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Width of Nucleation Region of Si Nanocrystal Grains Prepared by Pulsed Laser Ablation with Different Laser Fluence 不同激光辐照强度下脉冲激光烧蚀制备硅纳米晶的成核区宽度
Pub Date : 2015-03-23 DOI: 10.1155/2015/105685
Z. Deng, X. Pang, Xuecheng Ding, L. Chu, Ying-long Wang
Si nanocrystal grains were prepared by pulsed laser ablation with different laser fluence in Ar gas of 10 Pa at room temperature. The as-formed grains in the space deposited on the substrates and distributed in a certain range apart from target. According to the depositing position and radius of grains, the nucleation locations of grains in the space were roughly calculated. The results indicated that the width of nucleation region broadened with increasing of ion densities diagnosed by Langmuir probe, which increased with laser fluence from 2 J/cm2 to 6 J/cm2; that is, width of nucleation region broadened with addition of laser fluence. At the same time, the width broadened with the terminal formation position moving backward and the initial formation position of grains moving toward ablated spot. The experimental results were explained reasonably by nucleation thermokinetic theory.
采用不同激光辐照强度的脉冲激光烧蚀方法,在10 Pa氩气中制备了硅纳米晶。在空间中形成的颗粒沉积在基体上,并在远离靶材的一定范围内分布。根据晶粒的沉积位置和半径,粗略计算出晶粒在空间中的形核位置。结果表明:Langmuir探针检测的成核区宽度随着离子密度的增加而变宽,离子密度随激光能量从2 J/cm2增加到6 J/cm2;即随着激光通量的增加,成核区宽度变宽。同时,随着晶粒最终形成位置向后移动,晶粒初始形成位置向烧蚀点移动,晶粒宽度逐渐变宽。用成核热动力学理论对实验结果进行了合理的解释。
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引用次数: 3
Issues Affecting the Synthetic Scalability of Ternary Metal Ferrite Nanoparticles 影响三元金属铁氧体纳米颗粒合成可扩展性的问题
Pub Date : 2015-01-01 DOI: 10.1155/2015/105862
Lauren Morrow, A. Barron
Ternary Mn-Zn ferrite (MnxZn1-xFe2O4) nanoparticles (NPs) have been prepared by the thermal decomposition of an oleate complex, sodium dodecylbenzenesulfonate (SDBS) mediated hydrazine decomposition of the chloride salts, and triethylene glycol (TREG) mediated thermal decomposition of the metal acetylacetonates. Only the first method was found to facilitate the synthesis of uniform, isolable NPs with the correct Mn : Zn ratio (0.7 : 0.3) as characterized by small angle X-ray scattering (SAXS), transmission electron microscopy (TEM), and inductively coupled plasma-optical emission spectroscopy (ICP-OES). Scaling allowed for retention of the composition and size; however, attempts to prepare Zn-rich ferrites did not result in NP formation. Thermogravimetric analysis (TGA) indicated that the incomplete decomposition of the metal-oleate complexes prior to NP nucleation for Zn-rich compositions is the cause.
通过油酸配合物的热分解、十二烷基苯磺酸钠(SDBS)介导的氯盐肼分解和三甘醇(TREG)介导的金属乙酰丙酮酸盐的热分解制备了锰锌铁氧体纳米颗粒(MnxZn1-xFe2O4)。通过小角x射线散射(SAXS)、透射电子显微镜(TEM)和电感耦合等离子体光学发射光谱(ICP-OES)表征,发现只有第一种方法可以合成均匀、可分离的纳米粒子,且Mn: Zn比为0.7:0.3。缩放允许保留成分和大小;然而,试图制备富锌铁氧体并没有导致NP的形成。热重分析(TGA)表明,富锌成分在NP成核之前金属油酸配合物的不完全分解是其原因。
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引用次数: 5
Carbon Dot Based Sensing of Dopamine and Ascorbic Acid 基于碳点的多巴胺和抗坏血酸传感
Pub Date : 2014-12-29 DOI: 10.1155/2014/178518
Upama Baruah, Neelam Gogoi, Achyut Konwar, M. Deka, D. Chowdhury, G. Majumdar
We demonstrate carbon dot based sensor of catecholamine, namely, dopamine and ascorbic acid. Carbon dots (CDs) were prepared from a green source: commercially available Assam tea. The carbon dots prepared from tea had particle sizes of ∼0.8 nm and are fluorescent. Fluorescence of the carbon dots was found to be quenched in the presence of dopamine and ascorbic acid with greater sensitivity for dopamine. The minimum detectable limits were determined to be 33 μM and 98 μM for dopamine and ascorbic acid, respectively. The quenching constants determined from Stern-Volmer plot were determined to be 5 × 10−4 and 1 × 10−4 for dopamine and ascorbic acid, respectively. A probable mechanism of quenching has been discussed in the paper.
我们展示了基于碳点的传感器的儿茶酚胺,即多巴胺和抗坏血酸。碳点(cd)是由一种绿色来源制备的:市售的阿萨姆茶。用茶叶制备的碳点粒径为~ 0.8 nm,具有荧光性。发现碳点的荧光在多巴胺和抗坏血酸存在时被淬灭,对多巴胺更敏感。多巴胺和抗坏血酸的最低检出限分别为33 μM和98 μM。通过Stern-Volmer图确定多巴胺和抗坏血酸的猝灭常数分别为5 × 10−4和1 × 10−4。本文讨论了一种可能的淬火机理。
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引用次数: 56
Synthesis of Platinum Nanoparticles from K2PtCl4 Solution Using Bacterial Cellulose Matrix 利用细菌纤维素基质从K2PtCl4溶液合成纳米铂
Pub Date : 2014-12-14 DOI: 10.1155/2014/285954
H. Aritonang, D. Onggo, C. Ciptati, C. Radiman
Platinum (Pt) nanoparticles have been synthesized from a precursor solution of potassium tetrachloroplatinate (K2PtCl4) using a matrix of bacterial cellulose (BC). The formation of Pt nanoparticles occurs at the surface and the inside of the BC membrane by reducing the precursor solution with a hydrogen gas reductant. The Pt nanoparticles obtained from the variations of precursor concentration, between 3 mM and 30 mM, and the formation of Pt nanoparticles have been studied using X-ray diffraction (XRD), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), and thermogravimetry analysis (TGA). Based on X-ray diffraction patterns, Pt particles have sizes between 6.3 nm and 9.3 nm, and the Pt particle size increases with an increase in precursor concentration. The morphology of the Pt nanoparticles was observed by SEM-EDS and the content of Pt particles inside the membrane is higher than that on the surface of BC membranes. This analysis corresponds to the TGA analysis, but the TGA analysis is more representative in how it describes the content of Pt particles in the BC membrane.
以细菌纤维素(BC)为基质,以四氯铂酸钾(K2PtCl4)为前体溶液合成了铂(Pt)纳米颗粒。铂纳米粒子的形成发生在BC膜的表面和内部,是通过用氢气还原剂还原前驱体溶液来实现的。采用x射线衍射(XRD)、扫描电镜-能谱仪(SEM-EDS)和热重分析(TGA)研究了前驱体浓度在3 ~ 30 mM范围内变化得到的Pt纳米颗粒和Pt纳米颗粒的形成过程。x射线衍射图显示,Pt颗粒尺寸在6.3 ~ 9.3 nm之间,且Pt颗粒尺寸随前驱体浓度的增加而增大。通过扫描电镜能谱仪(SEM-EDS)对纳米Pt的形貌进行了观察,发现膜内的Pt含量高于BC膜表面的Pt含量。该分析与TGA分析相对应,但TGA分析在描述BC膜中Pt颗粒含量方面更具代表性。
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引用次数: 26
Aqueous Colloidal Stability of Graphene Oxide and Chemically Converted Graphene 氧化石墨烯和化学转化石墨烯的水性胶体稳定性
Pub Date : 2014-11-13 DOI: 10.1155/2014/640281
S. Kashyap, Shashank Mishra, S. Behera
Graphene oxide (GO) was prepared by modified Hummer’s method, and chemically converted graphene (CCG) was prepared by further reduction of the aqueous GO colloid. The effect of pH on particle size, particle charge, and light absorption of the aqueous colloids of GO and CCG was studied with titration against HCl or NaOH, to find the ideal characteristics for a stable dispersion. The GO colloid was stable in the pH range of 4–11, whereas the CCG colloid gained stability at a relatively narrower pH range of 7–10. Poor stability of the colloids was observed for both GO and CCG colloids at both extremes of the pH scale. Both of the colloids exhibited average size of ~1 micron in the low pH range, whereas for higher pH the size ranged between 300 and 500 nm. The UV-Vis spectra showed absorption peak at 230 nm for GO colloids that shifted to 260 nm for the CCG colloid. Such shift can be ascribed to restoring of electronic conjugation of the C=C bonds in CCG.
采用改进的Hummer方法制备氧化石墨烯(GO),通过进一步还原水相氧化石墨烯胶体制备化学转化石墨烯(CCG)。通过对HCl或NaOH的滴定,研究了pH对氧化石墨烯和CCG水性胶体粒径、粒子电荷和光吸收的影响,以找到稳定分散的理想特性。氧化石墨烯胶体在pH值4-11范围内稳定,而CCG胶体在相对较窄的pH值7-10范围内稳定。在两个极端的pH尺度下,氧化石墨烯和CCG胶体的稳定性都很差。在低pH范围内,两种胶体的平均粒径均为~1微米,而在高pH范围内,胶体的粒径在300 ~ 500 nm之间。紫外可见光谱显示氧化石墨烯胶体的吸收峰位于230 nm处,CCG胶体的吸收峰移至260 nm处。这种转变可以归因于CCG中C=C键的电子共轭的恢复。
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引用次数: 85
Spectropolarimetric Properties of a Gallium Nanoparticle Layer on a Sapphire Substrate 蓝宝石衬底上镓纳米颗粒层的光谱偏振特性
Pub Date : 2014-11-02 DOI: 10.1155/2014/408350
Prashanth Raman, K. Fuller, D. Gregory
Gallium nanoparticles (Ga NPs) are currently the subject of vigorous research as possible substrates in surface-enhanced Raman scattering (SERS) experiments in the ultraviolet spectral domain. Verification of any comprehensive model of the interaction of electromagnetic radiation with Ga NPs requires that complete polarimetric measurements be made. These spectropolarimetric properties can be obtained using a Mueller matrix spectropolarimeter (MMSP). The position of localized surface plasmon resonances (LSPRs) and spectral depolarization data of Ga NPs in the 300 to 1100 nm spectral region are presented. Spectral depolarization data may be of value in creating a better understanding of how light couples to individual nanoparticles, as well as the role played by interparticle coupling and the connection to phenomena such as SERS.
镓纳米粒子(Ga NPs)作为表面增强拉曼散射(SERS)实验的衬底是目前研究的热点。验证电磁辐射与Ga NPs相互作用的任何综合模型都需要进行完整的极化测量。这些光谱偏振特性可以用米勒矩阵光谱偏振计(MMSP)获得。给出了局域表面等离子体共振(LSPRs)的位置和Ga NPs在300 ~ 1100nm光谱区的光谱退极化数据。光谱去极化数据可能有助于更好地理解光如何与单个纳米粒子耦合,以及粒子间耦合所起的作用和与SERS等现象的联系。
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引用次数: 2
Plasmonic and Thermooptical Properties of Spherical Metallic Nanoparticles for Their Thermoplasmonic and Photonic Applications 球形金属纳米颗粒的热等离子体和热光学性质及其在热等离子体和光子方面的应用
Pub Date : 2014-10-14 DOI: 10.1155/2014/893459
V. Pustovalov, L. Astafyeva, W. Fritzsche
Investigations and use of nanoparticles (NPs) as photothermal (PT) agents in laser and optical nanotechnology are fast growing areas of research and applications. The potential benefits of NPs applications include possibility for thermal imaging and treatment of materials containing of NPs, applications of NPs for light-to-thermal energy conversion, in catalysis, laser nanomedicine, and chemistry. Efficiency of applications of metallic NPs for laser and optical nanotechnology depends on plasmonic and thermophysical properties of NPs, characteristics of radiation, and surrounding medium. Here we present the results of comparative analysis of NP properties (plasmonic, thermooptical, and others) allowing selecting their parameters for thermoplasmonic and photonic applications. Plasmonic and thermooptical properties of several metallic (aurum, silver, platinum, cobalt, zinc, nickel, titanium, cuprum, aluminum, molybdenum, vanadium, and palladium) NPs are theoretically investigated and analysis of them is carried out. Investigation of the influence of NPs parameters (type of metal, radii, optical indexes, density, and heat capacity of NP material), characteristics of radiation (wavelength and pulse duration), and ambient parameters on plasmonic and thermophysical properties of NPs has been carried out. It was established that maximum value of thermooptical parameter (maximum NP temperature) can be achieved with the use of absorption efficiency factor of NP smaller than its maximum value.
纳米粒子作为光热剂在激光和光学纳米技术中的研究和应用是一个快速发展的研究和应用领域。纳米粒子应用的潜在好处包括热成像和处理含有纳米粒子的材料的可能性,纳米粒子在光热能量转换、催化、激光纳米医学和化学中的应用。金属纳米粒子在激光和光学纳米技术中的应用效率取决于纳米粒子的等离子体和热物理性质、辐射特性和周围介质。在这里,我们提出了NP性质(等离子体、热光学和其他)的比较分析结果,允许为热等离子体和光子应用选择它们的参数。对几种金属(金、银、铂、钴、锌、镍、钛、铜、铝、钼、钒和钯)NPs的等离子体和热光学性质进行了理论研究和分析。研究了纳米粒子参数(纳米粒子材料的金属类型、半径、光学指标、密度和热容)、辐射特性(波长和脉冲持续时间)和环境参数对纳米粒子等离子体和热物理性质的影响。利用NP的吸收效率因子小于其最大值时,可以获得热光学参数的最大值(最大NP温度)。
{"title":"Plasmonic and Thermooptical Properties of Spherical Metallic Nanoparticles for Their Thermoplasmonic and Photonic Applications","authors":"V. Pustovalov, L. Astafyeva, W. Fritzsche","doi":"10.1155/2014/893459","DOIUrl":"https://doi.org/10.1155/2014/893459","url":null,"abstract":"Investigations and use of nanoparticles (NPs) as photothermal (PT) agents in laser and optical nanotechnology are fast growing areas of research and applications. The potential benefits of NPs applications include possibility for thermal imaging and treatment of materials containing of NPs, applications of NPs for light-to-thermal energy conversion, in catalysis, laser nanomedicine, and chemistry. Efficiency of applications of metallic NPs for laser and optical nanotechnology depends on plasmonic and thermophysical properties of NPs, characteristics of radiation, and surrounding medium. Here we present the results of comparative analysis of NP properties (plasmonic, thermooptical, and others) allowing selecting their parameters for thermoplasmonic and photonic applications. Plasmonic and thermooptical properties of several metallic (aurum, silver, platinum, cobalt, zinc, nickel, titanium, cuprum, aluminum, molybdenum, vanadium, and palladium) NPs are theoretically investigated and analysis of them is carried out. Investigation of the influence of NPs parameters (type of metal, radii, optical indexes, density, and heat capacity of NP material), characteristics of radiation (wavelength and pulse duration), and ambient parameters on plasmonic and thermophysical properties of NPs has been carried out. It was established that maximum value of thermooptical parameter (maximum NP temperature) can be achieved with the use of absorption efficiency factor of NP smaller than its maximum value.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"29 1","pages":"1-15"},"PeriodicalIF":0.0,"publicationDate":"2014-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86219449","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Plant-Mediated Green Synthesis of Iron Nanoparticles 植物介导的铁纳米颗粒绿色合成
Pub Date : 2014-10-02 DOI: 10.1155/2014/140614
M. Herlekar, S. Barve, Rakesh Kumar
In the recent years, nanotechnology has emerged as a state-of-the-art and cutting edge technology with multifarious applications in a wide array of fields. It is a very broad area comprising of nanomaterials, nanotools, and nanodevices. Amongst nanomaterials, majority of the research has mainly focused on nanoparticles as they can be easily prepared and manipulated. Physical and chemical methods are conventionally used for the synthesis of nanoparticles; however, due to several limitations of these methods, research focus has recently shifted towards the development of clean and eco-friendly synthesis protocols. Magnetic nanoparticles constitute an important class of inorganic nanoparticles, which find applications in different areas by virtue of their several unique properties. Nevertheless, in comparison with biological synthesis protocols for noble metal nanoparticles, limited study has been carried out with respect to biological synthesis of magnetic nanoparticles. This review focuses on various studies outlining the novel routes for biosynthesis of these nanoparticles by plant resources along with outlining the future scope of work in this area.
近年来,纳米技术已成为一项先进的尖端技术,在许多领域得到广泛的应用。这是一个非常广泛的领域,包括纳米材料、纳米工具和纳米器件。在纳米材料中,由于纳米颗粒易于制备和操作,研究主要集中在纳米颗粒上。物理和化学方法通常用于纳米粒子的合成;然而,由于这些方法的一些局限性,研究重点最近转移到开发清洁和环保的合成方案。磁性纳米颗粒是一类重要的无机纳米颗粒,凭借其独特的性能在不同的领域得到了广泛的应用。然而,与贵金属纳米颗粒的生物合成方案相比,磁性纳米颗粒的生物合成研究有限。本文综述了利用植物资源生物合成这些纳米颗粒的新途径,并概述了该领域未来的工作范围。
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引用次数: 239
Synthesis of Silver Nanoparticles in Photosynthetic Plants 纳米银在光合植物中的合成
Pub Date : 2014-09-25 DOI: 10.1155/2014/963961
R. Prasad
Nanobiotechnology is emerging as a field of applied biological science and nanotechnology. Synthesis of nanoparticles is done by various physical and chemical methods but the biological methods are relatively simple, cost-effective, nontoxic, and environmentally friendly methods. The present review focuses on the synthesis of nanoparticles with special emphasis on the use of plants parts for the synthesis process, its applications, and future prospectus.
纳米生物技术是应用生物科学和纳米技术的一个新兴领域。纳米粒子的合成有多种物理和化学方法,但生物方法是相对简单、经济、无毒、环保的方法。本文对纳米颗粒的合成进行了综述,重点介绍了植物成分在纳米颗粒合成中的应用,并展望了纳米颗粒的应用前景。
{"title":"Synthesis of Silver Nanoparticles in Photosynthetic Plants","authors":"R. Prasad","doi":"10.1155/2014/963961","DOIUrl":"https://doi.org/10.1155/2014/963961","url":null,"abstract":"Nanobiotechnology is emerging as a field of applied biological science and nanotechnology. Synthesis of nanoparticles is done by various physical and chemical methods but the biological methods are relatively simple, cost-effective, nontoxic, and environmentally friendly methods. The present review focuses on the synthesis of nanoparticles with special emphasis on the use of plants parts for the synthesis process, its applications, and future prospectus.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"1 1","pages":"1-8"},"PeriodicalIF":0.0,"publicationDate":"2014-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87880179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 316
Preparation of Cerium Orthophosphate Nanosphere by Coprecipitation Route and Its Structural, Thermal, Optical, and Electrical Characterization 共沉淀法制备正磷酸铈纳米球及其结构、热、光学和电学表征
Pub Date : 2014-09-16 DOI: 10.1155/2014/125360
S. Verma, K. Bamzai
Cerium orthophosphate (CePO4) nanoparticles were synthesized via wet chemical coprecipitation technique using cerium nitrate hexahydrate for Ce3
以六水硝酸铈为原料,采用湿化学共沉淀法合成了正磷酸铈(CePO4)纳米颗粒
{"title":"Preparation of Cerium Orthophosphate Nanosphere by Coprecipitation Route and Its Structural, Thermal, Optical, and Electrical Characterization","authors":"S. Verma, K. Bamzai","doi":"10.1155/2014/125360","DOIUrl":"https://doi.org/10.1155/2014/125360","url":null,"abstract":"Cerium orthophosphate (CePO4) nanoparticles were synthesized via wet chemical coprecipitation technique using cerium nitrate hexahydrate for Ce3","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"98 1","pages":"1-12"},"PeriodicalIF":0.0,"publicationDate":"2014-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90008608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 26
期刊
Journal of Nanoparticles
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