum inhibitory concentration (MIC). The dark yellow color of the M. spicata extract aqueous solution indicates the successful synthesis of the AgNPs. UV spectra of the NPs show a gradual increase in absorption with increasing concentration of aqueous M. spicata extract solution from 0.25 to 1.00 mM, accompanied by a shift in the wavelength from 455 to 479 nm along with a change in the nanoparticle size from 31 to 9 nm. The tests also showed a high activity of the particles against bacteria (E. coli) ranging between 15.6 and 62.5 µg/ml. From the AgNPs, it was confirmed that aqueous M. spicata extract is an effective biosolvent for the synthesis of different sizes of AgNPs according to the solvent concentration. The AgNPs also proved effectual for the killing of bacteria.
{"title":"Effect of Different Ratios of Mentha spicata Aqueous Solution Based on a Biosolvent on the Synthesis of AgNPs for Inhibiting Bacteria","authors":"M. Qaeed, Abdulmajeed H. Hendi, Asad A. Thahe, Saleh M. Al-Maaqar, A. M. Osman, A. Ismail, A. Mindil, Alharthi A. Eid, F. Aqlan, E. Al-Nahari, A. Obaid, M. K. Warsi, A. Saif, A. Al-Farga","doi":"10.1155/2023/3599501","DOIUrl":"https://doi.org/10.1155/2023/3599501","url":null,"abstract":"Our work was devoted to studying the effect of different concentrations of Mentha spicata aqueous extract on the green synthesis of silver nanoparticles (AgNPs) in order to obtain the most effective of these concentrations for bacteria inhibitory activity. Different concentrations of the aqueous M. spicata extract (0.25, 0.50, 0.75, and 1.00 mM) were used as biological solvent to synthesize AgNPs by means of the reduction method. The crystal structure and morphology of the NPs were characterized UV–vis spectra, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The inhibition effect of AgNPs on Escherichia coli was studied to determine the minimum inhibitory concentration (MIC). The dark yellow color of the M. spicata extract aqueous solution indicates the successful synthesis of the AgNPs. UV spectra of the NPs show a gradual increase in absorption with increasing concentration of aqueous M. spicata extract solution from 0.25 to 1.00 mM, accompanied by a shift in the wavelength from 455 to 479 nm along with a change in the nanoparticle size from 31 to 9 nm. The tests also showed a high activity of the particles against bacteria (E. coli) ranging between 15.6 and 62.5 µg/ml. From the AgNPs, it was confirmed that aqueous M. spicata extract is an effective biosolvent for the synthesis of different sizes of AgNPs according to the solvent concentration. The AgNPs also proved effectual for the killing of bacteria.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"111 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77881254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Luciana Sampaio Ribeiro, Francisco Javier Rios, Armindo Santos
The fabrication of SS (stainless steel)-UO2 cermet-type advanced nuclear fuel pellets suitable for use in power reactors depends on the development of metallic (SS), ceramic (UO2), and cermet (SS-UO2) microspheres with special characteristics. In this work, a nonconventional powder metallurgy process was developed to produce porous SS microspheres aiming to contribute to solve the bottlenecks found in the SS-UO2 cermet pellet manufacturing. SS, UO2, and SS-UO2 microspheres and SS-UO2 cermet pellets were fabricated and characterized (XRD, EDX, EDS, and SEM). Hard (153 ± 5 µm; 132.2 ± 24.7 MPa; 72% TD) and soft (216 ± 10 µm; 1.3 ± 0.4 MPa; 17% TD) SS, hard (176 ± 6 µm; 147.4 ± 25.0 MPa; 99% TD) UO2, and cermet (SS-UO2) microspheres were obtained. The soft porous SS microspheres did not micronize properly in situ, but their high compressibility favors the compaction of the green SS-UO2 cermet pellet; in this pellet, the UO2 microspheres behaved as rigid inclusions. This favored the obtainment of sintered SS-UO2 cermet pellets with high geometric densities (93% TD), excellent metal–ceramic interaction, and the preservation of the physical integrity of the UO2 microspheres. The usage of high fractions of the SS-UO2 cermet microspheres obtained mixed with low fractions of the said soft porous SS microspheres is already under development. This will enable the fabrication of SS-UO2 cermet pellets with a volume fraction greater than 42 vol% UO2, a homogeneous distribution of UO2 microspheres in the metallic matrix, and null connection between them. The oxide–metal reduction mechanisms were discussed. The applicability of the process is already being explored in the manufacture of porous NdFeB microspheres.
{"title":"Porous Stainless Steel Microsphere Synthesis by a Nonconventional Powder Metallurgy Process Useful in the Cermet-Type Advanced Nuclear Fuel Fabrication","authors":"Luciana Sampaio Ribeiro, Francisco Javier Rios, Armindo Santos","doi":"10.1155/2023/3555763","DOIUrl":"https://doi.org/10.1155/2023/3555763","url":null,"abstract":"The fabrication of SS (stainless steel)-UO2 cermet-type advanced nuclear fuel pellets suitable for use in power reactors depends on the development of metallic (SS), ceramic (UO2), and cermet (SS-UO2) microspheres with special characteristics. In this work, a nonconventional powder metallurgy process was developed to produce porous SS microspheres aiming to contribute to solve the bottlenecks found in the SS-UO2 cermet pellet manufacturing. SS, UO2, and SS-UO2 microspheres and SS-UO2 cermet pellets were fabricated and characterized (XRD, EDX, EDS, and SEM). Hard (153 ± 5 µm; 132.2 ± 24.7 MPa; 72% TD) and soft (216 ± 10 µm; 1.3 ± 0.4 MPa; 17% TD) SS, hard (176 ± 6 µm; 147.4 ± 25.0 MPa; 99% TD) UO2, and cermet (SS-UO2) microspheres were obtained. The soft porous SS microspheres did not micronize properly in situ, but their high compressibility favors the compaction of the green SS-UO2 cermet pellet; in this pellet, the UO2 microspheres behaved as rigid inclusions. This favored the obtainment of sintered SS-UO2 cermet pellets with high geometric densities (93% TD), excellent metal–ceramic interaction, and the preservation of the physical integrity of the UO2 microspheres. The usage of high fractions of the SS-UO2 cermet microspheres obtained mixed with low fractions of the said soft porous SS microspheres is already under development. This will enable the fabrication of SS-UO2 cermet pellets with a volume fraction greater than 42 vol% UO2, a homogeneous distribution of UO2 microspheres in the metallic matrix, and null connection between them. The oxide–metal reduction mechanisms were discussed. The applicability of the process is already being explored in the manufacture of porous NdFeB microspheres.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"148 10","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72453955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Concrete is a material made from cement that is widely used because it has a high compressive strength, is resistant to water, is easy to mold, and is cheap to make. But concrete’s biggest problem is that it’s easy to break because it does not resist cracking well, has low tensile strength, and cannot take a lot of stress. Researchers have been successful in enhancing the quality of cement composites by using fibers, admixtures, and other cementitious materials. When it comes to building objects, nanotechnology could open up a whole new world. Building materials have made nanosized materials that are used to make cementitious materials stronger and last longer. For example, they stop microcracks from starting and spreading. One of the most well-known graphene derivative nanomaterials is graphene oxide (GO), which has a lot of active oxygen-containing groups on its surface, outstanding mechanical properties, and thermal conductivity. Researchers have found that adding small amounts of GO in various dosages increases the flexural, tensile, and compressive strengths of cement paste and mortar. The majority of studies have looked at cement paste and mortar. There are few GO-concrete studies. One of the most characteristic graphene derivative nanomaterials, graphene oxide (GO), has a huge specific surface area, outstanding mechanical properties, thermal conductivity, and a lot of active oxygen-containing groups on its surface. Small amounts of GO at various dosages boost the flexural, tensile, and compressive strengths of cement paste and mortar, according to researchers. Most researches have examined cement paste and mortar. There are few GO-concrete studies. This article review paper will be useful for engineers and researchers investigating the impact of GO on mechanical qualities and advanced nanomaterials in cement-based materials like concrete. It will also be a point of reference for further research.
{"title":"Cement-Based Graphene Oxide Composites: A Review on Their Mechanical and Microstructure Properties","authors":"Amin Kedir, Merga Gamachu, Alexander Gladwin Alex","doi":"10.1155/2023/6741000","DOIUrl":"https://doi.org/10.1155/2023/6741000","url":null,"abstract":"Concrete is a material made from cement that is widely used because it has a high compressive strength, is resistant to water, is easy to mold, and is cheap to make. But concrete’s biggest problem is that it’s easy to break because it does not resist cracking well, has low tensile strength, and cannot take a lot of stress. Researchers have been successful in enhancing the quality of cement composites by using fibers, admixtures, and other cementitious materials. When it comes to building objects, nanotechnology could open up a whole new world. Building materials have made nanosized materials that are used to make cementitious materials stronger and last longer. For example, they stop microcracks from starting and spreading. One of the most well-known graphene derivative nanomaterials is graphene oxide (GO), which has a lot of active oxygen-containing groups on its surface, outstanding mechanical properties, and thermal conductivity. Researchers have found that adding small amounts of GO in various dosages increases the flexural, tensile, and compressive strengths of cement paste and mortar. The majority of studies have looked at cement paste and mortar. There are few GO-concrete studies. One of the most characteristic graphene derivative nanomaterials, graphene oxide (GO), has a huge specific surface area, outstanding mechanical properties, thermal conductivity, and a lot of active oxygen-containing groups on its surface. Small amounts of GO at various dosages boost the flexural, tensile, and compressive strengths of cement paste and mortar, according to researchers. Most researches have examined cement paste and mortar. There are few GO-concrete studies. This article review paper will be useful for engineers and researchers investigating the impact of GO on mechanical qualities and advanced nanomaterials in cement-based materials like concrete. It will also be a point of reference for further research.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"31 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83096544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. Ananth, T. Muthu Krishnan, S. Thirugnanam, Tewedaj Tariku Olkeba
Aluminum matrix composites are widely employed in aerospace, military, automobile, and transport applications. The high-strength with low-weight materials are required to fulfill the requirement of high-performance applications. The low-weight materials are reinforced with hard reinforcements to obtain high-strength-to-weight properties for using high-performance applications. The process parameters of fabrication technique define the mechanical and tribological properties. Many types of optimization tools are used for optimizing the process parameters of fabrication method. In this research, the aluminum alloy 7050 and boron carbide are selected as matrix material and reinforcement material. The fabrication of Al7050/B4C composites is produced by the stir casting method. The optimization on stir casting process parameters is done by using the Taguchi approach. The L9 orthogonal array is chosen for this investigation. The chosen input stir casting process parameters are wt% B4C, stirring time (10, 15, and 20 min), stirring speed (300, 350, and 400 rpm), and melting temperature (700, 750, and 800°C). The microhardness is selected as a valuable response parameter for optimizing the stir casting process parameters. The influencing stir casting process parameter sequence is determined by using mean table. The influencing parameters of stir casting on microhardness are stirring speed, stirring time, wt% B4C, and melting temperature. The 9 wt% of boron carbide addition increases the microhardness, and it is higher than the other wt%. The optimum combination of input process parameter combination is 9 wt% boron carbide, 750°C melting temperature, 350 rpm stirring speed, and 15 min stirring time (A3B2C2D2). The percentage of microhardness value improvement is 20.3%.
铝基复合材料广泛应用于航空航天、军事、汽车和运输等领域。为了满足高性能应用的要求，需要高强度、低重量的材料。低重量材料与硬增强增强，以获得使用高性能应用的高强度重量性能。加工工艺参数决定了材料的力学性能和摩擦学性能。许多类型的优化工具被用于优化制造方法的工艺参数。本研究选择7050铝合金和碳化硼作为基体材料和增强材料。采用搅拌铸造法制备了Al7050/B4C复合材料。采用田口法对搅拌铸造工艺参数进行了优化。本研究选用L9正交阵列。所选择的输入搅拌铸造工艺参数为wt% B4C，搅拌时间(10,15和20分钟)，搅拌速度(300,350和400 rpm)，熔化温度(700,750和800°C)。选择显微硬度作为优化搅拌铸造工艺参数的有价值的响应参数。采用平均表法确定了搅拌铸造工艺参数的影响顺序。搅拌铸造对显微硬度的影响参数有搅拌速度、搅拌时间、wt% B4C和熔化温度。碳化硼添加量为9 wt%时，合金的显微硬度有所提高，且高于其他wt%。输入工艺参数组合的最佳组合为碳化硼质量分数为9 wt%，熔化温度为750℃，搅拌速度为350 rpm，搅拌时间为15 min (A3B2C2D2)。显微硬度值改善率为20.3%。
{"title":"Optimization on Stir Casting Process Parameters of Al7050/Nano-B4C Metal Matrix Composites","authors":"G. Ananth, T. Muthu Krishnan, S. Thirugnanam, Tewedaj Tariku Olkeba","doi":"10.1155/2023/3615093","DOIUrl":"https://doi.org/10.1155/2023/3615093","url":null,"abstract":"Aluminum matrix composites are widely employed in aerospace, military, automobile, and transport applications. The high-strength with low-weight materials are required to fulfill the requirement of high-performance applications. The low-weight materials are reinforced with hard reinforcements to obtain high-strength-to-weight properties for using high-performance applications. The process parameters of fabrication technique define the mechanical and tribological properties. Many types of optimization tools are used for optimizing the process parameters of fabrication method. In this research, the aluminum alloy 7050 and boron carbide are selected as matrix material and reinforcement material. The fabrication of Al7050/B4C composites is produced by the stir casting method. The optimization on stir casting process parameters is done by using the Taguchi approach. The L9 orthogonal array is chosen for this investigation. The chosen input stir casting process parameters are wt% B4C, stirring time (10, 15, and 20 min), stirring speed (300, 350, and 400 rpm), and melting temperature (700, 750, and 800°C). The microhardness is selected as a valuable response parameter for optimizing the stir casting process parameters. The influencing stir casting process parameter sequence is determined by using mean table. The influencing parameters of stir casting on microhardness are stirring speed, stirring time, wt% B4C, and melting temperature. The 9 wt% of boron carbide addition increases the microhardness, and it is higher than the other wt%. The optimum combination of input process parameter combination is 9 wt% boron carbide, 750°C melting temperature, 350 rpm stirring speed, and 15 min stirring time (A3B2C2D2). The percentage of microhardness value improvement is 20.3%.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"59 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74617064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Surrya prakash, V. Rajangam, Joby Joseph, S. Rajeshkannan, E. Shankar, A. Gopalan, Pravin P. Patil, Subash Thanappan
Aluminum metal matrix composites (AMCs) have been employed in automobile manufacturing to reduce weight. Also this research concentrates on the tribological performances on the processed AMCs by the stir casting liquefying method. The aluminum alloy Al2024 was employed to nanoparticles of aluminum oxide for the preparation of AMCs with constant processing condition of stirring speed to produce the homogeneous dispersion. The processed composites were further investigated to identify the wear characteristics. Therefore, the dry sliding condition was achieved on the processed composites. The input parameters of dry sliding conditions are sliding distance, functional load, and sliding velocity, and the output characteristics are wear rate and coefficient of friction (COF). Those input parameters are framed by the Taguchi L9 array and parameters were further employed to optimize with grey relational analysis. From the L9 parameters, the better wear rate and COF were accumulated in the following parameter: 2,100 mm of sliding distance, 25 N of functional load, and 2.5 m/s of sliding velocity, respectively. Then the wear rates and COF values are subjected to produce the predicted responses with supporting of artificial neural network. Most of the predicted values are much higher than the actual wear response vales. The wear resistance of all the samples composed better performances with dispersion of nanoaluminum oxide particles on the Al2024 alloy.
{"title":"Synthesized Nanoaluminum Oxide with Al2024 to Investigate Wear Behavior by Grey Relational Approach and ANN","authors":"D. Surrya prakash, V. Rajangam, Joby Joseph, S. Rajeshkannan, E. Shankar, A. Gopalan, Pravin P. Patil, Subash Thanappan","doi":"10.1155/2023/9788451","DOIUrl":"https://doi.org/10.1155/2023/9788451","url":null,"abstract":"Aluminum metal matrix composites (AMCs) have been employed in automobile manufacturing to reduce weight. Also this research concentrates on the tribological performances on the processed AMCs by the stir casting liquefying method. The aluminum alloy Al2024 was employed to nanoparticles of aluminum oxide for the preparation of AMCs with constant processing condition of stirring speed to produce the homogeneous dispersion. The processed composites were further investigated to identify the wear characteristics. Therefore, the dry sliding condition was achieved on the processed composites. The input parameters of dry sliding conditions are sliding distance, functional load, and sliding velocity, and the output characteristics are wear rate and coefficient of friction (COF). Those input parameters are framed by the Taguchi L9 array and parameters were further employed to optimize with grey relational analysis. From the L9 parameters, the better wear rate and COF were accumulated in the following parameter: 2,100 mm of sliding distance, 25 N of functional load, and 2.5 m/s of sliding velocity, respectively. Then the wear rates and COF values are subjected to produce the predicted responses with supporting of artificial neural network. Most of the predicted values are much higher than the actual wear response vales. The wear resistance of all the samples composed better performances with dispersion of nanoaluminum oxide particles on the Al2024 alloy.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"16 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86669931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ban Ali Sabri, M. Satgunam, A. Manap, C. L. Gnanasagaran, K. Ramachandran
The aim of this study is to investigate the effect of isopropyl triisostearoyl titanate (KR-TTS) as a titanate coupling agent (TCA) on surface modification of TiO2 nanotube (TNT) material. From the physical and chemical studies that have been performed on the modified TiO2 nanotube, scanning electron microscope micrographs, energy-dispersive X-ray and viscosity indicated that there was significant reduction in particle aggregation of the modified TiO2 Nanotube. FTIR spectroscopy confirmed that the functional group of the TCA reacted with the hydroxyl groups present on the surface of TiO2 nanotube resulting in an altered surface property from being hydrophilic to hydrophobic. X-ray diffraction indicated that crystalline structure did not change upon the modification with the coupling agent. Isopropyl triisostearoyl titanate (KR-TTS) is found to be superior in performance and has a significant effect on the dispersion and resolving of agglomeration. This paper presents the effect of surface modification with the TCA of isopropyl triisostearoyl titanate (KR-TTS) type on the TiO2 nanotube material.
{"title":"Physical and Chemical Investigation of TiO2 Nanotubes Treated with Isopropyl Triisostearoyl Titanate (KR-TTS)","authors":"Ban Ali Sabri, M. Satgunam, A. Manap, C. L. Gnanasagaran, K. Ramachandran","doi":"10.1155/2023/7961857","DOIUrl":"https://doi.org/10.1155/2023/7961857","url":null,"abstract":"The aim of this study is to investigate the effect of isopropyl triisostearoyl titanate (KR-TTS) as a titanate coupling agent (TCA) on surface modification of TiO2 nanotube (TNT) material. From the physical and chemical studies that have been performed on the modified TiO2 nanotube, scanning electron microscope micrographs, energy-dispersive X-ray and viscosity indicated that there was significant reduction in particle aggregation of the modified TiO2 Nanotube. FTIR spectroscopy confirmed that the functional group of the TCA reacted with the hydroxyl groups present on the surface of TiO2 nanotube resulting in an altered surface property from being hydrophilic to hydrophobic. X-ray diffraction indicated that crystalline structure did not change upon the modification with the coupling agent. Isopropyl triisostearoyl titanate (KR-TTS) is found to be superior in performance and has a significant effect on the dispersion and resolving of agglomeration. This paper presents the effect of surface modification with the TCA of isopropyl triisostearoyl titanate (KR-TTS) type on the TiO2 nanotube material.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"14 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85106529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. Natrayan, Raviteja Surakasi, Pravin P. Patil, S. Kaliappan, V. Selvam, P. Murugan
High specific strength, strength-to-weight ratio, cheap cost, and other advantages, nanofillers are now the subject of most research on natural fibers. The current research’s main goal is to combine the Taguchi and artificial neural networks (ANN) approaches to maximize the mechanical characteristics of nanocomposites. The parameters: (i) nano-SiO2 wt%, (ii) banana fiber wt%, (iii) compression pressure in MPa, and (iv) compression molding temperature in °C were selected to achieve the objectives above. An L16 orthogonal array was used to optimize the process parameters based on the Taguchi technique. According to the intended experiment, mechanical characteristics, such as tension, bending, and impact strength, were assessed. The ANN was used to forecast outcomes that were optimized. The fiber mat thickness of banana fiber and the weight ratio of nano-SiO2 showed a considerable improvement in the mechanical characteristics of hybrid composites. According to the Taguchi technique, the most significant mechanical characteristics were 47.36 MPa tensile, 64.48 MPa flexural, and 35.33 kJ of impact under circumstances of 5% SiO2, 19 MPa pressure, and 110 °C. With 95% accuracy, ANN-predicted mechanical strength. The ANN forecast was more accurate than the regression model and experimental data. The above nanobased hybrid composites are mainly employed to satisfy the needs of the contemporary vehicle sector.
{"title":"Optimizing Numerous Influencing Parameters of Nano-SiO2/Banana Fiber-Reinforced Hybrid Composites using Taguchi and ANN Approach","authors":"L. Natrayan, Raviteja Surakasi, Pravin P. Patil, S. Kaliappan, V. Selvam, P. Murugan","doi":"10.1155/2023/3317584","DOIUrl":"https://doi.org/10.1155/2023/3317584","url":null,"abstract":"High specific strength, strength-to-weight ratio, cheap cost, and other advantages, nanofillers are now the subject of most research on natural fibers. The current research’s main goal is to combine the Taguchi and artificial neural networks (ANN) approaches to maximize the mechanical characteristics of nanocomposites. The parameters: (i) nano-SiO2 wt%, (ii) banana fiber wt%, (iii) compression pressure in MPa, and (iv) compression molding temperature in °C were selected to achieve the objectives above. An L16 orthogonal array was used to optimize the process parameters based on the Taguchi technique. According to the intended experiment, mechanical characteristics, such as tension, bending, and impact strength, were assessed. The ANN was used to forecast outcomes that were optimized. The fiber mat thickness of banana fiber and the weight ratio of nano-SiO2 showed a considerable improvement in the mechanical characteristics of hybrid composites. According to the Taguchi technique, the most significant mechanical characteristics were 47.36 MPa tensile, 64.48 MPa flexural, and 35.33 kJ of impact under circumstances of 5% SiO2, 19 MPa pressure, and 110 °C. With 95% accuracy, ANN-predicted mechanical strength. The ANN forecast was more accurate than the regression model and experimental data. The above nanobased hybrid composites are mainly employed to satisfy the needs of the contemporary vehicle sector.","PeriodicalId":16442,"journal":{"name":"Journal of Nanomaterials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79413147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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