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Effect of low OBM contamination on long-term integrity of API class H cement slurries – Experimental study 低OBM污染对API H级水泥浆长期完整性的影响——实验研究
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-11-03 DOI: 10.1016/j.petrol.2022.111191
Nachiket Arbad , Catalin Teodoriu , Mahmood Amani

Drilling mud acts as an important primary barrier during the well construction phase, while the integrity of cement sheath is critical throughout the life cycle of the well. The mud-spacer-cement interactions highly affect the long-term integrity of the cement sheath and in other words the well integrity. Even today, the spacers are not capable of displacing all the drilling mud present in the wellbore before performing cementing operations and the cement slurry is contaminated with a small amount of drilling fluid and/or spacers. Oil based mud (OBM) is highly preferred over water-based mud (WBM) as a drilling fluid when drilling in challenging environments, but with current push for more environmentally drilling fluids the Water Base Muds (WBM) are preferred.

The detrimental effects of high OBM contamination (>5%) on the mechanical and rheological properties of API Cement slurries have been fairly studied in the previous decade. This study focuses on the strength development of low OBM contaminated (0.8%, 1.6%, 3.2%, 6.3%) API Class H cement slurries cured for up to 28 days at ambient temperature as well as the elevated temperature of 75 °C. The Ultrasonic Pulse Velocity (UPV) was measured by performing the non-destructive tests before performing the destructive tests which measure the actual Unconfined Compressive Strength (UCS). Based on the 141 samples tested in this study, even for 0.8% OBM contamination the strength of Class H cement samples cured for 7 days at 75 °C was reduced by 23%, and for 3.2% OBM contamination it was reduced by 39%. Novel correlations of UCS vs time and UCS vs UPV were developed to accurately simulate the downhole conditions and predict the long-term integrity of the wellbore cement. A reliable dataset for developing cement data repositories was established which also can be merged with existing databases.

钻井泥浆在油井施工阶段起着重要的主要屏障作用,而水泥环的完整性在油井的整个生命周期中至关重要。泥浆间隔层-水泥相互作用高度影响水泥环的长期完整性,换句话说,影响井的完整性。即使在今天,间隔器也不能在执行固井操作之前置换井筒中存在的所有钻井泥浆,并且水泥浆被少量钻井液和/或间隔器污染。在具有挑战性的环境中钻井时,油基泥浆(OBM)比水基泥浆(WBM)更受青睐,但随着目前对更环保钻井液的推动,水基泥浆(WBM)是首选。高OBM污染(>;5%)对API水泥浆的机械和流变性能的有害影响在过去十年中已经得到了充分的研究。本研究的重点是低OBM污染(0.8%、1.6%、3.2%、6.3%)API H级水泥浆在环境温度和75°C的高温下固化28天的强度发展。在进行测量实际无侧限抗压强度(UCS)的破坏性试验之前,通过进行非破坏性试验来测量超声脉冲速度(UPV)。根据本研究中测试的141个样本,即使有0.8%的OBM污染,在75°C下固化7天的H类水泥样本的强度也降低了23%,对于3.2%的OBM污染物,强度降低了39%。开发了UCS与时间和UCS与UPV的新相关性,以准确模拟井下条件并预测井筒水泥的长期完整性。建立了一个用于开发水泥数据库的可靠数据集,该数据集也可以与现有数据库合并。
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引用次数: 0
Denoising research of petrographic thin section images with the global residual generative adversarial network 基于全局残差生成对抗性网络的岩相薄片图像去噪研究
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-11-11 DOI: 10.1016/j.petrol.2022.111204
Shaowei Pan , Jincai Ma , Xiaomei Fu , Dou Chen , Ning Xu , Guowei Qin

Petrographic thin section images have an important role in depositional environment inference, prediction of reservoir physical properties, and oil and gas analysis. To overcome the current challenges in thin section image denoising, we propose the global residual generative adversarial network (GR-GAN). Compared with the classical generative adversarial network (GAN), the residual network structure of the GR-GAN is reconstructed, and the loss function is redefined. The GR-GAN is then applied to denoise the thin section images in two different oilfields. The final denoising results confirmed that the GR-GAN achieves the best denoising effects on both visual evaluation metrics and objective evaluation metrics compared with colour block-matching 3D filtering (CBM3D), K-singular value decomposition (K-SVD), the GAN and a fast and flexible denoising network (FFDNet). Specifically, the peak signal-to-noise ratio (PSNR) and structural similarity (SSIM) generated by the GR-GAN on the test set are 28.2410 and 0.9674, 28.1075 and 0.9443, and 27.9919 and 0.9399, respectively, when the Gaussian noise is 15 dB, 25 dB and 35 dB, respectively, in the thin section image of the small-pore and fine-throat-type structures of J Oilfield; however, the data become 27.2841 and 0.9228, 26.8177 and 0.9162, and 26.3043 and 0.9068 for CBM3D, respectively, and these data generated by other methods are between the aforementioned two sets of data. The normalized root mean squared error (NRMSE) generated by the GR-GAN and CBM3D with the test set are 0.0327 and 0.1382, 0.0584 and 0.1341, and 0.0786 and 0.1382, respectively, when the Gaussian noise is 15 dB, 25 dB and 35 dB, respectively, and the NRMSE generated by the other methods is also between the aforementioned two sets of data. For other types of thin section images, when the Gaussian noise is 15 dB, 25 dB and 35 dB, respectively, CBM3D, K-SVD, the GAN, FFDNet and the GR-GAN show similar denoising effects as previously described. Moreover, in a denoising experiment repeated more than 10 times with the above methods, the GR-GAN has the shortest mean running time of 1.0589 s, and the mean running times of CBM3D, K-SVD, the GAN and FFDNet are 6.4609 s, 155.3158 s, 1.9394 s and 1.0622 s, respectively.

岩石学薄片图像在沉积环境推断、储层物性预测和油气分析中具有重要作用。为了克服目前薄切片图像去噪的挑战,我们提出了全局残差生成对抗性网络(GR-GAN)。与经典的生成对抗性网络(GAN)相比,对GR-GAN的残差网络结构进行了重构,并重新定义了损失函数。然后应用GR-GAN对两个不同油田的薄片图像进行去噪处理。最终的去噪结果证实,与色块匹配三维滤波(CBM3D)、K-奇异值分解(K-SVD)、GAN和快速灵活的去噪网络(FFDNet)相比,GR-GAN在视觉评价指标和客观评价指标上都取得了最佳的去噪效果。具体来说,在J油田小孔和细喉型结构的薄片图像中,当高斯噪声分别为15dB、25dB和35dB时,GR-GAN在测试集上产生的峰值信噪比(PSNR)和结构相似性(SSIM)分别为28.2410和0.9674、28.1075和0.9443、27.9919和0.9399;然而,CBM3D的数据分别为27.2841和0.9228、26.8177和0.9162以及26.3043和0.9068,并且通过其他方法生成的这些数据在上述两组数据之间。当高斯噪声分别为15dB、25dB和35dB时,GR-GAN和CBM3D与测试集产生的归一化均方根误差(NRMSE)分别为0.0327和0.1382、0.0584和0.1341以及0.0786和0.1382,并且其他方法产生的NRMSE也在上述两组数据之间。对于其他类型的薄片图像,当高斯噪声分别为15dB、25dB和35dB时,CBM3D、K-SVD、GAN、FFDNet和GR-GAN显示出与先前描述的类似的去噪效果。此外,在用上述方法重复10次以上的去噪实验中,GR-GAN的平均运行时间最短,为1.0589s,CBM3D、K-SVD、GAN和FFDNet的平均运行次数分别为6.4609s、155.3158s、1.9394s和1.0622s。
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引用次数: 1
Chemical treatment of oilfield wastewater and the effect of temperature on treatment efficiency: A review 油田废水化学处理及温度对处理效果的影响综述
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-10-08 DOI: 10.1016/j.petrol.2022.111089
Arafat Husain , Mamdouh A. Al-Harthi

Treatment of the oilfield wastewater from the chemical and petroleum industries, often present in the form of emulsion, is one of the major environmental concern in current times. Demulsification is presently the most viable method to separate the oil and water from a rigid, homogenous emulsion especially, chemical demulsification. Mostly, chemical demulsifiers used at high temperature can give enhanced separation efficiency and result in the use of less dosage of expensive chemicals. Mainly, the reservoir conditions also exist at high temperature, thus, it is important to consider the effect of temperature for the selection of best choice among available demulsifiers. The review discusses the recent discoveries and modification among the existing demulsifiers such as triblock EO-PO copolymer, non-biodegradable polymers, branched copolymers and others. The major chemical demulsifiers and their upcoming alternatives such as the nanomaterial demulsifiers and ionic liquids have also been discussed in great details. Chemical structure and molecular weight were found to influence the emulsion breaking ability of a demulsifier. The surface properties play an important role in the selection of appropriate demulsifier whether hydrophobic or hydrophilic. Method of heating whether microwave or conventional heating, doesn't play a significant role in influencing the emulsion breaking efficiency of polymeric surfactants. However, microwave heating is preferred for demulsification by ionic liquids. Lastly, the whole mechanism of chemical demulsification and few upcoming chemical treatments for demulsification are also well described in brief.

化工和石油工业的油田废水通常以乳化液的形式存在,其处理是当今环境关注的主要问题之一。破乳是目前从刚性均质乳化液中分离油水最可行的方法,特别是化学破乳。在高温下使用化学破乳剂可以提高分离效率,减少昂贵化学品的用量。主要是储层条件也存在高温,因此,在现有破乳剂中选择最佳破乳剂时,考虑温度的影响是很重要的。综述了现有破乳剂如三嵌段EO-PO共聚物、不可生物降解聚合物、支链共聚物等的最新发现和改性。对主要的化学破乳剂及其未来的替代品,如纳米材料破乳剂和离子液体也进行了详细的讨论。研究了破乳剂的化学结构和分子量对破乳能力的影响。无论是疏水破乳剂还是亲水破乳剂,其表面性质对选择合适的破乳剂起着重要的作用。加热方式无论是微波加热还是常规加热,对聚合物表面活性剂的破乳效果影响不大。然而,微波加热是离子液体破乳的首选方法。最后,简要介绍了化学破乳的整个机理和几种即将出现的化学破乳方法。
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引用次数: 9
The thermoporoelastic coupling analysis of wellbore stability in shale formation under supercritical CO2 drilling conditions 超临界CO2钻井条件下页岩地层井筒稳定性热—孔—弹耦合分析
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-10-28 DOI: 10.1016/j.petrol.2022.111146
Bing Bai , Mian Chen , Yan Jin , Shiming Wei , Haiyan Zheng

Supercritical carbon dioxide (ScCO2) drilling can effectively protect shale formation from hydration damage and improve drilling rate comparing to conventional drilling technology. The wellbore stability of shale formation is one considerable issue under ScCO2 drilling conditions. In this study, the numerical simulations are performed to calculate collapse cycling time of shale formation under ScCO2 drilling conditions based on thermoporoelastic coupling model. The results show that comparing to water seepage condition, the variation of formation temperature is larger, pore pressure and stress are lower for ScCO2 seepage condition without adsorption effect, the comparison between water and ScCO2 seepage conditions verifies the thermoporoelastic coupling model. For ScCO2 drilling conditions, if adsorption‒induced strain is ignored, the risk of wellbore collapse will be slightly underestimated comparing to the results with adsorption effect. When adsorption‒enhanced elastic modulus is ignored, the risk of wellbore collapse will be significantly underestimated comparing to the results with adsorption effect. The wellbore collapse may occur with the increasing well depth for ScCO2 drilling conditions. This study can provide the theoretical guidance for exploiting shale reservoirs using ScCO2.

与常规钻井技术相比,超临界二氧化碳(ScCO2)钻井可以有效保护页岩地层免受水化损害,提高钻井速度。在ScCO2钻井条件下,页岩地层的井筒稳定性是一个相当重要的问题。本文基于热孔弹耦合模型,对ScCO2钻井条件下页岩地层崩塌循环时间进行了数值模拟。结果表明:与水渗流条件相比,无吸附作用的ScCO2渗流条件下,地层温度变化较大,孔隙压力和应力较低,水与ScCO2渗流条件的对比验证了热孔弹耦合模型。在ScCO2钻井条件下,如果忽略吸附引起的应变,则与吸附效应的结果相比,井眼坍塌的风险略显低估。当不考虑吸附增强弹性模量时,与考虑吸附效应的结果相比,井眼坍塌的风险被大大低估。在ScCO2钻井条件下,随着井深的增加,可能发生井筒坍塌。该研究可为利用ScCO2开发页岩储层提供理论指导。
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引用次数: 1
Cluster structure of interfacial molecules studied by oblique incidence reflectance difference: Influences of salt ion on oil-water interfacial properties 斜入射反射差研究界面分子团簇结构:盐离子对油水界面性质的影响
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-10-28 DOI: 10.1016/j.petrol.2022.111147
Zhaohui Meng , Fankai Qin , Anqi Li , Huimin Li , Sijie Dong , Chao Song , Xinyang Miao , Wenzheng Yue , Kun Zhao , Honglei Zhan

Tuning the concentration of the ions is beneficial for improving oil recovery by water flooding. Despite the widely recognized distribution of salt ions at the water interface, their effects on the structure of interfacial water, such as hydrogen(H) bonds, are unclear. In this study, using oblique incident reflectance difference (OIRD) technique and interfacial rheometer to analyze the alkanes-ion solution interface, we show that ions have a significant effect on the perturbation of hydrogen bonds at the alkanes-water interface. The change in the water layer structure follows the gradual increase in the concentration of Na2SO4/Na2CO3 and the decrease in the interfacial tension, and dielectric constant at the alkane-solution interface. Specifically, structure-breaking anions such as SO42− and CO32− decrease the average H-bonding of water at the alkane/water interface, thus damaging the molecular cluster structure at the interface. Although Cl will form hydration ions with water molecules, it will not break the hydrogen bond structure between water molecules at the interface. These results indicate the mechanism of anion effects on the alkane/water interface, and for samples with high saturated alkane content, a repellent solution containing SO42− can be preferentially selected for repelling, providing a new idea for the study of the molecular boundary of the oil-water interface.

调整离子浓度有利于提高水驱采收率。尽管人们普遍认识到盐离子在水界面上的分布,但它们对界面水结构(如氢键)的影响尚不清楚。本研究利用斜入射反射差(OIRD)技术和界面流变仪对烷烃-离子溶液界面进行了分析,发现离子对烷烃-水界面氢键的扰动有显著影响。水层结构的变化是随着Na2SO4/Na2CO3浓度的逐渐增加和烷烃-溶液界面张力和介电常数的降低而发生的。具体来说,SO42−和CO32−等破坏结构的阴离子降低了水在烷烃/水界面上的平均氢键,从而破坏了界面上的分子簇结构。虽然Cl−会与水分子形成水合离子,但不会破坏界面处水分子间的氢键结构。这些结果说明了阴离子作用在烷烃/水界面上的机理,对于饱和烷烃含量高的样品,可以优先选择含有SO42−的驱避液进行驱避,为油水界面分子边界的研究提供了新的思路。
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引用次数: 0
A fully integrated reservoir/pipeline network model and its application on the evaluation of subsea water separation performance 一种完全集成的储层/管网模型及其在水下分离性能评估中的应用
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-11-15 DOI: 10.1016/j.petrol.2022.111140
Yuxi Wang , Segen Farid Estefen , Marcelo Igor Lourenço

Subsea water separation (SSWS) is a promising cutting-edge technology in handling specific problems related to offshore development, but the close evaluation of SSWS performance is quite lacking. This work develops an integrated production modeling (IPM) approach to comprehensively quantify the effect of SSWS both from technological and economical perspectives. A fully-implicit integrated production model is proposed, which assembles 3D reservoir equations and pipeline network equations together and seeks for simultaneous solutions. The feature of simultaneous hydro-thermal solution provides a remarkable value in the analysis of flow assurance issues related to wax deposition in the subsea flowlines. The indexing and mapping frameworks make the model prone to configuring different scenarios, both in temporal and spatial dimensions. A case study is presented to analyze the performance of SSWS under four subsea configurations in a pre-salt deepwater condition by three quantitative indicators: NPV, oil recovery, and wax-free index. Results show that subsea water separation has the potential to increase final oil recovery and project NPV for a clustered well system, while limited benefits shall be expected in a satellite well configuration. Also, higher risk of wax deposition is observed in a satellite well configuration compared to a clustered well system. The IPM approach, together with an economic model, provide decision makers with a way to estimate the break-even price on the investment of a subsea water separation station. The methodology proposed in this work also provides a guide in future assessment of other potential subsea technologies.

海底水分离(SSWS)是一项很有前途的尖端技术,可以处理与海上开发相关的特定问题,但对SSWS性能的深入评估相当缺乏。这项工作开发了一种集成生产建模(IPM)方法,从技术和经济角度全面量化SSWS的影响。提出了一种全隐式集成生产模型,该模型将三维油藏方程和管网方程组合在一起并寻求同时解。同时水热溶液的特性在分析海底管线中蜡沉积的流动保障问题方面具有重要的价值。索引和映射框架使模型易于在时间和空间维度上配置不同的场景。通过NPV、原油采收率和无蜡指数三个量化指标,分析了盐下深水条件下四种水下配置下SSWS的性能。结果表明,海底水分离技术有可能提高集束井系统的最终采收率和项目NPV,而卫星井配置的效益有限。此外,与集群井系统相比,卫星井配置中蜡沉积的风险更高。IPM方法与经济模型一起,为决策者提供了一种估算海底水分离站投资盈亏平衡价格的方法。在这项工作中提出的方法也为未来评估其他潜在的海底技术提供了指导。
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引用次数: 4
Applying Massively Parallel Interface for MPFA scheme with advanced linearization for fluid flow in porous media 多孔介质中流体流动的先进线性化MPFA方案的大规模并行界面应用
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-11-09 DOI: 10.1016/j.petrol.2022.111190
Longlong Li , Mark Khait , Denis Voskov , Kirill M. Terekhov , Ahmad Abushaikha

We apply Massively Parallel Interface for MPFA-O scheme with state-of-the-art Operator-Based Linearization (OBL) approach for multiphase flow in porous media. The implementation of MPFA-O scheme enhances the modelling capabilities for non-K-orthogonal mesh. A fully implicit scheme is applied to guarantee the stability of solutions when a mass-based formulation is involved to keep the flexibility of the framework for general-purpose reservoir simulation. As the MPFA-O introduces more non-zeros elements in the Jacobian matrix than the traditional TPFA, massively parallel computations via Message Passing Interface (MPI) in this work help to guarantee competitive computational efficiency for high-fidelity geological models. Concerning the Jacobian assembly hassle, we apply the OBL approach which introduces operators combining the fluid and rock properties in the conservation equations and discretizes the operators in the physical parameter space. By computing values and derivatives of the operators via a multilinear interpolation, the assembly of Jacobian matrix and residual vector could be drastically simplified. Another benefit of the OBL is that by only evaluating operator values on the predefined nodes in the physical parameter space, the overhead related to complex phase behavior and property evaluation is significantly reduced. In the end, we present several benchmark cases to rigorously demonstrate the accuracy, convergence, and robustness of the framework and two challenging field-scale cases to further prove its computing performance and parallel scalability.

我们将MPFA-O方案的大规模并行接口与最先进的基于算子的线性化(OBL)方法应用于多孔介质中的多相流。MPFA-O格式的实现增强了非K正交网格的建模能力。当涉及基于质量的公式时,应用完全隐式方案来保证解的稳定性,以保持通用油藏模拟框架的灵活性。由于MPFA-O在雅可比矩阵中引入了比传统的TPFA更多的非零元素,因此本工作中通过消息传递接口(MPI)进行的大规模并行计算有助于确保高保真地质模型具有竞争力的计算效率。关于雅可比装配问题,我们应用OBL方法,该方法引入了结合守恒方程中流体和岩石性质的算子,并在物理参数空间中离散化了算子。通过多线性插值计算算子的值和导数,可以极大地简化雅可比矩阵和残差向量的组装。OBL的另一个优点是,通过仅评估物理参数空间中预定义节点上的算子值,显著减少了与复杂相位行为和特性评估相关的开销。最后,我们提出了几个基准案例来严格证明该框架的准确性、收敛性和鲁棒性,并提出了两个具有挑战性的领域规模案例来进一步证明其计算性能和并行可扩展性。
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引用次数: 0
A novel apparatus and method for lab-scale study of wellbore integrity using CT imaging and analysis 一种利用CT成像和分析进行井筒完整性实验室规模研究的新型装置和方法
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-11-06 DOI: 10.1016/j.petrol.2022.111209
Alexander Anya, Hossein Emadi, Marshall Watson

Well drilling, completions, stimulation, and enhanced oil recovery operations induce downhole conditions that may negatively impact the integrity of the annular seal and consequently hinder zonal isolation. Thus, the ability to accurately quantify the evolution of the annular seal in response to the prevailing downhole environment is critical for the optimal design of the annular barrier for the life of a well. Thanks to increased accessibility and recent advancements in computing power and techniques, X-ray computed tomography has gained popularity as a non-destructive analysis method in materials science and geomechanics due to its ability to reveal details about the interior volume of objects in real-time without physical disassembly.

Therefore, in this study, a novel apparatus is presented for the construction of a lab-scale wellbore, with the purpose of simulating downhole processes while simultaneously monitoring wellbore elements of interest in real-time via x-ray computed tomography. The benefits of this novel setup for wellbore integrity are demonstrated via applications to two test cases: the mechanical evolution of annular cement under stresses induced by cyclic water injection as a function of the mechanical properties of the cased and cemented wellbore system; the evaluation of nano magnesium oxide performance as an additive for autogenous shrinkage mitigation in annular cement.

The results of the studies presented illustrate the benefits of combining x-ray computed tomography with lab-scale wellbore process simulations. The results of the cyclic water injection study suggest that residual strain in the cement is the major factor in annular seal degradation under cyclic downhole pressure fluctuations. Nano magnesium oxide is also shown to be very effective in preventing autogenous shrinkage of Class H cement. However, more study is required to characterize its effectiveness in a wider range of cement formulations. Finally, suggestions are offered on how to improve the experimental procedure presented while future potential applications of the apparatus are discussed.

钻井、完井、增产和强化采油作业会导致井下条件对环形密封的完整性产生负面影响,从而阻碍区域隔离。因此,准确量化环形密封件响应于主要井下环境的演变的能力对于环形屏障在井的寿命内的最佳设计是至关重要的。由于可访问性的提高以及计算能力和技术的最新进步,X射线计算机断层扫描作为一种非破坏性分析方法在材料科学和地质力学中越来越受欢迎,因为它能够实时揭示物体内部体积的细节,而无需物理拆卸。因此,在本研究中,提出了一种用于建造实验室规模井筒的新型设备,目的是模拟井下过程,同时通过x射线计算机断层扫描实时监测感兴趣的井筒元件。通过应用于两个测试案例,证明了这种新型装置对井筒完整性的好处:环形水泥在循环注水引起的应力下的机械演化,作为套管和胶结井筒系统机械性能的函数;纳米氧化镁作为减缓环空水泥自收缩添加剂的性能评价。所提供的研究结果说明了将x射线计算机断层扫描与实验室规模的井筒过程模拟相结合的好处。循环注水研究结果表明,在循环井下压力波动的情况下,水泥中的残余应变是环空密封劣化的主要因素。纳米氧化镁也被证明在防止H类水泥的自收缩方面非常有效。然而,还需要更多的研究来表征其在更广泛的水泥配方中的有效性。最后,对如何改进实验程序提出了建议,并对该装置未来的潜在应用进行了讨论。
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引用次数: 3
New insights into Upper Cretaceous hydrocarbon traps of platform-basin flanks in the Sahel Eastern Tunisian petroleum province: Inferred optimal hydrocarbon reserves accumulations 突尼斯东部萨赫勒石油省平台盆地侧翼上白垩纪油气圈闭的新见解:推断的最佳油气储量聚集
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-11-13 DOI: 10.1016/j.petrol.2022.111232
Mourad Bédir , Amina Mabrouk El Asmi

The eastern Tunisian margin is considered an Upper Cretaceous and Eocene petroleum province. It has been affected by Mesozoic rifting and Cenozoic compression. Several oil and gas shows and accumulations have been discovered in Upper Cretaceous carbonates within structural anticlinal closures. These anticlinal highs represent inherited rift platform horsts with hiatuses, unconformities and sediment erosion. Seismic sequence stratigraphy and seismic tectonic analyses of Mesozoic and Cenozoic horizons, delineate the control of deep-rooted transtensional and transpressional Flower structure fault corridors, intruded by Upper Triassic salt. Petroleum system modelling and time events chart reconstruction of real and pseudo-wells, indicate that Cretaceous source rocks maturation and hydrocarbon generation began during Late Cretaceous with expulsion occurring from Eocene to Pliocene times. Hence, Upper Cretaceous petroleum system dynamics is intimately linked to basin geodynamics; where hydrocarbon migration pathways could follow the migration, rotation and tilting of platform and basin blocks. The volume of Lower Fahden and Bahloul source rocks expelled hydrocarbons from the basin kitchens, is much greater than that found in the drilled anticlinal axis. These hydrocarbons could have been trapped along the platform-basin border flanks and may not have reached the highest position on the anticlinal crest closure. Such pathways explain the unaccounted-for hydrocarbon volumes. These volumes could be trapped along the faults seal branches, unconformities, pinchouts as well as in the evidenced progradational and reefal system tracts sequences in the flank borders of the platforms. These traps could represent new exploration targets as potential structural and stratigraphic plays.

突尼斯东部边缘被认为是上白垩纪和始新世的石油省。它受到中生代裂谷作用和新生代挤压作用的影响。在构造背斜闭合带内的上白垩纪碳酸盐岩中发现了一些油气显示和聚集。这些背斜高点代表了具有间断、不整合和沉积物侵蚀的继承裂谷平台地垒。中新生代地层的地震序列地层学和地震构造分析,描绘了上三叠统盐侵入的深层张拉和挤压Flower结构断裂走廊的控制。真实井和伪井的石油系统建模和时间事件图重建表明,白垩纪烃源岩成熟和生烃始于晚白垩世,排烃发生在始新世至上新世。因此,上白垩纪油气系统动力学与盆地地球动力学密切相关;其中油气运移路径可以遵循平台和盆地块体的运移、旋转和倾斜。Lower Fahden和Bahloul烃源岩从盆地厨房排出的碳氢化合物的体积远大于钻探背斜轴中发现的体积。这些碳氢化合物可能沿着平台-盆地边界侧翼被捕获,可能没有到达背斜顶部闭合的最高位置。这些途径解释了碳氢化合物体积的下落不明。这些体积可能沿着断层封闭分支、不整合面、尖灭面以及平台侧翼边界的已证明的进积和退积系统域序列被捕获。这些圈闭可能代表新的勘探目标,作为潜在的构造和地层区块。
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引用次数: 2
Modified Laponite synthesized with special wettability as a multifunctional additive in oil-based drilling fluids 具有特殊润湿性的改性褐铁矿作为油基钻井液多功能添加剂的合成
2区 工程技术 Q1 Earth and Planetary Sciences Pub Date : 2023-01-01 Epub Date: 2022-11-05 DOI: 10.1016/j.petrol.2022.111211
Xiaoxiao Ni, He Shi, Jiaqi Zhang, Rentong Liu, Jianhua Wang, Rongchao Cheng

In this study, Modified Laponite with lyophobic wettability was synthesized as a multi-functional additive to solve instability of emulsions, rheological deterioration, and wellbore instability of oil-based drilling fluid. Properties and its influence on emulsion stability, rheological behavior and plugging property were investigated. The results showed that Modified Laponite was in a shape of sheet layer and had micro-meter length and nano-meter thickness which was in match with the diameter of shale pores. And it was proved to be resistant to approximately 450 °C by thermogravimetric analysis measurement. Mechanism analysis revealed that Modified Laponite could stable the oil-based drilling fluid through four sections. Firstly, Modified Laponite with lyophobic wettability could promote its existence in the interface of brine/mineral oil. Secondly, Modified Laponite could decrease the interfacial tension from 32.8 to 13.5 mN/m to maintain the emulsion particles in a small size for a long time then to ensure the emulsion stability. Thirdly, Modified Laponite could enhance the shear-thinning rheological behavior which could maintain the rheological stability and enhance the sedimentation stability in ultra-deep reservoirs with high temperature and high pressure conditions. Fourthly, Modified Laponite could plug the shale pores effectively by preventing pressure transmission and enhancing shale compressive strength, and decrease the filtration volume of oil-based drilling fluid from 7.4 mL to 2.6 mL after aging at 180 °C for 16 h to stable the wellbore. Therefore, Modified Laponite was a multifunctional additive to stable the emulsion, enhance the rheological stability and strength the wellbore stability, which could ensure the application of oil-based drilling fluid in drilling process of ultra-deep reservoirs.

本研究合成了具有疏液润湿性的改性Laponite作为一种多功能添加剂,以解决油基钻井液的乳液不稳定性、流变劣化和井筒不稳定性。研究了乳液的性质及其对乳液稳定性、流变性能和封堵性能的影响。结果表明,改性后的Laponite呈片状,具有微米级长度和纳米级厚度,与页岩孔隙直径相匹配。通过热重分析测量,它被证明能耐受约450°C。机理分析表明,改性Laponite能使油基钻井液稳定四段。首先,具有疏液润湿性的改性Laponite可以促进其在盐水/矿物油界面中的存在。其次,改性Laponite可以将界面张力从32.8降低到13.5mN/m,使乳液颗粒长时间保持小尺寸,从而确保乳液的稳定性。第三,改性Laponite可以增强剪切变稀流变行为,在高温高压条件下保持超深层储层的流变稳定性,增强沉积稳定性。第四,改性Laponite可以通过防止压力传递和提高页岩抗压强度来有效堵塞页岩孔隙,并将油基钻井液在180°C老化16h后的过滤量从7.4mL降低到2.6mL,以稳定井筒。因此,改性Laponite是一种稳定乳化液、增强流变稳定性、增强井筒稳定性的多功能添加剂,可以保证油基钻井液在超深储层钻井过程中的应用。
{"title":"Modified Laponite synthesized with special wettability as a multifunctional additive in oil-based drilling fluids","authors":"Xiaoxiao Ni,&nbsp;He Shi,&nbsp;Jiaqi Zhang,&nbsp;Rentong Liu,&nbsp;Jianhua Wang,&nbsp;Rongchao Cheng","doi":"10.1016/j.petrol.2022.111211","DOIUrl":"10.1016/j.petrol.2022.111211","url":null,"abstract":"<div><p><span><span>In this study, Modified Laponite with lyophobic wettability<span> was synthesized as a multi-functional additive to solve instability of emulsions, rheological deterioration, and wellbore instability of oil-based drilling fluid. Properties and its influence on emulsion stability, </span></span>rheological behavior<span> and plugging property were investigated. The results showed that Modified Laponite was in a shape of sheet layer and had micro-meter length and nano-meter thickness which was in match with the diameter of shale pores. And it was proved to be resistant to approximately 450 °C by thermogravimetric analysis<span> measurement. Mechanism analysis revealed that Modified Laponite could stable the oil-based drilling fluid through four sections. Firstly, Modified Laponite with lyophobic wettability could promote its existence in the interface of brine/mineral oil. Secondly, Modified Laponite could decrease the interfacial tension from 32.8 to 13.5 mN/m to maintain the emulsion particles in a small size for a long time then to ensure the emulsion stability. Thirdly, Modified Laponite could enhance the shear-thinning rheological behavior which could maintain the rheological stability and enhance the sedimentation stability in ultra-deep reservoirs with high temperature and high pressure conditions. Fourthly, Modified Laponite could plug the shale pores effectively by preventing pressure transmission and enhancing shale </span></span></span>compressive strength, and decrease the filtration volume of oil-based drilling fluid from 7.4 mL to 2.6 mL after aging at 180 °C for 16 h to stable the wellbore. Therefore, Modified Laponite was a multifunctional additive to stable the emulsion, enhance the rheological stability and strength the wellbore stability, which could ensure the application of oil-based drilling fluid in drilling process of ultra-deep reservoirs.</p></div>","PeriodicalId":16717,"journal":{"name":"Journal of Petroleum Science and Engineering","volume":"220 ","pages":"Article 111211"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43614920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
Journal of Petroleum Science and Engineering
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