首页 > 最新文献

Journal of Nanoparticles最新文献

英文 中文
Microwave Assisted Biosynthesis of Silver Nanoparticles Using the Rhizome Extract of Alpinia galanga and Evaluation of Their Catalytic and Antimicrobial Activities 高良姜根茎提取物微波辅助合成纳米银及其催化抑菌活性评价
Pub Date : 2014-05-13 DOI: 10.1155/2014/967802
Siby Joseph, B. Mathew
Biomediated methods are considered to be a safer alternative to conventional physicochemical methods for the fabrication of nanomaterials due to their eco-friendly nature. In the present study, silver nanoparticles (AgNPs) were synthesized by microwave irradiation using aqueous rhizome extract of the medicinal plant Alpinia galanga. The nanoparticles were also synthesized under ambient condition without the assistance of microwave radiation and the former method was found to be much faster than the latter. The silver nanoparticles were characterized by UV-vis., FTIR, XRD, and HR-TEM analysis. UV-vis. spectroscopic studies provided ample evidences for the formation of nanoparticles. The FTIR spectrum confirmed the presence of plant phytochemicals as stabilizing agent around the AgNPs. XRD and HR-TEM analyses clearly proved the crystalline nature of the nanoparticles. From the TEM images, the nanoparticles were found to be roughly spherical in shape with an average diameter of 20.82 ± 1.8 nm. The nanoparticles showed outstanding catalytic activity for the reduction of methyl orange by NaBH4. The AgNPs were also evaluated for their antimicrobial activity by well diffusion method against S. aureus, B. subtilis, V. cholera, S. paratyphi, and A. niger. They were found to be highly toxic against all the tested pathogenic strains.
由于其生态友好性,生物介导方法被认为是传统物理化学方法制造纳米材料的一种更安全的替代方法。本研究以药用植物高良姜根茎水提物为原料,采用微波辐照法制备银纳米颗粒。在无微波辅助的环境条件下合成纳米粒子,前者比后者快得多。用紫外可见光谱对纳米银进行了表征。, FTIR, XRD和HR-TEM分析。紫外可见。光谱研究为纳米颗粒的形成提供了充分的证据。FTIR光谱证实了植物化学物质作为AgNPs周围的稳定剂的存在。XRD和HR-TEM分析清楚地证明了纳米颗粒的结晶性。TEM图像显示,纳米颗粒大致为球形,平均直径为20.82±1.8 nm。纳米颗粒对NaBH4还原甲基橙表现出优异的催化活性。用孔扩散法评价AgNPs对金黄色葡萄球菌、枯草芽孢杆菌、霍乱弧菌、副伤寒葡萄球菌和黑孢杆菌的抑菌活性。发现它们对所有测试的致病菌株都有很高的毒性。
{"title":"Microwave Assisted Biosynthesis of Silver Nanoparticles Using the Rhizome Extract of Alpinia galanga and Evaluation of Their Catalytic and Antimicrobial Activities","authors":"Siby Joseph, B. Mathew","doi":"10.1155/2014/967802","DOIUrl":"https://doi.org/10.1155/2014/967802","url":null,"abstract":"Biomediated methods are considered to be a safer alternative to conventional physicochemical methods for the fabrication of nanomaterials due to their eco-friendly nature. In the present study, silver nanoparticles (AgNPs) were synthesized by microwave irradiation using aqueous rhizome extract of the medicinal plant Alpinia galanga. The nanoparticles were also synthesized under ambient condition without the assistance of microwave radiation and the former method was found to be much faster than the latter. The silver nanoparticles were characterized by UV-vis., FTIR, XRD, and HR-TEM analysis. UV-vis. spectroscopic studies provided ample evidences for the formation of nanoparticles. The FTIR spectrum confirmed the presence of plant phytochemicals as stabilizing agent around the AgNPs. XRD and HR-TEM analyses clearly proved the crystalline nature of the nanoparticles. From the TEM images, the nanoparticles were found to be roughly spherical in shape with an average diameter of 20.82 ± 1.8 nm. The nanoparticles showed outstanding catalytic activity for the reduction of methyl orange by NaBH4. The AgNPs were also evaluated for their antimicrobial activity by well diffusion method against S. aureus, B. subtilis, V. cholera, S. paratyphi, and A. niger. They were found to be highly toxic against all the tested pathogenic strains.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"51 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2014-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84187122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 46
Copper Oxide Nanoparticles for Advanced Refrigerant Thermophysical Properties: Mathematical Modeling 用于先进制冷剂热物理性质的氧化铜纳米颗粒:数学建模
Pub Date : 2014-04-30 DOI: 10.1155/2014/890751
S. Fadhilah, R. Marhamah, A. Izzat
In modern days, refrigeration systems are important for industrial and domestic applications. The systems consume more electricity as compared to other appliances. The refrigeration systems have been investigated thoroughly in many ways to reduce the energy consumption. Hence, nanorefrigerant which is one kind of nanofluids has been introduced as a superior properties refrigerant that increased the heat transfer rate in the refrigeration system. Many types of materials could be used as the nanoparticles to be suspended into the conventional refrigerants. In this study, the effect of the suspended copper oxide (CuO) nanoparticles into the 1,1,1,2-tetrafluoroethane, R-134a is investigated by using mathematical modeling. The investigation includes the thermal conductivity, dynamic viscosity, and heat transfer rate of the nanorefrigerant in a tube of evaporator. The results show enhanced thermophysical properties of nanorefrigerant compared to the conventional refrigerant. These advanced thermophysical properties increased the heat transfer rate in the tube. The nanorefrigerant could be a potential working fluid to be used in the refrigeration system to increase the heat transfer characteristics and save the energy usage.
在现代,制冷系统是重要的工业和家庭应用。与其他电器相比,这些系统消耗更多的电力。制冷系统已经在许多方面进行了深入的研究,以减少能源消耗。因此,纳米制冷剂作为纳米流体的一种,作为一种提高制冷系统传热速率的性能优越的制冷剂而被引入。许多类型的材料都可以用作悬浮在传统制冷剂中的纳米颗粒。本研究采用数学模型研究了悬浮氧化铜(CuO)纳米颗粒对1,1,1,2-四氟乙烷R-134a的影响。研究了纳米制冷剂在蒸发器管内的导热系数、动态粘度和传热速率。结果表明,纳米制冷剂的热物理性能比常规制冷剂有所提高。这些先进的热物理特性提高了管内的传热速率。纳米制冷剂可以作为一种潜在的工质应用于制冷系统,提高制冷系统的传热性能,节约制冷系统的能耗。
{"title":"Copper Oxide Nanoparticles for Advanced Refrigerant Thermophysical Properties: Mathematical Modeling","authors":"S. Fadhilah, R. Marhamah, A. Izzat","doi":"10.1155/2014/890751","DOIUrl":"https://doi.org/10.1155/2014/890751","url":null,"abstract":"In modern days, refrigeration systems are important for industrial and domestic applications. The systems consume more electricity as compared to other appliances. The refrigeration systems have been investigated thoroughly in many ways to reduce the energy consumption. Hence, nanorefrigerant which is one kind of nanofluids has been introduced as a superior properties refrigerant that increased the heat transfer rate in the refrigeration system. Many types of materials could be used as the nanoparticles to be suspended into the conventional refrigerants. In this study, the effect of the suspended copper oxide (CuO) nanoparticles into the 1,1,1,2-tetrafluoroethane, R-134a is investigated by using mathematical modeling. The investigation includes the thermal conductivity, dynamic viscosity, and heat transfer rate of the nanorefrigerant in a tube of evaporator. The results show enhanced thermophysical properties of nanorefrigerant compared to the conventional refrigerant. These advanced thermophysical properties increased the heat transfer rate in the tube. The nanorefrigerant could be a potential working fluid to be used in the refrigeration system to increase the heat transfer characteristics and save the energy usage.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"25 1","pages":"1-5"},"PeriodicalIF":0.0,"publicationDate":"2014-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78799675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 39
Influence of Gas Sort on the Nucleation Region Width of Si Nanocrystal Grains Prepared by Pulsed Laser Ablation 气体种类对脉冲激光烧蚀制备硅纳米晶成核区宽度的影响
Pub Date : 2014-03-30 DOI: 10.1155/2014/760712
Z. Deng, L. Chu, Xuecheng Ding, Aili Qin, G. Fu, Ying-long Wang
We have calculated the nucleation region (NR) location of Si nanocrystal grains prepared by pulsed laser ablation (PLA) with fluence of 4 J/cm2 in 10 Pa gas at room temperature, and ambient gases were He, Ne, and Ar, respectively. Results of calculation indicated that NR width in Ne gas was narrowest, while it was widest in He gas. Maximum mean size of grains deposited on substrates under ablated spot, which were placed horizontally, was the smallest in Ne gas. It would be attribute to more effective energy transfer during the process of collision when atomic mass of Si and ambient gas Ne are more close to each other. In this work, an additional gas flow with the same element as ambient gas was introduced, which is vertical to the plume axis at different lateral positions above ablated spot.
在室温条件下,以4 J/cm2脉冲激光烧蚀(PLA)制备的Si纳米晶在10 Pa气体中,环境气体分别为He、Ne和Ar,计算了其成核区(NR)位置。计算结果表明,Ne气中NR宽度最窄,He气中最宽。在Ne气体中,水平放置的烧蚀点下沉积的颗粒的最大平均尺寸最小。这可能是由于Si原子质量与周围气体Ne的原子质量越接近,碰撞过程中的能量传递越有效。在本研究中,在烧蚀点上方的不同横向位置,引入了与周围气体具有相同元素的额外气体流,该气体流垂直于羽流轴。
{"title":"Influence of Gas Sort on the Nucleation Region Width of Si Nanocrystal Grains Prepared by Pulsed Laser Ablation","authors":"Z. Deng, L. Chu, Xuecheng Ding, Aili Qin, G. Fu, Ying-long Wang","doi":"10.1155/2014/760712","DOIUrl":"https://doi.org/10.1155/2014/760712","url":null,"abstract":"We have calculated the nucleation region (NR) location of Si nanocrystal grains prepared by pulsed laser ablation (PLA) with fluence of 4 J/cm2 in 10 Pa gas at room temperature, and ambient gases were He, Ne, and Ar, respectively. Results of calculation indicated that NR width in Ne gas was narrowest, while it was widest in He gas. Maximum mean size of grains deposited on substrates under ablated spot, which were placed horizontally, was the smallest in Ne gas. It would be attribute to more effective energy transfer during the process of collision when atomic mass of Si and ambient gas Ne are more close to each other. In this work, an additional gas flow with the same element as ambient gas was introduced, which is vertical to the plume axis at different lateral positions above ablated spot.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"64 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2014-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84781303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Green Chemistry Based Benign Routes for Nanoparticle Synthesis 基于绿色化学的纳米颗粒合成良性途径
Pub Date : 2014-03-24 DOI: 10.1155/2014/302429
Parth Malik, R. Shankar, V. Malik, N. Sharma, T. Mukherjee
Green chemistry has been an eye catching area of interest since the past few years. With the problem of energy crisis looming high and its constraint being particularly vulnerable on the developing economies, the need for giving alternative traditional chemistry a serious consideration as well as adequate room for development has received significant boost through the coveted efforts of multidisciplinary and interdisciplinary scientific fields. Nanoscience has been the right field in this dimension as it opens up the door to multiple opportunities through enabling a number of chemical, biochemical, and biophysical transformations in a significantly easier and reliable manner. The use of nanoparticles has made the fields of catalysis, synthesis, and enzyme immobilizations as well as molecular interactions a lot much easier, rapid and easily controllable. This review article sheds light on the popular alternative synthesis routes being employed for the synthesis of nanoparticles, the pivotal being from microbes, plants, and chemical routes via sonication, microwaving, and many others.
自过去几年以来,绿色化学一直是一个引人注目的领域。由于能源危机的问题日益突出,发展中经济体特别容易受到其限制,因此,通过多学科和跨学科科学领域令人垂涎的努力,给予替代传统化学的认真考虑以及充分的发展空间的需要得到了极大的推动。纳米科学一直是这个维度的正确领域,因为它以一种非常容易和可靠的方式实现了许多化学、生物化学和生物物理转化,为多种机会打开了大门。纳米粒子的使用使得催化、合成、酶固定以及分子相互作用等领域变得更加容易、快速和易于控制。本文综述了目前常用的纳米颗粒合成途径,主要有微生物合成、植物合成、超声波合成、微波合成等化学合成途径。
{"title":"Green Chemistry Based Benign Routes for Nanoparticle Synthesis","authors":"Parth Malik, R. Shankar, V. Malik, N. Sharma, T. Mukherjee","doi":"10.1155/2014/302429","DOIUrl":"https://doi.org/10.1155/2014/302429","url":null,"abstract":"Green chemistry has been an eye catching area of interest since the past few years. With the problem of energy crisis looming high and its constraint being particularly vulnerable on the developing economies, the need for giving alternative traditional chemistry a serious consideration as well as adequate room for development has received significant boost through the coveted efforts of multidisciplinary and interdisciplinary scientific fields. Nanoscience has been the right field in this dimension as it opens up the door to multiple opportunities through enabling a number of chemical, biochemical, and biophysical transformations in a significantly easier and reliable manner. The use of nanoparticles has made the fields of catalysis, synthesis, and enzyme immobilizations as well as molecular interactions a lot much easier, rapid and easily controllable. This review article sheds light on the popular alternative synthesis routes being employed for the synthesis of nanoparticles, the pivotal being from microbes, plants, and chemical routes via sonication, microwaving, and many others.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"9 1","pages":"1-14"},"PeriodicalIF":0.0,"publicationDate":"2014-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79987177","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 267
Performance of Water-Based Zinc Oxide Nanoparticle Coolant during Abrasive Grinding of Ductile Cast Iron 水基氧化锌纳米粒子冷却剂在球墨铸铁磨料磨削中的性能
Pub Date : 2014-03-05 DOI: 10.1155/2014/175896
M. Rahman, K. Kadirgama
This paper presents the performance of ductile cast iron grinding machining using water-based zinc oxide nanoparticles as a coolant. The experimental data was utilized to develop the mathematical model for first- and second-order models. The second order gives worthy performance of the grinding. The results indicate that the optimum parameters for the grinding model are 20 m/min table speed and 42.43 μm depth of cut for single-pass grinding. For multiple-pass grinding, optimization is at a table speed equal to 35.11 m/min and a depth of cut equal to 29.78 μm. The model fit was adequate and acceptable for sustainable grinding using a 0.15% volume concentration of zinc oxide nanocoolant. This paper quantifies the impact of water-based ZnO nanoparticle coolant on the achieved surface quality. It is concluded that the surface quality is the most influenced by the depth of cut(s) and table speed.
研究了水基氧化锌纳米颗粒作为冷却剂对球墨铸铁的磨削加工性能。利用实验数据建立了一阶和二阶模型的数学模型。二阶磨削具有良好的磨削性能。结果表明:该磨削模型的最佳参数为20 m/min的工作台速度和42.43 μm的切削深度。对于多道次磨削,优化条件为工作台转速为35.11 m/min,切割深度为29.78 μm。使用0.15%体积浓度的氧化锌纳米冷却剂,模型拟合是充分和可接受的。本文量化了水基纳米氧化锌冷却剂对表面质量的影响。结果表明,切削深度和工作台速度对表面质量的影响最大。
{"title":"Performance of Water-Based Zinc Oxide Nanoparticle Coolant during Abrasive Grinding of Ductile Cast Iron","authors":"M. Rahman, K. Kadirgama","doi":"10.1155/2014/175896","DOIUrl":"https://doi.org/10.1155/2014/175896","url":null,"abstract":"This paper presents the performance of ductile cast iron grinding machining using water-based zinc oxide nanoparticles as a coolant. The experimental data was utilized to develop the mathematical model for first- and second-order models. The second order gives worthy performance of the grinding. The results indicate that the optimum parameters for the grinding model are 20 m/min table speed and 42.43 μm depth of cut for single-pass grinding. For multiple-pass grinding, optimization is at a table speed equal to 35.11 m/min and a depth of cut equal to 29.78 μm. The model fit was adequate and acceptable for sustainable grinding using a 0.15% volume concentration of zinc oxide nanocoolant. This paper quantifies the impact of water-based ZnO nanoparticle coolant on the achieved surface quality. It is concluded that the surface quality is the most influenced by the depth of cut(s) and table speed.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"1 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2014-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90772034","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
The Mode of Action of Silver and Silver Halides Nanoparticles against Saccharomyces cerevisiae Cells 银和卤化银纳米颗粒对酿酒酵母细胞的作用模式
Pub Date : 2014-02-13 DOI: 10.1155/2014/568635
A. Kudrinskiy, A. Ivanov, E. Kulakovskaya, A. Klimov, P. Zherebin, D. V. Khodarev, Anh-Tuan Le, L. T. Tam, G. Lisichkin, Y. Krutyakov
Silver and silver halides nanoparticles (NPs) (Ag, AgCl, AgBr, and AgI) capped with two different stabilizers (sodium citrate and nonionic surfactant Tween 80) were obtained via sodium borohydride reduction of silver nitrate in an aqueous solution. The effect of the biocidal action of as-prepared synthesized materials against yeast cells Saccharomyces cerevisiae was compared to the effect produced by silver nitrate and studied through the measurement of cell loss and kinetics of K
通过硼氢化钠在水溶液中还原硝酸银,得到了两种不同稳定剂(柠檬酸钠和非离子表面活性剂Tween 80)覆盖的银和卤化银纳米颗粒(Ag、AgCl、AgBr和AgI)。将制备的合成材料对酵母细胞的杀灭效果与硝酸银的杀灭效果进行了比较,并通过测定细胞损失和K动力学进行了研究
{"title":"The Mode of Action of Silver and Silver Halides Nanoparticles against Saccharomyces cerevisiae Cells","authors":"A. Kudrinskiy, A. Ivanov, E. Kulakovskaya, A. Klimov, P. Zherebin, D. V. Khodarev, Anh-Tuan Le, L. T. Tam, G. Lisichkin, Y. Krutyakov","doi":"10.1155/2014/568635","DOIUrl":"https://doi.org/10.1155/2014/568635","url":null,"abstract":"Silver and silver halides nanoparticles (NPs) (Ag, AgCl, AgBr, and AgI) capped with two different stabilizers (sodium citrate and nonionic surfactant Tween 80) were obtained via sodium borohydride reduction of silver nitrate in an aqueous solution. The effect of the biocidal action of as-prepared synthesized materials against yeast cells Saccharomyces cerevisiae was compared to the effect produced by silver nitrate and studied through the measurement of cell loss and kinetics of K","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"58 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2014-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85167724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
Nanoparticles: Workhorses of Nanoscience 纳米粒子:纳米科学的主力
Pub Date : 2014-01-01 DOI: 10.1007/978-3-662-44823-6
C. M. Donegá, Springer
{"title":"Nanoparticles: Workhorses of Nanoscience","authors":"C. M. Donegá, Springer","doi":"10.1007/978-3-662-44823-6","DOIUrl":"https://doi.org/10.1007/978-3-662-44823-6","url":null,"abstract":"","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"46 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74970374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 38
Small Angle X-Ray Scattering Technique for the Particle Size Distribution of Nonporous Nanoparticles 无孔纳米颗粒粒径分布的小角x射线散射技术
Pub Date : 2013-12-22 DOI: 10.1155/2013/640436
A. Agbabiaka, M. Wiltfong, Chiwoo Park
Nanoparticles are small particles whose sizes are less than 100 nm. They have many industrial applications due to their unique properties. Their properties are often size-dependent; thus the accurate determination of nanoparticle sizes is important for quality assurance of nanoparticle production processes. A small angle X-ray scattering technique is a promising method used for characterizing nanoparticle sizes. It has distinctive advantages over other techniques such as electron microscope techniques. In this paper, we review the state-of-the-art methods for determining the sizes of nanoparticles with small angle X-ray experiments and discuss the advantages and limitations of the state-of-the-art methods.
纳米颗粒是尺寸小于100纳米的小颗粒。由于其独特的性能,它们有许多工业应用。它们的属性通常与尺寸有关;因此,纳米颗粒尺寸的准确测定对于保证纳米颗粒生产过程的质量至关重要。小角度x射线散射技术是表征纳米颗粒尺寸的一种很有前途的方法。与其他技术如电子显微镜技术相比,它具有明显的优势。本文综述了利用小角度x射线实验测定纳米颗粒尺寸的最新方法,并讨论了最新方法的优点和局限性。
{"title":"Small Angle X-Ray Scattering Technique for the Particle Size Distribution of Nonporous Nanoparticles","authors":"A. Agbabiaka, M. Wiltfong, Chiwoo Park","doi":"10.1155/2013/640436","DOIUrl":"https://doi.org/10.1155/2013/640436","url":null,"abstract":"Nanoparticles are small particles whose sizes are less than 100 nm. They have many industrial applications due to their unique properties. Their properties are often size-dependent; thus the accurate determination of nanoparticle sizes is important for quality assurance of nanoparticle production processes. A small angle X-ray scattering technique is a promising method used for characterizing nanoparticle sizes. It has distinctive advantages over other techniques such as electron microscope techniques. In this paper, we review the state-of-the-art methods for determining the sizes of nanoparticles with small angle X-ray experiments and discuss the advantages and limitations of the state-of-the-art methods.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"9 1","pages":"1-11"},"PeriodicalIF":0.0,"publicationDate":"2013-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79141778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 38
Magnetization and Specific Absorption Rate Studies of Ball-Milled Iron Oxide Nanoparticles for Biomedicine 生物医学用球磨氧化铁纳米颗粒的磁化及比吸收率研究
Pub Date : 2013-09-28 DOI: 10.1155/2013/181820
Philip Burnham, N. Dollahon, Calvin H. Li, A. J. Viescas, G. Papaefthymiou
Comparative studies are presented of iron oxide nanoparticles in the 7–15 nm average diameter range ball milled in hexane in the presence of oleic acid. Transmission electron microscopy identified spherical particles of decreasing size as milling time and/or surfactant concentration increased. Micromagnetic characterization via Mossbauer spectroscopy at room temperature yielded broadened magnetic spectroscopic signatures, while macromagnetic characterization via vibrating sample magnetometry of 7-8 nm diameter particles showed largely superparamagnetic behavior at room temperature and hysteretic at 2 K. Zero-field and field-cooled magnetization curves exhibited a broad maximum at ~215 K indicating the presence of strong interparticle magnetic interactions. The specific absorption rates of ferrofluids based on these nanoparticle preparations were measured in order to test their efficacies as hyperthermia agents.
在油酸的存在下,用己烷球磨法制备了平均直径为7 ~ 15 nm的氧化铁纳米颗粒。透射电镜发现,随着磨矿时间和表面活性剂浓度的增加,球形颗粒的尺寸逐渐减小。在室温下,通过穆斯堡尔谱法进行微磁表征,获得了更宽的磁谱特征,而在7-8 nm直径的颗粒上,通过振动样品磁强计进行宏磁表征,在室温下显示出很大的超顺磁行为,在2 K时显示出滞后性。零场和场冷磁化曲线在~215 K处表现出宽的最大值,表明存在强的粒子间磁相互作用。测量了基于这些纳米颗粒制剂的铁磁流体的特定吸收率,以测试它们作为热疗剂的功效。
{"title":"Magnetization and Specific Absorption Rate Studies of Ball-Milled Iron Oxide Nanoparticles for Biomedicine","authors":"Philip Burnham, N. Dollahon, Calvin H. Li, A. J. Viescas, G. Papaefthymiou","doi":"10.1155/2013/181820","DOIUrl":"https://doi.org/10.1155/2013/181820","url":null,"abstract":"Comparative studies are presented of iron oxide nanoparticles in the 7–15 nm average diameter range ball milled in hexane in the presence of oleic acid. Transmission electron microscopy identified spherical particles of decreasing size as milling time and/or surfactant concentration increased. Micromagnetic characterization via Mossbauer spectroscopy at room temperature yielded broadened magnetic spectroscopic signatures, while macromagnetic characterization via vibrating sample magnetometry of 7-8 nm diameter particles showed largely superparamagnetic behavior at room temperature and hysteretic at 2 K. Zero-field and field-cooled magnetization curves exhibited a broad maximum at ~215 K indicating the presence of strong interparticle magnetic interactions. The specific absorption rates of ferrofluids based on these nanoparticle preparations were measured in order to test their efficacies as hyperthermia agents.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"167 1","pages":"1-13"},"PeriodicalIF":0.0,"publicationDate":"2013-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80495389","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 22
Characterization and Modification of Mesoporous Silica Nanoparticles Prepared by Sol-Gel 溶胶-凝胶法制备介孔二氧化硅纳米颗粒的表征与改性
Pub Date : 2013-09-25 DOI: 10.1155/2013/102823
Meysam Keshavarz, N. Ahmad
Mesoporous silica nanoparticles (MSNs) were synthesized by sol-gel reaction at normal pressure by using TEOS as a silica source and CTAB as a directing agent in ammonia solution at 323 K subsequently calcined at 823 K. Then inorganic pores were modified with metal-supported MSN with attention to the acidity, surface area, pore size, and ability of ion exchange. Crystalline size was shown to decrease up to 20 molar ratios of Si/Al followed by increasing while further adding nanoparticles-aluminium. Moreover, the XRD patterns revealed the mesostructured material for all with 2D hexagonal structure. The obtained results from the XRD patterns were confirmed by using BET and EDX. The BET surface areas revealed the spherical shape for all samples with a decrease in the pore volume and surface area for various AlMSNs which emphasized that the loading of Al and was compatible with XRD results. MSN was prepared by sol-gel methods followed by loading of Al in order to prepare AlMSN which possess strong Lewis acidic sites. This modification occurred by using various molar ratios of 0, 5, 10, 20, 50, and 100 Si/Al, respectively. The XRD patterns of various ratios of Si/Al were interpreted in terms of strain, nanocrystalline size, and distribution of the particle size by deriving Wiliamson Hall equation.
以正硅酸乙酯(TEOS)为硅源,CTAB为导向剂,在323 K的氨溶液中经823 K煅烧,在常压下通过溶胶-凝胶反应合成了介孔二氧化硅纳米颗粒(MSNs)。然后用金属负载的MSN对无机孔隙进行了改性,并注意了酸度、比表面积、孔径和离子交换能力。当Si/Al的摩尔比达到20时,晶体尺寸减小,随后随着纳米颗粒-铝的进一步加入而增大。此外,XRD图谱显示材料的介观结构均为二维六边形结构。用BET和EDX对XRD谱图的结果进行了验证。所有样品的BET表面积均呈球形,各种AlMSNs的孔体积和表面积都有所减小,这强调了Al的负载,与XRD结果一致。采用溶胶-凝胶法制备了具有强路易斯酸位的铝微球。通过使用不同的摩尔比分别为0、5、10、20、50和100的Si/Al进行改性。通过推导williamson Hall方程,从应变、纳米晶尺寸和粒径分布等方面解释了不同Si/Al比的XRD谱图。
{"title":"Characterization and Modification of Mesoporous Silica Nanoparticles Prepared by Sol-Gel","authors":"Meysam Keshavarz, N. Ahmad","doi":"10.1155/2013/102823","DOIUrl":"https://doi.org/10.1155/2013/102823","url":null,"abstract":"Mesoporous silica nanoparticles (MSNs) were synthesized by sol-gel reaction at normal pressure by using TEOS as a silica source and CTAB as a directing agent in ammonia solution at 323 K subsequently calcined at 823 K. Then inorganic pores were modified with metal-supported MSN with attention to the acidity, surface area, pore size, and ability of ion exchange. Crystalline size was shown to decrease up to 20 molar ratios of Si/Al followed by increasing while further adding nanoparticles-aluminium. Moreover, the XRD patterns revealed the mesostructured material for all with 2D hexagonal structure. The obtained results from the XRD patterns were confirmed by using BET and EDX. The BET surface areas revealed the spherical shape for all samples with a decrease in the pore volume and surface area for various AlMSNs which emphasized that the loading of Al and was compatible with XRD results. MSN was prepared by sol-gel methods followed by loading of Al in order to prepare AlMSN which possess strong Lewis acidic sites. This modification occurred by using various molar ratios of 0, 5, 10, 20, 50, and 100 Si/Al, respectively. The XRD patterns of various ratios of Si/Al were interpreted in terms of strain, nanocrystalline size, and distribution of the particle size by deriving Wiliamson Hall equation.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"44 1","pages":"1-4"},"PeriodicalIF":0.0,"publicationDate":"2013-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77531880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
期刊
Journal of Nanoparticles
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1