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Predictive Analytical Model for Hydrate Growth Initiation Point in Multiphase Pipeline System 多相管道系统水合物生长起爆点预测分析模型
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-04-15 DOI: 10.11648/j.pse.20230701.13
Akinsete O. Oluwatoyin, Obode Elizabeth, Isehunwa Sunday
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引用次数: 0
Optimization of the Oxidative Desulphurization of Residual Oil Using Hydrogen Peroxide 过氧化氢氧化脱硫渣油工艺的优化研究
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-04-11 DOI: 10.11648/j.pse.20230701.12
Sadiq Tijjani Ahmed, C. Muhammad, Aminu Bayawa Muhammad, Ibrahim Muhammad Danmallam, Sirajo Abubakar Zauro, Bilyaminu Ahmad Rafi
: The role of fuel in global economy cannot be overemphasized, it is necessary to develop new and more efficient technologies in desulphurization processes at a low cost. This research focuses on optimization of desulphurization using oxidative method for higher yields, utilizing dual acetic/formic acid catalyst on residual oil with sulphur concentration > 0.50%wt and emphasizes the improvement of physicochemical properties primarily suitable for use in fuels where regulation is becoming more stringent. The process was conducted using H 2 O 2 oxidant concentration 12.5-25.0% (w/w), CH 3 COOH/HCOOH acid catalyst mixture 12.5-22.0% (w/w), and reaction temperature 40-60°C. Optimization of the desulphurization parameters was done using response surface methodology based on Box-Behnken design. The optimum yield of desulphurization (60.93%) was achieved at the oxidant 18.75% (w/w), acetic/formic mixture of 17.25% (w/w), and reaction temperature of 50°C. In general, the experimentally confirmatory figures in two solutions of 63.29 ± 0.47% and 61.04 ± 0.13% match the predicted values of 62.82% and 60.91%, respectively. The total sulphur content in residual oil was reduced from 0.67 to 0.26%wt. GC-MS of the untreated sample confirm the presence of 1,2-benzisothiazole,3-(hexahydro-1H-azepin-1-yl)- 1,1-dioxide, Nickel(II)bis(N,N-dihexyldithiocarbamate and Diethyl[3-[n-octadecylmercapto]-P-n-butyl-anilino methy lene] malonate with a total percentage peak area of 11.83%. In the treated sample shows no sulphur compounds. The physicochemical analysis for both treated and untreated residual oil according to ASTM were found to be within acceptable limit except sulphur content of untreated sample. After the desulphurization, treated residual oil shows a remarkable improvement in the physicochemical parameters. Hence can be applicable in industrial process and automobiles with very low sulphur emission.
燃料在全球经济中的作用怎么强调都不过分,有必要开发新的、更高效的低成本脱硫技术。本研究的重点是优化氧化法脱硫以提高收率,利用双乙酸/甲酸催化剂处理硫浓度为> 0.50%wt的渣油,并强调改善物化性能,主要适用于监管越来越严格的燃料。反应条件为h2o2氧化剂浓度12.5 ~ 25.0% (w/w), ch3cooh /HCOOH酸性催化剂浓度12.5 ~ 22.0% (w/w),反应温度40 ~ 60℃。采用基于Box-Behnken设计的响应面法对脱硫工艺参数进行了优化。当氧化剂用量为18.75% (w/w),乙酸/甲酸混合物用量为17.25% (w/w),反应温度为50℃时,脱硫收率为60.93%。总的来说,在63.29±0.47%和61.04±0.13%两种溶液下的实验验证值与预测值分别为62.82%和60.91%。残油中总硫含量由0.67 wt降至0.26%wt。未经处理的样品经GC-MS确认存在1,2-苯并异噻唑、3-(六氢- 1h -氮平-1-基)- 1,1-二氧化二氮、镍(II)二(N,N-二己基二硫代氨基甲酸乙酯和二乙基[3-[N-十八烷基巯基]- p -正丁基苯胺甲烯]丙二酸盐,总百分比峰面积为11.83%。经处理的样品中不含硫化合物。根据ASTM对处理过和未处理过的剩余油进行理化分析,除未处理样品的硫含量外,其余均在可接受范围内。经脱硫处理后的渣油理化参数有明显改善。适用于硫排放量极低的工业过程和汽车。
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引用次数: 0
Terpane Characterization of Crude Oils from Niger Delta, Nigeria: A Geochemical Appraisal 尼日利亚尼日尔三角洲原油萜烷特征:地球化学评价
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-03-20 DOI: 10.11648/j.pse.20230701.11
Mark Obinna Onyema, Michael Junior Ajie
: The geochemistry of crude oils from the Niger Delta, Nigeria, were evaluated using the characterization of C 19 to C 35 terpanes. Analyses of two representative crude oils from Western and Central Niger Delta showed abundances of C 19 to C 29 tricyclic terpanes constituted 12.09% and 29.74%, C 24 tetracyclic terpane 0.31% and 0.15% and C 27 to C 35 pentacyclic terpanes 87.61% and 70.12%, respectively. Diagnostic ratios of terpanes indicated relatively low abundances of C 23 , C 28 and C 29 tricyclic terpanes, low abundances of homohopanes, a significantly high abundance of oleanane and that the Niger Delta crude oils were derived from terrestrial organic matter source rocks deposited in an oxic environment during the Tertiary period. Multivariate oil-oil correlation plot showed the Western and Central Niger Delta crude oils are not distinct, but moderately related (genetically). However, diagnostic ratios of C 24 tetracyclic terpane, which was high and moderate and gammacerane, which was low and high, revealed crude oils from Western Niger Delta were derived from predominantly terrestrial source and crude oils from Central Niger Delta were derived from terrestrial source with input from marine organic matter, respectively. Tricyclic terpanes/hopanes and isomerization ratios of C 32 homohopanes indicated the Niger Delta crude oils were generated at high maturity, at top of the oil generation window.
利用c19至c35萜烷的表征,对尼日利亚尼日尔三角洲原油的地球化学进行了评价。对尼日尔三角洲西部和中部两种代表性原油的分析表明,c19 ~ c29三环萜烷的丰度分别为12.09%和29.74%,c24四环萜烷的丰度分别为0.31%和0.15%,c27 ~ c35五环萜烷的丰度分别为87.61%和70.12%。萜烷的诊断比值表明,c23、c28和c29三环萜烷丰度相对较低,同藿烷丰度较低,齐墩烷丰度显著较高,表明尼日尔三角洲原油来源于第三纪沉积于缺氧环境的陆相有机质烃源岩。多元油-油相关图显示,尼日尔三角洲西部和中部原油不明显,但有一定的相关性(遗传)。然而,c24四环萜烷(高、中)和伽马蜡烷(低、高)的诊断比值表明,尼日尔三角洲西部原油主要来自陆源,而尼日尔三角洲中部原油则主要来自陆源,并有海相有机质的输入。三环萜烷/藿烷和c32型藿烷异构化比值表明,尼日尔三角洲原油处于高成熟度,处于生油窗口的顶端。
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引用次数: 0
Denoising research of petrographic thin section images with the global residual generative adversarial network 基于全局残差生成对抗性网络的岩相薄片图像去噪研究
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111204
Shaowei Pan , Jincai Ma , Xiaomei Fu , Dou Chen , Ning Xu , Guowei Qin

Petrographic thin section images have an important role in depositional environment inference, prediction of reservoir physical properties, and oil and gas analysis. To overcome the current challenges in thin section image denoising, we propose the global residual generative adversarial network (GR-GAN). Compared with the classical generative adversarial network (GAN), the residual network structure of the GR-GAN is reconstructed, and the loss function is redefined. The GR-GAN is then applied to denoise the thin section images in two different oilfields. The final denoising results confirmed that the GR-GAN achieves the best denoising effects on both visual evaluation metrics and objective evaluation metrics compared with colour block-matching 3D filtering (CBM3D), K-singular value decomposition (K-SVD), the GAN and a fast and flexible denoising network (FFDNet). Specifically, the peak signal-to-noise ratio (PSNR) and structural similarity (SSIM) generated by the GR-GAN on the test set are 28.2410 and 0.9674, 28.1075 and 0.9443, and 27.9919 and 0.9399, respectively, when the Gaussian noise is 15 dB, 25 dB and 35 dB, respectively, in the thin section image of the small-pore and fine-throat-type structures of J Oilfield; however, the data become 27.2841 and 0.9228, 26.8177 and 0.9162, and 26.3043 and 0.9068 for CBM3D, respectively, and these data generated by other methods are between the aforementioned two sets of data. The normalized root mean squared error (NRMSE) generated by the GR-GAN and CBM3D with the test set are 0.0327 and 0.1382, 0.0584 and 0.1341, and 0.0786 and 0.1382, respectively, when the Gaussian noise is 15 dB, 25 dB and 35 dB, respectively, and the NRMSE generated by the other methods is also between the aforementioned two sets of data. For other types of thin section images, when the Gaussian noise is 15 dB, 25 dB and 35 dB, respectively, CBM3D, K-SVD, the GAN, FFDNet and the GR-GAN show similar denoising effects as previously described. Moreover, in a denoising experiment repeated more than 10 times with the above methods, the GR-GAN has the shortest mean running time of 1.0589 s, and the mean running times of CBM3D, K-SVD, the GAN and FFDNet are 6.4609 s, 155.3158 s, 1.9394 s and 1.0622 s, respectively.

岩石学薄片图像在沉积环境推断、储层物性预测和油气分析中具有重要作用。为了克服目前薄切片图像去噪的挑战,我们提出了全局残差生成对抗性网络(GR-GAN)。与经典的生成对抗性网络(GAN)相比,对GR-GAN的残差网络结构进行了重构,并重新定义了损失函数。然后应用GR-GAN对两个不同油田的薄片图像进行去噪处理。最终的去噪结果证实,与色块匹配三维滤波(CBM3D)、K-奇异值分解(K-SVD)、GAN和快速灵活的去噪网络(FFDNet)相比,GR-GAN在视觉评价指标和客观评价指标上都取得了最佳的去噪效果。具体来说,在J油田小孔和细喉型结构的薄片图像中,当高斯噪声分别为15dB、25dB和35dB时,GR-GAN在测试集上产生的峰值信噪比(PSNR)和结构相似性(SSIM)分别为28.2410和0.9674、28.1075和0.9443、27.9919和0.9399;然而,CBM3D的数据分别为27.2841和0.9228、26.8177和0.9162以及26.3043和0.9068,并且通过其他方法生成的这些数据在上述两组数据之间。当高斯噪声分别为15dB、25dB和35dB时,GR-GAN和CBM3D与测试集产生的归一化均方根误差(NRMSE)分别为0.0327和0.1382、0.0584和0.1341以及0.0786和0.1382,并且其他方法产生的NRMSE也在上述两组数据之间。对于其他类型的薄片图像,当高斯噪声分别为15dB、25dB和35dB时,CBM3D、K-SVD、GAN、FFDNet和GR-GAN显示出与先前描述的类似的去噪效果。此外,在用上述方法重复10次以上的去噪实验中,GR-GAN的平均运行时间最短,为1.0589s,CBM3D、K-SVD、GAN和FFDNet的平均运行次数分别为6.4609s、155.3158s、1.9394s和1.0622s。
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引用次数: 1
Stochastic modelling of wellbore leakage in British Columbia 不列颠哥伦比亚省井筒泄漏的随机模型
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111199
E. Trudel , I.A. Frigaard

Wellbore leakage is complicated to understand due to the range of potential leakage pathways and uncertainties regarding their capacities. In this study we present a novel approach to modelling realistic leakage along microannulus pathways of varying thickness. We use stochastic methods to calibrate leakage pathway dimensions to the surface casing vent flow (SCVF) leakage rates reported in British Columbia, Canada. Results shows that representing dry microannulus thicknesses with a lognormal distribution provides a good fit for the intermediate ranges of SVCF flow rates, but that a dry microannulus alone cannot account for all instances of wellbore leakage. We then approach small and high flow rates independently, offering explanations for these. This includes a wet microannulus/mud channel model to account for instances of poor mud removal, which is better able to account for the less frequent higher leakage rates. We conclude that flow rates above 10 m3/day are progressively likely to be caused by significant failures in mud displacement during primary cementing, or other extreme events such as casing failure due to geological or operational factors.

由于潜在泄漏途径的范围和泄漏能力的不确定性,井眼泄漏很难理解。在这项研究中,我们提出了一种新的方法来模拟沿着不同厚度的微环路径的真实泄漏。我们使用随机方法将泄漏通道尺寸校准为加拿大不列颠哥伦比亚省报道的地面套管排气流(SCVF)泄漏率。结果表明,用对数正态分布表示干微环空厚度可以很好地适应SVCF流量的中间范围,但仅干微环空不能解释所有的井筒泄漏情况。然后,我们分别研究了小流量和大流量,并给出了解释。这包括一个湿微环空/泥浆通道模型,以解释泥浆去除不良的情况,这能够更好地解释不太频繁的高泄漏率。我们得出的结论是,超过10 m3/天的流量越来越有可能是由初次固井期间泥浆置换的重大失败或其他极端事件(如地质或操作因素导致的套管损坏)引起的。
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引用次数: 3
The thermoporoelastic coupling analysis of wellbore stability in shale formation under supercritical CO2 drilling conditions 超临界CO2钻井条件下页岩地层井筒稳定性热—孔—弹耦合分析
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111146
Bing Bai , Mian Chen , Yan Jin , Shiming Wei , Haiyan Zheng

Supercritical carbon dioxide (ScCO2) drilling can effectively protect shale formation from hydration damage and improve drilling rate comparing to conventional drilling technology. The wellbore stability of shale formation is one considerable issue under ScCO2 drilling conditions. In this study, the numerical simulations are performed to calculate collapse cycling time of shale formation under ScCO2 drilling conditions based on thermoporoelastic coupling model. The results show that comparing to water seepage condition, the variation of formation temperature is larger, pore pressure and stress are lower for ScCO2 seepage condition without adsorption effect, the comparison between water and ScCO2 seepage conditions verifies the thermoporoelastic coupling model. For ScCO2 drilling conditions, if adsorption‒induced strain is ignored, the risk of wellbore collapse will be slightly underestimated comparing to the results with adsorption effect. When adsorption‒enhanced elastic modulus is ignored, the risk of wellbore collapse will be significantly underestimated comparing to the results with adsorption effect. The wellbore collapse may occur with the increasing well depth for ScCO2 drilling conditions. This study can provide the theoretical guidance for exploiting shale reservoirs using ScCO2.

与常规钻井技术相比,超临界二氧化碳(ScCO2)钻井可以有效保护页岩地层免受水化损害,提高钻井速度。在ScCO2钻井条件下,页岩地层的井筒稳定性是一个相当重要的问题。本文基于热孔弹耦合模型,对ScCO2钻井条件下页岩地层崩塌循环时间进行了数值模拟。结果表明:与水渗流条件相比,无吸附作用的ScCO2渗流条件下,地层温度变化较大,孔隙压力和应力较低,水与ScCO2渗流条件的对比验证了热孔弹耦合模型。在ScCO2钻井条件下,如果忽略吸附引起的应变,则与吸附效应的结果相比,井眼坍塌的风险略显低估。当不考虑吸附增强弹性模量时,与考虑吸附效应的结果相比,井眼坍塌的风险被大大低估。在ScCO2钻井条件下,随着井深的增加,可能发生井筒坍塌。该研究可为利用ScCO2开发页岩储层提供理论指导。
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引用次数: 1
New direction for regional reservoir quality prediction using machine learning - Example from the Stø Formation, SW Barents Sea, Norway 利用机器学习进行区域储层质量预测的新方向——以挪威西南巴伦支海Stø组为例
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111149
H.N. Hansen, B.G. Haile, R. Müller, J. Jahren

Recently, the petroleum industry has focused on deeply buried reservoir discoveries and exploring potential CO2 storage sites close to existing infrastructure to increase the life span of already operating installations to save time and cost. It is therefore essential for the petroleum industry to find an innovative approach that exploits the existing core- and well log data to be successful in their endeavor of effectively characterizing and predicting reservoir quality. Continuous data sources (e.g. wireline logs) have a huge potential compared with expensive, time inefficient and sporadic data from cores in determining reservoir quality for use in a regional context. However, whereas core analysis offers in-depth knowledge about rock properties and diagenetic processes, continuous data sources can be difficult to interpret without a formation-specific framework. Here, we demonstrated how the pre-existing core data could be effectively used by integrating petrographic- and facies data with a pure predictive machine learning (ML) based porosity predictor. The inclusion of detailed core analysis is important for determining which reservoir parameter(s) that should be modeled and for the interpretation of model outputs. By applying this methodology, a framework for deducing lithological and diagenetic attributes can be established to aid reservoir quality delineation from wireline logs that can be used in frontier areas. With the ML porosity model, a Random Forest Regressor, the square of the correlation was 0.84 between predicted- and helium porosity test data over a large dataset consisting of 38 wells within the Stø Formation across the SW Barents Sea. By integrating the continuous ML porosity logs and core data, it was possible to differentiate three distinct bed types on wireline log responses within the Stø Formation. Particularly, the relationship between Gamma ray (GR) and porosity was effective in separating high porosity clean sand-, low porosity cemented clean sand and more clay and silt rich intervals. Additionally, in the P-wave velocity (VP) - density domain, separation of high porosity clean sand- and heavily cemented low porosity clean sand intervals were possible. The results also show that the ML derived porosity curves coincide with previously published and independent facies data from a selection of the wells included in the study. This demonstrates the applicability of the model in the region, because the Stø Formation has been described to exhibit similar lithological- and mineralogical properties over large parts of the Western Barents Sea area. Even though, continuous porosity data could be estimated from other sources like VP, neutron or density logs, this would generally require matrix and fluid information. This study demonstrated the effectiveness of the ML model in generating continuous porosity logs that are useful for characterizing and predicting reservoir properties in new wells. This methodology

最近,石油行业将重点放在了深埋油藏的发现上,并在现有基础设施附近勘探潜在的二氧化碳储存地点,以延长现有设施的使用寿命,从而节省时间和成本。因此,石油行业必须找到一种创新的方法,利用现有的岩心和测井数据,成功地有效表征和预测储层质量。与昂贵、费时且零散的岩心数据相比,连续数据源(如电缆测井)在确定储层质量方面具有巨大的潜力,可用于区域环境。然而,尽管岩心分析提供了对岩石性质和成岩过程的深入了解,但如果没有特定于地层的框架,就很难解释连续的数据源。在这里,我们展示了如何通过将岩石学和相数据与纯粹的基于预测机器学习(ML)的孔隙度预测器相结合,有效地利用已有的岩心数据。包含详细的岩心分析对于确定应该建模的储层参数和解释模型输出非常重要。通过应用该方法,可以建立一个推断岩性和成岩属性的框架,以帮助在前沿地区使用电缆测井曲线来描绘储层质量。使用ML孔隙度模型(一种随机森林回归器),在由38口井组成的大型数据集中,预测孔隙度和氦气孔隙度测试数据之间的相关平方为0.84。通过整合连续的ML孔隙度测井和岩心数据,可以在Stø地层中通过电缆测井响应区分出三种不同的层型。特别是伽马射线(GR)与孔隙度之间的关系对于分离高孔隙度洁净砂、低孔隙度胶结洁净砂以及富含粘土和粉砂的层段是有效的。此外,在纵波速度(VP) -密度域中,可以分离高孔隙度洁净砂层和重度胶结的低孔隙度洁净砂层。结果还表明,ML导出的孔隙度曲线与先前发表的独立相数据相吻合,这些数据来自于研究中包括的一些井。这证明了该模型在该地区的适用性,因为在西巴伦支海的大部分地区,storo组已经被描述为具有相似的岩性和矿物学性质。尽管连续孔隙度数据可以从其他来源(如VP、中子或密度测井)估计,但这通常需要基质和流体信息。该研究证明了ML模型在生成连续孔隙度测井数据方面的有效性,这对于新井的储层性质表征和预测非常有用。该方法提供了一套工作流程,可以利用已获得的岩心和测井数据进行前沿勘探,适用于全球其他地层和勘探场景。
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引用次数: 0
Cluster structure of interfacial molecules studied by oblique incidence reflectance difference: Influences of salt ion on oil-water interfacial properties 斜入射反射差研究界面分子团簇结构:盐离子对油水界面性质的影响
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111147
Zhaohui Meng , Fankai Qin , Anqi Li , Huimin Li , Sijie Dong , Chao Song , Xinyang Miao , Wenzheng Yue , Kun Zhao , Honglei Zhan

Tuning the concentration of the ions is beneficial for improving oil recovery by water flooding. Despite the widely recognized distribution of salt ions at the water interface, their effects on the structure of interfacial water, such as hydrogen(H) bonds, are unclear. In this study, using oblique incident reflectance difference (OIRD) technique and interfacial rheometer to analyze the alkanes-ion solution interface, we show that ions have a significant effect on the perturbation of hydrogen bonds at the alkanes-water interface. The change in the water layer structure follows the gradual increase in the concentration of Na2SO4/Na2CO3 and the decrease in the interfacial tension, and dielectric constant at the alkane-solution interface. Specifically, structure-breaking anions such as SO42− and CO32− decrease the average H-bonding of water at the alkane/water interface, thus damaging the molecular cluster structure at the interface. Although Cl will form hydration ions with water molecules, it will not break the hydrogen bond structure between water molecules at the interface. These results indicate the mechanism of anion effects on the alkane/water interface, and for samples with high saturated alkane content, a repellent solution containing SO42− can be preferentially selected for repelling, providing a new idea for the study of the molecular boundary of the oil-water interface.

调整离子浓度有利于提高水驱采收率。尽管人们普遍认识到盐离子在水界面上的分布,但它们对界面水结构(如氢键)的影响尚不清楚。本研究利用斜入射反射差(OIRD)技术和界面流变仪对烷烃-离子溶液界面进行了分析,发现离子对烷烃-水界面氢键的扰动有显著影响。水层结构的变化是随着Na2SO4/Na2CO3浓度的逐渐增加和烷烃-溶液界面张力和介电常数的降低而发生的。具体来说,SO42−和CO32−等破坏结构的阴离子降低了水在烷烃/水界面上的平均氢键,从而破坏了界面上的分子簇结构。虽然Cl−会与水分子形成水合离子,但不会破坏界面处水分子间的氢键结构。这些结果说明了阴离子作用在烷烃/水界面上的机理,对于饱和烷烃含量高的样品,可以优先选择含有SO42−的驱避液进行驱避,为油水界面分子边界的研究提供了新的思路。
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引用次数: 0
Chemical treatment of oilfield wastewater and the effect of temperature on treatment efficiency: A review 油田废水化学处理及温度对处理效果的影响综述
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111089
Arafat Husain , Mamdouh A. Al-Harthi

Treatment of the oilfield wastewater from the chemical and petroleum industries, often present in the form of emulsion, is one of the major environmental concern in current times. Demulsification is presently the most viable method to separate the oil and water from a rigid, homogenous emulsion especially, chemical demulsification. Mostly, chemical demulsifiers used at high temperature can give enhanced separation efficiency and result in the use of less dosage of expensive chemicals. Mainly, the reservoir conditions also exist at high temperature, thus, it is important to consider the effect of temperature for the selection of best choice among available demulsifiers. The review discusses the recent discoveries and modification among the existing demulsifiers such as triblock EO-PO copolymer, non-biodegradable polymers, branched copolymers and others. The major chemical demulsifiers and their upcoming alternatives such as the nanomaterial demulsifiers and ionic liquids have also been discussed in great details. Chemical structure and molecular weight were found to influence the emulsion breaking ability of a demulsifier. The surface properties play an important role in the selection of appropriate demulsifier whether hydrophobic or hydrophilic. Method of heating whether microwave or conventional heating, doesn't play a significant role in influencing the emulsion breaking efficiency of polymeric surfactants. However, microwave heating is preferred for demulsification by ionic liquids. Lastly, the whole mechanism of chemical demulsification and few upcoming chemical treatments for demulsification are also well described in brief.

化工和石油工业的油田废水通常以乳化液的形式存在,其处理是当今环境关注的主要问题之一。破乳是目前从刚性均质乳化液中分离油水最可行的方法,特别是化学破乳。在高温下使用化学破乳剂可以提高分离效率,减少昂贵化学品的用量。主要是储层条件也存在高温,因此,在现有破乳剂中选择最佳破乳剂时,考虑温度的影响是很重要的。综述了现有破乳剂如三嵌段EO-PO共聚物、不可生物降解聚合物、支链共聚物等的最新发现和改性。对主要的化学破乳剂及其未来的替代品,如纳米材料破乳剂和离子液体也进行了详细的讨论。研究了破乳剂的化学结构和分子量对破乳能力的影响。无论是疏水破乳剂还是亲水破乳剂,其表面性质对选择合适的破乳剂起着重要的作用。加热方式无论是微波加热还是常规加热,对聚合物表面活性剂的破乳效果影响不大。然而,微波加热是离子液体破乳的首选方法。最后,简要介绍了化学破乳的整个机理和几种即将出现的化学破乳方法。
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引用次数: 9
Key factors controlling deep Carboniferous volcanic reservoirs in the east slope of Mahu Sag, Junggar Basin, NW China 准噶尔盆地马湖凹陷东斜坡深石炭系火山岩储层控制因素
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 DOI: 10.1016/j.petrol.2022.111223
Lu Xia , Yiwei Zhao , Chunlan Yu , Kelai Xi , Yiming Ablimiti , Hailei Liu , Lei Chen

Considering the complex factors controlling volcanic reservoirs, the Carboniferous strata in the eastern slope area of the Mahu Sag (ESMS) in the northwestern Junggar Basin (NJB) were investigated using rock cores, thin sections, scanning electron microscope (SEM), physical properties, major elements, X-ray fluorescence (XRF), well logging, and seismic data. The volcanic rocks revealed by drilling are mostly weathering crust reservoirs (WCRs), the formation of which in and around the study area is significantly controlled by weathering and leaching (WL). Most types of volcanic rock can be improved by long-term weathering. Favorable reservoirs in the ESMS are often developed within 150 m below the tectonic unconformity boundary at the top of the Carboniferous. The longer the weathering duration, the better are the overall quality of the WCRs. Weathering duration of about 40 Ma is probably an important threshold in the NJB. Ultra-long leaching of atmospheric water and strong late dissolution of acidic fluids before oil and gas accumulations are important for reservoir development and petroleum accumulation in volcanic strata filled with authigenic minerals, especially calcite. The early regional tectonic movement affected the volcanic eruption and controlled the lithofacies distribution. The linear density of fractures was negatively correlated with the distance from the main controlling fault. Owing to the relatively weak filling, high-angle fractures contribute significantly to the reservoir permeability. The physical properties of volcanic breccia are better than those of tuff, and the porosity, permeability, and fracture density of andesite are higher than those of basalt. The physical properties of near-source facies belts of a volcanic edifice are better than those of far-source facies ones. Favorable exploration areas are the structural highs and fault zones where the duration of WL is more than 40 Ma, explosive facies and effusive facies near the crater are developed, or the inherited ancient buried hills transformed by faults and fractures near excellent source rocks, where the dissolution of atmospheric water and organic acidic fluids are strong.

考虑到控制火山岩储层的复杂因素,利用岩心、薄片、扫描电镜(SEM)、物性、主元素、x射线荧光(XRF)、测井和地震等资料,对准噶尔盆地西北部马湖凹陷东部斜坡区石炭系地层进行了研究。钻探发现的火山岩多为风化壳储层,研究区内及周边的风化淋滤作用对风化壳储层的形成具有明显的控制作用。大多数类型的火山岩都可以通过长期的风化作用得到改善。石炭系顶部构造不整合边界以下150 m范围内往往发育有利储层。风化时间越长,wcr的整体质量越好。40 Ma左右的风化持续时间可能是NJB的一个重要阈值。在油气成藏前,大气水的超长浸出作用和酸性流体的强后期溶蚀作用对油气发育和富含自生矿物(尤其是方解石)的火山岩地层的油气成藏具有重要意义。早期区域构造运动影响了火山喷发,控制了岩相分布。裂缝线密度与离主控断层的距离呈负相关。由于充填程度相对较弱,高角度裂缝对储层渗透率的贡献较大。火山角砾岩的物性优于凝灰岩,安山岩的孔隙度、渗透率和裂缝密度均高于玄武岩。火山大厦近源相带物性优于远源相带。有利勘探区域为白垩世持续时间大于40 Ma的构造高位和断裂带,火山口附近发育爆炸相和喷涌相,或优良烃源岩附近断裂、裂缝改造的继承古潜山,大气水和有机酸性流体溶蚀作用强。
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引用次数: 2
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Journal of Petroleum Science and Engineering
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