V. Homaunmir, S. Tohidi, G. Grigorya, M. A. Z. Shirazi
Various concentrations of copper oxide were embedded into silica matrix of xerogel forms using copper source Cu(NO3)2·3H2O. The xerogel samples were prepared by hydrolysis and condensation of tetraethyl orthosilicate (TEOS) with determination of new molar ratios of the components by the sol-gel method. In this paper, three samples of copper oxide were doped into silica matrices using different concentrations. We obtained 10, 20, and 30 wt.% of copper oxide in silica matrices labeled as A, B, and C, respectively. The absorption and transmittance spectra of the gel matrices were treated at different concentrations by Uv-vis spectrophotometer. Quantities of water and transparency in the silica network change the spectral characteristics of Cu2
{"title":"Dependence Properties of Sol-Gel Derived CuO@SiO2 Nanostructure to Diverse Concentrations of Copper Oxide","authors":"V. Homaunmir, S. Tohidi, G. Grigorya, M. A. Z. Shirazi","doi":"10.1155/2013/156813","DOIUrl":"https://doi.org/10.1155/2013/156813","url":null,"abstract":"Various concentrations of copper oxide were embedded into silica matrix of xerogel forms using copper source Cu(NO3)2·3H2O. The xerogel samples were prepared by hydrolysis and condensation of tetraethyl orthosilicate (TEOS) with determination of new molar ratios of the components by the sol-gel method. In this paper, three samples of copper oxide were doped into silica matrices using different concentrations. We obtained 10, 20, and 30 wt.% of copper oxide in silica matrices labeled as A, B, and C, respectively. The absorption and transmittance spectra of the gel matrices were treated at different concentrations by Uv-vis spectrophotometer. Quantities of water and transparency in the silica network change the spectral characteristics of Cu2","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"1 1","pages":"1-5"},"PeriodicalIF":0.0,"publicationDate":"2013-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79994389","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Recent technology and experiments have fabricated high-quality superconducting MgB2 nanoparticles. We investigate properties of two-gap superconductivity in nanosized systems by using a two-sublevel model. In the present work, we analyze the results obtained for superconducting granules in the case of multiband superconductivity. We discuss the finite size effect in multiband superconductors. A definition of the critical level spacing of two-gap superconductivity is also presented, and we discuss the condensation energy and the parity gap of two-gap superconductivity in relation to the size dependence of those properties with two bulk gaps and the effective pair scattering process between two sublevels.
{"title":"Condensation Energy for a Two-Gap Superconducting State in Nanoparticles","authors":"S. Kruchinin, H. Kawabe, H. Nagao, Y. Nakazawa","doi":"10.1155/2013/576232","DOIUrl":"https://doi.org/10.1155/2013/576232","url":null,"abstract":"Recent technology and experiments have fabricated high-quality superconducting MgB2 nanoparticles. \u0000We investigate properties of two-gap superconductivity in nanosized systems by using a \u0000two-sublevel model. In the present work, we analyze the results obtained for superconducting granules \u0000in the case of multiband superconductivity. We discuss the finite size effect in multiband \u0000superconductors. A definition of the critical level spacing of two-gap superconductivity is also presented, \u0000and we discuss the condensation energy and the parity gap of two-gap superconductivity \u0000in relation to the size dependence of those properties with two bulk gaps and the effective pair \u0000scattering process between two sublevels.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"11 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2013-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86491484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Kajbafvala, Minghang Li, H. Bahmanpour, M. Maneshian, A. Kauffmann
1 Department of Materials Science and Engineering, North Carolina State University, 911 Partners Way, Engineering Building I, Raleigh, NC 27695-7907, USA 2Department of Materials Science and Engineering, University of North Texas, Denton, TX 76203, USA 3Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616, USA 4Leibniz Institute for Solid State and Materials Research Dresden, P.O. Box 27 01 16, 01171 Dresden, Germany
{"title":"Nano/Microstructured Materials: Rapid, Low-Cost, and Eco-Friendly Synthesis Methods","authors":"A. Kajbafvala, Minghang Li, H. Bahmanpour, M. Maneshian, A. Kauffmann","doi":"10.1155/2013/530170","DOIUrl":"https://doi.org/10.1155/2013/530170","url":null,"abstract":"1 Department of Materials Science and Engineering, North Carolina State University, 911 Partners Way, Engineering Building I, Raleigh, NC 27695-7907, USA 2Department of Materials Science and Engineering, University of North Texas, Denton, TX 76203, USA 3Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616, USA 4Leibniz Institute for Solid State and Materials Research Dresden, P.O. Box 27 01 16, 01171 Dresden, Germany","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"8 1","pages":"1-3"},"PeriodicalIF":0.0,"publicationDate":"2013-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79587537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Verma, V. Agrawal, K. Jain, R. Pasricha, S. Chand
Nanocrystalline Cu2ZnSnS4 (CZTS) powder was synthesized by a hydrothermal process, using thiourea as sulfur precursor. The powder was qualitatively analyzed using X-ray to identify the phase, and the size of the particles was determined using transmission electron microscopy (TEM). Raman peak at 337.5 cm−1 confirms the formation of pure CZTS particles. The powder was also synthesized solvothermally using ethylenediamine as solvent. The hydrothermally synthesized powder indicated the presence of the kesterite phase Cu2ZnSnS4 and particle size of about 4-5 nm. This environmentally green synthesis by hydrothermal route can produce gram scale synthesis of material with a chemical yield in excess of ~ 90%. UV Vis absorption spectra measurements indicated the band gap of as-synthesized CZTS nanoparticles to be 1.7 eV, which is near the optimum value for photovoltaic solar cell, showing its possible use in photovoltaics.
{"title":"Green Synthesis of Nanocrystalline Cu2ZnSnS4 Powder Using Hydrothermal Route","authors":"S. Verma, V. Agrawal, K. Jain, R. Pasricha, S. Chand","doi":"10.1155/2013/685836","DOIUrl":"https://doi.org/10.1155/2013/685836","url":null,"abstract":"Nanocrystalline Cu2ZnSnS4 (CZTS) powder was synthesized by a hydrothermal process, using thiourea as sulfur precursor. The powder was qualitatively analyzed using X-ray to identify the phase, and the size of the particles was determined using transmission electron microscopy (TEM). Raman peak at 337.5 cm−1 confirms the formation of pure CZTS particles. The powder was also synthesized solvothermally using ethylenediamine as solvent. The hydrothermally synthesized powder indicated the presence of the kesterite phase Cu2ZnSnS4 and particle size of about 4-5 nm. This environmentally green synthesis by hydrothermal route can produce gram scale synthesis of material with a chemical yield in excess of ~ 90%. UV Vis absorption spectra measurements indicated the band gap of as-synthesized CZTS nanoparticles to be 1.7 eV, which is near the optimum value for photovoltaic solar cell, showing its possible use in photovoltaics.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"61 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2013-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73938875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nanocrystalline electrodes in liquid junction devices possess a number of unique properties arising from their convoluted structure and the dimensions of their building units. The light-induced charge separation and transport in photoelectrochemical systems using nanocrystalline/nanoporous semiconductor electrodes is discussed here in connection with the basic principles of the (Schottky) barrier theory. Recent models for charge transfer kinetics in normal and unipolar (dye-sensitized) cells are reviewed, and novel concepts and materials are considered.
{"title":"Charge Transfer in Nanocrystalline Semiconductor Electrodes","authors":"M. Bouroushian","doi":"10.1155/2013/953153","DOIUrl":"https://doi.org/10.1155/2013/953153","url":null,"abstract":"Nanocrystalline electrodes in liquid junction devices possess a number of unique properties arising from their convoluted structure and the dimensions of their building units. The light-induced charge separation and transport in photoelectrochemical systems using nanocrystalline/nanoporous semiconductor electrodes is discussed here in connection with the basic principles of the (Schottky) barrier theory. Recent models for charge transfer kinetics in normal and unipolar (dye-sensitized) cells are reviewed, and novel concepts and materials are considered.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"53 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2013-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90838679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A nanocomposite coating was formed by incorporating nanoalumina pigment in a waterborne polyurethane dispersion (WPUD) to different loading levels (0.1% and 1.0% by weight). Electrochemical performance of the nanocomposite coating was evaluated by applying these nanomodified coatings on mild steel substrate and exposing them to salt-spray, humidity, and accelerated UV weathering. The surface morphology of the composite coating was evaluated using various analytical techniques. SEM and AFM were used to investigate the dispersion of nanoalumina pigment and surface morphological changes of the nanomodified coating, before and after exposure to the test environment. Mechanical properties like scratch resistance were studied by using nanoscratch technique (Nanoindenter TI-900, Hysitron Inc, USA) and hardness using pencil hardness test method. The results showed an improvement in the corrosion, UV weathering, and mechanical properties of the coatings at lower concentration (0.1% by wt), indicating the positive effect of addition of nanoalumina pigment to the coating.
{"title":"Effect of Nanoalumina on the Electrochemical and Mechanical Properties of Waterborne Polyurethane Composite Coatings","authors":"S. Dhoke, Narayani Rajgopalan, A. Khanna","doi":"10.1155/2013/527432","DOIUrl":"https://doi.org/10.1155/2013/527432","url":null,"abstract":"A nanocomposite coating was formed by incorporating nanoalumina pigment in a waterborne polyurethane dispersion (WPUD) to different loading levels (0.1% and 1.0% by weight). Electrochemical performance of the nanocomposite coating was evaluated by applying these nanomodified coatings on mild steel substrate and exposing them to salt-spray, humidity, and accelerated UV weathering. The surface morphology of the composite coating was evaluated using various analytical techniques. SEM and AFM were used to investigate the dispersion of nanoalumina pigment and surface morphological changes of the nanomodified coating, before and after exposure to the test environment. Mechanical properties like scratch resistance were studied by using nanoscratch technique (Nanoindenter TI-900, Hysitron Inc, USA) and hardness using pencil hardness test method. The results showed an improvement in the corrosion, UV weathering, and mechanical properties of the coatings at lower concentration (0.1% by wt), indicating the positive effect of addition of nanoalumina pigment to the coating.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"344 1","pages":"1-11"},"PeriodicalIF":0.0,"publicationDate":"2013-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75463989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Satyajit Tripathy, Sabyasachi Das, S. Dash, S. Chattopadhyay, Somenath Roy
The applications of nanotechnology to pharmacology are the potential appliance of biodegradable polymers and convection-enhanced drug delivery in the diagnostics and treatment of diseases. Chitosan is a natural polysaccharide that has attracted significant scientific interest during the last two decades. The present study was to evaluate the possible effects of chitosan tripolyphosphate conjugated nanochloroquine against Plasmodium berghei infection on select makers of oxidative damage and antioxidant status in mitochondria of liver and spleen. P. berghei infection was developed in Swiss mice by intraperitoneal injection of 200 µL of infected blood. Parasite-infected mice were treated with chloroquine and nanoconjugated chloroquine. Superoxide radical generation, nitrate level, and oxidized glutathione were increased significantly () in the mitochondria of infected group as compared to control group, and reduced glutathione level, activity of SOD, GPx, GR, and GST, and mitochondrial transmembrane potential were decreased significantly (), which were increased or decreased significantly () near to normal in nanoconjugated chloroquine treated group than chloroquine treated group. So, the findings may suggest the advantageous role of nanoconjugated chloroquine against the P. berghei induced oxidative damage in hepatic and splenic mitochondria.
{"title":"The Impact of Nanochloroquine on Restoration of Hepatic and Splenic Mitochondrial Damage against Rodent Malaria","authors":"Satyajit Tripathy, Sabyasachi Das, S. Dash, S. Chattopadhyay, Somenath Roy","doi":"10.1155/2013/106152","DOIUrl":"https://doi.org/10.1155/2013/106152","url":null,"abstract":"The applications of nanotechnology to pharmacology are the potential appliance of biodegradable polymers and convection-enhanced drug delivery in the diagnostics and treatment of diseases. Chitosan is a natural polysaccharide that has attracted significant scientific interest during the last two decades. The present study was to evaluate the possible effects of chitosan tripolyphosphate conjugated nanochloroquine against Plasmodium berghei infection on select makers of oxidative damage and antioxidant status in mitochondria of liver and spleen. P. berghei infection was developed in Swiss mice by intraperitoneal injection of 200 µL of infected blood. Parasite-infected mice were treated with chloroquine and nanoconjugated chloroquine. Superoxide radical generation, nitrate level, and oxidized glutathione were increased significantly () in the mitochondria of infected group as compared to control group, and reduced glutathione level, activity of SOD, GPx, GR, and GST, and mitochondrial transmembrane potential were decreased significantly (), which were increased or decreased significantly () near to normal in nanoconjugated chloroquine treated group than chloroquine treated group. So, the findings may suggest the advantageous role of nanoconjugated chloroquine against the P. berghei induced oxidative damage in hepatic and splenic mitochondria.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"65 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2013-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81461727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Sant, Tejal Gujarathi, S. Harne, Sougata Ghosh, Rohini Kitture, S. Kale, B. Chopade, K. Pardesi
Development of an ecofriendly, reliable, and rapid process for synthesis of nanoparticles using biological system is an important bulge in nanotechnology. Antioxidant potential and medicinal value of Adiantum philippense L. fascinated us to utilize it for biosynthesis of gold and silver nanoparticles (AuNPs and AgNPs). The current paper reports utility of aqueous extract of A. philippense L. fronds for the green synthesis of AuNPs and AgNPs. Effect of various parameters on synthesis of nanoparticles was monitored by UV-Vis spectrometry. Optimum conditions for AuNPs synthesis were 1 : 1 proportion of original extract at pH 11 and 5 mM tetrachloroauric acid, whereas optimum conditions for AgNPs synthesis were 1 : 1 proportion of original extract at pH 12 and 9 mM silver nitrate. Characterization of nanoparticles was done by TEM, SAED, XRD, EDS, FTIR, and DLS analyses. The results revealed that AuNPs and AgNPs were anisotropic. Monocrystalline AuNPs and polycrystalline AgNPs measured 10 to 18 nm in size. EDS and XRD analyses confirmed the presence of elemental gold and silver. FTIR analysis revealed a possible binding of extract to AuNPs through –NH2 group and to AgNPs through C=C group. These nanoparticles stabilized by a biological capping agent could further be utilized for biomedical applications.
{"title":"Adiantum philippense L. Frond Assisted Rapid Green Synthesis of Gold and Silver Nanoparticles","authors":"D. Sant, Tejal Gujarathi, S. Harne, Sougata Ghosh, Rohini Kitture, S. Kale, B. Chopade, K. Pardesi","doi":"10.1155/2013/182320","DOIUrl":"https://doi.org/10.1155/2013/182320","url":null,"abstract":"Development of an ecofriendly, reliable, and rapid process for synthesis of nanoparticles using biological system is an important bulge in nanotechnology. Antioxidant potential and medicinal value of Adiantum philippense L. fascinated us to utilize it for biosynthesis of gold and silver nanoparticles (AuNPs and AgNPs). The current paper reports utility of aqueous extract of A. philippense L. fronds for the green synthesis of AuNPs and AgNPs. Effect of various parameters on synthesis of nanoparticles was monitored by UV-Vis spectrometry. Optimum conditions for AuNPs synthesis were 1 : 1 proportion of original extract at pH 11 and 5 mM tetrachloroauric acid, whereas optimum conditions for AgNPs synthesis were 1 : 1 proportion of original extract at pH 12 and 9 mM silver nitrate. Characterization of nanoparticles was done by TEM, SAED, XRD, EDS, FTIR, and DLS analyses. The results revealed that AuNPs and AgNPs were anisotropic. Monocrystalline AuNPs and polycrystalline AgNPs measured 10 to 18 nm in size. EDS and XRD analyses confirmed the presence of elemental gold and silver. FTIR analysis revealed a possible binding of extract to AuNPs through –NH2 group and to AgNPs through C=C group. These nanoparticles stabilized by a biological capping agent could further be utilized for biomedical applications.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"128 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2013-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83100092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The unique property of the silver nanoparticles having the antimicrobial activity drags the major attention towards the present nanotechnology. The environmentally nontoxic, ecofriendly, and cost-effective method that has been developed for the synthesis of silver nanoparticles using plant extracts creates the major research interest in the field of nanobiotechnology. The synthesized silver nanoparticles have been characterized by the UV-visible spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM). Further, the antibacterial activity of silver nanoparticles was evaluated by well diffusion method, and it was found that the biogenic silver nanoparticles have antibacterial activity against Escherichia coli (ATCC 25922), Staphylococcus aureus (ATCC 29213), Pseudomonas aeruginosa (ATCC 27853), Azotobacter chroococcum WR 9, and Bacillus licheniformis (MTCC 9555).
{"title":"Antibacterial Activity of Silver Nanoparticles Synthesized by Bark Extract of Syzygium cumini","authors":"R. Prasad, V. Swamy","doi":"10.1155/2013/431218","DOIUrl":"https://doi.org/10.1155/2013/431218","url":null,"abstract":"The unique property of the silver nanoparticles having the antimicrobial activity drags the major attention towards the present nanotechnology. The environmentally nontoxic, ecofriendly, and cost-effective method that has been developed for the synthesis of silver nanoparticles using plant extracts creates the major research interest in the field of nanobiotechnology. The synthesized silver nanoparticles have been characterized by the UV-visible spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM). Further, the antibacterial activity of silver nanoparticles was evaluated by well diffusion method, and it was found that the biogenic silver nanoparticles have antibacterial activity against Escherichia coli (ATCC 25922), Staphylococcus aureus (ATCC 29213), Pseudomonas aeruginosa (ATCC 27853), Azotobacter chroococcum WR 9, and Bacillus licheniformis (MTCC 9555).","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"2013 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2013-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77841681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wood is a renewable material widely used in many applications due to its unique properties and distinctive look. However, as wood is organically constituted, it is slowly destroyed by the long-term impact of oxygen, UV radiations, water, and biological attacks (Mahltig et al., 2008). Therefore, protective treatments are necessary to improve the mechanical, thermal, and chemical properties of wood. In order to improve the mechanical properties of sugar maple (Acer saccharum Marsh.), as this species is widely used in the wood products industry, samples of sugar maple were impregnated with sols of metal oxides (AlO(OH), SiO2, and ZrO2). The weight gain and two different techniques of microscopy were used to evaluate the efficiency of the impregnation in the wood samples. The mechanical properties were evaluated using hardness test, scratch test, and impact test. It was shown that the maple samples impregnated with ZrO2 led to the greatest improvement of the mechanical properties.
木材是一种可再生材料,由于其独特的性能和独特的外观,被广泛应用于许多领域。然而,由于木材是有机构成的,它会被氧气、紫外线辐射、水和生物攻击的长期影响慢慢破坏(Mahltig et al., 2008)。因此,保护处理是必要的,以改善木材的机械,热学和化学性能。由于糖枫在木制品工业中被广泛使用,为了改善糖枫的机械性能,对糖枫样品进行了金属氧化物(AlO(OH), SiO2和ZrO2)溶胶浸渍。用增重和两种不同的显微镜技术来评价木材样品的浸渍效率。通过硬度试验、划痕试验和冲击试验对其力学性能进行了评价。结果表明,ZrO2浸渍后的枫材力学性能得到最大程度的改善。
{"title":"Metal Oxide Sol-Gels (, AlO(OH), and ) to Improve the Mechanical Performance of Wood Substrates","authors":"V. Landry, P. Blanchet, G. Boivin","doi":"10.1155/2013/273204","DOIUrl":"https://doi.org/10.1155/2013/273204","url":null,"abstract":"Wood is a renewable material widely used in many applications due to its unique properties and distinctive look. However, as wood is organically constituted, it is slowly destroyed by the long-term impact of oxygen, UV radiations, water, and biological attacks (Mahltig et al., 2008). Therefore, protective treatments are necessary to improve the mechanical, thermal, and chemical properties of wood. In order to improve the mechanical properties of sugar maple (Acer saccharum Marsh.), as this species is widely used in the wood products industry, samples of sugar maple were impregnated with sols of metal oxides (AlO(OH), SiO2, and ZrO2). The weight gain and two different techniques of microscopy were used to evaluate the efficiency of the impregnation in the wood samples. The mechanical properties were evaluated using hardness test, scratch test, and impact test. It was shown that the maple samples impregnated with ZrO2 led to the greatest improvement of the mechanical properties.","PeriodicalId":16507,"journal":{"name":"Journal of Nanoparticles","volume":"116 1","pages":"1-8"},"PeriodicalIF":0.0,"publicationDate":"2013-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89811156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}