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Dependence Properties of Sol-Gel Derived CuO@SiO2 Nanostructure to Diverse Concentrations of Copper Oxide 溶胶-凝胶衍生CuO@SiO2纳米结构对不同浓度氧化铜的依赖性
Pub Date : 2013-09-19 DOI: 10.1155/2013/156813
V. Homaunmir, S. Tohidi, G. Grigorya, M. A. Z. Shirazi
Various concentrations of copper oxide were embedded into silica matrix of xerogel forms using copper source Cu(NO3)2·3H2O. The xerogel samples were prepared by hydrolysis and condensation of tetraethyl orthosilicate (TEOS) with determination of new molar ratios of the components by the sol-gel method. In this paper, three samples of copper oxide were doped into silica matrices using different concentrations. We obtained 10, 20, and 30 wt.% of copper oxide in silica matrices labeled as A, B, and C, respectively. The absorption and transmittance spectra of the gel matrices were treated at different concentrations by Uv-vis spectrophotometer. Quantities of water and transparency in the silica network change the spectral characteristics of Cu2
用铜源Cu(NO3)2·3H2O将不同浓度的氧化铜包埋在干凝胶形式的二氧化硅基体中。采用正硅酸四乙酯(TEOS)水解缩合制备了干凝胶样品,并用溶胶-凝胶法测定了各组分的新摩尔比。本文将三种氧化铜样品以不同浓度掺杂到二氧化硅基体中。我们分别在标记为A、B和C的二氧化硅基质中获得了10、20和30 wt.%的氧化铜。用紫外-可见分光光度计对不同浓度凝胶基质的吸收光谱和透射光谱进行了处理。二氧化硅网络中的水量和透明度改变了Cu2的光谱特征
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引用次数: 3
Condensation Energy for a Two-Gap Superconducting State in Nanoparticles 纳米粒子中双间隙超导态的凝聚能
Pub Date : 2013-09-04 DOI: 10.1155/2013/576232
S. Kruchinin, H. Kawabe, H. Nagao, Y. Nakazawa
Recent technology and experiments have fabricated high-quality superconducting MgB2 nanoparticles. We investigate properties of two-gap superconductivity in nanosized systems by using a two-sublevel model. In the present work, we analyze the results obtained for superconducting granules in the case of multiband superconductivity. We discuss the finite size effect in multiband superconductors. A definition of the critical level spacing of two-gap superconductivity is also presented, and we discuss the condensation energy and the parity gap of two-gap superconductivity in relation to the size dependence of those properties with two bulk gaps and the effective pair scattering process between two sublevels.
最近的技术和实验已经制备出高质量的超导MgB2纳米颗粒。利用双亚能级模型研究了纳米系统中双间隙超导的性质。在本工作中,我们分析了在多带超导情况下超导颗粒的结果。讨论了多带超导体的有限尺寸效应。给出了双间隙超导临界能级间距的定义,讨论了双间隙超导的凝聚能和宇称间隙与两个体隙的尺寸依赖性以及两个亚能级之间的有效对散射过程。
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引用次数: 1
Nano/Microstructured Materials: Rapid, Low-Cost, and Eco-Friendly Synthesis Methods 纳米/微结构材料:快速、低成本和环保的合成方法
Pub Date : 2013-07-24 DOI: 10.1155/2013/530170
A. Kajbafvala, Minghang Li, H. Bahmanpour, M. Maneshian, A. Kauffmann
1 Department of Materials Science and Engineering, North Carolina State University, 911 Partners Way, Engineering Building I, Raleigh, NC 27695-7907, USA 2Department of Materials Science and Engineering, University of North Texas, Denton, TX 76203, USA 3Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616, USA 4Leibniz Institute for Solid State and Materials Research Dresden, P.O. Box 27 01 16, 01171 Dresden, Germany
1北卡罗来纳州立大学材料科学与工程系,北卡罗来纳州罗利27695-7907,美国2北德克萨斯大学材料科学与工程系,德克萨斯州丹顿76203,美国3加州大学戴维斯分校化学工程与材料科学系,加利福尼亚州95616,美国4德累斯顿莱布尼茨固体与材料研究所,德国德累斯顿01171
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引用次数: 17
Green Synthesis of Nanocrystalline Cu2ZnSnS4 Powder Using Hydrothermal Route 水热法绿色合成纳米晶Cu2ZnSnS4粉末
Pub Date : 2013-06-27 DOI: 10.1155/2013/685836
S. Verma, V. Agrawal, K. Jain, R. Pasricha, S. Chand
Nanocrystalline Cu2ZnSnS4 (CZTS) powder was synthesized by a hydrothermal process, using thiourea as sulfur precursor. The powder was qualitatively analyzed using X-ray to identify the phase, and the size of the particles was determined using transmission electron microscopy (TEM). Raman peak at 337.5 cm−1 confirms the formation of pure CZTS particles. The powder was also synthesized solvothermally using ethylenediamine as solvent. The hydrothermally synthesized powder indicated the presence of the kesterite phase Cu2ZnSnS4 and particle size of about 4-5 nm. This environmentally green synthesis by hydrothermal route can produce gram scale synthesis of material with a chemical yield in excess of ~ 90%. UV Vis absorption spectra measurements indicated the band gap of as-synthesized CZTS nanoparticles to be 1.7 eV, which is near the optimum value for photovoltaic solar cell, showing its possible use in photovoltaics.
以硫脲为前驱体,采用水热法制备了纳米Cu2ZnSnS4 (CZTS)粉体。用x射线对粉末进行定性分析,鉴定相,用透射电子显微镜(TEM)测定颗粒大小。在337.5 cm−1处的拉曼峰证实了纯CZTS粒子的形成。并以乙二胺为溶剂热合成了该粉体。水热合成的粉末中存在kesterite相Cu2ZnSnS4,粒径约为4 ~ 5 nm。采用水热法进行绿色环保合成,可生产出克级合成材料,化学收率可达90%以上。紫外可见吸收光谱测量表明,合成的CZTS纳米粒子带隙为1.7 eV,接近光伏太阳能电池的最佳带隙,显示了其在光伏领域的应用前景。
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引用次数: 24
Charge Transfer in Nanocrystalline Semiconductor Electrodes 纳米晶半导体电极中的电荷转移
Pub Date : 2013-05-25 DOI: 10.1155/2013/953153
M. Bouroushian
Nanocrystalline electrodes in liquid junction devices possess a number of unique properties arising from their convoluted structure and the dimensions of their building units. The light-induced charge separation and transport in photoelectrochemical systems using nanocrystalline/nanoporous semiconductor electrodes is discussed here in connection with the basic principles of the (Schottky) barrier theory. Recent models for charge transfer kinetics in normal and unipolar (dye-sensitized) cells are reviewed, and novel concepts and materials are considered.
液体结器件中的纳米晶电极由于其卷曲的结构和其构建单元的尺寸而具有许多独特的性质。本文结合肖特基势垒理论的基本原理,讨论了纳米晶/纳米孔半导体电极在光电化学体系中的光致电荷分离和输运。在正常和单极(染料敏化)细胞电荷转移动力学的最新模型进行了回顾,并考虑了新的概念和材料。
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引用次数: 2
Effect of Nanoalumina on the Electrochemical and Mechanical Properties of Waterborne Polyurethane Composite Coatings 纳米氧化铝对水性聚氨酯复合涂料电化学性能和力学性能的影响
Pub Date : 2013-05-20 DOI: 10.1155/2013/527432
S. Dhoke, Narayani Rajgopalan, A. Khanna
A nanocomposite coating was formed by incorporating nanoalumina pigment in a waterborne polyurethane dispersion (WPUD) to different loading levels (0.1% and 1.0% by weight). Electrochemical performance of the nanocomposite coating was evaluated by applying these nanomodified coatings on mild steel substrate and exposing them to salt-spray, humidity, and accelerated UV weathering. The surface morphology of the composite coating was evaluated using various analytical techniques. SEM and AFM were used to investigate the dispersion of nanoalumina pigment and surface morphological changes of the nanomodified coating, before and after exposure to the test environment. Mechanical properties like scratch resistance were studied by using nanoscratch technique (Nanoindenter TI-900, Hysitron Inc, USA) and hardness using pencil hardness test method. The results showed an improvement in the corrosion, UV weathering, and mechanical properties of the coatings at lower concentration (0.1% by wt), indicating the positive effect of addition of nanoalumina pigment to the coating.
将纳米氧化铝颜料加入水性聚氨酯分散体(WPUD)中,以不同的负载水平(0.1%和1.0%重量)形成纳米复合涂层。通过将纳米改性涂层涂覆在低碳钢基体上,并将其暴露于盐雾、湿度和加速紫外线老化中,对纳米复合涂层的电化学性能进行了评价。利用各种分析技术对复合涂层的表面形貌进行了评价。利用扫描电镜(SEM)和原子力显微镜(AFM)研究了纳米氧化铝颜料的分散情况,以及纳米改性涂层暴露于测试环境前后的表面形态变化。采用纳米划痕技术(nanoindentter TI-900, hyysitron Inc, USA)研究了耐划伤等力学性能,采用铅笔硬度测试法研究了硬度。结果表明,在较低浓度(0.1% wt)下,纳米氧化铝颜料对涂层的腐蚀、紫外老化和力学性能有改善,表明在涂层中添加纳米氧化铝颜料有积极的作用。
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引用次数: 15
The Impact of Nanochloroquine on Restoration of Hepatic and Splenic Mitochondrial Damage against Rodent Malaria 纳米氯喹对啮齿动物疟疾肝脾线粒体损伤修复的影响
Pub Date : 2013-05-16 DOI: 10.1155/2013/106152
Satyajit Tripathy, Sabyasachi Das, S. Dash, S. Chattopadhyay, Somenath Roy
The applications of nanotechnology to pharmacology are the potential appliance of biodegradable polymers and convection-enhanced drug delivery in the diagnostics and treatment of diseases. Chitosan is a natural polysaccharide that has attracted significant scientific interest during the last two decades. The present study was to evaluate the possible effects of chitosan tripolyphosphate conjugated nanochloroquine against Plasmodium berghei infection on select makers of oxidative damage and antioxidant status in mitochondria of liver and spleen. P. berghei infection was developed in Swiss mice by intraperitoneal injection of 200 µL of infected blood. Parasite-infected mice were treated with chloroquine and nanoconjugated chloroquine. Superoxide radical generation, nitrate level, and oxidized glutathione were increased significantly () in the mitochondria of infected group as compared to control group, and reduced glutathione level, activity of SOD, GPx, GR, and GST, and mitochondrial transmembrane potential were decreased significantly (), which were increased or decreased significantly () near to normal in nanoconjugated chloroquine treated group than chloroquine treated group. So, the findings may suggest the advantageous role of nanoconjugated chloroquine against the P. berghei induced oxidative damage in hepatic and splenic mitochondria.
纳米技术在药理学中的应用是生物可降解聚合物和对流增强药物输送在疾病诊断和治疗中的潜在应用。壳聚糖是一种天然多糖,在过去的二十年中引起了科学界的极大兴趣。本研究旨在探讨壳聚糖三聚磷酸偶联纳米氯喹抗伯氏疟原虫感染对肝脏和脾脏线粒体氧化损伤和抗氧化状态的影响。通过向瑞士小鼠腹腔注射200µL感染血液,使其感染伯氏假体。用氯喹和纳米共轭氯喹治疗寄生虫感染小鼠。与对照组相比,感染组线粒体超氧自由基生成、硝酸盐水平、氧化谷胱甘肽水平显著升高(),谷胱甘肽水平、SOD、GPx、GR、GST活性、线粒体跨膜电位显著降低(),纳米共轭氯喹处理组较氯喹处理组显著升高或降低(),接近正常水平。因此,研究结果可能提示纳米共轭氯喹对伯氏弧菌诱导的肝脏和脾脏线粒体氧化损伤具有有利作用。
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引用次数: 14
Adiantum philippense L. Frond Assisted Rapid Green Synthesis of Gold and Silver Nanoparticles 金、银纳米颗粒的快速绿色合成
Pub Date : 2013-05-16 DOI: 10.1155/2013/182320
D. Sant, Tejal Gujarathi, S. Harne, Sougata Ghosh, Rohini Kitture, S. Kale, B. Chopade, K. Pardesi
Development of an ecofriendly, reliable, and rapid process for synthesis of nanoparticles using biological system is an important bulge in nanotechnology. Antioxidant potential and medicinal value of Adiantum philippense L. fascinated us to utilize it for biosynthesis of gold and silver nanoparticles (AuNPs and AgNPs). The current paper reports utility of aqueous extract of A. philippense L. fronds for the green synthesis of AuNPs and AgNPs. Effect of various parameters on synthesis of nanoparticles was monitored by UV-Vis spectrometry. Optimum conditions for AuNPs synthesis were 1 : 1 proportion of original extract at pH 11 and 5 mM tetrachloroauric acid, whereas optimum conditions for AgNPs synthesis were 1 : 1 proportion of original extract at pH 12 and 9 mM silver nitrate. Characterization of nanoparticles was done by TEM, SAED, XRD, EDS, FTIR, and DLS analyses. The results revealed that AuNPs and AgNPs were anisotropic. Monocrystalline AuNPs and polycrystalline AgNPs measured 10 to 18 nm in size. EDS and XRD analyses confirmed the presence of elemental gold and silver. FTIR analysis revealed a possible binding of extract to AuNPs through –NH2 group and to AgNPs through C=C group. These nanoparticles stabilized by a biological capping agent could further be utilized for biomedical applications.
开发一种环保、可靠、快速的利用生物体系合成纳米颗粒的方法是纳米技术的一个重要发展方向。黄芪的抗氧化潜力和药用价值吸引了我们利用它来生物合成金和银纳米粒子(AuNPs和AgNPs)。本文报道了菲立蓬叶水提物在绿色合成AuNPs和AgNPs中的应用。采用紫外-可见光谱法监测各参数对纳米颗粒合成的影响。合成AuNPs的最佳条件为:1∶1的原始提取液,pH为11,5 mM的四氯金酸;合成AgNPs的最佳条件为:1∶1的原始提取液,pH为12,9 mM的硝酸银。通过TEM, SAED, XRD, EDS, FTIR和DLS分析对纳米颗粒进行了表征。结果表明,AuNPs和AgNPs具有各向异性。单晶AuNPs和多晶AgNPs的尺寸为10至18纳米。EDS和XRD分析证实了元素金和银的存在。FTIR分析显示,提取物可能通过-NH2基团与AuNPs结合,通过C=C基团与AgNPs结合。这些由生物封盖剂稳定的纳米颗粒可以进一步用于生物医学应用。
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引用次数: 69
Antibacterial Activity of Silver Nanoparticles Synthesized by Bark Extract of Syzygium cumini 茴香树皮提取物合成纳米银的抗菌活性研究
Pub Date : 2013-04-30 DOI: 10.1155/2013/431218
R. Prasad, V. Swamy
The unique property of the silver nanoparticles having the antimicrobial activity drags the major attention towards the present nanotechnology. The environmentally nontoxic, ecofriendly, and cost-effective method that has been developed for the synthesis of silver nanoparticles using plant extracts creates the major research interest in the field of nanobiotechnology. The synthesized silver nanoparticles have been characterized by the UV-visible spectroscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM). Further, the antibacterial activity of silver nanoparticles was evaluated by well diffusion method, and it was found that the biogenic silver nanoparticles have antibacterial activity against Escherichia coli (ATCC 25922), Staphylococcus aureus (ATCC 29213), Pseudomonas aeruginosa (ATCC 27853), Azotobacter chroococcum WR 9, and Bacillus licheniformis (MTCC 9555).
纳米银具有抗菌活性的独特性质引起了目前纳米技术的广泛关注。利用植物提取物合成银纳米粒子的方法是一种环境无毒、生态友好、成本效益高的方法,是纳米生物技术领域的主要研究方向。利用紫外可见光谱、原子力显微镜(AFM)和扫描电子显微镜(SEM)对合成的纳米银进行了表征。此外,通过孔扩散法对纳米银的抑菌活性进行了评价,发现纳米银对大肠杆菌(ATCC 25922)、金黄色葡萄球菌(ATCC 29213)、铜绿假单胞菌(ATCC 27853)、绿球菌偶氮菌WR 9和地衣芽孢杆菌(MTCC 9555)具有抑菌活性。
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引用次数: 127
Metal Oxide Sol-Gels (, AlO(OH), and ) to Improve the Mechanical Performance of Wood Substrates 金属氧化物溶胶-凝胶(,AlO(OH),和),以改善木材基材的机械性能
Pub Date : 2013-04-29 DOI: 10.1155/2013/273204
V. Landry, P. Blanchet, G. Boivin
Wood is a renewable material widely used in many applications due to its unique properties and distinctive look. However, as wood is organically constituted, it is slowly destroyed by the long-term impact of oxygen, UV radiations, water, and biological attacks (Mahltig et al., 2008). Therefore, protective treatments are necessary to improve the mechanical, thermal, and chemical properties of wood. In order to improve the mechanical properties of sugar maple (Acer saccharum Marsh.), as this species is widely used in the wood products industry, samples of sugar maple were impregnated with sols of metal oxides (AlO(OH), SiO2, and ZrO2). The weight gain and two different techniques of microscopy were used to evaluate the efficiency of the impregnation in the wood samples. The mechanical properties were evaluated using hardness test, scratch test, and impact test. It was shown that the maple samples impregnated with ZrO2 led to the greatest improvement of the mechanical properties.
木材是一种可再生材料,由于其独特的性能和独特的外观,被广泛应用于许多领域。然而,由于木材是有机构成的,它会被氧气、紫外线辐射、水和生物攻击的长期影响慢慢破坏(Mahltig et al., 2008)。因此,保护处理是必要的,以改善木材的机械,热学和化学性能。由于糖枫在木制品工业中被广泛使用,为了改善糖枫的机械性能,对糖枫样品进行了金属氧化物(AlO(OH), SiO2和ZrO2)溶胶浸渍。用增重和两种不同的显微镜技术来评价木材样品的浸渍效率。通过硬度试验、划痕试验和冲击试验对其力学性能进行了评价。结果表明,ZrO2浸渍后的枫材力学性能得到最大程度的改善。
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引用次数: 4
期刊
Journal of Nanoparticles
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