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Retracted: The Mathematical Analysis of the New Fractional Order Ebola Model 撤回:新分数阶埃博拉模型的数学分析
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-21 DOI: 10.1155/2023/9854956
Journal of Nanomaterials
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引用次数: 1
Retracted: Copper Oxide Nanoparticles Incorporated in the Metal Mesh Used to Enhance the Heat Transfer Performance of the Catalytic Converter and to Reduce Emission 撤回:金属网中的纳米氧化铜颗粒用于提高催化转换器的传热性能和减少排放
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-21 DOI: 10.1155/2023/9810313
Journal of Nanomaterials
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引用次数: 0
Retracted: Utilization of Eco-Friendly Waste Eggshell Catalysts for Enhancing Liquid Product Yields through Pyrolysis of Forestry Residues 撤回:利用环保型废蛋壳催化剂提高林业废弃物热解液体产品产量
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-21 DOI: 10.1155/2023/9848562
Journal of Nanomaterials
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引用次数: 18
Retracted: Spatial-Temporal Variation Characteristics of Soil Moisture and Nutrients Based on Nanomaterials in the Root Zone of Haloxylon ammodendron Seedlings 撤回:基于纳米材料的哈龙幼苗根区土壤水分和养分的时空变化特征
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-21 DOI: 10.1155/2023/9825217
Journal of Nanomaterials
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引用次数: 0
Retracted: The Study of Expanded Polytetrafluoroethylene New Material in Dural Repair 撤回:硬脑膜修复中的膨胀聚四氟乙烯新材料研究
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-21 DOI: 10.1155/2023/9860505
Journal of Nanomaterials
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引用次数: 0
Insight into Perovskite Solar Cell Formation for Various Organohalides Perovskite Precursors in the Presence of Water at the Molecular Level 不同有机卤化物钙钛矿前体在水的存在下在分子水平上形成钙钛矿太阳能电池
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-19 DOI: 10.1155/2023/6279023
S. Zhantuarov, A. Kemelbekova, A. Shongalova, K. Aimaganbetov, Zh. A. Sailau, A. Aldongarov, A. Serikkanov, N. Chuchvaga, Nurlan Almas
Recently, hybrid (organic–inorganic) metal halide perovskites have gained significant attention due to their excellent performance in optoelectronics and photovoltaics (PV). Single-junction PV cells made from these materials have achieved record efficiencies of over 25%, with the potential for further improvement in the future. The crystal structure of organohalide perovskite semiconductors plays a crucial role in the success of perovskites. In this study, we used classical all-atom molecular dynamics simulations to investigate the dynamics of ionic precursors as they form organic halide perovskite units in the presence of water as a solvent. During the analysis of radial distribution functions, interaction energies, hydrogen bonding, and diffusion coefficients, it was confirmed that organic precursors aggregate in the absence of water and disperse in the presence of water. The interaction energies also showed that the organic precursors of the perovskite have weaker interactions with Pb than the other components of the perovskite. The hydrogen bonding analysis revealed that the number of hydrogen bonds between the organic precursors and Cl decreases in the presence of water, but hydrogen bonds form between the organic precursors/water and Cl/water. Additionally, the diffusion coefficients of the organic precursors were found to be in the following increasing order: 2,2-(ethylenedioxy) bis ethylammonium (EDBE2+) < guanidium (GA+) < phenethylammonium (PEA+) < iso-butylammonium (Iso-BA+).
近年来,杂化(有机-无机)金属卤化物钙钛矿因其在光电子学和光伏(PV)领域的优异性能而受到广泛关注。由这些材料制成的单结光伏电池的效率达到了创纪录的25%以上,并且在未来有进一步提高的潜力。有机卤化物钙钛矿半导体的晶体结构对钙钛矿的成功起着至关重要的作用。在这项研究中,我们使用经典的全原子分子动力学模拟来研究离子前体在水作为溶剂存在下形成有机卤化物钙钛矿单元的动力学。通过对径向分布函数、相互作用能、氢键和扩散系数的分析,证实了有机前驱体在无水时聚集,有水时分散。相互作用能还表明,钙钛矿有机前驱体与Pb的相互作用弱于钙钛矿的其他组分。氢键分析表明,有水存在时,有机前驱体与Cl之间的氢键数减少,而有机前驱体/水与Cl/水之间形成氢键。有机前驱体的扩散系数依次为2,2-(乙二氧基)二乙基铵(EDBE2+) <胍(GA+) <苯乙基铵(PEA+) <异丁铵(Iso-BA+)。
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引用次数: 0
Improving the Photo Electro Catalytic Degradation of Methylene Blue by Modified TiO2/ITO Photo Anodes 改性TiO2/ITO光阳极改善亚甲基蓝的光电催化降解
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-15 DOI: 10.1155/2023/1722978
Jihad Alsaleh Almohammad, M. Hashem, Hanan Alchaghouri, I. Alghoraibi
TiO2 photoanodes have gained significant attention for the removal of organic pollutants through photoelectrocatalytic processes, with the aim of developing a cost-effective and efficient method for improving the degradation of pollutants in surface water. This study investigated the effects of adding titanium nanooxide (Degussa P25) containing 70% anatase and 30% rutile phases on the properties of nanostructured TiO2 photoanodes prepared on glass substrates (indium tin oxide (ITO)) using sol–gel/dip coating techniques The results obtained from ultraviolet–visible transmittance spectroscopy, electrochemical (EC) impedance spectroscopy, photocurrent, and atomic force microscopy analyses revealed that the addition of Degussa P25 improved the electrical conductivity of the TiO2/ITO anode and reduced the optical bandgap from 3.50 to 3.35 eV, while the size of the titanium oxide particles decreased to about 75 nm. The EC impedance spectra measurement confirms that the addition of titanium nanooxide Degussa P25 improved the electrical conductivity for TiO2/ITO anode. The photoelectrocatalysis (PEC) performance of the TiO2 photoanodes was investigated via the degradation of methylene blue (MB) under UVA light irradiation. The AB photoanode (with the addition of Degussa P25) exhibited excellent PEC performance, with 95.9% color removal efficiency and 63% total organic carbon (TOC) removal efficiency, compared to 92% color removal efficiency and 56% TOC removal efficiency for the A photoanode (without the addition of Degussa P25). The kinetic constants (k) were 134 × 10−4, 110 × 10−4 (min−1) for A and AB anodes, respectively, and the degradation of MB followed first-order kinetics for all anodes. The A and AB anodes were compared as electrodes for the degradation of MB using PEC, photocatalysis (PC), and EC technologies. Subsequently, The A and AB anodes were utilized as electrodes to compare the performance of PEC, PC, and EC technologies for the degradation of MB. The results showed that the AB anode exhibited higher efficiency in all PC technologies, with color removal (%) efficiencies of 95.9% (PEC), 33% (PC), and 21% (EC) compared to 92% (PEC), 28% (PC), and 19% (EC) for the A anode. Additionally, the photooxidation process had a 2.1% effect on the degradation of the initial MB concentration.
二氧化钛光阳极在通过光电催化过程去除有机污染物方面受到了极大的关注,其目的是开发一种经济有效的方法来改善地表水中污染物的降解。本文研究了添加含有70%锐钛矿和30%金红石相的纳米氧化钛(Degussa P25)对采用溶胶-凝胶/浸涂技术在玻璃衬底(氧化铟锡(ITO))上制备的纳米结构TiO2光阳极性能的影响。原子力显微镜分析结果表明,加入Degussa P25提高了TiO2/ITO阳极的电导率,将光学带隙从3.50 eV减小到3.35 eV,而氧化钛颗粒的尺寸减小到约75 nm。EC阻抗谱测试证实,纳米氧化钛Degussa P25的加入提高了TiO2/ITO阳极的电导率。通过UVA光照射对亚甲基蓝(MB)的降解,研究了TiO2光阳极的光电催化性能。AB光阳极(添加德固赛P25)表现出优异的PEC性能,其去色效率为95.9%,总有机碳(TOC)去除率为63%,而A光阳极(未添加德固赛P25)的去色效率为92%,TOC去除率为56%。A和AB阳极的动力学常数k分别为134 × 10−4和110 × 10−4 (min−1),所有阳极对MB的降解均符合一级动力学。比较了A和AB阳极作为PEC、光催化(PC)和EC技术降解MB的电极。随后,将A和AB阳极用作电极,比较PEC、PC和EC技术对MB的降解性能。结果表明,AB阳极在所有PC技术中都表现出更高的效率,其去色效率(%)分别为95.9% (PEC)、33% (PC)和21% (EC),而A阳极的去色效率为92% (PEC)、28% (PC)和19% (EC)。此外,光氧化过程对初始MB浓度的降解有2.1%的影响。
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引用次数: 1
The Effect of Internalized Paramagnetic Nanoparticles on Caenorhabditis elegans Locomotion in the Presence of Magnetic Field 内化顺磁性纳米颗粒对磁场作用下秀丽隐杆线虫运动的影响
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-10 DOI: 10.1155/2023/1634691
E. Gourgou, E. Mirzakhalili, Yang Zhang, B. Epureanu
Caenorhabditis elegans nematodes are broadly used to investigate the impact of environmental factors on animal physiology and behavior. Here, C. elegans with internalized paramagnetic nanoparticles were placed inside a magnetic field (MF) to explore its effects on locomotion. We hypothesized that internalized paramagnetic nanoparticles combined with external MF affect C. elegans’ locomotion machinery. To test our hypothesis, we used adult C. elegans fed on bacteria mixed with paramagnetic nanoparticles of 1 μm, 100, and 40 nm diameter. The presence of nanoparticles inside the worms’ body (alimentary canal, body muscle) was verified by fluorescent and electron microscopy. A custom-made software was used to track freely moving C. elegans in the absence or presence of MF, sequentially, for 200 + 200 s. We used established metrics to quantify locomotion-related parameters, including posture, motion, and path features. Key attributes of C. elegans locomotion (stay ratio, forward over backward motion, speed) were affected only in worms with internalized nanoparticles of 100 nm in the presence of MF (reduced speed, increased stay ratio, decreased forward/backward ratio), in contrast to untreated worms. Our work shows that internalized particles of specific properties affect C. elegans locomotion under MF. Hence, it contributes to clarifying the effects of MF and activated nanoparticles on C. elegans locomotion, thus fueling further research.
秀丽隐杆线虫被广泛用于研究环境因素对动物生理和行为的影响。本研究将线虫内化的顺磁性纳米颗粒置于磁场(MF)中,以探索其对运动的影响。我们假设内源性顺磁性纳米颗粒与外源性磁场联合影响秀丽隐杆线虫的运动机制。为了验证我们的假设,我们用线虫成虫喂养了混合了直径为1 μm、100和40 nm的顺磁性纳米颗粒的细菌。荧光显微镜和电子显微镜证实了蠕虫体内(消化道、身体肌肉)存在纳米颗粒。使用定制的软件在没有或存在MF的情况下依次跟踪秀丽隐杆线虫的自由移动,时间为200 + 200 s。我们使用既定的指标来量化运动相关参数,包括姿势、运动和路径特征。与未处理的线虫相比,只有在MF存在下内服100 nm纳米颗粒的线虫运动的关键属性(停留比、向前/向后运动、速度)受到影响(速度降低、停留比增加、向前/向后比降低)。我们的工作表明,特定性质的内化颗粒影响线虫在MF下的运动。因此,这有助于阐明MF和活化纳米颗粒对秀丽隐杆线虫运动的影响,从而为进一步的研究提供依据。
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引用次数: 0
Cadmium Sulfide Nanoparticles: Synthesis, Characterization, and Antimicrobial Study 硫化镉纳米颗粒:合成、表征和抗菌研究
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-07 DOI: 10.1155/2023/8187000
Amrit Regmi, Yamlal Basnet, Sitaram Bhattarai, S. K. Gautam
Group II–VI cadmium sulfide nanoparticles (CdS NPs), a potential alternative to antibiotics, were synthesized using cadmium acetate [Cd(Ac)2] as a precursor, sodium sulfate as a reducing agent, and starch as a capping agent through chemical precipitation techniques. The CdS NPs were characterized using different characterizing techniques; X-ray diffraction and selected area electron diffraction patterns verify that the nanoparticles had cubic zinc blende structure with average dimension size of 2.43 nm. Scanning electron mictroscope and transmission electron microscope images illustrated that the particles were uniformly distributed in cluster form, and FTIR and EDX confirmed the synthesized nanoparticles were pure. The CdS NPs show relevant antimicrobial sensitivity against Gram-positive and Gram-negative bacterial strains and the zone of inhibition increases with the increase in the concentration of nanoparticles. In comparison to Gram-positive and Gram-negative bacteria, the synthesized nanoparticles were reported to be more effective toward Staphylococcus aureus, Gram-positive bacteria.
以醋酸镉[Cd(Ac)2]为前体,硫酸钠为还原剂,淀粉为封盖剂,通过化学沉淀法合成了II-VI族硫化镉纳米颗粒(CdS NPs),这是一种潜在的抗生素替代品。采用不同的表征技术对CdS NPs进行了表征;x射线衍射图和选择区域电子衍射图验证了纳米颗粒具有立方型闪锌矿结构,平均尺寸为2.43 nm。扫描电镜和透射电镜图像表明,纳米颗粒呈簇状均匀分布,FTIR和EDX证实合成的纳米颗粒纯度较高。CdS NPs对革兰氏阳性和革兰氏阴性菌株均表现出相应的抗菌敏感性,且抑制区随纳米颗粒浓度的增加而增大。与革兰氏阳性菌和革兰氏阴性菌相比,合成的纳米颗粒对革兰氏阳性菌金黄色葡萄球菌更有效。
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引用次数: 1
Optimization of Machining Parameters of Natural/Glass Fiber with Nanoclay Polymer Composite Using Response Surface Methodology 利用响应面法优化纳米粘土复合材料加工天然/玻璃纤维的工艺参数
4区 材料科学 Q2 Materials Science Pub Date : 2023-06-02 DOI: 10.1155/2023/9485769
S. Ragunath, M. Rathod, K. Saravanan, N. Rakesh, Melkamu Kifetew
Machining processes are one of the most important finishing operations in the fabrication of composites, which contain natural fibers. However, it is difficult to attain a better fishing on the final components. Hence, an attempt has been made in the work to achieve a good surface finish in compression-molded hybrid fiber composites containing nanoclay particles by optimizing the milling parameters. Experiments were conducted by using Box–Behnken design (response surface methodology (RSM)) to optimize the milling process parameters such as spindle speed (16, 24, and 32 rpm), feed rate (0.1, 0.2, and 0.3 mm/rev.), and depth of cut (1, 1.5, 2 mm) along with different vol% of nanoclay content (3%, 6%, and 9%). The surface roughness of machined fiber composite was measured, and the most influential parameters were analyzed by analysis of variance, evaluation of signal-to-noise ratio, and mathematical models of responses were developed by RSM. The experimental results (A2B1C4D3) indicated that the feed rate is one of the most significant parameters, followed by nanoclay content, depth of cut, and spindle speed. Surface roughness was found to decrease continuously (2.18–2.08 µm) with increasing nanoclay content (up to 6%) at a certain limit and further addition of clay content (above 6%); the results were declined (2.42 µm) for the same levels of other parameters.
机械加工是制备含天然纤维的复合材料中最重要的精加工工序之一。然而,在最终部件上很难获得更好的钓鱼效果。因此,本文试图通过优化铣削参数,使含纳米粘土颗粒的压缩成型混杂纤维复合材料具有良好的表面光洁度。实验采用Box-Behnken设计(响应面法)优化铣削工艺参数,如主轴转速(16、24和32 rpm)、进给速度(0.1、0.2和0.3 mm/rev.)和切削深度(1、1.5、2mm)以及纳米粘土含量的不同vol%(3%、6%和9%)。对加工后的复合材料表面粗糙度进行了测量,通过方差分析、信噪比评价等方法分析了影响复合材料表面粗糙度的主要参数,并利用RSM方法建立了复合材料表面粗糙度响应的数学模型。实验结果(A2B1C4D3)表明,进给速度是最重要的参数之一,其次是纳米粘土含量、切削深度和主轴转速。在一定限度内,随着纳米粘土含量的增加(达到6%)和粘土含量的进一步增加(超过6%),表面粗糙度不断减小(2.18 ~ 2.08µm);对于相同水平的其他参数,结果下降了2.42µm。
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引用次数: 0
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Journal of Nanomaterials
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